JPS62212468A - Disperse dye composition for polyester fiber and dyeing or printing method - Google Patents
Disperse dye composition for polyester fiber and dyeing or printing methodInfo
- Publication number
- JPS62212468A JPS62212468A JP5266986A JP5266986A JPS62212468A JP S62212468 A JPS62212468 A JP S62212468A JP 5266986 A JP5266986 A JP 5266986A JP 5266986 A JP5266986 A JP 5266986A JP S62212468 A JPS62212468 A JP S62212468A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- formulas
- tables
- dye
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 229920000728 polyester Polymers 0.000 title claims abstract description 16
- 238000004043 dyeing Methods 0.000 title claims abstract description 15
- 239000000835 fiber Substances 0.000 title claims abstract description 14
- 239000000986 disperse dye Substances 0.000 title claims abstract description 10
- 239000000203 mixture Substances 0.000 title claims description 22
- 238000000034 method Methods 0.000 title claims description 13
- 239000000975 dye Substances 0.000 claims abstract description 89
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 24
- 125000001309 chloro group Chemical group Cl* 0.000 claims abstract description 24
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims abstract description 12
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 12
- 239000000460 chlorine Substances 0.000 claims abstract description 9
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims 24
- 125000004429 atom Chemical group 0.000 claims 1
- 238000010186 staining Methods 0.000 abstract description 5
- 238000002156 mixing Methods 0.000 abstract description 4
- 239000000987 azo dye Substances 0.000 abstract description 3
- 238000012545 processing Methods 0.000 abstract description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 4
- 229910052794 bromium Chemical group 0.000 abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 36
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 description 32
- 239000005844 Thymol Substances 0.000 description 16
- 229960000790 thymol Drugs 0.000 description 16
- 238000000859 sublimation Methods 0.000 description 10
- 230000008022 sublimation Effects 0.000 description 10
- 238000005406 washing Methods 0.000 description 10
- 239000000047 product Substances 0.000 description 9
- 238000013329 compounding Methods 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229920000161 Locust bean gum Polymers 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- IDCBOTIENDVCBQ-UHFFFAOYSA-N TEPP Chemical compound CCOP(=O)(OCC)OP(=O)(OCC)OCC IDCBOTIENDVCBQ-UHFFFAOYSA-N 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-M hydrosulfide Chemical compound [SH-] RWSOTUBLDIXVET-UHFFFAOYSA-M 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000000711 locust bean gum Substances 0.000 description 2
- 235000010420 locust bean gum Nutrition 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- QIVUCLWGARAQIO-OLIXTKCUSA-N (3s)-n-[(3s,5s,6r)-6-methyl-2-oxo-1-(2,2,2-trifluoroethyl)-5-(2,3,6-trifluorophenyl)piperidin-3-yl]-2-oxospiro[1h-pyrrolo[2,3-b]pyridine-3,6'-5,7-dihydrocyclopenta[b]pyridine]-3'-carboxamide Chemical compound C1([C@H]2[C@H](N(C(=O)[C@@H](NC(=O)C=3C=C4C[C@]5(CC4=NC=3)C3=CC=CN=C3NC5=O)C2)CC(F)(F)F)C)=C(F)C=CC(F)=C1F QIVUCLWGARAQIO-OLIXTKCUSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000003869 coulometry Methods 0.000 description 1
- 239000012043 crude product Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- XULSCZPZVQIMFM-IPZQJPLYSA-N odevixibat Chemical compound C12=CC(SC)=C(OCC(=O)N[C@@H](C(=O)N[C@@H](CC)C(O)=O)C=3C=CC(O)=CC=3)C=C2S(=O)(=O)NC(CCCC)(CCCC)CN1C1=CC=CC=C1 XULSCZPZVQIMFM-IPZQJPLYSA-N 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
Landscapes
- Coloring (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は、ポリエステル繊維用ネービ色、又は黒色染料
組成物、及びその染料方法に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a navy or black dye composition for polyester fibers and a dyeing method thereof.
〔従来の技術及び発明が解決しようとする問題点〕ポリ
エステル系繊維の染色に分散型水不溶性染料を使用する
ことはよく知られているが、ポリエステル系繊維を黒色
に染色する単品の分散染料は現在知られていないため、
一般には黄、青、赤、茶色などの分散染料を適当に色合
せした配合染料が使用されている。[Prior art and problems to be solved by the invention] It is well known that dispersed water-insoluble dyes are used to dye polyester fibers, but single disperse dyes that dye polyester fibers black are As it is currently unknown,
Generally, blended dyes are used that are appropriately color-matched disperse dyes such as yellow, blue, red, and brown.
そのため、単色の色に染める（例えば黄色、赤色、青色
）場合に比較して、ネービ、あるいは黒色に染色する場
合は多くの染料を使用せざるを得ない。Therefore, compared to when dyeing a single color (for example, yellow, red, or blue), more dye must be used when dyeing navy or black.
そのため、染色時の染料の利用率すなわち、ポリエステ
ルへの染着率が低くなり、コスト上又は、未染着染料が
後処理時に、染色物を汚染することが多かった。これら
の改良を目標とした技術としては、特開昭６０−２８４
５５などが知られている。As a result, the utilization rate of the dye during dyeing, that is, the rate of dyeing the polyester, is low, and due to cost reasons, the undyed dye often contaminates the dyed product during post-treatment. As a technology aiming at these improvements, Japanese Patent Application Laid-Open No. 60-284
55 etc. are known.
しかし、この技術でもその改良は充分でなかった。However, even with this technology, the improvement was not sufficient.
本願発明者らは、染着性向上、染色時、後処理時の汚染
性の小さいネービ色、又は黒色染料の開発を目標に鋭意
検討の結果、全染料原末に対して式（Ｉ）
〔式（Ｉｌ中Ｘは臭素原子又は塩素原子を表わす。〕で
示される染料ｌＯ〜３０重量係、
式（ＩＩ）
で示される染料４０〜６０重量係、
式（ｍ）
〔式（ＩＩＩ）中Ｘは塩素原子又は臭素原子を表わし。The inventors of the present application have conducted intensive studies with the aim of developing navy or black dyes that improve dyeability and have low staining properties during dyeing and post-processing, and have found that formula (I) A dye represented by the formula (X in Il represents a bromine atom or a chlorine atom) 10 to 30 weight percent, a dye represented by the formula (II) 40 to 60 weight percent, a dye represented by the formula (m) [X in formula (III) represents a chlorine atom or a bromine atom.
Ｒは炭素数１〜５のアルキル基を表わす。〕で示される
染料又は一般式（ＩＶ）
〔式（ＩＶ）中、Ｘは塩素または臭素原子を表わし、Ｒ
はメチル基又はエチル基を表わす。〕を１０〜３０重量
係、又調色に必要ならば一般式〔式（ｖ）中Ｘは臭素原
子、又は塩素原子を表わす〕で示される染料、又は一般
式（Ｖｌ）
〔式（ＶＤ中Ｒはメチル基、又はエチル基を表わす〕で
示される染料を０〜１０重量係重量台してなるポリエス
テル繊維用黒色分散組成物、及びこれを用いた染色また
は捺染方法。また１本発明は全染料原末に対し、前記式
（Ｉ）で示される染料２０〜５０重量壬、前記式（ｎ）
で示される染料５〜１５重量係、前記式（ｍ）又は■）
で示される染料２０〜５０重量係、及び必要に応じて前
記一般式（ｖ）又は（Ｖｌ）で示される染料０〜１０重
量％の割合で配合してなるポリエステル繊維用ネービ色
分散条料組成物、及びこれを用いた染色または捺染方法
が良好な結果を得ることを見い出し本願発明に達した。R represents an alkyl group having 1 to 5 carbon atoms. ] or general formula (IV) [In formula (IV), X represents a chlorine or bromine atom, and R
represents a methyl group or an ethyl group. ] of 10 to 30% by weight, and if necessary for color toning, a dye represented by the general formula [in formula (v), X represents a bromine atom or a chlorine atom], or a dye represented by the general formula (Vl) [formula (in VD R represents a methyl group or an ethyl group] A black dispersion composition for polyester fibers comprising a dye represented by 0 to 10 weight ratios, and a dyeing or printing method using the same. 20 to 50 g of the dye represented by the formula (I) and the formula (n) per dye bulk powder;
5 to 15 weight percent of the dye represented by the formula (m) or ■)
A navy colored dispersion strip composition for polyester fibers containing 20 to 50% by weight of the dye represented by the formula (v) or (Vl) as required, and 0 to 10% by weight of the dye represented by the general formula (V) or (Vl). The present invention was achieved by discovering that a material and a dyeing or printing method using the same can obtain good results.
本発明で用いる式（Ｉ）〜式（Ｖｌ）で示される染料は
、公知アゾ染料もしくはその類似のアゾ染料であり、容
易に入手、もしくは常法に従うて合成出来る。The dyes represented by formulas (I) to (Vl) used in the present invention are known azo dyes or similar azo dyes, and can be easily obtained or synthesized according to conventional methods.
一般式（Ｉ）〜（Ｖｌ）で示される染料の具体例は以下
の様である。Specific examples of the dyes represented by general formulas (I) to (Vl) are as follows.
一般式（Ｉ）
一般式（ｍ）
一般弐〇Ｖ）
一般式（Ｖ）
一般式（Ｖｌ）
本発明の実施にあたっては、配合に供する各染料のプレ
スケーキを適当な分散剤と共に水性媒体中で微粒化分散
し、そのまま液状であるいはスプレー乾燥法等により粉
末状とした後、所定の割合に配合してネービ色または黒
色染料組成物とするのが有利である。General formula (I) General formula (m) General formula (V) General formula (V) General formula (Vl) In carrying out the present invention, the press cake of each dye to be blended is placed in an aqueous medium together with a suitable dispersant. It is advantageous to micronize and disperse the dye, either as it is in a liquid state or to form a powder by a spray drying method, and then blending it in a predetermined proportion to form a navy or black dye composition.
この様にして得られた染料組成物を用いてポリエステル
系繊維を染色するには、加圧下１０５℃以上、好ましく
は１１０〜１４０℃で染色する方法、０−フェニルフェ
ノール等のキャリアーの存在下に比較的高温、例えば水
の沸点で染色する方法あるいは染料分散液を布にパディ
ングし、１５０〜２３０℃で３０〜６０秒乾熱処理を行
う方法（サーモゾル法）等があげられる。In order to dye polyester fibers using the dye composition obtained in this way, dyeing is carried out under pressure at 105°C or higher, preferably at 110 to 140°C, and in the presence of a carrier such as 0-phenylphenol. Examples include a method of dyeing at a relatively high temperature, for example, the boiling point of water, or a method of padding cloth with a dye dispersion and dry heat treatment at 150 to 230° C. for 30 to 60 seconds (thermosol method).
一方、捺染を行う場合には、染料組成物をグアガムやロ
ーカストビーンガム等の適当な糊剤と共に練り合せこれ
を布に印捺して、スチーミング又はサーモゾール法で処
理して目的を達する。On the other hand, in the case of printing, the dye composition is kneaded with a suitable thickening agent such as guar gum or locust bean gum, and this is printed on cloth, which is then treated by steaming or thermosol method to achieve the purpose.
以下本発明の効果を表−１によって説明する。The effects of the present invention will be explained below with reference to Table-1.
表−１は、本発明染料組成物の実施例及び比較例として
の市販染料を使用して捺染した結果を示したものである
。表−１から明らかなように、本発明の配合染料は、い
ずれも比較例としての市販染料よりも各種堅牢度が優れ
ており、特に機内昇華性、白湯汚染性が少ないことがわ
かる。Table 1 shows the results of printing using Examples of the dye composition of the present invention and commercially available dyes as comparative examples. As is clear from Table 1, all of the blended dyes of the present invention are superior to the commercially available dyes as comparative examples in various fastnesses, and are particularly less susceptible to in-machine sublimation and hot water staining.
（以下余白）
ｒｊＱ絹書の浄書（内容に変更なし）
明細書の浄Ｉ（内容に変更なし）
以下、実施例を挙げて本発明を更に詳しく説明するが１
本発明はこれらに限定されるものではない。(Leaving space below) rjQ silk engraving (no change in content) Engraving of specification I (no change in content) Below, the present invention will be explained in more detail with reference to examples.
The present invention is not limited to these.
実施例中の「部」は電量部を示す。"Part" in the examples indicates a coulometric part.
〔実施例−１〕
前記式（Ｉ−１）の染料原体５．０部を、デモールＮ（
花王アトラス製品）５部、及び水１８部と共に微粒化分
散し、配合成分（Ａ）を調整した。同じく、前記式（Ｉ
Ｉ）の染料原体１２部を、チモールＮ１０部、及び水２
５部と共に微粒化分散し、配合成分（Ｂ）を、また前記
式（ｍ−１）の染料原体５部を、チモール８３部と水６
部と共に微粒化分散し、配合成分（Ｃ）をそれぞれ別々
に調整した。[Example-1] 5.0 parts of the dyestuff of formula (I-1) above was mixed with Demol N
Kao Atlas product) and 18 parts of water were atomized and dispersed to prepare a blended component (A). Similarly, the formula (I
12 parts of the dyestuff I), 10 parts of thymol N, and 2 parts of water
Component (B) and 5 parts of the dyestuff of formula (m-1) were mixed with 83 parts of thymol and 6 parts of water.
Component (C) was adjusted separately.
さらに前記（Ｖ−ｔ）の染料原体２部を、チモール８３
部と水６部と共に微粒化分散し、配合成分ＣＤ）を調整
し、これらの配合成分（Ａ） 、 （Ｂ）、（Ｃ）、お
よび（Ｄ）を配合して黒色染料組成物１００部を得た。Furthermore, thymol 83
1 part and 6 parts of water were atomized and dispersed, the compounding component CD) was adjusted, and these compounding components (A), (B), (C), and (D) were blended to make 100 parts of a black dye composition. Obtained.
この黒色染料組成物１００部に水２００部を加えた後、
Ｏ／Ｗ型エマルジョン糊２８０部、メイプロガムＮＰ（
加工中ローカストビーン系ガムＭＡＹＨＡＬＬ社製品）
１２チペ一スト４２０部と共に練り合わせポリエステル
繊維上に印捺し１７５゛Ｃで８分間高温スチーミングを
行な９た。その後染色物をソーダ灰３部、ハイドロサル
ファイド３部、スコアロール４００（ノニオン型界面活
性剤花王アトラス社製品）１．５部と水３０００部より
なる浴中で６５℃、１０分間還元洗浄処理を行ない水洗
、乾燥して濃度の高い黒色捺染物が得られた。捺染物は
還元洗浄時の白湯汚染性、発色時の機内昇華汚染性等が
極めて少なく、また日光、昇華、水、洗濯等の諸堅牢度
は優秀であった。After adding 200 parts of water to 100 parts of this black dye composition,
280 parts of O/W type emulsion glue, Maypro Gum NP (
Processing locust bean gum (MAYHALL product)
The resulting mixture was kneaded with 420 parts of 1200 g of 1200 ml of 100% polyester, printed on a polyester fiber, and subjected to high-temperature steaming at 175° C. for 8 minutes. Thereafter, the dyed material was subjected to a reduction cleaning treatment at 65°C for 10 minutes in a bath consisting of 3 parts of soda ash, 3 parts of hydrosulfide, 1.5 parts of Score Roll 400 (a nonionic surfactant manufactured by Kao Atlas Co., Ltd.) and 3000 parts of water. After washing with water and drying, a black print with high density was obtained. The printed product had very little hot water staining during reduction washing and in-machine sublimation staining during color development, and had excellent fastness to sunlight, sublimation, water, washing, etc.
〔実施例−２〕
前記式（Ｉ−１）の染料原体５．６部をチモール８５部
及び水１８部と共に微粒化分散し、配合成分（Ｅ）とし
前記式（ＩＩ）の染料原体１１，２部をチモールＮ１０
部、及び水２０部より調整した配合成分（Ｆ）、前記式
（Ｉ’Ｖ−１）５．５部、デモ−／ＩｚＮ５．５部及び
水１０部より調整した配合成分（Ｇ）と前記式（Ｖｌ−
１）の染料原体２０部、デモールＮ２．０部及び水５部
２部より調整した配合成分（Ｈ）を配合して黒色染料組
成物１００部を得た。[Example-2] 5.6 parts of the dyestuff of the formula (I-1) above was atomized and dispersed with 85 parts of thymol and 18 parts of water to form a blended component (E), and the dyestuff of the above formula (II) was dispersed. 11.2 parts thymol N10
Component (F) prepared from 1 part and 20 parts of water, 5.5 parts of the above formula (I'V-1), 5.5 parts of Demo/IzN and 10 parts of water, and the above formula (G). Formula (Vl-
A blending component (H) prepared from 20 parts of the dye base material (1), 2.0 parts of Demol N, and 5 parts and 2 parts of water was blended to obtain 100 parts of a black dye composition.
この黒色染料組成物１００部を用いて実施例−１と同様
にして捺染したら、還元洗浄時の白湯汚染、発色時の機
内昇華の少なく、耐光、昇華、水、洗濯等の諸堅牢度の
漫れた黒色捺染物が得られた。When printing was carried out in the same manner as in Example 1 using 100 parts of this black dye composition, there was less hot water contamination during reduction washing, less in-machine sublimation during color development, and improved fastness to light, sublimation, water, washing, etc. A black printed product was obtained.
〔実施例−３〕
前記式Ｃｌ−１）の染料原体６．０部を、チモール８５
．０部および水１０部と共に微粒化分散し、配合成分（
Ｊ）を調整した。これに、前記式（ＩＩ）の染料原体１
２．０部を、チモールＮ１０部および水２０部と共に微
粒化分散して調整した配合成分（Ｉｏ及ヒ、前記式（ｍ
−１）の染料原体６．０部を。[Example-3] 6.0 parts of the dyestuff of the formula Cl-1) was mixed with thymol 85
．． Atomized and dispersed with 0 parts and 10 parts of water, the blended ingredients (
J) was adjusted. To this, the dyestuff 1 of the formula (II)
2.0 parts of thymol N was atomized and dispersed with 10 parts of thymol N and 20 parts of water.
-6.0 parts of the dyestuff from 1).
チモールＮ１０部と水２１部と共に微粒化分散して調整
した配合成分（Ｌ）を配合して、（Ｊ）、■）、（Ｌ）
の三成分よりなる黒色染料組成物１００部を得た。(J), (■), (L) by blending the blended component (L) prepared by atomizing and dispersing it with 10 parts of thymol N and 21 parts of water.
100 parts of a black dye composition consisting of three components was obtained.
これを用いて実施例−■と同様にして、捺染したら還元
洗浄時の白湯汚染１発色時の機内昇華の少なく、耐光、
昇華、水、洗濯等の諸堅牢度の優れた黒色捺染物が得ら
れた。Using this, printing was carried out in the same manner as in Example-■.
A black printed product with excellent fastness to sublimation, water, washing, etc. was obtained.
〔実施例−４〕
前記式（Ｉ−１）の染料原体１０部と前記式（■−１）
の染料原体１０部を、チモールＮ１２部および水３４部
と共に微粒化分散し、配合成分（Ｍ）を調整した。これ
に前記式（ＩＩ）の染料原体３部をチモール８３部およ
び水９部と共に微粒化分散して調整した配合成分（Ｎ）
及び、前記式（Ｖ−１）の染料原体２部を、チモール８
２部と水１５部と共に微粒化分散して調整した配合成分
（Ｐ）を配合してＣＭ） 、 （Ｎ）、（Ｐ）の三成分
よりなるネービ色配合染料組成物１００部を得た。[Example-4] 10 parts of the dyestuff of the formula (I-1) and the formula (■-1)
10 parts of the raw dye was atomized and dispersed together with 12 parts of thymol N and 34 parts of water to adjust the blended component (M). Compounding component (N) prepared by atomizing and dispersing 3 parts of the dyestuff of formula (II) above with 83 parts of thymol and 9 parts of water.
and 2 parts of the dyestuff of formula (V-1) above, thymol 8
2 parts and 15 parts of water were blended together with component (P), which was prepared by atomization and dispersion, to obtain 100 parts of a navy color blended dye composition consisting of the three components CM), (N), and (P).
このネーピ色染料粗成物５０部を用いて実施例１と同様
にして捺染したら、還元洗浄時の白湯汚染、発色時の機
内昇華性が少なく、耐光、水、洗濯等の諸堅牢度の優れ
たネービ色捺染物が帰られた。When printing was carried out in the same manner as in Example 1 using 50 parts of this napi color dye crude product, there was little hot water contamination during reduction washing, sublimation in the machine during color development, and excellent fastness to light, water, washing, etc. The navy colored textiles were returned.
〔実施例−５〕
前記式（Ｉ−１）の染料原体１０部をチモールＮ１０部
及び水１５部と共に微粒化分散して配合成分（Ｑ）を調
整した。前記式（ｎ）の染料原体２部をチモール８１部
及び水１０部と共に微粒化分散して配合成分（Ｒ）を調
整した。前記式（ＩＶ−３）の染料原体１０部をチモー
ルＮ１０部及び水１０部と共に微粒化分散して配合成分
（Ｓ）を調整した。[Example-5] Component (Q) was prepared by atomizing and dispersing 10 parts of the dyestuff of formula (I-1) with 10 parts of thymol N and 15 parts of water. A compounding component (R) was prepared by atomizing and dispersing 2 parts of the dyestuff of formula (n) with 81 parts of thymol and 10 parts of water. A blended component (S) was prepared by atomizing and dispersing 10 parts of the dyestuff of formula (IV-3) with 10 parts of thymol N and 10 parts of water.
前記式（ＶＩ−２）の染料原体２０部をチモール８２部
及び水１８部と共に微粒化分散して配合成分（Ｔ）を調
整した。Component (T) was prepared by atomizing and dispersing 20 parts of the dyestuff of formula (VI-2) with 82 parts of thymol and 18 parts of water.
これらの配合成分（Ｑ）、（Ｒ）、（Ｓ）、（Ｔ）を配
合し、ネービ色染料組成物１００部を得た。These ingredients (Q), (R), (S), and (T) were blended to obtain 100 parts of a navy dye composition.
昇華性が少なく、耐光、水、洗濯等の堅牢度の優れたネ
ーピ色捺染物が得られた。A napi color print with low sublimation and excellent fastness to light, water, washing, etc. was obtained.
〔実施ｌＮ−６）
実施例−１で得られる黒色染料組成物１０部を高級アル
コールＫＭエステル３部を含む水３０００部中に、均一
に分散させて染浴を調製する。次いでテトロンスパン糸
ｌＯＯ部を浸漬し、１３０℃で６０分間染色後、染色物
を苛性ソーダ３部、ハイドロサルファイド３部、ベタイ
ン型両性界面活性剤３部と水３０００部よりなる浴中で
６５℃で１０分間還元洗浄処理を行ない、水洗、乾燥し
て濃度の高い黒色染゛色物が得られた。本染色物は日光
、昇華、水等の諸堅牢度が優れていた。[Example 1N-6] A dye bath is prepared by uniformly dispersing 10 parts of the black dye composition obtained in Example-1 in 3,000 parts of water containing 3 parts of higher alcohol KM ester. Next, 100 parts of the Tetron spun yarn was immersed and dyed at 130°C for 60 minutes, and then the dyed product was dyed at 65°C in a bath consisting of 3 parts of caustic soda, 3 parts of hydrosulfide, 3 parts of a betaine type amphoteric surfactant, and 3000 parts of water. A reduction cleaning treatment was performed for 10 minutes, followed by washing with water and drying to obtain a highly concentrated black dye. This dyed product had excellent fastness to sunlight, sublimation, water, etc.
〔実施例−７〕
実施例−４で得られるネーピ色染料組成物５部を用いて
、実施例−６と同様にしてテトロンスパン糸を染色した
ら耐光、昇華、水等の諸堅牢度の優れたネービ色染色物
が得られた。[Example 7] Tetron spun yarn was dyed in the same manner as in Example 6 using 5 parts of the Napi color dye composition obtained in Example 4, and it had excellent light fastness, sublimation fastness, water fastness, etc. A navy dyed product was obtained.
（以下余白） 手続補正書く方式） 昭和６１年６月１２日(Margin below) Procedure amendment writing method) June 12, 1986
Claims (1)
で示される染料１０〜３０重量％、 式（II） ▲数式、化学式、表等があります▼（II） で示される染料４０〜６０重量％、 式（III） ▲数式、化学式、表等があります▼（III） 〔式（III）中Ｘは臭素原子、又は塩素原子を表わし、
Ｒは炭素数１〜５のアルキル基を表わす〕で示される染
料、又は 一般式（IV） ▲数式、化学式、表等があります▼（IV） 〔式（IV）中、Ｘは塩素または臭素原子、Ｒはメチル基
、又はエチル基を表わす。〕 で示される染料１０〜３０重量％、そして色調を合わせ
るために必要に応じて、 式（Ｖ） ▲数式、化学式、表等があります▼（Ｖ） 〔式（Ｖ）中Ｘは塩素原子、又は臭素原子を表わす。〕 で示される染料、又は式（VI） ▲数式、化学式、表等があります▼（VI） 〔式（VI）中Ｒはメチル基、又はエチル基を表わす。〕 で示される染料を０〜１０重量％を加えてなることを特
徴とするポリエステル繊維用黒色分散染料組成物。 ２）式（ I ） ▲数式、化学式、表等があります▼（ I ） 〔式（ I ）中Ｘは塩素原子、又は臭素原子を表わす〕
で示される染料１０〜３０重量％、 式（II） ▲数式、化学式、表等があります▼（II） で示される染料４０〜６０重量％、 式（III） ▲数式、化学式、表等があります▼（III） 〔式（III）中Ｘは塩素原子、又は臭素原子を表わし、
Ｒは炭素数１〜５のアルキル基を表わす〕で示される染
料、又は 一般式（IV） ▲数式、化学式、表等があります▼（IV） 〔式（IV）中、Ｘは塩素または臭素原子、Ｒはメチル基
又はエチル基を表わす。〕 で示される染料１０〜３０重量％、そして色調を合わせ
るために必要に応じて 式（Ｖ） ▲数式、化学式、表等があります▼（Ｖ） 〔式（Ｖ）中Ｘは塩素原子、又は臭素原子を表わす。〕 で示される染料、又は式（VI） ▲数式、化学式、表等があります▼（VI） 〔式（VI）中Ｒはメチル基、又はエチル基を表わす。〕 で示される染料０〜１０重量％を配合してなる黒色分散
染料組成物を用いることを特徴とするポリエステル繊維
の染色または捺染方法。 ３）式（ I ） ▲数式、化学式、表等があります▼（ I ） 〔式（ I ）中Ｘは塩素原子、又は臭素原子を表わす〕
で示される染料２０〜５０重量％、 式（II） ▲数式、化学式、表等があります▼（II） で示される染料５〜１５重量％ 式（III） ▲数式、化学式、表等があります▼（III） 〔式（III）中Ｘは臭素原子、又は塩素原子を表わし、
Ｒは炭素数１〜５のアルキル基を表わす〕で示される染
料、又は一般式（IV） ▲数式、化学式、表等があります▼（IV） 〔式（IV）中、Ｘは塩素または臭素原子、Ｒはメチル基
、又はエチル基を表わす。〕 で示される染料２０〜５０重量％、そして調色の必要に
応じて式（Ｖ） ▲数式、化学式、表等があります▼（Ｖ） 〔式（Ｖ）中Ｘは塩素原子、又は臭素原子を表わす。〕 又は、式（VI） ▲数式、化学式、表等があります▼（VI） 〔式（VI）中Ｒはメチル基、又はエチル基を表わす。〕 で示される染料０〜１０％を配合してなることを特徴と
するポリエステル繊維用ネービ色分散染料組成物。 ４）式（ I ） ▲数式、化学式、表等があります▼（ I ） 〔式（ I ）中Ｘは塩素原子又は臭素原子を表わす。〕
で示される染料２０〜５０重量％、 式（II） ▲数式、化学式、表等があります▼（II） で示される染料５〜１５重量％、 式（III） ▲数式、化学式、表等があります▼（III） 〔式（III）中Ｘは塩素原子、又は臭素原子を表わし、
Ｒは炭素数１〜５のアルキル基を表わす〕で示される染
料又は一般式（IV） ▲数式、化学式、表等があります▼（IV） 〔式（IV）中Ｘは塩素または臭素原子、Ｒはメチル基又
はエチル基を表わす。〕 で示される染料２０〜５０重量％、又は調色の必要に応
じて、式（Ｖ） ▲数式、化学式、表等があります▼（Ｖ） 〔式（Ｖ）中Ｘは塩素原子、又は臭素原子を表わす。〕 又は、式（VI） ▲数式、化学式、表等があります▼（VI） 〔式（VI）中Ｒはメチル基、又はエチル基を表わす。〕 で示される染料０〜１０％を配合してなるネービ色分散
染料組成物を用いることを特徴とするポリエステル繊維
の染色または捺染方法。[Claims] 1) Formula (I) ▲There are mathematical formulas, chemical formulas, tables, etc.▼(I) [In formula (I), X represents a chlorine atom or a bromine atom. ]
10-30% by weight of the dye represented by formula (II) ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ 40-60% by weight of the dye represented by (II), formula (III) ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼(III) [X in formula (III) represents a bromine atom or a chlorine atom,
R represents an alkyl group having 1 to 5 carbon atoms] or general formula (IV) ▲ Numerical formulas, chemical formulas, tables, etc. are available ▼ (IV) [In formula (IV), X is a chlorine or bromine atom , R represents a methyl group or an ethyl group. ] 10 to 30% by weight of the dye represented by Formula (V) ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ (V) [In formula (V), X is a chlorine atom, Or represents a bromine atom. ] Dye represented by formula (VI) ▲ Numerical formulas, chemical formulas, tables, etc. are available ▼ (VI) [In formula (VI), R represents a methyl group or an ethyl group. ] A black disperse dye composition for polyester fibers, characterized in that it contains 0 to 10% by weight of the dye shown below. 2) Formula (I) ▲There are mathematical formulas, chemical formulas, tables, etc.▼(I) [In formula (I), X represents a chlorine atom or a bromine atom]
10-30% by weight of the dye represented by formula (II) ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ 40-60% by weight of the dye represented by (II), formula (III) ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼(III) [X in formula (III) represents a chlorine atom or a bromine atom,
R represents an alkyl group having 1 to 5 carbon atoms] or general formula (IV) ▲ Numerical formulas, chemical formulas, tables, etc. are available ▼ (IV) [In formula (IV), X is a chlorine or bromine atom , R represents a methyl group or an ethyl group. ] 10 to 30% by weight of the dye represented by the formula (V) as necessary to match the color tone ▲ Numerical formulas, chemical formulas, tables, etc. are available ▼ (V) [In the formula (V), X is a chlorine atom, or Represents a bromine atom. ] Dye represented by formula (VI) ▲ Numerical formulas, chemical formulas, tables, etc. are available ▼ (VI) [In formula (VI), R represents a methyl group or an ethyl group. ] A method for dyeing or printing polyester fibers, which comprises using a black disperse dye composition containing 0 to 10% by weight of the dye represented by the formula. 3) Formula (I) ▲There are mathematical formulas, chemical formulas, tables, etc.▼(I) [In formula (I), X represents a chlorine atom or a bromine atom]
20-50% by weight of the dye represented by Formula (II) ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ (II) 5-15% by weight of the dye represented by Formula (III) ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ (III) [X in formula (III) represents a bromine atom or a chlorine atom,
R represents an alkyl group having 1 to 5 carbon atoms] or general formula (IV) ▲ Numerical formulas, chemical formulas, tables, etc. are available ▼ (IV) [In formula (IV), X is a chlorine or bromine atom , R represents a methyl group or an ethyl group. ] 20 to 50% by weight of the dye represented by Formula (V) ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ (V) [In Formula (V), X is a chlorine atom or a bromine atom represents. ] Or formula (VI) ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ (VI) [In formula (VI), R represents a methyl group or an ethyl group. ] A navy colored disperse dye composition for polyester fibers, characterized in that it contains 0 to 10% of the dye represented by: 4) Formula (I) ▲There are mathematical formulas, chemical formulas, tables, etc.▼(I) [In formula (I), X represents a chlorine atom or a bromine atom. ]
20-50% by weight of the dye represented by Formula (II) ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ 5-15% by weight of the dye represented by (II), Formula (III) ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼(III) [X in formula (III) represents a chlorine atom or a bromine atom,
R represents an alkyl group having 1 to 5 carbon atoms] or general formula (IV) ▲ Numerical formulas, chemical formulas, tables, etc. are available ▼ (IV) [In formula (IV), X is a chlorine or bromine atom, R represents a methyl group or an ethyl group. ] Formula (V) ▲ Numerical formulas, chemical formulas, tables, etc. are available ▼ (V) [In formula (V), X is a chlorine atom or bromine atom. represents an atom. ] Or formula (VI) ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ (VI) [In formula (VI), R represents a methyl group or an ethyl group. ] A method for dyeing or printing polyester fibers, characterized by using a navy disperse dye composition containing 0 to 10% of the dye represented by the formula.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5266986A JPS62212468A (en) | 1986-03-12 | 1986-03-12 | Disperse dye composition for polyester fiber and dyeing or printing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5266986A JPS62212468A (en) | 1986-03-12 | 1986-03-12 | Disperse dye composition for polyester fiber and dyeing or printing method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62212468A true JPS62212468A (en) | 1987-09-18 |
Family
ID=12921275
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5266986A Pending JPS62212468A (en) | 1986-03-12 | 1986-03-12 | Disperse dye composition for polyester fiber and dyeing or printing method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62212468A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998020078A1 (en) * | 1996-11-01 | 1998-05-14 | Nippon Kayaku Kabushiki Kaisha | Dye composition and method for dyeing hydrophobic fiber with the same |
| CN101984001A (en) * | 2010-07-30 | 2011-03-09 | 江苏亚邦染料股份有限公司 | Compound type direct-printing black disperse dye with high fastness |
| CN102653635A (en) * | 2012-03-15 | 2012-09-05 | 江苏之江化工有限公司 | Printing black disperse dyes |
| WO2020147344A1 (en) * | 2019-01-16 | 2020-07-23 | 浙江博澳染料工业有限公司 | Dispersed dark blue dye preparation method and application |
-
1986
- 1986-03-12 JP JP5266986A patent/JPS62212468A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998020078A1 (en) * | 1996-11-01 | 1998-05-14 | Nippon Kayaku Kabushiki Kaisha | Dye composition and method for dyeing hydrophobic fiber with the same |
| US6159249A (en) * | 1996-11-01 | 2000-12-12 | Nippon Kayaku Kabushiki Kaisha | Dye composition and method for dyeing hydrophobic fiber with the same |
| CN101984001A (en) * | 2010-07-30 | 2011-03-09 | 江苏亚邦染料股份有限公司 | Compound type direct-printing black disperse dye with high fastness |
| CN102653635A (en) * | 2012-03-15 | 2012-09-05 | 江苏之江化工有限公司 | Printing black disperse dyes |
| WO2020147344A1 (en) * | 2019-01-16 | 2020-07-23 | 浙江博澳染料工业有限公司 | Dispersed dark blue dye preparation method and application |
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