JPS62250112A - Gas blowing plug - Google Patents

Gas blowing plug

Info

Publication number
JPS62250112A
JPS62250112A JP9385486A JP9385486A JPS62250112A JP S62250112 A JPS62250112 A JP S62250112A JP 9385486 A JP9385486 A JP 9385486A JP 9385486 A JP9385486 A JP 9385486A JP S62250112 A JPS62250112 A JP S62250112A
Authority
JP
Japan
Prior art keywords
plug body
plug
refractory
heat conduction
disposed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP9385486A
Other languages
Japanese (ja)
Inventor
Nobunari Asano
浅野 信成
Hironori Fukushima
裕法 福島
Suehiro Yamada
山田 末広
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Engineering Corp
TYK Corp
Original Assignee
NKK Corp
Nippon Kokan Ltd
TYK Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NKK Corp, Nippon Kokan Ltd, TYK Corp filed Critical NKK Corp
Priority to JP9385486A priority Critical patent/JPS62250112A/en
Publication of JPS62250112A publication Critical patent/JPS62250112A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D1/00Treatment of fused masses in the ladle or the supply runners before casting
    • B22D1/002Treatment with gases
    • B22D1/005Injection assemblies therefor

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Treatment Of Steel In Its Molten State (AREA)
  • Carbon Steel Or Casting Steel Manufacturing (AREA)

Abstract

PURPOSE:To prevent the deterioration and damage of a shell by disposing a heat conduction blocking material consisting of low heat conductive refractories between the shell disposed to the bottom surface side and side surface of a plug body and the plug body. CONSTITUTION:This gas blowing plug is constituted of the plug body 21 consisting of the carbonaceous refractories having many through-holes 22 penetrating the plug from the base side to the top surface side, the shell 28 disposed to at least the base side and side face side of the plug body 21 and the heat conduction blocking material 23 consisting of the low heat conductive refractories interposed between the shell 28 and the plug body 21. This heat conduction blocking material 23 has <=2.5kcal/mhr deg.C heat conductivity at 1,000 deg.C and is constituted of a truncated cone-shaped porous refractories 24 disposed on the base side of the plug body 21 and sleeve-shaped dense refractories 25 disposed to the peripheral side face side of the plug body 21.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、容器の底壁または側壁に取付けられ、容鼎内
の溶湯中にガスを吹込んで溶湯のガス撹拌等を行なうガ
ス吹込みプラグに関する。
Detailed Description of the Invention (Industrial Application Field) The present invention relates to a gas injection plug that is attached to the bottom wall or side wall of a container and that blows gas into the molten metal in the container to stir the molten metal. Regarding.

(従来の技術) この種ガス吹込みプラグにおいては、従来、耐火粒子相
互を少量の微粉で結合させたポーラスレンガを耐火物と
して用いたポーラスプラグが多用されていた。
(Prior Art) In this type of gas injection plug, porous plugs using porous bricks, in which refractory particles are bonded to each other with a small amount of fine powder, are conventionally used as a refractory.

ところが、近年、耐用向上のために、第2図に示すよう
に、ち密質の耐火物に多数の貫通細孔1を形成してプラ
グ本体2を構成した貫通孔プラグが見直されるようにな
った。この貫通孔プラグのプラグ本体2を構成する耐火
物の材質としては、AQ20コーC,Mg0−C等の黒
鉛を含んだものが溶融金I2!(溶鋼)とのぬれ性に優
れている点(黒鉛は液体をはじき易い。)で注目されて
いる。
However, in recent years, in order to improve durability, as shown in Figure 2, through-hole plugs in which the plug body 2 is formed by forming a large number of through-holes 1 in a dense refractory material have been reviewed. . The refractory material constituting the plug body 2 of this through-hole plug is molten gold I2!, which contains graphite such as AQ20 Co-C and Mg0-C. It is attracting attention for its excellent wettability with (molten steel) (graphite easily repels liquids).

(発明が解決しようとする問題点) しかしながら、含炭素質の耐火物は熱伝導性が良いため
、プラグ使用時の赤熱度が高くなり、耐火物を囲む鉄皮
3,4の劣化、鉄皮3と鉄皮4との溶接部5の劣化、お
よび鉄皮4とガス導入管6との溶接部7の劣化が生じ易
く、その結果として、損耗により耐用が限られるのでは
なく、その鉄皮3,4からのガスリーク発生によって耐
用が限られていた。第3図に、VAD (Vacuua
+ ArcDegassing)操業の3チヤージ目に
生じた鉄皮劣化状態を示す。
(Problem to be solved by the invention) However, since carbon-containing refractories have good thermal conductivity, the degree of redness increases when the plug is used, leading to deterioration of the iron shells 3 and 4 surrounding the refractory, and 3 and the steel shell 4, and the weld 7 between the steel shell 4 and the gas introduction pipe 6. Its service life was limited due to gas leaks from parts 3 and 4. Figure 3 shows the VAD (Vacuua
+ArcDegassing) Shows the state of deterioration of the iron shell that occurred during the third charge of operation.

そこで、第4図に示すように、含黒鉛耐火物(含炭素質
耐火物)に貫通細孔11を形成してなるプラグ本体12
の周側面部に八β203を90%含むスリーブ状の耐火
物(低熱伝導性耐火物)13を配設し、その周囲に鉄皮
14,15を設けた構成の貫通孔プラグが提案された。
Therefore, as shown in FIG. 4, a plug body 12 is formed by forming through holes 11 in a graphite-containing refractory (carbon-containing refractory).
A through-hole plug has been proposed in which a sleeve-shaped refractory (low thermal conductivity refractory) 13 containing 90% of 8β203 is disposed on the peripheral side surface of the refractory, and iron skins 14 and 15 are provided around the sleeve-shaped refractory 13.

この貫通孔プラグにおいては、VAD操業の4チヤージ
目にガスリークが生じた。また、その使用後量について
調べたところ、第2図に示すものと比較して、側面鉄皮
14の酸化・劣化、側面鉄皮14の頂部の溶損・亀裂に
ついては大幅に減少していたが、側面鉄皮14と底面鉄
皮15との溶接部16、底面鉄皮15とガス供給管17
との溶接部18の劣化により亀裂が生じ、また底面鉄皮
15も酸化していた。なお、この使用後量を回収する時
、プラグ下部の押えレンガを外した時点での底面鉄皮1
5は完全に赤熱しており、その時点で800℃以上であ
った。したがって、使用時は1100℃以上であったと
推察される。
In this through-hole plug, a gas leak occurred during the fourth charge of VAD operation. In addition, when we investigated the amount after use, we found that the oxidation and deterioration of the side iron skin 14 and the erosion and cracking of the top of the side iron skin 14 were significantly reduced compared to those shown in Figure 2. However, the welded part 16 between the side iron skin 14 and the bottom iron skin 15, the bottom iron skin 15 and the gas supply pipe 17
Deterioration of the welded part 18 caused cracks, and the bottom iron skin 15 was also oxidized. In addition, when collecting this amount after use, the bottom iron skin 1 at the time when the holding brick at the bottom of the plug is removed.
No. 5 was completely red hot and the temperature was 800° C. or higher at that point. Therefore, it is presumed that the temperature was 1100°C or higher during use.

本発明は前記事情にもとづいてなされたもので、その目
的とするところは、鉄皮の劣化・損傷を防止することが
できるガス吹込みプラグを提供することにある。
The present invention was made based on the above-mentioned circumstances, and an object thereof is to provide a gas injection plug that can prevent deterioration and damage to the iron shell.

(問題点を解決するための手段) 本発明は、前記問題点を解決するために、下面側から上
面側に貫通する多数の貫通細孔を有した含炭素質耐火物
からなるプラグ本体の少なくとも下面側および側面側に
鉄皮を配設したガス吹込みプラグにおいて、前記鉄皮と
前記プラグ本体との間に、低熱伝導性耐火物からなる熱
伝導阻止部材を配設したことを特徴とするものである。
(Means for Solving the Problems) In order to solve the above problems, the present invention provides at least one plug body made of a carbon-containing refractory having a large number of through holes penetrating from the lower surface side to the upper surface side. A gas blowing plug in which a steel shell is provided on the lower surface side and the side surface side, characterized in that a heat conduction blocking member made of a low thermal conductive refractory is disposed between the steel shell and the plug body. It is something.

(作用) 低熱伝導性耐火物からなる熱伝導阻止部材の介在によっ
て、熱伝導性の良い含炭素質耐火物からなるプラグ本体
からの熱を鉄皮に伝わり難くする。
(Function) The interposition of the heat conduction blocking member made of a low heat conductive refractory makes it difficult for heat from the plug body made of a carbon-containing refractory with good heat conductivity to be transmitted to the iron skin.

(実施例) 以下、本発明の一実施例を第1図を参照しながら説明す
る。
(Example) An example of the present invention will be described below with reference to FIG.

第1図中21は底面側から上面側に貫通する多数の貫通
細孔22を有した円錐台状のプラグ本体であり、このプ
ラグ本体21は含炭素質耐火物で形成されている。この
プラグ本体21の底面側および周側面側には低熱伝導性
耐火物からなる熱伝導阻止部材23が配設されている。
Reference numeral 21 in FIG. 1 is a truncated conical plug body having a large number of through holes 22 penetrating from the bottom side to the top side, and this plug body 21 is made of a carbonaceous refractory. A heat conduction blocking member 23 made of a low heat conductive refractory is disposed on the bottom side and the circumferential side of the plug body 21.

この熱伝導阻止部材23は、1000℃における熱伝導
率が2.5kcal/ mhr’c以下のものであり、
プラグ本体21の底面側に配置される円錐台状の多孔質
耐火物24と、プラグ本体21の周側面側に配置される
スリーブ状のち密質耐火物25とで構成されている。な
お、プラグ本体21の底面とち密質耐火物25の上面と
の間にはスペーサ26が介在され、これにより均圧室2
7が形成されている。
This heat conduction blocking member 23 has a thermal conductivity of 2.5 kcal/mhr'c or less at 1000°C,
It is composed of a truncated cone-shaped porous refractory 24 disposed on the bottom side of the plug body 21 and a sleeve-shaped dense refractory 25 disposed on the circumferential side of the plug body 21. Note that a spacer 26 is interposed between the bottom surface of the plug body 21 and the top surface of the dense refractory 25, so that the pressure equalization chamber 2
7 is formed.

また、熱伝導阻止部材23の周側面側および底面側には
、シール鉄皮28が配設されている。
Further, a sealing iron skin 28 is provided on the circumferential side and the bottom side of the heat conduction blocking member 23.

このシール鉄皮28は、熱伝導阻止部材230周a面側
に配設ざルる側面鉄皮29と、熱伝導阻止部材28の底
面側に配設される底面鉄皮30とで構成され、側面鉄皮
29と底面鉄皮30とは溶接部31により接合されてい
る。底面鉄皮30は熱伝導阻止部材23の底面から離間
して配設されており、これにより底面鉄皮30と熱伝導
阻止部材23の底面との間に均圧室32が形成されてい
る。
This seal skin 28 is composed of a side skin 29 disposed on the side a of the circumference of the heat conduction blocking member 230, and a bottom steel skin 30 disposed on the bottom side of the heat conduction blocking member 28. The side iron skin 29 and the bottom iron skin 30 are joined by a welded portion 31. The bottom iron skin 30 is arranged apart from the bottom surface of the heat conduction blocking member 23, thereby forming a pressure equalizing chamber 32 between the bottom iron skin 30 and the bottom surface of the heat conduction blocking member 23.

また、底面鉄皮30には均圧室32内にガスを導入する
ガス導入管33が溶接部34により接続されている。
Further, a gas introduction pipe 33 for introducing gas into the pressure equalization chamber 32 is connected to the bottom iron skin 30 by a welded portion 34 .

このように構成されたガス吹込みプラグとしての貫通孔
プラグは取鍋の底壁あるいはIll壁に取付けられ、ガ
ス導入!33から均圧室32内に吹込みガスが導入され
る。この導入されたガスは多孔質耐火物24を通って均
圧室27に導入され、ざらにプラグ本体21の貫通細孔
22を通うて取鋼内の溶鋼中に吹込まれ、これによって
mMの撹拌等が行われる。
The through-hole plug as a gas blowing plug configured in this way is attached to the bottom wall or Ill wall of the ladle, and gas is introduced! Blow gas is introduced into the pressure equalization chamber 32 from 33 . This introduced gas is introduced into the pressure equalization chamber 27 through the porous refractory 24, and is roughly blown into the molten steel in the tapped steel through the through holes 22 of the plug body 21, thereby stirring the mm. etc. will be carried out.

このプラグ使用状態においては、プラグ本体21の先端
が溶鋼に接しているが、このプラグ本体21は溶融金属
とのぬれ性に優れている含炭素質耐火物で形成されてい
るため、溶鋼をはじき易い。したがって、貫通細孔22
に溶鋼が浸入して貫通細孔22が閉塞されるということ
がない。
When this plug is in use, the tip of the plug body 21 is in contact with the molten steel, but since the plug body 21 is made of a carbon-containing refractory that has excellent wettability with molten metal, it repels the molten steel. easy. Therefore, the through hole 22
There is no possibility that molten steel will infiltrate and block the through pores 22.

一方、プラグ本体21の先端が溶鋼に接していることか
ら、溶鋼からの熱が熱伝導性の良い含炭素質耐火物から
なるプラグ本体21に伝えられることになる。しかしな
がら、プラグ本体21と鉄皮28との間には、低熱伝導
性耐火物からなる熱伝導阻止部材23が介在されている
ので、プラグ本体21からの熱が鉄皮28に伝わり難い
。したがって、鉄皮28の劣化・損傷を防止することを
防止することができる。
On the other hand, since the tip of the plug body 21 is in contact with the molten steel, heat from the molten steel is transferred to the plug body 21 made of a carbonaceous refractory with good thermal conductivity. However, since the heat conduction blocking member 23 made of a low thermally conductive refractory is interposed between the plug body 21 and the iron skin 28, the heat from the plug body 21 is difficult to be transmitted to the iron skin 28. Therefore, deterioration and damage to the iron skin 28 can be prevented.

次に実験例を説明する。Next, an experimental example will be explained.

(実験例1) プラグ本体21は、AJ2203が75%、Cが15%
含有され、かつ1000°Cにおける熱伝導率が11.
0kcal/mhr℃、高さが20On+mである耐火
物で、ち茫質耐火物25は、A2203が90%含有さ
れ、かつ1000℃における熱伝導率が1.8kcal
/”lllhr℃である耐火物で、 多孔質耐火物24は、A2203が91%含有され、か
ツ1000℃における熱伝導率が0.8kca17’m
hr’c高さが100+uである耐火物で、スペーサ2
6は、八2203が85%含有され、かつ高さが3++
+s+である耐火モルタルで、側面鉄皮29は、厚さ0
.8mmの5tJS304で、 底面鉄皮3oは、厚さ4.5mmの5S41で、溶接部
31.34の材質は、5US309で、それぞれ構成し
たところ、VAD (fi高温度1620℃、ガス吹込
み時間30分)操業にて10チヤージ使用可能であった
。この場合、ガスリークの発生はなく、回収時における
押えレンガを外したときの赤熱度は低く、600〜70
0℃と推察される。
(Experiment Example 1) The plug body 21 is made of 75% AJ2203 and 15% C.
and has a thermal conductivity of 11.
A refractory with a temperature of 0 kcal/mhr°C and a height of 20 On+m, the somber refractory 25 contains 90% A2203 and has a thermal conductivity of 1.8 kcal at 1000°C.
Porous refractory 24 contains 91% A2203 and has a thermal conductivity of 0.8kca17'm at 1000℃.
Spacer 2 is made of refractory material with an hr'c height of 100+u.
6 contains 85% of 82203 and has a height of 3++
+s+ refractory mortar, side iron skin 29 has a thickness of 0
.. The bottom steel shell 3o was made of 5S41 with a thickness of 4.5mm, and the material of the welded part 31.34 was made of 5US309. 10 charges could be used during operation. In this case, there is no gas leak, and the degree of redness is low when the holding brick is removed during recovery, with a temperature of 600 to 70.
It is estimated to be 0℃.

また、プラグ本体21の残存寸法は 180+1101
であった。
Also, the remaining dimensions of the plug body 21 are 180+1101
Met.

(実験例2) プラグ本体21は、Mgoが76%、C、I’)(19
,5%含有され、かつ1000℃における熱伝導率が1
3.0kcal、/ mhr’C1高さが200mmで
ある耐火物で構成し、 ち密質耐火物25は、Aj2zO3が96%含有され、
かつ1000℃における熱伝導率が2.3kcal/m
 h r ’Cである耐火物であって、プラグ本体21
の周面および多孔質耐火物25の周面にパラフィンを薄
くコートしておき、これを中心体として外周部にキャス
タブルを流し込み、その後乾燥したものである。
(Experiment Example 2) The plug body 21 contains 76% Mgo, C, I') (19
, 5%, and the thermal conductivity at 1000°C is 1.
3.0 kcal, / mhr'C1 It is composed of a refractory with a height of 200 mm, and the dense refractory 25 contains 96% Aj2zO3,
And the thermal conductivity at 1000℃ is 2.3kcal/m
The plug body 21 is a refractory which is h r 'C.
The peripheral surface of the porous refractory material 25 and the peripheral surface of the porous refractory material 25 are thinly coated with paraffin, and castable is poured around the outer periphery using this as a center body, followed by drying.

その他の多孔質耐火物24、スペーサ26、側面鉄皮2
9、底面鉄皮30、溶接部31.34の材質、および使
用条件は実験例1と同様としたところ、プラグは使用後
も良好(プラグ本体21の残存寸法200mm )であ
った。実験例1より若干鉄皮28の劣化は大であったが
、更に2〜3チヤージは使用可能と思われた。
Other porous refractories 24, spacers 26, side iron skins 2
9. The materials of the bottom iron skin 30, the welded parts 31 and 34, and the conditions of use were the same as in Experimental Example 1, and the plug remained in good condition even after use (the remaining size of the plug body 21 was 200 mm). Although the deterioration of the iron skin 28 was slightly greater than in Experimental Example 1, it seemed possible to use it for 2 to 3 more charges.

なお、実験例1、実験例2ともに細孔径は0.2mmと
したが、予めプラグ本体21の頂部も鉄皮(厚さ2n+
ll1)で囲うようにしたプラグにおいては、細孔径を
0.3mmとしたところ、良好の結果が1qられた。こ
れは初期酸化を防ぐために行われたものであるが、結果
的に受鋼の際、溶鋼がこの頂部の鉄皮を溶かすのに熱を
とられ細孔へ入る溶鋼の粘性を高めたものと考えられる
。2チヤージ目以降は頂部を覆うように鉄板を2〜3枚
投入したところ、5チヤージまで使用することができた
In addition, although the pore diameter was set to 0.2 mm in both Experimental Examples 1 and 2, the top of the plug body 21 was also made of iron skin (thickness 2n+
In the plug surrounded by ll1), good results were obtained when the pore diameter was set to 0.3 mm. This was done to prevent initial oxidation, but as a result, when receiving the steel, the molten steel was heated as it melted the iron skin at the top, increasing the viscosity of the molten steel entering the pores. Conceivable. After the 2nd charge, I put 2 to 3 iron plates to cover the top and was able to use it up to 5 charges.

(発明の効巣) 以上説明したように本発明によれば、底面側から上面側
に貫通する多数の貫通細孔を有した含炭素質耐火物から
なるプラグ本体と、このプラグ本体の少なくとも底面側
および側面側に配設される鉄皮と、この鉄皮と前記プラ
グ本体との間に介在される低熱伝導性耐火物からなる熱
伝導阻止部材とを具漏したから、低熱伝導性耐火物から
なる熱伝導阻止部材の介在によって、熱伝導性の良い含
炭素質耐火物からなるプラグ本体からの熱を鉄皮に伝わ
り難くすることができ、以て、鉄皮の劣化・損傷を防止
することができる等の優れた効果を奏する。
(Effects of the Invention) As explained above, according to the present invention, there is provided a plug body made of a carbonaceous refractory having a large number of through holes penetrating from the bottom side to the top side, and at least the bottom side of the plug body. Since the iron skin disposed on the sides and the side surface side and the heat conduction blocking member made of a low thermal conductive refractory interposed between the iron skin and the plug body are omitted, the low thermal conductive refractory is By interposing the heat conduction blocking member made of a heat conduction prevention member, it is possible to make it difficult for the heat from the plug body made of a carbon-containing refractory with good thermal conductivity to be transmitted to the steel shell, thereby preventing deterioration and damage of the steel shell. It has excellent effects such as:

【図面の簡単な説明】[Brief explanation of drawings]

第1因は本発明の一実施例を示すガス吹込みプラグの断
面図、第25iiIは従来のガス吹込みプラグを示す断
面図、第3図は従来のガス吹込みプラグの使用後の状態
を示す斜視図、第4図は本発明に先行して提案されたガ
ス吹込みプラグである。 21・・・プラグ本体、22・・・貫通細孔、28・・
・鉄皮、23・・・熱伝導阻止部材、24・・・多孔質
耐火物、25・・・ち密質耐火物。 出願人代理人  弁理士 鈴江武彦 第1図
The first factor is a cross-sectional view of a gas blowing plug showing an embodiment of the present invention, No. 25iii is a cross-sectional view showing a conventional gas blowing plug, and Fig. 3 shows the state of the conventional gas blowing plug after use. The perspective view shown in FIG. 4 is a gas blowing plug proposed prior to the present invention. 21...Plug body, 22...Through hole, 28...
- Iron skin, 23... Heat conduction blocking member, 24... Porous refractory, 25... Dense refractory. Applicant's agent Patent attorney Takehiko Suzue Figure 1

Claims (3)

【特許請求の範囲】[Claims] (1)底面側から上面側に貫通する多数の貫通細孔を有
した含炭素質耐火物からなるプラグ本体と、このプラグ
本体の少なくとも底面側および側面側に配設される鉄皮
と、この鉄皮と前記プラグ本体との間に介在される低熱
伝導性耐火物からなる熱伝導阻止部材とを具備したこと
を特徴とするガス吹込みプラグ。
(1) A plug body made of a carbonaceous refractory having a large number of through holes penetrating from the bottom side to the top side, an iron skin disposed at least on the bottom side and side sides of the plug body, and A gas injection plug comprising a heat conduction blocking member made of a low heat conductive refractory interposed between the iron shell and the plug body.
(2)熱伝導阻止部材は、1000℃における熱伝導率
が2.5kcal/mhr℃以下であることを特徴とす
る特許請求の範囲第1項記載のガス吹込みプラグ。
(2) The gas blowing plug according to claim 1, wherein the heat conduction blocking member has a thermal conductivity of 2.5 kcal/mhr°C or less at 1000°C.
(3)熱伝導阻止部材は、プラグ本体の底面側に配置さ
れる多孔質耐火物と、プラグ本体の側面側に配置される
ち密質耐火物とで構成したことを特徴とする特許請求の
範囲第1項記載のガス吹込みプラグ。
(3) Claims characterized in that the heat conduction blocking member is composed of a porous refractory disposed on the bottom side of the plug body and a dense refractory disposed on the side surface side of the plug body. The gas injection plug described in item 1.
JP9385486A 1986-04-23 1986-04-23 Gas blowing plug Pending JPS62250112A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP9385486A JPS62250112A (en) 1986-04-23 1986-04-23 Gas blowing plug

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP9385486A JPS62250112A (en) 1986-04-23 1986-04-23 Gas blowing plug

Publications (1)

Publication Number Publication Date
JPS62250112A true JPS62250112A (en) 1987-10-31

Family

ID=14094002

Family Applications (1)

Application Number Title Priority Date Filing Date
JP9385486A Pending JPS62250112A (en) 1986-04-23 1986-04-23 Gas blowing plug

Country Status (1)

Country Link
JP (1) JPS62250112A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05140662A (en) * 1991-01-28 1993-06-08 Tokyo Yogyo Co Ltd Refractory for gas blowing
WO2004079019A3 (en) * 2003-03-06 2004-11-11 Techcom Imp Exp Gmbh Gas bubbling element and corresponding gas bubbling system

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05140662A (en) * 1991-01-28 1993-06-08 Tokyo Yogyo Co Ltd Refractory for gas blowing
WO2004079019A3 (en) * 2003-03-06 2004-11-11 Techcom Imp Exp Gmbh Gas bubbling element and corresponding gas bubbling system
JP2006519930A (en) * 2003-03-06 2006-08-31 テクコム・インポート・エクスポート・ゲーエムベーハー Gas purging element (GASBUBLINGELEMENT) and corresponding gas purging system

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