JPS62241858A - Picture frame - Google Patents
Picture frameInfo
- Publication number
- JPS62241858A JPS62241858A JP7923386A JP7923386A JPS62241858A JP S62241858 A JPS62241858 A JP S62241858A JP 7923386 A JP7923386 A JP 7923386A JP 7923386 A JP7923386 A JP 7923386A JP S62241858 A JPS62241858 A JP S62241858A
- Authority
- JP
- Japan
- Prior art keywords
- slag
- copper
- picture frame
- paint
- phosphate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002893 slag Substances 0.000 claims description 47
- 239000010949 copper Substances 0.000 claims description 31
- 229910052802 copper Inorganic materials 0.000 claims description 30
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 29
- 239000003973 paint Substances 0.000 claims description 14
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 22
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 14
- 239000003086 colorant Substances 0.000 description 12
- 235000011007 phosphoric acid Nutrition 0.000 description 12
- 238000003723 Smelting Methods 0.000 description 10
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 9
- 229910019142 PO4 Inorganic materials 0.000 description 7
- 229910052742 iron Inorganic materials 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- 235000021317 phosphate Nutrition 0.000 description 7
- 239000011230 binding agent Substances 0.000 description 6
- 239000012141 concentrate Substances 0.000 description 6
- 239000010452 phosphate Substances 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 6
- 238000001723 curing Methods 0.000 description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical class O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 239000004137 magnesium phosphate Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 239000001488 sodium phosphate Substances 0.000 description 2
- 235000011008 sodium phosphates Nutrition 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical class [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-N Metaphosphoric acid Chemical compound OP(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-N 0.000 description 1
- 208000005072 Oncogenic osteomalacia Diseases 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 229910000754 Wrought iron Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- MHJAJDCZWVHCPF-UHFFFAOYSA-L dimagnesium phosphate Chemical compound [Mg+2].OP([O-])([O-])=O MHJAJDCZWVHCPF-UHFFFAOYSA-L 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000001227 electron beam curing Methods 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 238000009415 formwork Methods 0.000 description 1
- TVZISJTYELEYPI-UHFFFAOYSA-N hypodiphosphoric acid Chemical compound OP(O)(=O)P(O)(O)=O TVZISJTYELEYPI-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 description 1
- 229910000157 magnesium phosphate Inorganic materials 0.000 description 1
- 229960002261 magnesium phosphate Drugs 0.000 description 1
- 235000010994 magnesium phosphates Nutrition 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000005341 metaphosphate group Chemical group 0.000 description 1
- 239000011823 monolithic refractory Substances 0.000 description 1
- 229910000401 monomagnesium phosphate Inorganic materials 0.000 description 1
- 235000019785 monomagnesium phosphate Nutrition 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 229940005657 pyrophosphoric acid Drugs 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- XOSXWYQMOYSSKB-LDKJGXKFSA-L water blue Chemical compound CC1=CC(/C(\C(C=C2)=CC=C2NC(C=C2)=CC=C2S([O-])(=O)=O)=C(\C=C2)/C=C/C\2=N\C(C=C2)=CC=C2S([O-])(=O)=O)=CC(S(O)(=O)=O)=C1N.[Na+].[Na+] XOSXWYQMOYSSKB-LDKJGXKFSA-L 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- -1 with high chroma Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/34—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing cold phosphate binders
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Mirrors, Picture Frames, Photograph Stands, And Related Fastening Devices (AREA)
- Aftertreatments Of Artificial And Natural Stones (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
本発明は、額縁に関するものであり、特には銅製錬にお
いて産出する銅スラグを利用して重厚感があり、且つ装
飾性に優れた額縁に関するものである。本額縁は、ＥＢ
Ｃ塗料によって金、銀、赤、ピンク、ブルー、黒等の彩
度の高い彩色をすることが出来、非常に美Ｈ−１ものと
することが出来る。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a picture frame, and in particular to a picture frame that is made of copper slag produced in copper smelting and has a profound feel and is highly decorative. This picture frame is EB
With C paint, it is possible to paint with high saturation such as gold, silver, red, pink, blue, black, etc., and it is possible to make it extremely beautiful H-1.
発明の背景
銅製錬においては、その製錬方法に応じて自溶炉スラグ
、反射炉スラグ、溶鉱炉スラグ、転炉スラグ、Ｍｌ法錬
鏝炉スラグ等の各種スラグが発生する。現在もつとも多
く採用されている自溶炉法を例にとると、銅精鉱は少量
の溶剤と共に自溶炉シャフト部に装入され、シャフト部
における溶解及び酸化製錬の後、セラトラ一部において
マットとスラグが生成する。産出する自溶炉スラグは一
般ＫＴ、（）−タル） ）’ ＠含有量が４０〜５５％
であり、そして次のような成分を主成分とする：この他
、ＡＩｔｏ、 、ＭｇＯｌＣａＯｌＺｎ％Ｐｂ。BACKGROUND OF THE INVENTION In copper smelting, various types of slag are generated depending on the smelting method, such as flash furnace slag, reverberatory furnace slag, blast furnace slag, converter slag, and Ml smelting iron furnace slag. Taking the flash-smelting furnace method, which is currently widely used, as an example, copper concentrate is charged into the shaft of the flash-smelting furnace together with a small amount of solvent, and after melting and oxidation smelting in the shaft, a part of the seratra Generates mats and slag. The flash smelting furnace slag produced is general KT, ()-tal) )' @ content is 40-55%
The main components are: AIto, , MgOlCaOlZn%Pb.
Ｃｕ等が少量含まれている。自溶炉で産出するマットは
転炉精錬されるが、この場合に転炉スラグが産出する。Contains a small amount of Cu etc. The matte produced in the flash furnace is refined in a converter, and in this case converter slag is produced.
転炉スラグは５％前後の銅を含んでいるのが鍜選鉱場へ
送り、銅を回収するが、その残りのスラグは高い鉄組成
により「鉄精鉱」と呼ばれている。反射炉スラグ及び溶
鉱炉スラグもそれぞれ反射炉及び溶鉱炉において産出す
るスラグであり、若干の変動はあるが、上記と同様の組
成を有している。更には、近年、ＭＩ法と呼ばれる連続
製鋼法が実施されており、これは溶融炉、錬鏝炉及び製
鋼炉という３つの炉を樋で連結し、連続的に粗餉を製造
するものである。この場合に錬鎧炉から産出するスラグ
がＭＩ法錬釧炉スラグと呼ばれる。こうして、国内では
銅スラグが年間約２００万トン程産出されている。Converter slag, which contains around 5% copper, is sent to a mill to recover the copper, but the remaining slag is called ``iron concentrate'' due to its high iron content. Reverberatory furnace slag and blast furnace slag are also slags produced in reverberatory furnaces and blast furnaces, respectively, and have the same compositions as above, although there are slight variations. Furthermore, in recent years, a continuous steel manufacturing method called the MI method has been implemented, in which three furnaces, a melting furnace, a wrought iron furnace, and a steelmaking furnace, are connected by a gutter to continuously produce coarse steel. . In this case, the slag produced from the Rengo Furnace is called MI Horen Senro Slag. In this way, approximately 2 million tons of copper slag is produced annually in Japan.
こうした銅スラグは従来、粉砕後、主として埋立材とし
て再利用されていただけであった。Conventionally, such copper slag has been mainly reused as a landfill material after being crushed.
しかしながら、最近、銅スラグの有する性状をもつと積
極的に多様な製品として活用する気運が高まっており、
銅スラグの再活用の仕方について検討が加えられつつあ
る。However, recently there has been a growing trend to actively utilize the properties of copper slag in a variety of products.
Consideration is being given to ways to reuse copper slag.
発明の概要
本発明者等が銅スラグの再活用について検討を重ねた結
果、銅スラグ粒子は結合剤としてリン酸及び（又は）リ
ン酸塩を用いて凝結硬化させることにより焼成せずども
充分の強度が発現し、しかも型枠への流込みによって自
在な模様付き成型体が容易に作製しうろことが見出され
た。固化速度もきわめて早い、外観色も深床のある、重
厚感のある好適なものである。そこで、本発明者等はこ
うした成型体を額縁として利用することを想到し、更に
試行を重ねたところ、好結果を得た。Summary of the Invention As a result of repeated studies by the present inventors regarding the reuse of copper slag, copper slag particles can be solidified and hardened using phosphoric acid and/or phosphate as a binder, without having to be fired. It has been found that the molded product exhibits strength and can easily be molded with any desired pattern by pouring it into a mold. The solidification rate is extremely fast, and the exterior color is deep and deep, giving it a solid feel. Therefore, the present inventors came up with the idea of using such a molded body as a picture frame, and after repeated trials, they obtained good results.
銅スラグのリン酸塩結合型不焼成成型体は次のような特
性を有する：
（１）焼成せずに硬化する。The phosphate-bonded unfired molded body of copper slag has the following properties: (1) It hardens without firing.
（２）固化速度がきわめて速い。(2) The solidification rate is extremely fast.
（３）流込成型によって任意の形態のものを作製しさる
。(3) Manufacture any shape by casting.
（４）凹凸のある模様を成型時に容易に創出しうる。(4) An uneven pattern can be easily created during molding.
（５）硬度が高く、傷つきｋくい。(5) High hardness and scratch resistance.
（６）耐熱性がある。(6) Heat resistant.
（７）耐水性がある。(7) Water resistant.
（８）重厚感のある美しい外観色を呈する。(8) Exhibits a beautiful exterior color with a solid feel.
（９） 白色化が可能である。(9) Whitening is possible.
０１ ｊ！ｉ料、％にＥＢＣ塗料による彩色が自在に
もたらされる。01 j! Coloring with EBC paint can be freely applied to the i materials and %.
収り 安価である。It fits and is inexpensive.
こうした特性は、上記成型体を額縁として用いることを
好適ならしめる。These characteristics make the molded body suitable for use as a picture frame.
本発明における銅スラグのリン酸塩結合量不焼成成型体
とは、銅製錬において産出する銅スラグ゛の粒子に９ン
酸及び（又は）リン酸塩を添加混合し、所望の形態を有
する型枠内に流込みそして常温で凝結硬化させることに
より得られる成型体を云う。銅スラグに着色剤その他の
添加剤を混入することが出来、本明細ではそれらを含め
て銅スラグと称する。In the present invention, the phosphate-bound unfired molded body of copper slag is a molded product having a desired shape, which is obtained by adding and mixing nine phosphoric acid and/or phosphate to the particles of copper slag produced in copper smelting. A molded product obtained by pouring it into a frame and allowing it to solidify and harden at room temperature. Coloring agents and other additives can be mixed into the copper slag, and in this specification they are collectively referred to as copper slag.
銅製錬から産出される銅スラグとしては前述したような
各種のものがあるが、それぞれの製造方式に基き、組成
の差異を有している。しかじなが′ら、その主成分は、
Ｔ、Ｆｅ３５〜６０％、ｆｆ１ｅｏ−８ｉｏ１２０〜４
０％、Ｆｅ、 ０４１〜２５ ％そして８１０．２０〜
３５チの範囲にあると一般的に言うことが出来る。但し
、転炉産出銅スラグはＦｅ１０４が多いことを特徴とす
る。次は自溶炉スラグと転炉鉄精鉱との差異を示す：
本発明においては、自溶炉スラグ、反射炉スラグ、溶鉱
炉スラグ、転炉スラグ、ＭＩ法錬鐘炉ス２グ等いずれを
も対象とするが、特にはＴ、Ｆｅ４０〜５５ ％、 ２
ＦｅＯ・５ｉＯ１２０〜３０ ％、Ｆｅｄ ０４ １５
〜２５ ％モしてＳＩｏ、 ２１〜２９％を主成分とす
るスラグ、特定的には転炉産出鉄精鉱を対象とする。こ
うしたスラグは、通常、０．５〜４１％Ａ１．０．．０
．２〜３％ＭｇＯ，０，５〜４％Ｃａ０，１〜５％Ｚｎ
その他の不純物を含有しているが、これら副成分は本発
明においてほとんど影畳を与えない。但し、深床のある
外観色の現出には微妙な作用を呈しているものと思われ
る。There are various types of copper slag produced from copper smelting as described above, but each has a different composition based on its production method. The main ingredients are:
T, Fe35-60%, ff1eo-8io120-4
0%, Fe, 041~25% and 810.20~
It can be generally said that it is in the range of 35 inches. However, copper slag produced in a converter is characterized by a high content of Fe104. The following shows the difference between flash furnace slag and converter iron concentrate: In the present invention, any of flash furnace slag, reverberatory furnace slag, blast furnace slag, converter slag, MI Horen Furnace slag, etc. It also targets T, Fe40-55%, 2
FeO・5iO120-30%, Fed 04 15
-25% SIo, slag whose main component is 21-29%, specifically iron concentrate produced in a converter. Such slags typically range from 0.5 to 41% A1.0. ．． 0
．． 2-3% MgO, 0.5-4% Ca0, 1-5% Zn
Although it contains other impurities, these subcomponents have little effect on the present invention. However, it seems to have a subtle effect on the appearance of a deep-floored exterior color.
こうした銅スラグは、水砕、風砕、機械的粉砕により細
く粉砕される。２００メツシユ以下に整粒することが好
ましい。Such copper slag is finely ground by water crushing, wind crushing, or mechanical crushing. It is preferable to size the particles to 200 meshes or less.
リン酸は、それ自身が接着力を有しているわけではない
が、金属配化物等の他の物質と反応して塩類をつくり、
こうした塩類が結合材としての役割を果し、特に鉤スラ
グ粒子用結合材として優れた適性を有している。不定形
耐火物等へのリン酸及びリン酸塩結合材の使用は知られ
ているが、銅スラグ用結合材としてこれらを単独で使用
する試みは本発明が初めてである。Phosphoric acid itself does not have adhesive strength, but it reacts with other substances such as metal conjugates to create salts.
These salts play a role as a binder and are particularly suitable as a binder for hook slag particles. Although the use of phosphoric acid and phosphate binders in monolithic refractories and the like is known, the present invention is the first attempt to use these alone as binders for copper slag.
リン酸としては、次亜リン酸、亜リン酸、次リン酸、メ
タリン酸、ピロリン酸及びオルソリン酸等様々のものが
存在するが、本発明においてはそのいずれをも含むもの
である。しかし、工業的にもっとも重要で、生産量も多
いのがオルソリン酸であり、実用的にはこれで充分であ
る。リン酸塩には、オルソリン欲塩、ピ四リン酸塩、ポ
リリン酸塩、メタリン酸塩等があり、本発明では、広く
用いられるリン酸アルミニウム（例第１リン酸アルミニ
ウム）、リン酸ナトリウム（例第−１υ′ン酸ナトリウ
ム）及びリン酸マグネシウム（側鎖１リン酸マグネシウ
ム）を単独であるいは組合せ及び又はこれらの結合組成
物で好適に用いることが出来る。There are various phosphoric acids such as hypophosphorous acid, phosphorous acid, hypophosphoric acid, metaphosphoric acid, pyrophosphoric acid, and orthophosphoric acid, and the present invention includes any of them. However, orthophosphoric acid is industrially most important and produced in large quantities, and is sufficient for practical use. Phosphates include orthophosphoric salts, pi-tetraphosphates, polyphosphates, metaphosphates, etc. In the present invention, widely used aluminum phosphates (e.g. monobasic aluminum phosphate), sodium phosphates ( EXAMPLE Sodium phosphate (sodium nitrate) and magnesium phosphate (side chain monomagnesium phosphate) can be suitably used alone or in combination and/or in combination compositions thereof.
リン酸及びリン酸塩は３０〜８０チ水溶液として用いら
れる。リン酸は一般に８５〜７０％程度の水溶液として
市販されており、これらをそのまま用いてもよい。Phosphoric acid and phosphate salts are used as 30-80% aqueous solutions. Phosphoric acid is generally commercially available as an approximately 85-70% aqueous solution, and these may be used as they are.
銅スラグ粒子とリン酸及び（或いは）リン酸塩との混合
物は、リン酸及び（或いは）リン酸塩を１〜６０重量％
添加し、充分に混錬することにより生成される。結合剤
は、銅スラグ粒子全体を結合するに適正でなければなら
ず、多すぎてはならない。こうした目的ＶＣ１〜６０重
量％、好ましくは１〜４０重量％、より好ましくは５〜
３０重量％が適正である。The mixture of copper slag particles and phosphoric acid and/or phosphate contains 1 to 60% by weight of phosphoric acid and/or phosphate.
It is produced by adding and thoroughly kneading. The binder must be adequate to bind the entire copper slag particles and not be too much. Such purpose VC1-60% by weight, preferably 1-40% by weight, more preferably 5-60% by weight
30% by weight is appropriate.
必要に応じ、ベンガラのよう力着色料、顔料等を添加し
てもよい。これらは、銅スラグの６０チまで添加するこ
とが出来る。If necessary, a coloring agent such as iron oxide, a pigment, etc. may be added. These can be added up to 60 inches of copper slag.
生成する銅スラグスラリーは、所望の額縁形態に応じた
型枠内に流込まれ、凝結硬化される。硬化は、３０秒〜
１０分の短時間で完了する。花模様等の額縁に多く見ら
れる模様付けは、型枠に然るべき転写模様を付けておく
ことにより自在に創出しうる。The resulting copper slag slurry is poured into a mold according to the desired picture frame form and allowed to set and harden. Curing takes 30 seconds or more
Complete in just 10 minutes. Patterns often seen on picture frames, such as flower patterns, can be freely created by attaching an appropriate transfer pattern to the frame.
本発明による成型品は、前述したように、着色剤を適量
混合することにより様々の色を発現することが出来る。As described above, the molded product according to the present invention can exhibit various colors by mixing an appropriate amount of a coloring agent.
例えば、ベンガラ（ｐｅ！ｏｓ）は赤褐色をそしてＴ１
０．は白青色を生みだす。その他斯界で知られる着色剤
を単独で或いは複数種組合せて使用することにより無数
の着色が可能である。更には、８０℃前後の蒸気養生に
よって白色を生みだすことが出来る。着色剤と蒸気養生
との組合せによって一段と深床のある色を生みだすこと
が出来る。For example, Red Garland (pe!os) has a reddish-brown color and T1
0. produces a white-blue color. Innumerable colors are possible by using other coloring agents known in the art alone or in combination. Furthermore, a white color can be produced by steam curing at around 80°C. A combination of colorants and steam curing can produce even deeper colors.
本発明による成型品は塗料との適合性も良好であり、＊
質上すぺでの塗料によって彩色可能である。特に、アル
カリ分を含ま々いことから、ＥＢＣ塗料（電子線硬化塗
料）の使用が可能であり、きわめて美しい外観の密着性
の良い艙膜の形成が可能であり、これら製品の高級感、
重厚感等をかもし出し、更に一層広い分野での製品化を
可能ならしめる。The molded product according to the present invention also has good compatibility with paint, *
Due to its quality, it can be colored with special paints. In particular, since it contains alkaline content, it is possible to use EBC paint (electron beam curing paint), and it is possible to form a highly adhesive coating with an extremely beautiful appearance, giving these products a luxurious feel.
It creates a sense of solidity and makes it possible to commercialize products in an even wider range of fields.
ＥＢＣ塗料は、電子線によって塗料を硬化乾燥させる方
法において用いられる詭料であり、不飽和樹脂、オリゴ
マー、反応性希釈剤、着色剤、安定剤などから構成され
、ＥＢ（、ａ料に電子線を照射するとラジカルが発生し
、そのラジカルによって塗料が硬化乾燥することを原理
とする。ＷＢＣ樹脂は秒以下で硬化乾燥する。本成型品
はアルカリを含んでいないことから予備処理を要せず、
ＥＢＣ塗料の適用が可能であり、彩度の高い、金、銀、
ブルー、茶、ベージュ、黄、ライトグリーン、メタリッ
ク色等の塗装タイルが短時間で得られる。EBC paint is a material used in the method of curing and drying paint with electron beams, and is composed of unsaturated resins, oligomers, reactive diluents, colorants, stabilizers, etc. Radicals are generated when irradiated with , and the radicals harden and dry the paint.WBC resin hardens and dries in less than seconds.This molded product does not require any pre-treatment as it does not contain alkali.
It is possible to apply EBC paint, with high chroma, gold, silver,
Painted tiles in blue, brown, beige, yellow, light green, metallic colors, etc. can be obtained in a short time.
更に、この塗膜は、硬度が高く傷つきにくいこと及び耐
摩耗性が良好か点でも優れている。Furthermore, this coating film is excellent in that it has high hardness and is hard to scratch, and has good abrasion resistance.
発明の効果
銅スラグを額縁とい５全く意外な用途において再活用し
た。Effects of the invention: Copper slag was reused in a totally unexpected purpose: picture frames.
実施例１
粒度２００メツシユ以下の次の鉄精鉱を使用した：
Ｔｏ Ｆｅ ４７．５１％
Ｆｅ１０． ２１’％
２ＦａＯ・Ｓ ｊｏｔ ２５．１ ％８１０、
２２．５％
ＡＩ！ Ｏｓ１５％
ＭｇＯ１６８％
ＣａＯｔ ４％
Ｚｎ ２．７チ
Ｐｂ １４％
Ｃｕ α６チ
Ｓ Ｑ、０４％
上記鉄精鉱に着色剤としてＴ Ｉ Ｏｓを７：３の比率
で加えた後濃度５０チのリン酸水溶液を５８１の割合で
添加し、混錬後３０ｃＷｔ×２０ｃＩＩＬの大きさの額
縁型枠に流込んだ。型枠には全体的に花模様を付した。Example 1 The following iron concentrate with a particle size of 200 mesh or less was used: To Fe 47.51% Fe10. 21'% 2FaO・S jot 25.1%810,
22.5% AI! Os15% MgO168% CaOt 4% Zn 2.7T Pb 14% Cu α6T S Q, 04% After adding TIOs as a colorant to the above iron concentrate at a ratio of 7:3, phosphoric acid with a concentration of 50T The aqueous solution was added at a ratio of 581 parts, and after kneading, it was poured into a picture frame mold having a size of 30 cWt x 20 cIIL. The entire formwork has a floral pattern.
硬化後、落水色の非常に重厚味のある外観色の額縁が得
られた。After curing, a picture frame with a falling water blue appearance and a very solid appearance was obtained.
実施例２
着色剤を加えない実施例１の成型品に、アクリルタイプ
ＥＢＣ塗料を塗布し、不活性ガス中ＥＢ照射により塗膜
を硬化させた。非常に彩度の高いみどり色の額縁が得ら
れた。Example 2 An acrylic type EBC paint was applied to the molded product of Example 1 without the addition of a colorant, and the paint film was cured by EB irradiation in an inert gas. A green picture frame with extremely high saturation was obtained.
Claims (1)
縁。 ２）表面をＥＢＣ塗料により塗装した特許請求の範囲第
１項記載の額縁。[Claims] 1) A picture frame made of a phosphate-bonded unfired molded body of copper slag. 2) The picture frame according to claim 1, the surface of which is coated with EBC paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7923386A JPS62241858A (en) | 1986-04-08 | 1986-04-08 | Picture frame |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7923386A JPS62241858A (en) | 1986-04-08 | 1986-04-08 | Picture frame |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62241858A true JPS62241858A (en) | 1987-10-22 |
Family
ID=13684157
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7923386A Pending JPS62241858A (en) | 1986-04-08 | 1986-04-08 | Picture frame |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62241858A (en) |
-
1986
- 1986-04-08 JP JP7923386A patent/JPS62241858A/en active Pending
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