JPS62207813A - Exhaust gas treatment device for ar-o2 refining furnace - Google Patents

Exhaust gas treatment device for ar-o2 refining furnace

Info

Publication number
JPS62207813A
JPS62207813A JP5202986A JP5202986A JPS62207813A JP S62207813 A JPS62207813 A JP S62207813A JP 5202986 A JP5202986 A JP 5202986A JP 5202986 A JP5202986 A JP 5202986A JP S62207813 A JPS62207813 A JP S62207813A
Authority
JP
Japan
Prior art keywords
gas
damper
gaseous
recovery system
way valve
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP5202986A
Other languages
Japanese (ja)
Inventor
Masanari Yamazaki
政成 山崎
Nobuyuki Fujikura
信幸 藤倉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kawasaki Heavy Industries Ltd
Original Assignee
Kawasaki Heavy Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kawasaki Heavy Industries Ltd filed Critical Kawasaki Heavy Industries Ltd
Priority to JP5202986A priority Critical patent/JPS62207813A/en
Publication of JPS62207813A publication Critical patent/JPS62207813A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To recover gaseous CO and gaseous Ar by providing three lines; gaseous CO recovering line, CO2 diffusing line and gaseous Ar recovering line and changing over the three lines by gaseous CO recovering line and gaseous Ar recovering line 3-way valves respectively. CONSTITUTION:The tampon gas of an Ar-O2 refining furnace 1 in the initial period of blowing is treated in the following manner: The gaseous CO2 is released from a chimney 9 by closing damper 12 of the gaseous CO recovering line 3-way valve 12, opening a damper 13, and at the same time, by opening damper 14 of the gaseous Ar recovering line 3-way valve and closing damper 15. Only the 3-way valve of the gaseous CO recovering line is operated and the gaseous CO is recovered in a gas holder 8 by opening the damper 12 and closing the damper 13 when the concn. of the gaseous CO is high. The gaseous Ar is recovered into a gas holder 10 by closing the damper 12 of the gaseous CO recovering line 3-way valve, opening the damper 13, closing the damper 14 of the Ar recovering line 3-way valve and opening the damper 15 when the concn. of the gaseous Ar is high.

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明は、Ar−0,精錬炉から発生するAr及びCO
ガスの回収装置に関する。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention is directed to the use of Ar-0, Ar and CO generated from smelting furnaces.
This invention relates to a gas recovery device.

[従来の技術] Ar−02精錬炉は、多量のArガスが使用される。こ
のArガスは、高価なガスであるため、これを回収し、
再使用される。
[Prior Art] The Ar-02 refining furnace uses a large amount of Ar gas. This Ar gas is an expensive gas, so it is collected and
Reused.

従来のAr回収方法は、精錬炉から発生するCOガスと
Arガスの混合ガス中のCOガスを燃焼して、ArとC
O2ガスの混合ガスとし、この混合ガスを精錬炉に導い
て、Arガスを再使用すると共にCO2ガスは精錬に際
して脱炭(CO2+ C= 2 CO)に寄与せしめる
ものがある(特公昭57−20372号1特公昭55−
34847号)。
The conventional Ar recovery method burns CO gas in a mixed gas of CO gas and Ar gas generated from a refining furnace to recover Ar and C.
A mixed gas of O2 gas is introduced into a refining furnace, where Ar gas is reused and CO2 gas contributes to decarburization (CO2+ C= 2 CO) during refining (Japanese Patent Publication No. 57-20372). No. 1 Special Public Service 1984-
No. 34847).

又、別の^「回収方法としては、精錬炉から発生するC
OガスとArの混合ガス中のCOガスを燃焼して、Ar
とCO2ガスの混合ガスにし、この混合ガスを冷却し、
C02ガスを吸収材にて吸収分離して、Arガスを回収
する方法がある(特公昭52’−28750号、特公昭
50−11999号)。
In addition, there is another method for recovering C generated from smelting furnaces.
By burning CO gas in a mixture of O gas and Ar, Ar
and CO2 gas, and cool this mixed gas,
There is a method of recovering Ar gas by absorbing and separating C02 gas using an absorbent material (Japanese Patent Publication No. 52'-28750, Japanese Patent Publication No. 11999-1987).

[発明が解決しようとする問題点] 上記従来のAr回収方法は、いづれも精錬炉から発生す
るCOガスをすべて燃焼させるものであった。
[Problems to be Solved by the Invention] All of the conventional Ar recovery methods described above burn all of the CO gas generated from the refining furnace.

そのため、燃料として或いは化学産業等に使用できるC
Oガスは、無駄に捨てられてしまい、省資源の観点から
好ましくなく、又精錬炉から発生する大量のCOガスを
燃焼させることにより、ガスの容積が大きくなって、A
rを回収するための各m器も大型化するという欠点があ
った。
Therefore, C can be used as fuel or in the chemical industry, etc.
O gas is wasted and is undesirable from the viewpoint of resource conservation.Also, by burning a large amount of CO gas generated from the smelting furnace, the volume of gas becomes large and A
There was a drawback that each m device for collecting r was also large in size.

[発明の目的] 本発明は、上記問題乃至は欠点を解決するためになされ
たものであり、COガスの回収とArの回収を効率よく
行うようにしたAr−02精錬炉の排ガス処理装置を提
供することを目的とするものである。
[Object of the Invention] The present invention has been made to solve the above-mentioned problems or drawbacks, and provides an exhaust gas treatment device for an Ar-02 refining furnace that efficiently recovers CO gas and Ar. The purpose is to provide

[問題点を解決するための手段] 上記問題点を解決するために本発明は、計−〇、精錬時
に発生するCOガス、^「ガスの濃度に合せて回収する
ようにしたものである。即ち、本発明の排ガス処理装置
は、Ar−02精峠炉から発生するCOガスを回収する
ための水封弁を備えたCOガス回収系と、CO2ガスを
排出するための放散系と、Arガスを回収するためのA
rガス回収系との三つの系を主導路より分岐して設ける
。そして、この分岐した三つの系をそれぞれ交互に切換
えるCOガス回収系及びAr回収系三方弁を設けたもの
である。
[Means for Solving the Problems] In order to solve the above problems, the present invention is designed to recover CO gas generated during refining in accordance with the concentration of the CO gas. That is, the exhaust gas treatment apparatus of the present invention includes a CO gas recovery system equipped with a water seal valve for recovering CO gas generated from the Ar-02 Seitouge furnace, a diffusion system for discharging CO2 gas, and an Ar A for recovering gas
Three systems including the r-gas recovery system are provided branching off from the main path. A three-way valve for a CO gas recovery system and an Ar recovery system is provided to alternately switch between these three branched systems.

[作 用] 本発明の排ガス処理装置は、以上のように構成されてい
るので、COガスの濃度の高い排ガスは、COガス回収
系により回収し、又Arガスの濃度の高い排ガスは、A
rガス回収系により回収する。この^「ガス回収に際し
ては、混合している少量のCOガスは燃焼してCO2ガ
スとし、前述した従来技術により^「ガスのみを分離回
収する。この場合COガスは少量であるので、大型の機
器は必要としない。そして、上記COガス回収系及び^
「ガス回収系は、三方弁により切換えられる。
[Function] Since the exhaust gas treatment device of the present invention is configured as described above, exhaust gas with a high concentration of CO gas is recovered by the CO gas recovery system, and exhaust gas with a high concentration of Ar gas is recovered by the A gas recovery system.
rRecovered by gas recovery system. When recovering this gas, a small amount of mixed CO gas is burned to become CO2 gas, and using the conventional technology mentioned above, only the gas is separated and recovered. In this case, since the amount of CO gas is small, a large No equipment is required.The above CO gas recovery system and ^
“The gas recovery system is switched by a three-way valve.

[実施例] 先ず、第2図及び第3図によりAr −0,精錬の経時
的な徘ガス組成について説明する。
[Example] First, the composition of wandering gas over time during Ar-0 and refining will be explained with reference to FIGS. 2 and 3.

第2図は、250 Ton炉の実例で、吹錬開始より2
5分乃至は35分までの精錬は、ozffiが多く、こ
の間の精錬炉から出る排ガスは、cOガス濃度が高い、
又、吹!1li35分から55分までは、Arガスのみ
が使用されて精錬が行われ、55分から95分の間では
、Arガスと少量の02が使用されて精錬される。従っ
て、吹錬開始後35分から95分の間では、^「ガス濃
度の高い排ガスが発生する。
Figure 2 shows an example of a 250 ton furnace.
Refining for 5 minutes to 35 minutes has a large amount of ozffi, and the exhaust gas emitted from the refining furnace during this period has a high cO gas concentration.
Again, blow! From 1li35 minutes to 55 minutes, only Ar gas is used for refining, and from 55 minutes to 95 minutes, Ar gas and a small amount of 02 are used for refining. Therefore, from 35 minutes to 95 minutes after the start of blowing, exhaust gas with high gas concentration is generated.

この実例からみて、吹錬開始から35分までは、COガ
スの回収を行い、35分以後95分までは、Arガスの
回収を行う。
From this example, CO gas is recovered for 35 minutes from the start of blowing, and Ar gas is recovered for 95 minutes after 35 minutes.

第3図は、120Ton炉の実例で、吹錬開始から11
分まではCOガス濃度が高い排ガスが発生し、11分以
後55分までは、^「ガス濃度の高い排ガスが発生する
Figure 3 shows an example of a 120 ton furnace.
From 11 minutes to 55 minutes, exhaust gas with a high CO gas concentration is generated.

従って、この炉の場合は、吹錬開始後11分までは、C
Oガス回収を行い、11分以後55分までは、Arガス
の回収を行う。
Therefore, in the case of this furnace, C
O gas is recovered, and Ar gas is recovered from 11 minutes to 55 minutes.

上記^「ガス回収に際して、少量のO3により生成され
るCOガスは、燃焼してCO2ガスとなし、従来技術に
よりCO,ガスは分離して純度の高いArガスを回収す
る。
``During gas recovery, CO gas generated by a small amount of O3 is burned to become CO2 gas, and using conventional technology, CO and gas are separated to recover highly pure Ar gas.

又上記回収に際しては、時間を一つの基準として行うこ
ともできるが、COガス又は計ガス濃度を検知して行う
こともできる。
In addition, the above-mentioned collection can be performed using time as a reference, but it can also be performed by detecting the CO gas or metered gas concentration.

次に第1図により、本発明の排ガス処理装置の一実施例
を説明する0図において、1は転炉(精錬炉)である、
転炉1内にある溶銑中には、酸素吹込みランス2より純
酸素が吹込まれると共に、下方より^「ガス18が吹込
まれて精錬される。このとぎ溶銑中のCと0.とが反応
して大量のCOガスが発生する。従って、転炉1からは
COガスとArガスの混合ガスが排出される。この排出
された排ガスは誘引送風機により冷却器3に誘引され冷
却される。4及び5は集塵器である。8はCOガス回収
ホルダである。
Next, referring to FIG. 1, in FIG.
Pure oxygen is blown into the hot metal in the converter 1 from the oxygen injection lance 2, and gas 18 is blown in from below for refining. A large amount of CO gas is generated by the reaction. Therefore, a mixed gas of CO gas and Ar gas is discharged from the converter 1. This discharged exhaust gas is drawn into the cooler 3 by an induced blower and is cooled. 4 and 5 are dust collectors. 8 is a CO gas recovery holder.

フは水封弁、19は水封式逆止弁であり、それぞれ主導
路20より分岐されたダクトの途中に設けられ、COガ
ス回収系を構成している。
19 is a water seal valve, and 19 is a water seal type check valve, each of which is provided in the middle of a duct branched from the main channel 20, and constitutes a CO gas recovery system.

12はCOガス回収系の入口に設けられたダンパである
。9は主導路20より分岐したダクト21に接続された
煙突であり、CO2ガスを放散するための放散系を構成
している。14は放散系の入口に設けられたダンパであ
る。10はアルゴンガス回収ホルダであり、主導路20
より分岐されたダクト22に接続されてアルゴンガス回
収系を構成している。15はアルゴンガス回収系の人口
に設けられたダンパである。
12 is a damper provided at the inlet of the CO gas recovery system. A chimney 9 is connected to a duct 21 branched from the main channel 20, and constitutes a dissipation system for dissipating CO2 gas. 14 is a damper provided at the entrance of the radiation system. 10 is an argon gas recovery holder, and a main path 20
The argon gas recovery system is connected to a duct 22 which is further branched. 15 is a damper installed in the argon gas recovery system.

16は押込み送風機であり、アルゴンガスホルダ10内
のArガスを転炉1の炉口部に供給し、炉口とフード2
3との間をシールする。11は炉口とフード23間を密
封するためのスカートである。17はArガスを炉口に
導くための導管である。又、前記ダンパ12とダンパ1
3は、一体となって動作し、ダンパ13が開のときダン
パ12は閑の状!(図の状態)となり、その逆にダンパ
13が閉のときはダンパ12は開の状態となる。このよ
うにダンパ12,13によりCOガス回収系三方弁が形
成される。又、ダンパ14と15は一体となって動作し
、ダンパ14が閉のときダンパ15は開となり、その逆
にダンパ14が開のときダンパ15は閉となって、Ar
回収系三方弁が形成される。
16 is a forced air blower, which supplies Ar gas in the argon gas holder 10 to the furnace mouth of the converter 1, and connects the furnace mouth and the hood 2.
Seal between 3 and 3. 11 is a skirt for sealing between the furnace mouth and the hood 23. 17 is a conduit for guiding Ar gas to the furnace mouth. Moreover, the damper 12 and the damper 1
3 operates in unison, and when the damper 13 is open, the damper 12 is idle! (the state shown in the figure), and conversely, when the damper 13 is closed, the damper 12 is in the open state. In this way, the dampers 12 and 13 form a three-way valve for the CO gas recovery system. Further, the dampers 14 and 15 operate in unison, and when the damper 14 is closed, the damper 15 is open, and conversely, when the damper 14 is open, the damper 15 is closed, and the Ar
A recovery system three-way valve is formed.

以上のように構成した本実施例の作用について説明する
。吹錬の初期におけるタンポンガス(爆発防止用の00
2ガス)は、煙突9より放出される。即ち、COガス回
収系三方弁(ダンパ12,13)のダンパ12を閑とな
し、ダンパ13を開となす、と同時にArガス回収系三
方弁(ダンパ14.+5)のダンパ14を開となし、ダ
ンパ15を閉となして、放散系を開放し、C02ガスを
煙突9より放散する。
The operation of this embodiment configured as above will be explained. Tampon gas at the beginning of blowing (00 to prevent explosion)
2 gas) is released from the chimney 9. That is, the damper 12 of the CO gas recovery system three-way valve (dampers 12, 13) is left idle and the damper 13 is opened, and at the same time, the damper 14 of the Ar gas recovery system three-way valve (dampers 14.+5) is opened. , the damper 15 is closed, the dissipation system is opened, and the CO2 gas is dissipated from the chimney 9.

次にCOガス濃度の高い時期(時間的又は、COガス濃
度検出により検知する)は、COガス回収系三方弁(ダ
ンパ12,13)のみを操作し、ダンパ12を開となし
、ダンパ13を閉となして、COガスをガスホルダ8に
回収する。次にArガス濃度が高い時期(時間的又はA
rガス濃度検出により検知する)は、CO回収系三方弁
のダンパ12を閉となし、ダンパ13を開となす、と同
時にAr回回数系三方弁ダンパ14を閉となし、ダンパ
15を開となす、或いはCOガスを回収している間に、
又はCO,ガスを煙突9より放散後に、予め^「回数系
三方弁のダンパ14を閉、ダンパ15を開の状態にして
おいて、Arガス回収時にCOガス回収系三方弁の操作
のみで、^「回収系を開放することができる。
Next, when the CO gas concentration is high (detected over time or by CO gas concentration detection), only the CO gas recovery system three-way valve (dampers 12, 13) is operated, damper 12 is opened, and damper 13 is closed. It is closed and CO gas is collected into the gas holder 8. Next, the period when the Ar gas concentration is high (temporal or
(detected by R gas concentration detection) closes the damper 12 of the CO recovery system three-way valve and opens the damper 13, and at the same time closes the Ar cycle system three-way valve damper 14 and opens the damper 15. While collecting eggplant or CO gas,
Alternatively, after dissipating CO and gas from the chimney 9, close the damper 14 of the three-way valve and open the damper 15 in advance, and when recovering Ar gas, simply operate the three-way valve of the CO gas recovery system. ^ “We can open up the recovery system.

このようにして、アルゴンガス回収タンク10に回収さ
れた^「ガスは、アルゴンガス精製袋!(図示省略)へ
導かれる。アルゴンガス精製装置では、少量含まれてい
るCOガスを燃焼してCO2ガスとなし、吸収装置等に
よりC02ガスを吸収分離し、純度の高い^「ガスを回
収する。この場合、含有されているC02ガスは少量で
あるので、アルゴンガス精製装置は小型化で診る。
In this way, the gas collected in the argon gas recovery tank 10 is led to an argon gas purification bag (not shown).In the argon gas purification device, the CO gas contained in a small amount is combusted to produce CO2. The CO2 gas is absorbed and separated using an absorption device, etc., and the highly pure gas is recovered.In this case, since the amount of CO2 gas contained is small, the argon gas purification device should be miniaturized.

[発明の効果] 以上詳述した通り本発明による^「−02精錬炉の排ガ
ス処理装置によれば、COガス回収系とCOxガス放散
系及び^「ガス回収系の三つの系統を設け、これら三つ
の系をそれぞれCOガス回収系三方弁と、Ar回収系三
方弁にて切換えるようにしたので、COガスの回収とA
rガスの回収が可能となり、又、このようにCOガスと
Arガスを分けて回収したので、回収される^「ガス中
に含まれるCOガスは少量となり、^「精製装置を小型
化することができるなど優れた効果を奥する。
[Effects of the Invention] As detailed above, according to the present invention, the -02 refining furnace exhaust gas treatment system is provided with three systems: a CO gas recovery system, a COx gas diffusion system, and a gas recovery system. Since the three systems are switched by a three-way valve for the CO gas recovery system and a three-way valve for the Ar recovery system, CO gas recovery and A
It is now possible to recover r gas, and since the CO gas and Ar gas are collected separately in this way, the amount of CO gas contained in the gas is small, which makes it possible to downsize the purification equipment. It has great effects such as being able to do things.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明の一実施例を示すAr−(h$lt錬炉
の排ガス処理装置の構成図である。第2図は2、507
on炉、第3図は、120 Ton炉の実例に基いて、
夫々排ガスの組成を経時的に示した図である。 1・・・転炉  7・・・水封弁  8・・・COガス
ホルダ  9・・・煙突  10・・・アルゴンガスホ
ルダ  12,13,14.15・・・ダンパ19・・
・水封式逆止弁 水封弁7.水封式逆止弁19.COガスホルダ8・・・
COガス回収系 ダクト21.煙突9・・・放散系 ダクト22.アルゴンガスホルダ10・・・Arガス回
収系 ダンパ12.ダンパ13・・・COガス回収系三方弁
FIG. 1 is a block diagram of an exhaust gas treatment device for an Ar-(h$lt furnace) showing one embodiment of the present invention.
Figure 3 is based on an example of a 120 Ton furnace.
It is a figure showing the composition of each exhaust gas over time. 1... Converter 7... Water seal valve 8... CO gas holder 9... Chimney 10... Argon gas holder 12, 13, 14. 15... Damper 19...
・Water seal check valve Water seal valve 7. Water seal check valve 19. CO gas holder 8...
CO gas recovery system duct 21. Chimney 9...Dissipation system duct 22. Argon gas holder 10...Ar gas recovery system damper 12. Damper 13...CO gas recovery system three-way valve

Claims (1)

【特許請求の範囲】[Claims] Ar−O_2精錬炉から発生するCOガスを回収するた
めの水封逆止弁を備えたCOガス回収系と、CO_2ガ
スを排出するための放散系と、Arガスを回収するため
のArガス回収系とを主導路より分岐し、この分岐した
COガス回収系と放散系とArガス回収系とを、それぞ
れ交互に切換えるCOガス回収系及びAr回収系三方弁
を備えたAr−O_2精錬炉の排ガス処理装置。
A CO gas recovery system equipped with a water seal check valve to recover CO gas generated from the Ar-O_2 refining furnace, a dissipation system to discharge CO_2 gas, and an Ar gas recovery system to recover Ar gas. This is an Ar-O_2 smelting furnace equipped with a CO gas recovery system and an Ar recovery system three-way valve that branches the CO gas recovery system from the main path and alternately switches between the branched CO gas recovery system, the dissipation system, and the Ar gas recovery system. Exhaust gas treatment equipment.
JP5202986A 1986-03-10 1986-03-10 Exhaust gas treatment device for ar-o2 refining furnace Pending JPS62207813A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP5202986A JPS62207813A (en) 1986-03-10 1986-03-10 Exhaust gas treatment device for ar-o2 refining furnace

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP5202986A JPS62207813A (en) 1986-03-10 1986-03-10 Exhaust gas treatment device for ar-o2 refining furnace

Publications (1)

Publication Number Publication Date
JPS62207813A true JPS62207813A (en) 1987-09-12

Family

ID=12903385

Family Applications (1)

Application Number Title Priority Date Filing Date
JP5202986A Pending JPS62207813A (en) 1986-03-10 1986-03-10 Exhaust gas treatment device for ar-o2 refining furnace

Country Status (1)

Country Link
JP (1) JPS62207813A (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59152210A (en) * 1983-02-18 1984-08-30 Hitachi Ltd Recovery method of argon
JPS602617A (en) * 1983-06-21 1985-01-08 Kawasaki Heavy Ind Ltd Method for fractionating, recovering and reutilizing converter gas

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59152210A (en) * 1983-02-18 1984-08-30 Hitachi Ltd Recovery method of argon
JPS602617A (en) * 1983-06-21 1985-01-08 Kawasaki Heavy Ind Ltd Method for fractionating, recovering and reutilizing converter gas

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