JPS62201980A - Water based ink composition for writing utensil - Google Patents
Water based ink composition for writing utensilInfo
- Publication number
- JPS62201980A JPS62201980A JP61042973A JP4297386A JPS62201980A JP S62201980 A JPS62201980 A JP S62201980A JP 61042973 A JP61042973 A JP 61042973A JP 4297386 A JP4297386 A JP 4297386A JP S62201980 A JPS62201980 A JP S62201980A
- Authority
- JP
- Japan
- Prior art keywords
- based ink
- water
- water based
- parts
- lubricant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 239000000203 mixture Substances 0.000 title claims abstract description 6
- 239000000049 pigment Substances 0.000 claims abstract description 10
- 239000000314 lubricant Substances 0.000 claims abstract description 9
- 239000011734 sodium Substances 0.000 claims abstract description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 3
- -1 amine salt Chemical group 0.000 claims abstract description 3
- 239000003086 colorant Substances 0.000 claims abstract description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052700 potassium Inorganic materials 0.000 claims abstract 2
- 239000011591 potassium Chemical group 0.000 claims abstract 2
- 229910052708 sodium Inorganic materials 0.000 claims abstract 2
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 abstract description 6
- 239000002184 metal Substances 0.000 abstract description 6
- 239000000126 substance Substances 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- 238000005096 rolling process Methods 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 31
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 12
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 238000005119 centrifugation Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical compound [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- IZUPBVBPLAPZRR-UHFFFAOYSA-N pentachlorophenol Chemical compound OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IZUPBVBPLAPZRR-UHFFFAOYSA-N 0.000 description 2
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- YTSHQZGXQLQMFD-UHFFFAOYSA-N 2-aminoethanol;styrene Chemical compound NCCO.C=CC1=CC=CC=C1 YTSHQZGXQLQMFD-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 1
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical class NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 239000013556 antirust agent Substances 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- NBISUMCCBFKFEY-UHFFFAOYSA-N azane;styrene Chemical compound N.C=CC1=CC=CC=C1 NBISUMCCBFKFEY-UHFFFAOYSA-N 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 239000003984 copper intrauterine device Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- MOFOBJHOKRNACT-UHFFFAOYSA-N nickel silver Chemical compound [Ni].[Ag] MOFOBJHOKRNACT-UHFFFAOYSA-N 0.000 description 1
- 239000010956 nickel silver Substances 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- FDRCDNZGSXJAFP-UHFFFAOYSA-M sodium chloroacetate Chemical compound [Na+].[O-]C(=O)CCl FDRCDNZGSXJAFP-UHFFFAOYSA-M 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- RPOHBMAQTOJHKM-UHFFFAOYSA-M sodium;2-chloropropanoate Chemical compound [Na+].CC(Cl)C([O-])=O RPOHBMAQTOJHKM-UHFFFAOYSA-M 0.000 description 1
- WFITUPFQQAGOBI-UHFFFAOYSA-M sodium;carbonochloridate Chemical compound [Na+].[O-]C(Cl)=O WFITUPFQQAGOBI-UHFFFAOYSA-M 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- XOSXWYQMOYSSKB-LDKJGXKFSA-L water blue Chemical compound CC1=CC(/C(\C(C=C2)=CC=C2NC(C=C2)=CC=C2S([O-])(=O)=O)=C(\C=C2)/C=C/C\2=N\C(C=C2)=CC=C2S([O-])(=O)=O)=CC(S(O)(=O)=O)=C1N.[Na+].[Na+] XOSXWYQMOYSSKB-LDKJGXKFSA-L 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は着色剤として顔料を少なくとも用いた筆記具用
水性インキに関し、更に詳しくはチップ部が金属である
ボールペンに最適な性能。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a water-based ink for writing instruments that uses at least a pigment as a coloring agent, and more specifically, to a water-based ink for writing instruments that has optimal performance for a ballpoint pen whose tip portion is metal.
例えばボールの回転によるボール受座の掌性の少ない筆
記具用水性インキに関するものである。For example, the present invention relates to a water-based ink for writing instruments in which the ball seat is less sensitive to ball rotation due to the rotation of the ball.
（従来の技術及びその問題点）
従来の金属チップを使用した筆記具としては顔料および
水性媒体からなる水性インキを使用した水性金属ボール
ペンがあるが、水性媒体のために金属チップの超硬ボー
ルとボール受座の潤滑がスムースでなく、筆記中にボー
ル受座が摩耗して、多くの文字が書けなくなる欠截を有
していた。この欠点を改善せんとして
■潤滑剤として活性剤の添加 ■インキ中のグリコール
類を増量して粘度をアップするなどの対策があるが、（
１）活性剤の添加は水性インキの表面張力を低下せしむ
る為に筆跡かにじむ。（２）グリコール類の増量による
インキの粘度の増加は速４１：きに不利な傾向を示すと
いうように何れも問題点を有していた。(Prior art and its problems) Conventional writing instruments using metal tips include water-based metal ballpoint pens that use water-based ink consisting of pigments and water-based media, but because of the water-based medium, carbide balls and balls with metal tips The lubrication of the catch was not smooth, and the ball catch wore out during writing, making it impossible to write many letters. In order to improve this drawback, there are measures such as ■ Adding an activator as a lubricant ■ Increasing the amount of glycols in the ink to increase the viscosity.
1) The addition of an activator lowers the surface tension of the water-based ink, causing handwriting to smear. (2) An increase in the viscosity of the ink due to an increase in the amount of glycols has a disadvantageous tendency in both cases.
（問題点を解決する為の手段〕
本発明者らは、上述せる問題点を解決すべく鋭意研究し
た結果本発明を完成したものであって１本発明は、音色
剤として顔料を少なくとも使用した水性インキにおいて
、下記一般式で示される潤滑剤を含有してなることを特
徴とする筆記具用水性インキ組成物ｆｒ：０旨とするも
のである。(Means for Solving the Problems) The present inventors have completed the present invention as a result of intensive research to solve the above-mentioned problems. A water-based ink composition for writing instruments fr:0 is characterized in that the water-based ink contains a lubricant represented by the following general formula.
一般式
％式％
本発明に使用する音色剤の顔料は一般に公知の有機顔料
、無機顔料が使用できその使用量は水性インキ中３〜２
０重量％が望ましい。尚。General formula % Formula % As the pigment of the tone agent used in the present invention, generally known organic pigments and inorganic pigments can be used, and the amount used is 3 to 2 in the water-based ink.
0% by weight is desirable. still.
染料を併用することもできる。A dye can also be used in combination.
水性媒体としては、エチレングリコール、グリセリンな
どの多価アルコヘール、エチｌ／ングリコールモノメチ
ルエーテルなどの七Ｏソルヴ。Examples of aqueous media include polyhydric alcohols such as ethylene glycol and glycerin, and 7O solves such as ethyl/nglycol monomethyl ether.
ジエチレングリコールモノメチルエーテルなどのカービ
トール、ホルムアミドなどの１ジアミドの単独または混
合して使用される。これらの水性媒体の使用量は水性イ
ンキ中５〜４０重量％が望ましい。Carbitol such as diethylene glycol monomethyl ether and diamide such as formamide are used alone or in combination. The amount of these aqueous media used is preferably 5 to 40% by weight in the aqueous ink.
本発明の骨子である潤滑剤はボールとボール受座の摩耗
を防止するものであって１次のようにして合成される。The lubricant, which is the essence of the present invention, is intended to prevent wear between the ball and the ball seat, and is synthesized in the following manner.
１） Ｒ＝０１２Ｈ２５，ｍ＝＝ ０． ｎ ＝ １
、 Ｍ＝Ｎａの場合
ラウリルアルコールに金属ナトリウムか水酸化ナトリウ
ムを反応させてアルコラードを作る。次にエタノール中
モノクロル叶酸ナトリウムと縮合してＣｌ２Ｈ２５０Ｃ
Ｈ２ＣＯＯＮａを得る。1) R=012H25, m== 0. n = 1
, When M=Na, alcolade is produced by reacting lauryl alcohol with metallic sodium or sodium hydroxide. Next, it is condensed with sodium monochloroformate in ethanol to form Cl2H250C.
Obtain H2COONa.
２ン 几 ”Ｃｌ８Ｈ３７１ｍ＝ ２ 、
ｎ ＝ １ 、 Ｍ＝Ｎａ の場合
ステアリルアルコールにエチレンオキサイド２モルを縮
合させ１次にモノクロル酢酸ナトリウムと反応させて
ＣＩ ８Ｈ５ｙ （ＯＣＲ２０Ｈ２） ２ ・０ＯＨ２
ＣＯＯＮａを得る。2"Cl8H371m=2,
When n = 1, M = Na, stearyl alcohol is condensed with 2 moles of ethylene oxide and then reacted with sodium monochloroacetate to form CI 8H5y (OCR20H2) 2 .0OH2
Obtain COONa.
３） ａ＝＝ｃ６Ｈ１、、ｍ＝ ４＋
ｎ ＝２＋ Ｍ＝ＮＨａ の場合
ヘキサノールにエチレンオキサイドを４モル反応させ１
次にモノクロルプロピオンｍｔ絹合しアンモニア水で中
オロして
Ｃ６Ｈ１５（ＯＣＨ２ＣＨ２） ４・０ＣＨ２ＣＨ２Ｃ
ＯＯＮＨ４を得る。3) a==c6H1,,m=4+
When n = 2+ M = NHa, react 4 moles of ethylene oxide with hexanol and 1
Next, combine monochloropropion mt silk and rinse with aqueous ammonia to obtain C6H15(OCH2CH2) 4・0CH2CH2C
Obtain OONH4.
４） Ｒ＝Ｃ１４１（２９，ｍ＝ Ｏ，ｎ ＝ ２．
Ｍ＝Ｎａの場合
テトラテカノールのアルコラードにモノクロルプロピオ
ン酸ナトリウムを縮合し。4) R=C141(29, m=O, n=2.
When M=Na, sodium monochloropropionate is condensed with alcoholade of tetratecanol.
Ｃ＋ ４Ｈ２９００Ｈ２ｃＨ２ｃＯＯＮａを得る。C+ 4H2900H2cH2cOONa is obtained.
本発明の（閏滑剤の１吏用量は水性インキ中０．０５〜
１０重量％が望ましい。The lubricant of the present invention is used in a water-based ink in a dosage of 0.05~
10% by weight is desirable.
音色剤を水性インキにする分散剤としては。As a dispersant for making tonal agents into water-based inks.
界面活性剤ならアニオン系、ノニオン系、カチオン系な
どが水溶性樹脂ならスチレン−アクリル酸共重合物、ス
チレン−マレイン酸共重合物。For surfactants, use anionic, nonionic, and cationic types, and for water-soluble resins, use styrene-acrylic acid copolymer and styrene-maleic acid copolymer.
アクリル酸エステル−アクリル酸共重合物の単独または
混合物が水性インキ中１．０〜１５重量％使用できる。The acrylic ester-acrylic acid copolymer alone or as a mixture can be used in an amount of 1.0 to 15% by weight in the aqueous ink.
その他必要に応じて防カビ剤、防錆剤などが使用できる
。Other antifungal agents, antirust agents, etc. can be used as necessary.
筆記具用水性インキの製造は、顔料インキの一般的な製
造法であるボールミル、ロール・ミル、サンド・ミル、
アトライターなどにより容易に作ることが出来る。Water-based ink for writing instruments is manufactured using ball mills, roll mills, sand mills, and other general manufacturing methods for pigment inks.
It can be easily made using an attritor or the like.
（作用）
本発明における潤滑剤は、水性インキの表面張力を下げ
ず、且つ１弱いアニオン性の為水性媒体と相溶性がよく
水性インキを増粘しないという特性を有しているので、
筆跡かにじんだり。(Function) The lubricant in the present invention does not lower the surface tension of the water-based ink, and is weakly anionic, so it has good compatibility with the water-based medium and does not thicken the water-based ink.
Handwriting smears.
連番性に不利であるといっだ問題点を発生しないと考え
られる。It is thought that no problem will arise if the serial numbering is disadvantageous.
（実施例） 本発明を実施例に従って具体的に説明する。(Example) The present invention will be specifically explained according to examples.
実施例中１一部コとあるのは「重１部」を表わすものと
する。In the examples, "1 part" means "1 part heavy".
実施例１
カーボン・ブラック（ファーネス
タイプ） １０部スチレン−
アクリル酸共重合体の
モノエタノールアミン塩（モル
比２：１） １０部Ｃｌ２Ｈ２ｓ
ＯＣＨ２ＣＯＯＮａ ０．５部エチレ
ングリコール ２０部水
５９．
５ 部上記成分を小形のボットミルに入れ１１００時間
分散埃、遠心分離処理により粗大なカーボン粒子を除去
することにより、＃Ｊ４科分Ｚ５重量％の筆記具用黒色
水性インキを得た。Example 1 Carbon black (furnace type) 10 parts styrene
Monoethanolamine salt of acrylic acid copolymer (molar ratio 2:1) 10 parts Cl2H2s
OCH2COONa 0.5 parts Ethylene glycol 20 parts Water
59.
5 parts of the above ingredients were placed in a small bot mill and dispersed for 1100 hours, followed by centrifugation to remove coarse carbon particles, thereby obtaining a black aqueous ink for writing instruments containing #J4 family Z5% by weight.
比較例１
実施例１に使用したＣ １２Ｈ２５０ＣＨ２ＣＯＯＮａ
の代りに、同ｉｔのノニルフェノールのエチレンオキサ
イド２０モル付加物を使用シフ、同（子：・こして筆記
具用黒色水性インキを得た。Comparative Example 1 C 12H250CH2COONa used in Example 1
Instead, a 20 mol ethylene oxide adduct of the same nonylphenol was used, and a black aqueous ink for writing instruments was obtained.
実施例２
ポリ塩素化鋼フタロシアニン １２部スチレン−
マレイン酸共重合体の
アンモニウム塩（モル比５：１，１ ８部０１８Ｈ５
ｙ （ＯＣＲ２０Ｈ２）２− ＱＣ！Ｈ２Ｃ０ＯＮａ
５部プロピレングリコール １
５部水
６０部上記成分を小形のサンド・グラインタ
ーに入れ、６時間分散径遠心処理により粗大なポリ塩素
化銅７タロソアニンの粒子を除去することにより、顔料
分９０重量％の筆記具用緑色水性インキを得た。Example 2 Polychlorinated steel phthalocyanine 12 parts styrene
Ammonium salt of maleic acid copolymer (molar ratio 5:1,1 8 parts 018H5
y (OCR20H2)2- QC! H2C0ONa
5 parts propylene glycol 1
5 parts water
60 parts The above ingredients were placed in a small sand grinder and coarse polychlorinated copper 7 talosoanine particles were removed by centrifugation for 6 hours to obtain a green water-based ink for writing instruments with a pigment content of 90% by weight. Ta.
比較例２
実施例２に使用した
Ｃｌ８Ｈ３ｙ （ＯＣＨ２ＣＨ２） ２−０ＣＨ２ＣＯ
ＯＮａ の代りに同量のプロピレングリコールを使用
し、同様にして筆記具用緑色水性インキを得た。Comparative Example 2 Cl8H3y (OCH2CH2) 2-0CH2CO used in Example 2
A green water-based ink for writing instruments was obtained in the same manner using the same amount of propylene glycol instead of ONa.
実施例６
キナクリドン・レッド １５部スチレン
−アクリル酸共重合体の
モノメチルアミン塩（モル比４
・１） １０部
Ｃ６Ｈｓ−ＣＯＣＨ２ＣＨ２）４・０ＣＨ２ＣＨ２ＣＯ
ＯＮＨ４２部エチレングリコール １０
部ベンゾトリアゾール ０．５部ペンタ
クロルフェノール ｏ、 ｉ ｇ水
６２
．４ 部上記成分をロール分散し遠心分離処理により粗
大なキナクリドン・レッドの粒子を除去することにより
顔料分１０．０ｆｉｆｉ％の筆記具用水性インキを得た
。Example 6 Quinacridone Red 15 parts Monomethylamine salt of styrene-acrylic acid copolymer (molar ratio 4.1) 10 parts C6Hs-COCH2CH2)4.0CH2CH2CO
ONH42 parts ethylene glycol 10
Part benzotriazole 0.5 part Pentachlorophenol o, i g Water
62
．． 4 parts A water-based ink for writing instruments having a pigment content of 10.0 fifi% was obtained by roll-dispersing the above components and removing coarse quinacridone red particles by centrifugation.
比１ｆｆｌクリ３
実施例３に使用した
０６Ｈ５（ＯＣＨ２ＣＨ２）４・０ＣＨ２ＣＩ−１２Ｃ
ＯＯＮＨ４の代りに同着の水を使用し、同様にして、車
記具用赤色水性インキを得た。Ratio 1ffl 3 06H5(OCH2CH2)4・0CH2CI-12C used in Example 3
A red water-based ink for car markings was obtained in the same manner using the same water instead of OONH4.
実施例４
銅フタロシアニン １２部ウォーター
ブルー＃ ９ （Ｃ，１，Ａｃ１ｄＢＩｕｅ９ 、オリ
エント化学工業■
製） ４部スチレン−マ
レイン酸共重合体の
ナトリウム塩（モル比２１） ８部グリセリン
５部エチレングリコール
５部０１ａＨ２９０ｃＨ２０Ｈ２Ｎａ
３部水
６５ 部上記成分を小形の
サンドグラインダーに入れ、４時間分散後、遠心分離処
理により粗大な銅フタロシアニンの粒子を除去すること
により顔料分ａ９重量％の筆記具用Ｗ色水性インキを得
た。Example 4 Copper phthalocyanine 12 parts Water Blue #9 (C,1,Ac1dBIue9, manufactured by Orient Kagaku Kogyo ■) 4 parts Sodium salt of styrene-maleic acid copolymer (molar ratio 21) 8 parts Glycerin
5 parts ethylene glycol
5 parts 01aH290cH20H2Na
3 parts water
65 parts of the above components were placed in a small sand grinder, and after being dispersed for 4 hours, coarse copper phthalocyanine particles were removed by centrifugation to obtain a W color aqueous ink for writing instruments with a pigment content of 9% by weight.
比較例年
実施例４に使用したＣ ＋ ４Ｎ（２９０Ｃ１−Ｉ２Ｃ
１−１２ｃＯＯＮａの代９に同量のソルビタウラウレー
トを１吏用し、同様に１．て筆記共用青色水性インキを
得た。Comparative Example: C + 4N (290C1-I2C) used in Example 4.
The same amount of sorbitau laurate was added to 1-12 cOONa, and 1. A blue water-based ink for common writing was obtained.
（発明の効果ン
実施例１〜４および比較例１〜４にて得られた容色筆記
具用水性インキを、金属チップを有する水性ボールペン
に充填し試験した結果を表−１に示す。(Effects of the Invention) The water-based inks for color-containing writing instruments obtained in Examples 1 to 4 and Comparative Examples 1 to 4 were filled into a water-based ballpoint pen with a metal tip and tested. Table 1 shows the results.
表−１（口＝５の平均）
（庄 ）
※１試作した筆記具用水性インキを０．５ （Ｂ ｍ超
硬ボールを有する洋白チップの筆記具に充填し、ＪＩＳ
Ｐ５２０１の用紙に荷重１００ｇ。Table-1 (Average of mouth = 5) (Sho) *1 The prototype water-based ink for writing instruments was filled into a writing instrument with a nickel silver tip with a 0.5 (Bm carbide ball) and the JIS
Load 100g on P5201 paper.
筆記角度７０°、速ｆｌＪ−７ｃＩｎ／ ｓｅｅの条件
で輝線筆記し１，２００ｍｍのそのボール沈みを測定し
てチップ摩耗の目安とする。A bright line was written under the conditions of a writing angle of 70° and a speed of flJ-7cIn/see, and the ball sinking of 1,200 mm was measured and used as a measure of chip wear.
※２筆記具用水性インキを充填した筆記具にてＪＩ８Ｐ
３２０１の用紙に３０３ ／ ｓｅｅの条件で直線を１
０本書き、筆跡の状＠（カスレなど）を目視評価する。*2 JI8P with a writing instrument filled with water-based ink
Draw a straight line on 3201 paper under the condition of 303/see.
Visually evaluate the condition of the handwriting (stains, etc.).
※３筆記具用水性インキを充填した筆記具にてＪＩ８Ｐ
３２０１の用紙に直線を書き、筆記直後と籠記後２０秒
後の筆記線の巾を比較して評価する。*3 JI8P with a writing instrument filled with water-based ink for writing instruments
A straight line is drawn on a sheet of paper No. 3201, and the width of the written line is compared immediately after the writing and 20 seconds after the basket is written for evaluation.
※４ １，２００ｍ螺線筆輝線、その筆記線の状態を目
視判定する。*4 Visually judge the condition of the 1,200m spiral bright line and the written line.
以上の如く本発明による水性インキ組成物はボール沈み
がなく、更に速書き性に優れ、又筆跡のにじみが生じな
いという優れた効果を有するものである。As described above, the water-based ink composition according to the present invention has excellent effects such as no ball sinking, excellent speed writing properties, and no bleeding of handwriting.
Claims (1)
いて、下記一般式で示される潤滑剤を含有してなること
を特徴とする筆記具用水性インキ組成物。 一般式 Ｒ−（ＯＣＨ＿２ＣＨ＿２）＿ｍ・Ｏ（ＣＨ＿２）＿ｎ
・ＣＯＯＭ （Ｒは炭素数５〜２０のアルキル基 ｍは０か１〜１０の整数 ｎは１または２ Ｍはナトリウム、カリウム、アンモニウムアミン塩を表
わす。）[Scope of Claims] A water-based ink composition for writing instruments, characterized in that the water-based ink uses at least a pigment as a coloring agent and contains a lubricant represented by the following general formula. General formula R-(OCH_2CH_2)_m・O(CH_2)_n
・COOM (R is an alkyl group having 5 to 20 carbon atoms m is 0 or an integer from 1 to 10 n is 1 or 2 M represents sodium, potassium, or ammonium amine salt.)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61042973A JPS62201980A (en) | 1986-02-28 | 1986-02-28 | Water based ink composition for writing utensil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61042973A JPS62201980A (en) | 1986-02-28 | 1986-02-28 | Water based ink composition for writing utensil |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62201980A true JPS62201980A (en) | 1987-09-05 |
Family
ID=12650980
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61042973A Pending JPS62201980A (en) | 1986-02-28 | 1986-02-28 | Water based ink composition for writing utensil |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62201980A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2017507173A (en) * | 2014-01-30 | 2017-03-16 | カオウ ケミカルズ ゲーエムベーハーＫａｏ Ｃｈｅｍｉｃａｌｓ Ｇｍｂｈ | Ionic liquid |
-
1986
- 1986-02-28 JP JP61042973A patent/JPS62201980A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2017507173A (en) * | 2014-01-30 | 2017-03-16 | カオウ ケミカルズ ゲーエムベーハーＫａｏ Ｃｈｅｍｉｃａｌｓ Ｇｍｂｈ | Ionic liquid |
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