JPS62249045A - Method and instrument for detecting moisture in oil - Google Patents
Method and instrument for detecting moisture in oilInfo
- Publication number
- JPS62249045A JPS62249045A JP9131586A JP9131586A JPS62249045A JP S62249045 A JPS62249045 A JP S62249045A JP 9131586 A JP9131586 A JP 9131586A JP 9131586 A JP9131586 A JP 9131586A JP S62249045 A JPS62249045 A JP S62249045A
- Authority
- JP
- Japan
- Prior art keywords
- oil
- gas sensor
- microporous filter
- moisture
- electric resistance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 15
- 239000000919 ceramic Substances 0.000 claims abstract description 8
- 229920005989 resin Polymers 0.000 claims abstract description 5
- 239000011347 resin Substances 0.000 claims abstract description 5
- 229910052751 metal Inorganic materials 0.000 claims abstract description 4
- 239000002184 metal Substances 0.000 claims abstract description 4
- 239000005373 porous glass Substances 0.000 claims abstract description 4
- 239000003921 oil Substances 0.000 claims description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 239000010687 lubricating oil Substances 0.000 claims description 10
- 238000001514 detection method Methods 0.000 claims description 5
- 239000007789 gas Substances 0.000 abstract description 17
- 229910052760 oxygen Inorganic materials 0.000 abstract description 5
- 239000001301 oxygen Substances 0.000 abstract description 3
- 239000004065 semiconductor Substances 0.000 abstract description 2
- 229910010252 TiO3 Inorganic materials 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 230000008929 regeneration Effects 0.000 description 5
- 238000011069 regeneration method Methods 0.000 description 5
- 239000011148 porous material Substances 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000010705 motor oil Substances 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
Landscapes
- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
Abstract
Description
【発明の詳細な説明】 発Ｊｊ （７） ４１忙九訪 本発明は、油中水分の検出法及びその装置に関する。[Detailed description of the invention] From Jj (7) 41 busy visit The present invention relates to a method and apparatus for detecting moisture in oil.
光期−昧用
現在油中の水分を測定する方法には、Ｊ Ｉ Ｓで定め
られている蒸留法、又は、カールフィッシャー法がある
。Methods for measuring the water content in oil during the photoperiod include the distillation method specified by JIS or the Karl Fischer method.
これらは、油をサンプリングし、一定の処理を施して、
油中の水分を測定するものであり、迅速に油中の水分ｈ
ｋを精度良く把握することが困難であった。These are made by sampling oil, applying certain treatments,
This is a device that measures the moisture in oil, and quickly determines the moisture content h in oil.
It was difficult to accurately grasp k.
」二記の改良法としては、特公昭５６−２５９８３号が
提案されているが、この方法もＬ ｉ Ｉ（を使用して
４０中の水分をＨ２ガスを発生させることにより、精度
良い値を求める分析方法である。”2 is proposed in Japanese Patent Publication No. 56-25983, but this method also generates H2 gas from the moisture in 40 using Li This is the desired analytical method.
いずれにしても、迅速分析は、困難である。In any case, rapid analysis is difficult.
本発明者等は、鋭意検討した結果、上記従来法の問題点
を解決すべく以下の発明をなした。As a result of intensive studies, the present inventors have made the following invention in order to solve the problems of the above-mentioned conventional method.
ｍへＭ栽。M-plant to m.
即ち、本発明は、ガスセンサの周囲にマイクロポーラス
フィルターを配置し、油中の水分を検出することを特徴
とする油中水分の検出法に関する。That is, the present invention relates to a method for detecting moisture in oil, which is characterized by arranging a microporous filter around a gas sensor and detecting moisture in oil.
また、その実施態様としては、ガスセンサが。Further, an embodiment thereof is a gas sensor.
電気抵抗式又は、非電気抵抗式からなるものであること
を特徴とする上記油中水分の検出法、マイクロポーラス
フィルターが、樹脂性あるいは、セラミック性、多孔ガ
ラス、多孔金属であることを特徴とする上記油中水分の
検出法、油が、自動車用又は船舶用潤滑油であることを
特徴とする上記油中水分の検出法である。The above method for detecting moisture in oil is characterized by being of an electrical resistance type or a non-electric resistance type, and characterized in that the microporous filter is made of resin, ceramic, porous glass, or porous metal. The method for detecting moisture in oil is characterized in that the oil is lubricating oil for automobiles or ships.
さらに他の発明としては、ガスセンサーの周囲にマイク
ロポーラスフィルターを配置し、潤滑油中の水分データ
が、自動車の運転席で把握できることからなることを特
徴とする油中水分の検出装置を提供する。Still another invention provides a detection device for moisture in oil, characterized in that a microporous filter is arranged around a gas sensor so that moisture data in lubricating oil can be grasped from the driver's seat of an automobile. .
四の °ｒ・な１日
本発明における水分の検出法は、油中の水分をガスセン
サの周囲に配置したマイクロポーラスフィルターを選択
的に通過する水蒸気を該センサにより検知するのである
。The moisture detection method in the Japanese invention uses a gas sensor to detect water vapor that selectively passes through a microporous filter disposed around a gas sensor.
マイクロポーラスフィルターは、樹脂性のものあるいは
、セラミック性、多孔ガラス性、多孔金属性のものが用
いられる。The microporous filter used is one made of resin, ceramic, porous glass, or porous metal.
樹脂性のものは、素子部分については使い捨て方式で使
用される。The resin type is used in a disposable manner for the element portion.
この例としては、シリコン樹脂、アクリル樹脂、フッ素
樹脂等高分子材料が用いられる。Examples of this material include polymeric materials such as silicone resin, acrylic resin, and fluororesin.
セラミックフィルターとしては、Ａｌ、０３．Ｚｒｏ、
、ＴｉＯ，等のものが使用される。As the ceramic filter, Al, 03. Zro,
, TiO, etc. are used.
これらの細孔径は、０．０１〜１．０μｍ前後のものが
、使用される。即ち、油や水等の液体は通過せず水蒸気
が通過できる孔径である。The diameter of these pores used is approximately 0.01 to 1.0 μm. In other words, the pore size is such that liquids such as oil and water cannot pass through, but water vapor can pass through.
ガスセンサとしては、電気抵抗式、非電気抵抗式が用い
られる。As the gas sensor, an electric resistance type or a non-electric resistance type is used.
電気抵抗方式では、表面感応型、バルク感応型および酸
素イオン伝導型がある６０表面感応型としては、ＳｎＯ
，系、ＺｎＯ系、Ｖ、Ｏ，系等のセラミックタイプ等、
バルク感応型としては、多孔質焼結体Ｆｅｄ、系、Ｃｏ
Ｏ，系、Ｔ ｉ Ｏ，系等又。In the electrical resistance method, there are surface sensitive type, bulk sensitive type and oxygen ion conductive type.60 Surface sensitive type includes SnO
Ceramic types such as , ZnO, V, O, etc.
As the bulk sensitive type, porous sintered body Fed, system, Co
O, system, T i O, system, etc.
酸素イオン伝導型としては、ＺｒＯ□系、Ｙ、Ｏ。Examples of oxygen ion conductive types include ZrO□ series, Y, and O.
系がある。There is a system.
非電気抵抗方式では、金属−半導体、Ｐｄ−Ｔｉ０．等
、ガス感応性Ｐ ｄ −ＭＯＳ等がある。In the non-electrical resistance method, metal-semiconductor, Pd-Ti0. etc., gas-sensitive P d -MOS, etc.
対象とする油は、モーター油、ディーゼル油、舶用エン
ジン油等の潤滑油及び重油等である。The target oils include lubricating oils such as motor oil, diesel oil, and marine engine oil, as well as heavy oil.
例えば、潤滑油である場合は、自動車用あるいは船舶用
等広く対象となる。For example, in the case of lubricating oil, it can be used in a wide range of applications such as automobiles and ships.
検知器は、固定式あるいは携帯型のどちらでも良い。The detector can be either fixed or portable.
自動車用であれば、オイルパンに検知素子を設置し、運
転席でその水分を把握することができる。For automobiles, a detection element can be installed in the oil pan to detect moisture from the driver's seat.
通常自動車用では、１台につき３．５〜１ｏＱ前後の潤
滑油が用いられる。Normally, lubricating oil of around 3.5 to 1 oQ is used for each vehicle.
また、船舶用であれば、油をサンプリング後直ちに測定
するか、あるいは精製設備に設置し、劣化した潤滑油の
再生度合あるいは、再生のスタート時点を把握すること
ができる。船舶用の場合。In addition, for ships, it is possible to measure the oil immediately after sampling or to install it in a refining facility to determine the degree of regeneration of degraded lubricating oil or the starting point of regeneration. For ships.
船一杯につき２００Ｑ前後の潤滑油が用いられる。Approximately 200Q of lubricating oil is used per ship.
また、水分を測定するということは、その油の劣化の度
合をも間接的に把握することにもなる。Measuring moisture also indirectly determines the degree of deterioration of the oil.
通常測定の対象となる水分量は０．５％以下の場合が多
い。The moisture content that is normally measured is often 0.5% or less.
測定の温度は、０℃〜１００℃前後の場合が通常である
。The measurement temperature is usually around 0°C to 100°C.
油中の水分が、極めて少ない場合は、測定対象の油を一
定の容器内に配置せしめ、ガスセンサの周囲にマイクロ
ポーラスフィルターを配置した検知素子を配置し、油表
面を均等に加圧し、水蒸気がマイクロポーラスフィルタ
ーを選択的に通過し易いタイプとすることができる。If the water content in the oil is extremely low, place the oil to be measured in a certain container, place a detection element with a microporous filter around the gas sensor, and evenly pressurize the oil surface to prevent water vapor. It can be of a type that can selectively pass through a microporous filter.
また、これ等の装置は、防爆型としておくことが好まし
い。Further, it is preferable that these devices be explosion-proof.
以上のように本発明を用いることにより、以下の効果を
得ることができる。By using the present invention as described above, the following effects can be obtained.
充」Ｂ榎裏米
（１）油中の水分が迅速にかつ精度良く測定することが
できる。Mitsuru'B Enoki Uramai (1) Moisture in oil can be measured quickly and with high accuracy.
（２）油の劣化を早期に発見できるため、設備機器の保
安、ひいては交通安全上の意義がある。(2) Oil deterioration can be detected early, which is significant in terms of equipment security and traffic safety.
（３）油の再生において、再生スタート時、完了時の把
握に便利である。(3) In oil regeneration, it is convenient to know when regeneration starts and when regeneration is completed.
実施例１ 第１図をもって本発明の詳細な説明する。Example 1 The present invention will be explained in detail with reference to FIG.
潤滑油（１）中の水分を測定するため、アルミナ基台（
６）にガスセンサ（３）を設置し、その側面をセラミッ
クフィルター（４）で囲んだものを用いた。In order to measure the moisture in lubricating oil (1), an alumina base (
6) was equipped with a gas sensor (3) and its sides were surrounded by a ceramic filter (4).
ガスセンサは、ＳｎＯ，＋Ｐｄを用いて行った。The gas sensor used was SnO and +Pd.
油中の水分が、セラミックフィルター（ＡＩ。The water in the oil is removed by a ceramic filter (AI).
０３製の細孔径が平均４００人のもの）に囲まれた水蒸
気を検知することにより０．８重量％であることを実際
の油中の水分の直接分析値との変換値により迅速に求め
ることができた。By detecting the water vapor surrounded by the 0.03 pore size (with an average pore size of 400 people), it was possible to quickly determine that the water content was 0.8% by weight by converting the value from the direct analysis of the actual water content in the oil. was completed.
尚、８＋１１定は、リード線（５）から、結線された回
路により測定した。装置は、防爆タイプとした。The 8+11 constant was measured using a circuit connected from the lead wire (5). The equipment was explosion-proof.
第１図は、本発明の実施態様を示す。
ｊ−はｄｔ１滑浦、２はサーミスタ方式のセンサ一部、
；３はガスセンサー、４はポーラスフィルター、６はノ
１（板である。FIG. 1 shows an embodiment of the invention. j- is dt1 nameura, 2 is part of the thermistor type sensor,
3 is a gas sensor, 4 is a porous filter, and 6 is a plate.
Claims (5)
を配置し、油中の水分を検出することを特徴とする油中
水分の検出法。(1) A method for detecting moisture in oil, which is characterized by arranging a microporous filter around a gas sensor and detecting moisture in oil.
らなるものであることを特徴とする特許請求の範囲第１
項記載の油中水分の検出法。(2) Claim 1, characterized in that the gas sensor is of an electrical resistance type or a non-electric resistance type.
Method for detecting moisture in oil as described in Section 1.
、セラミック性、多孔ガラス、多孔金属であることを特
徴とする特許請求の範囲第１項記載の油中水分の検出法
。(3) The method for detecting water in oil according to claim 1, wherein the microporous filter is made of resin, ceramic, porous glass, or porous metal.
特徴とする特許請求の範囲第１項記載の油中水分の検出
法。(4) The method for detecting moisture in oil according to claim 1, wherein the oil is lubricating oil for automobiles or ships.
を配置し、潤滑油中の水分データが、自動車の運転席で
把握できることからなることを特徴とする油中水分の検
出装置。(5) A detection device for moisture in oil, characterized in that a microporous filter is arranged around a gas sensor so that moisture data in lubricating oil can be grasped from the driver's seat of an automobile.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9131586A JPS62249045A (en) | 1986-04-22 | 1986-04-22 | Method and instrument for detecting moisture in oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9131586A JPS62249045A (en) | 1986-04-22 | 1986-04-22 | Method and instrument for detecting moisture in oil |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62249045A true JPS62249045A (en) | 1987-10-30 |
Family
ID=14023031
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9131586A Pending JPS62249045A (en) | 1986-04-22 | 1986-04-22 | Method and instrument for detecting moisture in oil |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62249045A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010039345A1 (en) * | 2008-09-30 | 2010-04-08 | Qualitrol Company, Llc | Hydrogen sensor with air access |
| US8511160B2 (en) | 2011-03-31 | 2013-08-20 | Qualitrol Company, Llc | Combined hydrogen and pressure sensor assembly |
| US8707767B2 (en) | 2011-03-31 | 2014-04-29 | Qualitrol Company, Llc | Combined hydrogen and pressure sensor assembly |
| US8839658B2 (en) | 2011-03-31 | 2014-09-23 | Qualitrol Company, Llc | Combination of hydrogen and pressure sensors |
-
1986
- 1986-04-22 JP JP9131586A patent/JPS62249045A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010039345A1 (en) * | 2008-09-30 | 2010-04-08 | Qualitrol Company, Llc | Hydrogen sensor with air access |
| CN102165310A (en) * | 2008-09-30 | 2011-08-24 | 夸利特洛尔有限公司 | Hydrogen sensor with air access |
| US8028561B2 (en) | 2008-09-30 | 2011-10-04 | Qualitrol Company, Llc | Hydrogen sensor with air access |
| US8511160B2 (en) | 2011-03-31 | 2013-08-20 | Qualitrol Company, Llc | Combined hydrogen and pressure sensor assembly |
| US8707767B2 (en) | 2011-03-31 | 2014-04-29 | Qualitrol Company, Llc | Combined hydrogen and pressure sensor assembly |
| US8839658B2 (en) | 2011-03-31 | 2014-09-23 | Qualitrol Company, Llc | Combination of hydrogen and pressure sensors |
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