JPS62199762A - Production of multicolored dial for timepiece - Google Patents
Production of multicolored dial for timepieceInfo
- Publication number
- JPS62199762A JPS62199762A JP4266886A JP4266886A JPS62199762A JP S62199762 A JPS62199762 A JP S62199762A JP 4266886 A JP4266886 A JP 4266886A JP 4266886 A JP4266886 A JP 4266886A JP S62199762 A JPS62199762 A JP S62199762A
- Authority
- JP
- Japan
- Prior art keywords
- dial
- timepiece
- multicolored
- coating
- nitriding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- 239000000463 material Substances 0.000 claims abstract description 17
- 239000002184 metal Substances 0.000 claims abstract description 9
- 229910052751 metal Inorganic materials 0.000 claims abstract description 9
- 238000000576 coating method Methods 0.000 claims abstract description 8
- 238000005121 nitriding Methods 0.000 claims abstract description 8
- 239000011248 coating agent Substances 0.000 claims abstract description 7
- 239000002131 composite material Substances 0.000 claims abstract description 5
- 238000005530 etching Methods 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims description 13
- 150000002739 metals Chemical class 0.000 claims description 6
- 229910001361 White metal Inorganic materials 0.000 claims description 4
- 239000010969 white metal Substances 0.000 claims description 4
- 238000004040 coloring Methods 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 2
- 238000009792 diffusion process Methods 0.000 abstract description 4
- 238000007747 plating Methods 0.000 description 8
- 238000005260 corrosion Methods 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 238000013461 design Methods 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 235000019646 color tone Nutrition 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229910000960 colored gold Inorganic materials 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 235000019640 taste Nutrition 0.000 description 1
Abstract
Description
【発明の詳細な説明】 （産業上の利用分野） 本発明は、時計用外装部品の文字板に関する。[Detailed description of the invention] (Industrial application field) The present invention relates to a dial plate of an exterior part for a timepiece.
（発明の概要）
時計用文字板として具備しなければならない耐食性、耐
変色性および密着性の品質面を大巾に改良しながら、精
密加工に適した機械加工条件ならびにメッキ処理に代わ
る代替方法を見い出し、価格も安価ならしめることに成
功した新規の時計用多色文字板およびその製造に関する
ものである。(Summary of the invention) The present invention provides machining conditions suitable for precision machining and an alternative method to plating, while significantly improving the quality aspects of corrosion resistance, discoloration resistance, and adhesion that must be provided for a watch dial. The present invention relates to a new multicolored dial for watches that has been successfully made inexpensive and its manufacture.
、（従来の技術）
従来、時計用文字板は、主に銅合金材料が用いられ、所
望の部品形状に加工後、ニッケル（以下Ｈ１）、銀（以
下Ａｏ）、金（以下Ａｕ）メッキを単層あるいは複層に
して、耐食性・高級化を得ていた。(Prior art) Traditionally, watch dials are mainly made of copper alloy materials, which are processed into the desired shape and then plated with nickel (hereinafter referred to as H1), silver (hereinafter referred to as Ao), and gold (hereinafter referred to as Au). It was made into a single layer or multiple layers to achieve corrosion resistance and high quality.
又、ＡＱメッキにおいては、耐食性が劣るため、メッキ
処理後のクリアーラッカーの塗布が必要である。Furthermore, since AQ plating has poor corrosion resistance, it is necessary to apply a clear lacquer after the plating process.
（発明が邂決しようとする問題点）
メッキ処理は複雑な工程と高価格な装置を必要とすると
同時に密着性や錆を発生しゃずいという欠点を有してい
ること。又、Ａｕ、 ＡＱを用いるため原料費も非常に
高価格であり、原料費削減のため、局部的メッキを行な
うにしても工程、装置とも現在の技術では、さらに１ｉ
雑で高価格になるという欠点を有していること。ざらに
Ａｇメッキにおいては、耐食性が非常に劣るため、メッ
キ処理後クリアーラッカー塗布の必要が有り経済性が悪
いという多くの欠点を有している。(Problems to be Solved by the Invention) Plating requires complicated processes and expensive equipment, and at the same time has drawbacks such as poor adhesion and the possibility of rust. In addition, since Au and AQ are used, the raw material costs are very high, and even if local plating is performed to reduce raw material costs, the current technology for both process and equipment requires an additional 1i.
It has the disadvantage of being complicated and expensive. Generally speaking, Ag plating has many drawbacks such as very poor corrosion resistance and the need to apply clear lacquer after plating, which is not economical.
（問題点を解決するための手段）
多色化でデザインに新規性を与えかつ従来以上の品質を
確保するとともに製造価格を安価にするために、被加工
材（母材）表面に異種金属を被覆しエツチング法により
異種金属を部分的に除去したのち、窒化処理法（熱処理
）により、母材の着色ならびに異種金属間の拡散による
密着性の改善かできること、母材Ｔｉと白色金属の冷面
圧延が可能でありしかも被覆白色金属の厚みが高精度に
コントロールができることを見い出し、本発明を完成さ
せたものである。(Means to solve the problem) In order to add novelty to the design through multi-coloring, ensure higher quality than before, and reduce manufacturing costs, dissimilar metals are applied to the surface of the workpiece (base material). After partially removing dissimilar metals by coating and etching, nitriding (heat treatment) can be used to color the base material and improve adhesion by diffusion between the dissimilar metals. The present invention was completed by discovering that rolling is possible and that the thickness of the coated white metal can be controlled with high precision.
（作用）
デザインの多様化、消費者の嗜好から求められている現
在、多色化でアサインに新規性を持たせ、しかも従来以
上の品質を確保ができ、安価にすることができる。又、
母材Ｔｉの材料強度が高いため薄型化・高級化への対応
ができる。(Function) Nowadays, designs are diversifying and consumers' tastes are demanding it, and by using multiple colors, it is possible to add novelty to assignments, ensure higher quality than before, and make it cheaper. or,
Because the base material Ti has high material strength, it can be made thinner and more sophisticated.
（実施例）
第１図は本発明に用いた被加工材（母材）と異種金属の
被覆工程の一例である。(Example) FIG. 1 is an example of a process of coating a workpiece (base material) and different metals used in the present invention.
ＡのＴｉを１の洗浄槽で洗浄後、２の酸化皮膜除去を行
なった後、ＡのＴｉの表面にＢのＮｉ箔を供給し３のロ
ールで冷間接着を行ない、４の炉体で拡散加熱を行ない
、Ｔｉの表面に連続的にＮｉを被覆し、Ｃの複合材を作
製した。After cleaning the Ti in A in the cleaning tank 1 and removing the oxide film in 2, the Ni foil in B was supplied to the surface of the Ti in A and cold bonded with the rolls in 3, and then in the furnace body in 4. Diffusion heating was performed to continuously coat the surface of Ti with Ni to produce a composite material of C.
次に複合材を所望の部品形状になる様に、プレス加工・
エツチング加工・窒化処理を行ない試料を作製した。第
２図はプレス上り、第３図はエツチング上りの試料断面
図である。Next, press the composite material into the desired part shape.
A sample was prepared by etching and nitriding. FIG. 2 is a cross-sectional view of the sample after pressing, and FIG. 3 is a cross-sectional view of the sample after etching.
次に窒化処理（着色処理）を次の条件で行った。Next, nitriding treatment (coloring treatment) was performed under the following conditions.
処理条件
温度 ９００℃±５℃
保持時間 ３時間
雰囲気 高純度Ｎ２ガス
この処理においてＡのＴｉ材は金色に着色、ＢのＮｉは
変化しない。Processing conditions Temperature: 900°C±5°C Holding time: 3 hours Atmosphere: High-purity N2 gas In this process, the Ti material A is colored gold, and the Ni material B is unchanged.
第−表は本発明の試料と従来用いられている時計用文字
板との耐食性試験の結果を示すものである。なお本発明
品との比較に用いた試料は従来がら行なわれている方法
にて作製した。Table 1 shows the results of corrosion resistance tests on samples of the present invention and conventional watch dials. Note that the sample used for comparison with the product of the present invention was prepared by a conventional method.
又、耐食性試験結果の判定は、時計用文字板として要求
されている耐湿潤試験、耐硫化試験、耐光性試験を行な
い総合的に判断したものである。In addition, the results of the corrosion resistance test are determined comprehensively by conducting a moisture resistance test, a sulfur resistance test, and a light resistance test, which are required for watch dials.
第 −表 ◎優れている。 Ｏ良好。 ×劣る。Chapter - Table ◎Excellent. O good condition. ×Inferior.
本発明品は従来のもの以上の良好の結果が得られた。The product of the present invention gave better results than the conventional product.
なお、上記の実施例は本発明の一部をなすもので、Ｔｉ
の窒化処理は処理温度を９００〜１２００℃、処理時間
を１〜１２時間の範囲で種々変えることにより金色〜黄
土色の色調が得られることや、母材Ｔ１と白色金属の巾
、方向、厚み等を種々組合せることにより第４図に示す
様なバラエティ−に富んだデザインが可能でかつ非常に
新規性の高い時計用文字板が提供できる。Note that the above embodiment forms part of the present invention, and Ti
In the nitriding treatment, a golden to ocher color tone can be obtained by varying the treatment temperature in the range of 900 to 1200°C and treatment time in the range of 1 to 12 hours, and the width, direction, and thickness of the base material T1 and the white metal can be changed. By various combinations of the above, it is possible to create a wide variety of designs as shown in FIG. 4, and to provide highly novel watch dials.
（発明の効果）
本発明方法で作製した時計用多色文字板は母材と被覆部
が異なる色調を有し、装飾化しており、しかも植字の役
目も有りデザイン的にも良いものが得られる
又、高価格でかつ品質の不安定なメッキ処理に代わり、
所望の部分の白色金属の形成ならびに窒化処理により母
材の着色とともに密着性も高められ品質的に安定で量産
性に優れた経済的に安価でしかも軽量・薄型化に対応で
きる時計用多色文字板およびその製造方法が供給できる
。(Effects of the Invention) The multicolored dial for a watch produced by the method of the present invention has different color tones in the base material and the covering part, is decorative, and also has the role of typesetting, resulting in a good design. In addition, instead of plating which is expensive and has unstable quality,
Formation of white metal in desired areas and nitriding process color the base material and improve adhesion.Multi-color letters for watches are stable in quality, excellent in mass production, economically inexpensive, and can be made lighter and thinner. Boards and methods of manufacturing the same can be provided.
【図面の簡単な説明】
第１図は実施例被覆工程、第２図は実施例プレス加ニレ
イアウド図、第３図は時計部品の断面図、第４図（ａ）
、（ｂ）、（Ｃ）は他の実施例である多色文字板の平面
図である。
Δ・・・母材、 Ｂ・・・反覆金属、 Ｃ・・・複
合材、１・・・洗浄、 ２・・・酸化被膜除去、３・
・・接着圧延、４・・・拡散熱処理５・・・時計部品、
Ｄ・・・カレンダー窓。
第４図[Brief explanation of the drawings] Figure 1 is an example coating process, Figure 2 is an example press layout diagram, Figure 3 is a sectional view of a watch part, Figure 4 (a)
, (b) and (C) are plan views of multicolor dial plates according to other embodiments. Δ... Base material, B... Repeated metal, C... Composite material, 1... Cleaning, 2... Oxide film removal, 3...
... Adhesive rolling, 4... Diffusion heat treatment 5... Watch parts,
D...Calendar window. Figure 4
Claims (2)
を被覆した複合材を、所望の部品形状に加工したあと、
被覆金属をエッチング法により部分的に除去したのち、
窒化処理法により一種以上の金属を着色することにより
、二種以上の多色模様を有することを特徴とする時計用
多色文字板の製造方法。(1) After processing a composite material in which the Ti material surface is coated with one or more different metals into the desired part shape,
After partially removing the coating metal using an etching method,
A method for manufacturing a multicolored dial for a timepiece, characterized in that it has two or more multicolored patterns by coloring one or more metals using a nitriding process.
とを特徴とする特許請求の範囲第（１）項記載の時計用
多色文字板の製造方法。(2) The method for manufacturing a multicolor dial for a timepiece as set forth in claim (1), wherein the covering material contains one type of white metal such as Ni.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4266886A JPS62199762A (en) | 1986-02-27 | 1986-02-27 | Production of multicolored dial for timepiece |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4266886A JPS62199762A (en) | 1986-02-27 | 1986-02-27 | Production of multicolored dial for timepiece |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62199762A true JPS62199762A (en) | 1987-09-03 |
Family
ID=12642400
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4266886A Pending JPS62199762A (en) | 1986-02-27 | 1986-02-27 | Production of multicolored dial for timepiece |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62199762A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010126792A (en) * | 2008-11-28 | 2010-06-10 | Toyota Central R&D Labs Inc | Method for producing corrosion resistant conductive material |
-
1986
- 1986-02-27 JP JP4266886A patent/JPS62199762A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010126792A (en) * | 2008-11-28 | 2010-06-10 | Toyota Central R&D Labs Inc | Method for producing corrosion resistant conductive material |
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