JPS62204704A - Perfume container - Google Patents
Perfume containerInfo
- Publication number
- JPS62204704A JPS62204704A JP61046321A JP4632186A JPS62204704A JP S62204704 A JPS62204704 A JP S62204704A JP 61046321 A JP61046321 A JP 61046321A JP 4632186 A JP4632186 A JP 4632186A JP S62204704 A JPS62204704 A JP S62204704A
- Authority
- JP
- Japan
- Prior art keywords
- limonene
- acrylonitrile
- container
- weight
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002304 perfume Substances 0.000 title description 3
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims description 34
- 229940087305 limonene Drugs 0.000 claims description 17
- 235000001510 limonene Nutrition 0.000 claims description 17
- 239000011347 resin Substances 0.000 claims description 15
- 229920005989 resin Polymers 0.000 claims description 15
- 239000003205 fragrance Substances 0.000 claims description 11
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 10
- 150000002825 nitriles Chemical class 0.000 claims description 9
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- 150000001993 dienes Chemical class 0.000 claims 1
- 239000002075 main ingredient Substances 0.000 claims 1
- 239000000178 monomer Substances 0.000 claims 1
- 229920003051 synthetic elastomer Polymers 0.000 claims 1
- 239000005061 synthetic rubber Substances 0.000 claims 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 10
- 229920001577 copolymer Polymers 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 230000014759 maintenance of location Effects 0.000 description 4
- 229920000459 Nitrile rubber Polymers 0.000 description 3
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000002386 air freshener Substances 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- MJEMIOXXNCZZFK-UHFFFAOYSA-N ethylone Chemical compound CCNC(C)C(=O)C1=CC=C2OCOC2=C1 MJEMIOXXNCZZFK-UHFFFAOYSA-N 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 238000010559 graft polymerization reaction Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
Landscapes
- Containers Having Bodies Formed In One Piece (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、高二） ＩＪル樹脂よりなる香料用容器に関
する。DETAILED DESCRIPTION OF THE INVENTION (Industrial Field of Application) The present invention relates to a container for perfume made of high grade resin.
（従来の技術）
従来、リモネンを原料とする香料、例えば香水、芳香剤
、食料品などの容器の材質としては金属及び／又はガラ
スが用いられていた。しかし、価格、重量、取り扱い上
の安全性などの点から代替え材料が強く望まれ、今まで
に種々のプラスチックを用い、試行が繰り返されていた
が、どれも保香性に劣りリモネンの快香を保つことはで
きなかった。(Prior Art) Conventionally, metal and/or glass have been used as materials for containers for fragrances made from limonene, such as perfumes, air fresheners, and foodstuffs. However, there is a strong desire for alternative materials due to price, weight, handling safety, etc., and trials have been repeated using various plastics, but all of them have inferior scent retention, and the pleasant scent of limonene has failed. could not be kept.
（発明が解決しようとする問題点）
従来のプラスチック容器では通常の香料においては、そ
の保香期間に差はあるがかろうじて香りを保つことはで
きたが、それでも長期間に憤ることは困難であった。し
かし特にリモネンに関しては短期間でさえ、はとんどそ
の快香を保つことはできず、製造時の快香が流通時には
失われてしまい、期待通りの香りのままでおくことがで
きないという問題があった。(Problem to be solved by the invention) Conventional plastic containers have been able to barely retain the scent of ordinary fragrances, although there are differences in the fragrance retention period, but it is still difficult to retain the fragrance for a long period of time. Ta. However, the problem with limonene in particular is that it is not possible to maintain its pleasant aroma even for a short period of time, and the pleasant aroma at the time of manufacture is lost during distribution, making it impossible to maintain the aroma as expected. was there.
本発明は上述の従来技術の問題点を解決しようとするも
のである。The present invention seeks to solve the problems of the prior art described above.
（問題点を解決するための手段）
本発明者は、かかる問題を鋭意検討し、樹脂として高ニ
トリル樹脂を用いることにより解決しうろことを見出し
、遂に本発明を完成した。(Means for Solving the Problems) The inventors of the present invention have diligently studied these problems, found that they can be solved by using a high nitrile resin as the resin, and have finally completed the present invention.
すなわち、本発明はリモネンを主要成分とする香料を入
れる容器であって、該容器が高ニトリル樹脂からなるこ
とを特徴とする香料用容器である。That is, the present invention is a container for storing a fragrance containing limonene as a main component, and is characterized in that the container is made of a high nitrile resin.
本発明で用いる高二） ＩＪル樹脂とはアクリロニトリ
ル、メタクリレートリルなどの不飽和ニトリルを主体と
する共重合体であって不飽和ニトリル分を５０重量％以
上含むものである。コモノマーとしては、スチレン、ブ
タジェン、イソプレン、メチルアクリレート、エチルア
クリレート、メチルメタクリレート、エチルメタアクリ
レートなどであり、これらの１種以上をアクリロニトリ
ルと共重合させる。The high molecular weight resin used in the present invention is a copolymer mainly composed of unsaturated nitriles such as acrylonitrile and methacrylate, and contains 50% by weight or more of unsaturated nitrile. Examples of comonomers include styrene, butadiene, isoprene, methyl acrylate, ethyl acrylate, methyl methacrylate, and ethyl methacrylate, and one or more of these is copolymerized with acrylonitrile.
また、高ニトリル樹脂としてはブタジェン−アクリロニ
トリル共重合体、イソプレン−アクリロニトリル共重合
体、ブタジェン−スチレン共重合体、ポリブタジェン、
ポリイソプレｙなどのゴム状重合体との混合物およびこ
れらのゴム状重合体の存在下にアクリロニトリルと上記
コモノマーをグラフト重合させたものも用い得る。In addition, high nitrile resins include butadiene-acrylonitrile copolymer, isoprene-acrylonitrile copolymer, butadiene-styrene copolymer, polybutadiene,
Mixtures with rubbery polymers such as polyisoprey, and graft polymerization of acrylonitrile and the above comonomers in the presence of these rubbery polymers may also be used.
本発明の容器の形状は特に制限がなく、内容物に応じ、
大きさ、取り扱い易さ、ファツション性などを考慮し形
成されたものであればどんな形状のものでも良い。また
表面にシール、印刷などが施されているものであっても
良い。The shape of the container of the present invention is not particularly limited, and depending on the contents,
Any shape may be used as long as it is formed with consideration to size, ease of handling, fashionability, etc. Further, the surface may have a sticker, printing, etc. applied thereto.
実施例１
ブタジェン−アクリロニトリルゴム状共重合体（フリジ
エン７０重量％） １０重量部の存在下に、アクリロ
ニトリル７５重量部とアクリル酸メチル２５重量部から
なる混合物を重合させて得た高ニトリル樹脂（アクリロ
ニトリル分約７５重量％、窒素分析による）を用い、射
出成形により内容積５０１ｎ！、平均肉厚５００μｍの
容器を得た。Example 1 A high nitrile resin (acrylonitrile) obtained by polymerizing a mixture consisting of 75 parts by weight of acrylonitrile and 25 parts by weight of methyl acrylate in the presence of 10 parts by weight of butadiene-acrylonitrile rubbery copolymer (70 parts by weight of freediene). (approx. 75% by weight, based on nitrogen analysis), and the internal volume is 501n by injection molding! A container having an average wall thickness of 500 μm was obtained.
この容器中にリモネン０．１２を溶かしたイソプロパツ
ール溶液３０ｆｎｌを入れ、密封して室温で暗所で１ケ
月間保存した。その後開封してリモネンイソプロパツー
ル溶液中のリモネン量をガスクロマトグラフィで分析し
たところ、約９５％が残存していることがわかった。30 fnl of an isopropanol solution containing 0.12% of limonene was placed in this container, the container was sealed, and the container was stored at room temperature in a dark place for one month. Thereafter, when the package was opened and the amount of limonene in the limonene isopropanol solution was analyzed by gas chromatography, it was found that about 95% remained.
実施例２
樹脂として、ブタジェン−アクリロニトリルゴム状共重
合体（ブタジェン８０重量％）１０重量部の存在下に、
アクリロニトリル７０重量部、メタクリル酸メチル２５
重量部とスチレン５重量部からなる混合物を重合させて
得た高ニトリル樹脂（アクリロニトリル分約６５重量％
、窒素分析による）を用いるほかは実施例１を繰返した
。Example 2 In the presence of 10 parts by weight of butadiene-acrylonitrile rubbery copolymer (80% by weight of butadiene) as a resin,
70 parts by weight of acrylonitrile, 25 parts by weight of methyl methacrylate
High nitrile resin (acrylonitrile content: about 65% by weight) obtained by polymerizing a mixture consisting of 5 parts by weight and 5 parts by weight of styrene.
, by nitrogen analysis) was repeated.
１ケ月の保存後のリモネンイソプロパツール溶液中のリ
モネン残存量は約９３％であった。The residual amount of limonene in the limonene isopropanol solution after storage for one month was about 93%.
比較例１
樹脂としてポリプロピレンを用いる他は’１ｕｌＪ１を
繰返した。Comparative Example 1 '1ulJ1 was repeated except that polypropylene was used as the resin.
１ケ月の保存後のリモネンイソプロパツール溶液中のリ
モネン残存量は約４５％と悪かった。The residual amount of limonene in the limonene isopropanol solution after one month of storage was poor at about 45%.
比較例２
樹脂として硬質塩化ビニル樹脂を用いるほかは実施例１
を繰返した。Comparative Example 2 Example 1 except that hard vinyl chloride resin is used as the resin
repeated.
１ケ月の保存後のリモネンイソプロパツール溶液中のリ
モネン残存量は約１５％と悪かった。The residual amount of limonene in the limonene isopropanol solution after one month of storage was poor at about 15%.
（発明の効果）
本発明では高アクリロニトリル樹脂を使用しているので
従来のプラスチックでは不可能とされていたリモネンを
主要成分とする香料の保香効果が著しく良好となり、リ
モネンを含有するものに対し、従来の金属製又はガラス
製の容器に替え、軽量で取り扱いが更に便利となり、特
に著しく保香性の良い容器を提供することが可能となる
。(Effects of the invention) Since the present invention uses a high acrylonitrile resin, the fragrance retention effect of fragrances containing limonene as a main component, which was considered impossible with conventional plastics, is significantly improved, and compared to those containing limonene. In place of conventional metal or glass containers, it is possible to provide a container that is lighter in weight, more convenient to handle, and has particularly excellent fragrance retention.
Claims (1)
て、該容器が高ニトリル樹脂からなることを特徴とする
香料用容器。 ２、高ニトリル樹脂が多量のアクリロニトリルと該アク
リロニトリルと共重合性を有する単量体成分を共役ジエ
ン系合成ゴムの存在下で重合させて製造したものである
特許請求の範囲第一項記載のリモネンを主要原料とする
香料用容器。[Scope of Claims] 1. A container for a fragrance containing a fragrance containing limonene as a main component, characterized in that the container is made of a high nitrile resin. 2. Limonene according to claim 1, wherein the high nitrile resin is produced by polymerizing a large amount of acrylonitrile and a monomer component copolymerizable with the acrylonitrile in the presence of a conjugated diene synthetic rubber. Containers for fragrances whose main ingredients are
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61046321A JPS62204704A (en) | 1986-03-05 | 1986-03-05 | Perfume container |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61046321A JPS62204704A (en) | 1986-03-05 | 1986-03-05 | Perfume container |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62204704A true JPS62204704A (en) | 1987-09-09 |
Family
ID=12743897
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61046321A Pending JPS62204704A (en) | 1986-03-05 | 1986-03-05 | Perfume container |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62204704A (en) |
-
1986
- 1986-03-05 JP JP61046321A patent/JPS62204704A/en active Pending
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