JPS62179465A - Deodorant for refrigerator and freezer - Google Patents
Deodorant for refrigerator and freezerInfo
- Publication number
- JPS62179465A JPS62179465A JP61020742A JP2074286A JPS62179465A JP S62179465 A JPS62179465 A JP S62179465A JP 61020742 A JP61020742 A JP 61020742A JP 2074286 A JP2074286 A JP 2074286A JP S62179465 A JPS62179465 A JP S62179465A
- Authority
- JP
- Japan
- Prior art keywords
- calcium chloride
- salts
- chloride salt
- water
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002781 deodorant agent Substances 0.000 title description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 104
- 239000000126 substance Substances 0.000 claims description 72
- 150000001875 compounds Chemical class 0.000 claims description 61
- 235000019645 odor Nutrition 0.000 claims description 58
- 229910001868 water Inorganic materials 0.000 claims description 50
- 150000003839 salts Chemical class 0.000 claims description 49
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 48
- 239000003795 chemical substances by application Substances 0.000 claims description 38
- 230000001877 deodorizing effect Effects 0.000 claims description 28
- 230000002378 acidificating effect Effects 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 14
- 230000007935 neutral effect Effects 0.000 claims description 11
- 239000003463 adsorbent Substances 0.000 claims description 8
- 239000000945 filler Substances 0.000 claims description 8
- 230000007062 hydrolysis Effects 0.000 claims description 6
- 238000006460 hydrolysis reaction Methods 0.000 claims description 6
- 239000011148 porous material Substances 0.000 claims description 4
- 230000000873 masking effect Effects 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 82
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 53
- 229910021529 ammonia Inorganic materials 0.000 description 39
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 22
- 239000007864 aqueous solution Substances 0.000 description 19
- -1 dihydrate salts Chemical class 0.000 description 19
- 235000013162 Cocos nucifera Nutrition 0.000 description 17
- 244000060011 Cocos nucifera Species 0.000 description 17
- 150000001412 amines Chemical class 0.000 description 17
- 239000002253 acid Substances 0.000 description 16
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 15
- 238000010521 absorption reaction Methods 0.000 description 13
- 238000002156 mixing Methods 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 12
- 239000000047 product Substances 0.000 description 12
- 239000011800 void material Substances 0.000 description 12
- 230000000694 effects Effects 0.000 description 10
- 239000011347 resin Substances 0.000 description 10
- 229920005989 resin Polymers 0.000 description 10
- 239000000463 material Substances 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 230000002939 deleterious effect Effects 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 238000006467 substitution reaction Methods 0.000 description 8
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 7
- 238000010670 acid alkali reaction Methods 0.000 description 7
- 239000003513 alkali Substances 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- 230000035699 permeability Effects 0.000 description 7
- 241000251468 Actinopterygii Species 0.000 description 6
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 150000001735 carboxylic acids Chemical class 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- 239000000835 fiber Substances 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 6
- 150000002739 metals Chemical class 0.000 description 6
- 241000894006 Bacteria Species 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 5
- 150000001298 alcohols Chemical class 0.000 description 5
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 5
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical class [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 5
- 239000003245 coal Substances 0.000 description 5
- 239000003814 drug Substances 0.000 description 5
- 229940079593 drug Drugs 0.000 description 5
- 229910002804 graphite Inorganic materials 0.000 description 5
- 239000010439 graphite Substances 0.000 description 5
- 229920003002 synthetic resin Polymers 0.000 description 5
- 239000000057 synthetic resin Substances 0.000 description 5
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 150000001450 anions Chemical class 0.000 description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 159000000007 calcium salts Chemical class 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 4
- 244000005700 microbiome Species 0.000 description 4
- 150000002823 nitrates Chemical class 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 239000000741 silica gel Substances 0.000 description 4
- 229910002027 silica gel Inorganic materials 0.000 description 4
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 4
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 4
- 238000009423 ventilation Methods 0.000 description 4
- 239000010457 zeolite Substances 0.000 description 4
- 229920001817 Agar Polymers 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 3
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 3
- 229910021536 Zeolite Inorganic materials 0.000 description 3
- 239000006096 absorbing agent Substances 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 description 3
- 239000004067 bulking agent Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 150000003841 chloride salts Chemical class 0.000 description 3
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
- 230000001747 exhibiting effect Effects 0.000 description 3
- 239000000417 fungicide Substances 0.000 description 3
- 239000013056 hazardous product Substances 0.000 description 3
- 150000004687 hexahydrates Chemical class 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 230000000737 periodic effect Effects 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Chemical group 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 231100000331 toxic Toxicity 0.000 description 3
- 230000002588 toxic effect Effects 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 239000001692 EU approved anti-caking agent Substances 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 229910021607 Silver chloride Inorganic materials 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- 239000008272 agar Substances 0.000 description 2
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- IWOUKMZUPDVPGQ-UHFFFAOYSA-N barium nitrate Chemical compound [Ba+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O IWOUKMZUPDVPGQ-UHFFFAOYSA-N 0.000 description 2
- 150000001642 boronic acid derivatives Chemical class 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Chemical group [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 150000001805 chlorine compounds Chemical group 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 2
- 239000000571 coke Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000004332 deodorization Methods 0.000 description 2
- 238000010494 dissociation reaction Methods 0.000 description 2
- 230000005593 dissociations Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000002360 explosive Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 239000000383 hazardous chemical Substances 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 239000012433 hydrogen halide Substances 0.000 description 2
- 229910000039 hydrogen halide Inorganic materials 0.000 description 2
- 239000003456 ion exchange resin Substances 0.000 description 2
- 229920003303 ion-exchange polymer Polymers 0.000 description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 2
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000005923 long-lasting effect Effects 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 230000009965 odorless effect Effects 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920005672 polyolefin resin Polymers 0.000 description 2
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 2
- 229910001961 silver nitrate Inorganic materials 0.000 description 2
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 239000004317 sodium nitrate Substances 0.000 description 2
- 235000010344 sodium nitrate Nutrition 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052979 sodium sulfide Inorganic materials 0.000 description 2
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- DHEQXMRUPNDRPG-UHFFFAOYSA-N strontium nitrate Chemical compound [Sr+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O DHEQXMRUPNDRPG-UHFFFAOYSA-N 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- 150000004685 tetrahydrates Chemical class 0.000 description 2
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 2
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 2
- 229910000368 zinc sulfate Inorganic materials 0.000 description 2
- 229960001763 zinc sulfate Drugs 0.000 description 2
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 1
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- WUPHOULIZUERAE-UHFFFAOYSA-N 3-(oxolan-2-yl)propanoic acid Chemical compound OC(=O)CCC1CCCO1 WUPHOULIZUERAE-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 239000005695 Ammonium acetate Substances 0.000 description 1
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 1
- AGVJBLHVMNHENQ-UHFFFAOYSA-N Calcium sulfide Chemical class [S-2].[Ca+2] AGVJBLHVMNHENQ-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- 229910021555 Chromium Chloride Inorganic materials 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- WBZRSFDJNJXREC-UHFFFAOYSA-N Cl[Cl]Cl Chemical compound Cl[Cl]Cl WBZRSFDJNJXREC-UHFFFAOYSA-N 0.000 description 1
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 1
- QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 1
- 239000002211 L-ascorbic acid Substances 0.000 description 1
- 235000000069 L-ascorbic acid Nutrition 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910021380 Manganese Chloride Inorganic materials 0.000 description 1
- GLFNIEUTAYBVOC-UHFFFAOYSA-L Manganese chloride Chemical compound Cl[Mn]Cl GLFNIEUTAYBVOC-UHFFFAOYSA-L 0.000 description 1
- 206010026864 Masochism Diseases 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 241000238413 Octopus Species 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 1
- 244000273256 Phragmites communis Species 0.000 description 1
- 235000014676 Phragmites communis Nutrition 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920005830 Polyurethane Foam Polymers 0.000 description 1
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 1
- 239000004111 Potassium silicate Substances 0.000 description 1
- 241000282806 Rhinoceros Species 0.000 description 1
- 241000282798 Rhinocerotidae Species 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- IDCBOTIENDVCBQ-UHFFFAOYSA-N TEPP Chemical compound CCOP(=O)(OCC)OP(=O)(OCC)OCC IDCBOTIENDVCBQ-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 229930003268 Vitamin C Natural products 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- MQRWBMAEBQOWAF-UHFFFAOYSA-N acetic acid;nickel Chemical compound [Ni].CC(O)=O.CC(O)=O MQRWBMAEBQOWAF-UHFFFAOYSA-N 0.000 description 1
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 1
- 150000008043 acidic salts Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- JLDSOYXADOWAKB-UHFFFAOYSA-N aluminium nitrate Chemical compound [Al+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O JLDSOYXADOWAKB-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 235000011126 aluminium potassium sulphate Nutrition 0.000 description 1
- 235000019257 ammonium acetate Nutrition 0.000 description 1
- 229940043376 ammonium acetate Drugs 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- 239000007798 antifreeze agent Substances 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000002956 ash Substances 0.000 description 1
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 1
- 229910001626 barium chloride Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 235000014121 butter Nutrition 0.000 description 1
- QCUOBSQYDGUHHT-UHFFFAOYSA-L cadmium sulfate Chemical compound [Cd+2].[O-]S([O-])(=O)=O QCUOBSQYDGUHHT-UHFFFAOYSA-L 0.000 description 1
- 229910000331 cadmium sulfate Inorganic materials 0.000 description 1
- 229910052980 cadmium sulfide Inorganic materials 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical class [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- 235000012255 calcium oxide Nutrition 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000003729 cation exchange resin Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 235000013351 cheese Nutrition 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- QSWDMMVNRMROPK-UHFFFAOYSA-K chromium(3+) trichloride Chemical compound [Cl-].[Cl-].[Cl-].[Cr+3] QSWDMMVNRMROPK-UHFFFAOYSA-K 0.000 description 1
- GRWVQDDAKZFPFI-UHFFFAOYSA-H chromium(III) sulfate Chemical compound [Cr+3].[Cr+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRWVQDDAKZFPFI-UHFFFAOYSA-H 0.000 description 1
- 150000001868 cobalt Chemical class 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 229940011182 cobalt acetate Drugs 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 1
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 1
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000013527 degreasing agent Substances 0.000 description 1
- 238000005237 degreasing agent Methods 0.000 description 1
- WCOATMADISNSBV-UHFFFAOYSA-K diacetyloxyalumanyl acetate Chemical compound [Al+3].CC([O-])=O.CC([O-])=O.CC([O-])=O WCOATMADISNSBV-UHFFFAOYSA-K 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 150000004683 dihydrates Chemical class 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 229960002089 ferrous chloride Drugs 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229940093915 gynecological organic acid Drugs 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 description 1
- 239000011654 magnesium acetate Substances 0.000 description 1
- 235000011285 magnesium acetate Nutrition 0.000 description 1
- 229940069446 magnesium acetate Drugs 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000011565 manganese chloride Substances 0.000 description 1
- 235000002867 manganese chloride Nutrition 0.000 description 1
- 229940099607 manganese chloride Drugs 0.000 description 1
- MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(2+);dinitrate Chemical compound [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 229940078494 nickel acetate Drugs 0.000 description 1
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 1
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical group 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002954 polymerization reaction product Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 239000011496 polyurethane foam Substances 0.000 description 1
- 235000011056 potassium acetate Nutrition 0.000 description 1
- 229940050271 potassium alum Drugs 0.000 description 1
- GNHOJBNSNUXZQA-UHFFFAOYSA-J potassium aluminium sulfate dodecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.[Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GNHOJBNSNUXZQA-UHFFFAOYSA-J 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- VBKNTGMWIPUCRF-UHFFFAOYSA-M potassium;fluoride;hydrofluoride Chemical compound F.[F-].[K+] VBKNTGMWIPUCRF-UHFFFAOYSA-M 0.000 description 1
- 230000002062 proliferating effect Effects 0.000 description 1
- 230000035755 proliferation Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910001923 silver oxide Inorganic materials 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 229910001631 strontium chloride Inorganic materials 0.000 description 1
- AHBGXTDRMVNFER-UHFFFAOYSA-L strontium dichloride Chemical compound [Cl-].[Cl-].[Sr+2] AHBGXTDRMVNFER-UHFFFAOYSA-L 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- AFNRRBXCCXDRPS-UHFFFAOYSA-N tin(ii) sulfide Chemical compound [Sn]=S AFNRRBXCCXDRPS-UHFFFAOYSA-N 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
- WUUHFRRPHJEEKV-UHFFFAOYSA-N tripotassium borate Chemical compound [K+].[K+].[K+].[O-]B([O-])[O-] WUUHFRRPHJEEKV-UHFFFAOYSA-N 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
発明の目的
産業上の利用分野
本発明は、冷蔵庫内や冷凍庫内の臭気、と〈Ｋ魚貝肉、
その他の肉類から発生するアンモニア臭、低級アミン魚
臭（主として、トリメチルアミン）、メルカプタン臭、
低級アルコール等の庫内悪臭を強力に吸着化合物化して
無臭化し、効果が速効性で持続性をもち、塩化カルシウ
ム塩の使用量によフ、使用時間の自由な調節が可能な冷
蔵床用兼冷凍庫用脱臭剤に関する。DETAILED DESCRIPTION OF THE INVENTION The purpose of the invention is to reduce odors in refrigerators and freezers,
Ammonia odor, lower amine fish odor (mainly trimethylamine), mercaptan odor emitted from other meats,
It is a product that can be used for refrigerated floors, making it odorless by strongly adsorbing lower alcohols and other odors in the refrigerator.It has a fast-acting and long-lasting effect, and can freely adjust the usage time depending on the amount of calcium chloride salt used. Regarding deodorizers for freezers.
従来技術
冷蔵庫用や冷６ＪＬ犀用脱某剤としては、ヤシガラ活性
炭が広く使用されている。BACKGROUND OF THE INVENTION Coconut shell activated carbon is widely used as a dewatering agent for refrigerators and cold 6JL rhinoceros.
発明が解決しようとする問題点
周知のヤシガラ活性炭は、アンモニア臭、低級アミン魚
臭等の粒子の小さい悪臭に対しては、＃王とんどその効
果を発揮しない。従って、ヤシガラ活性炭のみでは、冷
蔵庫内や冷凍庫１・Ｊの悪臭を十分に除去することが困
難である。Problems to be Solved by the Invention Known coconut shell activated carbon does not exhibit its effectiveness against small-particle odor such as ammonia odor and low-grade amine fish odor. Therefore, it is difficult to sufficiently remove the bad odor inside the refrigerator and freezer 1/J using coconut shell activated carbon alone.
問題点を解決するだめの手段
本発明は、ヤシガラ活性炭単独では脱某が困難なアンモ
ニア臭、低級アミン魚臭、メルカプタン某、低級アルコ
ール等の庫内悪臭を強力に除去することがり能で、その
効果が速効性及び侍枕９：′！ｉ″発薄するすぐれた品
質の冷蔵庫用兼冷凍庫用脱某剤の提供を目的とする。Means to Solve the Problems The present invention is capable of powerfully removing odor in the refrigerator such as ammonia odor, lower amine fish odor, certain mercaptan, lower alcohol, etc., which are difficult to remove using coconut shell activated carbon alone. Fast-acting and Samurai Pillow 9:'! The purpose of the present invention is to provide a certain degreasing agent for refrigerators and freezers of excellent quality that thins the product.
本発明は、塩化カルシウム塩が強力な吸湿性をもってい
ること、アンモニアは、低温になるほど水によく溶解す
ること、冷蔵庫内や冷凍庫内は、比較的乾燥した状態か
つ低温であって、空気が循環しているため、少ない湿気
ではあるが、アンモニアを多量に溶解した状態で塩化カ
ルシウム塩に吸収されること、塩化カルシウム塩は、吸
湿によって次第に固化し、最後には水溶液になる場合と
、ならない場合とあるが、塩化カルシウム塩の水溶液は
、水の存在において加水分解を起し、酸性を呈するため
、アルカリ性物質であるアンモニアと酸アルカリ反応及
び置換反応を起し、弱酸性の塩化アンモニウム塩と、弱
アルカリ性の水酸化カルシウム塩とを生成してアンモニ
ア臭を吸着すること、及び同時に分子化合物（高次化合
物、有慎分子化合物、付加化合物と称することもめる）
をつくること、低級アミン魚臭（主としてトリメチルア
ミン）に対しても、上記アンモニアの場合と同様なこと
がいえること、上記トリメチルアミン（（Ｃｆ（ａ ）
３Ｎ ）は、水に対する溶解度がアンモニアよプも少
ないが、アンモニアよジも強いアルカリ性物質であって
、庫内空気の１Ｊｉｉ環によって上記アンモニアの場合
と同様に塩化カルシウム塩と分子化合物（前記カッコ曹
参照）をつくると共に、湿気を吸収した塩化カル７ウム
塩と水の存在において酸アルカリ反応及び置換反応を起
して塩化カルシウム塩に吸着され、脱臭されること、メ
ルカプタンは、水に微溶で空気よシも重く、低所に蓄積
するが、冷蔵庫内や冷凍庫内では空気が循環しているの
で、塩化カルシウム塩に触れて４分子の化合物〔（分子
化合物）（前記カップ嘗参照）〕をつくると同時にアル
コラードを生成して脱臭されること、アルコラードは、
加水分解によシ最終的に４分子の化合物〔（分子化合物
）（前記カッコ書参照）〕に移行すること、低級アルコ
ールは水に非常によく溶け、塩化カルシウム塩と４分子
の化合物〔（分子化合物）（前記カッコ曹参照）〕をつ
くシ、前記低級アミン魚臭の場合と同様に塩化カルシウ
ム塩に吸着され、脱臭されること等に着目したうえで、
塩化カルシウム塩と、この塩化カルシウム塩と反応しな
いヤシガラ活性炭、多孔質の高品質活性炭（ともに酸性
活性化したものと、アルカリ活性化したものがあプ、夫
々吸収する成分が異なるが）、ゼオライト等の多孔性薬
剤、吸湿性、潮解性、水溶性で水の存在において加水分
解を起して酸性を呈する塩類、空隙保持剤、増量剤及び
その他の臭気を吸収または分解する薬剤またはその他の
臭気をマスキングする薬剤及び同様な元素もしくはその
元素の化合物とを混合使用、又は上記吸湿性、潮解性、
水溶性で水の存在において加水分解を起して酸性を呈す
る塩類、ヤシガラ活性炭、前記鍋品質活性炭（ともにア
ルカリ活性化したもの、酸性活性化したものとの両方が
ロシ、夫々吸収する成分が異なるが）、ゼオライト等の
多孔性薬剤、空隙保持剤、増量剤及びその他の臭気を吸
収または分解する薬剤またはその他の臭気をマスキング
する薬剤及び同様な元素またはその元素の化合物と塩化
カルシウム塩とを混合した物とを併用してなることであ
る。The present invention requires that calcium chloride salt has a strong hygroscopic property, that ammonia dissolves better in water as the temperature decreases, and that the inside of a refrigerator or freezer is relatively dry and low temperature, and air is circulated. Therefore, although there is little moisture, a large amount of dissolved ammonia is absorbed by the calcium chloride salt, and the calcium chloride salt gradually solidifies due to moisture absorption, and may or may not eventually become an aqueous solution. However, since an aqueous solution of calcium chloride salt undergoes hydrolysis in the presence of water and becomes acidic, it undergoes an acid-alkali reaction and a substitution reaction with ammonia, which is an alkaline substance, and forms a weakly acidic ammonium chloride salt. It adsorbs ammonia odor by producing weakly alkaline calcium hydroxide salts, and at the same time molecular compounds (also referred to as higher-order compounds, prudent molecular compounds, and addition compounds).
The same thing can be said for lower amine fishy odor (mainly trimethylamine) as in the case of ammonia, and that the above trimethylamine ((Cf(a)
3N) has a lower solubility in water than ammonia, but it is also a stronger alkaline substance than ammonia, and the 1Jii ring in the air in the refrigerator causes it to form calcium chloride salts and molecular compounds (the above-mentioned parentheses), as in the case of ammonia. Mercaptans are slightly soluble in water and are adsorbed by the calcium chloride salt through acid-alkali reactions and substitution reactions in the presence of water.Mercaptans are slightly soluble in water. Air is heavy and accumulates in low places, but as air circulates inside refrigerators and freezers, it comes into contact with calcium chloride salt and forms a four-molecule compound [(molecular compound) (see cup size above)]. Alcolade is deodorized by producing alcolade at the same time as it is made.
As a result of hydrolysis, lower alcohols are very soluble in water, and with calcium chloride salt, a compound of 4 molecules [(molecular compound) (see parentheses above)] is formed. Compound) (see parentheses above)], paying attention to the fact that it is adsorbed by calcium chloride salt and deodorized as in the case of the lower amine fish odor, etc.
Calcium chloride salt, coconut shell activated carbon that does not react with this calcium chloride salt, porous high-quality activated carbon (both are acid activated and alkali activated, although each absorbs different components), zeolite, etc. porous agents, hygroscopic, deliquescent, water-soluble salts that hydrolyze to become acidic in the presence of water, porosity retaining agents, bulking agents, and other odor-absorbing or decomposing agents or other odor-absorbing agents. Using a masking agent in combination with a similar element or a compound of that element, or using the above-mentioned hygroscopic, deliquescent,
Salts that are water-soluble and become acidic through hydrolysis in the presence of water, coconut shell activated carbon, and the pot-quality activated carbon (both alkali-activated and acid-activated) have different absorption components. ), mixing calcium chloride salts with porous agents such as zeolites, void retaining agents, bulking agents and other odor-absorbing or decomposing agents or other odor-masking agents and similar elements or compounds of such elements; It is made by using together with the same thing.
作 用
本発明は、上記技術手段からなるので、透湿性かつ通気
性のある容器に充填して使用するときは、塩化カルシウ
ム塩は、吸湿性を強力に発揮し、冷ＲＩ４内や冷ＯＮ、
Ｎｔ内が低温かつ少ない湿気状態であるにもかかわらず
、低温下はど水によく溶解するアンモニア共を多量に磐
屏した冷湿気を強力に吸収すると共に、塩化カルシウム
塩は、水の存在において加水分解を起して酸性を呈する
ため、アルカリ性を呈するＷ質でるるアンモニア臭、ト
リメチルアミン臭寺とばアルカリ反応及び置換反応を起
して塩をつくること、塩化カルシウム塩は分子化合物（
前記カッコ畜参照）生成作用（有機分子化合物生成作用
）を発揮することなどによシ、冷蔵庫内や冷凍庫内の湿
気を吸収せしめながら、悪臭を強力に除去せしめること
が可能になると共に、冷凍庫内で使用するときは、既に
発生した績の除去は無理としても、吸湿作用によって新
たな媚の発生を防ぐことが可能になる。Function The present invention consists of the above-mentioned technical means, so when used by filling it in a moisture-permeable and air-permeable container, the calcium chloride salt strongly exhibits hygroscopicity, and is not used in cold RI4 or cold ON.
Despite the low temperature and low humidity inside Nt, calcium chloride salt strongly absorbs cold moisture containing a large amount of ammonia, which dissolves well in water at low temperatures. Calcium chloride salt is a molecular compound (
By exhibiting the generation effect (organic molecular compound generation effect), it is possible to strongly remove bad odors while absorbing moisture in the refrigerator or freezer. When used in the dry season, even if it is impossible to remove the damage that has already occurred, it is possible to prevent new damage from occurring due to its moisture absorption effect.
実施例
本発明の実施例を使用可能な塩化カルシウム塩のＪｗｉ
類、実験例、試験例などを含めて以下に説明する。Examples Jwi of calcium chloride salts that can be used with examples of the present invention
It will be explained below, including examples, experiments, test examples, etc.
使用可能な塩化カルシウム塩は、無水塩、−水塩、二水
塩、四水塩、六水塩、塩化カルシウム塩と反応しない耐
酸性で多孔性の吸水性粒子（無機物及び有機物の双方を
含む）に塩化カルシウム塩水溶液を吸収せしめた粒子な
どがある。Calcium chloride salts that can be used include anhydrous salts, -hydrate salts, dihydrate salts, tetrahydrate salts, hexahydrate salts, and acid-resistant, porous water-absorbing particles (including both inorganic and organic materials) that do not react with calcium chloride salts. ) have absorbed an aqueous solution of calcium chloride salt.
さらには、アルカリ土類金属であるカルシウム元素、カ
ルシウム塩酸化物、カルシウム塩水酸化物、カルシウム
炭酸塩、その他のカルシウム塩に塩酸を加えてつくった
塩化カルシウム塩、強酸或いは弱酸による塩化物の交換
反応に二ってつくった塩化カルシウム塩、イオン交換樹
脂、及びスルホン化石炭等でつくった塩化カルシウム塩
、その他あらゆる製法で得られた塩化カルシウム塩の使
用が可能である。Furthermore, calcium chloride salts made by adding hydrochloric acid to calcium elements, which are alkaline earth metals, calcium salt oxides, calcium salt hydroxides, calcium carbonates, other calcium salts, and chloride exchange reactions with strong or weak acids are also available. It is possible to use calcium chloride salts prepared by two methods, ion exchange resins, calcium chloride salts prepared from sulfonated coal, etc., and calcium chloride salts obtained by any other manufacturing method.
本発明製品の薬剤としては、塩化カルシウム塩の二水塩
が粒状を呈するので、最も使用に適している。As the drug of the present invention, the dihydrate salt of calcium chloride salt is most suitable for use because it is in the form of granules.
空隙保持剤は、粒子の塩化カルシウム塩が吸湿によって
塊になることを防ぐために、塩化カルシウム塩に混合使
用する場合と、塩化カルシウム塩が塊になっても支障が
ないときは、混合することなく併用する場合とろる。従
って、空隙保持剤は、脱臭作用をもっていても、いなく
ても構わないが、上記混合使用及び併用の場合の条件と
して、粒子であること、塩化カルシウム塩と反応しない
安定した耐酸性の有機物又は無機物であることが必要で
ある。空隙保持剤の具体例を列挙すれば、混合使用可能
なものとして、脱臭作用の−あるもの（ヤシガラ活性炭
、素灰、ゼオライト、二酸化珪素粒（シリカゲル粒）等
）、スル夾ン化石炭、イオン交換樹脂その他等、脱臭作
用のないもの（耐酸性の合成樹脂ベレット、食塩、コー
クス粒、陶器粒その他等）の両方がち９、併用可能なも
のは、上記混合使用可能なもののほか、木酸水溶液（主
成分は石炭酸、グアヤコール酸等）、アルカリにて安定
化された二酸化塩累水溶液に不凍剤水溶液（たトエハ、
プロピレングリコール、エチレングリコールなど）を配
合した寒天ゲル状Ｗ（この場合、冷蔵庫内や冷凍庫内が
乾燥状態を呈するため、寒天ゲル状物は、水分が蒸発し
て体積を縮少し、使用期間の目盛番になる）、スルホン
化石炭又は陽イオン交換樹脂に上記不凍剤水溶液を配合
して得た水溶液を含浸せしめた粒状物などがらる。In order to prevent the calcium chloride salt particles from agglomerating due to moisture absorption, the porosity retaining agent is used when mixed with the calcium chloride salt, and when it is used without causing any problem even if the calcium chloride salt becomes agglomerated. It melts when used together. Therefore, the pore retaining agent may or may not have a deodorizing effect, but the above-mentioned conditions for mixed use and combination use include that it is a particle, and that it is a stable acid-resistant organic substance that does not react with calcium chloride salt or It must be inorganic. Specific examples of void retaining agents that can be used in combination include those with deodorizing properties (coconut shell activated carbon, raw ash, zeolite, silicon dioxide particles (silica gel particles), etc.), sulfur-impregnated coal, and ions. Replacement resins and other materials that do not have a deodorizing effect (acid-resistant synthetic resin pellets, salt, coke grains, ceramic grains, etc.)9.In addition to the above-mentioned products that can be used in combination, wood acid aqueous solution (Main components are carbolic acid, guaiacholic acid, etc.), antifreeze solution (Tatoeha,
Agar gel-like W containing propylene glycol, ethylene glycol, etc. (In this case, since the inside of the refrigerator or freezer is dry, the agar gel-like product loses moisture and shrinks in volume, and the scale of the usage period granules impregnated with an aqueous solution obtained by blending the above-mentioned antifreeze agent aqueous solution with sulfonated coal or cation exchange resin.
あらゆる元素もしくはその化合物は、添加剤として使用
するもので、塩化カルシウム塩、上記空隙保持剤などと
混合使用する場合と、上記を隙保持剤、増量剤、他の脱
臭剤を塩化カルシウム塩と併用する場合とアシ、塩化カ
ルシウム塩との間における条件は、併用する場合にはと
くに問題ないが、混合使用する場合には塩化カルシウム
塩と反応しないことを条件とする。Any element or its compound is used as an additive, and may be used in combination with calcium chloride salt, the above-mentioned porosity-retaining agents, etc., or in combination with the above-mentioned porosity-retaining agent, filler, or other deodorizing agent with calcium chloride salt. There are no particular problems with the conditions between the combination of reeds and calcium chloride salts, but when they are used in combination, the condition is that they do not react with the calcium chloride salts.
上記のあらゆる元素もしくはその化合物は、下記する元
素の単体もしくはその化合物を含むものとする。All of the above elements or their compounds include the elements listed below or their compounds.
現在の元素の周期表に記載されている元素（元素の周期
表（長周期型）を下記する）とその化合物、該周期表に
記載されていないが現存する元素とその化合物、将米新
しく作シ出される元素とその化合物、添加することによ
シ、その物質としてそれなシの脱臭作用を有する物質、
添加しても何等反応せず、何等の効果をも奏せず、品質
を低下せしめない物質、添加すると塩化カルシウム塩と
反応して若干効果を変化せしめるかもしれない物質、有
害又は無害な物質、Ｊ、Ｅ内の他の脱臭に効果のある物
質が添加された他の物質、上記各物質の混合物質又は併
用物質、その他、気体、液体、固体などのあらゆる物質
とその物質から新しく生成される物質、上記元素、化合
物、物質などが有機物又は無機物からなるものなど、過
去、現在、未来にわたるあらゆる元素とその化合物や誘
導体などを含むものであり、化合物は、酸性、中性、ア
ルカリ性等あらゆるものを含むものでろる。Elements listed in the current periodic table of elements (the periodic table of elements (long period type) is shown below) and their compounds, existing elements and their compounds that are not listed in the periodic table, newly created elements in the future. Elements and their compounds that are emitted, substances that have a deodorizing effect when added,
Substances that do not react in any way, do not produce any effects, and do not reduce quality when added; Substances that may react with calcium chloride salt and slightly change the effect when added; Substances that are harmful or harmless; Other substances added with other effective deodorizing substances in J and E, mixtures or combined substances of each of the above substances, and any other substances such as gases, liquids, solids, etc., and newly generated from these substances. Substances include all elements and their compounds and derivatives in the past, present, and future, such as those elements, compounds, and substances that are organic or inorganic.Compounds include all kinds of elements such as acidic, neutral, alkaline, etc. It is something that includes.
しかして、塩化カルシウム塩の粉末に前記仝隙保持剤、
固結防止剤（黒鉛、活性炭、その他等）又は増量剤（食
塩、コークス粒、その他等）及び他の吸湿性、潮解性で
あって中性又は酸性の塩類（たとえば、中性の硝酸ナト
リウム、酸性を呈する硝酸マグネシュウム塩、その他等
）を予め混合して粒状に成形したものを使用できる。Therefore, the above-mentioned gap retaining agent is added to the powder of calcium chloride salt.
Anticaking agents (graphite, activated carbon, etc.) or bulking agents (salt, coke granules, etc.) and other hygroscopic, deliquescent, neutral or acidic salts (e.g. neutral sodium nitrate, It is possible to use a mixture of acidic magnesium nitrate salt, etc.) mixed in advance and formed into granules.
本発明の脱臭剤は、下記の脱臭手段に供される脱臭剤を
含むもつである。The deodorizing agent of the present invention includes a deodorizing agent that is subjected to the following deodorizing means.
Ａ、アンモニア臭、低級アミン刺具のようなアルカリ性
物質で水に溶解する物質を速効的に脱臭する手段。A. A means of quickly deodorizing substances that dissolve in water with alkaline substances such as ammonia odor and lower amine prickling tools.
（１）、塩化カルシウム塩の表面に耐酸性、耐アルカリ
性の安定な塩化カルシウム塩と比重が同じ程度（比重約
２前後）の粉末又は粒子状の黒鉛（非常に安定な炭素原
子で塩化カルシウム塩とも反応しない）等を塩化カルシ
ウム塩と混合し、塩化カルシウム塩が水の存在において
湿気を帯びても固化しないようにした状態にし、水の存
在において加水分解を起して酸性を呈し、アルカリ性物
質であるアンモニア臭、低級アミン刺具と酸アルカリ反
応置換反応を起し、速効的に脱臭する手段。(1) On the surface of the calcium chloride salt, powder or particulate graphite (calcium chloride salt with extremely stable carbon atoms) having the same specific gravity (specific gravity around 2) as the stable calcium chloride salt with acid resistance and alkali resistance. The calcium chloride salt is mixed with calcium chloride salt so that it does not solidify even if it becomes moist in the presence of water, and it hydrolyzes in the presence of water to become acidic and form an alkaline substance. A method for quickly deodorizing the ammonia odor by causing an acid-alkali reaction substitution reaction with a lower amine prick.
（２）、上記（１）における如く混合した塩化カルシウ
ム塩に刺激性のない程度（たとえば、ＩＸ〜３ｘ前後）
に稀釈した酸性水層液（たとえば、稀塩酸、稀硝酸、そ
の他等で塩化カルシウム塩と反応し不溶性物質をつくら
ない酸の稀釈水浴液）を加えることによシ、一層酸性度
を増し、アルカリ性物質であるアンモニア臭、低域アミ
ン魚臭との間に起す酸アルカリ反応置換反応に酸アルカ
リ反応を付加せしめて強力かつ速効的に脱臭する手段。(2) To the extent that the calcium chloride salt mixed as in (1) above is not irritating (for example, around IX to 3x)
By adding a diluted acidic aqueous solution (e.g. diluted hydrochloric acid, diluted nitric acid, etc., which does not react with calcium chloride salts to form insoluble substances), the acidity can be further increased and alkaline A strong and fast deodorizing method that adds an acid-alkali reaction to the acid-alkali reaction substitution reaction that occurs between substances such as ammonia odor and low-range amine fish odor.
（３）、上記（１）に記した如く混合した塩化カルシウ
ム塩に、種々の潮解性、吸湿性、水溶性である物質であ
シ、かつ水溶液にした場合にそれ自体が塩化カルシウム
塩と同様に水の存在において加水分解を起して酸性を呈
する物質であって、塩化カルシウム塩と反応して不溶性
物質をつくらない物質（以下、塩類（１）と称す）を加
え、湿気を帯びさせることＫよシ、アルカリ性物質であ
るアンモニア臭、低級アミン刺具を速効的に脱臭する手
段。塩類（１）は、非常に種類が多く、又重金属塩は有
毒性の物質が多い。硝酸塩等は、爆発性の危険物が多い
が、少量を加える程度なら問題ないと思われる。(3) Add various deliquescent, hygroscopic, and water-soluble substances to the calcium chloride salt mixed as described in (1) above, and when it is made into an aqueous solution, it itself is similar to the calcium chloride salt. Adding a substance (hereinafter referred to as salts (1)) that hydrolyzes in the presence of water and becomes acidic and that does not react with calcium chloride salt to create an insoluble substance (hereinafter referred to as salts (1)) to make it moist. A quick and effective way to deodorize ammonia odor, which is an alkaline substance, and lower amine needles. There are many types of salts (1), and many heavy metal salts are toxic. Although many nitrates are dangerous and explosive, there is no problem if only a small amount is added.
上記塩類（１）の例を挙げれば、（ａ）、塩化物として
、塩化アルミニウム、塩化ストロンチウム、塩化ニッケ
ル、塩化マグネシウム、塩化コバルト、塩化アルミニウ
ム、塩化クロム、塩化マンガン、その他等（以上、潮解
性）、その他項化アンチモン（吸湿性、その他等）、そ
の他等、塩化バリウム（水溶性、有毒、その他等）、そ
の他等。（ｂ）、硝酸塩として、硝酸マグネシウム（危
険物）、硝酸アルミニウム、硝酸コバルト（危険物）、
硝酸第二鉄（危険物）、硝酸第二銅（危険物、劇物）、
硝酸マンガン（危険物、劇物）（以上、潮解性、危険物
）、その他、硝酸亜鉛（危険物、劇物）、硝酸ストロン
チウム（危険物）、硝酸バリウム（危険物、劇物）（以
上、水溶性）、その他等。（Ｃ）、酢識塩として、酢酸
コバルト（潮解性）、酢酸ナマリ（劇物）、酢酸亜鉛、
酢酸ニッケル（以上、水溶性）、その他等。（ｄ）、酸
化物として、五酸化リン、その他等。（ｅ）、硫酸塩と
して、硫酸鋼（劇物）、硫酸アルミニウム、硫酸亜鉛（
、ＪｌｌＪ物、劇薬）、１１を酸コバルト（劇物）（以
上、水溶性）、その他等。これらの塩Ｍ （１）は、単
に塩化カルシウム塩の反応の効果を挙げるのではなく、
−Ｓを交換（塩化カルシウム塩を減じ、その減量分だけ
塩類（１）を加えて総量を変化せしめないこと）したも
のであシ、分子化合物をつくらない。Examples of the above salts (1) include (a), chlorides such as aluminum chloride, strontium chloride, nickel chloride, magnesium chloride, cobalt chloride, aluminum chloride, chromium chloride, manganese chloride, and others (deliquescent); ), other antimony (hygroscopic, etc.), others, etc., barium chloride (water-soluble, toxic, others, etc.), etc. (b) As nitrates, magnesium nitrate (hazardous material), aluminum nitrate, cobalt nitrate (hazardous material),
Ferric nitrate (hazardous material), cupric nitrate (dangerous material, deleterious material),
Manganese nitrate (dangerous, deleterious) (deliquescent, hazardous), others, zinc nitrate (dangerous, deleterious), strontium nitrate (dangerous), barium nitrate (dangerous, deleterious) water-soluble), etc. (C), as vinegar salts, cobalt acetate (deliquescent), namari acetate (deleterious substance), zinc acetate,
Nickel acetate (water soluble), etc. (d) As an oxide, phosphorus pentoxide, etc. (e) As sulfates, steel sulfate (deleterious substance), aluminum sulfate, zinc sulfate (
, JllJ substance, powerful drug), cobalt acid 11 (deleterious substance) (all of the above, water-soluble), and others. These salts M (1) do not simply enhance the reaction effects of calcium chloride salts, but also
-S is exchanged (reducing the calcium chloride salt and adding salt (1) by the amount of the reduced amount without changing the total amount), and does not form a molecular compound.
（４）、前記（１）に記したように混合した塩化カルシ
ウム塩に、中性塩で塩化カルシウム塩と反応して不溶性
物質をつくらない物質（以下、塩類（２）と称す）の水
溶液を加え、塩化カルシウム塩に湿気を帯びさせること
によシ、水の存在において加水分解を起し、酸性を呈し
、アルカリ性物質であるアンモニア臭、低級アミン部具
を速効的に脱臭する手段。この手段は、効果的には単に
水を加えることと大差ない。(4) To the calcium chloride salt mixed as described in (1) above, add an aqueous solution of a substance (hereinafter referred to as salts (2)) that is a neutral salt and does not react with the calcium chloride salt to form an insoluble substance. In addition, by moistening calcium chloride salt, it undergoes hydrolysis in the presence of water, exhibiting acidity, and is a means for rapidly deodorizing ammonia odor and lower amine parts, which are alkaline substances. This procedure is effectively no different from simply adding water.
次に、塩類（２）を例示すると、（ａ）塩化物として、
塩化ナトリウム、塩化カリウム（以上、中性で水溶性）
その他、（ｂ）ａＭｃｌ！、塩として、硝酸ナトリウム
（危険物）（中性で潮解性）、硝酸カリウム（中性で水
溶性危険物）その他等。Next, to illustrate salts (2), as (a) chloride,
Sodium chloride, potassium chloride (neutral and water-soluble)
Others, (b) aMcl! , as salts, sodium nitrate (hazardous substance) (neutral and deliquescent), potassium nitrate (neutral and water-soluble hazardous substance), etc.
尚、硝酸塩は、爆発性の物質が多いが、少量であれば問
題ないと思われる。（ｃ）酢酸塩として、酢酸マグネシ
ウム（水溶性）、その他等。Although many nitrates are explosive substances, there is no problem if they are used in small amounts. (c) As acetate, magnesium acetate (water-soluble), others, etc.
（５）、塩化カルシウム塩に前記（１）の如く黒鉛また
はヤシガラ活性炭を混合し、さらに上記（４）に記載し
た如く塩類（２）を添加した塩化カルシウム塩に、刺激
臭のない程度の酸の水溶液を配合し、混合液に変化を起
こさせないで湿気を帯びさせることによシ、酸性を強め
、アルカリ性物質であるアンモニア臭、低級アミン部具
等を強力に脱臭する手段。(5) Calcium chloride salt is mixed with graphite or coconut shell activated carbon as described in (1) above, and salts (2) are added as described in (4) above. A method for strongly deodorizing ammonia odor, which is an alkaline substance, and lower amine parts, etc. by blending an aqueous solution of and adding moisture to the mixture without causing any change, thereby increasing acidity.
上記（５）の場合を例示すると、塩化、カルシウム塩に
塩化ナトリウム塩を添加し、さらに刺激共のない程度の
稀塩酸等を加える。To illustrate the case (5) above, sodium chloride salt is added to the chloride or calcium salt, and dilute hydrochloric acid or the like is further added to an extent that does not cause irritation.
Ｂ、アルカリ性物質の併用によシ、Ａ化水素、メルカプ
タン類、サルファイド頬、低級脂肪酸、酢酸、ノルマル
酪酸、脂肪族カルボン酸、芳香族カルボン酸、酸性ガス
類等の酸性物質を速効的脱臭する手段。アルカリ性物質
を塩化カルシウム塩と併用すると、水の存在においてカ
ルボン酸類の脱臭に有効である。前記Ａ、（すに記載し
た塩化カルシウム塩と混合する場合には、塩化カルシウ
ム塩の効力が減じられることを考慮して、アルカリと反
応しない物質かつ吸着性物質に予めアルカリ性物質を吸
収せしめて、なるべく反応しないようにする。たとえば
、多孔性のヤシガラ活性炭等に吸収せしめて塩化カルシ
ウム塩に混合する手段がある。しかして、アルカリ性物
質混合の場合、ごく夕景ならば、上記吸着性物′Ｘを用
いずに直接混合しても差支えないと思われる。このよう
な事情から、塩化カルシウム塩とアルカリ性物質とは、
併用することが望ましい。B. When used in combination with alkaline substances, A. Rapidly deodorizes acidic substances such as hydrogen hydride, mercaptans, sulfide cheeks, lower fatty acids, acetic acid, n-butyric acid, aliphatic carboxylic acids, aromatic carboxylic acids, and acidic gases. means. The use of alkaline substances in combination with calcium chloride salts is effective in deodorizing carboxylic acids in the presence of water. Above A, (taking into consideration that the efficacy of the calcium chloride salt will be reduced when mixing it with the calcium chloride salt described in 1), the alkaline substance is absorbed in advance into a substance that does not react with alkali and is adsorbent, Avoid reaction as much as possible.For example, there is a method of absorbing it into porous coconut shell activated carbon and mixing it with calcium chloride salt.However, in the case of mixing alkaline substances, if it is a sunset view, the adsorbent 'X' It seems that there is no problem in directly mixing without using calcium chloride salt and alkaline substance.
It is desirable to use them together.
アルカリ性物質としては、（ａ）第−又は第二燐酸塩と
して、第−又は第二燐酸ナトリウム（水溶性）、その他
等、（ｂ）酢酸塩として、酢酸カリウム（潮解性）その
他、酢酸ナトリウム（水溶性）、その他等、（Ｃ）硫化
物として、硫化ナトリウム＜ＷＡ解住）、その他等、（
ｄ）水酸化物として、水酸化ナトリウム（潮解性）、水
酸化カリウム（潮解性）、水酸化カルシウム塩、その他
等。Examples of alkaline substances include (a) primary or secondary phosphates such as primary or secondary sodium phosphate (water-soluble), etc. (b) acetates such as potassium acetate (deliquescent), others, sodium acetate ( (C) As a sulfide, sodium sulfide < WA decomposition), others, etc.
d) As hydroxides, sodium hydroxide (deliquescent), potassium hydroxide (deliquescent), calcium hydroxide salts, and others.
Ｃ６持続性を持たせるために塩化カルシウム塩の底面に
少量加えて不溶性物質の皮膜を薄くつくシ、反応を緩慢
にする手段。In order to make C6 sustainable, a small amount is added to the bottom of the calcium chloride salt to form a thin film of an insoluble substance, which is a means of slowing down the reaction.
塩化カルシウム塩は、損失を招くので、多量に加えるこ
とができない。又、多量に加えると脱臭効果が低下する
。下記の塩類は、塩化カルシウム塩と反応して不溶性物
質（たとえば、不溶解性カルシウム塩）をつくるので、
コントロール剤となる。たとえば、硫酸塩として、硫酸
亜鉛、硫酸アルミニウム、硫酸カドミウム、硫酸クロム
、その他等。硫化物として、硫化カドミウム、硫化ナト
リウム、その他等、水に溶けにくくなるが、徐々に加水
分解して水に溶けるようになるものとして、硫化カルシ
ウム塩がある。第三燐酸塩として、第三燐酸ナトリウム
（水に口Ｔｆａ）。ホウ酸塩として、ホウ酸ナトリウム
、ホウ酸カリウム（水溶性）、その他等。Calcium chloride salts cannot be added in large amounts as this will result in losses. Also, if a large amount is added, the deodorizing effect will decrease. The following salts react with calcium chloride salts to form insoluble substances (e.g., insoluble calcium salts).
Acts as a control agent. For example, sulfates include zinc sulfate, aluminum sulfate, cadmium sulfate, chromium sulfate, and others. Cadmium sulfide, sodium sulfide, and other sulfides are difficult to dissolve in water, but calcium sulfide salts gradually hydrolyze and become soluble in water. As a tertiary phosphate, sodium tertiary phosphate (Tfa in water). As borates, sodium borate, potassium borate (water soluble), etc.
炭酸塩として、炭ばカリウム（吸温性）、その他等、炭
酸ナトリウム（水溶性）その他等。珪酸塩として、珪酸
ナトリウム、珪酸カリウム（以上、水溶性）、その他等
。Carbonates include potassium charcoal (endothermic), others, sodium carbonate (water soluble), etc. Silicates include sodium silicate, potassium silicate (water-soluble), and others.
Ｄ、吸着剤法で、物理的に脱臭する物質と塩化カルシウ
ム塩との混合使用又は併用手板。この場合は、種々の他
の臭気も吸看して脱臭する。D. Mixture or combined use of physically deodorizing substances and calcium chloride salt using the adsorbent method. In this case, various other odors are also absorbed and deodorized.
吸着剤を例示すれば、活性白土、モレオニラーシープ、
アルミナシリカゲル、シリカゲル、活性炭（とくに、ヤ
シガラ活性炭は、他の臭気を吸収させるためと、固結を
防止せしめるために使用することに最も適した性質を有
する）、その他等。ここで混合夏用する場合は、塩化カ
ルシウム埴と反応しない吸着剤が好ましい。Examples of adsorbents include activated clay, moreonilla sheep,
Alumina silica gel, silica gel, activated carbon (especially coconut shell activated carbon has properties that are most suitable for use in absorbing other odors and preventing caking), and others. If mixed summer use is desired, an adsorbent that does not react with calcium chloride clay is preferable.
これまで種々の薬剤について記してきたが、実験の結果
、塩化カルシウム塩（無水塩、二水塩及びそれらの混合
物）と、ヤシガラ活性炭または多孔質の高品質活性炭（
ともに酸性活性化したものと、アルカリ活性化したもの
とがアシ、それぞれ吸収する成分が異なってくるが）と
の混合または併用が、とくに広い範囲にわたって臭気を
吸収し、かつ互に欠点を補ない得るため、すぐれている
という結論に達した。塩化カルシウム塩（無水塩、二水
塩またはこれらの混合物）は、アンモニア臭、トリメチ
ルアミン美、低級アルコールと分子化合物（前記カッコ
薔参照）をつ〈シ、少ない塩化カルシウム塩量で多量の
蒸気を吸収せしめることができる。その反面、吸湿によ
って固化する欠点がるる。上記塩化力ルシクム塩は、六
水塩になっても、２９．５℃以下では水溶液にならない
ため、ヤシガラ活性炭または前記高品質活性炭を空隙保
持剤として使用することが可能でおる。一方、ヤシガラ
活性炭または前記高品質活性炭は、非常に多孔性かつ吸
着保持力の大きな薬剤で、臭気としては、メチルメルカ
プタン、硫化メチルなどの硫黄化合物、アルコール類、
脂肪酸類、ハロゲン化炭化水床、脂肪族炭化水素、芳香
族炭化木葉、エステル類などを強力に吸収する。その欠
点として、多孔質が吸湿によって埋ってしまうため、極
端に吸収力を失なう。塩化カルシウム塩と併用または混
合することにより、その失なった湿気を塩化カル７ウム
塩が吸収してまたもとの乾燥状態に戻る。従って、前記
ヤシガラ活性炭類を乾燥状態に保持せしめ得て、長期に
わたって脱臭せしめ得る。この二種類を塩化カルシウム
塩と混合使用または併用する場合、塩化カルシウム塩の
比率が多い場合は、前記ヤシガラ活性炭類を乾燥せしめ
得ると共に、アンモニア臭、トリメチルアミン共、低級
アルコールなどに対する吸収が強力になシ、前記ヤシガ
ラ活性炭類の比率が多いと、前記臭気類に対する吸収が
強力になるので、これら両者の混合使用または併用によ
って優れた品質の製品が得られるという結＃１Ｉｔ−得
た。I have written about various drugs so far, but as a result of experiments, I found that calcium chloride salts (anhydrous salts, dihydrate salts, and mixtures thereof) and coconut shell activated carbon or porous high-quality activated carbon (
Mixing or combined use of both acid-activated products and alkali-activated products (although each absorbs different components) absorbs odors over a particularly wide range, and they do not compensate for each other's shortcomings. I have come to the conclusion that it is excellent. Calcium chloride salts (anhydrous salts, dihydrate salts or mixtures thereof) have no odor of ammonia, trimethylamine, lower alcohols and molecular compounds (see parentheses above), and absorb a large amount of vapor with a small amount of calcium chloride salt. You can force it. On the other hand, it has the disadvantage of solidifying due to moisture absorption. Even if the chlorinated lucicum salt becomes a hexahydrate, it does not become an aqueous solution at temperatures below 29.5°C, so it is possible to use coconut shell activated carbon or the above-mentioned high-quality activated carbon as a pore retaining agent. On the other hand, coconut shell activated carbon or the above-mentioned high-quality activated carbon is a highly porous and highly adsorbing agent, and its odor includes sulfur compounds such as methyl mercaptan and methyl sulfide, alcohols,
Strongly absorbs fatty acids, halogenated hydrocarbon beds, aliphatic hydrocarbons, aromatic carbonized leaves, esters, etc. The disadvantage is that the pores are filled with moisture, resulting in a significant loss of absorbency. By using or mixing with calcium chloride salt, the calcium chloride salt absorbs the lost moisture and returns to the original dry state. Therefore, the coconut shell activated carbon can be kept in a dry state and deodorized for a long period of time. When these two types are mixed or used in combination with calcium chloride salt, if the ratio of calcium chloride salt is high, the coconut shell activated carbon can be dried, and the absorption of ammonia odor, trimethylamine, lower alcohol, etc. will be strong. Conclusion #1It was obtained that when the ratio of the coconut shell activated carbon is high, the absorption of the odors becomes strong, and a product of excellent quality can be obtained by using a mixture or a combination of the two.
なお、併用の場合は、他の空隙保持剤（たとえば、合成
樹脂ペレット、石炭ガラ、その他等）、固結防止剤（た
とえば、黒鉛、その他等）を塩化カルシウム塩に混合し
て固結を防止するようにする。In addition, when used in combination, other void retaining agents (e.g., synthetic resin pellets, coal shavings, etc.) and anti-caking agents (e.g., graphite, others, etc.) may be mixed with calcium chloride salt to prevent caking. I'll do what I do.
Ｅ、吸着剤法で、化学的に吸着して脱臭する物質の混合
使用又は併用手段。この場合も、種々の他の臭気の脱臭
が可能でおる。吸着剤を例示すれば、イオン交俟樹脂、
スルフォン化石炭、その他等。E. Mixing or combined use of substances that chemically adsorb and deodorize using the adsorbent method. In this case as well, various other odors can be deodorized. Examples of adsorbents include ion exchange resins,
Sulfonated coal, etc.
Ｆ、錯化合物として脱臭する手段。硫酸第一鉄とＬ−ア
スコルビンＶ＜ビタミンＣ）とを混合した鉄アスコルビ
ン改化合物は、第一鉄（二価）が化学反応性に富み、空
気中で酸化されて安定な第二鉄（三価）に変化するのを
防ぐだめの酸化防止剤であるＬ−アスコルビン酸を加え
、酸化を防止するようにしたもので、中性から弱酸性の
粂件下で配位（錯化合物の一桟である）という化学反応
でアンモニア臭と結合して脱臭し、低級アミ７類臭も脱
臭するとされ、又中性或いは弱アルカリ性で硫化水素、
メチルメルカプタン臭とイオン結合して脱臭するとされ
る。F. Means for deodorizing as a complex compound. In the iron-ascorbin modified compound, which is a mixture of ferrous sulfate and L-ascorbine V<vitamin C, ferrous iron (divalent) has high chemical reactivity and is oxidized in the air to form stable ferric iron (trivalent iron). L-ascorbic acid, which is an antioxidant that prevents the compound from changing into a complex compound, is added to prevent oxidation. It is said that it combines with the odor of ammonia and deodorizes it through a chemical reaction called ammonia odor.
It is said to deodorize by ionic bonding with methyl mercaptan odor.
錯化合物をつくる性質を有している物質を例示すれば、
（混合使用又は併用が可能なもので、添加量は微ｆ）、
銀塩として、塩化銀（水に不溶でアンモニアに可溶、劇
物、危険物、混合使用可能）、硝酸銀（水に可溶、併用
可能）、その他等。銅塩として、硫酸銅（水に可溶、吸
湿性、劇物、弁用可能）、その他等。コバルト塩として
、第二塩化コバルト（水溶性、併用可能）、第一鉄塩と
して、塩化第一鉄（潮解性、併用可能）、その他等。Examples of substances that have the property of forming complex compounds are:
(Can be mixed or used in combination, the amount added is very small f),
Silver salts include silver chloride (insoluble in water, soluble in ammonia, deleterious and dangerous substances, can be used in combination), silver nitrate (soluble in water, can be used in combination), and others. Copper salts include copper sulfate (soluble in water, hygroscopic, toxic, can be used in valves), etc. As a cobalt salt, cobalt dichloride (water-soluble, can be used in combination), as a ferrous salt, ferrous chloride (deliquescent, can be used in combination), etc.
Ｇ、 Ｒ４ｍ性を帯びた物質を併用する手段。酸化剤と
して、次亜塩素酸ソーダ、晒粉（水に可溶）、その他等
。この薬剤を添加することによシ、殺菌性を呈し、細直
等の発生を防ぎ得るため、食品を保存しやすくする。ガ
ス類として、塩素ガス、過酸化水素、その他等。これら
のはか、殺菌剤を混合使用又は併用することによシ、殺
菌性によって細菌等の繁殖を押え、同時にアンモニア臭
、トリメチルアミン臭等を酸化して無臭化する。たとえ
ば、安定化二ば化塩素水を寒天ゲルに封じ込めたものを
併用する手段が考えられる。G. Means of using a substance with R4m properties in combination. Oxidizing agents include sodium hypochlorite, bleaching powder (soluble in water), and others. By adding this drug, it exhibits bactericidal properties and can prevent the occurrence of thinning, etc., making it easier to preserve foods. Gases include chlorine gas, hydrogen peroxide, and others. By mixing or using these fungicides, the bactericidal properties suppress the proliferation of bacteria, etc., and at the same time, ammonia odor, trimethylamine odor, etc. are oxidized to make them odorless. For example, it is conceivable to use a stabilized chlorine dichloride solution sealed in agar gel.
Ｈ８還元剤を混合使用する手段。酸化第−鉄等の還元剤
を加えることによシ、なんらかの酸化物質の生成を防ぐ
ことが考えられる。A means of using a mixture of H8 reducing agents. It is possible to prevent the production of some oxidized substances by adding a reducing agent such as ferrous oxide.
■、共重合物の混合使用手段。たとえば、アルミニウム
ミョウバン、その他等があり、多少のなんらかのガス類
を吸収することが考えられる。■Means for mixing and using copolymers. For example, there are aluminum alum, etc., which can absorb some gases.
Ｊ、酸化物の混合使用又は併用手段（但し、危険物が多
いので注意）。たとえば、酸化カルシウム塩、シリカゲ
ル（珪酸）、酸化銀、その他等。これらは、空隙保持剤
、増量剤、添加剤などとして使用できる。J. Mixed use or combined use of oxides (however, be careful as there are many dangerous substances). For example, calcium oxide salts, silica gel (silicic acid), silver oxide, etc. These can be used as void retaining agents, fillers, additives, and the like.
Ｋ、 （＋ｉｌＥ化物を混合使用する手段。たとえば、
硫化鉄、硫化錫、硫化亜鉛、その他等。これらは、水に
不溶性なので、空隙保持剤、増量剤、添加剤などとして
使用できる。K, (Means for using a mixture of +ilE compounds. For example,
Iron sulfide, tin sulfide, zinc sulfide, etc. Since these are insoluble in water, they can be used as porosity retainers, fillers, additives, and the like.
Ｌ０元素類の混合使用手段（但し、危険物が多いので注
意）。たとえば、黒鉛等の炭木物、重金属の鋼、銀、プ
ラチナ、金、その他等の安定なものは、空隙保持剤、増
量剤などとして使用できる。ナトリウム、カリウム、カ
ルシウム、マグネシウム、その他等は、水によシ発火し
てアルカリ性物質となる危険物であるが、なかＫは安定
な元素があシ、増量剤、空隙保持剤などとして使用でき
る。金属類は、カルボン酸と置換反応を起して脱臭作用
を発揮する。塩化カルシウム塩と混合使用又は併用すれ
ば、カルボン酸（カルボキシル基−ＣＯＯＨを有する化
合物の総称）と置換反応を起す。置換反応は、イオン化
傾向によって起こる。上記金属は、水の存在において有
効でろｐＸＪｊＩｔ内の水分がなくなれば反応しなくな
る。カルボキシル基の数によって、モノカルボン酸（１
個）、ジカルボン酸（２個）、などと区別し、またカル
ボキシル基の結合する炭化水素基に従って飽和、不飽和
カルボン酸、脂肪族カルボン酸、芳香族カルボン酸、な
どの別がメジ、さらに他にＯＨ基のあるものをオキシカ
ルボン酸（オキシ酸）、といい、−ＣＯＯ）ＩのＨは、
Ｈ＋とじて離れる性質があるため酸性を呈し、金属と置
換して塩をつくる。たとえば、ギ酸、酢酸、ノルマル酪
酸、乳酸、脂肪酸などのカルボン酸は、庫内の冷湿気に
よシ吸収され、アンモニア水となったアンモニア臭とは
化合しやスく、カルボン酸アンモニウム塩となシ、中性
又は弱アルカリ性を呈する。このカルボン酸アンモニウ
ム塩が塩化カルシウム塩の吸湿作用によって塩化カルシ
ウム塩に吸収される。従って、カルボン酸アンモニウム
塩は、反応過程で生成した水酸化カルシウム塩と置換反
応し、不溶比の物質をつくって多少脱臭される。又、カ
ルボン酸は、前記したように金属と置換反応を起し、不
溶性の金属塩となる性質があるが、水の存在が必要でろ
るため、庫内が乾燥状態であれば、あまり効果を期待す
ることはできない。Means for mixed use of L0 elements (however, be careful as there are many dangerous substances). For example, stable materials such as charcoal and wood materials such as graphite, heavy metals such as steel, silver, platinum, gold, and others can be used as void retainers, fillers, and the like. Sodium, potassium, calcium, magnesium, and others are dangerous substances that ignite when mixed with water and become alkaline substances, but potassium is a stable element and can be used as a filler, a filler, a porosity retaining agent, and the like. Metals exhibit a deodorizing effect by causing a substitution reaction with carboxylic acids. When mixed or used together with calcium chloride salt, a substitution reaction occurs with carboxylic acid (a general term for compounds having a carboxyl group -COOH). Substitution reactions occur due to ionization tendencies. The above metals are effective in the presence of water, but become unreactive when the water in pXJjIt disappears. Depending on the number of carboxyl groups, monocarboxylic acids (1
2), dicarboxylic acids (2), etc., and depending on the hydrocarbon group to which the carboxyl group is bonded, saturated, unsaturated carboxylic acids, aliphatic carboxylic acids, aromatic carboxylic acids, etc. Those with an OH group are called oxycarboxylic acids (oxyacids), and H in -COO)I is
Because it has the property of separating from H+, it becomes acidic and replaces metals to form salts. For example, carboxylic acids such as formic acid, acetic acid, n-butyric acid, lactic acid, and fatty acids are absorbed by the cold humidity in the refrigerator, and are easily combined with the ammonia odor that becomes aqueous ammonia, forming carboxylic acid ammonium salts. It exhibits neutral or slightly alkaline properties. This carboxylic acid ammonium salt is absorbed into the calcium chloride salt by the hygroscopic action of the calcium chloride salt. Therefore, the carboxylic acid ammonium salt undergoes a displacement reaction with the calcium hydroxide salt produced during the reaction process, creating a substance with an insoluble ratio, which is somewhat deodorized. Also, as mentioned above, carboxylic acids have the property of causing a substitution reaction with metals to form insoluble metal salts, but since they require the presence of water, they are not very effective if the inside of the refrigerator is dry. You can't expect much.
しかし）イオン化傾向（Ｋ＞Ｃａ）ｌＪａ＞Ｍｇ＞ＡＩ
＞Ｚｎ＞Ｆｅ＞Ｎｉ＞Ｓｎ＞Ｐｂ＞ｉｆ） によＬＡＩ
＞Ｚｎ＞Ｆｅ＞Ｎｉ＞Ｓｎ等の金属を湿らせて併用する
ことができる。（Ｋ、Ｃａ、Ｎａ、Ｍｇ等は、水の存在
罠おいて発火するため不適当でらる）。However) ionization tendency (K>Ca)lJa>Mg>AI
＞Zn＞Fe＞Ni＞Sn＞Pb＞if) yo LAI
Metals such as >Zn>Fe>Ni>Sn can be used together in a wet state. (K, Ca, Na, Mg, etc. are unsuitable because they ignite in the presence of water).
水素よシもイオン化傾向の大きな金属は、酸に溶解して
イオンとなシ、同イオン水素ガスを発生する。反応例を
記すと、
６ ＣＨａＣＯＯＨ＋ ２ＡＩ
酢 酸 アルミニウム
→２ （ＣｆｈＣＯＯ） Ａｌ ＋３ｔｈ↑カルボ
ン酸は、水酸化カルシウム、炭酸ナトリウム塩、水酸化
ナトリウム、水酸化カリウム、水酸化アルミニウム、水
酸マグネシウム、その他等による湿気を帯びたアルカリ
性物質に吸収せしめて脱臭することができる。Metals that have a strong tendency to ionize, like hydrogen, dissolve in acids and turn into ions, producing ionic hydrogen gas. A reaction example is as follows: 6 CHaCOOH+ 2AI Acetate Aluminum → 2 (CfhCOO) Al +3th↑Carboxylic acids include calcium hydroxide, sodium carbonate, sodium hydroxide, potassium hydroxide, aluminum hydroxide, magnesium hydroxide, etc. It can be absorbed into moist alkaline substances to deodorize it.
Ｍ、気化性防かび剤、不揮性防かび剤等の混合便用又は
併用手段。かびの発生を防止することができるが、人体
に有害なので、配合量を微量にするように注意すべきで
ある。M, means for mixing or using volatile fungicides, non-volatile fungicides, etc. Although it can prevent the growth of mold, it is harmful to the human body, so care should be taken to keep the amount added to a very small amount.
Ｎ、その他の手段。香料、顔料、ガス体（アルゴン、ヘ
リウム、その他等）、固形物で徨々の物質（たとえば、
硫酸バリウム、その他尋）を壇蛍剤として、又、酒石酸
のような有機酸がアンモニアと化合物乞つくる薬剤など
を添加剤として塩化カルシウム塩と混合使用又は併用す
るすべてのものを含む。N. Other means. Fragrances, pigments, gaseous bodies (argon, helium, etc.), solid substances (e.g.
It includes all substances in which barium sulfate (barium sulfate, etc.) is used as a fluorescent agent, and organic acids such as tartaric acid are used in combination with ammonia as additives, mixed or used together with calcium chloride salts.
冷蔵側、冷Ｉｉ犀で匣用するときは、前記塩化カルシウ
ム塩、前記空隙保持剤、前記薬剤、前記元素もしくは前
記化合物（有機物、無機物等全てを含む。以下、前記空
隙保持剤等と略称す）を熱可塑性合成樹脂孔あきフィル
ム製袋（たとえば、ポリオレフィン系樹脂、塩化ビニル
樹脂、ナイロン樹脂、テトロン樹脂、塩化ビニリデン樹
脂、テフロン樹脂等）、通気性及び透湿性を有する不織
布製袋（たとえば、ポリオレフィン系樹脂繊維、上記熱
可塑性合成樹脂繊維、金属繊維、ガラス繊維、炭素繊維
、その他繊維状物製不織布等）、織物製袋（たとえば、
上記不織布製袋に使用したと同じ繊維の織物、人絹織物
、綿織物、生糸載物、麻織物、その他の動植物繊維織物
、金属繊維、織物、ガラス１：威維織匈寺）、通気性及
び透湿性をもち、かつ非親水性のポリオレフィン系多孔
性シート状合成樹脂製袋（たとえば、徳山ｄ達株式会社
製の商品名ＮＦシート、槓水化学工菓株式会社製の商品
名セルボア等）などの容袋に密封した後、通気性及び透
湿性をもった容器（開閉蓋の付いた箱など）に収容する
。このはか前記塩化カルシウム塩、前記空隙保持剤等と
、他の脱臭剤とを夫々各別の通気性及び透湿性容袋に密
封した後、一つの上記容器に収容することができるし、
前記空隙保持剤等の混合された塩化カルシウム塩と、前
記空隙保持剤等とを夫々各別の上記容袋に密封し、一つ
の容器に収容して併用することができる。さらに、通気
性及び透湿性のある上記容器内部に幾つかの小室を画成
し、その小室は相互に通気及び透湿が可能なるように構
成せしめ（たとえば、塩化カルシウム塩及び空隙保持剤
などの粒子径以下の径の通気孔を画壁に無数に開穿する
）、該小室一つおきに塩化カルシウム塩と前記空隙保持
剤等との混合物を、上記容袋に収容することなく直接収
容することができる。通気性及び透湿性を有する前記容
袋及び前記容器は、塩化カルシウム塩が水溶液になると
加水分解を起し、Ｐ）Ｉ５前後の酸性を呈することを考
慮して、耐峻性、耐アルカリ性の材質でるることが好ま
しい。通気性及び透湿性を有する前記容器は、塩化カル
シウム塩が吸湿によって液化することを考慮して、周壁
土部適所に通気孔を開穿すると共に、周壁下部は通気孔
を開穿せずに構成し、８器内部を通気及び透湿が可能な
画壁（前記容器の通気孔と同様な通気孔を水平画壁に開
穿する）で上下二段に仕切プ、上部を脱臭室、下部を吸
水室（吸水性材料として、ヤシガラ活性炭、綿、綿状パ
ルプ、二酸化珪素粒、厚手の２紙、ゼオライト、海綿、
連続気泡のポリウレタンフォーム、吸水性ポリマー、そ
の他の吸水性材料及び珪酸ナトリウム塩、炭酸ナトリウ
ム塩、硝石灰、生石灰、その他等塩化カルシウム塩と反
応して中性塩類として固化せしめる薬剤を収容する室）
として使用するようにし、冷蔵厚内や冷凍厚内での漏水
を防止するようにする。冷蔵厚内や冷凍庫内は、比較的
乾燥しているので、ドアの開閉が著しくＩｐＡ繁でなけ
れば、塩化カルシウムは吸湿→固化で終るが、温度及び
湿度が筒い場合にドアの開閉が者しく＠緊であれば、固
化→液化という変化を起すことがあり、一旦水浴液にな
ると、冷凍庫に収納しても凍結しないし、酸性を呈する
ために漏水防止に注意を心安とする。通気性及び透湿性
を有する前記容器に通気性及び透湿性を有する開閉蓋を
具備せしめ、塩化カルシウム塩、前記空隙保持剤等など
収容物の漏出を防ぐと共に、交換を可能ならしめる。な
お、通気性及び透湿性を有する前記容器に代えて、既に
汎用されている冷械庫用の脱臭剤用容器を使用すること
ができるが、この場合は、吸水室を備えていないので、
塩化カルシウム塩水浴液の溜り具合に注意する必貴がる
る。On the refrigerated side, when using cold Ii rhinoceroses, the calcium chloride salt, the void retaining agent, the drug, the element or the compound (including all organic substances, inorganic substances, etc.) will be abbreviated as the void retaining agent, etc. ), thermoplastic synthetic resin perforated film bags (e.g., polyolefin resin, vinyl chloride resin, nylon resin, Tetron resin, vinylidene chloride resin, Teflon resin, etc.), air-permeable and moisture-permeable nonwoven fabric bags (e.g., Polyolefin resin fibers, thermoplastic synthetic resin fibers, metal fibers, glass fibers, carbon fibers, nonwoven fabrics made from other fibrous materials, etc.), woven bags (e.g.
Fabrics made of the same fibers used in the above non-woven bags, human silk fabrics, cotton fabrics, raw silk materials, hemp fabrics, other animal and plant fiber fabrics, metal fibers, fabrics, glass Moisture permeable and non-hydrophilic polyolefin porous sheet-like synthetic resin bags (for example, NF sheet manufactured by Tokuyama datsu Co., Ltd., Cellbore manufactured by Kansui Kagaku Koka Co., Ltd.), etc. After sealing the container in a container, store it in an air-permeable and moisture-permeable container (such as a box with an opening/closing lid). After the above-mentioned calcium chloride salt, the above-mentioned void retaining agent, etc., and other deodorizing agent are each sealed in separate air-permeable and moisture-permeable containers, they can be housed in one of the above-mentioned containers,
The mixed calcium chloride salt, such as the void retaining agent, and the void retaining agent, etc., can be sealed in separate bags, and then housed in one container and used together. Further, several chambers are defined inside the air-permeable and moisture-permeable container, and the chambers are configured to allow air and moisture to pass through each other (e.g., calcium chloride salts and porosity retaining agents, etc.). A large number of ventilation holes with a diameter equal to or smaller than the particle size are opened in the partition wall), and a mixture of calcium chloride salt and the void retaining agent, etc. is directly stored in every other small chamber without being placed in the container bag. be able to. The air-permeable and moisture-permeable container bag and container are made of tough and alkali-resistant materials, considering that calcium chloride salt undergoes hydrolysis when turned into an aqueous solution and exhibits acidity of around P)I5. It is preferable to come out. The container, which has air permeability and moisture permeability, has ventilation holes drilled at appropriate locations in the soil of the surrounding wall, taking into consideration that calcium chloride salt liquefies due to moisture absorption, and the lower portion of the surrounding wall is constructed without opening holes. The interior of the 8 vessels is divided into upper and lower parts by a wall that allows ventilation and moisture permeability (ventilation holes similar to those in the container described above are opened in the horizontal wall).The upper part is a deodorizing room, and the lower part is a Water absorption chamber (water absorption materials include coconut shell activated carbon, cotton, flocculent pulp, silicon dioxide grains, thick paper, zeolite, sponge,
chamber containing open-cell polyurethane foam, water-absorbing polymers, other water-absorbing materials, and agents that react with sodium silicate salts, sodium carbonate salts, nitric lime, quicklime, and other isocalcium chloride salts to solidify as neutral salts)
It should be used as a refrigerator to prevent water leakage inside the refrigerator or freezer. The inside of a refrigerator or freezer is relatively dry, so unless the door is opened and closed very frequently, calcium chloride will absorb moisture and solidify, but if the temperature and humidity are too high, it will become difficult to open and close the door. If it is very hot, it may undergo a change from solidification to liquefaction, and once it becomes a water bath liquid, it will not freeze even if stored in the freezer, and since it is acidic, care should be taken to prevent water leakage. The air-permeable and moisture-permeable container is provided with an air-permeable and moisture-permeable opening/closing lid to prevent leakage of the contents such as calcium chloride salt, the void retaining agent, etc., and to enable replacement. In addition, instead of the above-mentioned container having air permeability and moisture permeability, it is possible to use a deodorizer container that is already widely used for refrigerators, but in this case, since it is not equipped with a water absorption chamber,
Be careful of how the calcium chloride salt bath solution accumulates.
また、吸水室を備えている吸湿剤（商品名、湿気とり、
塩化カルシウム塩を使った吸湿＊ｌＪ、ｌも使用できる
。以上のことから、通気性及び透湿性を有する前記容器
の全部又は一部（周壁下部及び底部）を透明にすれば、
塩化カルシウム塩の前記変化程度を透視確認し得て便利
でおる。In addition, moisture absorbers (product name, moisture remover,
Moisture absorption*lJ,l using calcium chloride salt can also be used. From the above, if all or a part (lower part of the peripheral wall and bottom part) of the container having air permeability and moisture permeability is made transparent,
It is convenient to be able to visually confirm the degree of change in the calcium chloride salt.
該透明材質としては、アクリル樹脂、アクリルスチレン
樹脂、ポリスチレン樹脂、ＡＢＳ樹脂、ポリプロピレン
樹脂、塩化ビニル樹脂、中低圧ポリエチレン樹脂、ノ・
イインパクトスチロール樹脂などの耐酸性、耐アルカリ
性資材が使用可能でろる。The transparent materials include acrylic resin, acrylic styrene resin, polystyrene resin, ABS resin, polypropylene resin, vinyl chloride resin, medium and low pressure polyethylene resin,
Acid-resistant and alkali-resistant materials such as impact styrene resin can be used.
塩化カルシウム塩は、無水塩におっては白色の吸湿Ｍ解
性の塊であシ、二水塩は吸湿潮解性の粒子状であるので
、本発明で使用するのに適している。塩化カルシウム塩
は、非常に吸湿潮解性が強く、水分を吸収して無水塩→
−水堪→二水塩→四水塩→六水塩→水溶液と変化する。The calcium chloride salt is suitable for use in the present invention because the anhydrous salt is a white, hygroscopic, M-deliquescent mass, and the dihydrate salt is a hygroscopic, deliquescent, particulate form. Calcium chloride salt is highly hygroscopic and deliquescent; it absorbs water and becomes an anhydrous salt.
- Changes from water tank → dihydrate → tetrahydrate → hexahydrate → aqueous solution.
四水塩は固結し、六水塩は固結していて融点２９．５℃
であシ、最後には水溶液になる。塩化カルシウム塩は、
冷蔵庫内や冷凍厚内が比較的乾燥状態であるにも拘らず
、さらにａ湿するため、微生物や細菌等の生存に必要な
水分を奪ってしまう。従って、蛋白質や脂肪を分解する
微生物や細菌等は、冷蔵庫内や冷凍庫内の低温状態にお
いて水分なしで増殖を抑制されることになり、それら微
生物や細菌等の生存に適さないガ囲気がつくられ、食品
の長期保存が可能になる。塩化カルシウム塩を冷凍庫で
使用すると、強力な吸湿力によって、新たな霜の発生を
防止せしめ得る。Tetrahydrate is solidified, hexahydrate is solidified and has a melting point of 29.5℃
Finally, it becomes an aqueous solution. Calcium chloride salt is
Even though the inside of a refrigerator or freezer is relatively dry, it becomes even more humid, which deprives microorganisms and bacteria of the moisture they need to survive. Therefore, microorganisms and bacteria that decompose proteins and fats are inhibited from proliferating in the low-temperature conditions of refrigerators and freezers without moisture, and a cage is created that is unsuitable for the survival of these microorganisms and bacteria. It becomes possible to preserve food for a long time. Calcium chloride salts can be used in freezers to prevent new frost formation due to their strong hygroscopicity.
実験例
酢酸（ＣＨａＣＯＯＨ）を使用して脱臭効果をテストし
たところ、アンモニア水の存在において、下記反応を示
して脱臭された。Experimental Example When the deodorizing effect was tested using acetic acid (CHaCOOH), in the presence of aqueous ammonia, the following reaction occurred and deodorization occurred.
ＣＨｓＣＯＯＨ＋ＮＨ４ＯＨ−＋ ＣＨ３ＣＯＯＮＨ４
＋ Ｈ２Ｏ酢 酸 アンモニア水 酢酸アンモ
ニウム塩 水２ＣＨ３ＣＯＯＮＨ４＋ ＣａＣ
ｌ２ →酢酸アンモニウム塩 塩化カルシウム塩化
カルシウム塩 塩化アンモニウム塩となり、不
溶性の物質をつ〈シ、アンモニアは塩化アンモニウム塩
となって脱臭される。従って、庫内の少量のアンモニア
臭は、塩化カルシウム塩の存在において、少量の酢酸、
牛乳（乳酸）、バター、チーズ（酪酸）、脂肪酸などの
脱臭にめる程度の効果を発揮する。CHsCOOH+NH4OH−+ CH3COONH4
+ H2O acetic acid Ammonia water Ammonium acetate water 2CH3COONH4+ CaC
12 → Ammonium acetate salt Calcium chloride Calcium chloride salt It becomes an ammonium chloride salt and produces an insoluble substance. Ammonia becomes an ammonium chloride salt and is deodorized. Therefore, a small amount of ammonia odor in the refrigerator is caused by a small amount of acetic acid, in the presence of calcium chloride salt.
It is effective in deodorizing milk (lactic acid), butter, cheese (butyric acid), fatty acids, etc.
製品試験例（１）
刺激臭のない程度の稀塩ば又は稀硝酸、その他等、塩化
カルシウム塩と反応して沈澱を起さない水溶液を塩化カ
ルシウム塩の二水塩に加えて成る程度湿気を帯びさせ九
ところ、アンモニア共、低級アミン部具（主としてトリ
メチルアミン）を当初よりも速効的に脱臭した。これは
、アンモニア臭、低級アミン部具がアルカリ性物質を呈
するためであると思われる。Product test example (1) Add aqueous solutions such as dilute chloride salt, dilute nitric acid, etc. that do not react with calcium chloride salts and cause precipitation without irritating odor to dihydrate salts of calcium chloride salts to remove moisture to a certain extent. However, both ammonia and lower amine parts (mainly trimethylamine) were deodorized more quickly than before. This is thought to be because the ammonia odor and lower amine parts exhibit an alkaline substance.
製品試験例（２）
潮解性、吸湿性又は水容性の物質で、水溶液が酸性（ア
ルカリ性を呈するものは、塩化カルシウム塩と反応して
、被虐を無効にする化合物をつくるので除く）を呈し、
塩化カルシウム塩と反応して沈澱を起し、不溶性物質（
塩化カルシウム塩を他の化合物にして無効にする）をつ
くらない場合も、アンモニア臭、前記低級アミン部具を
脱臭した。これは、アンモニア臭、低級アミン部具など
がアルカリ性物質を呈するためでろると思われる。たと
えば、塩化アルミニウム塩、塩化マグネシウム塩、硝酸
アルミニウム塩、硝酸マグネシウム塩、その他等（その
他の無毒性の塩化塩、硝ｆ×塩、その他等を含む）。Product test example (2) Deliquescent, hygroscopic, or water-soluble substances whose aqueous solution is acidic (excluding those that are alkaline because they react with calcium chloride salts and create compounds that nullify masochism). ,
Reacts with calcium chloride salts to cause precipitation and insoluble substances (
Even when the calcium chloride salt is not made into other compounds to make it ineffective, the ammonia odor and the lower amine parts are deodorized. This is thought to be due to the odor of ammonia and the presence of alkaline substances in lower amine parts. For example, aluminum chloride salt, magnesium chloride salt, aluminum nitrate salt, magnesium nitrate salt, etc. (including other non-toxic chloride salts, nitrate salts, etc.).
製品試験例（３）
アンモニア水溶液と錯化合物をつくる物質の水溶液（酸
性を呈する）を加えたところ、アンモニア臭を当初から
脱臭する効果が発揮された。Product Test Example (3) When an aqueous solution (exhibiting acidity) of a substance that forms a complex compound with an ammonia aqueous solution was added, the effect of deodorizing the ammonia odor was exhibited from the beginning.
（たとえば、塩化銀、硝酸銀等）。これは、アンモニア
臭と錯化合物をつくるためである。但し、塩化カルシウ
ム塩と沈澱を起す物質（たとえば、１流酸塩、珪酸塩、
炭酸塩、講故塩、硼酸塩等）を除くものとする。但し、
併用する場合は使用できる。(e.g. silver chloride, silver nitrate, etc.). This is to create a complex compound with the ammonia odor. However, substances that cause precipitation with calcium chloride salts (for example, 1-sulfate salts, silicates,
Carbonates, salts, borates, etc.) shall be excluded. however,
Can be used in combination.
上記の製品試験例は、単に塩化カルシウム塩を増量した
のに比し、アンモニア臭、トリメチルアミン臭、低級ア
ルコール類等と分子化合物〔（有機分子化合物）（前記
カッコ書参照）〕ツ＜ウス、単に酸アルカリ反応によシ
、アンモニア臭、低級アミン部具を脱臭するにすぎなく
、実用性に乏しい。又、塩酸、蛸酸、酢酸類等は、冷蔵
庫、冷凍庫に発錆させるという問題点がある。In the above product test example, compared to simply increasing the amount of calcium chloride salt, it was found that ammonia odor, trimethylamine odor, lower alcohols, etc. and molecular compounds [(organic molecular compounds) (see parentheses above)] It only deodorizes ammonia odor and lower amine parts due to acid-alkali reaction, and is of little practical use. Furthermore, hydrochloric acid, octopus acid, acetic acid, and the like have the problem of causing rust in refrigerators and freezers.
ここで分子化合物に言及する。Reference is made here to molecular compounds.
高次化合物とは、各成分の原子が普通の原子価を満足し
ているような化合物を一次化合物といい、−次代合物が
形式的に分子間で結合して生じた形で表わせるような化
合物を高次化合物と呼ぶ。しかし、この考えかたは便宜
的なものにすぎない。錯塩、複塩、有機分子化合物、水
和物が含まれる。ＫＨＦ２（ＫＦ−ＨＦ ） 、 Ｈ２
５０４（Ｈｚ（）ＳＯ３） 、 （Ｃｏ（ＮＨ３）ｓ
〕Ｃ１！ （ＣＯＣｌ２・６ＮＨ３）などは（）内の一
次化合物の結合で表わしうる高次化合物である。A higher-order compound is a compound in which the atoms of each component satisfy the normal valences, and a -order compound can be formally expressed as a result of intermolecular bonding. These compounds are called higher-order compounds. However, this way of thinking is only a convenient one. Includes complex salts, double salts, organic molecular compounds, and hydrates. KHF2 (KF-HF), H2
504(Hz()SO3), (Co(NH3)s
]C1! (COCl2.6NH3) etc. are higher-order compounds that can be represented by the combination of primary compounds in parentheses.
付加化合物とは、２種またはそれ以上の分子がガロわシ
合って、Ａ＋Ｂ＋Ｃ−＋ＡＢＣのようにして生じた化合
物を付加化合物という。有機化合物とくに不飽和化合物
における重合反応生成物、不飽和結合へのハロゲン化水
素の付加、ＣＯ＋ Ｃｌ ｚ→ＣＯＣｌ２のような反応
など多くの例がるる。（付加化合物は、分子化合物（有
機分子化合物）に対する適切な表現とは思われないが、
このように称する文献が見受けられるので敢えて記載す
る）。An addition compound refers to a compound formed by combining two or more types of molecules in a manner such as A+B+C-+ABC. There are many examples, such as polymerization reaction products in organic compounds, especially unsaturated compounds, addition of hydrogen halides to unsaturated bonds, and reactions such as CO+ Cl z→COCl2. (Additional compound does not seem to be an appropriate expression for molecular compounds (organic molecular compounds), but
Since there are documents that refer to it in this way, I will write it here).
付加反応とは、２種の化合物が直接結合して、新しい別
の化合物を生成する反工５をいう。有機化学では、下側
のように不飽和結合をもつ有機化合物に水素、ハロゲン
化水素、水、ハロゲンなどが付加する反応が賞賛である
。たとえば、水素の付加ＣＨ２＝ＣＨ２＋ＣＨ２→ＣＨ
：Ｉ ＣＨａ、水の付加ＣＨミＣＨ＋Ｈ２０→Ｃｔ（：
＋ＣＨＯ，ハロゲンの付加ＲＣＨ＝ＣＨ−Ｒ＋Ｂｒｚ−
＋Ｒ−ＣＨ（Ｂｒ）−ＣＨ（Ｂｒ） −Ｒ、ハロゲン化
水素の付加ＣＨ２−ＣＨ２＋ ＨＢｒ−＋ＣＨａ ＣＨ
ｚ （Ｂｒ ）。Addition reaction refers to a reaction process 5 in which two types of compounds are directly combined to produce a new different compound. In organic chemistry, reactions in which hydrogen, hydrogen halide, water, halogen, etc. are added to organic compounds with unsaturated bonds, as shown below, are praised. For example, addition of hydrogen CH2=CH2+CH2→CH
:I CHa, addition of water CHmiCH+H20→Ct(:
+CHO, addition of halogen RCH=CH-R+Brz-
+R-CH(Br)-CH(Br) -R, addition of hydrogen halide CH2-CH2+ HBr-+CHa CH
z (Br).
複塩とは、組成のうえで、水にとかすと個々の成分イオ
ンにｌｓ離するものを複塩という。組成のうえからは、
錯塩と区別できず、解離しヤすい点で錯塩と区別される
。たとえば、カリウムミョウバンＫＡｌ（ＳＯ４）２・
１２ｆ（ｚＯは、水にとけてカリウムイオ／に、アルミ
ニウムイオン３＋
ＡＩＸｇｆｉ酸イオンＳＯ４などに解離する。しかし、
錯塩でも多少の解離は認められ、また結合の性質も本質
−的な差異はない。A double salt is a salt that separates into individual component ions when dissolved in water. From the composition,
It is indistinguishable from complex salts and is distinguished from complex salts by its ease of dissociation. For example, potassium alum KAl(SO4)2.
12f (zO dissolves in water and dissociates into potassium ion/aluminum ion 3+ AIXgfi acid ion SO4 etc. However,
Even in complex salts, some degree of dissociation is observed, and there is no essential difference in the nature of the bonds.
分子化合物とは、分子と分子との間で、夫々の原子の組
成の−１まで結合を生じたものをいう。A molecular compound refers to a compound in which bonds are formed between molecules up to -1 of the composition of each atom.
高次化合物と同じ意味で用いられることもある。Sometimes used interchangeably with higher-order compounds.
錯塩とは、錯体の中で、錯陽イオンと普通の陰イオン、
錯陰イオンと普通の陽イオン、錯陽イオンと錯陰イオン
の間に夫々イオン結合が生じてつくられた塩。一般に美
しい色彩をもった結晶または結晶性粉末で、水にとかす
とそれら有色の錯イオンや普通のイオンを生じっつ′Ｎ
離する。しかし、＊Ｉｓ・′４陰両イオンの結合による
ものは、不溶性またＶ１６溶性のものが多い。A complex salt is a complex consisting of a complex cation, a normal anion,
A salt created by forming ionic bonds between a complex anion and a normal cation, or between a complex cation and a complex anion. Generally, it is a crystal or crystalline powder with beautiful colors, and when dissolved in water, it produces colored complex ions and ordinary ions.
Let go. However, most of the compounds resulting from the combination of *Is and '4 anions are insoluble or V16 soluble.
中性の分子形の一体などは、これに含まれない。This does not include monoliths of neutral molecular forms.
古くは、錯塩という用語が錯体をすべて代表していた。In ancient times, the term complex salt represented all complexes.
発明の効果
本発明は、上記した発明の構成からなるので、周知の脱
臭剤では十分に脱臭できなかったアンモニア臭（湿気に
とくに吸収されやすい）、トリメチルアミン臭、メルカ
プタン美、低級アルコール等の如きひどい恋臭物質（魚
貝間より発する臭気）などは、塩化カルシウム塩の吸湿
作用及び冷蔵庫内と冷凍庫内とにおける空気循環によシ
、塩化カルシウム塩に吸収され、化学的に分子化合物（
前記カッコ曹参照）ｔつくり、また塩化カルシウム塩が
吸湿によって固化及び水溶液化してくると加水分解して
は注を呈するために、アルカリ性物質であるアンモニア
臭、低級アミン部具（主としてトリメチルアミンＡ）等
と酸アルカリ反応及び置俣反応を起して塩をつくる反応
が加味され、脱臭作用が増すと共に、速効的で持続性の
ある脱臭効果を発揮する。そして、冷蔵厚内や冷凍床内
の湿気を除去し、微生物や細菌等の増殖を抑制する効果
がある。さらに、冷凍体で使用すれば、強力な吸湿作用
によって、既にできた。硝の除去は無理としても、その
後の橿の発生音防止できると共に、冷Ｒ庫内の前記した
ひどい悪臭と同様の庫内悪臭を除去し得る。Effects of the Invention Since the present invention has the structure described above, it eliminates bad odor such as ammonia odor (which is particularly easily absorbed by moisture), trimethylamine odor, mercaptan odor, lower alcohol, etc., which cannot be sufficiently deodorized by known deodorants. Due to the hygroscopic action of calcium chloride salts and air circulation in the refrigerator and freezer, substances such as Koi-odor substances (odors emitted from fish and shellfish) are absorbed by calcium chloride salts and chemically converted into molecular compounds (
Also, when calcium chloride salt solidifies and becomes an aqueous solution due to absorption of moisture, it hydrolyzes and exhibits an odor of ammonia, which is an alkaline substance, lower amine components (mainly trimethylamine A), etc. In addition to the acid-alkali reaction and Okimata reaction to create salt, the deodorizing effect is increased and the deodorizing effect is fast-acting and long-lasting. It also has the effect of removing moisture within the refrigerator compartment and freezing floor, and suppressing the growth of microorganisms and bacteria. In addition, when used in frozen form, it is already formed due to its strong hygroscopic action. Even if it is impossible to remove the slag, it is possible to prevent the subsequent noise generated by the slag, and it is possible to eliminate the odor in the refrigerator similar to the above-mentioned terrible odor inside the refrigerator.
ｉ＆後に、塩化カルシウム塩を使用して工場などにおい
て、アンモニア臭、トリメチルアミン臭、低級アルコー
ルなどを脱臭することは、低温でないために効果は少な
いが、ある程度は脱臭可能である。After i&, deodorizing ammonia odor, trimethylamine odor, lower alcohol, etc. using calcium chloride salt in a factory or the like has little effect because the temperature is not low, but deodorization is possible to some extent.
特許出願人 松 下 敏 子−・）Patent applicant Toshiko Matsushita)
Claims (1)
い他の吸湿性、潮解性、又は水溶性で水の存在において
加水分解を起して酸性を呈する塩類の一種又は複数種の
脱臭薬剤、空隙保持剤、増量剤及び他の臭気を吸収する
活性炭、その他等の一種又は複数種の吸着性脱臭剤及び
他の臭気を発するマスキング法による薬剤と同じく反応
しないあらゆる元素もしくはその元素の中性又は酸性を
呈する化合物とを混合使用、または、上記薬剤と他の酸
性臭気を吸収するアルカリ性薬剤及びあらゆる元素のア
ルカリ性化合物に空隙保持剤または増量剤等を混合した
物と塩化カルシウム塩とを併用してなる冷蔵庫用兼冷凍
庫用脱臭剤。Calcium chloride salt and one or more types of deodorizing agents and pore retaining agents that do not react with the calcium chloride salt and other hygroscopic, deliquescent, or water-soluble salts that undergo hydrolysis in the presence of water and become acidic. , fillers and other odor-absorbing activated carbons, and other adsorbent deodorizers and other odor-emitting masking agents, as well as any element or neutral or acidic form of the element that does not react with it. Refrigerators made by using a mixture of the above chemicals and other alkaline chemicals that absorb acidic odors, alkaline compounds of all elements, and a porosity retaining agent or filler, etc., and calcium chloride salt. A deodorizer for the freezer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61020742A JPS62179465A (en) | 1986-01-31 | 1986-01-31 | Deodorant for refrigerator and freezer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61020742A JPS62179465A (en) | 1986-01-31 | 1986-01-31 | Deodorant for refrigerator and freezer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62179465A true JPS62179465A (en) | 1987-08-06 |
Family
ID=12035646
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61020742A Pending JPS62179465A (en) | 1986-01-31 | 1986-01-31 | Deodorant for refrigerator and freezer |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62179465A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0630978A (en) * | 1992-05-12 | 1994-02-08 | Hokkaido Electric Power Co Inc:The | Deodorant and activation of deodorant |
| JP2011183255A (en) * | 2010-03-04 | 2011-09-22 | Aomori Prefectural Industrial Technology Research Center | Calcium-alkaline type adsorptive material and method for manufacturing this material |
| JP2015043868A (en) * | 2013-08-28 | 2015-03-12 | Ｊｆｅミネラル株式会社 | Agent for inhibiting generation of ammonia gas, and method for inhibiting generation of ammonia gas |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5010708A (en) * | 1973-06-05 | 1975-02-04 | ||
| JPS60139338A (en) * | 1983-12-27 | 1985-07-24 | Nisshin Kagaku Kk | Deodorant |
| JPS60206425A (en) * | 1984-03-28 | 1985-10-18 | Enkuraa Bijinesu:Kk | Dehumidification type deodorant composition |
| JPS61106161A (en) * | 1984-10-31 | 1986-05-24 | 梶原 博文 | Solid deodorant composition |
-
1986
- 1986-01-31 JP JP61020742A patent/JPS62179465A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5010708A (en) * | 1973-06-05 | 1975-02-04 | ||
| JPS60139338A (en) * | 1983-12-27 | 1985-07-24 | Nisshin Kagaku Kk | Deodorant |
| JPS60206425A (en) * | 1984-03-28 | 1985-10-18 | Enkuraa Bijinesu:Kk | Dehumidification type deodorant composition |
| JPS61106161A (en) * | 1984-10-31 | 1986-05-24 | 梶原 博文 | Solid deodorant composition |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0630978A (en) * | 1992-05-12 | 1994-02-08 | Hokkaido Electric Power Co Inc:The | Deodorant and activation of deodorant |
| JP2011183255A (en) * | 2010-03-04 | 2011-09-22 | Aomori Prefectural Industrial Technology Research Center | Calcium-alkaline type adsorptive material and method for manufacturing this material |
| JP2015043868A (en) * | 2013-08-28 | 2015-03-12 | Ｊｆｅミネラル株式会社 | Agent for inhibiting generation of ammonia gas, and method for inhibiting generation of ammonia gas |
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