JPS62244414A - Engine fuel filter - Google Patents

Engine fuel filter

Info

Publication number
JPS62244414A
JPS62244414A JP61087272A JP8727286A JPS62244414A JP S62244414 A JPS62244414 A JP S62244414A JP 61087272 A JP61087272 A JP 61087272A JP 8727286 A JP8727286 A JP 8727286A JP S62244414 A JPS62244414 A JP S62244414A
Authority
JP
Japan
Prior art keywords
polyamide resin
nylon
sintered body
porous
resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP61087272A
Other languages
Japanese (ja)
Inventor
Makoto Hiyamizu
冷水 真
Kazuhiro Nagashima
長島 一博
Toshinobu Sugiyama
杉山 敏宣
Tsutomu Suyama
陶山 勉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toray Industries Inc
Nikko Rica Corp
Original Assignee
Toray Industries Inc
Nikko Rica Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toray Industries Inc, Nikko Rica Corp filed Critical Toray Industries Inc
Priority to JP61087272A priority Critical patent/JPS62244414A/en
Publication of JPS62244414A publication Critical patent/JPS62244414A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/14Other self-supporting filtering material ; Other filtering material
    • B01D39/16Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
    • B01D39/1638Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being particulate
    • B01D39/1653Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being particulate of synthetic origin
    • B01D39/1661Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being particulate of synthetic origin sintered or bonded

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Filtering Materials (AREA)

Abstract

PURPOSE:To provide an engine fuel filter to remove water content and fine foreign matters from the fuel completely by using a porous sintered material of polyamide resin or resin composition polyamide as main component. CONSTITUTION:Polyamide resin powder such as 6-6-nylon, 6-nylon, 6-10-nylon, 12-nylon and the like is used alone or as a mixture of more than two kinds, to which, if necessary, a little of other thermoplastic resin filler is added, and is cold compression molded in mold. The, in a state not oxidized (in high boiling oil, or in vacuum, or else in neutral atmosphere), above-said is heated up and sintered in a temperature less than melting point and more than flexing point of polyamide resin. By said process, a porous sintered material with continuous micro-pores is prepared. Said sintered material is superb in not only removing foreign matters but also in removing water content.

Description

【発明の詳細な説明】 〈産業上の利用分野〉 本発明は自動車カッリンエンジン用燃料フィルタ、自動
車ディーゼルエンジン用燃料フィルタ、およびトラクタ
ー、υ1運は、芝刈り機、発電機など汎用エンジンに用
いる燃料フィルタに関するものである。
[Detailed Description of the Invention] <Industrial Application Field> The present invention is applicable to fuel filters for automobile engines, fuel filters for automobile diesel engines, and general-purpose engines such as tractors, lawn mowers, and generators. This relates to fuel filters.

〈従来の技術〉 従来から自動車エンジン用燃料フィルタは合成繊維から
なる微細な網状、または金属製の網状、さらには特殊な
加工を施した濾紙状の濾過材が用いられている。
<Prior Art> Conventionally, fuel filters for automobile engines have used filter media in the form of fine meshes made of synthetic fibers, meshes made of metal, or specially processed filter paper.

〈発明が解決しJ、)とする問題点〉 しかしながら、上記従来のン濾過祠はいずれも次のよう
な問題点かある。
<Problems to be Solved by the Invention> However, all of the above-mentioned conventional filtration houses have the following problems.

(1)金属製の網状、おJ:びン戸紙状フィルタはガソ
リン、軽油などの燃料に混入した水分を完全に除去する
ことができない。
(1) Metal mesh, paper-like filters cannot completely remove water mixed into fuels such as gasoline and diesel oil.

(2)網状フィルタにおいては燃料タンクなどに、混入
した砂、ごみなどの異物の除去が困難である。即ち、網
状フィルタの異物の除去能力は網の目開きの大きさに影
響され、従来のフィルタではン濾過時の圧力損失、強度
および経済性の点から100〜300メツシユが限界で
あり、40μ以下の異物を完全に除去づることが困ガ1
である。
(2) With a mesh filter, it is difficult to remove foreign substances such as sand and dirt that have entered the fuel tank. In other words, the foreign matter removal ability of a mesh filter is affected by the size of the mesh opening, and with conventional filters, the limit is 100 to 300 meshes from the viewpoint of pressure loss during filtration, strength, and economic efficiency, and 40μ or less It is difficult to completely remove foreign substances from
It is.

本発明壱らは上記の問題点を解決すべく鋭意研究を重ね
た結果、ポリアミド樹脂およびポリアミド樹脂を主成分
とした樹脂組成物の多孔質焼結体を用いることにより、
自動車エンジン用燃料または汎用エンジン用燃料に適し
たフィルタを発明するに至った。
As a result of intensive research to solve the above-mentioned problems, we have found that by using a porous sintered body of a polyamide resin and a resin composition mainly composed of the polyamide resin,
A filter suitable for automobile engine fuel or general-purpose engine fuel has been invented.

〈問題点を解決するための手段〉 本発明の目的を達成するためのエンジン用燃料フィルタ
は、ポリアミド樹脂またはポリアミド樹脂を主成分とす
る樹脂組成物の多孔質焼結体からなるものである。
<Means for Solving the Problems> An engine fuel filter for achieving the object of the present invention is made of a porous sintered body of a polyamide resin or a resin composition containing a polyamide resin as a main component.

本発明におけるポリアミド樹脂は粉末が好ましく、例え
ば6・6−ナイロン(ポリへキサメチレンアジピン酸ア
ミド)、6−ナイロン(ε−カブロラクタムの重合体)
、6・10−ナイロン(ポリへキサメチレンセバシン酸
アミド)、12−ナイロン(ω−ラウロラクタムの重合
体)、さらには11−ナイロン(11−アミノウンデカ
ン酸の重合体)、4・6−ナイロンなどの粉末が挙げら
れる。この粉末を単独、若しくは二種以」二混合し、さ
らに必要に応じて他の熱可塑性樹脂、熱硬化性樹脂充填
物を少量添加し、金型中にて冷間圧縮成型した後、無酸
化状態、即ら高沸点油中、または真空中、中性雰囲気中
にてポリアミド樹脂の融点以下屈曲点以上の温度にて加
熱焼結せしめることにより、多孔質焼結体を得ることか
Cきる。この焼結体は連続した微細孔からなる多孔質構
造を有し、本発明の目的に適している・。
The polyamide resin in the present invention is preferably a powder, such as 6,6-nylon (polyhexamethylene adipic acid amide), 6-nylon (ε-cabrolactam polymer)
, 6,10-nylon (polyhexamethylene sebacamide), 12-nylon (ω-laurolactam polymer), 11-nylon (11-aminoundecanoic acid polymer), 4,6-nylon Examples include powders such as. This powder is used alone or mixed together, and if necessary, a small amount of other thermoplastic resin or thermosetting resin filler is added, and after cold compression molding in a mold, the powder is free from oxidation. A porous sintered body can be obtained by heating and sintering the polyamide resin at a temperature below the melting point and above the bending point of the polyamide resin in high-boiling oil, vacuum, or a neutral atmosphere. This sintered body has a porous structure consisting of continuous micropores and is suitable for the purpose of the present invention.

く作用〉 本発明のエンジン用燃料フィルタは次のように作用する
ものである。
Function> The engine fuel filter of the present invention functions as follows.

本発明者らは自動車エンジン用、および汎用エンジン用
燃わ1フイルタとして、多孔質ポリアミド樹脂焼結体が
好適に使用しうるよう実験を重ね、次のような結果を得
た。
The present inventors conducted repeated experiments to find that a porous polyamide resin sintered body could be suitably used as a combustion filter for automobile engines and general-purpose engines, and obtained the following results.

本発明において燃わ1川フイルタとして、第一に重要な
特性は¥C物の除去性であるが、多孔質ポリアミド樹脂
焼結体中の連結した微細孔の穴形状と孔径とに関係かあ
る3゜ 第1図は多孔yetポリアミド樹脂焼結体の走査型電子
顕微鏡にJでる断面写真であるが、その微細孔は焼結体
中で不規則に屈曲しており、また、その穴形状も不定形
であるため、ガソリンなどの燃料に混入した異物の粒径
よりも多孔質ポリアミド樹脂焼結体中の微細孔はかなり
大きくて−2= も異物の除去性は良好になる。
In the present invention, the first important characteristic of the combustible river filter is the ability to remove ¥C substances, but this is related to the shape and diameter of the connected micropores in the porous polyamide resin sintered body. 3゜Figure 1 is a cross-sectional photograph taken with a scanning electron microscope of a porous yet polyamide resin sintered body. Since the porous polyamide resin sintered body has an amorphous shape, the micropores in the porous polyamide resin sintered body are considerably larger than the particle size of foreign substances mixed in fuel such as gasoline, and the removal of foreign substances is also good.

第2図に多孔質ポリアミド樹脂焼結体中の微細孔の平均
孔径と異物の除去率の関係を示ザ。
Figure 2 shows the relationship between the average pore diameter of micropores in a porous polyamide resin sintered body and the foreign matter removal rate.

試験は一定濃度の異物混入液を一定時間連続濾過した後
、フィルタにより除去された異物の除去率を測定した。
In the test, a liquid containing foreign substances at a certain concentration was continuously filtered for a certain period of time, and then the removal rate of foreign substances removed by the filter was measured.

なお、異物として混入した物質は試験用ダスト(JIS
  78901)の8種を使用した。また、平均孔径に
ついては走査型電子顕微鏡により測定した。
In addition, substances mixed in as foreign substances are classified as test dust (JIS
78901) were used. Moreover, the average pore diameter was measured using a scanning electron microscope.

次に、第二に重要な水分の除去性については、ポリアミ
ド樹脂は本来水に対する接触角が大きいことから、水分
の除去性は多孔質ポリアミド樹脂焼結体表面の微細孔の
孔径に影響される。
Next, regarding the second important water removability, since polyamide resin inherently has a large contact angle with water, the water removability is influenced by the pore size of the micropores on the surface of the porous polyamide resin sintered body. .

第3図に表面の孔径と水分との除去率との関係を示す。FIG. 3 shows the relationship between the surface pore diameter and the water removal rate.

また、圧力損失については多孔質ポリアミド樹脂焼結体
中の微細孔の孔径とその開口数に関係することから、そ
の変動数を焼結含油合金の有効多孔率試験方法(JIS
  Z2506)に準じて、有効多孔率として表わし、
圧力損失と=  4 − 有効多孔率との関係を第4図に示す。
In addition, since the pressure drop is related to the diameter and numerical aperture of the micropores in the porous polyamide resin sintered body, the number of fluctuations in the pressure loss is calculated using the effective porosity test method for sintered oil-impregnated alloys (JIS
Z2506), expressed as effective porosity,
The relationship between pressure drop and = 4 - effective porosity is shown in Figure 4.

そして、燃Itフィルタとしでたえず燃料からの圧力を
受りることから、その強度を焼結含油軸受の圧環強さ試
験方法(J IS  72507)に準じて、圧環強度
として測定した。その結果、ガソリンなどの粘度の低い
燃料の場合はポンプの吐出圧カフに9/cm2程度まで
は圧環強度1.5Kg/ 繭2程度のポリアミド樹脂の
みで製造された多孔質焼結体で十分にたえうる。また、
軽油などの比較的粘度の高い燃料、あるいは燃料ポンプ
の吐出圧力か7b/cm”を越える場合には、圧環強度
を向上ざUるために、ポリアミド樹脂粉末に無機物質(
例えば、ガラス粉、アルミナ粉、その細金属酸化物など
)を適量添加して製造された、またはポリアミド樹脂に
熱硬化性樹脂(エポキシ樹脂、フェノール樹脂など)を
適量添加し、共結せしめ製造された圧環強度2.0Kg
/ #2以上の多孔質ポリアミド樹脂焼結体により好適
に使用し得る。
Since the filter is constantly subjected to pressure from fuel, its strength was measured as radial crushing strength according to the radial crushing strength test method for sintered oil-impregnated bearings (JIS 72507). As a result, in the case of low viscosity fuel such as gasoline, a porous sintered body made only of polyamide resin with a radial crushing strength of 1.5 kg/cocoon 2 is sufficient for pump discharge pressure cuffs up to about 9/cm2. It's worth it. Also,
When using fuel with relatively high viscosity such as light oil, or when the discharge pressure of the fuel pump exceeds 7 b/cm, inorganic substances (
For example, it is manufactured by adding an appropriate amount of thermosetting resin (epoxy resin, phenol resin, etc.) to polyamide resin and co-bonded with it. Radial crushing strength 2.0Kg
/ Porous polyamide resin sintered body of #2 or more can be used more preferably.

〈実施例〉 以下、実施例を挙げて本発明をさらに具体的にに!明づ
−る。
<Example> Hereinafter, the present invention will be described in more detail with reference to Examples! It becomes clear.

実施例1 溶解晶析法により調製した6・6−ナイロンの50〜5
00μ程度の粉末89を、金型中に振り込み冷間圧縮成
型により成型圧力500 Kg/ cm 2にて、外径
26mm、内径20m、全長50mmの圧粉成型体を得
た。次に、この成型体を250’C12時間窒素気流中
にて加熱焼結せしめlこ。
Example 1 50-5 of 6,6-nylon prepared by solution crystallization method
Powder 89 of about 00μ was poured into a mold and subjected to cold compression molding at a molding pressure of 500 Kg/cm 2 to obtain a powder compact with an outer diameter of 26 mm, an inner diameter of 20 m, and a total length of 50 mm. Next, this molded body was heated and sintered at 250'C in a nitrogen stream for 12 hours.

そして、この焼結体を金属焼結材料の焼結密度試験方法
(JIS  72505>、焼結含油合金の有効多孔率
試験方法(JIS  22506)、焼結含油軸受の圧
環強ざ試験方法(JIS  Z2507>に準じて、密
度、有効多孔率、圧環強度を測定したところ、密度0.
803 / cm3、有効多孔率32.0%、圧環強度
1.(Jg/馴2であった。
The sintered body was then tested according to the sintered density test method for metal sintered materials (JIS 72505>), the effective porosity test method for sintered oil-impregnated alloys (JIS 22506), and the crush strength test method for sintered oil-impregnated bearings (JIS Z2507). When the density, effective porosity, and radial crushing strength were measured according to the above method, the density was 0.
803/cm3, effective porosity 32.0%, radial crushing strength 1. (It was Jg/2.

また、自動車エンジン用燃斜フィルタ、または汎用エン
ジン用燃料フィルタとしての使用目的のため、自動中ガ
ソリ〕/機関用フューエルフィルタ試験方θ、(、)I
s  D1608)、自動車ディーゼル■開用フューエ
ルフィルタ性能試験方法(JIS  D1617)に準
じて、圧力損失試験、コンタミナント捕そく容量および
清浄効率試験、高温試験、低温試験、ガソリン浸せき試
験、水分餌1試験などを行った。圧力損失については1
0m1toであり、その他の試験にd3いてもすべて良
好であった。表−1にその結果を示す。
In addition, for the purpose of use as a combustion angle filter for automobile engines or a fuel filter for general-purpose engines, we also provide test methods for fuel filters for automatic gasoline/engines θ, (,) I
Pressure loss test, contaminant trapping capacity and cleaning efficiency test, high temperature test, low temperature test, gasoline immersion test, moisture bait 1 test, in accordance with the automotive diesel open fuel filter performance test method (JIS D1617). etc. 1 for pressure loss
0mlto, and all other tests were good even if it was d3. Table 1 shows the results.

実施例2 粒径50〜500μ程度の6・6−ナイロン粉末70重
量%、粒径200μ以下の12−ナイロン粉末30重量
%をホールミルにて2時間部合し、次に、この混合粉末
10qを実施例1と同−条f+にて成型、焼結せしめた
Example 2 70% by weight of 6,6-nylon powder with a particle size of about 50 to 500μ and 30% by weight of 12-nylon powder with a particle size of 200μ or less were combined in a whole mill for 2 hours, and then 10q of this mixed powder was mixed. It was molded and sintered using the same thread f+ as in Example 1.

そして、実施例1ど同様に各種の測定、試験を行ったと
ころ、密度0.78’j/cm3、有効多孔率35.0
%、圧環強W’1.E3に3/mm2.1IfE力損失
8mH(]てあり、その他の試験もすべて良好な結果で
あった。表−1にその結果を示す。
Then, when various measurements and tests were performed in the same manner as in Example 1, the density was 0.78'j/cm3, and the effective porosity was 35.0.
%, radial crushing strength W'1. E3 had a 3/mm2.1 IfE force loss of 8 mH (], and all other tests had good results. Table 1 shows the results.

実施例3 粒度’100〜600μ程度の6・6−ナイロン粉末8
0重量%、粒径100μ以下のエポキシ樹脂(エピコー
ト1009)20重量%をボールミルにて2時間部合し
た。
Example 3 6,6-nylon powder 8 with a particle size of about 100 to 600μ
0% by weight and 20% by weight of an epoxy resin (Epicoat 1009) having a particle size of 100 μm or less was combined in a ball mill for 2 hours.

次に、内寸法が外径26#、内径20m、全長50mの
円筒状の金属容器に上記混合粉末10gを充填し、金属
容器ごと窒素気流中にて250℃、2時間加熱共結せし
めた。
Next, 10 g of the above mixed powder was filled into a cylindrical metal container with inner dimensions of 26 mm in outer diameter, 20 m in inner diameter, and 50 m in total length, and the metal container was heated and coagulated at 250° C. for 2 hours in a nitrogen stream.

この焼結体は実施例1と同様に試験を行い、密度0.8
0 g/cm ” 、有効多孔率34.0%、圧環強度
2.5Kj7/m2であり、圧力損失については8mH
(]であった。また、その他の試験においてもすべて良
好な結果を得た。表−1にその結果を示す。
This sintered body was tested in the same manner as in Example 1, and the density was 0.8.
0 g/cm”, effective porosity 34.0%, radial crushing strength 2.5Kj7/m2, and pressure loss 8mH.
( ].Furthermore, good results were obtained in all other tests.Table 1 shows the results.

−ρ  − 〈発明の効果〉 本発明のエンジン用燃斜フィルタはポリアミド樹脂また
はポリアミド樹脂を主成分とする樹脂組成物の多孔質焼
結体で構成されるため、燃料中の水分および微細な異物
をも完全に除去することができる。
−ρ − <Effects of the Invention> Since the engine combustion angle filter of the present invention is composed of a porous sintered body of polyamide resin or a resin composition mainly composed of polyamide resin, moisture and fine foreign matter in the fuel are eliminated. can also be completely removed.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明のフィルタに使用する多孔質ポリアミド
樹脂焼結体の走査電子顕微鏡による断面写真、第2図は
多孔質ポリアミド樹脂焼結体の平均孔径と異物の除去率
の関係を示すグラフ、第3図は同じく表面孔径と水分の
除去率の関係を示すグラフ、第4図は同じく有効多孔率
と圧力損失の関係を示すグラフである。 特許出願大東し株式会社 8興リカ  株式会社 第1図 第2図 “050   100500    。6、。 第3図
Fig. 1 is a cross-sectional photograph taken by a scanning electron microscope of a porous polyamide resin sintered body used in the filter of the present invention, and Fig. 2 is a graph showing the relationship between the average pore diameter of the porous polyamide resin sintered body and the foreign matter removal rate. , FIG. 3 is a graph showing the relationship between surface pore diameter and water removal rate, and FIG. 4 is a graph showing the relationship between effective porosity and pressure loss. Patent application Daitoshi Co., Ltd. 8ko Rica Co., Ltd. Figure 1 Figure 2 "050 100500. 6. Figure 3

Claims (1)

【特許請求の範囲】 ポリアミド樹脂、またはポリアミド樹脂を 主成分とする樹脂組成物の多孔質焼結体からなるエンジ
ン用燃料フィルタ。
[Claims] An engine fuel filter comprising a porous sintered body of a polyamide resin or a resin composition containing a polyamide resin as a main component.
JP61087272A 1986-04-16 1986-04-16 Engine fuel filter Pending JPS62244414A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP61087272A JPS62244414A (en) 1986-04-16 1986-04-16 Engine fuel filter

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61087272A JPS62244414A (en) 1986-04-16 1986-04-16 Engine fuel filter

Publications (1)

Publication Number Publication Date
JPS62244414A true JPS62244414A (en) 1987-10-24

Family

ID=13910130

Family Applications (1)

Application Number Title Priority Date Filing Date
JP61087272A Pending JPS62244414A (en) 1986-04-16 1986-04-16 Engine fuel filter

Country Status (1)

Country Link
JP (1) JPS62244414A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5370540A (en) * 1991-04-02 1994-12-06 Canon Kabushiki Kaisha Circuit board connector and a board using the same
JP2009287415A (en) * 2008-05-27 2009-12-10 Unitica Fibers Ltd Automobile fuel filter material

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5370540A (en) * 1991-04-02 1994-12-06 Canon Kabushiki Kaisha Circuit board connector and a board using the same
JP2009287415A (en) * 2008-05-27 2009-12-10 Unitica Fibers Ltd Automobile fuel filter material

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