JPS62177078A - Ink composition for screen printing - Google Patents
Ink composition for screen printingInfo
- Publication number
- JPS62177078A JPS62177078A JP61018374A JP1837486A JPS62177078A JP S62177078 A JPS62177078 A JP S62177078A JP 61018374 A JP61018374 A JP 61018374A JP 1837486 A JP1837486 A JP 1837486A JP S62177078 A JPS62177078 A JP S62177078A
- Authority
- JP
- Japan
- Prior art keywords
- ink composition
- screen printing
- inorganic powder
- particle size
- matte
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 36
- 238000007650 screen-printing Methods 0.000 title claims description 25
- 239000000843 powder Substances 0.000 claims abstract description 26
- 239000002245 particle Substances 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 5
- 239000011521 glass Substances 0.000 abstract description 5
- 238000005299 abrasion Methods 0.000 abstract description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 3
- 239000005995 Aluminium silicate Substances 0.000 abstract description 2
- 235000012211 aluminium silicate Nutrition 0.000 abstract description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 abstract description 2
- 239000010419 fine particle Substances 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- 239000011347 resin Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 239000000377 silicon dioxide Substances 0.000 description 5
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000007822 coupling agent Substances 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 2
- 239000006087 Silane Coupling Agent Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- YJLUBHOZZTYQIP-UHFFFAOYSA-N 2-[5-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-1,3,4-oxadiazol-2-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1=NN=C(O1)CC(=O)N1CC2=C(CC1)NN=N2 YJLUBHOZZTYQIP-UHFFFAOYSA-N 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000008450 motivation Effects 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 210000001685 thyroid gland Anatomy 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明はスクリーン印刷用インキ組成物に関し、詳しぐ
は、そのインキ組成物による塗膜特性とじて耐摩耗性、
耐水性更には艶消調、梨地調といった装飾的効果を著し
く向上せしめたスクリーン印刷用インキ組成物に関する
ものである。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to an ink composition for screen printing.
The present invention relates to an ink composition for screen printing that has significantly improved water resistance and decorative effects such as matte and matte finishes.
（従来の技術とその問題点）
従来から筆記具用軸、化粧用客間９時計用品といっだ装
飾品については、特にその表面処理一つによっても商品
価値が犬きく左右され、まだ、消費者における購買意欲
もこれによって多大な影響を受ける為、それらには種々
の表面処理の工夫が施されてきている。(Conventional technology and its problems) Traditionally, the product value of decorative items such as writing utensil shafts and cosmetic and clock supplies has been greatly influenced by the surface treatment, and the consumer's interest still remains. Purchasing motivation is also greatly affected by this, so various surface treatments have been devised for these products.
中でもスクリーン印刷法は、比較的容易に艶消調、梨地
調を表出せしめることが可能である等のことから近年そ
れら装飾品に対して益々多用されるに至っているが２反
面、以下の如き欠点も併せ有しており、改良の要望が高
まってきている。Among these, the screen printing method has been increasingly used for decorative items in recent years because it can relatively easily produce a matte or satin finish. It also has drawbacks, and there is a growing demand for improvements.
即ち、スクリーン印刷法によって装飾品に艶消調或は梨
地調を表出せんとする場合、そのインキ組成物にシリカ
粉や樹脂粉体を混合することが知られているが、当該方
法では、得られる塗膜は外観上見映えは良いものの、塗
膜硬度が鉛筆芯硬度で３１−Ｔ以下のものとなり、多少
の衝撃でも塗膜が剥離し易くなる他、シリカ粉等が水分
を吸収し易い特性を有していることから印刷面の樹脂が
膨潤し２表面硬度の低下や塗膜の密着性不良を招くなど
機能面での欠点を有していることである。That is, when attempting to create a matte or satin finish on decorative items by screen printing, it is known that silica powder or resin powder is mixed into the ink composition, but in this method, Although the resulting paint film looks good, the hardness of the paint film is less than 31-T on a pencil lead hardness, and the paint film is likely to peel off even with some impact, and silica powder absorbs moisture. Because of its easy-to-understand characteristics, the resin on the printed surface swells, leading to a decrease in surface hardness and poor adhesion of the coating film, which has functional drawbacks.
（問題点を解決するだめの手段） 本発明は以上の状況に鑑みなされたもので。(Failure to solve the problem) The present invention was made in view of the above circumstances.
スクリーン印刷用インキ組成物において、平均粒径０１
〜５０μｍの無孔質無機粉体を含有することを特徴とす
るスクリーン印刷用インキ組成物を要旨とすることによ
り、装飾品における外観意匠上の装飾的効果向上は勿論
の事、耐摩耗性、耐水性といった機能面での向上も図る
ものである。In the screen printing ink composition, the average particle size is 01
By providing a screen printing ink composition characterized by containing a non-porous inorganic powder of ~50 μm, it not only improves the decorative effect on the appearance of decorative articles, but also improves abrasion resistance and It also aims to improve functionality such as water resistance.
本発明において使用される無孔質無機粉体としては、ガ
ラスパウダー、アルミナ、チタン。Examples of the nonporous inorganic powder used in the present invention include glass powder, alumina, and titanium.
二酸化チタン、カオリン、セリサイト等ｌ結晶性の高い
物質が挙げられ、これらは一種もしくは二種以上混合し
て使用される。この無孔質無機粉体の色調は白色系のも
のが望壕しくインキの色調をあ寸り損わない程度のもの
がよい。而して無孔質無機粉体の平均粒径ば０１〜５０
８ｍである。その平均粒径が０１μｍより小さいと艶消
調、梨地調の表出が困難とな９．丑だ。Examples include highly crystalline substances such as titanium dioxide, kaolin, and sericite, which may be used alone or in combination of two or more. The color tone of this non-porous inorganic powder is preferably white, and preferably has a color tone that does not overshadow the color tone of the ink. Therefore, the average particle size of the non-porous inorganic powder is 01 to 50.
It is 8m. 9. If the average particle size is smaller than 0.1 μm, it will be difficult to produce a matte or satin finish.9. It's ox.
５０μｍ より太きいとスクリーン印刷時のスクリーン
の目詰りを生じ易い為好捷しくないからである。This is because if it is thicker than 50 μm, the screen is likely to become clogged during screen printing, which is not desirable.
尚、使用する無孔質無機粉体によっては、インキ組成物
中の樹脂との接着性が悪いものも有り、これによって塗
膜の耐久性を低下せしめる場合も有ることから、予め該
無孔質無機粉体の表面をシラン系カップリング剤、クロ
ム系カップリング剤、チタン系カップリング剤等にょ９
表面改質を行なうことが望ましい。これらカップリング
剤の選定に当たっては、使用するインキ組成物中の樹脂
材質を考慮の上適宜選択すればよい。Depending on the nonporous inorganic powder used, some may have poor adhesion to the resin in the ink composition, which may reduce the durability of the coating film. Treat the surface of the inorganic powder with silane coupling agents, chromium coupling agents, titanium coupling agents, etc.9
It is desirable to perform surface modification. When selecting these coupling agents, they may be selected as appropriate, taking into consideration the resin material in the ink composition to be used.
本発明における上記無孔質無機粉体を除いたスクリーン
印刷用インキ組成物は、従来より公知のものがそのまオ
使用され、具体的には市販物として、セリコールＪＭ、
同ＦＭ−ＤＣＩＯ。In the present invention, the screen printing ink composition excluding the above-mentioned non-porous inorganic powder is a conventionally known ink composition, and specifically, commercially available products such as Sericol JM,
Same FM-DCIO.
同Ｖｓ−０００，同ＰＳ−０００，同ＤＰ −０００、
同Ｎ Ａ Ｌ 、同５０００．同７００口（以上、帝国
インキ■製）、セイコー１０００゜同１ろ００．同１６
９０．同５Ｇ１６Ｄ（以上。Same Vs-000, Same PS-000, Same DP-000,
Same N A L, same 5000. Same 700 units (manufactured by Teikoku Ink ■), Seiko 1000° Same 1ro 00. Same 16th
90. Same 5G16D (and above).
セイコーアドバンス■製）、ビントップ、ビンエイト、
ハイキット（以上、■永瀬スクリーン印刷所製）、ビン
ライ）１０００シリーズ（以上、十条化工■製）等が挙
げられる。これらインキ組成物は金属又は樹脂等の被印
刷面拐質に合わせて適宜選択されるもので、製造に際し
ては上記した無孔質無機粉体を三本ロール等により先の
インキ組成物に十分混合分散せしめて所望のスクリーン
印刷用インキ組成物を得るものである。この場合の無孔
質無機粉体の使用割合は、無機粉体側々の比重により若
干異なるが得られる塗膜の耐久性等を考慮して概ねイン
キ組成物全重量に対して１〜６０重量％が好ましい。Seiko Advance ■), Bin Top, Bin Eight,
Examples include Hi-Kit (all manufactured by Nagase Screen Printing Co., Ltd.) and Binrai) 1000 series (manufactured by Jujo Kako ■). These ink compositions are appropriately selected depending on the material of the surface to be printed, such as metal or resin, and during production, the above-mentioned non-porous inorganic powder is thoroughly mixed with the previous ink composition using a triple roll or the like. The desired screen printing ink composition is obtained by dispersing the ink composition. In this case, the proportion of the non-porous inorganic powder to be used varies slightly depending on the specific gravity of each inorganic powder, but considering the durability of the resulting coating film, etc., the proportion of the non-porous inorganic powder used is generally 1 to 60% by weight based on the total weight of the ink composition. % is preferred.
尚、塗膜の艶消調或は梨地調といった装飾的効果をより
高めるために、上記無孔質無機粉体と共に従来から利用
されているシリカ粉や樹脂粉体を併用し得ること勿論で
あり、更に、塗膜と被印刷面との密着性を向上すべく被
印刷面にクリヤーコーティングを施してもよいものであ
る。Incidentally, in order to further enhance the decorative effect of the coating film, such as a matte tone or satin tone, it is of course possible to use conventionally used silica powder or resin powder together with the above-mentioned non-porous inorganic powder. Furthermore, a clear coating may be applied to the printing surface in order to improve the adhesion between the coating film and the printing surface.
（実施例） 以下２本発明を実施例に基づき更に詳細に説明する。(Example) The present invention will be explained in more detail below based on two examples.
実施例１
市販の黒色スクリーン印刷用インキ組成物（セイコー１
３００． セイコーアドバンス■Ｍ）に、無孔質無機粉
体として、シラン系カップリング剤（エポキシシラン５
Ｖ６０５２，３４（レシリコン■製）１％メタノール溶
液で処理したガラスパウダー（平均粒径７μＩｎ 、
日本電気ガラス■製）を４０重量％添加し、これを三
本ロールで十分に混合分散して黒色のスクリーン印刷用
インキ組成物を得だ、。Example 1 Commercially available black screen printing ink composition (Seiko 1
300. A silane coupling agent (epoxy silane 5) is added to Seiko Advance ■M) as a non-porous inorganic powder.
V6052,34 (manufactured by Resilicon ■) Glass powder treated with 1% methanol solution (average particle size 7μIn,
A black screen printing ink composition was obtained by adding 40% by weight of Nippon Electric Glass (manufactured by Nippon Electric Glass) and thoroughly mixing and dispersing this with a three-roll roll.
６一
次いでこのインキ組成物を使用し、シルクスクリーン印
刷法によってニッケルめっきした真鍮軸（径Ｂｕｔｔ、
長さ８０ｍ ）に印刷を施し、１７０”Ｃ，３０分間熱
処理して梨地調の軸を得た。6 Next, using this ink composition, a nickel-plated brass shaft (diameter Butt,
A shaft with a satin finish was obtained by printing on a length of 80 m and heat-treating it at 170''C for 30 minutes.
実施例２
実施例１にて作成したインキ組成物にシリカ粉（サイロ
イド１６１．富士デヴイソン化学■製）を１重量％添加
し、これを十分拐”拌混合して黒色のスクリーン印刷用
インキ組成物を得た。Example 2 1% by weight of silica powder (Syroid 161, manufactured by Fuji Davison Chemical Co., Ltd.) was added to the ink composition prepared in Example 1, and this was thoroughly stirred and mixed to obtain a black screen printing ink composition. I got it.
次いでこのインキ組成物を使用し、シルクスクリーン印
刷法によって、アルマイト処理を施したアルミニウムに
金色の有機染料による染色を行ないこの後アクリル系コ
ーティングを行なった軸（径Ｂｙｎｍ、長さ８０ｍ ）
に印刷を施し。Next, using this ink composition, alumite-treated aluminum was dyed with a golden organic dye using a silk screen printing method, and then an acrylic coating was applied to a shaft (diameter Bynm, length 80m).
Printed on.
１６０°Ｃｌ２Ｏ分間熱処理して艶消調の軸を得だ。A matte finish was obtained by heat treatment at 160°CCl2O.
実施例６
実施例１にて作成したインキ組成物に平均粒径５μｍの
ナイロンボール（東し■製）を１重量％添加し、これを
十分攪拌混合して黒色のスクリーン印刷用インキ組成物
を得た。Example 6 1% by weight of nylon balls (manufactured by Toshi) with an average particle size of 5 μm were added to the ink composition prepared in Example 1, and the mixture was thoroughly stirred and mixed to obtain a black screen printing ink composition. Obtained.
次いでこのインキ組成物を使用し、シルクスクリーン印
刷法によって、実施例２に記載の軸と同様の軸に印刷を
施し、１７０°Ｃ，２０分間熱処理して艶消調の軸を得
た。Next, using this ink composition, a shaft similar to the shaft described in Example 2 was printed by a silk screen printing method, and heat treated at 170° C. for 20 minutes to obtain a matte shaft.
実施例４
市販の白色スクリーン印刷用インキ組成物（セリコール
ｖｓ−ｏｏｏ、帝国インキ■製）に、無孔質無機粉体と
して平均粒径６μｍのアルミナビーズ（ＬＵＸＥＴ、Ｅ
Ｎ、住友化学工業■製）を５０重量％添加し、これを高
速攪拌後、ロール加工によって十分分散せしめ白色のス
クリーン印刷用インキ組成物を得た。Example 4 Alumina beads (LUXET, E
50 wt.
次いでこのインキ組成物を使用し、シルクスクリーン印
刷法によってＡＢＳの樹脂軸（径８跋、長さ１０伽）に
印刷を施し、７０°Ｃ９３０分間熱処理して艶消調の軸
を得だ。Next, this ink composition was used to print on an ABS resin shaft (diameter: 8 mm, length: 10 mm) using a silk screen printing method, and heat treated at 70° C. for 930 minutes to obtain a matte shaft.
比較例１
市販の黒色スクリーン印刷用インキ組成物（セイコー１
３００． セイコーアドバンス■製）に、シリカ粉（
サイロイド１６１．富士デヴイソン化学■製）を１５重
量％添加し、これを十分攪拌混合して黒色のスクリーン
印刷用インキ組成物を得た。Comparative Example 1 Commercially available black screen printing ink composition (Seiko 1
300. (manufactured by Seiko Advance ■), silica powder (
Thyroid 161. 15 wt.
次いでこのインキ組成物を使用し、シルクスクリーン印
刷法によって、実施例１に記載の軸と同様の軸に印刷を
施し、艶消調の軸を得だ。This ink composition was then used to print on a shaft similar to the shaft described in Example 1 by silk screen printing to obtain a matte shaft.
比較例２
市販の黒色スクリーン印刷用インキ組成物（セイコー１
３００． セイコーアドパ、ンス■製）に、平均粒径５
μ丁ηのナイロンボール（東し■製）を２０重量％添加
し、これを十分攪拌混合シテ黒色のスクリーン印刷用イ
ンキ組成物を得た。Comparative Example 2 Commercially available black screen printing ink composition (Seiko 1
300. Seiko Adopa (manufactured by Nsu) has an average particle size of 5.
20% by weight of nylon balls (manufactured by Toshi) were added and mixed thoroughly to obtain a black screen printing ink composition.
次いでこのインキ組成物を使用し、シルクスクリーン印
刷法によって、実施例２に記載の軸と同様の軸に印刷を
施し、梨地調の軸を得た。Next, this ink composition was used to print on a shaft similar to the shaft described in Example 2 by silk screen printing to obtain a satin-like shaft.
（発明の効果）
以上実施例１〜４及び比較例１，２で得られた軸につい
て５通常の状態及び沸騰水処理（９５°Ｃ以上のイオン
交換水に２０分間浸漬）後の二条件下で、夫々表面硬度
、密着性に関する試験を行々った。結果は下表のとおり
である。(Effect of the invention) Regarding the shafts obtained in Examples 1 to 4 and Comparative Examples 1 and 2, under two conditions: 5 normal state and after boiling water treatment (immersion in ion-exchanged water at 95°C or higher for 20 minutes). We conducted tests on surface hardness and adhesion. The results are shown in the table below.
※１表面硬度・・・・・・鉛筆芯にて測定。（ＪＩＳ
Ｈ８６０２）※２密着性・・・・・・カッターにより１
飢間隔のマス目を１００個刻設し、市販の粘
着性テープによりこれを剥した
＝１０−
際の残りの個数を調べだ。*1 Surface hardness: Measured with pencil lead. (JIS
H8602) *2 Adhesion...1 depending on the cutter
Carve out 100 grids with the same spacing, peel them off using commercially available adhesive tape, and find out how many squares are left.
（クロスカット試験）
上述した如く本発明のスクリーン印刷用インキ組成物に
よれば、その塗膜特性として耐摩耗性、耐水性等が著し
く向上し、もって機能上及び外観上共に優れた装飾品が
得られるものである。(Cross-cut test) As described above, the screen printing ink composition of the present invention significantly improves coating film properties such as abrasion resistance and water resistance, thereby producing decorative articles that are excellent in both functionality and appearance. That's what you get.
Claims (1)
１〜５０μｍの無孔質無機粉体を含有することを特徴と
するスクリーン印刷用インキ組成物。In the screen printing ink composition, the average particle size is 0.
An ink composition for screen printing, comprising a nonporous inorganic powder of 1 to 50 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61018374A JPS62177078A (en) | 1986-01-30 | 1986-01-30 | Ink composition for screen printing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61018374A JPS62177078A (en) | 1986-01-30 | 1986-01-30 | Ink composition for screen printing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62177078A true JPS62177078A (en) | 1987-08-03 |
Family
ID=11969935
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61018374A Pending JPS62177078A (en) | 1986-01-30 | 1986-01-30 | Ink composition for screen printing |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62177078A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5344842A (en) * | 1976-10-06 | 1978-04-22 | Yuasa Battery Co Ltd | Method of producing lead battery |
| JPS5912978A (en) * | 1982-06-30 | 1984-01-23 | デグツサ・アクチエンゲゼルシヤフト | Vehicle for carrying out precise screen print and relief-like decoration on ceramic and other article |
-
1986
- 1986-01-30 JP JP61018374A patent/JPS62177078A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5344842A (en) * | 1976-10-06 | 1978-04-22 | Yuasa Battery Co Ltd | Method of producing lead battery |
| JPS5912978A (en) * | 1982-06-30 | 1984-01-23 | デグツサ・アクチエンゲゼルシヤフト | Vehicle for carrying out precise screen print and relief-like decoration on ceramic and other article |
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