JPS62200658A - Cell with leading substance - Google Patents

Cell with leading substance

Info

Publication number
JPS62200658A
JPS62200658A JP61042753A JP4275386A JPS62200658A JP S62200658 A JPS62200658 A JP S62200658A JP 61042753 A JP61042753 A JP 61042753A JP 4275386 A JP4275386 A JP 4275386A JP S62200658 A JPS62200658 A JP S62200658A
Authority
JP
Japan
Prior art keywords
battery
positive
negative electrode
insulating
gasket
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP61042753A
Other languages
Japanese (ja)
Inventor
Naoyuki Sugano
直之 菅野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sony Corp
Original Assignee
Sony Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sony Corp filed Critical Sony Corp
Priority to JP61042753A priority Critical patent/JPS62200658A/en
Publication of JPS62200658A publication Critical patent/JPS62200658A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/102Primary casings; Jackets or wrappings characterised by their shape or physical structure
    • H01M50/109Primary casings; Jackets or wrappings characterised by their shape or physical structure of button or coin shape
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/528Fixed electrical connections, i.e. not intended for disconnection
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Connection Of Batteries Or Terminals (AREA)

Abstract

PURPOSE:To improve the sealing property between positive and negative electrodes to enhance the reliability, and make it possible to save labor and simplify the process of the manufacture, by furnishing a coating layer of insulating paint at the all periphery of the positive and negative electrodes unified through a gasket. CONSTITUTION:To a positive electrode can 1 filled with a positive electrode function substance 3, a negative electrode can 2 filled with a negative electrode function substance 5 is overlapped through a separator 4 containing an electrolyte, the openings are enclosed through a gasket 6, and leading substances 7 and 8 are installed to the cans 1 and 2 to be the leading terminals. Moreover, all around the cans 1 and 2, including the gasket 6, a coating layer 9 of an insulating paint is composed continuously. Therefore, the enclosure property between the positive and the negative electrode is improved to enhance reliability, and a labor saving and simplification of the manufacture are realized because the process of the insulator is no more than a painting, drying and hardening.

Description

【発明の詳細な説明】 に関するものであり、特に正極と負極にリード体を設け
たリード体付電池に関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a battery with a lead body, in which a positive electrode and a negative electrode are provided with lead bodies.

〔発明の概要〕[Summary of the invention]

本発明は、正極あるいは負極に外部端子となるリード体
を設けたリード体付電池において、正極と負極にまたが
り全周にわたって絶縁塗料の塗布層を形成することによ
り、電池の信頼性の向上、価格の削減、製造工程の簡略
化を図ろうとするものである0 〔従来の技術〕 を維持し長期保存性にすぐれていること、また環境変化
に対しても優れた耐漏液特性を示すこと等から、長期信
頼性が必要条件であるメモリーバックアップ用電源とし
て広く用いられるようになっている。そして、これら電
池の用途の多様化に伴なって、例えば正極及び負極に外
部端子となるリード体を設けたリード体付電池が供給さ
れている。
The present invention improves the reliability of the battery and reduces the cost by forming a coating layer of insulating paint over the entire circumference of the positive and negative electrodes in a battery equipped with a lead that serves as an external terminal on the positive or negative electrode. 0 [Conventional technology] It is aimed at reducing the amount of water and simplifying the manufacturing process. It has become widely used as a memory backup power supply where long-term reliability is a prerequisite. With the diversification of the uses of these batteries, for example, batteries with lead bodies are being supplied in which the positive electrode and the negative electrode are provided with lead bodies serving as external terminals.

このリード体付電池では、電子機器等への直接半田付等
も可能となる。
This lead-equipped battery can also be directly soldered to electronic devices and the like.

ところで、このようにリード体付電池はバックアップ用
電源としてすぐれた特性を有しているが、リード体が両
極に付いているため、電池の運搬の際など特に、他の電
池と接触したり、それ自身の対極と接触してしまう可能
性が大きく、事故が起こりやすい。そのため電池の全周
囲にわたって、正極と負極を包み込むような形で絶縁材
を密着させて事故を防止する必要がある。
By the way, batteries with lead bodies have excellent characteristics as a backup power source, but since the lead bodies are attached to both poles, they may come into contact with other batteries, especially when transporting the battery. There is a high possibility that it will come into contact with its own opposite pole, and accidents are likely to occur. Therefore, to prevent accidents, it is necessary to apply insulating material tightly around the entire circumference of the battery, enveloping the positive and negative electrodes.

従来、上記絶縁材としては、塩化ビニルのような絶縁性
の被覆チューブを用いていた。しかし、被覆チューブ材
を用いた場合には、電池の製造工程、例えば電池への被
覆チューブ材の巻き付け、溶着、加熱収縮等の工程が必
要となり、加工費用が電池の価格に対して大きな比重を
占めてしまい好ましくない。さらに被覆チューブを用い
て絶縁をする際、チューブ材を薄膜化しようとすると、
特に電池の角部等において破れを生ずる等、所定の絶縁
特性を確保することが難かしくなり、さらに保護用薄膜
等を使用する必要性が生じる。また、電気機器の小型、
軽量化が進んでいるため、ボタン型電池の小瓢薄型化が
要望されているが、そうした小型、薄型化された電池の
絶縁材としてチューブ材を適用した場合、現在使用され
ている自動被覆機器では対応できず、小型、薄型電池専
用の自動被覆機器が必要となる。このように絶縁材とし
てチューブ材を用いた場合、工程が複雑になる上、加工
費が非常に高くなり電池価格に対して大きな比重を占め
てしまう。
Conventionally, an insulating coated tube such as vinyl chloride has been used as the above-mentioned insulating material. However, when coated tube material is used, battery manufacturing processes such as winding, welding, and heat shrinkage of the coated tube material around the battery are required, and the processing cost is high relative to the price of the battery. I don't like it because it takes up too much space. Furthermore, when trying to make the tube material thinner when insulating using coated tubes,
Particularly, breakage occurs at the corners of the battery, making it difficult to ensure desired insulation properties, and furthermore, it becomes necessary to use a protective thin film or the like. In addition, small electrical equipment,
Due to the progress in weight reduction, there is a demand for smaller and thinner button-type batteries.If tube material is used as the insulation material for such small and thinner batteries, the automatic covering equipment currently used However, automatic coating equipment specifically designed for small, thin batteries is required. When a tube material is used as an insulating material in this way, the process becomes complicated and the processing cost becomes extremely high, which accounts for a large percentage of the battery price.

〔発明が解決しようとする問題点〕 このように従来のリード体付電池では、絶縁性を得るた
めに、電池周囲に被覆チューブを密着させていたが、被
覆工程が複雑であり、特に電池の小型、薄型化に対応す
るためには新たな設備投資が必要となり、電池の価格に
対して加工費が大きな比重を占めてしまっていた。
[Problems to be solved by the invention] As described above, in conventional lead-equipped batteries, a covering tube is tightly attached around the battery in order to obtain insulation, but the covering process is complicated, and the In order to respond to smaller and thinner batteries, new capital investment was required, and processing costs accounted for a large proportion of the battery price.

そこで本発明は、このような従来のものの有する問題点
を解決するために提案されたものであり、不用意な短絡
等に対して充分な絶縁特性をもつ信頼性の高いリード体
付電池を提供することを目的とし、さらに生産性に優れ
たリード体付電池を提供することを目的としている。
Therefore, the present invention was proposed in order to solve the problems of the conventional products, and provides a highly reliable lead-equipped battery with sufficient insulation properties against accidental short circuits, etc. The purpose of this invention is to provide a lead-equipped battery with excellent productivity.

〔問題を解決するための手段〕[Means to solve the problem]

本発明は、上述の目的を達成するために、正極と負極が
ガスケットを介して一体化され、上記正極と負極にまた
がって全周にわたって絶縁塗料の塗布層を有し、上記正
極及び負極にそれぞれリード体を設けたことを特徴とす
るものであるQ本発明が適用されるリード体付電池は、
例えば第1図に示すように正極作用物質3を充填した正
極缶1に、電解液を含有するセパレータ4を介して負極
作用物質5を充填した負極缶2を重ね合わせ、開口部を
ガスケット6を介して密封して構成されるものである。
In order to achieve the above-mentioned object, the present invention integrates a positive electrode and a negative electrode through a gasket, has a coating layer of insulating paint over the entire circumference of the positive electrode and the negative electrode, and has a coating layer of an insulating paint on the positive electrode and the negative electrode, respectively. Q A battery with a lead body to which the present invention is applied is characterized by being provided with a lead body.
For example, as shown in FIG. 1, a positive electrode can 1 filled with a positive electrode active substance 3 is stacked with a negative electrode can 2 filled with a negative electrode active substance 5 via a separator 4 containing an electrolyte, and the opening is closed with a gasket 6. It is configured to be sealed tightly through the

上記正極缶1及び負極缶2には、それぞれ外部へのリー
ド端子となるリード体7,8が溶着等の手法により取り
付けられている0 そして本発明では、上記正極缶1と負極缶2の局面に、
上記ガスケット6部も含んで連続的に絶縁塗料の塗布層
9を形成し、上記リード体1,8の不用意な接触による
短絡等を防止するようになっている。
Lead bodies 7 and 8, which serve as lead terminals to the outside, are attached to the positive electrode can 1 and the negative electrode can 2, respectively, by a method such as welding. To,
A coating layer 9 of an insulating paint is continuously formed on the gasket 6 to prevent short circuits caused by careless contact between the leads 1 and 8.

上記塗布層9形成に用いられる絶縁塗料は、合成樹脂の
如き樹脂成分を主体とするもので、必要に応じて着色剤
、増粘剤等を添加してもよい。また、主体となる樹脂成
分としては、金属密着性に優れ、絶縁性の高いものが好
ましく、ポリウレタン樹脂やアクリル圏脂、エポキシ樹
脂等が好適である0 上記絶縁塗料の塗布方法としては、通常の手法が使用で
き、例えばハケ塗法、スプレー法、ロール塗法、静電式
塗布法等によればよい。
The insulating paint used to form the coating layer 9 is mainly composed of a resin component such as a synthetic resin, and a colorant, a thickener, etc. may be added as necessary. In addition, the main resin component is preferably one that has excellent metal adhesion and high insulation properties, and polyurethane resin, acrylic resin, epoxy resin, etc. For example, brush coating, spraying, roll coating, electrostatic coating, etc. may be used.

〔作 用〕[For production]

以上のように、本発明のリード体付電池では、絶縁材を
絶縁塗料の塗布層としているので、この絶縁塗料が液体
状であることから塗布面積、塗布厚さなどが任意に調整
でき、様々の形状を有する電池に対応できる。さらに絶
縁塗料の金属密着性がすぐれているためガスケットシー
ル部の形状にも対応でき、正極と負極間の密封性能が向
上し、電池の信頼性も向上する。また、絶縁材の加工工
程が、塗布、乾燥硬化工程だけでよく、装置の簡略化、
省力化が図れる。
As described above, in the battery with lead body of the present invention, the insulating material is a coating layer of insulating paint, and since this insulating paint is in liquid form, the coating area, coating thickness, etc. can be adjusted arbitrarily, and various Compatible with batteries having the following shapes. Furthermore, the excellent metal adhesion of the insulating paint allows it to be adapted to the shape of the gasket seal, improving the sealing performance between the positive and negative electrodes and improving battery reliability. In addition, the insulating material processing process only requires coating, drying and curing, which simplifies the equipment and
Labor saving can be achieved.

〔実施例〕〔Example〕

以下、本発明をより具体的な実施例により説明する。な
お、本発明が以下の実施例に限定されるものではないこ
とは言うまでもない。
The present invention will be explained below using more specific examples. It goes without saying that the present invention is not limited to the following examples.

実施例1 光硬化型アクリル樹脂に着色剤及び増粘剤を添加した絶
縁塗料を用い、この塗料を試験体電池(コイン型リチウ
ム電池CR,2430)側面全周(ガスケットシール部
も含む。)に回転ロール法により0.111jlの均一
な厚さで塗布し、続いて塗布面に紫外線ランプ(スペク
トロニクス社製、B100型、紫外線強度7rrLW/
CrA)で光を5分間照射し、塗料を硬化させた0塗膜
は鉛筆強度で4Hであった0 次に、この試験体にリード体用タグをスポット溶接で溶
着した。このようにして出来上がった試験体電池を実施
例1とした。
Example 1 Using an insulating paint made by adding a colorant and a thickener to a photocurable acrylic resin, this paint was applied to the entire side surface (including the gasket seal part) of a test battery (coin-type lithium battery CR, 2430). The coating was applied to a uniform thickness of 0.111jl using a rotating roll method, and then the coated surface was heated with an ultraviolet lamp (manufactured by Spectronics, model B100, ultraviolet intensity 7rrLW/
CrA) was irradiated with light for 5 minutes to cure the paint, and the paint film had a pencil strength of 4H.Next, a lead body tag was welded to this test piece by spot welding. The test battery thus produced was designated as Example 1.

実施例2 リード体用タブをスポット溶接で溶着した試験体電池の
全面に実施例1で用いた絶縁塗料を0.1隨の均一な厚
さで塗布し、続いて紫外線ランプを用い紫外線強度7m
W/cniで光を5分間照射し塗料を硬化させた。塗膜
は、鉛筆強度で4Hであった。この試験体電池を実施例
2とした。
Example 2 The insulating paint used in Example 1 was applied to a uniform thickness of 0.1 mm over the entire surface of a test battery with lead tabs welded by spot welding, and then an ultraviolet light intensity of 7 m was applied using an ultraviolet lamp.
The paint was cured by irradiating it with light using W/cni for 5 minutes. The coating film had a pencil strength of 4H. This test battery was designated as Example 2.

実施例3 絶縁塗料として、アクリル変性ウレタン樹脂に着色剤及
び増粘剤を添加したものを用いた。この塗料を試験体電
池側面全周及びガスケットシール部も同時に0.111
jlの均一な厚さで塗布し、続いて紫外線ランプを照射
し、先の実施例1と同じ条件で塗布膜を硬化させた。塗
膜の鉛筆硬度は2Hであった。次にこの試験体にリード
用タブをスポット溶接で溶着した。この試験体電池を実
施例3とした。
Example 3 As an insulating paint, an acrylic modified urethane resin to which a colorant and a thickener were added was used. This paint was applied to the entire circumference of the test battery side and the gasket seal part at the same time.
The coating film was coated to a uniform thickness of Jl, and then irradiated with an ultraviolet lamp to cure the coating film under the same conditions as in Example 1 above. The pencil hardness of the coating film was 2H. Next, a lead tab was welded to this test piece by spot welding. This test battery was designated as Example 3.

実施例4 絶縁塗料としてエポキシ樹脂に硬化剤、着色剤及び増加
剤を添加したものを使用した。この絶縁塗料を試験体電
池側面全周及びガスケットシール部も同時に0.1Uの
均一な厚さで塗布し、続いて100℃恒温槽中で5分間
乾燥、硬化させた。塗膜の鉛筆硬度は3Hであった。次
にこの試験体にリード体用タグをスポット溶接で溶着し
た。この試験体電池を実施例4とした。
Example 4 An epoxy resin containing a curing agent, a coloring agent, and an increasing agent was used as an insulating coating. This insulating paint was simultaneously applied to the entire circumference of the side surface of the test cell and the gasket seal portion to a uniform thickness of 0.1 U, and then dried and cured for 5 minutes in a 100° C. constant temperature bath. The pencil hardness of the coating film was 3H. Next, a lead body tag was welded to this test piece by spot welding. This test battery was designated as Example 4.

実施例5 実施例1において絶縁塗料の塗膜厚を0.036とし、
他は実施例1と同様の方法で試験体電池を炸裂した。こ
れを実施例5とした。
Example 5 In Example 1, the coating thickness of the insulating paint was set to 0.036,
Otherwise, the test battery was exploded in the same manner as in Example 1. This was designated as Example 5.

比較例1 従来、絶縁材として使用されている塩化ビニル製の0.
1u厚の絶縁チューブを用い、これを試験体電池の側面
全周に被覆させたものを比較例1とした0 上述の実施例1〜実施例5及び比較例1の各サンプル電
池について、絶縁膜の絶縁性能を試験するために、塗膜
面の絶縁抵抗を測定し、塗膜面と対極における電圧を測
定した。さらに負極側タブを正極端子の塗膜面へ接地し
、保存中(1力月、3力月、6力月)の電圧を測定した
Comparative Example 1 A 0.000V made of vinyl chloride, which has been conventionally used as an insulating material.
Comparative Example 1 was obtained by using an insulating tube with a thickness of 1 μ and covering the entire side surface of the test battery. In order to test the insulation performance of the electrode, the insulation resistance of the coating surface was measured, and the voltage between the coating surface and the opposite electrode was measured. Furthermore, the negative electrode side tab was grounded to the coating surface of the positive electrode terminal, and the voltage during storage (1 month, 3 months, and 6 months) was measured.

この結果を第1表に示す。The results are shown in Table 1.

(以下金1:l) この表より、各実施例においては、いずれの絶縁塗料を
用いても非常にすぐれた絶縁効果を示していることがわ
かる。また、実施例1及び実施例。
(Hereinafter, gold is 1:1) From this table, it can be seen that in each of the examples, an extremely excellent insulating effect is exhibited no matter which insulating paint is used. Also, Example 1 and Examples.

5では、絶縁塗料の塗膜厚さを0.1諺と0.0311
13について比較したものであるが、まったく同じ結果
を示し、塗膜が薄くても絶縁性能は充分であることを示
している。さらに、各実施例は絶縁チューブを用いた比
較例と比べてもまったく同様な結果を示し、絶縁チュー
ブの代りに絶縁塗料を用いても充分実用性があることを
示している。
5, the coating thickness of the insulating paint is 0.1 and 0.0311.
No. 13 was compared and showed exactly the same results, indicating that the insulation performance is sufficient even if the coating film is thin. Furthermore, each of the examples showed exactly the same results as the comparative example using an insulating tube, indicating that it is sufficiently practical to use an insulating paint instead of an insulating tube.

〔発明の効果〕〔Effect of the invention〕

上述の説明からも明らかなように絶縁塗料は、従来絶縁
材として用いられてきた絶縁チューブξ比べ同等もしく
はそれ以上の絶縁性能を有している。また、絶縁塗料は
、液体状であるため塗布面の形状に制約を受けず、小型
(小径、薄型)電池の絶縁材として有効であり、塗膜厚
を任意に調整でき、非常に薄膜化することもできる。
As is clear from the above description, the insulating paint has an insulating performance equal to or better than that of the insulating tube ξ, which has been conventionally used as an insulating material. In addition, since insulating paint is in liquid form, it is not limited by the shape of the surface it is applied to, making it effective as an insulating material for small (small diameter, thin) batteries.The thickness of the coating film can be adjusted arbitrarily, making it extremely thin. You can also do that.

また、本発明に用いた絶縁塗料は、金属に対する塗膜の
密着性が優れているため、ガスヶ、/l−シール部の密
封性が向上し、電池の信頼性も向上する。さらに、液体
状であるため、取扱いが容易であり製造工程の省力化、
簡略化が図れ作業性を向上することができる。
Further, since the insulating paint used in the present invention has excellent adhesion of the coating film to metal, the sealing performance of the gas cover and /l- sealing portion is improved, and the reliability of the battery is also improved. Furthermore, since it is in liquid form, it is easy to handle and saves labor in the manufacturing process.
Simplification can be achieved and work efficiency can be improved.

したがって、本発明のリード体付電池は、優れた絶縁性
、密封性、保存性を有し信頼性の高いものとなるととも
に、生産性の点でも実用的Iii値は極めて高いと言え
る。
Therefore, it can be said that the battery with lead body of the present invention has excellent insulation properties, sealing properties, and storage stability, and is highly reliable, and also has an extremely high practical Iiii value in terms of productivity.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は、本発明を適用したリード体付電池の例を示す
一部破断側面図である。
FIG. 1 is a partially cutaway side view showing an example of a battery with a lead body to which the present invention is applied.

Claims (1)

【特許請求の範囲】[Claims] 正極と負極がガスケットを介して一体化され、上記正極
と負極にまたがって全周にわたって絶縁塗料の塗布層を
有し、上記正極及び負極にそれぞれリード体を設けたこ
とを特徴とするリード体付電池。
With a lead body, the positive electrode and the negative electrode are integrated through a gasket, the positive electrode and the negative electrode have a coated layer of insulating paint over the entire circumference, and a lead body is provided on each of the positive electrode and the negative electrode. battery.
JP61042753A 1986-02-27 1986-02-27 Cell with leading substance Pending JPS62200658A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP61042753A JPS62200658A (en) 1986-02-27 1986-02-27 Cell with leading substance

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61042753A JPS62200658A (en) 1986-02-27 1986-02-27 Cell with leading substance

Publications (1)

Publication Number Publication Date
JPS62200658A true JPS62200658A (en) 1987-09-04

Family

ID=12644759

Family Applications (1)

Application Number Title Priority Date Filing Date
JP61042753A Pending JPS62200658A (en) 1986-02-27 1986-02-27 Cell with leading substance

Country Status (1)

Country Link
JP (1) JPS62200658A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2230704A1 (en) * 2007-04-13 2010-09-22 VARTA Microbattery GmbH Button cell with coated outer surface

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2230704A1 (en) * 2007-04-13 2010-09-22 VARTA Microbattery GmbH Button cell with coated outer surface

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