JPS62177869A - Sealed type battery - Google Patents

Sealed type battery

Info

Publication number
JPS62177869A
JPS62177869A JP61019275A JP1927586A JPS62177869A JP S62177869 A JPS62177869 A JP S62177869A JP 61019275 A JP61019275 A JP 61019275A JP 1927586 A JP1927586 A JP 1927586A JP S62177869 A JPS62177869 A JP S62177869A
Authority
JP
Japan
Prior art keywords
battery
electrode
carbon
terminal
carbon electrode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP61019275A
Other languages
Japanese (ja)
Other versions
JPH0570908B2 (en
Inventor
Isao Aramaki
勲 荒巻
Imakichi Hirasawa
今吉 平沢
Takao Miyashita
宮下 隆雄
Takayuki Kitano
北野 隆之
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Resonac Corp
Original Assignee
Shin Kobe Electric Machinery Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shin Kobe Electric Machinery Co Ltd filed Critical Shin Kobe Electric Machinery Co Ltd
Priority to JP61019275A priority Critical patent/JPS62177869A/en
Publication of JPS62177869A publication Critical patent/JPS62177869A/en
Publication of JPH0570908B2 publication Critical patent/JPH0570908B2/ja
Granted legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/04Cells with aqueous electrolyte
    • H01M6/06Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid
    • H01M6/10Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid with wound or folded electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/572Means for preventing undesired use or discharge
    • H01M50/584Means for preventing undesired use or discharge for preventing incorrect connections inside or outside the batteries
    • H01M50/59Means for preventing undesired use or discharge for preventing incorrect connections inside or outside the batteries characterised by the protection means
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/572Means for preventing undesired use or discharge
    • H01M50/574Devices or arrangements for the interruption of current
    • H01M50/583Devices or arrangements for the interruption of current in response to current, e.g. fuses
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/572Means for preventing undesired use or discharge
    • H01M50/584Means for preventing undesired use or discharge for preventing incorrect connections inside or outside the batteries
    • H01M50/588Means for preventing undesired use or discharge for preventing incorrect connections inside or outside the batteries outside the batteries, e.g. incorrect connections of terminals or busbars

Abstract

PURPOSE:To sharply enhance the safety of a battery by forming its terminal plates with such protective functional elements as being broken when electric current exceeding the defined level flows through. CONSTITUTION:A protective functional element 3 is welded on nickel or stainless steel wire net in a carbon electrode 1, by means of a resistance welder. One more separator is further piled on the carbon electrode 1 so that all of these components may be press-molded into one body. Since this press-molding process causes the carbon electrode 1 to be caught in both upper and lower separators 2, there is no chance of allowing gaps to be generated between the carbon electrode 1 and respective upper/lower separator 2 so that these components can be completely formed in one body. If a lithium electrode 7 is wound in layers in a spiral form as its starting point of winding comes inside, an electrode group 5 is formed. Five protective functional elements 3 also serving as the terminal plates of carbon electrodes 1 and a terminal 6 for just taking out electricity for the sake of a lithium electrode 7 come out from this electrode group 5. In this case, protective functional elements 3 broken due to flow of electric current more than 10A are employed.

Description

【発明の詳細な説明】 産業上の利用分野 本発明は、密閉型電池の安全性を向上させることに関す
るものである。
DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to improving the safety of sealed batteries.

従来の技術 ニカド蓄電池や鉛蓄電池等のように充電→放電初充電を
繰返すことによって再生使用可能な二次電池及びリチウ
ム/二酸化マンガン、リチウム/ (Ok”)n%アル
カリマンガン電池等のように放電すれば再生できない一
次電池から安全jc [気エネルギーを取り出すtこめ
に、種々の工夫がなされている。例えば、これら電池を
複数個直列に接続したり、またこのように直列に接続し
た電池群を、さらに複数個並列に接続したりして組電池
とし、機器の電源に用いる機会が、最近多くみられる。
Conventional technology Rechargeable secondary batteries such as Ni-Cd storage batteries and lead-acid batteries, which can be reused by repeating the initial charge and discharge, and rechargeable batteries such as lithium/manganese dioxide, lithium/(Ok”)n% alkaline manganese batteries, etc. Various techniques have been devised to safely extract energy from primary batteries that cannot be recycled.For example, several of these batteries may be connected in series, or a group of batteries connected in series may be Recently, there have been many opportunities to connect multiple batteries in parallel to form assembled batteries and use them as power sources for devices.

このような場合、各電池の性能を把握し、基準性能から
の許容範囲内にある電池を選択しc組電池とする方法を
とるが、さらに安全性を高めるのに出力端子にサーモス
イッチや温度ヒユーズ等を接続するといった方法が有効
とされている。すなわら、これらの方法はいずれも電池
外に電池を保護する保護機能素子を設けるものである。
In such cases, the method is to understand the performance of each battery, select a battery that is within the allowable range from the standard performance, and use it as a C battery. An effective method is to connect a fuse or the like. In other words, all of these methods involve providing a protective function element outside the battery to protect the battery.

発明が解決しようとする問題点 従来技術はいずれも電池外における電気的短絡や二次7
打池における過充電及び過放電を電池外に設けた保護機
能素子で検出し、外部回路を遮断する方法がとられてい
るが、電池で最も危険な事態は電池内部で発生する正極
と負極の直接接触である。この電極同志の接触か発生す
ると電池内部で大電流が流れるため、はとんどジュール
熱によっC熱が発生し、電池内部温度が昇をもたらし、
爆発を起こすことになるか、従来の技術ではこの種の危
険性を未然に防ぐことはできず、発生した後で安全処理
を施すことができない。
Problems to be Solved by the Invention All of the conventional techniques have problems such as electrical short circuits outside the battery and secondary
Overcharging and overdischarging during battery charging are detected using a protective function element installed outside the battery, and the external circuit is cut off. However, the most dangerous situation with batteries is when the positive and negative electrodes Direct contact. When this contact occurs between the electrodes, a large current flows inside the battery, which generates C heat due to Joule heat, causing the internal temperature of the battery to rise.
Conventional technology cannot prevent this type of hazard or provide safety measures after it occurs.

第6図は電池を複数個直列に接続した組電池のブロック
図であるか、この接続で組雷、池を強制的に放電すると
、ル゛池性能の悪い電池では■極性とe極在が逆転する
いわゆる転極か発生する。この事態を防ぐため各電池に
並列にダイオードを接続することか知られている。ここ
で、電池■が転極した場合、電池「に並列に接続された
ダイオードには順方向に電流が流れるので電池■はダイ
オードの順方向電圧降下分以上には深く転極しない。す
なわら、電流のほとんどは電池■を流れず、ダイオード
を流れる。しtこがって、強制放電しても電池■の温度
はそれ程上昇しないが、この方法は電池外での電気短絡
や過放電に対して電池性能の低い電池を保護するだけで
、電池内部における電極の接触短絡に対し′〔は有効な
手段となり得ないことは明らかである。すなわら、密閉
した電池内での短絡防止については有効な対策がなされ
ていないのが現状である。
Figure 6 is a block diagram of a battery assembly in which multiple batteries are connected in series.If the battery is forcibly discharged with this connection, the polarity and e polarity will change in a battery with poor battery performance. A so-called polarity reversal occurs. In order to prevent this situation, it is known to connect a diode in parallel to each battery. Here, when battery ■ reverses polarity, current flows in the forward direction through the diode connected in parallel with battery ", so battery ■ will not reverse polarity deeper than the forward voltage drop of the diode. In other words, , most of the current does not flow through the battery ■, but through the diode.Although forced discharge does not significantly increase the temperature of the battery, this method prevents electrical shorts and overdischarge outside the battery. On the other hand, it is clear that '['] cannot be an effective means to prevent short circuits between electrodes inside the battery by simply protecting batteries with low battery performance. Currently, no effective countermeasures have been taken.

本発明は電池内での電気短絡を素早く検出し、損傷を抑
制することによって電池の安全性を飛躍的に向上させよ
うとするものである。
The present invention aims to dramatically improve the safety of batteries by quickly detecting electrical short circuits within batteries and suppressing damage.

問題点を解決するための手段 上記の目的を達成するために、電極を小面積の複数個の
部分電極から構成して部分電池とし、各部分電池から電
池の出力端子に所定電流以上の電流が流れた時に断線す
る保護機能素子例えばフユーズで接続するようにしたも
のである。
Means for Solving the Problems In order to achieve the above object, the electrode is constructed from a plurality of partial electrodes of small area to form a partial battery, and a current of a predetermined current or higher is applied from each partial battery to the output terminal of the battery. The connection is made using a protective function element, such as a fuse, which is disconnected when the current flows.

作用 これにより、部分電池で電気短絡した場合、この部分電
池の内部抵抗が極めC小さくなることによって、この部
分電池と並列に接続され°〔いる他の部分電池から大き
な7流が流れ込むが、この瞬間に保護機能素子が断線す
るので、電気短絡した部分電池を他の部分電池から切り
離すことができる。
As a result, when an electrical short circuit occurs in a partial battery, the internal resistance of this partial battery becomes extremely small, and a large current flows from other partial batteries connected in parallel with this partial battery, but this Since the protective function element is instantly disconnected, the electrically short-circuited partial battery can be separated from other partial batteries.

実施例 本発明の一実施例を説明する。Example An embodiment of the present invention will be described.

電池は負極にリチウム、正極にカーボン電極を用い、電
解液に正極活物質である塩化チオニールと四塩化アルミ
ニウム酸リチウムの混合非水溶液を用いtこものである
。、第1図は本発明になる正極活物質を還元するカーボ
ン電極を示し、カーボン電極lとリチウム電極を電気的
に絶縁するセパレータ2とカーボンを極1を重ね合せた
構造を示している。セパレータ2は上記混合非水溶液に
対して化学的及び機械的にも安定な無機質繊維でできて
おり、寸法は幅43簡、長さ500酎、厚さ0.2 r
rtmである。カーボン電極りは次のようにし°〔製作
する。まずカーボン粉末と適当量の水の混合物にポリテ
トラフルオロエチレンディスバージョンをポリテトラフ
ルオロエチレンに換算して全重量の3〜504の範囲に
入るように添加しC混練する。この混練物をニッケルま
たはステンレス金網に塗布し、乾燥後、加圧成型しtこ
後空気中、280〜340″Cの範囲の温度で焼成する
と多孔質のカーボン電極lが得られる。カーボン電極1
の寸法は幅40IIIIII、長さ86珊、厚き0.5
甥で、これらカーボン電極1を5枚、セパレータ2上に
51の間隔をおいて重ねである。カーボン電極1には図
に示したようにニッケルまたはステンレス金網に抵抗溶
接機で保護機能素子3が溶接されている。カーボン[極
1の上側にさらにもう一枚セパレータを重ね、加圧成型
して一体化する。
The battery uses lithium for the negative electrode, a carbon electrode for the positive electrode, and a mixed non-aqueous solution of thionyl chloride and lithium aluminum tetrachloride, which are active materials for the positive electrode, as the electrolyte. FIG. 1 shows a carbon electrode for reducing a positive electrode active material according to the present invention, and shows a structure in which a carbon electrode 1 is superimposed on a separator 2 that electrically insulates a carbon electrode 1 and a lithium electrode. The separator 2 is made of inorganic fibers that are chemically and mechanically stable against the mixed non-aqueous solution, and its dimensions are 43mm wide, 500mm long, and 0.2mm thick.
rtm. The carbon electrode is manufactured as follows. First, polytetrafluoroethylene dispersion is added to a mixture of carbon powder and an appropriate amount of water in an amount ranging from 3 to 504 of the total weight in terms of polytetrafluoroethylene, and the mixture is kneaded. This kneaded product is applied to a nickel or stainless wire mesh, dried, pressure molded, and then fired in air at a temperature in the range of 280 to 340"C to obtain a porous carbon electrode. Carbon electrode 1
The dimensions are width 40III, length 86, thickness 0.5
Five of these carbon electrodes 1 are stacked on top of the separator 2 at intervals of 51. As shown in the figure, the carbon electrode 1 has a protective function element 3 welded to a nickel or stainless wire mesh using a resistance welder. Carbon [Lay another separator on top of pole 1 and press-mold to integrate.

この加圧成型によりカーボン電極1は上下セパレータ2
にくい込むことになるので、カーボン電極1とと下セパ
レータ2は空隙が生じることなく完全2こ一体化される
。これを第2図に示すように、リチウム電極7に重ね、
リチウム電極7が捲きはじめに内側に位置するようにス
パイラル状に捲くと電極群5が構成される。この電極群
5からはカーボン電極1用の端子を兼ねた保護機能素子
3が5個、リチウム電極7用に純粋に電気を取出Vため
の端子6が出ている。本実施例ではtOX以上の電流が
流れた時に断線する保護機能素子3を用いた。第3図は
電極群5を収納缶12に収納し、5個の保護機能素子3
を電池蓋8の中央部にセラミック1[で絶縁しtこ出力
端子9に、リチウム電極7用の端子6を収納缶【2の内
壁に溶接し、電池蓋8で収納缶12を密封したリチウム
−塩化チオニール電池を示す。
Through this pressure molding, the carbon electrode 1 becomes the upper and lower separators 2.
Since the carbon electrode 1 and the lower separator 2 are embedded in each other, the carbon electrode 1 and the lower separator 2 are completely integrated without creating a gap. As shown in FIG. 2, this is stacked on the lithium electrode 7,
The electrode group 5 is formed by spirally winding the lithium electrode 7 so that it is located on the inside at the beginning of the winding. From this electrode group 5, there are five protective function elements 3 which also serve as terminals for the carbon electrode 1, and a terminal 6 for purely extracting electricity for the lithium electrode 7. In this embodiment, a protective function element 3 which is disconnected when a current exceeding tOX flows is used. FIG. 3 shows an electrode group 5 stored in a storage can 12 and five protective function elements 3.
A terminal 6 for the lithium electrode 7 is insulated with ceramic 1 in the center of the battery lid 8, and a terminal 6 for the lithium electrode 7 is welded to the inner wall of the storage can 2, and the storage can 12 is sealed with the battery lid 8. - Indicates a thionyl chloride battery.

電池蓋8にはもう1つ予備端子I Oがセラミック11
で絶縁されて設けられCいるが、これには第1図で示し
た5枚のカーボン電極lのうち入点からの端子4を接続
し〔いる。したがって、電池外部で予備端子IOと収納
缶12を接続すると、5枚のうちの1枚のカーボン電極
冨とリチウム電極7か電池内部で電気的に短絡したこと
になる。第3図の電池において、電池蓋8と収納缶12
の周辺合せ部はレーデ溶接機で連続溶融溶接されている
。電池蓋8の中央部の出力端子9は金属性のチューブ状
になっcbす、電池蓋8と収納缶12の周辺合せ部を溶
接後、この出力端子9から?イ解液を注入し、その開口
部を封止すると電池が完成する。ただし、電池を製品と
しC製作する場合には予備端子1oは必要ない。
There is another spare terminal IO on the battery cover 8 which is a ceramic 11.
A terminal 4 from the input point of the five carbon electrodes 1 shown in FIG. 1 is connected to this. Therefore, when the spare terminal IO and the storage can 12 are connected outside the battery, one of the five carbon electrodes and the lithium electrode 7 are electrically short-circuited inside the battery. In the battery shown in FIG. 3, the battery cover 8 and storage can 12
The peripheral joints are continuously fused welded using a Rede welding machine. The output terminal 9 in the center of the battery cover 8 is shaped like a metallic tube. The battery is completed by injecting lysate and sealing the opening. However, when manufacturing a battery as a product, the spare terminal 1o is not necessary.

発明の効果 第4図は本発明になるリチウム−塩化チオニール電池で
、予備端子10と収納缶L2を電気的に短絡した時の電
池内部温度の上昇を示しtこもので、従来電池の短絡結
果をあわせ°〔示しCいる。これによると、従来電池で
は約9分後にリチウムの融点に近い【60°Cまで上昇
している。すなわち、従来電池の内部で電気的短絡が発
生した場合、電池内部温度の上昇は抑えることは難しく
、リチウムが溶融して爆発の危険性か極め〔高くなる。
Effects of the Invention Figure 4 shows the rise in internal temperature of the lithium-thionyl chloride battery according to the present invention when the spare terminal 10 and the storage can L2 are electrically short-circuited, which is much better than the short-circuit results of the conventional battery. Align ° [show C. According to this, in a conventional battery, the temperature rises to 60°C, which is close to the melting point of lithium, after about 9 minutes. That is, when an electrical short circuit occurs inside a conventional battery, it is difficult to suppress the rise in internal temperature of the battery, and the risk of explosion due to lithium melting becomes extremely high.

これに対して、本発明になる電池では20分経過後でも
約95°Cまでしか上昇せず、しかも飽和の傾向を示し
ていることから安全性の高い電池であることが証明され
た。
On the other hand, the battery of the present invention only rose to about 95°C even after 20 minutes and showed a tendency to saturate, proving that it is a highly safe battery.

第5図は本発明になる電池と従来電池におい〔、それぞ
れ予備端子10と収納缶12を故意に電気的に短絡させ
電池内部での短絡をシュレートさせだ時の電池雪圧の経
時変化を示したものである。ただし、従来1「池には保
護機能素子は入っ〔いない。電流検出器の一端を予備端
子に接続し、他端を収納缶12に短絡させた時の電流を
測定した。電気的に短絡させると約15秒後に電流はI
OAに達し、本発明になる電池ではその直後に3,6v
の開路電圧に復帰し゛〔いる。これは、短絡したカーボ
ン1i極lの保護機能索子3が断線したことを示し゛〔
いる。
FIG. 5 shows changes in battery snow pressure over time for the battery according to the present invention and the conventional battery, respectively, when the spare terminal 10 and the storage can 12 are intentionally electrically shorted to prevent a short circuit inside the battery. It is something that However, in conventional 1, there is no protective function element in the pond.The current was measured when one end of the current detector was connected to the spare terminal and the other end was short-circuited to the storage can 12. After about 15 seconds, the current becomes I
Immediately after reaching OA, in the battery of the present invention, 3.6v
The voltage has returned to the open circuit voltage. This indicates that the protective function cable 3 of the short-circuited carbon pole 1 is disconnected.
There is.

上述のように本発明電池は価格的にみても従来電池に比
べてほぼ同等で、且つ安全性か極めて高い点でコストパ
ーフォーマンスに優れており、その工業的価値の大なる
ものである。
As mentioned above, the battery of the present invention has excellent cost performance because it is almost equivalent in price to conventional batteries and is extremely safe, and has great industrial value.

【図面の簡単な説明】[Brief explanation of drawings]

第り図は本発明になる電池Iこ用いるカーボン極をセパ
レータに重ねた状態を示す正面図、第2図は本発明にな
る電池の電極群を示す平面図、第3図は本発明になるリ
チウム−塩化チオニール電池を示す平面図、第4図は従
来と本発明におけるリチウム−塩化チオニール電池をそ
れぞれ予備端子と収納缶を短絡させ電、池内部での短あ
る。 1はカーボン電極、2はセパレータ、3は保護機能素子
、4は端子、5は電極群、6は端子、7はリチウム電極
、8は電池蓋、9は出力端子、IOは予備端子、itは
セラミック、12は収納缶
Figure 2 is a front view showing the carbon electrodes used in the battery I according to the present invention stacked on a separator, Figure 2 is a plan view showing the electrode group of the battery according to the present invention, and Figure 3 is the present invention. FIG. 4 is a plan view showing a lithium-thionyl chloride battery, in which a conventional lithium-thionyl chloride battery and a lithium-thionyl chloride battery according to the present invention are short-circuited between a spare terminal and a storage case, respectively. 1 is a carbon electrode, 2 is a separator, 3 is a protective function element, 4 is a terminal, 5 is an electrode group, 6 is a terminal, 7 is a lithium electrode, 8 is a battery cover, 9 is an output terminal, IO is a spare terminal, it is Ceramic, 12 is a storage can

Claims (1)

【特許請求の範囲】[Claims] 正極、負極およびセパレータからなる電極群を収納缶に
収納し、収納缶の開口部を電池蓋で密封し、電池蓋の中
央部に絶縁体で電池蓋と電気的に絶縁した端子を設け、
該正極およびもしくは負極を小面積の複数個の部分電極
から構成し、該部分電極からの端子板を前記端子に接続
し、該端子板を所定電流以上の電流が流れた時に断線す
る保護機能素子から構成したことを特徴とする密閉型電
池。
An electrode group consisting of a positive electrode, a negative electrode, and a separator is stored in a storage can, the opening of the storage can is sealed with a battery lid, and a terminal is provided in the center of the battery lid, which is electrically insulated from the battery lid with an insulator.
A protective function element in which the positive electrode and/or the negative electrode is composed of a plurality of partial electrodes with a small area, a terminal plate from the partial electrode is connected to the terminal, and the terminal plate is disconnected when a current exceeding a predetermined current flows. A sealed battery characterized by being composed of.
JP61019275A 1986-01-31 1986-01-31 Sealed type battery Granted JPS62177869A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP61019275A JPS62177869A (en) 1986-01-31 1986-01-31 Sealed type battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61019275A JPS62177869A (en) 1986-01-31 1986-01-31 Sealed type battery

Publications (2)

Publication Number Publication Date
JPS62177869A true JPS62177869A (en) 1987-08-04
JPH0570908B2 JPH0570908B2 (en) 1993-10-06

Family

ID=11994894

Family Applications (1)

Application Number Title Priority Date Filing Date
JP61019275A Granted JPS62177869A (en) 1986-01-31 1986-01-31 Sealed type battery

Country Status (1)

Country Link
JP (1) JPS62177869A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0397457A2 (en) * 1989-05-08 1990-11-14 Eveready Battery Company, Inc. Spirally wound electrode assemblies and cells containing such
FR2655479A1 (en) * 1989-12-04 1991-06-07 Accumulateurs Fixes High-power lithium cell
EP0822605A2 (en) * 1996-07-30 1998-02-04 Saft Cylindrical electrochemical generator with spirally wounded electrodes
EP1035611A2 (en) * 1999-03-12 2000-09-13 Sony Corporation Solid electrolyte battery
EP1202364A1 (en) * 2000-10-26 2002-05-02 Isao Matsumoto Spirally-rolled electrodes with separator and the batteries therewith
EP1661194A1 (en) * 2003-09-01 2006-05-31 Byd Company Limited Cylindrical lithium ion secondary battery

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0397457A2 (en) * 1989-05-08 1990-11-14 Eveready Battery Company, Inc. Spirally wound electrode assemblies and cells containing such
FR2655479A1 (en) * 1989-12-04 1991-06-07 Accumulateurs Fixes High-power lithium cell
EP0822605A2 (en) * 1996-07-30 1998-02-04 Saft Cylindrical electrochemical generator with spirally wounded electrodes
FR2752089A1 (en) * 1996-07-30 1998-02-06 Accumulateurs Fixes CYLINDRICAL ELECTROCHEMICAL GENERATOR
EP0822605A3 (en) * 1996-07-30 1998-04-29 Saft Cylindrical electrochemical generator with spirally wounded electrodes
EP1035611A2 (en) * 1999-03-12 2000-09-13 Sony Corporation Solid electrolyte battery
EP1035611A3 (en) * 1999-03-12 2004-05-12 Sony Corporation Solid electrolyte battery
EP1202364A1 (en) * 2000-10-26 2002-05-02 Isao Matsumoto Spirally-rolled electrodes with separator and the batteries therewith
US8187738B2 (en) 2000-10-26 2012-05-29 Isao Matsumoto Spirally-rolled electrodes with separator and the batteries therewith
EP1661194A1 (en) * 2003-09-01 2006-05-31 Byd Company Limited Cylindrical lithium ion secondary battery
EP1661194A4 (en) * 2003-09-01 2008-04-16 Byd Co Ltd Cylindrical lithium ion secondary battery

Also Published As

Publication number Publication date
JPH0570908B2 (en) 1993-10-06

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