JPS62194439A - Method for extracting additive - Google Patents
Method for extracting additiveInfo
- Publication number
- JPS62194439A JPS62194439A JP3620986A JP3620986A JPS62194439A JP S62194439 A JPS62194439 A JP S62194439A JP 3620986 A JP3620986 A JP 3620986A JP 3620986 A JP3620986 A JP 3620986A JP S62194439 A JPS62194439 A JP S62194439A
- Authority
- JP
- Japan
- Prior art keywords
- solvent
- specimen
- additive
- flask
- weighed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000654 additive Substances 0.000 title claims abstract description 16
- 230000000996 additive effect Effects 0.000 title claims abstract description 10
- 238000000034 method Methods 0.000 title claims description 5
- 239000002904 solvent Substances 0.000 claims abstract description 14
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000011347 resin Substances 0.000 claims abstract description 7
- 229920005989 resin Polymers 0.000 claims abstract description 7
- 239000004033 plastic Substances 0.000 claims description 4
- 229920003023 plastic Polymers 0.000 claims description 4
- 239000011148 porous material Substances 0.000 claims description 2
- -1 polytetrafluoroethylene Polymers 0.000 claims 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims 1
- 239000004810 polytetrafluoroethylene Substances 0.000 claims 1
- 238000004445 quantitative analysis Methods 0.000 claims 1
- 238000000605 extraction Methods 0.000 abstract description 12
- 238000001035 drying Methods 0.000 abstract description 2
- 238000000638 solvent extraction Methods 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 206010051602 Laziness Diseases 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
Landscapes
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
- Sampling And Sample Adjustment (AREA)
- Extraction Or Liquid Replacement (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、ゴム・プラスチック等の添加物の溶剤抽出方
法に関するものである。DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to a method for solvent extraction of additives for rubber, plastics, etc.
（従来の技術）
ゴム製品に関する溶剤抽出はＪＩＳに定められており、
これに準じてプラスチック等も行っている。(Prior art) Solvent extraction for rubber products is stipulated by JIS.
We also do plastics and other products in accordance with this.
試料２ｇを７ｍｇまで正しく秤量し、あらかじめ溶剤で
抽出した分析化学用口紙に包むか、第２図のように円筒
口紙１に入れ、抽出器１０のサイフオンカップ２中に置
き、あらかじめ恒量になったフラスコ３に溶剤を入れ、
抽出装置を組み立ててフラスコを加熱すると、溶剤の蒸
気が右側の管を通って上昇し、原管冷却器４で冷やされ
、液化して試料の上に落ちる。溶剤は試料中の添加物を
溶出し、左側の管に入り、十分たまるとサイフオンの原
理により流出し、下のフラスコ３に落ちる。これを繰り
返す。このようにして抽出が終った後、抽出液を水浴上
で加熱し溶剤を留出した後、フラスコを７０００ｉ：ｊ
ＯＣの空気洛中で恒量になるまで乾燥を繰り返す。そし
て抽出後と抽出前のフラスコ重量の差を添加物の量とし
ている。Weigh 2g of the sample correctly to 7mg, wrap it in a cap for analytical chemistry that has been extracted with a solvent in advance, or put it in a cylindrical cap 1 as shown in Figure 2, place it in the siphon cup 2 of the extractor 10, and make it to a constant weight in advance. Pour the solvent into flask 3,
When the extraction apparatus is assembled and the flask is heated, the solvent vapor rises through the right tube, is cooled in the raw tube cooler 4, liquefies and falls onto the sample. The solvent elutes the additives in the sample, enters the left tube, and when it accumulates enough, it flows out according to the siphon principle and falls into flask 3 below. Repeat this. After the extraction is completed in this way, the extract is heated on a water bath to distill off the solvent, and the flask is heated to 7000 i:j.
Repeat drying in OC air until constant weight is reached. The difference in flask weight after extraction and before extraction is taken as the amount of additive.
（発明が解決しようとする問題点）
上述の従来の溶剤抽出方法は、恒量にしたフラスコ重量
の前後の差を添加物量としている。この添加物量は通常
１０％前後であり、試料２ｇの場合０２ｇ程となる。一
方フラスコの重量が！；０−１．０ｇで恒量といっても
数ｍｇのバラツキがあるため、分析精度にも影響があっ
た。(Problems to be Solved by the Invention) In the above-mentioned conventional solvent extraction method, the amount of additive is determined by the difference between the flask weights before and after the constant weight. The amount of this additive is usually around 10%, and in the case of 2 g of sample, it is about 0.2 g. On the other hand, the weight of the flask! ; Even though the weight is constant at 0-1.0 g, there is a variation of several mg, which also affected the accuracy of analysis.
また、少量の試料を対象にする場合は精度的な問題が大
きくなる。Furthermore, when a small amount of sample is used, accuracy becomes a major problem.
以上のような問題点を本発明は解決しようとするもので
ある。The present invention is intended to solve the above-mentioned problems.
（問題点を解決するための手段）
従来、試料をあらかじめ溶剤抽出した分析化学用口紙に
包むか、円筒口紙に入れていたのを、第１図のように、
あらかじめｍｇの単位まで秤量された四弗化エチレン樹
脂フィルムを袋状にしたもの１１にθ／ｇ程の試料を入
れて秤量し、これを抽出器のサイフオンカップ２の中に
入れ、一方抽出フラスコ３には溶剤を入れ抽出装置を組
立てる。(Means for solving the problem) Conventionally, the sample was wrapped in a solvent-extracted wrapper for analytical chemistry or placed in a cylindrical wrapper, as shown in Figure 1.
A sample of about θ/g is placed in a bag 11 of a tetrafluoroethylene resin film weighed in advance to the unit of mg, weighed, and placed in the siphon cup 2 of the extractor, and extracted on the other hand. Fill flask 3 with solvent and assemble the extraction device.
（作用）
少量の試料で分析ができ、／装置で多試料の抽出ができ
る。(Function) A small amount of sample can be analyzed, and the device can extract multiple samples.
（実施例）
あらかじめｍｇの単位まで秤量された四弗化エチレン樹
脂フィルムからなる袋状のものにａ／ｇ程の試料を入れ
秤量する。これを抽出装置のサイフオンカップ中に入れ
、装置を組み立てて湯浴上で加熱しながら抽出を行う。(Example) A sample of approximately a/g is placed in a bag-shaped bag made of a tetrafluoroethylene resin film that has been weighed in advance to the unit of mg, and then weighed. Place this in the siphon cup of the extraction device, assemble the device, and perform extraction while heating it on a hot water bath.
抽出を終った後、サイフオンカップ中の試料を取り出し
、風乾した後、７０°ｃ＋ｔ０ｃの空気洛中で乾燥し秤
量する。After the extraction is completed, the sample in the siphon cup is taken out and air-dried, then dried in an air chamber at 70°C+t0c and weighed.
抽出前後の差が溶剤抽出された添加量である。The difference before and after extraction is the amount of solvent extracted.
なお、四弗化エチレン多孔質フィルムの孔径は、１０．
１１より小さいと小さ過ぎ１００ 、ｔｌを越えると大
きすぎる。Note that the pore diameter of the tetrafluoroethylene porous film is 10.
If it is smaller than 11, it is too small, and if it exceeds tl, it is too large.
（発明の効果）
以上説明したように口紙から四弗化エチレン樹脂フィル
ムで作成した袋状のものを用いることにしたので
（１） 少量の試料で分析が可能になった。(Effects of the Invention) As explained above, since it was decided to use a bag-shaped bag made of tetrafluoroethylene resin film from the opening paper, (1) analysis became possible with a small amount of sample.
（２）分析精度が従来に比べ向上した。(2) Analysis accuracy has improved compared to conventional methods.
従来 ＣＶ値 ５〜７％
拳法 ＣＶ値 ３〜ｊ％
（３）／試料／／装置が多試料／／装置と分析能力が向
上した。Conventional CV value: 5-7% Kenpo CV value: 3-j% (3) / Samples // The device has a large number of samples // The device and analytical ability have improved.
（４１フラスコの恒量が不要となり分析時間が短縮でき
た。(41 It was not necessary to constantly weigh the flasks, and the analysis time could be shortened.
等の効果がでた。The effect was as follows.
第１図は本発明の添加物の抽出方法の説明図。
第２図は従来技術による添加物の抽出方法の説明図であ
る。
１・・・円筒口紙、２・・・サイフオンカップ、３・・
・フラスコ、４・・・原管冷却器、１１・・・四弗化エ
チレン樹脂フィルムを袋状にしたもの。
千１図
カシ怠FIG. 1 is an explanatory diagram of the additive extraction method of the present invention. FIG. 2 is an explanatory diagram of a conventional method for extracting additives. 1... Cylindrical opening paper, 2... Saifon cup, 3...
- Flask, 4... Raw tube cooler, 11... Bag-shaped tetrafluoroethylene resin film. 1,100 figures of oak laziness
Claims (1)
において、四弗化エチレン樹脂多孔質フィルムの袋にゴ
ム・プラスチックの試料を入れて、その試料中の添加物
を溶剤で抽出することを特徴とする添加物の抽出方法。 ２、四弗化エチレン多孔質フィルムは孔径１０〜１００
μｍであることを特徴とする特許請求の範囲第１項記載
の添加物の抽出方法。[Claims] 1. In quantitative analysis of additives contained in rubber, plastic, etc., a rubber/plastic sample is placed in a bag made of polytetrafluoroethylene resin porous film, and the additives in the sample are removed using a solvent. A method for extracting additives, which is characterized by extracting with. 2. Tetrafluoroethylene porous film has a pore size of 10 to 100
The method for extracting an additive according to claim 1, wherein the additive is .mu.m.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3620986A JPS62194439A (en) | 1986-02-20 | 1986-02-20 | Method for extracting additive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3620986A JPS62194439A (en) | 1986-02-20 | 1986-02-20 | Method for extracting additive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62194439A true JPS62194439A (en) | 1987-08-26 |
Family
ID=12463358
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3620986A Pending JPS62194439A (en) | 1986-02-20 | 1986-02-20 | Method for extracting additive |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62194439A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01107803A (en) * | 1987-10-22 | 1989-04-25 | Shonan Koryo Kk | Extractor for component of animal and plant |
| CN105582691A (en) * | 2014-10-24 | 2016-05-18 | 中国石油化工股份有限公司 | Extraction agent, application thereof, and method of measuring crosslinking degree of polymer |
| CN109045749A (en) * | 2018-09-25 | 2018-12-21 | 浙江农林大学 | The multiple organic extraction element of one kind and method |
-
1986
- 1986-02-20 JP JP3620986A patent/JPS62194439A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01107803A (en) * | 1987-10-22 | 1989-04-25 | Shonan Koryo Kk | Extractor for component of animal and plant |
| CN105582691A (en) * | 2014-10-24 | 2016-05-18 | 中国石油化工股份有限公司 | Extraction agent, application thereof, and method of measuring crosslinking degree of polymer |
| CN109045749A (en) * | 2018-09-25 | 2018-12-21 | 浙江农林大学 | The multiple organic extraction element of one kind and method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| So et al. | Kinetics of oil extraction from canola (rapeseed) | |
| US4199558A (en) | Tissue processing method | |
| Yu et al. | Phase equilibria of oleic acid, methyl oleate, and anhydrous milk fat in supercritical carbon dioxide | |
| JPS62194439A (en) | Method for extracting additive | |
| US3615651A (en) | Gelatinizing blood for feed | |
| US3669629A (en) | Apparatus for determining fat concentration in materials | |
| McDowell et al. | Phthalate esters in sediments near a sewage treatment plant outflow in Hamilton Harbour, Ontario: SFE extraction and environmental distribution | |
| AU2015100497A4 (en) | Sampling unit for concentrates preparation device | |
| US3170767A (en) | Apparatus for quantitative determination of fatty material and water in biological tissue | |
| CN208757004U (en) | A kind of grease separating and reclaiming device | |
| CN102759490A (en) | Measuring method for encapsulating agent in porous granular ammonium nitrate | |
| GB2057280A (en) | Lution in particular an extract and for storing the recovemethod and apparatus for the recovery of solvent from a sored solvent | |
| CN207081656U (en) | A kind of volatile matter prepares collection device | |
| DK366782A (en) | PROCEDURE FOR TIME-MARKING SEDIMENTATION PROCESSES AND DEVICE FOR EXERCISING THE PROCEDURE | |
| áO'Keeffe | Matrix solid phase dispersion linked to solid phase extraction for β-agonists in liver samples: an update | |
| CN113252496B (en) | Method for measuring content of binder in PBX explosive | |
| RU2034293C1 (en) | Method for determination of celluloid composition | |
| CN108444863A (en) | A kind of front and back test method to gas adsorption situation of coal extracting | |
| CN107790206A (en) | QuEChERS test tubes | |
| US2384230A (en) | Extraction thimble | |
| Ackman et al. | Determination of Isopropyl Alcohol in Fish Protein Concentrate by Solvent Extraction and Gas–Liquid Chromatography | |
| SU1104415A1 (en) | Device for determination of mercury content in powder samples | |
| Herty | Per Cent Tables for Oil in Cottonseed Products with Method of Analysis | |
| CN112630087A (en) | Method for determining fat in food | |
| JPH1099602A (en) | Automatic membrane separating device and automatic membrane separating method |