JPS62169158A - Thermally developable color photosensitive material - Google Patents
Thermally developable color photosensitive materialInfo
- Publication number
- JPS62169158A JPS62169158A JP1156386A JP1156386A JPS62169158A JP S62169158 A JPS62169158 A JP S62169158A JP 1156386 A JP1156386 A JP 1156386A JP 1156386 A JP1156386 A JP 1156386A JP S62169158 A JPS62169158 A JP S62169158A
- Authority
- JP
- Japan
- Prior art keywords
- group
- silver
- photosensitive material
- acid
- heat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 title claims abstract description 56
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 14
- 125000003118 aryl group Chemical group 0.000 claims abstract description 12
- 125000000623 heterocyclic group Chemical group 0.000 claims abstract description 11
- 125000004442 acylamino group Chemical group 0.000 claims abstract description 6
- 125000003282 alkyl amino group Chemical group 0.000 claims abstract description 5
- 125000001951 carbamoylamino group Chemical group C(N)(=O)N* 0.000 claims abstract description 5
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims abstract description 4
- 239000000126 substance Substances 0.000 claims description 9
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 6
- 239000000178 monomer Substances 0.000 abstract description 17
- 125000001424 substituent group Chemical group 0.000 abstract description 13
- 229920001577 copolymer Polymers 0.000 abstract description 12
- 230000001105 regulatory effect Effects 0.000 abstract 1
- -1 silver halide Chemical class 0.000 description 108
- 229910052709 silver Inorganic materials 0.000 description 49
- 239000004332 silver Substances 0.000 description 49
- 239000010410 layer Substances 0.000 description 43
- 238000000034 method Methods 0.000 description 30
- 229920000642 polymer Polymers 0.000 description 27
- 108010010803 Gelatin Proteins 0.000 description 23
- 229920000159 gelatin Polymers 0.000 description 23
- 239000008273 gelatin Substances 0.000 description 23
- 235000019322 gelatine Nutrition 0.000 description 23
- 235000011852 gelatine desserts Nutrition 0.000 description 23
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 21
- 239000000243 solution Substances 0.000 description 20
- 239000002253 acid Substances 0.000 description 18
- 150000001875 compounds Chemical class 0.000 description 18
- 238000011161 development Methods 0.000 description 17
- 229920002554 vinyl polymer Polymers 0.000 description 15
- 239000011230 binding agent Substances 0.000 description 12
- 239000000839 emulsion Substances 0.000 description 12
- 239000000203 mixture Substances 0.000 description 12
- 150000003839 salts Chemical class 0.000 description 12
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 12
- 239000003795 chemical substances by application Substances 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 230000015572 biosynthetic process Effects 0.000 description 10
- 238000000576 coating method Methods 0.000 description 10
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 10
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 10
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 10
- 239000002904 solvent Substances 0.000 description 10
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 9
- 239000003638 chemical reducing agent Substances 0.000 description 9
- 238000003786 synthesis reaction Methods 0.000 description 9
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 9
- 238000004061 bleaching Methods 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 8
- 239000000975 dye Substances 0.000 description 8
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 8
- 150000003378 silver Chemical class 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 7
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 125000002947 alkylene group Chemical group 0.000 description 6
- 239000002585 base Substances 0.000 description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 6
- 239000003505 polymerization initiator Substances 0.000 description 6
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 5
- 206010070834 Sensitisation Diseases 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 125000000732 arylene group Chemical group 0.000 description 5
- 125000004429 atom Chemical group 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 5
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 5
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- 230000008313 sensitization Effects 0.000 description 5
- 239000011593 sulfur Substances 0.000 description 5
- 229910052717 sulfur Inorganic materials 0.000 description 5
- QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 description 4
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical group N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- 239000002202 Polyethylene glycol Substances 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 239000012190 activator Substances 0.000 description 4
- 125000003545 alkoxy group Chemical group 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 4
- 229910001864 baryta Inorganic materials 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 108700039708 galantide Proteins 0.000 description 4
- 125000005843 halogen group Chemical group 0.000 description 4
- 239000004816 latex Substances 0.000 description 4
- 229920000126 latex Polymers 0.000 description 4
- 239000011976 maleic acid Substances 0.000 description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 230000035945 sensitivity Effects 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 229940124530 sulfonamide Drugs 0.000 description 4
- 150000003456 sulfonamides Chemical class 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- WXTMDXOMEHJXQO-UHFFFAOYSA-N 2,5-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC(O)=CC=C1O WXTMDXOMEHJXQO-UHFFFAOYSA-N 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- WVKWKEWFTVEVCF-UHFFFAOYSA-N 2h-benzotriazole-4-sulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC2=NNN=C12 WVKWKEWFTVEVCF-UHFFFAOYSA-N 0.000 description 3
- PLYFWZGSBMDRKW-UHFFFAOYSA-N 2h-benzotriazole-4-sulfonic acid;silver Chemical compound [Ag].OS(=O)(=O)C1=CC=CC2=NNN=C12 PLYFWZGSBMDRKW-UHFFFAOYSA-N 0.000 description 3
- UVRCNEIYXSRHNT-UHFFFAOYSA-N 3-ethylpent-2-enamide Chemical compound CCC(CC)=CC(N)=O UVRCNEIYXSRHNT-UHFFFAOYSA-N 0.000 description 3
- SJVGFKBLUYAEOK-SFHVURJKSA-N 6-[4-[(3S)-3-(3,5-difluorophenyl)-3,4-dihydropyrazole-2-carbonyl]piperidin-1-yl]pyrimidine-4-carbonitrile Chemical compound FC=1C=C(C=C(C=1)F)[C@@H]1CC=NN1C(=O)C1CCN(CC1)C1=CC(=NC=N1)C#N SJVGFKBLUYAEOK-SFHVURJKSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- KXDAEFPNCMNJSK-UHFFFAOYSA-N Benzamide Chemical group NC(=O)C1=CC=CC=C1 KXDAEFPNCMNJSK-UHFFFAOYSA-N 0.000 description 3
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 150000003926 acrylamides Chemical class 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 125000001309 chloro group Chemical group Cl* 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 238000010556 emulsion polymerization method Methods 0.000 description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 description 3
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 125000001153 fluoro group Chemical group F* 0.000 description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910052751 metal Chemical group 0.000 description 3
- 239000002184 metal Chemical group 0.000 description 3
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 3
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 3
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- JEXVQSWXXUJEMA-UHFFFAOYSA-N pyrazol-3-one Chemical class O=C1C=CN=N1 JEXVQSWXXUJEMA-UHFFFAOYSA-N 0.000 description 3
- 239000010948 rhodium Substances 0.000 description 3
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 230000003595 spectral effect Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 2
- TUMNHQRORINJKE-UHFFFAOYSA-N 1,1-diethylurea Chemical compound CCN(CC)C(N)=O TUMNHQRORINJKE-UHFFFAOYSA-N 0.000 description 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- LUBJCRLGQSPQNN-UHFFFAOYSA-N 1-Phenylurea Chemical compound NC(=O)NC1=CC=CC=C1 LUBJCRLGQSPQNN-UHFFFAOYSA-N 0.000 description 2
- LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 description 2
- UZKWTJUDCOPSNM-UHFFFAOYSA-N 1-ethenoxybutane Chemical compound CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 2
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 2
- SGWZVZZVXOJRAQ-UHFFFAOYSA-N 2,6-Dimethyl-1,4-benzenediol Chemical compound CC1=CC(O)=CC(C)=C1O SGWZVZZVXOJRAQ-UHFFFAOYSA-N 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 description 2
- CDZAAIHWZYWBSS-UHFFFAOYSA-N 2-bromoethyl prop-2-enoate Chemical compound BrCCOC(=O)C=C CDZAAIHWZYWBSS-UHFFFAOYSA-N 0.000 description 2
- XUOKWZRAWBZOQM-UHFFFAOYSA-N 2-cyclohexylprop-2-enamide Chemical compound NC(=O)C(=C)C1CCCCC1 XUOKWZRAWBZOQM-UHFFFAOYSA-N 0.000 description 2
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 2
- KFNGWPXYNSJXOP-UHFFFAOYSA-N 3-(2-methylprop-2-enoyloxy)propane-1-sulfonic acid Chemical compound CC(=C)C(=O)OCCCS(O)(=O)=O KFNGWPXYNSJXOP-UHFFFAOYSA-N 0.000 description 2
- PIRPEUWCTMKABH-UHFFFAOYSA-N 4-methoxy-2-methylidenebutanamide Chemical compound COCCC(=C)C(N)=O PIRPEUWCTMKABH-UHFFFAOYSA-N 0.000 description 2
- PVKNQGWSRAGMNM-UHFFFAOYSA-N 5-amino-2-phenyl-1h-pyrazol-3-one Chemical compound N1C(N)=CC(=O)N1C1=CC=CC=C1 PVKNQGWSRAGMNM-UHFFFAOYSA-N 0.000 description 2
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- 239000004342 Benzoyl peroxide Substances 0.000 description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 2
- PCLIMKBDDGJMGD-UHFFFAOYSA-N N-bromosuccinimide Chemical compound BrN1C(=O)CCC1=O PCLIMKBDDGJMGD-UHFFFAOYSA-N 0.000 description 2
- JRNVZBWKYDBUCA-UHFFFAOYSA-N N-chlorosuccinimide Chemical compound ClN1C(=O)CCC1=O JRNVZBWKYDBUCA-UHFFFAOYSA-N 0.000 description 2
- LQZMLBORDGWNPD-UHFFFAOYSA-N N-iodosuccinimide Chemical compound IN1C(=O)CCC1=O LQZMLBORDGWNPD-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 2
- ISAKRJDGNUQOIC-UHFFFAOYSA-N Uracil Chemical compound O=C1C=CNC(=O)N1 ISAKRJDGNUQOIC-UHFFFAOYSA-N 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- 125000000738 acetamido group Chemical group [H]C([H])([H])C(=O)N([H])[*] 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 125000004422 alkyl sulphonamide group Chemical group 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- XSCHRSMBECNVNS-UHFFFAOYSA-N benzopyrazine Natural products N1=CC=NC2=CC=CC=C21 XSCHRSMBECNVNS-UHFFFAOYSA-N 0.000 description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- DIKBFYAXUHHXCS-UHFFFAOYSA-N bromoform Chemical compound BrC(Br)Br DIKBFYAXUHHXCS-UHFFFAOYSA-N 0.000 description 2
- FUSUHKVFWTUUBE-UHFFFAOYSA-N buten-2-one Chemical compound CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 2
- 125000002837 carbocyclic group Chemical group 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000004181 carboxyalkyl group Chemical group 0.000 description 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- ZEFVHSWKYCYFFL-UHFFFAOYSA-N diethyl 2-methylidenebutanedioate Chemical compound CCOC(=O)CC(=C)C(=O)OCC ZEFVHSWKYCYFFL-UHFFFAOYSA-N 0.000 description 2
- XSBSXJAYEPDGSF-UHFFFAOYSA-N diethyl 3,5-dimethyl-1h-pyrrole-2,4-dicarboxylate Chemical compound CCOC(=O)C=1NC(C)=C(C(=O)OCC)C=1C XSBSXJAYEPDGSF-UHFFFAOYSA-N 0.000 description 2
- 125000001240 enamine group Chemical group 0.000 description 2
- 229960005219 gentisic acid Drugs 0.000 description 2
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 2
- 150000008282 halocarbons Chemical class 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- LNCPIMCVTKXXOY-UHFFFAOYSA-N hexyl 2-methylprop-2-enoate Chemical compound CCCCCCOC(=O)C(C)=C LNCPIMCVTKXXOY-UHFFFAOYSA-N 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 150000007857 hydrazones Chemical class 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 2
- OKJPEAGHQZHRQV-UHFFFAOYSA-N iodoform Chemical compound IC(I)I OKJPEAGHQZHRQV-UHFFFAOYSA-N 0.000 description 2
- 125000005647 linker group Chemical group 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 2
- HRRDCWDFRIJIQZ-UHFFFAOYSA-N naphthalene-1,8-dicarboxylic acid Chemical compound C1=CC(C(O)=O)=C2C(C(=O)O)=CC=CC2=C1 HRRDCWDFRIJIQZ-UHFFFAOYSA-N 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical compound C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000001235 sensitizing effect Effects 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- 230000007480 spreading Effects 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- HNISBYCBIMPXKH-UHFFFAOYSA-N (1,1-dichloro-2-ethoxyethyl) prop-2-enoate Chemical compound CCOCC(Cl)(Cl)OC(=O)C=C HNISBYCBIMPXKH-UHFFFAOYSA-N 0.000 description 1
- GBVJQAULALBKDU-UHFFFAOYSA-N (1-bromo-2-methoxyethyl) prop-2-enoate Chemical compound COCC(Br)OC(=O)C=C GBVJQAULALBKDU-UHFFFAOYSA-N 0.000 description 1
- NGDOLKDENPCYIS-UHFFFAOYSA-N (2-chlorocyclohexyl) prop-2-enoate Chemical compound ClC1CCCCC1OC(=O)C=C NGDOLKDENPCYIS-UHFFFAOYSA-N 0.000 description 1
- MRIKSZXJKCQQFT-UHFFFAOYSA-N (3-hydroxy-2,2-dimethylpropyl) prop-2-enoate Chemical compound OCC(C)(C)COC(=O)C=C MRIKSZXJKCQQFT-UHFFFAOYSA-N 0.000 description 1
- QIVUCLWGARAQIO-OLIXTKCUSA-N (3s)-n-[(3s,5s,6r)-6-methyl-2-oxo-1-(2,2,2-trifluoroethyl)-5-(2,3,6-trifluorophenyl)piperidin-3-yl]-2-oxospiro[1h-pyrrolo[2,3-b]pyridine-3,6'-5,7-dihydrocyclopenta[b]pyridine]-3'-carboxamide Chemical compound C1([C@H]2[C@H](N(C(=O)[C@@H](NC(=O)C=3C=C4C[C@]5(CC4=NC=3)C3=CC=CN=C3NC5=O)C2)CC(F)(F)F)C)=C(F)C=CC(F)=C1F QIVUCLWGARAQIO-OLIXTKCUSA-N 0.000 description 1
- MPUZDPBYKVEHNH-BQYQJAHWSA-N (e)-2-methyl-3-phenylprop-2-enamide Chemical compound NC(=O)C(/C)=C/C1=CC=CC=C1 MPUZDPBYKVEHNH-BQYQJAHWSA-N 0.000 description 1
- GVTLFGJNTIRUEG-ZHACJKMWSA-N (e)-n-(3-methoxyphenyl)-3-phenylprop-2-enamide Chemical compound COC1=CC=CC(NC(=O)\C=C\C=2C=CC=CC=2)=C1 GVTLFGJNTIRUEG-ZHACJKMWSA-N 0.000 description 1
- HGRZLIGHKHRTRE-UHFFFAOYSA-N 1,2,3,4-tetrabromobutane Chemical compound BrCC(Br)C(Br)CBr HGRZLIGHKHRTRE-UHFFFAOYSA-N 0.000 description 1
- UDATXMIGEVPXTR-UHFFFAOYSA-N 1,2,4-triazolidine-3,5-dione Chemical compound O=C1NNC(=O)N1 UDATXMIGEVPXTR-UHFFFAOYSA-N 0.000 description 1
- GUMZPHOQHLZJOY-UHFFFAOYSA-N 1,3-oxazine-2,4-dione Chemical compound O=C1C=COC(=O)N1 GUMZPHOQHLZJOY-UHFFFAOYSA-N 0.000 description 1
- ODIRBFFBCSTPTO-UHFFFAOYSA-N 1,3-selenazole Chemical compound C1=C[se]C=N1 ODIRBFFBCSTPTO-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- BYQGKCXVBUPKOO-UHFFFAOYSA-N 1,4-dioctylcyclohexa-2,5-diene-1,4-diol Chemical compound CCCCCCCCC1(O)C=CC(O)(CCCCCCCC)C=C1 BYQGKCXVBUPKOO-UHFFFAOYSA-N 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- ZPANWZBSGMDWON-UHFFFAOYSA-N 1-[(2-hydroxynaphthalen-1-yl)methyl]naphthalen-2-ol Chemical compound C1=CC=C2C(CC3=C4C=CC=CC4=CC=C3O)=C(O)C=CC2=C1 ZPANWZBSGMDWON-UHFFFAOYSA-N 0.000 description 1
- YAOJJEJGPZRYJF-UHFFFAOYSA-N 1-ethenoxyhexane Chemical compound CCCCCCOC=C YAOJJEJGPZRYJF-UHFFFAOYSA-N 0.000 description 1
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 1
- GIVBQSUFWURSOS-UHFFFAOYSA-N 1-ethenyltriazole Chemical compound C=CN1C=CN=N1 GIVBQSUFWURSOS-UHFFFAOYSA-N 0.000 description 1
- IQIOOZJZTRAXTO-UHFFFAOYSA-M 1-ethyl-2H-1,3-thiazol-2-ylium bromide Chemical compound [Br-].CCS1=CC=N[CH+]1 IQIOOZJZTRAXTO-UHFFFAOYSA-M 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- KUIZKZHDMPERHR-UHFFFAOYSA-N 1-phenylprop-2-en-1-one Chemical compound C=CC(=O)C1=CC=CC=C1 KUIZKZHDMPERHR-UHFFFAOYSA-N 0.000 description 1
- CBQFBEBEBCHTBK-UHFFFAOYSA-N 1-phenylprop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)C(C=C)C1=CC=CC=C1 CBQFBEBEBCHTBK-UHFFFAOYSA-N 0.000 description 1
- ZXXYGKBYTSVDSY-UHFFFAOYSA-N 1-sulfanyl-4,5-dihydrotriazole Chemical compound SN1CCN=N1 ZXXYGKBYTSVDSY-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- ULEQVBQWYCGDON-UHFFFAOYSA-N 1h-benzimidazole;silver Chemical compound [Ag].C1=CC=C2NC=NC2=C1 ULEQVBQWYCGDON-UHFFFAOYSA-N 0.000 description 1
- IWDUDCDZGOLTTJ-UHFFFAOYSA-N 1h-imidazole;silver Chemical compound [Ag].C1=CNC=N1 IWDUDCDZGOLTTJ-UHFFFAOYSA-N 0.000 description 1
- VLPZUANQXMDIPV-UHFFFAOYSA-N 1h-pyrazole;silver Chemical compound [Ag].C=1C=NNC=1 VLPZUANQXMDIPV-UHFFFAOYSA-N 0.000 description 1
- AVRPFRMDMNDIDH-UHFFFAOYSA-N 1h-quinazolin-2-one Chemical compound C1=CC=CC2=NC(O)=NC=C21 AVRPFRMDMNDIDH-UHFFFAOYSA-N 0.000 description 1
- CISIJYCKDJSTMX-UHFFFAOYSA-N 2,2-dichloroethenylbenzene Chemical compound ClC(Cl)=CC1=CC=CC=C1 CISIJYCKDJSTMX-UHFFFAOYSA-N 0.000 description 1
- SNTWKPAKVQFCCF-UHFFFAOYSA-N 2,3-dihydro-1h-triazole Chemical compound N1NC=CN1 SNTWKPAKVQFCCF-UHFFFAOYSA-N 0.000 description 1
- GLDQAMYCGOIJDV-UHFFFAOYSA-N 2,3-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC=CC(O)=C1O GLDQAMYCGOIJDV-UHFFFAOYSA-N 0.000 description 1
- QHPKIUDQDCWRKO-UHFFFAOYSA-N 2,6-ditert-butyl-4-[2-(3,5-ditert-butyl-4-hydroxyphenyl)propan-2-yl]phenol Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(C(C)(C)C=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 QHPKIUDQDCWRKO-UHFFFAOYSA-N 0.000 description 1
- PYMWDAQVSJGRIA-UHFFFAOYSA-N 2-(1-bromo-6-methylcyclohexa-2,4-dien-1-yl)acetamide Chemical compound CC1C=CC=CC1(Br)CC(N)=O PYMWDAQVSJGRIA-UHFFFAOYSA-N 0.000 description 1
- DYNQKTWPOTTWGS-UHFFFAOYSA-N 2-(1-bromo-6-methylcyclohexa-2,4-dien-1-yl)sulfonylacetamide Chemical compound CC1C=CC=CC1(Br)S(=O)(=O)CC(N)=O DYNQKTWPOTTWGS-UHFFFAOYSA-N 0.000 description 1
- AGUJUBACOOIWDV-UHFFFAOYSA-N 2-(1-hydroxynaphthalen-2-yl)naphthalen-1-ol Chemical group C1=CC=CC2=C(O)C(C3=C(C4=CC=CC=C4C=C3)O)=CC=C21 AGUJUBACOOIWDV-UHFFFAOYSA-N 0.000 description 1
- QGTBRAFPWNISIJ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethyl 2-methylprop-2-enoate Chemical compound CCCCOCCOCCOC(=O)C(C)=C QGTBRAFPWNISIJ-UHFFFAOYSA-N 0.000 description 1
- WFTWWOCWRSUGAW-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl 2-methylprop-2-enoate Chemical compound CCOCCOCCOC(=O)C(C)=C WFTWWOCWRSUGAW-UHFFFAOYSA-N 0.000 description 1
- DAVVKEZTUOGEAK-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethyl 2-methylprop-2-enoate Chemical compound COCCOCCOC(=O)C(C)=C DAVVKEZTUOGEAK-UHFFFAOYSA-N 0.000 description 1
- HKUDVOHICUCJPU-UHFFFAOYSA-N 2-(2-methylprop-2-enoylamino)propane-1-sulfonic acid Chemical compound OS(=O)(=O)CC(C)NC(=O)C(C)=C HKUDVOHICUCJPU-UHFFFAOYSA-N 0.000 description 1
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 description 1
- RUYYZQCJUGZUCW-UHFFFAOYSA-N 2-(prop-2-enoylamino)ethyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OCCNC(=O)C=C RUYYZQCJUGZUCW-UHFFFAOYSA-N 0.000 description 1
- MVYVKSBVZFBBPL-UHFFFAOYSA-N 2-(prop-2-enoylamino)propane-1-sulfonic acid Chemical compound OS(=O)(=O)CC(C)NC(=O)C=C MVYVKSBVZFBBPL-UHFFFAOYSA-N 0.000 description 1
- NREKJIIPVVKRNO-UHFFFAOYSA-N 2-(tribromomethylsulfonyl)-1,3-benzothiazole Chemical compound C1=CC=C2SC(S(=O)(=O)C(Br)(Br)Br)=NC2=C1 NREKJIIPVVKRNO-UHFFFAOYSA-N 0.000 description 1
- 229920000536 2-Acrylamido-2-methylpropane sulfonic acid Polymers 0.000 description 1
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 description 1
- QMYCJCOPYOPWTI-UHFFFAOYSA-N 2-[(1-amino-1-imino-2-methylpropan-2-yl)diazenyl]-2-methylpropanimidamide;hydron;chloride Chemical compound Cl.NC(=N)C(C)(C)N=NC(C)(C)C(N)=N QMYCJCOPYOPWTI-UHFFFAOYSA-N 0.000 description 1
- BBFDQRZRKYWUHY-UHFFFAOYSA-N 2-[(1-hydroxynaphthalen-2-yl)methyl]naphthalen-1-ol Chemical class C1=CC2=CC=CC=C2C(O)=C1CC1=CC=C(C=CC=C2)C2=C1O BBFDQRZRKYWUHY-UHFFFAOYSA-N 0.000 description 1
- SZAQZZKNQILGPU-UHFFFAOYSA-N 2-[1-(2-hydroxy-3,5-dimethylphenyl)-2-methylpropyl]-4,6-dimethylphenol Chemical compound C=1C(C)=CC(C)=C(O)C=1C(C(C)C)C1=CC(C)=CC(C)=C1O SZAQZZKNQILGPU-UHFFFAOYSA-N 0.000 description 1
- UFIOPCXETLAGLR-UHFFFAOYSA-N 2-acetyloxyethyl prop-2-enoate Chemical compound CC(=O)OCCOC(=O)C=C UFIOPCXETLAGLR-UHFFFAOYSA-N 0.000 description 1
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 1
- ICGLGDINCXDWJB-UHFFFAOYSA-N 2-benzylprop-2-enamide Chemical compound NC(=O)C(=C)CC1=CC=CC=C1 ICGLGDINCXDWJB-UHFFFAOYSA-N 0.000 description 1
- LDLCZOVUSADOIV-UHFFFAOYSA-N 2-bromoethanol Chemical compound OCCBr LDLCZOVUSADOIV-UHFFFAOYSA-N 0.000 description 1
- MARXMDRWROUXMD-UHFFFAOYSA-N 2-bromoisoindole-1,3-dione Chemical compound C1=CC=C2C(=O)N(Br)C(=O)C2=C1 MARXMDRWROUXMD-UHFFFAOYSA-N 0.000 description 1
- CQJNLNKTOGXYCH-UHFFFAOYSA-N 2-bromophthalazin-1-one Chemical compound C1=CC=C2C(=O)N(Br)N=CC2=C1 CQJNLNKTOGXYCH-UHFFFAOYSA-N 0.000 description 1
- DJKKWVGWYCKUFC-UHFFFAOYSA-N 2-butoxyethyl 2-methylprop-2-enoate Chemical compound CCCCOCCOC(=O)C(C)=C DJKKWVGWYCKUFC-UHFFFAOYSA-N 0.000 description 1
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
- KSBRTGXRNZVPAT-UHFFFAOYSA-N 2-chlorophthalazin-1-one Chemical compound C1=CC=C2C(=O)N(Cl)N=CC2=C1 KSBRTGXRNZVPAT-UHFFFAOYSA-N 0.000 description 1
- AEPWOCLBLLCOGZ-UHFFFAOYSA-N 2-cyanoethyl prop-2-enoate Chemical compound C=CC(=O)OCCC#N AEPWOCLBLLCOGZ-UHFFFAOYSA-N 0.000 description 1
- JWCDUUFOAZFFMX-UHFFFAOYSA-N 2-ethenoxy-n,n-dimethylethanamine Chemical compound CN(C)CCOC=C JWCDUUFOAZFFMX-UHFFFAOYSA-N 0.000 description 1
- MLMGJTAJUDSUKA-UHFFFAOYSA-N 2-ethenyl-1h-imidazole Chemical class C=CC1=NC=CN1 MLMGJTAJUDSUKA-UHFFFAOYSA-N 0.000 description 1
- MOXDGMSQFFMNHA-UHFFFAOYSA-N 2-hydroxybenzenesulfonamide Chemical compound NS(=O)(=O)C1=CC=CC=C1O MOXDGMSQFFMNHA-UHFFFAOYSA-N 0.000 description 1
- KTWCUGUUDHJVIH-UHFFFAOYSA-N 2-hydroxybenzo[de]isoquinoline-1,3-dione Chemical compound C1=CC(C(N(O)C2=O)=O)=C3C2=CC=CC3=C1 KTWCUGUUDHJVIH-UHFFFAOYSA-N 0.000 description 1
- IEVADDDOVGMCSI-UHFFFAOYSA-N 2-hydroxybutyl 2-methylprop-2-enoate Chemical compound CCC(O)COC(=O)C(C)=C IEVADDDOVGMCSI-UHFFFAOYSA-N 0.000 description 1
- VWJAVBOLCVPIAK-UHFFFAOYSA-N 2-methoxybutyl 2-methylprop-2-enoate Chemical compound CCC(OC)COC(=O)C(C)=C VWJAVBOLCVPIAK-UHFFFAOYSA-N 0.000 description 1
- HFCUBKYHMMPGBY-UHFFFAOYSA-N 2-methoxyethyl prop-2-enoate Chemical compound COCCOC(=O)C=C HFCUBKYHMMPGBY-UHFFFAOYSA-N 0.000 description 1
- FSAHAOQXCSZZHG-UHFFFAOYSA-N 2-methyl-2-(2-methylprop-2-enoylamino)butane-1-sulfonic acid Chemical compound OS(=O)(=O)CC(C)(CC)NC(=O)C(C)=C FSAHAOQXCSZZHG-UHFFFAOYSA-N 0.000 description 1
- VSSGDAWBDKMCMI-UHFFFAOYSA-N 2-methyl-2-(2-methylprop-2-enoylamino)propane-1-sulfonic acid Chemical compound CC(=C)C(=O)NC(C)(C)CS(O)(=O)=O VSSGDAWBDKMCMI-UHFFFAOYSA-N 0.000 description 1
- SYPKYPCQNDILJH-UHFFFAOYSA-N 2-methyl-2-(prop-2-enoylamino)butane-1-sulfonic acid Chemical compound OS(=O)(=O)CC(C)(CC)NC(=O)C=C SYPKYPCQNDILJH-UHFFFAOYSA-N 0.000 description 1
- AEBNPEXFDZBTIB-UHFFFAOYSA-N 2-methyl-4-phenylbut-2-enamide Chemical compound NC(=O)C(C)=CCC1=CC=CC=C1 AEBNPEXFDZBTIB-UHFFFAOYSA-N 0.000 description 1
- KFTHUBZIEMOORC-UHFFFAOYSA-N 2-methylbut-2-enamide Chemical compound CC=C(C)C(N)=O KFTHUBZIEMOORC-UHFFFAOYSA-N 0.000 description 1
- ZXQOBTQMLMZFOW-UHFFFAOYSA-N 2-methylhex-2-enamide Chemical compound CCCC=C(C)C(N)=O ZXQOBTQMLMZFOW-UHFFFAOYSA-N 0.000 description 1
- LPNSCOVIJFIXTJ-UHFFFAOYSA-N 2-methylidenebutanamide Chemical compound CCC(=C)C(N)=O LPNSCOVIJFIXTJ-UHFFFAOYSA-N 0.000 description 1
- GASMGDMKGYYAHY-UHFFFAOYSA-N 2-methylidenehexanamide Chemical compound CCCCC(=C)C(N)=O GASMGDMKGYYAHY-UHFFFAOYSA-N 0.000 description 1
- YICILWNDMQTUIY-UHFFFAOYSA-N 2-methylidenepentanamide Chemical compound CCCC(=C)C(N)=O YICILWNDMQTUIY-UHFFFAOYSA-N 0.000 description 1
- BTOVVHWKPVSLBI-UHFFFAOYSA-N 2-methylprop-1-enylbenzene Chemical compound CC(C)=CC1=CC=CC=C1 BTOVVHWKPVSLBI-UHFFFAOYSA-N 0.000 description 1
- ODPPVFMETNCIRW-UHFFFAOYSA-N 2-methylprop-2-enoyloxymethanesulfonic acid Chemical compound CC(=C)C(=O)OCS(O)(=O)=O ODPPVFMETNCIRW-UHFFFAOYSA-N 0.000 description 1
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 description 1
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 description 1
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 1
- IMOLAGKJZFODRK-UHFFFAOYSA-N 2-phenylprop-2-enamide Chemical compound NC(=O)C(=C)C1=CC=CC=C1 IMOLAGKJZFODRK-UHFFFAOYSA-N 0.000 description 1
- SEILKFZTLVMHRR-UHFFFAOYSA-N 2-phosphonooxyethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOP(O)(O)=O SEILKFZTLVMHRR-UHFFFAOYSA-N 0.000 description 1
- GQTFHSAAODFMHB-UHFFFAOYSA-N 2-prop-2-enoyloxyethanesulfonic acid Chemical compound OS(=O)(=O)CCOC(=O)C=C GQTFHSAAODFMHB-UHFFFAOYSA-N 0.000 description 1
- JPXZAISSLVEZTK-UHFFFAOYSA-N 2-propan-2-yloxyethyl 2-methylprop-2-enoate Chemical compound CC(C)OCCOC(=O)C(C)=C JPXZAISSLVEZTK-UHFFFAOYSA-N 0.000 description 1
- UGWULZWUXSCWPX-UHFFFAOYSA-N 2-sulfanylideneimidazolidin-4-one Chemical class O=C1CNC(=S)N1 UGWULZWUXSCWPX-UHFFFAOYSA-N 0.000 description 1
- UHSLAFBDUFODHO-UHFFFAOYSA-N 2-tert-butyl-4-[2-(3-tert-butyl-4-hydroxy-5-methylphenyl)propan-2-yl]-6-methylphenol Chemical compound CC(C)(C)C1=C(O)C(C)=CC(C(C)(C)C=2C=C(C(O)=C(C)C=2)C(C)(C)C)=C1 UHSLAFBDUFODHO-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- DNMNQAUVYXEIKX-UHFFFAOYSA-N 2H-benzotriazol-4-ol silver Chemical compound [Ag].Oc1cccc2[nH]nnc12 DNMNQAUVYXEIKX-UHFFFAOYSA-N 0.000 description 1
- CMLFRMDBDNHMRA-UHFFFAOYSA-N 2h-1,2-benzoxazine Chemical compound C1=CC=C2C=CNOC2=C1 CMLFRMDBDNHMRA-UHFFFAOYSA-N 0.000 description 1
- XSFHICWNEBCMNN-UHFFFAOYSA-N 2h-benzotriazol-5-amine Chemical compound NC1=CC=C2NN=NC2=C1 XSFHICWNEBCMNN-UHFFFAOYSA-N 0.000 description 1
- GUOVBFFLXKJFEE-UHFFFAOYSA-N 2h-benzotriazole-5-carboxylic acid Chemical compound C1=C(C(=O)O)C=CC2=NNN=C21 GUOVBFFLXKJFEE-UHFFFAOYSA-N 0.000 description 1
- VAVIJGPIFNIPSG-UHFFFAOYSA-N 2h-benzotriazole-5-carboxylic acid;silver Chemical compound [Ag].C1=C(C(=O)O)C=CC2=NNN=C21 VAVIJGPIFNIPSG-UHFFFAOYSA-N 0.000 description 1
- IBWXIFXUDGADCV-UHFFFAOYSA-N 2h-benzotriazole;silver Chemical compound [Ag].C1=CC=C2NN=NC2=C1 IBWXIFXUDGADCV-UHFFFAOYSA-N 0.000 description 1
- XOHUESSDMRKYEV-UHFFFAOYSA-N 2h-phthalazin-1-one;silver Chemical compound [Ag].C1=CC=C2C(=O)NN=CC2=C1 XOHUESSDMRKYEV-UHFFFAOYSA-N 0.000 description 1
- OAOZZYBUAWEDRA-UHFFFAOYSA-N 3,4-dimethylidenehexane Chemical compound CCC(=C)C(=C)CC OAOZZYBUAWEDRA-UHFFFAOYSA-N 0.000 description 1
- NYYRRBOMNHUCLB-UHFFFAOYSA-N 3-chloro-n,n-dimethylpropan-1-amine Chemical class CN(C)CCCCl NYYRRBOMNHUCLB-UHFFFAOYSA-N 0.000 description 1
- NWKKCUWIMOZYOO-UHFFFAOYSA-N 3-methoxybutyl 2-methylprop-2-enoate Chemical compound COC(C)CCOC(=O)C(C)=C NWKKCUWIMOZYOO-UHFFFAOYSA-N 0.000 description 1
- OGMRHLUHIHYVRU-UHFFFAOYSA-M 3-methyl-1,3-thiazol-3-ium;bromide Chemical compound [Br-].C[N+]=1C=CSC=1 OGMRHLUHIHYVRU-UHFFFAOYSA-M 0.000 description 1
- WHNPOQXWAMXPTA-UHFFFAOYSA-N 3-methylbut-2-enamide Chemical compound CC(C)=CC(N)=O WHNPOQXWAMXPTA-UHFFFAOYSA-N 0.000 description 1
- AMHVHKFKFDBCTE-UHFFFAOYSA-N 3h-1,3-benzoxazole-2-thione;silver Chemical compound [Ag].C1=CC=C2OC(S)=NC2=C1 AMHVHKFKFDBCTE-UHFFFAOYSA-N 0.000 description 1
- ABJQKDJOYSQVFX-UHFFFAOYSA-N 4-aminonaphthalen-1-ol Chemical compound C1=CC=C2C(N)=CC=C(O)C2=C1 ABJQKDJOYSQVFX-UHFFFAOYSA-N 0.000 description 1
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
- VVAAYFMMXYRORI-UHFFFAOYSA-N 4-butoxy-2-methylidene-4-oxobutanoic acid Chemical compound CCCCOC(=O)CC(=C)C(O)=O VVAAYFMMXYRORI-UHFFFAOYSA-N 0.000 description 1
- HIPMXTORBGIBCC-UHFFFAOYSA-N 4-chlorobut-1-enylbenzene Chemical compound ClCCC=CC1=CC=CC=C1 HIPMXTORBGIBCC-UHFFFAOYSA-N 0.000 description 1
- LZHLUTZGFZAYCH-UHFFFAOYSA-N 4-cyano-2-methylidenebutanamide Chemical compound NC(=O)C(=C)CCC#N LZHLUTZGFZAYCH-UHFFFAOYSA-N 0.000 description 1
- RTTAGBVNSDJDTE-UHFFFAOYSA-N 4-ethoxy-2-methylidene-4-oxobutanoic acid Chemical compound CCOC(=O)CC(=C)C(O)=O RTTAGBVNSDJDTE-UHFFFAOYSA-N 0.000 description 1
- HFGHRUCCKVYFKL-UHFFFAOYSA-N 4-ethoxy-2-piperazin-1-yl-7-pyridin-4-yl-5h-pyrimido[5,4-b]indole Chemical compound C1=C2NC=3C(OCC)=NC(N4CCNCC4)=NC=3C2=CC=C1C1=CC=NC=C1 HFGHRUCCKVYFKL-UHFFFAOYSA-N 0.000 description 1
- PBMWEQHOZPTUQQ-UHFFFAOYSA-N 4-hydroxy-2-methylbut-2-enamide Chemical compound NC(=O)C(C)=CCO PBMWEQHOZPTUQQ-UHFFFAOYSA-N 0.000 description 1
- SXIFAEWFOJETOA-UHFFFAOYSA-N 4-hydroxy-butyl Chemical group [CH2]CCCO SXIFAEWFOJETOA-UHFFFAOYSA-N 0.000 description 1
- RTANHMOFHGSZQO-UHFFFAOYSA-N 4-methoxy-2,4-dimethylpentanenitrile Chemical compound COC(C)(C)CC(C)C#N RTANHMOFHGSZQO-UHFFFAOYSA-N 0.000 description 1
- OIYTYGOUZOARSH-UHFFFAOYSA-N 4-methoxy-2-methylidene-4-oxobutanoic acid Chemical compound COC(=O)CC(=C)C(O)=O OIYTYGOUZOARSH-UHFFFAOYSA-N 0.000 description 1
- LVGSUQNJVOIUIW-UHFFFAOYSA-N 5-(dimethylamino)-2-methylpent-2-enamide Chemical compound CN(C)CCC=C(C)C(N)=O LVGSUQNJVOIUIW-UHFFFAOYSA-N 0.000 description 1
- AFQMMWNCTDMSBG-UHFFFAOYSA-N 5-chloro-2h-benzotriazole;silver Chemical compound [Ag].ClC1=CC=C2NN=NC2=C1 AFQMMWNCTDMSBG-UHFFFAOYSA-N 0.000 description 1
- INRQKLGGIVSJRR-UHFFFAOYSA-N 5-hydroxypentyl prop-2-enoate Chemical compound OCCCCCOC(=O)C=C INRQKLGGIVSJRR-UHFFFAOYSA-N 0.000 description 1
- FJBXHJCLTSWMLN-UHFFFAOYSA-N 5-methoxy-2h-benzotriazole;silver Chemical compound [Ag].C1=C(OC)C=CC2=NNN=C21 FJBXHJCLTSWMLN-UHFFFAOYSA-N 0.000 description 1
- RYHAZBFRQQCSOJ-UHFFFAOYSA-N 5-methoxypent-1-en-3-one Chemical class COCCC(=O)C=C RYHAZBFRQQCSOJ-UHFFFAOYSA-N 0.000 description 1
- KEZABYZKUMNECW-UHFFFAOYSA-N 5-methylhexa-1,2,3,5-tetraene Chemical compound CC(=C)C=C=C=C KEZABYZKUMNECW-UHFFFAOYSA-N 0.000 description 1
- BBGRQUUSRRKFSS-UHFFFAOYSA-N 5-nitro-2h-benzotriazole;silver Chemical compound [Ag].C1=C([N+](=O)[O-])C=CC2=NNN=C21 BBGRQUUSRRKFSS-UHFFFAOYSA-N 0.000 description 1
- NUXLDNTZFXDNBA-UHFFFAOYSA-N 6-bromo-2-methyl-4h-1,4-benzoxazin-3-one Chemical compound C1=C(Br)C=C2NC(=O)C(C)OC2=C1 NUXLDNTZFXDNBA-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- KHBQMWCZKVMBLN-UHFFFAOYSA-N Benzenesulfonamide Chemical group NS(=O)(=O)C1=CC=CC=C1 KHBQMWCZKVMBLN-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- AXVCDCGTJGNMKM-UHFFFAOYSA-L C(C=1C(C(=O)[O-])=CC=CC1)(=O)[O-].[Ag+2] Chemical compound C(C=1C(C(=O)[O-])=CC=CC1)(=O)[O-].[Ag+2] AXVCDCGTJGNMKM-UHFFFAOYSA-L 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 244000168525 Croton tiglium Species 0.000 description 1
- IEPRKVQEAMIZSS-UHFFFAOYSA-N Di-Et ester-Fumaric acid Natural products CCOC(=O)C=CC(=O)OCC IEPRKVQEAMIZSS-UHFFFAOYSA-N 0.000 description 1
- IEPRKVQEAMIZSS-WAYWQWQTSA-N Diethyl maleate Chemical compound CCOC(=O)\C=C/C(=O)OCC IEPRKVQEAMIZSS-WAYWQWQTSA-N 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- XLYMOEINVGRTEX-ARJAWSKDSA-N Ethyl hydrogen fumarate Chemical compound CCOC(=O)\C=C/C(O)=O XLYMOEINVGRTEX-ARJAWSKDSA-N 0.000 description 1
- 206010073306 Exposure to radiation Diseases 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Natural products OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 1
- DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- 150000000996 L-ascorbic acids Chemical class 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920001213 Polysorbate 20 Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 229910021612 Silver iodide Inorganic materials 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 description 1
- LCXXNKZQVOXMEH-UHFFFAOYSA-N Tetrahydrofurfuryl methacrylate Chemical compound CC(=C)C(=O)OCC1CCCO1 LCXXNKZQVOXMEH-UHFFFAOYSA-N 0.000 description 1
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 1
- SPBCUHSBNAEWRE-UHFFFAOYSA-N [Ag].C(CCCC=C/CC=C/CC=C/CC=C/CCCCC)(=O)O Chemical compound [Ag].C(CCCC=C/CC=C/CC=C/CC=C/CCCCC)(=O)O SPBCUHSBNAEWRE-UHFFFAOYSA-N 0.000 description 1
- HOLVRJRSWZOAJU-UHFFFAOYSA-N [Ag].ICl Chemical compound [Ag].ICl HOLVRJRSWZOAJU-UHFFFAOYSA-N 0.000 description 1
- XEIPQVVAVOUIOP-UHFFFAOYSA-N [Au]=S Chemical compound [Au]=S XEIPQVVAVOUIOP-UHFFFAOYSA-N 0.000 description 1
- NZHXEWZGTQSYJM-UHFFFAOYSA-N [bromo(diphenyl)methyl]benzene Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)(Br)C1=CC=CC=C1 NZHXEWZGTQSYJM-UHFFFAOYSA-N 0.000 description 1
- PLPDMHMCKFCIOU-UHFFFAOYSA-N [chloro-[chloro(phenyl)methyl]peroxymethyl]benzene Chemical compound C=1C=CC=CC=1C(Cl)OOC(Cl)C1=CC=CC=C1 PLPDMHMCKFCIOU-UHFFFAOYSA-N 0.000 description 1
- CXSXCWXUCMJUGI-UHFFFAOYSA-N [methoxy(phenyl)methyl] prop-2-enoate Chemical compound C=CC(=O)OC(OC)C1=CC=CC=C1 CXSXCWXUCMJUGI-UHFFFAOYSA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 125000004453 alkoxycarbonyl group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000004390 alkyl sulfonyl group Chemical group 0.000 description 1
- 125000004414 alkyl thio group Chemical group 0.000 description 1
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical class OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001409 amidines Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000003927 aminopyridines Chemical class 0.000 description 1
- 150000005010 aminoquinolines Chemical class 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 229940051880 analgesics and antipyretics pyrazolones Drugs 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 125000004391 aryl sulfonyl group Chemical group 0.000 description 1
- 125000004421 aryl sulphonamide group Chemical group 0.000 description 1
- 125000004104 aryloxy group Chemical group 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 125000001164 benzothiazolyl group Chemical group S1C(=NC2=C1C=CC=C2)* 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- GCTPMLUUWLLESL-UHFFFAOYSA-N benzyl prop-2-enoate Chemical compound C=CC(=O)OCC1=CC=CC=C1 GCTPMLUUWLLESL-UHFFFAOYSA-N 0.000 description 1
- UUZYBYIOAZTMGC-UHFFFAOYSA-M benzyl(trimethyl)azanium;bromide Chemical compound [Br-].C[N+](C)(C)CC1=CC=CC=C1 UUZYBYIOAZTMGC-UHFFFAOYSA-M 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
- 125000002619 bicyclic group Chemical group 0.000 description 1
- YXVFYQXJAXKLAK-UHFFFAOYSA-N biphenyl-4-ol Chemical compound C1=CC(O)=CC=C1C1=CC=CC=C1 YXVFYQXJAXKLAK-UHFFFAOYSA-N 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 229950005228 bromoform Drugs 0.000 description 1
- VTTONGPRPXSUTJ-UHFFFAOYSA-N bufotenin Chemical compound C1=C(O)C=C2C(CCN(C)C)=CNC2=C1 VTTONGPRPXSUTJ-UHFFFAOYSA-N 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 description 1
- 150000001661 cadmium Chemical class 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 229920006217 cellulose acetate butyrate Polymers 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- AJPXTSMULZANCB-UHFFFAOYSA-N chlorohydroquinone Chemical compound OC1=CC=C(O)C(Cl)=C1 AJPXTSMULZANCB-UHFFFAOYSA-N 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 125000000853 cresyl group Chemical group C1(=CC=C(C=C1)C)* 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical class C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- KBLWLMPSVYBVDK-UHFFFAOYSA-N cyclohexyl prop-2-enoate Chemical compound C=CC(=O)OC1CCCCC1 KBLWLMPSVYBVDK-UHFFFAOYSA-N 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- RWYFURDDADFSHT-RBBHPAOJSA-N diane Chemical compound OC1=CC=C2[C@H]3CC[C@](C)([C@](CC4)(O)C#C)[C@@H]4[C@@H]3CCC2=C1.C1=C(Cl)C2=CC(=O)[C@@H]3CC3[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@@](C(C)=O)(OC(=O)C)[C@@]1(C)CC2 RWYFURDDADFSHT-RBBHPAOJSA-N 0.000 description 1
- JBSLOWBPDRZSMB-BQYQJAHWSA-N dibutyl (e)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C\C(=O)OCCCC JBSLOWBPDRZSMB-BQYQJAHWSA-N 0.000 description 1
- JBSLOWBPDRZSMB-FPLPWBNLSA-N dibutyl (z)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C/C(=O)OCCCC JBSLOWBPDRZSMB-FPLPWBNLSA-N 0.000 description 1
- OGVXYCDTRMDYOG-UHFFFAOYSA-N dibutyl 2-methylidenebutanedioate Chemical compound CCCCOC(=O)CC(=C)C(=O)OCCCC OGVXYCDTRMDYOG-UHFFFAOYSA-N 0.000 description 1
- 229940120124 dichloroacetate Drugs 0.000 description 1
- JXTHNDFMNIQAHM-UHFFFAOYSA-N dichloroacetic acid Chemical compound OC(=O)C(Cl)Cl JXTHNDFMNIQAHM-UHFFFAOYSA-N 0.000 description 1
- IEPRKVQEAMIZSS-AATRIKPKSA-N diethyl fumarate Chemical compound CCOC(=O)\C=C\C(=O)OCC IEPRKVQEAMIZSS-AATRIKPKSA-N 0.000 description 1
- ZWWQRMFIZFPUAA-UHFFFAOYSA-N dimethyl 2-methylidenebutanedioate Chemical compound COC(=O)CC(=C)C(=O)OC ZWWQRMFIZFPUAA-UHFFFAOYSA-N 0.000 description 1
- LDCRTTXIJACKKU-ONEGZZNKSA-N dimethyl fumarate Chemical compound COC(=O)\C=C\C(=O)OC LDCRTTXIJACKKU-ONEGZZNKSA-N 0.000 description 1
- 229960004419 dimethyl fumarate Drugs 0.000 description 1
- OEIWPNWSDYFMIL-UHFFFAOYSA-N dioctyl benzene-1,4-dicarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C=C1 OEIWPNWSDYFMIL-UHFFFAOYSA-N 0.000 description 1
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- YHAIUSTWZPMYGG-UHFFFAOYSA-L disodium;2,2-dioctyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCCCC(C([O-])=O)(C(C([O-])=O)S(O)(=O)=O)CCCCCCCC YHAIUSTWZPMYGG-UHFFFAOYSA-L 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 229930004069 diterpene Natural products 0.000 description 1
- 150000004141 diterpene derivatives Chemical class 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 description 1
- WNMORWGTPVWAIB-UHFFFAOYSA-N ethenyl 2-methylpropanoate Chemical compound CC(C)C(=O)OC=C WNMORWGTPVWAIB-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 125000005670 ethenylalkyl group Chemical group 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- GXRZIMHKGDIBEW-UHFFFAOYSA-N ethinamate Chemical compound NC(=O)OC1(C#C)CCCCC1 GXRZIMHKGDIBEW-UHFFFAOYSA-N 0.000 description 1
- 229960002209 ethinamate Drugs 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- VUFOSBDICLTFMS-UHFFFAOYSA-M ethyl-hexadecyl-dimethylazanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)CC VUFOSBDICLTFMS-UHFFFAOYSA-M 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- XLYMOEINVGRTEX-UHFFFAOYSA-N fumaric acid monoethyl ester Natural products CCOC(=O)C=CC(O)=O XLYMOEINVGRTEX-UHFFFAOYSA-N 0.000 description 1
- NKHAVTQWNUWKEO-UHFFFAOYSA-N fumaric acid monomethyl ester Natural products COC(=O)C=CC(O)=O NKHAVTQWNUWKEO-UHFFFAOYSA-N 0.000 description 1
- DWXAVNJYFLGAEF-UHFFFAOYSA-N furan-2-ylmethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC1=CC=CO1 DWXAVNJYFLGAEF-UHFFFAOYSA-N 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- CZLCEPVHPYKDPJ-UHFFFAOYSA-N guanidine;2,2,2-trichloroacetic acid Chemical compound NC(N)=N.OC(=O)C(Cl)(Cl)Cl CZLCEPVHPYKDPJ-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000003840 hydrochlorides Chemical class 0.000 description 1
- 229920001477 hydrophilic polymer Polymers 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000002883 imidazolyl group Chemical group 0.000 description 1
- 125000001841 imino group Chemical class [H]N=* 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- XUPFNPFFFUXGMP-UHFFFAOYSA-N isoindole-1,3-dione;silver Chemical compound [Ag].C1=CC=C2C(=O)NC(=O)C2=C1 XUPFNPFFFUXGMP-UHFFFAOYSA-N 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- AZEPWULHRMVZQR-UHFFFAOYSA-M lithium;dodecanoate Chemical compound [Li+].CCCCCCCCCCCC([O-])=O AZEPWULHRMVZQR-UHFFFAOYSA-M 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- CUONGYYJJVDODC-UHFFFAOYSA-N malononitrile Chemical class N#CCC#N CUONGYYJJVDODC-UHFFFAOYSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- VHRYZQNGTZXDNX-UHFFFAOYSA-N methacryloyl chloride Chemical compound CC(=C)C(Cl)=O VHRYZQNGTZXDNX-UHFFFAOYSA-N 0.000 description 1
- HNQIVZYLYMDVSB-UHFFFAOYSA-N methanesulfonimidic acid Chemical group CS(N)(=O)=O HNQIVZYLYMDVSB-UHFFFAOYSA-N 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 description 1
- MPHUYCIKFIKENX-UHFFFAOYSA-N methyl 2-ethenylbenzoate Chemical compound COC(=O)C1=CC=CC=C1C=C MPHUYCIKFIKENX-UHFFFAOYSA-N 0.000 description 1
- NKHAVTQWNUWKEO-IHWYPQMZSA-N methyl hydrogen fumarate Chemical compound COC(=O)\C=C/C(O)=O NKHAVTQWNUWKEO-IHWYPQMZSA-N 0.000 description 1
- BBBWQGQLFSDGIQ-UHFFFAOYSA-N methyl(3-phenylpropyl)sulfanium bromide Chemical compound [Br-].C(C1=CC=CC=C1)CC[SH+]C BBBWQGQLFSDGIQ-UHFFFAOYSA-N 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 125000002816 methylsulfanyl group Chemical group [H]C([H])([H])S[*] 0.000 description 1
- 125000004170 methylsulfonyl group Chemical group [H]C([H])([H])S(*)(=O)=O 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- OTVPURYEWXIAKH-UHFFFAOYSA-N n,n-dibromobenzenesulfonamide Chemical compound BrN(Br)S(=O)(=O)C1=CC=CC=C1 OTVPURYEWXIAKH-UHFFFAOYSA-N 0.000 description 1
- KFPBEVFQCXRYIR-UHFFFAOYSA-N n-(3,5-dichloro-4-hydroxyphenyl)benzenesulfonamide Chemical compound C1=C(Cl)C(O)=C(Cl)C=C1NS(=O)(=O)C1=CC=CC=C1 KFPBEVFQCXRYIR-UHFFFAOYSA-N 0.000 description 1
- WHZPMLXZOSFAKY-UHFFFAOYSA-N n-(4-hydroxyphenyl)benzenesulfonamide Chemical compound C1=CC(O)=CC=C1NS(=O)(=O)C1=CC=CC=C1 WHZPMLXZOSFAKY-UHFFFAOYSA-N 0.000 description 1
- DVNYDODOESWBJY-UHFFFAOYSA-N n-bromo-n-methylbenzenesulfonamide Chemical compound CN(Br)S(=O)(=O)C1=CC=CC=C1 DVNYDODOESWBJY-UHFFFAOYSA-N 0.000 description 1
- FWLGGSWAIHNLLW-UHFFFAOYSA-N n-bromo-n-phenylacetamide Chemical compound CC(=O)N(Br)C1=CC=CC=C1 FWLGGSWAIHNLLW-UHFFFAOYSA-N 0.000 description 1
- VBTQNRFWXBXZQR-UHFFFAOYSA-N n-bromoacetamide Chemical compound CC(=O)NBr VBTQNRFWXBXZQR-UHFFFAOYSA-N 0.000 description 1
- VQGWOOIHSXNRPW-UHFFFAOYSA-N n-butyl-2-methylprop-2-enamide Chemical compound CCCCNC(=O)C(C)=C VQGWOOIHSXNRPW-UHFFFAOYSA-N 0.000 description 1
- ZIWDVJPPVMGJGR-UHFFFAOYSA-N n-ethyl-2-methylprop-2-enamide Chemical compound CCNC(=O)C(C)=C ZIWDVJPPVMGJGR-UHFFFAOYSA-N 0.000 description 1
- RCLLINSDAJVOHP-UHFFFAOYSA-N n-ethyl-n',n'-dimethylprop-2-enehydrazide Chemical compound CCN(N(C)C)C(=O)C=C RCLLINSDAJVOHP-UHFFFAOYSA-N 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000004780 naphthols Chemical class 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 238000006396 nitration reaction Methods 0.000 description 1
- 150000002826 nitrites Chemical class 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 102000039446 nucleic acids Human genes 0.000 description 1
- 108020004707 nucleic acids Proteins 0.000 description 1
- NZIDBRBFGPQCRY-UHFFFAOYSA-N octyl 2-methylprop-2-enoate Chemical compound CCCCCCCCOC(=O)C(C)=C NZIDBRBFGPQCRY-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- XULSCZPZVQIMFM-IPZQJPLYSA-N odevixibat Chemical compound C12=CC(SC)=C(OCC(=O)N[C@@H](C(=O)N[C@@H](CC)C(O)=O)C=3C=CC(O)=CC=3)C=C2S(=O)(=O)NC(CCCC)(CCCC)CN1C1=CC=CC=C1 XULSCZPZVQIMFM-IPZQJPLYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical group 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- BIAGWOZIXODKKS-UHFFFAOYSA-N oxadiazole-4-thiol;silver Chemical compound [Ag].SC1=CON=N1 BIAGWOZIXODKKS-UHFFFAOYSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- HVAMZGADVCBITI-UHFFFAOYSA-M pent-4-enoate Chemical compound [O-]C(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-M 0.000 description 1
- GYDSPAVLTMAXHT-UHFFFAOYSA-N pentyl 2-methylprop-2-enoate Chemical compound CCCCCOC(=O)C(C)=C GYDSPAVLTMAXHT-UHFFFAOYSA-N 0.000 description 1
- ULDDEWDFUNBUCM-UHFFFAOYSA-N pentyl prop-2-enoate Chemical compound CCCCCOC(=O)C=C ULDDEWDFUNBUCM-UHFFFAOYSA-N 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- QIWKUEJZZCOPFV-UHFFFAOYSA-N phenyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1=CC=CC=C1 QIWKUEJZZCOPFV-UHFFFAOYSA-N 0.000 description 1
- WRAQQYDMVSCOTE-UHFFFAOYSA-N phenyl prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1 WRAQQYDMVSCOTE-UHFFFAOYSA-N 0.000 description 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
- 125000001639 phenylmethylene group Chemical group [H]C(=*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 125000003170 phenylsulfonyl group Chemical group C1(=CC=CC=C1)S(=O)(=O)* 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 108091008695 photoreceptors Proteins 0.000 description 1
- IJAPPYDYQCXOEF-UHFFFAOYSA-N phthalazin-1(2H)-one Chemical compound C1=CC=C2C(=O)NN=CC2=C1 IJAPPYDYQCXOEF-UHFFFAOYSA-N 0.000 description 1
- LFSXCDWNBUNEEM-UHFFFAOYSA-N phthalazine Chemical compound C1=NN=CC2=CC=CC=C21 LFSXCDWNBUNEEM-UHFFFAOYSA-N 0.000 description 1
- 125000005543 phthalimide group Chemical group 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- IIXIVLKPOPBJHI-UHFFFAOYSA-N prop-2-enamide styrene Chemical compound C(C=C)(=O)N.C(C=C)(=O)N.C=CC1=CC=CC=C1 IIXIVLKPOPBJHI-UHFFFAOYSA-N 0.000 description 1
- IBGXDQCATAOYOE-UHFFFAOYSA-N prop-2-enoyloxymethanesulfonic acid Chemical compound OS(=O)(=O)COC(=O)C=C IBGXDQCATAOYOE-UHFFFAOYSA-N 0.000 description 1
- ZQMAPKVSTSACQB-UHFFFAOYSA-N prop-2-enyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCC=C ZQMAPKVSTSACQB-UHFFFAOYSA-N 0.000 description 1
- BOQSSGDQNWEFSX-UHFFFAOYSA-N propan-2-yl 2-methylprop-2-enoate Chemical compound CC(C)OC(=O)C(C)=C BOQSSGDQNWEFSX-UHFFFAOYSA-N 0.000 description 1
- LYBIZMNPXTXVMV-UHFFFAOYSA-N propan-2-yl prop-2-enoate Chemical compound CC(C)OC(=O)C=C LYBIZMNPXTXVMV-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- NDGRWYRVNANFNB-UHFFFAOYSA-N pyrazolidin-3-one Chemical class O=C1CCNN1 NDGRWYRVNANFNB-UHFFFAOYSA-N 0.000 description 1
- 125000004076 pyridyl group Chemical group 0.000 description 1
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 description 1
- GJAWHXHKYYXBSV-UHFFFAOYSA-N quinolinic acid Chemical compound OC(=O)C1=CC=CN=C1C(O)=O GJAWHXHKYYXBSV-UHFFFAOYSA-N 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- KIWUVOGUEXMXSV-UHFFFAOYSA-N rhodanine Chemical class O=C1CSC(=S)N1 KIWUVOGUEXMXSV-UHFFFAOYSA-N 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 description 1
- 229940081974 saccharin Drugs 0.000 description 1
- 235000019204 saccharin Nutrition 0.000 description 1
- 239000000901 saccharin and its Na,K and Ca salt Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- 229940045105 silver iodide Drugs 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- VMPMKNVWTFEJAO-UHFFFAOYSA-N silver;2h-tetrazole Chemical compound [Ag].C=1N=NNN=1 VMPMKNVWTFEJAO-UHFFFAOYSA-N 0.000 description 1
- MNMYRUHURLPFQW-UHFFFAOYSA-M silver;dodecanoate Chemical compound [Ag+].CCCCCCCCCCCC([O-])=O MNMYRUHURLPFQW-UHFFFAOYSA-M 0.000 description 1
- OHGHHPYRRURLHR-UHFFFAOYSA-M silver;tetradecanoate Chemical compound [Ag+].CCCCCCCCCCCCCC([O-])=O OHGHHPYRRURLHR-UHFFFAOYSA-M 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- CJGJYOBXQLCLRG-UHFFFAOYSA-M sodium;2-hydroxy-3-prop-2-enoxypropane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(O)COCC=C CJGJYOBXQLCLRG-UHFFFAOYSA-M 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical group O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- BUUPQKDIAURBJP-UHFFFAOYSA-N sulfinic acid Chemical compound OS=O BUUPQKDIAURBJP-UHFFFAOYSA-N 0.000 description 1
- 125000000565 sulfonamide group Chemical group 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 239000004250 tert-Butylhydroquinone Substances 0.000 description 1
- SJMYWORNLPSJQO-UHFFFAOYSA-N tert-butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)(C)C SJMYWORNLPSJQO-UHFFFAOYSA-N 0.000 description 1
- RKSOPLXZQNSWAS-UHFFFAOYSA-N tert-butyl bromide Chemical compound CC(C)(C)Br RKSOPLXZQNSWAS-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 235000019281 tert-butylhydroquinone Nutrition 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- DDFYFBUWEBINLX-UHFFFAOYSA-M tetramethylammonium bromide Chemical compound [Br-].C[N+](C)(C)C DDFYFBUWEBINLX-UHFFFAOYSA-M 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 1
- 150000001467 thiazolidinediones Chemical class 0.000 description 1
- CBDKQYKMCICBOF-UHFFFAOYSA-N thiazoline Chemical compound C1CN=CS1 CBDKQYKMCICBOF-UHFFFAOYSA-N 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- YFDSDPIBEUFTMI-UHFFFAOYSA-N tribromoethanol Chemical compound OCC(Br)(Br)Br YFDSDPIBEUFTMI-UHFFFAOYSA-N 0.000 description 1
- 229950004616 tribromoethanol Drugs 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- JBWKIWSBJXDJDT-UHFFFAOYSA-N triphenylmethyl chloride Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)(Cl)C1=CC=CC=C1 JBWKIWSBJXDJDT-UHFFFAOYSA-N 0.000 description 1
- 229940035893 uracil Drugs 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/32—Colour coupling substances
- G03C7/36—Couplers containing compounds with active methylene groups
- G03C7/38—Couplers containing compounds with active methylene groups in rings
- G03C7/384—Couplers containing compounds with active methylene groups in rings in pyrazolone rings
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
Abstract
Description
【発明の詳細な説明】
[産業上の利用分野]
本発明は熱現象により画像を形成する熱現1堡カーラー
感光材料に関し、詳しくは熱現像により色素画像を形成
できる熱現像に適するマゼンタカプラーを含有する熱現
像カラー感光材料に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a heat-developable color photosensitive material that forms an image by a thermal phenomenon, and specifically relates to a magenta coupler suitable for heat development that can form a dye image by heat development. The present invention relates to a heat-developable color photosensitive material containing the present invention.
〔発明の′f!4景J
近年、現&工程を熱処理で行ない得る熱現像感光材料が
注目を集めている。['f of invention! 4 Kei J In recent years, heat-developable photosensitive materials that can be heat-treated in the development and processing steps have been attracting attention.
この様な熱現像感光材料については、例えば特公昭43
−4921@および同43−4924号公報にその記載
があり、有機銀塩、ハロゲン化銀およびi玉元剤から成
る感光材料が開示されている。Regarding such heat-developable photosensitive materials, for example,
-4921@ and No. 43-4924 disclose a photosensitive material comprising an organic silver salt, silver halide, and an i-ball base agent.
かかる熱現像感光材料に改良を加え、神々の方法によっ
て色画像を得る試みがなされている。Attempts have been made to improve such heat-developable photosensitive materials and obtain color images using divine methods.
例えば、米国特許第3,531.28G号、同第3,7
61.210号および同第3,764,328号等の6
明ff1l :g中にyy?6 /lXlX第1ミアミ
ン現像主桑化体とカプラーとの反応によって色画像を形
成させる熱現象カラー感光材料が開示されている。For example, U.S. Patent No. 3,531.28G, U.S. Pat.
No. 61.210 and No. 3,764,328, etc.
Akiraff1l: yy in g? A thermal color photosensitive material is disclosed in which a color image is formed by a reaction between a 6/lXlX primary myamine developing main compound and a coupler.
また、リサーチ・ディスクロージt −15108号お
よび同15127号には、スルホンアミドフェノール或
いはスルホンアミドアニリンの誘導体現像1桑の酸化体
とカプラーとの反応によって色画像を形成させる熱現像
カラー感光材料が開示されている。Furthermore, Research Disclosure No. 15108 and No. 15127 discloses a heat-developable color photosensitive material in which a color image is formed by the reaction of a coupler with an oxidized product of sulfonamide phenol or sulfonamide aniline. has been done.
しかしながら、これらの公報に開示されている熱現像カ
ラー感光材料に用いられているマゼンタカプラー、特に
銀の利用効率を高める為に用いられている2当mマゼン
タカプラーにおいては、著しく発色性が悪いかまたは著
しくカブリが高いという欠点を有していた。However, the magenta couplers used in the heat-developable color photosensitive materials disclosed in these publications, especially the 2 equim magenta couplers used to increase silver utilization efficiency, have significantly poor color development. Otherwise, it had the disadvantage of extremely high fog.
[発明の目的]
本発明の目的は、発色性が良好でかつカブリの少ない熱
現像カラー感光材料用マゼンタカプラーおよび該カプラ
ーを有する熱現像カラー感光材1′Nを提供することに
ある。[Object of the Invention] An object of the present invention is to provide a magenta coupler for a heat-developable color photosensitive material that has good color development and less fog, and a heat-developable color photosensitive material 1'N having the coupler.
[発明の構成]
本発明の上記目的は、支持体上に、少なくとも1層の熱
現像感光性層を有する熱現像カラー感光材料に下記一般
式(1)で表わされるマゼンタカプラーを含有する熱現
像カラー感光材料により達成される。[Structure of the Invention] The above object of the present invention is to provide a heat-developable color photosensitive material containing a magenta coupler represented by the following general formula (1) in a heat-developable color photosensitive material having at least one heat-developable photosensitive layer on a support. This can be achieved using color photosensitive materials.
一般式(1)
[式中、2はN原子と共に含窒素複素環残基を形成する
のに必要な原子群を表わし、R1はアルキル基、アリー
ル基、アルキルアミノ基、アニリノ基、アシルアミノ基
またはウレイド基を表わし、R2はアリール基または複
素環残基を表わす。但し、R+ 、R2の少なくとも一
つはバラスト基またはバラスト基で置換されている。]
[発明の具体的構成]
前記一般式(1)において、ZはN原子と共に含窒素複
素環残基を形成するのに必要な原子群を表わすが、この
含窒素複素環残基は、さらに他の炭素環(例えば、ベン
ゼン環等)または複素環残基と縮合環を形成してもよい
。含窒素複素環残基としては、特に窒素原子の隣接位に
カルボニル基を有するものが好ましく、例えばコハク酸
イミド残基、フタル閣イミド残基がにり好ましい。該含
窒素複素環残基は置換基を有するものを含み、これらの
置換基としては、例えば、アルキル基(例えば、メチル
基、エチル基等)、アリール基(例えば、フェニル基)
、アルコキシ基(例えば、メトキシ基、エトキシ基等)
、ニトロ基、スルファモイル基(例えば、ジエチルスル
ファモイル基)、ハロゲン原子(例えば、塩素、フッ素
)等が挙げられる。General formula (1) [In the formula, 2 represents an atomic group necessary to form a nitrogen-containing heterocyclic residue together with the N atom, and R1 is an alkyl group, an aryl group, an alkylamino group, an anilino group, an acylamino group, or It represents a ureido group, and R2 represents an aryl group or a heterocyclic residue. However, at least one of R+ and R2 is substituted with a ballast group or a ballast group. ] [Specific structure of the invention] In the general formula (1), Z represents an atomic group necessary to form a nitrogen-containing heterocyclic residue together with the N atom, but this nitrogen-containing heterocyclic residue further comprises: A fused ring may be formed with another carbocyclic ring (eg, benzene ring, etc.) or a heterocyclic residue. The nitrogen-containing heterocyclic residue is particularly preferably one having a carbonyl group adjacent to the nitrogen atom, such as a succinimide residue or a phthalimide residue. The nitrogen-containing heterocyclic residues include those having substituents, such as alkyl groups (e.g., methyl group, ethyl group, etc.), aryl groups (e.g., phenyl group).
, alkoxy group (e.g., methoxy group, ethoxy group, etc.)
, a nitro group, a sulfamoyl group (eg, diethylsulfamoyl group), a halogen atom (eg, chlorine, fluorine), and the like.
前記一般式(1)において、R1はアルキル基、アリー
ル基、アルキルアミノ基、アニリノ基、アシルアミノ基
またはウレイド基を表わすが、これらのアルキル基、ア
リール基、アルキルアミノ基、アニリノ塁、アシルアミ
ノ基、ウレイド基はそれぞれe Pj+ Jlを有する
ものを含み、これらの置換基としては、例えば、ハロゲ
ン原子(例えば、フッ素原子、塩素原子、臭素原子等)
、直鎖もしくは分岐鎖のアル4ニル基(例えば、メチル
基、エチル基、【−ブチル塁等)、アルコキシ基(例え
ば、メトキシ基、エトキシ基等)、アシルアミノ基(1
列えば、アセトアミド基、ベンズアミド基等)、アリー
ルオキシ基(例えば、フェニルオキシ基等)、アルコキ
シカルボニル基(例えばメトキシカルボニル基等)、ニ
トロ基、ヒドロキシ!3等が挙げられ、これらの置換基
は2つ以上あってもよく、2つ以上の時はそれらは同じ
でも異なっていてもよい。In the general formula (1), R1 represents an alkyl group, an aryl group, an alkylamino group, an anilino group, an acylamino group, or a ureido group; The ureido groups each include those having e Pj+ Jl, and examples of these substituents include halogen atoms (e.g., fluorine atom, chlorine atom, bromine atom, etc.)
, linear or branched alkyl groups (e.g., methyl group, ethyl group, [-butyl group, etc.), alkoxy groups (e.g., methoxy group, ethoxy group, etc.), acylamino groups (1
For example, acetamido group, benzamide group, etc.), aryloxy group (e.g., phenyloxy group, etc.), alkoxycarbonyl group (e.g., methoxycarbonyl group, etc.), nitro group, hydroxy! There may be two or more of these substituents, and when there are two or more, they may be the same or different.
前記一般式(1)において、R2はアリール基または?
!2素環残阜を表わザが、R2で表わされるアリール基
としては、例えば、フェニル基等が挙げられ、複素環残
基としては、例えば、ピリジル丼、イミダゾリル基、ベ
ンゾチアゾリル基等が挙げられる。In the general formula (1), R2 is an aryl group or ?
! The aryl group represented by R2, which represents a dicyclic residue, includes, for example, a phenyl group, and the heterocyclic residue includes, for example, a pyridyl group, an imidazolyl group, a benzothiazolyl group, etc. .
R2で表すされるアリール基、複素環残基はそれぞれ置
換基を右するものを含み、これらの置操りとしては、例
えば、ハ[1ゲン原子(例えば、フッ素原子、塩素原子
、臭素原子等)、置換基を有してもJ、いアルキル基(
例えば、メチル基、エチル基、トリフルオロメチル基等
)、アルコキシ基(例えば、メト・キシ基、エトキシ基
等)、アリールAギシ基(例えば、フェニルオキシ阜宿
)、アシルアミノ基(例えば、アセチルアミノ基′@)
、カルバモイルu (Fj Iiカルバモイル基を含み
、置換基としては、例えばメチル基、エチル基、)にル
基等)、アルキルスルホニル基(例えば、メチルスルホ
ニル基等)、アリールスルホニル基(例えば、フェニル
スルホニル基等)、アルキルスルホンアミド基(例えば
、メタンスルホンアミド基等)、アリールスルホンアミ
ド基(例えば、フェニルスルホンアミド基等)、スルフ
ァモイル基(置換スルファモイル基を含み、置換基とし
ては、例えば、メチル基、エチル基、フェニル基等)、
アルキルチオ基(例えば、メチルチオ曇等)、アリーレ
ン基(例えば、フェニルブJ13等)、シアノ基、二1
・0基、ヒドロキシu等が挙げられ、これらの置1rA
uは2つ以上あってもよく、2つ以上の時これらは同じ
であっても異なっていてムよい。The aryl group and heterocyclic residue represented by R2 each include a substituent, and these substitutions include, for example, H [1 atom (e.g., fluorine atom, chlorine atom, bromine atom, etc.) , J even if it has a substituent, an alkyl group (
For example, methyl group, ethyl group, trifluoromethyl group, etc.), alkoxy group (e.g., methoxy group, ethoxy group, etc.), aryl group (e.g., phenyloxy), acylamino group (e.g., acetylamino base'@)
, carbamoyl u (Fj Ii includes carbamoyl group, examples of substituents include methyl group, ethyl group, etc.), alkylsulfonyl group (for example, methylsulfonyl group, etc.), arylsulfonyl group (for example, phenylsulfonyl group, etc.) groups, etc.), alkylsulfonamide groups (e.g., methanesulfonamide groups, etc.), arylsulfonamide groups (e.g., phenylsulfonamide groups, etc.), sulfamoyl groups (including substituted sulfamoyl groups, and substituents include, for example, methyl groups). , ethyl group, phenyl group, etc.),
Alkylthio group (e.g., methylthio, etc.), arylene group (e.g., phenylbu J13, etc.), cyano group, 21
・0 group, hydroxy u, etc. are mentioned, and these positions 1rA
There may be two or more u's, and when there are two or more u's, they may be the same or different.
一般式(1)において、R1およびR2の少なくとも一
つはバラスト基またはバラスト基で置換されている基で
ある。ここで、本発明のバラスト基とは、熱現像時にマ
ゼンタカプラーを該マぜンタカプラーを有する熱現像カ
ラー感光材料中で非拡散性に変えるような分子の大きさ
及び形状を備えている有毀イを意味する。バラスト基の
代表的な例としては、炭素原子数の総和が8〜40UA
(より好ましくは12〜30個)の右別基であり、他の
特に好ましいバラスト基としてはポリマー残1、−であ
る。In general formula (1), at least one of R1 and R2 is a ballast group or a group substituted with a ballast group. Here, the ballast group of the present invention refers to a damaged compound having a molecular size and shape that makes the magenta coupler non-diffusible in the heat-developable color light-sensitive material containing the magenta coupler during heat development. means. As a typical example of a ballast group, the total number of carbon atoms is 8 to 40 UA.
(more preferably 12 to 30 groups), and other particularly preferred ballast groups are polymer residues 1, -.
バラスト基がポリマー残基のとき、一般式(1)で表わ
されるマゼンタカプラーは、エチレン性不飽和基または
エチレン性不飽lT133を有する基で置換された単量
体から誘3りされる繰り返し単位を資するポリマーマピ
ンタカプラーである。When the ballast group is a polymer residue, the magenta coupler represented by general formula (1) has a repeating unit derived from a monomer substituted with an ethylenically unsaturated group or a group having ethylenically unsaturated lT133. It is a useful polymer mappin coupler.
前記エヂレン性不飽′FI]具またはエチレン性不飽和
基を右するりとしては下記一般式(2)で表わされる基
が好ましい。The ethylenically unsaturated group or ethylenically unsaturated group is preferably a group represented by the following general formula (2).
一般式(2)
CH2=C−+Jl←→X1汁→J2増がん鮨、4
ml
式中、R3は水素原子、カルボキシ基またはアルキル基
(例えば、メチル基、エチル基等)を表わし、このアル
キル基は置換基を有するものも酋み、置換基としては、
例えば、ハロゲン原子(例えば、フッ素原子、塩素原子
等)、カルボキシ基等である(lR3で表わされるカル
ボキシ基および置換基のカルボキシ基は塩を形成しても
よい。General formula (2) CH2=C-+Jl←→X1 Soup→J2 Masugan Sushi, 4
ml In the formula, R3 represents a hydrogen atom, a carboxy group, or an alkyl group (for example, a methyl group, an ethyl group, etc.), and this alkyl group also includes those having a substituent.
Examples include halogen atoms (eg, fluorine atoms, chlorine atoms, etc.), carboxy groups, etc. (The carboxy group represented by lR3 and the carboxy group of the substituent may form a salt.
JlおよびJ2はそれぞれ2価の結合基を表わし、この
2価の結合基としては、例えば−NHGO−1−CON
H−1−COO−1−OCO−1−SCO−1−COS
−1−0−1−S−1−SO−1−8O2−等である。Jl and J2 each represent a divalent bonding group, and examples of the divalent bonding group include -NHGO-1-CON
H-1-COO-1-OCO-1-SCO-1-COS
-1-0-1-S-1-SO-1-8O2-, etc.
×1および×2はそれぞれ2価の炭化水素基を表わし、
2価の炭化水素基としては例えば、アルキレン基、アリ
ーレン基、アラルキレン基、アルキレンアリーレン基ま
たはアリーレンアルキレン基が挙げられ、アルキレン基
としては、例えば、メチレン基、エチレン基、プロピレ
ン基等であり、アリーレン基としては、例えば、フェニ
レン基等であり、アラルキレン基としては、フェニルメ
チレン塁等であり、アルキレンアリーレン基としては、
例えば、メチレンフェニレン基等であり、アリーレンア
ルキレン基としては、例えば、フェニレンメチレン塁等
である。り+ 、lIl+ 、Q2、m2はそれぞれO
または1を表わす。×1 and ×2 each represent a divalent hydrocarbon group,
Examples of the divalent hydrocarbon group include an alkylene group, an arylene group, an aralkylene group, an alkylenearylene group, and an arylenealkylene group. Examples of the alkylene group include a methylene group, an ethylene group, a propylene group, and an arylene group. Examples of the group include phenylene group, etc., examples of the aralkylene group include phenylmethylene group, and examples of the alkylene arylene group.
For example, it is a methylene phenylene group, and the arylene alkylene group is, for example, a phenylene methylene group. Ri+, lIl+, Q2, m2 are each O
Or represents 1.
本発明のマゼンタカプラーがポリマーカプラーである場
合には、単ご体力プラーの1種のみからなる綴り返し単
位のいわゆるホモポリマーであっても、単量体カプラー
の2種以−ヒを徂み合F)uたコポリマーであってもよ
く、さらにII!!の共i17合し得るエチレン性不飽
和基を有するコモツアーの1【1以上とからなるコポリ
マーであってもよい。When the magenta coupler of the present invention is a polymer coupler, even if it is a so-called homopolymer of a repeating unit consisting of only one type of monomer coupler, it may contain more than two types of monomer couplers. F) It may be a copolymer, and II! ! It may also be a copolymer consisting of one or more comotours having an ethylenically unsaturated group that can be combined with i17.
本発明のマゼンタカプラー単M体とコポリマーを形成し
1りる上記エチレン性不飽和基を有するコ〔ツマ−とし
ては、アクリル酸エステル類、ヌククリル酸エステル類
、ビニルニスデル類、オレフイン類、スチレンフr1、
クロトン酸エステル類、イタコン酸ジエステル類、マレ
イン酸ジエステル類、フマル酸ジエステル類、アクリル
アミド類、アリル化合物、ビニルエーテル類、ビニルエ
−テ類、ビニル異W1環化合物、グリシジルエステル類
、不飽和ニトリル類、多官能モノマー、各種不飽和酸等
を挙げることができる。A copolymer formed with the single M magenta coupler of the present invention and having the above-mentioned ethylenically unsaturated group [as the copolymer, acrylic esters, nucleic acid esters, vinyl nitrides, olefins, styrene fur r1,
Crotonate esters, itaconate diesters, maleate diesters, fumarate diesters, acrylamides, allyl compounds, vinyl ethers, vinyl ethers, vinyl hetero-W1 ring compounds, glycidyl esters, unsaturated nitrites, Examples include functional monomers and various unsaturated acids.
これらのコモノマーについて更に具体的に示すと、アク
リル酸エステル類としては、メブルアクリレート、エチ
ルアクリレート、n−プロピルアクリレート、イソプロ
ピルアクリレート、n−ブチルアクリレート、イソブチ
ルアクリレート、5ec−ブチルアクリレート、ter
t−ブチルアクリレ−1・、アミルアクリレート、ヘキ
シルアクリレ−1−12−エチルへキシルアクリレート
、オクチルアクリレ−1・、tert−オクチルアクリ
レ−1−12−クロロエチルアクリレート、2−ブロモ
エチルアクリレート、4−クロロブチルアクリレ−1・
、シアノエチルアクリレート、2−アセトキシエチルア
クリレート、ジメチルアミノエチルアクリレート、ベン
ジルアクリレート、メトキシベンジルアクリレート、2
−クロロシクロへキシルアクリレート、シクロへキシル
アクリレート、フルフリル7クリレー1・、テトラヒド
ロフルフリル7クリレート、フェニルアクリレート、5
−ヒドロキシペンチルアクリレート、2.2−ジメチル
−3−ヒドロキシプロピルアクリレート、2−メトキシ
エチルアクリレート、3−メトキシブアルアクリレート
、2−エトキシエチルアクリレ−1〜、2−iso−プ
ロポキシアクリレート、2−ブロモエチルアクリレート
、2−(2−メトキシエトキシ)エチルアクリレ−1−
12−(2−ブトキシエトキシ)エチルアクリレート、
ω−メトキシポリエヂレングリコールアクリレー1−(
付加モルan=9)1−ブロモ−2−メトキシエチルア
クリレート、1.1−ジクロロ−2−エトキシエチルア
クリレート等が挙げられる。To be more specific about these comonomers, the acrylic esters include mebru acrylate, ethyl acrylate, n-propyl acrylate, isopropyl acrylate, n-butyl acrylate, isobutyl acrylate, 5ec-butyl acrylate, ter
t-butyl acryle-1., amyl acrylate, hexyl acryle-1-12-ethylhexyl acrylate, octyl acryle-1., tert-octyl acryle-1-12-chloroethyl acrylate, 2-bromoethyl acrylate, 4-Chlorobutyl acrylate-1.
, cyanoethyl acrylate, 2-acetoxyethyl acrylate, dimethylaminoethyl acrylate, benzyl acrylate, methoxybenzyl acrylate, 2
-chlorocyclohexyl acrylate, cyclohexyl acrylate, furfuryl 7 acrylate 1, tetrahydrofurfuryl 7 acrylate, phenyl acrylate, 5
-Hydroxypentyl acrylate, 2,2-dimethyl-3-hydroxypropyl acrylate, 2-methoxyethyl acrylate, 3-methoxybutal acrylate, 2-ethoxyethyl acrylate-1~, 2-iso-propoxy acrylate, 2-bromoethyl Acrylate, 2-(2-methoxyethoxy)ethyl acrylate-1-
12-(2-butoxyethoxy)ethyl acrylate,
ω-Methoxypolyethylene glycol acrylate 1-(
Addition mole an=9) 1-bromo-2-methoxyethyl acrylate, 1,1-dichloro-2-ethoxyethyl acrylate, and the like.
ヌククリル酸エステル類の例としては、メチルメタクリ
レート、エチルメタクリレート、n−プロピルメタクリ
レート、イソプロピルメタクリレート、n−ブチルメタ
クリレート、イソブチルメタクリレート、5ec−ブチ
ルメタクリレート、tert−ブチルメタクリレート、
アミルメタクリレート、ヘキシルメタクリレート、シフ
Oへキシルメタクリレート、ベンジルメタクリレ−1・
、クロロベンジルメタクリレート、オクチルメタクリレ
−]・、スルホプロピルメタクリレート、N−エチル−
N−フェニルアミノエチルメタクリレ−1・、2−(3
−フェニルプロピル714=シ)ニブルメタクリレート
、ジメヂルアミノフエノキシエチルメタクリレ−1・、
フルフリルメタクリレート、テトラヒドロフルフリルメ
タクリレート、フェニルメタクリレート、クレジルメタ
クリレ−1・、ナフヂルメタクリレート、2−ヒドロキ
シブチルメタクリレート、4−ヒドロキシブチルメタク
リレ−1−11〜リエチレングリコールモノメタクリレ
ート、ジプロピレングリコールモノメタクリレ−1・、
2−メトキシブチルメタクリレート、3−メトキシブチ
ルメタクリレート、2−アセト4−ジメチルメタクリレ
ー1−12−アセトアセ1−キシエチルメタクリレート
、2−エトキシエチルメタクリレート、2−iso−プ
ロポキシエチルメタクリレート、2−ブトキシエチルメ
タクリレート、2−(2−メトキシエトキシ)エチルメ
タクリレート、2−(2−エトキシエトキシ)エチルメ
タクリレート、2−(2−ブトキシエトキシ)エチルメ
タクリレート、ω−メトキシポリエチレングリコールメ
タクリレート(付加モル数n−6)、アミルアクリレー
ト、メタクリル醒ジメチルアミノエチルメチルクロライ
ド塩などを挙げることができる。Examples of nuccrylic acid esters include methyl methacrylate, ethyl methacrylate, n-propyl methacrylate, isopropyl methacrylate, n-butyl methacrylate, isobutyl methacrylate, 5ec-butyl methacrylate, tert-butyl methacrylate,
Amyl methacrylate, hexyl methacrylate, Schiff O hexyl methacrylate, benzyl methacrylate-1.
, chlorobenzyl methacrylate, octyl methacrylate], sulfopropyl methacrylate, N-ethyl-
N-phenylaminoethyl methacrylate-1, 2-(3
-phenylpropyl 714=cy) nibble methacrylate, dimylaminophenoxyethyl methacrylate-1,
Furfuryl methacrylate, tetrahydrofurfuryl methacrylate, phenyl methacrylate, cresyl methacrylate-1, naphdyl methacrylate, 2-hydroxybutyl methacrylate, 4-hydroxybutyl methacrylate-1-11 to lyethylene glycol monomethacrylate, dipropylene glycol mono Methacrylate-1・,
2-methoxybutyl methacrylate, 3-methoxybutyl methacrylate, 2-aceto 4-dimethyl methacrylate 1-12-acetoacet 1-xyethyl methacrylate, 2-ethoxyethyl methacrylate, 2-iso-propoxyethyl methacrylate, 2-butoxyethyl methacrylate , 2-(2-methoxyethoxy)ethyl methacrylate, 2-(2-ethoxyethoxy)ethyl methacrylate, 2-(2-butoxyethoxy)ethyl methacrylate, ω-methoxypolyethylene glycol methacrylate (number of moles added n-6), amyl Examples include acrylate, methacrylic acidified dimethylaminoethylmethyl chloride salt, and the like.
ビニルエステル類の例としては、ビニルアセテート、ビ
ニルプロピオネート、ビニルプチレー1−、ビニルイソ
ブチレート、ビニルカプロニー]・、ビニルクロロアヒ
テ−1・、ビニルメトキシアf!アート、ビニルフェニ
ルアヒテート、支Ωffr正ビニル、昔ナリチル酸ビニ
ルなどがfげ1うれる。Examples of vinyl esters include vinyl acetate, vinyl propionate, vinyl petyray 1-, vinyl isobutyrate, vinyl caprony], vinyl chloroahite-1, vinyl methoxya f! Art, vinyl phenyl ahitate, Ωffr positive vinyl, vinyl nalycylate, etc. are popular.
またオレフィン類の例どしては、ジシクロペンタジェン
、エチレン、プロピレン、1−1テン、1−ペンテン、
331ヒビニル、JTA化ビニリデン、イソプレン、ク
ロロブレン、ブクジエン、2.3−ジエチルブタジエン
等を挙げることができる。Examples of olefins include dicyclopentadiene, ethylene, propylene, 1-1tene, 1-pentene,
331-hibinyl, JTA-ized vinylidene, isoprene, chlorobrene, bucdiene, 2,3-diethylbutadiene, and the like.
スチレン類どしては、例えば、スチレン、メブールスチ
レン、ジメチルスチレン、【−リメブルスヂレン、エチ
ルスチレン、イソプロビルスチレン、クロルエチルスヂ
レン、メト4シスヂレン、アセトギシスチレン、クロル
スチレン、ジクロルスチレン、プロムスヂレン、ビニル
安息香酸メチルエステルなどが挙げられる。Styrenes include, for example, styrene, meboulstyrene, dimethylstyrene, [-rimeblestyrene, ethylstyrene, isoprobylstyrene, chloroethylstyrene, metho4cisstyrene, acetogystyrene, chlorstyrene, dichlorostyrene, Examples include promsdylene and vinylbenzoic acid methyl ester.
クロトンt、iエステル類の例としては、クロトン酸ブ
チル、クロトン酸ブチルなどが挙げられる。Examples of croton t, i esters include butyl crotonate, butyl crotonate, and the like.
またイタコン酸ジエチル類としては、例えば、イタコン
酸ジメチル、イタコン酸ジエチル、イタコン酸ジブチル
などが挙げられる。Examples of diethyl itaconate include dimethyl itaconate, diethyl itaconate, and dibutyl itaconate.
マレイン酸ジエステル類としては、例えば、マレイン酸
ジエチル、マレイン故ジメブル、マレイン酸ジブチルな
どが挙げられる。Examples of maleic acid diesters include diethyl maleate, dimebble maleate, dibutyl maleate, and the like.
フマル酸ジエステル類としては、例えば、フマル酸ジエ
チル、フマル酸ジメチル、フマル酸ジブチルなどが挙げ
られる。Examples of the fumaric acid diesters include diethyl fumarate, dimethyl fumarate, and dibutyl fumarate.
その他のコモノマーの例としては、次のものが挙げられ
る。Examples of other comonomers include:
アクリルアミド類、例えば、アクリルアミド、メチルア
クリルアミド、エチルアクリルアミド、プロピルアクリ
ルアミド、ブチルアクリルアミド、tart−ブチルア
クリルアミド、シクロヘキシルアクリルアミド、ベンジ
ルアクリルアミド、ヒトOキシメブルアクリルアミド、
メトキシエチルアクリルアミド、ジメチルアミノエチル
アクリルアミド、フェニルアクリルアミド、ジメチルア
クリルアミド、ジエチルアクリルアミド、β−シアノエ
チルアクリルアミド、N−(2−アセトアセトキシエチ
ル)アクリルアミドなと;メタクリルアミド類、例えば
、メタクリルアミド、メチルメタクリルアミド、エチル
メタクリルアミド、プロピルメタクリル7ミド、ブチル
メタクリルアミド、tO「【−ブチルメタクリルアミド
、シクロヘキシルアクリルアミド、ベンジルメタクリル
アミド、ヒドロキシメチルメタクリルアミド、メトキシ
エチルアクリルアミド、ジメチルアミノエチルメタクリ
ルアミド、フェニルメタクリルアミド、ジエチルアクリ
ルアミド、ジエチルアクリルアミド、β−シアノエエチ
メタクリルアミド、N−(2−アセ1〜アセl−二tシ
エチル)メタクリルアミドなど:アリル化合物、例えば
、酢酸アリル、カブ0ン酸アリル、ラウリン酸アリル、
安Q晶義アリルなど;ビニルニーデル類、例えば、メチ
ルビニルエーテル、ブチルビニルエーテル、ヘキシルビ
ニルエーテル、メ1−ギシエヂルビニルエーテル、ジメ
チルアミノエチルビニルエーテルなど:ビニルスルボン
酸、例えば、メチルビニルケトン、フェニルビニルケト
ン、メトキシエチルビニルケトンなど;ビニル異部環化
合物、例えば、ビニルピリジン、N−ビニルイミダゾー
ル、N−ビニルAギサゾリドン、N−ビニルトリアゾー
ル、N−ビニルピロリドンなど;グリシジルエステル類
、例えば、グリシジルアクリレート、グリシジルメタク
リレートなど:不飽和ニトリル類、例えば、アクリロニ
1−リル、メタクリレートリルなど;多官能性tツマ−
1例えば、ジビニルベンゼン、スチレンビスアクリルア
ミド、エチレングリコールジメタクリレートなど。Acrylamides, such as acrylamide, methylacrylamide, ethylacrylamide, propylacrylamide, butylacrylamide, tart-butylacrylamide, cyclohexylacrylamide, benzylacrylamide, human Oximebruacrylamide,
Methoxyethyl acrylamide, dimethylaminoethyl acrylamide, phenylacrylamide, dimethylacrylamide, diethylacrylamide, β-cyanoethylacrylamide, N-(2-acetoacetoxyethyl)acrylamide; methacrylamides, such as methacrylamide, methylmethacrylamide, ethyl Methacrylamide, propylmethacrylamide, butylmethacrylamide, [-butylmethacrylamide, cyclohexylacrylamide, benzylmethacrylamide, hydroxymethylmethacrylamide, methoxyethylacrylamide, dimethylaminoethylmethacrylamide, phenylmethacrylamide, diethylacrylamide, diethyl Acrylamide, β-cyanoethymethacrylamide, N-(2-acetyl-acetyl-nitethyl)methacrylamide, etc.: Allyl compounds, such as allyl acetate, allyl turnipate, allyl laurate,
Allyl AnQ, etc.; Vinyl needles, such as methyl vinyl ether, butyl vinyl ether, hexyl vinyl ether, methyl vinyl ether, dimethylaminoethyl vinyl ether, etc.; Vinyl sulfonic acid, such as methyl vinyl ketone, phenyl vinyl ketone, methoxyethyl vinyl Ketones, etc.; Vinyl heterocyclic compounds, such as vinylpyridine, N-vinylimidazole, N-vinyl Agisazolidone, N-vinyltriazole, N-vinylpyrrolidone, etc.; Glycidyl esters, such as glycidyl acrylate, glycidyl methacrylate, etc.; Saturated nitriles, such as acrylonitrile, methacrylate trile, etc.; polyfunctional t-mers
1 For example, divinylbenzene, styrene bisacrylamide, ethylene glycol dimethacrylate, etc.
更に、アクリル酸、メタクリル酸、イタコン酸、マレイ
ン薗、イタコン酸モノアルキル、例えば、イタコン酸モ
ノメチル、イタコン酸モノエチル、イタコン酸モノブチ
ルなど;マレイン酸七ノアルキル、例えば、マレイン酸
モノメチル、マレイン酸モノエチル、マレイン酸Lノブ
チルなどニジトラコン酸、スチレンスルホン酸、ビニル
ベンジルスルホン酸、ビニルスルボン酸、アクリロイル
オキシアルキルスルホン酸、例えば、アクリロイルオキ
シメチルスルホン酸、アクリロイルオキシエチルスルホ
ン葭、アクリロイルオキシブ〔■ビルスルホン酸なと;
メタクリロイルオキシアルールスルホン酸、例えば、メ
ククリロイルオキシメブルスルホン酸、メタクリロイル
オキジエチルスルホン酸、メタクリロイルオキシプロピ
ルスルホン酸など;アクリルアミドアルキルスルホン醪
、例えば、2−アクリルアミド−2−メチルエタンスル
ホン酸、2−アクリルアミド−2−メチルプロパンスル
ボン酸、2−アクリルアミド−2−メチルブタンスルホ
ン酸など;メタクリルアミドアルキルスルホン酸、例え
ば、2−メタクリルアミド−2−メチルエタンスルホン
酸、2−メタクリルアミド−2−メチルプロパンスルホ
ン酸、2−メタクリルアミド−2−メチルブタンスルホ
ン酸など;アクリロイルオキシアルキルホスフェート、
例えば、アクリロイルオキシエチルホスフェ−1−13
−アクリロイルオキシプロビル−2−ホスフェ−1−な
ど;メタクリロイルオキシアルキルホスフェート、例え
ば、メタクリロイルオキシエチルホスフェート、3−メ
タクリロイルオキシプロピル=2−ホスフェートなど:
親水基を2ケ右する3−アリロキシ−2−ヒドロキシプ
ロパンスルホン酸ナトリウムなどが挙げられる。これら
の酸はアルカリ全屈(例えば、Na 、になど)または
アンモニウムイオンの塩であってもよい。さらにその他
のコモノマーとしては、米国特許第3,459,790
号、同第3.438.708号、同第3,554,98
7号、同第4.215.195号、同第4,247,6
73号、特開昭57−20573り号公報明細書等に記
載されている架橋性モノマーを用いることができる。こ
のような架橋性モノマーの例としては、具体的にはN−
(2−7セトアセトキシエチル)アクリルアミド、N−
(2−(2−7セトアセトキシエトキシ)エチル)アク
リルアミド等を挙げることができる。Furthermore, acrylic acid, methacrylic acid, itaconic acid, maleic acid, monoalkyl itaconate, such as monomethyl itaconate, monoethyl itaconate, monobutyl itaconate, etc.; heptanoalkyl maleate, such as monomethyl maleate, monoethyl maleate, maleic acid; Acid L-butyl, etc. ditraconic acid, styrene sulfonic acid, vinylbenzyl sulfonic acid, vinyl sulfonic acid, acryloyloxyalkyl sulfonic acid, such as acryloyloxymethyl sulfonic acid, acryloyloxyethyl sulfonate, acryloyl oxybu [■Bilsulfonic acid]
Methacryloyloxyallesulfonic acid, such as meccryloyloxymebrusulfonic acid, methacryloyloxymethylsulfonic acid, methacryloyloxypropylsulfonic acid, etc.; Acrylamidoalkylsulfonic acid, such as 2-acrylamido-2-methylethanesulfonic acid, 2- Acrylamido-2-methylpropanesulfonic acid, 2-acrylamido-2-methylbutanesulfonic acid, etc.; Methacrylamide alkylsulfonic acid, such as 2-methacrylamido-2-methylethanesulfonic acid, 2-methacrylamido-2-methyl propanesulfonic acid, 2-methacrylamido-2-methylbutanesulfonic acid, etc.; acryloyloxyalkyl phosphate,
For example, acryloyloxyethyl phosphate-1-13
-acryloyloxypropyl-2-phosphate-1-, etc.; methacryloyloxyalkyl phosphates, such as methacryloyloxyethyl phosphate, 3-methacryloyloxypropyl 2-phosphate, etc.:
Examples include sodium 3-allyloxy-2-hydroxypropanesulfonate, which has two hydrophilic groups. These acids may be alkaline (eg, Na, etc.) or salts of ammonium ions. Further, other comonomers include U.S. Pat. No. 3,459,790
No. 3,438.708, No. 3,554,98
No. 7, No. 4.215.195, No. 4,247,6
Crosslinkable monomers described in JP-A No. 73, JP-A No. 57-20573, etc. can be used. Examples of such crosslinking monomers include N-
(2-7cetoacetoxyethyl)acrylamide, N-
(2-(2-7cetoacetoxyethoxy)ethyl)acrylamide and the like can be mentioned.
本発明の一般式(1)で表わされるマゼンタカプラーが
、エチレン性不飽和基またはエチレン性不飽和基を有す
る基で置換されている単量体であり、他のコモノマーと
の共重合体であるコポリマーである場合、前記のマゼン
タカプラーの単量体は30〜7011%含まれる場合で
ある。The magenta coupler represented by the general formula (1) of the present invention is a monomer substituted with an ethylenically unsaturated group or a group having an ethylenically unsaturated group, and is a copolymer with another comonomer. In the case of a copolymer, the monomer content of the magenta coupler is 30 to 7011%.
一般的にポリマーカプラーは乳化重合法または溶液重合
法により重合され、本発明のマゼンタカプラーがポリマ
ーである場合のマゼンタカプラーも同様の方法で重合す
ることができる。乳化重合法については、米国特許第4
.0130,211号、同第3.370,952号に、
また親油性ポリマーをゼラチン水溶液中にラテックスの
形で分散する方法については、米国特許第3,451,
820号に記載されている方法を用いることができる。Generally, polymer couplers are polymerized by emulsion polymerization or solution polymerization, and when the magenta coupler of the present invention is a polymer, the magenta coupler can also be polymerized by the same method. Regarding the emulsion polymerization method, U.S. Patent No. 4
.. No. 0130,211, No. 3.370,952,
Further, regarding a method of dispersing a lipophilic polymer in the form of a latex in an aqueous gelatin solution, US Pat. No. 3,451,
The method described in No. 820 can be used.
これらの方法はホモポリマーの形成およびコポリマーの
形成にも応用でき、後者の場合、コモノマーは液体コモ
ノマーであるとよく、乳化重合の場合には常態で固定単
量体のための溶媒としても作用する。These methods can also be applied to the formation of homopolymers and copolymers; in the latter case the comonomer may be a liquid comonomer, which in the case of emulsion polymerization normally also acts as a solvent for the immobilized monomer. .
乳化重合法において用いられる乳化剤としては、界面活
性剤、高分子保護フロイドおよび共重合乳化剤が挙げら
れる。界面活性剤としては、当該分野において公知のア
ニオン活性剤、ノニオン活性剤、カチオン活性剤及び両
性活性剤が挙げられる。Emulsifiers used in the emulsion polymerization method include surfactants, polymeric protective fluids, and copolymer emulsifiers. Surfactants include anionic surfactants, nonionic surfactants, cationic surfactants, and amphoteric surfactants known in the art.
アニオン活性剤の例としては、石ケン類、ドデシルベン
ゼンスルホン酸ナトリウム、ラウリル硫酸ナトリウム、
ジオクチルスルホコハク酸ナトリウム、ノニオン活性剤
の硫!塩等が挙げられる。Examples of anionic activators include soaps, sodium dodecylbenzenesulfonate, sodium lauryl sulfate,
Sodium dioctyl sulfosuccinate, nonionic activator sulfur! Examples include salt.
ノニオン活性剤の例としては、ポリオキシエチレンノニ
ルフェニルエーテル、ポリオキシエチレンステアリン酸
エステル、ポリオキシエチレンソルビタンモノラウリル
酸エステル、ボリオギジ]。Examples of nonionic surfactants include polyoxyethylene nonylphenyl ether, polyoxyethylene stearate, polyoxyethylene sorbitan monolaurate, and boriogidi].
チレンーポリオキシプロピレンブロック共正合体等が挙
げられる。またカチオン活性剤の例としては、アルキル
ピリジウム塩、第3アミン短等が挙げられる。Examples include a tyrene-polyoxypropylene block copolymer. Further, examples of cationic activators include alkylpyridium salts, tertiary amine shorteners, and the like.
また、両性活性剤の例としては、ジメチルアルキルベタ
イン類、アルキルグリシン類等が挙げられる。また高分
子保護コロイドとしては、ポリビニルアルコール、ヒト
Oキシエチルセルロース等が挙げられる。これらの保護
コロイドは、単独で乳化剤として用いてもよく、また他
の界面活性剤と組み合せて用いてもよい。これらの活性
剤の種類およびその作用についてtよ、ベルギシェ・ケ
ミシx−インダストリ、(3clgische Ch
emischeI ndustrie) 28.113
−20 (1963)に記載されている。Furthermore, examples of amphoteric surfactants include dimethylalkylbetaines, alkylglycines, and the like. Further, examples of the polymeric protective colloid include polyvinyl alcohol, human O-oxyethylcellulose, and the like. These protective colloids may be used alone as emulsifiers or in combination with other surfactants. Regarding the types of these activators and their effects, please refer to Bergische Chemische x-Industrie (3clgische Ch.
28.113
-20 (1963).
溶液重合法等によって合成された親油性ポリマーをゼラ
チン水溶液中にラテックスの形で分散するには、まず親
油性ポリマーを有澄溶媒中に溶かしたのち、これをゼラ
チン水溶液中に分散剤の助けをかりて、超音波、コロイ
ドミル笠によりラテックス状に分散する。親油性ポリマ
ーをぜう1−ン水溶液中にラテックスの形で分散する方
法については米田特訂第3.451.820号に記載さ
れている。To disperse a lipophilic polymer synthesized by a solution polymerization method in the form of a latex in an aqueous gelatin solution, the lipophilic polymer is first dissolved in a clear solvent, and then dissolved in an aqueous gelatin solution with the help of a dispersant. Then, it is dispersed into latex using ultrasonic waves and a colloid mill. A method of dispersing a lipophilic polymer in the form of a latex in an aqueous solution of olefin is described in Yoneda Special Edition No. 3.451.820.
親油性ポリマーを溶解する有機溶媒としては、エステル
類、例えば酢酸メチル、酢酸エチル、61酸プロピル等
、アルコール類、ケ]−ン類、ハロゲン化炭化水素、エ
ーテル類等を用いることができる。As the organic solvent for dissolving the lipophilic polymer, esters such as methyl acetate, ethyl acetate, propyl 61-ate, etc., alcohols, carbons, halogenated hydrocarbons, ethers, etc. can be used.
またこれらの有機溶媒は、単独で又は2種以上を組み合
せて用いることができる。Moreover, these organic solvents can be used alone or in combination of two or more.
本発明のマゼンタポリマーカプラーを製造するにあたっ
て、重合に用いる溶媒としては単岱体および生成するマ
ゼンタポリマーカプラーの良r11媒であり、重合開始
剤との反応性が低いものが望ましい。具体的には水、l
−ルエン、アルコール(例えばメタノール、エタノール
、1so−プロパツール、tert−ブタノール等)、
アセトン、メチルエチルケトン、テ1−ラヒドロフラン
、ジオキサン、酢酸エチル、ジメチルボルムアミド、ジ
メチルスルホキシド、アセト二i−リル、塩化メチレン
等を挙げることかでき、これらの溶媒は単独でもしくは
2種以上混合して使用してもよい。In producing the magenta polymer coupler of the present invention, the solvent used for polymerization is preferably a solvent that is a good R11 medium for the monomer and the produced magenta polymer coupler and has low reactivity with the polymerization initiator. Specifically, water, l
- toluene, alcohol (e.g. methanol, ethanol, 1so-propanol, tert-butanol, etc.),
Examples include acetone, methyl ethyl ketone, tetrahydrofuran, dioxane, ethyl acetate, dimethylborumamide, dimethyl sulfoxide, acetonyl-lyl, methylene chloride, etc., and these solvents can be used alone or in a mixture of two or more. You may.
重合温度は重合開始剤の種類、使用する溶媒の種類等を
考處する必要があるが通常は30〜120℃の範囲であ
る。Although it is necessary to consider the type of polymerization initiator, the type of solvent used, etc., the polymerization temperature is usually in the range of 30 to 120°C.
本発明のマゼンタポリマーカプラーの乳化重合法および
溶液重合法に用いられる重合開始剤としては、以下に示
すものが挙げられる。Examples of the polymerization initiator used in the emulsion polymerization method and solution polymerization method of the magenta polymer coupler of the present invention include those shown below.
水溶性重合開始剤としては、例えば過硫酸カリウム、過
硫酸アンモニウム、過Iii!tr!IJナトリウム等
の過W& M塩類、4,4′−アゾビス−4−シアノ吉
草酸ナトリウム、2.2’ −アゾビス(2−アミジノ
プロパン)塩酸塩等の水溶性アゾ化合物、過酸化水素を
用いることができる。Examples of water-soluble polymerization initiators include potassium persulfate, ammonium persulfate, and perIII! tr! Use perw&m salts such as IJ sodium, water-soluble azo compounds such as sodium 4,4'-azobis-4-cyanovalerate, 2,2'-azobis(2-amidinopropane) hydrochloride, and hydrogen peroxide. I can do it.
また、溶液重合法に用いられる親油性重合開始剤として
は、例えばアゾビスイソブチロニトリル、2.2′〜ア
ゾビス−(2,4−ジメチルバレロニトリル)、2.2
’ −アゾビス(4−メトキシ−2,4−ジメチルバレ
ロニトリル)、1.1’−アゾビス(シクロへキサノン
−1−カルボニトリル)、2.2’ −アゾビスイソシ
アノ酪酸、2.2′−アゾビスイソ酪酸ジメチル、1.
1′−アゾビス(シクロへキサノン−1−カルボニトリ
ル>、4.4’ −アゾビス−4−シアノ古草駁宿のア
ゾ化合物、ベンゾイルパーオキサイド、ラウリルパー号
キサイド、り【]ロベンジルバーオキザイド、ジイソブ
ロピルバーオキシジカルボネート、ジ−t−ブチルパー
オキサイド等の過酸化物等を挙げることができる。これ
らのうち好ましいものは、ベンゾイルパーオキサイド、
クロロベンジルバーオキ勺イド、ラウリルパー号キサイ
ド等を挙げることができる。In addition, examples of the lipophilic polymerization initiator used in the solution polymerization method include azobisisobutyronitrile, 2.2'-azobis-(2,4-dimethylvaleronitrile), 2.2
' -azobis(4-methoxy-2,4-dimethylvaleronitrile), 1.1'-azobis(cyclohexanone-1-carbonitrile), 2.2' -azobisisocyanobutyric acid, 2.2'- Dimethyl azobisisobutyrate, 1.
1'-azobis(cyclohexanone-1-carbonitrile), 4,4'-azobis-4-cyano azo compound of ancient grass, benzoyl peroxide, lauryl peroxide, [] lobenzyl peroxide, Examples include peroxides such as diisopropylberoxydicarbonate and di-t-butyl peroxide. Among these, preferred are benzoyl peroxide,
Examples include chlorobenzyl peroxide and lauryl peroxide.
これらの重合開始剤は、乳化重合法および溶液重合法に
おいて七ツマー全aに対して0.01〜10mff1%
の範囲、好ましくは0,1〜5[i%の範囲で含有せし
めることができる。These polymerization initiators are used in an amount of 0.01 to 10mff1% based on the total a of seven polymers in emulsion polymerization and solution polymerization.
It can be contained in a range of, preferably 0.1 to 5 [i%].
さらにまた、上記重合法以外の重合法、例えば、懸濁重
合、塊状重合等の方法も適用することができる。Furthermore, polymerization methods other than the above-mentioned polymerization methods, such as suspension polymerization and bulk polymerization, can also be applied.
以下に本発明の前記一般式(1)で表わされるマゼンタ
カプラーの代表的具体例を示づが、本発明はこれらに限
定されるものではない。Typical specific examples of the magenta coupler represented by the general formula (1) of the present invention are shown below, but the present invention is not limited thereto.
例示化合物
−I
へ
リ本発明の前記一般式(1)で表わされ
るマゼンタカプラーの代表的合成例を示す。To Exemplified Compound-I
A typical synthesis example of the magenta coupler represented by the general formula (1) of the present invention will be shown below.
合成例−1
例示化合物M−3の合成
1−フェニル−3−アミノ−5−ピラゾロン、35(l
を300−のアセトニトリルと20 dの混合溶媒中に
加え、撹拌しながらα−(2,4−ジーtert−ペン
チルフェノキシ)路間クロライド70aと2001gの
アセトニトリルの混合溶液を滴下した後、さらに1時間
加熱還流をおこなった。Synthesis Example-1 Synthesis of Exemplified Compound M-3 1-phenyl-3-amino-5-pyrazolone, 35(l
was added to a mixed solvent of 300 g of acetonitrile and 20 g of acetonitrile, and a mixed solution of α-(2,4-di-tert-pentylphenoxy) chloride 70a and 2001 g of acetonitrile was added dropwise with stirring, followed by further 1 hour. The mixture was heated to reflux.
この反応液を冷却し、析出する固体をろ別、乾燥した。This reaction solution was cooled, and the precipitated solid was filtered off and dried.
この固体47.713を200顧の酢酸に加え、撹拌し
ながら25℃以下で8gの亜硝間ソーダを加え、ざらに
2時間空温で撹拌した。この反応液を600 *(lの
水に加え、析出する固体をろ別した。この固体25.3
Qを酢酸2501に溶解し、1G、 5(Jの北鉛を徐
々に加えた後、さらに30分撹拌し、反応液をろ過した
。ろalに無水コハクf45.(iQおよび無水酢酸2
5−を加え、2時間撹拌後ろ過し、ろ液を12の水に注
油し、析出する固体をろ別し、アセトコ1〜リルにて再
結晶して目的物21.20を得た。47.713 of this solid was added to 200 g of acetic acid, and while stirring, 8 g of internitrous soda was added at below 25° C., and the mixture was stirred roughly for 2 hours at air temperature. This reaction solution was added to 600*(l) of water, and the precipitated solid was filtered off.
After dissolving Q in acetic acid 2501 and gradually adding 1G and 5 (J) of northern lead, it was further stirred for 30 minutes and the reaction solution was filtered.
After stirring for 2 hours, the mixture was filtered, the filtrate was poured into water from Step 12, and the precipitated solid was filtered off and recrystallized with Acetocol 1-Ryl to obtain the desired product 21.20.
合成例−2
例示化合物M−15の合成
(1)カプラーモノマーの合成
1−フェニル−3−アミノ−5−ピラゾロンを出発原料
とし、合成例−1と同様にメタクリル酸クロライドによ
り1−フェニル−3−アミノ−5−ピラゾロンの3位の
アミノ基をアシル化し、さらに合成例−1と同様の方法
によりニトロリ化、還元、イミド化反応によりカプラー
モノマーを合成した。Synthesis Example 2 Synthesis of Exemplified Compound M-15 (1) Synthesis of Coupler Monomer Using 1-phenyl-3-amino-5-pyrazolone as a starting material, 1-phenyl-3 was synthesized with methacrylic acid chloride in the same manner as in Synthesis Example 1. The amino group at the 3-position of -amino-5-pyrazolone was acylated, and a coupler monomer was further synthesized by nitration, reduction, and imidization reactions in the same manner as in Synthesis Example-1.
(2)ポリマーの合成
上記で構成したカプラーモノマー6gとブチルアクリレ
ート40を5(h+12のジメチルホルムアミドに溶解
し、窒素気流下80〜82℃に維持し、200a+gの
2,2−アゾビスイソブチロニトリルを2時間間隔で2
回添加し、4時間反応させた。(2) Synthesis of polymer 6 g of the coupler monomer constructed above and 40 butyl acrylate were dissolved in 5 (h + 12) dimethylformamide, maintained at 80 to 82 °C under a nitrogen stream, and 200 a + g of 2,2-azobisisobutylene Nitrile 2 times at 2 hour intervals
The mixture was added twice and reacted for 4 hours.
反応終了後、反応液を5002の水に注ぎ込み、析出す
る固体をろ別、乾燥して目的のポリマー9.2gを得た
。After the reaction was completed, the reaction solution was poured into 5002 water, and the precipitated solid was filtered off and dried to obtain 9.2 g of the desired polymer.
本発明のカプラーは単独で用いてもよいし、2つ以上用
いてもよい。その使用口は限定的でなく、カプラーの種
類、単用かまたは2種以上の併用使用か、或いは本発明
の感光材料の写真構成層が単層かまたは2府以上の重層
か等に応じて決定すればよいが、例えばその使用量は1
12当たり0.005(1〜10g1好ましくは0.1
0〜5,0g用いることができる。The couplers of the present invention may be used alone or in combination of two or more. The usage thereof is not limited, and depends on the type of coupler, whether it is used alone or in combination of two or more, and whether the photographic constituent layer of the light-sensitive material of the present invention is a single layer or a multilayer of two or more layers. For example, the usage amount is 1.
0.005 per 12 (1 to 10 g 1 preferably 0.1
0 to 5.0 g can be used.
本発明に用いるカプラーを熱現像カラー感光材料の写真
構成口に含有せしめる方法は任意であり、例えば低沸点
溶媒(メタノール、エタノール、酢酸エチル等)または
高沸点溶媒(ジブチルフタレート、ジオクチルフタレー
ト、トリクレジルホスフェート等)に溶解した後、超音
波分散するか、あるいはアルカリ水溶液(例えば、水酸
化ナトリウム10%水溶液等)に溶解した後、鉱酸(V
Aえば、加重または晴間等)にて中和して用いるか、あ
るいは適当なポリマーの水溶液(例えば、ゼラチン、ポ
リビニルブチラール、ポリビニルピロリドン等)と共に
ボールミルを用いて分散させた後、使用することができ
る。The method of incorporating the coupler used in the present invention into the photographic component of the heat-developable color light-sensitive material is arbitrary. Mineral acid (V
A: For example, it can be used after being neutralized by applying weight or drying, or after being dispersed with an appropriate polymer aqueous solution (e.g., gelatin, polyvinyl butyral, polyvinyl pyrrolidone, etc.) using a ball mill. .
本発明の熱現像カラー感光材料には、前記カプラーと共
に感光性ハロゲン化銀を含有する。The heat-developable color photosensitive material of the present invention contains photosensitive silver halide together with the coupler.
本発明に用いられる感光性ハロゲン化銀としては、塩化
銀、臭化銀、沃化銀、塩臭化銀、塩沃化銀、沃臭化銀、
加法臭化m等があげられる。該感光性ハロゲン化銀は、
写真技術分野のシングルジェット法やダブルジェット法
等の任意の方法で調製することができるが、本発明に於
いては、通常のハロゲン化銀ゼラチン乳剤の調製方法に
従って調製した感光性ハロゲン化銀を含む感光性ハロゲ
ン化銀乳剤が好ましい結果を与える。The photosensitive silver halide used in the present invention includes silver chloride, silver bromide, silver iodide, silver chlorobromide, silver chloroiodide, silver iodobromide,
Examples include additive bromide m. The photosensitive silver halide is
Although it can be prepared by any method in the photographic field such as a single jet method or a double jet method, in the present invention, a photosensitive silver halide gelatin emulsion prepared according to a conventional method for preparing a silver halide gelatin emulsion is used. A light-sensitive silver halide emulsion containing 0.05 to 1.5 g gives favorable results.
該感光性ハロゲン化銀乳剤は、写真技術分野の任意の方
法で化学的に増感しても良い。かかる増感法としては、
金増感、イオウ増感、金−イオウ増感、還元増感等各種
の方法があげられる。The light-sensitive silver halide emulsion may be chemically sensitized by any method known in the photographic art. Such sensitization methods include
Various methods include gold sensitization, sulfur sensitization, gold-sulfur sensitization, and reduction sensitization.
上記感光性乳剤中のハロゲン化銀は、粗粒子であっても
微粒子であっても良いが、好ましい粒子サイズは、その
径が約0.001μm〜約1.5μmであり、さらに好
ましくは約0.01μm〜約0.5μmである。The silver halide in the above-mentioned photosensitive emulsion may be coarse or fine, but the preferred grain size is about 0.001 μm to about 1.5 μm, more preferably about 0.001 μm to about 1.5 μm, and more preferably about 0.001 μm to about 1.5 μm. .01 μm to about 0.5 μm.
、上記のようにwJ製された感光性ハロゲン化銀乳剤を
本発明の感光材料の構成層である熱現像性感光層に最も
好ましく適用することができる。The photosensitive silver halide emulsion prepared by WJ as described above can most preferably be applied to the heat-developable photosensitive layer which is a constituent layer of the photosensitive material of the present invention.
本発明において、他の感光性ハロゲン化銀の調製法とし
て、感光性銀塩形成成分を後述する有機銀塩と共存させ
、有機銀塩の一部に感光性ハロゲン化銀を形成させるこ
ともできる。このm製法に用いられる感光性銀塩形成成
分としては、無菌ハロゲン化物、例えば、MXnで表わ
されるハロゲン化物(ここで、MはH原子、NH4基ま
たは金属原子を表わし、Xは(/!、Brまたは■を表
わし、nはMがH原子、N84基の時は1、Mが金属原
子の時はその原子価を示す。金属原子としては、リチウ
ム、ナトリウム、カリウム、ルビジウム、セシウム、銅
、金、ベリリウム、マグネシウム、カルシウム、ストロ
ンチウム、バリウム、亜鉛、カドミウム、水銀、アルミ
ニウム、インジウム、ランタン、ルテニウム、タリウム
、ゲルマニウム、錫、鉛、アンチモン、ビスマス、クロ
ム、モリブデン、タングステン、マンガン、レニウム、
鉄、コバル1〜、ニッケル、ロジウム、パラジウム、オ
スミウム、イリジウム、白金、セリウム等があげられる
。)、含ハロゲン金m1体(例えば、K2 Pt C1
6,に2 Pt 3r s 、HAtl C14゜(N
H4)2 Ir C1s、(NHq )31r (、C
6゜(NH4)2 RU C16,(NHq )a R
(I C1a 。In the present invention, as another method for preparing photosensitive silver halide, it is also possible to allow a photosensitive silver salt-forming component to coexist with an organic silver salt described below to form photosensitive silver halide in a part of the organic silver salt. . The photosensitive silver salt-forming component used in this manufacturing method is a sterile halide, for example, a halide represented by MXn (where M represents an H atom, an NH4 group, or a metal atom, and X represents (/!, Br or ■, n is 1 when M is an H atom or an N84 group, and the valence when M is a metal atom.Metal atoms include lithium, sodium, potassium, rubidium, cesium, copper, Gold, beryllium, magnesium, calcium, strontium, barium, zinc, cadmium, mercury, aluminum, indium, lanthanum, ruthenium, thallium, germanium, tin, lead, antimony, bismuth, chromium, molybdenum, tungsten, manganese, rhenium,
Examples include iron, Kobal 1~, nickel, rhodium, palladium, osmium, iridium, platinum, and cerium. ), halogen-containing gold m1 body (for example, K2 Pt C1
6, 2 Pt 3rs, HAtl C14゜(N
H4)2 Ir C1s, (NHq)31r (,C
6゜(NH4)2 RU C16, (NHq)a R
(IC1a.
(NH4)a Rh C4!s、(NH4)3 Rh
3r s等)、オニウムハライド(例えば、テトラメチ
ルアンモニウムブロマイド、トリメデルフェニルアンモ
ニウムブロマイド、セチルエチルジメチルアンモニウム
ブロマイド、3−メチルチアゾリウムブロマイド、トリ
メチルベンジルアンモニウムブロマイドのような4級ア
ンモニウムハライド、テトラエチルフォスフオニウムブ
ロマイドのような4級)Aスフオニウムハライド、ベン
ジルエチルメチルスルホニウムブロマイド、1−エチル
チアゾリウムブロマイドのような3級スルホニウムハラ
イド等)、ハロゲン化炭化水素(例えば、ヨードホルム
、ブロモホルム、四臭化炭素、2−ブロモ−2−メチル
プロパン等)、N−ハロゲン化合物(N−クロロコハク
酸イミド、N−ブロモコハク酸イミド、N−ブロモフタ
ル酸イミド、N−ブロモアセトアミド、N−ヨードコハ
ク酸イミド、N−ブロモフタラジノン、N−クロロフタ
ラジノン、N−ブロモアセトアニリド、N、N−ジブロ
モベンゼンスルホンアミド、N−ブロモ−N−メチルベ
ンゼンスルホンアミド、1,3−ジブロモ−4,4−ジ
メチルヒダントイン等)、その他の含ハロゲン化合物(
例えば塩化トリフェニルメチル、臭化トリフェニルメチ
ル、2−ブロモ(ffi!酸、2−ブロモエタノール等
)などをあげることができる。(NH4)a Rh C4! s, (NH4)3 Rh
3rs, etc.), onium halides (e.g., quaternary ammonium halides such as tetramethylammonium bromide, trimedelphenylammonium bromide, cetylethyldimethylammonium bromide, 3-methylthiazolium bromide, trimethylbenzylammonium bromide, tetraethylphosph) quaternary sulfonium halides such as onium bromide, tertiary sulfonium halides such as benzylethylmethylsulfonium bromide, 1-ethylthiazolium bromide, etc.), halogenated hydrocarbons (e.g. iodoform, bromoform, tetrabromide, etc.), carbon, 2-bromo-2-methylpropane, etc.), N-halogen compounds (N-chlorosuccinimide, N-bromosuccinimide, N-bromophthalimide, N-bromoacetamide, N-iodosuccinimide, N-bromo phthalazinone, N-chlorophthalazinone, N-bromoacetanilide, N,N-dibromobenzenesulfonamide, N-bromo-N-methylbenzenesulfonamide, 1,3-dibromo-4,4-dimethylhydantoin, etc.), Other halogen-containing compounds (
Examples include triphenylmethyl chloride, triphenylmethyl bromide, 2-bromo (ffi! acid, 2-bromoethanol, etc.).
これら感光性ハロゲン化銀および感光性銀塩形成成分は
、種々の方法において組合せて使用でき、使用mは、一
層当り112に対して、0.001(1〜50gである
ことが好ましく、より好ましくは、 0.1g〜10
gである。These photosensitive silver halides and photosensitive silver salt-forming components can be used in combination in various methods, and the m used is 0.001 (preferably 1 to 50 g, more preferably 1 to 50 g) to 112 per layer. is 0.1g~10
It is g.
本発明の熱現象カラー感光材料は、青色光、緑色光、赤
色光に感光性を有する各層、即ち熱現像緑感光性層、熱
現像緑感光性層、熱現像緑感光性層として多層構成とづ
ることもできる。また、同色感光性図を2層以上(例え
ば、高感度層と低感度β)に分割して設けることもでき
る。The thermal color photosensitive material of the present invention has a multilayer structure including each layer sensitive to blue light, green light, and red light, that is, a heat-developable green-sensitive layer, a heat-developable green-sensitive layer, and a heat-developable green-sensitive layer. You can also write. Further, the same color photosensitive pattern can be divided into two or more layers (for example, a high-sensitivity layer and a low-sensitivity β layer).
上記の場合、各々用いられる胃感光性ハロゲン化銀乳剤
、緑感光性ハロゲン化銀乳剤、赤感光性ハロゲン化銀乳
剤は、前記ハロゲン化銀乳剤に各種の分光増感色素を加
えることによって得ることができる。In the above case, the stomach-sensitive silver halide emulsion, green-sensitive silver halide emulsion, and red-sensitive silver halide emulsion used, respectively, can be obtained by adding various spectral sensitizing dyes to the silver halide emulsion. I can do it.
本発明に用いられる代表的な分光増感色素としては、例
えばシアニン、メロシアニン、コンプレックス(3核又
は4核の)シアニン、ホロポーラ−シアニン、スチリル
、ヘミシアニン、オキソノール等があげられる。シアニ
ン類の色素のうちでチアゾリン、オキサゾリン、ビロリ
ン、ピリジン、オキサゾール、チアゾール、セレナゾー
ル、イミダゾールの様な塩基性核を有するものが、より
好ましい。この様な核にはアルキル基、アルキレン基、
ヒドロキシアルキル基、スルホアルギル基、カルボキシ
アルキル
縮合炭素環式または複素環色環を作る事の出来るエナミ
ン基を有していてもよい。また対称形でも非対称形でも
よく、またメチン鎖、ポリメチン鎖にアルキル基、フェ
ニル基、エナミン基、ヘテロ環置換基を有していてもよ
い。Typical spectral sensitizing dyes used in the present invention include, for example, cyanine, merocyanine, complex (trinuclear or tetranuclear) cyanine, holopolar cyanine, styryl, hemicyanine, oxonol, and the like. Among the cyanine dyes, those having a basic nucleus such as thiazoline, oxazoline, viroline, pyridine, oxazole, thiazole, selenazole, and imidazole are more preferred. Such nuclei include alkyl groups, alkylene groups,
It may have a hydroxyalkyl group, a sulfoargyl group, or an enamine group capable of forming a carboxyalkyl fused carbocyclic or heterocyclic ring. Further, it may be symmetrical or asymmetrical, and the methine chain or polymethine chain may have an alkyl group, a phenyl group, an enamine group, or a heterocyclic substituent.
メロシアニン色素は上記塩基性核の他に、例えばチオヒ
ダントイン核、ローダニン核、オキサゾリジオン核、チ
アゾリジンジオン核、バルビッール成核、チアゾリンチ
オン咳、マロノニトリル核、ピラゾロン核の様な酸性核
を有していてもよい。In addition to the above-mentioned basic nucleus, merocyanine dyes may have acidic nuclei such as thiohydantoin nucleus, rhodanine nucleus, oxazolidione nucleus, thiazolidinedione nucleus, barbyl nucleation, thiazolinthione nucleus, malononitrile nucleus, and pyrazolone nucleus. good.
これらの酸性核は更にアルキル基、アルキレン基、フェ
ニル基、カルボキシアルキル
ル基、ヒドロキシアルキル基、アルコギルアルキル基、
アルキルアミン基又はヘテロ環式核で買換されていても
よい。又必要ならばこれらの色素を組合わせて使用して
もよい。更にアスコルビンm M導体、アザインデンカ
ドミウム塩、有殿スルホン酸等、例えば米国特許第2,
933, 390号、同第2、937,089号の明
細書等に記載されている様な可視光を吸収しない超増感
性添加剤を併用することができる。These acidic nuclei further include alkyl groups, alkylene groups, phenyl groups, carboxyalkyl groups, hydroxyalkyl groups, alkogylalkyl groups,
It may be replaced with an alkylamine group or a heterocyclic nucleus. If necessary, these dyes may be used in combination. Furthermore, ascorbic mM conductors, azaindene cadmium salts, arideno sulfonic acids, etc., such as U.S. Patent No. 2,
A supersensitizing additive that does not absorb visible light, such as those described in the specifications of No. 933,390 and No. 2,937,089, can be used in combination.
これら色素の添加mはハロゲン化銀またはハロゲン化銀
形成成分1モル当り1X10−4モル〜1モルである。The addition m of these dyes is from 1.times.10@-4 mole to 1 mole per mole of silver halide or silver halide-forming component.
更に好ましくは、I X 1 0−4モル〜1×10″
1モルである。More preferably, I X 10-4 mol to 1×10″
It is 1 mole.
本発明の熱現像カラー感光材料においては、必要に応じ
て感度の上昇や現像性の向上を目的として各種の有機銀
塩を用いることができる。In the heat-developable color photosensitive material of the present invention, various organic silver salts can be used, if necessary, for the purpose of increasing sensitivity and improving developability.
本発明の熱現像カラー感光材料に用いられる有機銀塩と
しては、特公昭43−4921号、同44−26582
号、同45−18416号、同45−12700号、同
45−22185号、特開昭49−52(i26号、同
52−31728号、同52−137321号、同52
−141222号、同53−36224号および同53
−37610号等の各公報ならびに米国特許第3, 3
30, 633号、同第3,794,496号、同第4
,105,451号、同第4、 123, 274号、
同第4,IO2,980号等の各明細山中に記載されて
いるような脂肪族カルボン酸の銀塩、例えばラウリン酸
銀、ミリスチン酸銀、バルミヂン酸銀、ステアリンrl
i銀、アラキドン酸銀、べへンMWi、α−(1−フェ
ニルテトラゾールチオ)酢酸銀など、芳香族カルボン酸
銀、例えば安息香lS!2銀、フタル酸銀など、特公昭
44−26582号、同45−12700号、同45−
18416号、同45−22185号、特開昭52−3
1728号、同52−137321号、特開昭58−1
18638号、同58−118639号等の各公報に記
載されているようなイミノ基の銀塩、例えばベンゾトリ
アゾール銀、5−ニトロベンゾトリアゾール銀、5−ク
ロロベンゾトリアゾール銀、5−メトキシベンゾトリア
ゾール銀、4−スルホベンゾトリアゾール銀、4−ヒド
ロキシベンゾトリアゾール銀1.5−アミノベンゾトリ
アゾール銀、5−カルボキシベンゾトリアゾール銀、イ
ミダゾール銀、ベンズイミダゾール銀、6−ニドロペン
ズイミダゾール銀、ピラゾール銀、ウラゾール銀、1,
2.4−トリアゾール銀、1H−テトラゾール銀、3−
アミノ−5−ペンジルチオ−1,2,4−トリアゾール
銀、サッカリン銀、フタラジノン銀、フタルイミド銀な
ど、その他2−メルカプトベンゾオキサゾール銀、メル
カプトオキサジアゾール銀、2−メルカプトベンゾチア
ゾール
イミダゾール
ニル−1,2.4.−トリアゾール銀、4−ヒドロキシ
−6−メチル−1.3.3a.7−デトラザインデン銀
および5−メチル−7−ヒドロキシ−1、2.3.4.
6−ペンタザインデン銀などが挙げられる。以上の有機
銀塩のうちでもイミノ基の銀塩が好ましく、特にベンゾ
トリアゾール誘導体の銀塩、より好ましくはスルホベン
ゾ1〜リアゾール誘導体の銀塩が好ましい。Examples of organic silver salts used in the heat-developable color photosensitive material of the present invention include Japanese Patent Publication Nos. 43-4921 and 44-26582.
No. 45-18416, No. 45-12700, No. 45-22185, JP-A-49-52 (i26, No. 52-31728, No. 52-137321, No. 52)
-141222, 53-36224 and 53
Publications such as -37610 and U.S. Patent Nos. 3 and 3
No. 30, 633, No. 3,794,496, No. 4
, No. 105, 451, No. 4, No. 123, 274,
Silver salts of aliphatic carboxylic acids, such as silver laurate, silver myristate, silver valmidate, stearin rl, as described in the specifications of the same No. 4, IO2,980, etc.
Silver aromatic carboxylates, such as silver i, silver arachidonic acid, behen MWi, silver α-(1-phenyltetrazolthio) acetate, such as benzoic acid! 2 silver, silver phthalate, etc., Japanese Patent Publications No. 44-26582, No. 45-12700, No. 45-
No. 18416, No. 45-22185, JP-A-52-3
No. 1728, No. 52-137321, JP-A-58-1
Silver salts of imino groups such as those described in publications such as No. 18638 and No. 58-118639, such as silver benzotriazole, silver 5-nitrobenzotriazole, silver 5-chlorobenzotriazole, silver 5-methoxybenzotriazole , 4-sulfobenzotriazole silver, 4-hydroxybenzotriazole silver 1,5-aminobenzotriazole silver, 5-carboxybenzotriazole silver, imidazole silver, benzimidazole silver, 6-nidropenzimidazole silver, pyrazole silver, urazole silver ,1,
2.4-triazole silver, 1H-tetrazole silver, 3-
Silver amino-5-pendylthio-1,2,4-triazole, silver saccharin, silver phthalazinone, silver phthalimide, etc., silver 2-mercaptobenzoxazole, silver mercaptooxadiazole, silver 2-mercaptobenzothiazoleimidazol-1,2 .4. - triazole silver, 4-hydroxy-6-methyl-1.3.3a. 7-detrazaindene silver and 5-methyl-7-hydroxy-1, 2.3.4.
Examples include 6-pentazaindene silver. Among the above organic silver salts, imino group silver salts are preferred, and silver salts of benzotriazole derivatives are particularly preferred, and silver salts of sulfobenzo-1-lyazole derivatives are particularly preferred.
本発明に用いられる有機銀塩は、単独でも或いは2種以
上併用して用いてもよく、単離したものを適当な手段に
よりバインダー中に分散して使用に供してもよいし、ま
た適当なバインダー中で銀塩を[し、単離せずにそのま
ま使用に供してもよい。The organic silver salts used in the present invention may be used alone or in combination of two or more, and isolated ones may be used by dispersing them in a binder by appropriate means, or they may be used in a suitable form. The silver salt may be prepared in a binder and used as is without isolation.
該有機銀塩の使用口は、感光性ハロゲン化銀1モル当り
0.01〜500モルであることが好ましく、より好ま
しくは0.1モル〜100モルである。The amount of the organic silver salt to be used is preferably 0.01 to 500 mol, more preferably 0.1 to 100 mol, per 1 mol of photosensitive silver halide.
本発明の熱現像カラー感光材料に用いられる還元剤は、
熱現像カラー感光材料の分野で通常用いられるものを用
いることができ、例えば米国特許第3,531,286
号、同第3,761,270号、同第3。764132
8号各明Ii[明細、またR D N o.1214
6 、同No。The reducing agent used in the heat-developable color photosensitive material of the present invention is
Those commonly used in the field of heat-developable color photosensitive materials can be used; for example, those disclosed in U.S. Pat. No. 3,531,286
No. 3,761,270, No. 3.764132
No. 8 each Mei Ii [specifications, and R D No. 1214
6, same No.
15108、同N 0. 15127および特開昭56
−27132号公報等に記載のp−フェニレンジアミン
系およびp−アミンフェノール系現会主薬、フォスフォ
ロアミドフェノール系およびスルホンアミドフェノール
系現像主祭、またヒドラゾン系発色現像主薬が挙げられ
る。また、米国特許第3,342,599号、同第3,
719, 492号、特開昭53−135628号、
同54−79035号等に記載されている発色現像主薬
プレカーサー等も有利に用いることができる。15108, N0. 15127 and Japanese Unexamined Patent Publication No. 1983
Examples include p-phenylenediamine-based and p-aminephenol-based developing agents, phosphoramidophenol-based and sulfonamidophenol-based developing agents, and hydrazone-based color developing agents described in Publication No. 27132 and the like. Also, U.S. Patent No. 3,342,599;
No. 719, 492, JP-A-53-135628,
The color developing agent precursor described in Japanese Patent No. 54-79035 and the like can also be advantageously used.
特に好ましい還元剤として、特開昭56−146133
号明細四に記載されている下記一般式(3)で表わされ
る還元剤が挙げられる。As a particularly preferable reducing agent, JP-A-56-146133
Examples include reducing agents represented by the following general formula (3) described in Specification No. 4.
一般式(3)
式中、R4およびR5は水素原子、または置換基を有し
てもよい炭素原子数1〜30(好ましくは1〜4)のア
ルキル基を表わし、R4とR5とは閉環して複素環を形
成してもよい。Rs 、 R7R8およびR9は水素原
子、ハロゲン原子、ヒドロキシ基、アミノ基、アルコキ
シ基、アシルアミド基、スルホンアミド基、アルキルス
ルホンアミド基または置換基を有してもよい炭素原子数
1〜30(好ましくは1〜4)のアルキル基を表わし、
R6とR4およびR8とR5はそれぞれ閉環して複素環
を形成してもよい。Mはアルカリ余圧原子、アンモニウ
ム基、含窒素有機塩基または第4級窒素原子を含む化合
物を表わす。General formula (3) In the formula, R4 and R5 represent a hydrogen atom or an alkyl group having 1 to 30 carbon atoms (preferably 1 to 4) which may have a substituent, and R4 and R5 are ring-closed. may be used to form a heterocycle. Rs, R7R8 and R9 each have a hydrogen atom, a halogen atom, a hydroxy group, an amino group, an alkoxy group, an acylamido group, a sulfonamide group, an alkylsulfonamide group, or a carbon atom number of 1 to 30 (preferably 1 to 30 carbon atoms, which may have a substituent). 1 to 4) represents an alkyl group,
R6 and R4 and R8 and R5 may each be ring-closed to form a heterocycle. M represents an alkali excess atom, an ammonium group, a nitrogen-containing organic base, or a compound containing a quaternary nitrogen atom.
上記一般式(3)における含窒素有機塩基とは無t1M
と塩を生成し得る塩基性を示す窒素原子を含む有機化合
物であり、特に重要な有□塩基としてはアミン化合物が
挙げられる。そして鎮状のアミン化合物としては第1級
アミン、第2級アミン、第3級アミンなどが、また環状
のアミン化合物としては典型的なヘテロ環式有機塩基の
例として茗名なピリジン、キノリン、ピペリジン、イミ
ダゾール等が挙げられる。この他ヒドロキシルアミン、
ヒドラジン、アミジンなどの化合物も鎖状のアミンとし
て有用である。また含窒素布間塩基の塩としては上記の
ような有機塩基の無機酸塩(例えば塩酸塩、硫酸塩、硝
酸塩等)が好ましく用いられる。The nitrogen-containing organic base in the above general formula (3) has no t1M
It is an organic compound containing a basic nitrogen atom that can form a salt with a salt, and an especially important □ base includes an amine compound. Examples of amine compounds include primary amines, secondary amines, tertiary amines, etc., and examples of cyclic amine compounds include typical heterocyclic organic bases such as pyridine, quinoline, etc. Examples include piperidine and imidazole. In addition, hydroxylamine,
Compounds such as hydrazine and amidine are also useful as chain amines. As the salt of the nitrogen-containing base, inorganic acid salts of organic bases (eg, hydrochlorides, sulfates, nitrates, etc.) as mentioned above are preferably used.
一方、上記一般式における第4級窒素を含む化合物とし
ては、4価の共有結合を有する窒素化合物の塩または水
酸化物等が挙げられる。On the other hand, examples of the compound containing quaternary nitrogen in the above general formula include salts or hydroxides of nitrogen compounds having a tetravalent covalent bond.
次に一般式(3)で示される還元剤の好ましい具体例を
以下に示す。Next, preferred specific examples of the reducing agent represented by the general formula (3) are shown below.
以下余白
(R−1)
(R−2)
(R−3)
(R−4)
(R−7)
(R−8) 。6
(R−9)
H3
(R−10)
(R−11)
(R−12)
(R−15)
(R−16)
(R−17)
(R−18)
(R−19)
(R−20)
(R−21)
(R−22)
(R−23)
上記一般式(3)で表わされる還元剤は、公知の方法、
例えばホイベン・ペイル、メソッデン・デル・オーガニ
ツシエン・ヘミ−、バンドXI/2(1−1ouben
−Weyl 、 Methoden derOra
anischen Chen+ie 、 Band
XI/2) 645−703頁に2伎されている方法
に従って合成できる。The following margins are (R-1) (R-2) (R-3) (R-4) (R-7) (R-8). 6 (R-9) H3 (R-10) (R-11) (R-12) (R-15) (R-16) (R-17) (R-18) (R-19) (R- 20) (R-21) (R-22) (R-23) The reducing agent represented by the above general formula (3) can be prepared by a known method,
For example, Heuben Peil, Methoden der Organizien Hemi, Band XI/2 (1-1ouben
-Weyl, Methoden der Ora
Anischen Chen+ie, Band
XI/2) It can be synthesized according to the method described on pages 645-703.
その他以下に述べるような還元剤を用いることもできる
。Other reducing agents as described below can also be used.
例えば、フェノール類(例えばp−フェニルフェノール
、p−メトキシフェノール、2.6−ジー tert−
ブチル−p−クレゾール、N−メチル−〇−アミノフェ
ノール等)、スルホンアミドブ1ノール類[例えば4−
ベンゼンスルホンアミドフェノール、2−ペンピンスル
ホンアミドフェノール、2.6−ジクロロ−4−ベンゼ
ンスルホンアミドフェノール、2.6−ジプロモー4−
(1)−トルエンスルホンアミド)フェノール″3]、
またはポリヒドロキシベンピン類(例えばハイドロキノ
ン、tert−ブチルハイドロキノン、2.6−シメチ
ルハイドロキノン、クロロハイドロキノン、カルボキシ
ハイドロキノン、カテコール、3−カルボキシカテコー
ル等)、ナフト−ル類(例えばα−ナフトール、β−ナ
フトール、4−アミノナフト−ル、4−メトキシフェー
ル等)、ヒドロキシビナフチル類J3よびメチレンビス
ナフトール類[例えば1.1′−ジヒドロキシ−2,2
’ −ビナフチル、6.6′−ジブ口U−2,2’ −
ジヒドロキシ−1,1′−とナフチル、6,6−シニト
ロー2.2′−ジヒドロキシ−1,1′−ビナフチル、
4.4′−ジメI・キシ−1,1′−ジヒドロキシ−2
,2′−ビナフチル、ビス(2−ヒドロキシ−1−ナフ
チル)メタン等]、メチレンごスフエノール類[例えば
1.1−ビス(2−ヒドロキシ−3,5−ジエチルフェ
ニル)−3゜5.5−1〜リメチルヘキサン、1.1−
ビス(2−ヒドロキシ−3−tert−ブチル−5−メ
チルフェニル)メタン、1.1−ビス(2−ヒドロキシ
−3,5−ジーtart−ブチルフェニル)メタン、2
.6−メブレンピス(2−ヒドロキシ−3−tert−
ブチル−5−メチルフェニル)−4−メヂ−ルフェノー
ル、α−フェニル−α、α−ビス(2−ヒドロキシ−3
,5−ジーtert−ブチルフェニル)メタン、α−フ
ェニル−α、α−ビス(2−ヒドロキシ−3−tert
−ブチル−5−メチルフェニル)メタン、1.1−ビス
(2−ヒドロキシ−3,5−ジメチルフェニル)−2−
メチルプロパン、1.1.5.5−テトラキス(2−ヒ
ドロキシ−3,5−ジメチルフェニル)−2,4−エチ
ルペンタン、2,2−ビス(4−ヒドロキシ−3゜5−
ジメチルフェニル)プロパン、2.2−ビス(4−ヒド
ロキシ−3−メチル−5−tert−ブチルフェニル)
プロパン、2.2−ビス(4−ヒドロキシ−3,5−ジ
ーtert−ブチルフェニル)プロパン等]、アスコル
ビン酸類、3−ピラゾリドン類、ピラゾロン類、ヒドラ
ゾン類およびバラフェニレンジアミン類が挙げられる。For example, phenols (e.g. p-phenylphenol, p-methoxyphenol, 2,6-tert-
butyl-p-cresol, N-methyl-〇-aminophenol, etc.), sulfonamide butinols [e.g. 4-
Benzenesulfonamidophenol, 2-penpinesulfonamidophenol, 2,6-dichloro-4-benzenesulfonamidophenol, 2.6-dipromo 4-
(1)-Toluenesulfonamide)phenol''3],
or polyhydroxybenpines (e.g., hydroquinone, tert-butylhydroquinone, 2,6-dimethylhydroquinone, chlorohydroquinone, carboxyhydroquinone, catechol, 3-carboxycatechol, etc.), naphthols (e.g., α-naphthol, β- naphthol, 4-aminonaphthol, 4-methoxyphel, etc.), hydroxybinaphthyls J3 and methylene bisnaphthols [e.g. 1,1'-dihydroxy-2,2
' - Binaphthyl, 6.6' - Jib mouth U-2,2' -
dihydroxy-1,1'- and naphthyl, 6,6-sinitro-2,2'-dihydroxy-1,1'-binaphthyl,
4.4'-dimeI xy-1,1'-dihydroxy-2
, 2'-binaphthyl, bis(2-hydroxy-1-naphthyl)methane, etc.], methylene-sphenols [e.g. 1.1-bis(2-hydroxy-3,5-diethylphenyl)-3゜5.5- 1-limethylhexane, 1.1-
Bis(2-hydroxy-3-tert-butyl-5-methylphenyl)methane, 1,1-bis(2-hydroxy-3,5-di-tart-butylphenyl)methane, 2
.. 6-meblenpis (2-hydroxy-3-tert-
Butyl-5-methylphenyl)-4-medylphenol, α-phenyl-α, α-bis(2-hydroxy-3
, 5-di-tert-butylphenyl)methane, α-phenyl-α, α-bis(2-hydroxy-3-tert
-butyl-5-methylphenyl)methane, 1,1-bis(2-hydroxy-3,5-dimethylphenyl)-2-
Methylpropane, 1.1.5.5-tetrakis(2-hydroxy-3,5-dimethylphenyl)-2,4-ethylpentane, 2,2-bis(4-hydroxy-3°5-
dimethylphenyl)propane, 2,2-bis(4-hydroxy-3-methyl-5-tert-butylphenyl)
propane, 2,2-bis(4-hydroxy-3,5-di-tert-butylphenyl)propane, etc.], ascorbic acids, 3-pyrazolidones, pyrazolones, hydrazones, and paraphenylenediamines.
これら還元剤は単独、或いは2種以上組合せて用いるこ
ともできる。還元剤の使用量は、使用される感光性ハロ
ゲン化銀の種類、有機醒銀塩の種類およびその他の添加
剤の種類などに(?i存するが、通常は感光性ハロゲン
化銀1モルに対して0.01〜1500モルの範囲であ
り、好ましくは081〜200モルである。These reducing agents can be used alone or in combination of two or more. The amount of reducing agent to be used depends on the type of photosensitive silver halide, the type of organic silver halide used, and the type of other additives, but it is usually 1 mole of photosensitive silver halide. The amount ranges from 0.01 to 1500 mol, preferably from 081 to 200 mol.
本発明の熱現像カラー感光材温1に用いられるバインダ
ーとしては、ポリビニルブチラール、ポリ[ビニル、エ
チルセルロース、ポリメチルメタクリレート、セルロー
スアセテートブチレート、ポリビニルアルコール、ボリ
ヒニルピし]リドン、ゼラチンおよびフタル化ゼラチン
等の合成或いは天然の高分子物質を1又は2以上組合せ
て用いることができる。特に、ゼラチンまたはそのx
G体とポリビニルピロリドン、ポリビニルアルコール等
の親水性ポリマーとを併用することは好ましく、より好
ましくは特開昭59−229556号に記載の以下の如
きバインダーである。Examples of the binder used in the heat-developable color photosensitive material 1 of the present invention include polyvinyl butyral, poly[vinyl, ethylcellulose, polymethyl methacrylate, cellulose acetate butyrate, polyvinyl alcohol, polyvinylpylene]ridone, gelatin, and phthalated gelatin. One or a combination of two or more synthetic or natural polymeric substances can be used. In particular, gelatin or
It is preferable to use the G-form together with a hydrophilic polymer such as polyvinylpyrrolidone or polyvinyl alcohol, and more preferably the following binder described in JP-A-59-229556.
このバインダーは、ゼラチン及びビニルピロリドン重合
体を含むものである。ビニルピロリドン重合体はビニル
とロリドンの単−m合体であるポリビニルピロリドンで
あってもよいし、ビニルピロリドンと共重合可能な他の
モノマーの1又は2以上との共m合体(グラフト共重合
体を含む。)であってもよい。これらのポリマーはその
重合度に関係なく用いることができる。ポリビニルピロ
リドンは置換ポリビニルピロリドンであってもよく、好
ましいポリビニルピロリドンは分子m1.000〜40
0.000のものである。ビニルピロリドンと共重合可
能な他のモノマーとしては、アクリル酸、メタクリル酸
及びそのアルキルエステルの如き(メタ)アクリル酸エ
ステル類、ビニルアルコール類、ビニルイミダゾール類
、(メタ)アクリルアミド類、ビニルカルビノール類、
ビニルアルキルエーテル類等のビニル系七ツマー筈が挙
げられるが、組成比の少なくとも20%(重量%、以下
同じ)はポリビニルピロリドンであることが好ましい。This binder includes gelatin and vinylpyrrolidone polymer. The vinyl pyrrolidone polymer may be polyvinyl pyrrolidone, which is a mono-m polymer of vinyl and lolidone, or a co-m polymer (graft copolymer) with vinyl pyrrolidone and one or more other monomers copolymerizable with vinyl pyrrolidone. ) may be included. These polymers can be used regardless of their degree of polymerization. The polyvinylpyrrolidone may be substituted polyvinylpyrrolidone, and preferred polyvinylpyrrolidone has a molecular m1.000 to 40
It is of 0.000. Other monomers copolymerizable with vinylpyrrolidone include (meth)acrylic acid esters such as acrylic acid, methacrylic acid and alkyl esters thereof, vinyl alcohols, vinyl imidazoles, (meth)acrylamides, and vinyl carbinols. ,
Examples include vinyl-based hexamers such as vinyl alkyl ethers, but it is preferable that polyvinylpyrrolidone accounts for at least 20% (by weight, the same hereinafter) of the composition.
かかる共重合体の好ましい例はその分子■が5,000
〜400.000のらのである。A preferred example of such a copolymer has molecules 5,000
~400.000 ra.
ゼラチンは石灰!l!X理によるものでも酸処理による
ものでもよく、オセインゼラチン、ピッゲスギンピラチ
ン、ハイドゼラチン又はこれらをエステル化、フェニル
カルバモイル化等とした変性ゼラチンであってもよい。Gelatin is lime! l! The gelatin may be obtained by X-chemical treatment or acid treatment, and may be ossein gelatin, piggesgin pyratin, hydrogelatin, or modified gelatin obtained by esterifying or phenylcarbamoylating these gelatin.
上記バインダーにおいて、全バインダー二にXIしゼラ
チンが10〜90%であることが好ましく、より好まし
くは20〜60%であり、ポリビニルピロリドンが5〜
90%であることが好ましく、より好ましくは10〜8
0%である。In the above binder, gelatin preferably accounts for 10 to 90%, more preferably 20 to 60%, and polyvinylpyrrolidone accounts for 5 to 90% of the total binder.
It is preferably 90%, more preferably 10-8
It is 0%.
上記バインダーは、他の高分子物質を含有してもよく、
ゼラチン及び分子ε1,000〜400,000のポリ
ビニルピロリドンと他の1又は2以上の高分子物質との
混合物、ゼラチン及び分子m 5,000〜400、0
00のビニルピロリドン共正合体と他の1又は2以上の
高分子物質との混合物が好ましい。用いられる他の高分
子物質としては、ポリビニルアルコール、ポリアクリル
アミド、ポリメタクリルアミド、ポリビニルブチラール
、ポリエチレングリコール、ポリエチレングリコールエ
ステルや、或いはセルロースgB G体等のタンパク質
や、デンプン、アラビアゴム等の多糖類のような天然物
質が挙げられる。これらは0〜85%、好ましくは0〜
70%含有されてもよい。The binder may contain other polymeric substances,
Gelatin and a mixture of polyvinylpyrrolidone with molecules ε 1,000 to 400,000 and one or more other polymeric substances, gelatin and molecules m 5,000 to 400,0
A mixture of the vinylpyrrolidone copolymer of No. 00 and one or more other polymeric substances is preferred. Other polymeric substances that can be used include polyvinyl alcohol, polyacrylamide, polymethacrylamide, polyvinyl butyral, polyethylene glycol, polyethylene glycol ester, and proteins such as cellulose gB and polysaccharides such as starch and gum arabic. Natural substances such as These range from 0 to 85%, preferably from 0 to 85%.
It may be contained in an amount of 70%.
なお、上記ビニルピロリドン重合体は架橋ポリマーであ
ってもよいが、この場合、支持体上に■布した後に架橋
させること(自然放置による架橋反応の進行の場合を含
む)が好ましい。The above-mentioned vinylpyrrolidone polymer may be a crosslinked polymer, but in this case, it is preferable to crosslink it after spreading it on a support (including the case where the crosslinking reaction progresses by being allowed to stand).
バインダーの使用量は、通常1層当り1 m’に対して
0.05g〜50(lであり、好ましくは0.1g〜1
0(lである。また、バインダーは、本発明のカプラー
19に対して0.1〜10(]用いることが好ましく、
より好ましくは0.25〜4gである。The amount of binder used is usually 0.05 g to 50 (l) per 1 m' per layer, preferably 0.1 g to 1 m'.
0 (l). Furthermore, the binder is preferably used in the range of 0.1 to 10 (l) for the coupler 19 of the present invention,
More preferably, it is 0.25 to 4 g.
本発明の熱現像カラー感光材料に用いられる支持体とし
ては、例えばポリエチレンフィルム、セル・ロースアセ
テートフィルムおよびポリエチレンテレフタレートフィ
ルム、ポリ塩化ビニル等の合成プラスチックフィルム、
並びに7頁用原紙、印ρり用紙、バライタ紙およびレジ
ンコート紙等の紙支持体、並びに上記の合成プラスチッ
クフィルムに反射属を設けた支持体等が挙げられる。Examples of the support used in the heat-developable color photosensitive material of the present invention include polyethylene film, cellulose acetate film, polyethylene terephthalate film, synthetic plastic film such as polyvinyl chloride,
Also included are paper supports such as 7-page base paper, printing paper, baryta paper and resin-coated paper, and supports in which the above-mentioned synthetic plastic film is provided with a reflective layer.
特に本発明の熱現像カラー感光材料には各種の熱溶剤が
添加されることが好ましい。本発明の熱溶剤とは熱現像
を促進する物質であればよく、好ましくは常温下では固
体、半固体又は液体く好ましくは、常圧において沸点1
00℃以上、より好ましくは150℃以上)であって加
熱することにJ:ってバインダー中で溶解又は溶融づる
物質であって、好ましくは尿素m 4体(例えば、ジエ
チルウレア、ジエチルウレア、フェニルウレア等)、ア
ミド誘導体く例えば、アセトアミド、ベンズアミド等)
、多価アルコール類(例えば、1.5−ペンクンジオー
ル、1.6−ペンタンジオール、1.2−シクロヘキサ
ンジオール、ペンタエリスリ1−−ル、1−リメヂロー
ルエタン等)、又はポリアルレングリコール類が挙げら
れる。詳しい具体例としては、特開昭59−22955
6号に記載されている。これらの熱溶剤は単独でも二種
以上併用して用いても良い。In particular, it is preferable that various heat solvents be added to the heat-developable color photosensitive material of the present invention. The thermal solvent of the present invention may be any substance that promotes thermal development, and is preferably solid, semi-solid, or liquid at room temperature, and preferably has a boiling point of 1 at normal pressure.
00°C or higher, more preferably 150°C or higher) and is a substance that dissolves or melts in the binder, preferably urea m4 (for example, diethylurea, diethylurea, phenyl urea, etc.), amide derivatives (e.g., acetamide, benzamide, etc.)
, polyhydric alcohols (e.g., 1.5-pencundiol, 1.6-pentanediol, 1.2-cyclohexanediol, pentaerythryl, 1-rimedylolethane, etc.), or polyallene glycol Examples include: For a detailed example, see Japanese Patent Application Laid-Open No. 59-22955.
It is stated in No. 6. These thermal solvents may be used alone or in combination of two or more.
本発明の熱現像カラー感光月利には、上記各成分以外に
必要に応じ各種添加剤を添加することができる。例えば
現性促進剤としては、米国特許第3.220,840号
、同第3,531,285号、同第4,012,260
号、同第4,060,420号、同第4,088.49
6@、同第4,207,392号各明細III出、RD
N o、 15733、同N 0.15734、同N
0.15776、特開昭56−130745号、同5
6−132332号等に記載された尿素、グアニジウム
1〜リクロロアセテート等のアルカリ放出剤、特公昭4
5−12700号記載の有R酸、米国特許第3,667
.959号記載の −Go−、−8O2+、−5o−基
を有する非水性極性溶媒化合物、米国特許第3、438
.776号記載のメルトフォーマ−1米田特許第3.6
66、477号、特開昭51−19525号に記載のポ
リアルキレングリコール類等がある。また色調剤として
は、例えば特開昭46−4928号、同46−6077
号、同49−5019号、同49−5020号、同49
−91215号、同49−107727号、同50−2
524号、同50−67132号、同50−67641
号、同50−114217@、同52−33722号、
同52−99813号、同53−1020号、同53−
55115号、同53−7[3020号、同 53−1
25014号、同 54−156523号、同54−1
56524号、同 54−156525号、同 54−
15652G号、同55−40GO号、同55−406
1号、同55−32015号等の公報ならびに西独特許
第2,140.406丹、同第2.147.063号、
同2,220,618号、米国特許第3.080.25
4号、同第3.847.612号、同第3.782.9
41号、同第3,994,732号、同第4.123.
282@、同第4,201.582号等の各明細色に記
載されている化合物であるフタラジノン、フタルイミド
、ピラゾロン、キナゾリノン、N−ヒドロキシナフタル
イミド、ベンツオキサジン、デフ1−オキサジンジAン
、2゜3−ジヒドロ−フタラジンジオン、2.3−ジヒ
ドロ−1,3−オキサジン−2,4−ジオン、オキシピ
リジン、アミノピリジン、ヒドロキシキノリン、アミノ
キノリン、イソカルボスチリルルホンアミド、2H−1
.3−ペンシブアジン=2、4− (3H)ジオン、ベ
ンゾ1〜リアジン、メルカプトトリアゾール
ンタレン、フタル酸、ナフタル酸、フタルアミン酸等が
あり、これらの1つまたは、それ以上とイミダゾール化
合物との混合物、またフタル酸、ナフタル酸等の酸また
は酸無水物の少なくとも1つおよびフタラジン化合物の
混合物、さらには、フタラジンとマレイン酸、イタコン
酸、キノリン酸、ゲンチシン酸等の組合l!笠を挙げる
ことができる。In addition to the above-mentioned components, various additives may be added to the heat-developable color photosensitive material of the present invention as required. For example, as a developing accelerator, U.S. Pat.
No. 4,060,420, No. 4,088.49
6@, No. 4,207,392, each specification III, RD
No, 15733, same N 0.15734, same N
0.15776, JP-A No. 56-130745, No. 5
Alkali release agents such as urea and guanidium 1 to dichloroacetate described in No. 6-132332, etc.;
5-12700, U.S. Pat. No. 3,667
.. Non-aqueous polar solvent compound having -Go-, -8O2+, -5o- groups described in No. 959, U.S. Pat. No. 3,438
.. Melt former-1 described in No. 776 Yoneda Patent No. 3.6
66,477, and polyalkylene glycols described in JP-A-51-19525. In addition, as a color toning agent, for example, JP-A No. 46-4928, JP-A No. 46-6077
No. 49-5019, No. 49-5020, No. 49
-91215, 49-107727, 50-2
No. 524, No. 50-67132, No. 50-67641
No. 50-114217@, No. 52-33722,
No. 52-99813, No. 53-1020, No. 53-
No. 55115, No. 53-7 [No. 3020, No. 53-1
No. 25014, No. 54-156523, No. 54-1
No. 56524, No. 54-156525, No. 54-
No. 15652G, No. 55-40GO, No. 55-406
Publications such as No. 1 and No. 55-32015, as well as West German Patent Nos. 2,140.406 and 2.147.063,
No. 2,220,618, U.S. Patent No. 3.080.25
No. 4, No. 3.847.612, No. 3.782.9
No. 41, No. 3,994,732, No. 4.123.
Phthalazinone, phthalimide, pyrazolone, quinazolinone, N-hydroxynaphthalimide, benzoxazine, def-1-oxazine diane, 2゜3-dihydro-phthalazinedione, 2,3-dihydro-1,3-oxazine-2,4-dione, oxypyridine, aminopyridine, hydroxyquinoline, aminoquinoline, isocarbostyryl sulfonamide, 2H-1
.. 3-pensive azine = 2,4- (3H) dione, benzo-1-lyazine, mercaptotriazolene, phthalic acid, naphthalic acid, phthalamic acid, etc., and a mixture of one or more of these with an imidazole compound, Also, mixtures of at least one acid or acid anhydride such as phthalic acid and naphthalic acid and a phthalazine compound, and combinations of phthalazine and maleic acid, itaconic acid, quinolinic acid, gentisic acid, etc. I can raise a hat.
また、特開昭58−189628号、同58− 193
460号公報に記・戎された、3−アミノ−5−メルカ
プト−1゜2.4−トリアゾール類、3−アシルアミノ
−5−メルカブト−1,2,4−トリアゾール類も有効
である。Also, JP-A-58-189628, JP-A No. 58-193
3-amino-5-mercapto-1°2,4-triazoles and 3-acylamino-5-mercapto-1,2,4-triazoles described and published in Japanese Patent No. 460 are also effective.
またさらに、カブリ防止剤としては、例えば、特公昭4
711N3号、特Dfl Drl 49−901113
Q、Q49−10724号、同49−り7613号、同
50−101019号、同4!]−130720号、同
50−123331号、同51−47419号、同51
−57435号、同51−78227号、同51−10
4338号、同53−19825号、同53−2092
3号、同51−50725号、同51−3223号、同
51−42529号、同51−81124号、同54−
51821号、同55−93149号笠の公報、ならび
に英国特許第1.455,271号、米国特許第3.8
85.968号、同第3.700,457号、同第4.
137.079号、同第4.138.265号、西独特
許第2,617,907号等の各明細書に記載されてい
る化合物である第2水銀塩、或いは酸化剤(rIAえば
、N−ハロゲノアセトアミド、N−ハロゲノコハク酸イ
ミド、過J=素酸およびその塩類、無菌過fl?化物、
過硫酸塩等)、或いは、酸およびその塩(例えば、スル
フィン酸、ラウリン酸リチウム、ロジン、ジテルペン酸
、チオスルボンC)秀)、或いはイオウ含有化合物(例
えば、メルカプ1へ化合物放出性化合物、ヂAウラシル
、ジスルフィド、イオウ単体、メルカプト−1,2,4
=トリアゾール、チアゾリンチオン、ポリスルフィド化
合物等)、その他、オキサゾリン、1,2゜4−1〜リ
アゾール、フタルイミド答の化合物がイ・げられる。さ
らに別のカブリ防止剤として特開昭59−111G36
号に記載されているチオール(好ましくはヂオフェノー
ル化合物)化合物も有効である。Furthermore, as an antifoggant, for example,
No. 711N3, Special Dfl Drl 49-901113
Q, Q49-10724, Q49-7613, Q50-101019, Q4! ]-130720, 50-123331, 51-47419, 51
-57435, 51-78227, 51-10
No. 4338, No. 53-19825, No. 53-2092
No. 3, No. 51-50725, No. 51-3223, No. 51-42529, No. 51-81124, No. 54-
No. 51821, Kasa No. 55-93149, as well as British Patent No. 1.455,271 and U.S. Patent No. 3.8.
No. 85.968, No. 3.700,457, No. 4.
137.079, 4.138.265, and West German Patent No. 2,617,907, or oxidizing agents (such as rIA, N- Halogenoacetamide, N-halogenosuccinimide, peroxylic acid and its salts, sterile perfl? compound,
persulfates, etc.), or acids and their salts (e.g., sulfinic acid, lithium laurate, rosin, diterpene acid, thiosulfone C), or sulfur-containing compounds (e.g., mercap 1-releasing compounds, Uracil, disulfide, simple sulfur, mercapto-1,2,4
= triazole, thiazolinthione, polysulfide compounds, etc.), and other compounds such as oxazoline, 1,2°4-1 to lyazole, and phthalimide. Furthermore, as another antifoggant, JP-A-59-111G36
The thiol (preferably diphenol compound) compounds described in the above are also effective.
またカブリ防止剤としては、特願昭59−56506号
に記載のハイドロキノンM Q体(例えば、ジー [−
オクヂルハイドOキノン、ドデカニルハイドロキノン等
)や特願昭59−6G380号に記載のハイドロキノン
誘導体とベンゾトリアゾール、5−カルボキシベンゾト
リアゾール等)との(J1用が好ましく用いることがで
きる。In addition, as an antifoggant, hydroquinone MQ form (for example, G [-
Hydroquinone derivatives described in Japanese Patent Application No. 59-6G380 and benzotriazole, 5-carboxybenzotriazole, etc.) can be preferably used.
ざらに本発明者等ににり特願昭6O−2f32177号
、同130−263564号に出願された特許明m’r
’:jに記載されたポリマー抑制剤及びバラスト化抑制
剤は、本発明の熱現像カラー感光材料においては、特に
好ましいカブリ防止剤である。The patent application filed by the present inventors in Japanese Patent Application No. 6O-2F32177 and No. 130-263564
The polymer inhibitor and ballasting inhibitor described in ':j are particularly preferred antifoggants in the heat-developable color photosensitive material of the present invention.
また安定剤として特に処理後のプリントアウト防止剤を
同時に用いてもよく、例えば特開111048−452
28号、同 50−119624号、同 50−120
328号、同53−46020号公報等に記載のハロゲ
ン化炭化水素類、具体的にはテトラブロモブタン、トリ
ブロモエタノール、2−ブロモ−2−トリルアセトアミ
ド、2−ブロモ−2−トリルスルホニルアセトアミド、
2−トリブロモメチルスルホニルベンゾチアゾール、2
.4−ビス(トリブロモメチル)−6−メチルトリアジ
ンなどがあげられる。In addition, as a stabilizer, a printout preventive agent may be used at the same time, especially after processing, for example, in Japanese Patent Application Laid-Open No. 111048-452.
No. 28, No. 50-119624, No. 50-120
328, 53-46020, etc., specifically tetrabromobutane, tribromoethanol, 2-bromo-2-tolylacetamide, 2-bromo-2-tolylsulfonylacetamide,
2-tribromomethylsulfonylbenzothiazole, 2
.. Examples include 4-bis(tribromomethyl)-6-methyltriazine.
まな特公昭46−5393号、特開昭50−54329
号、同50−77034明細公報記載のように含イオウ
化合物を用いて後処理を行なってbよい。Mana Special Publication No. 1972-5393, JP 50-54329
A post-treatment may be carried out using a sulfur-containing compound as described in No. 50-77034.
ざらには、米国特許第3,301,078号、同第3.
50G、 444号、同第3.824.103号、同第
3.8,14,788号各明細占に記載のイソヂウIコ
ニウム系スクビライザープレカーサー、また米国特許第
3,669.670号、同第4,012,260号、同
第4.0(30,420号明細I M ニ記枝されたア
クチベータースタビライザーブレカーサー等を含有して
もよい。In particular, U.S. Patent No. 3,301,078;
50G, No. 444, No. 3.824.103, and No. 3.8,14,788, as well as U.S. Patent No. 3,669.670, No. 4,012,260, No. 4.0 (Specification IM of No. 30,420).
また、ショ糖、NH4Fe (SO4)2 ・12
820等の水放出剤を用いてもJ:り、さらにまた、特
開昭56−132332号のように水を供給し熱現像を
行なってもよい。Also, sucrose, NH4Fe (SO4)2 ・12
A water release agent such as 820 may be used, or heat development may be carried out by supplying water as in JP-A-56-132332.
本発明の熱現像カラー感光ohには、さらに上記成分以
外に必要に応じて、分光増感染1′31、ハレーション
防止染料、蛍光増白剤、硬膜剤、帯電防止剤、可塑剤、
延展剤等各種の添加剤、塗布助剤等が添加される。In addition to the above-mentioned components, the heat-developable color photosensitive OH of the present invention further includes spectral enhancement 1'31, antihalation dye, optical brightener, hardener, antistatic agent, plasticizer,
Various additives such as spreading agents, coating aids, etc. are added.
本発明の熱現像カラー感光材料は、基本的には同一層中
に(1)感光性ハロゲン化銀、(2)還元剤、(3)お
よび本発明のカプラー、(4)バインダー、必要に応じ
て(5)有ぼ銀塩を含有する。しかし、これらは必ずし
も単一の写真構成層中に含有させる必要はなく、例えば
、感光性層を2層に分け、前記(1)、(2)、(4)
、(5)の成分を一方側の感光性層に含有させ、この感
光性層に隣接する他方側の層に本発明のカブラー(3)
を含有せしめる等、相互に反応可能な状態であれば2以
上の写真開成層に分けて含有せしめてもよい。The heat-developable color photosensitive material of the present invention basically contains (1) photosensitive silver halide, (2) a reducing agent, (3) and the coupler of the present invention, and (4) a binder in the same layer. (5) Contains silver salt. However, these do not necessarily need to be contained in a single photographic constituent layer; for example, the photosensitive layer may be divided into two layers, and the above-mentioned (1), (2), and (4)
, (5) is contained in the photosensitive layer on one side, and the coupler (3) of the present invention is contained in the layer on the other side adjacent to this photosensitive layer.
If they are in a state where they can react with each other, they may be contained separately in two or more photographic development layers.
また、色感光性層を例えば、高感度層と低感成層等の2
層以上に分割して設【プてもよく、ざらに他の感色性を
異にする1または2以上の感光性層を有してもよいし、
上塗り層、下塗り居、バッキング層、中間層、或いはフ
ィルタ一層等各科の写真構成広を有していてもよい。In addition, the color photosensitive layer may be divided into two layers, such as a high-sensitivity layer and a low-sensitivity layer.
It may be divided into more than one layer, and may have one or more photosensitive layers with roughly different color sensitivities,
It may have various photographic compositions such as an overcoat layer, an undercoat layer, a backing layer, an intermediate layer, or a filter layer.
本発明の熱現像感光材と同様、保4L中間層、下塗居、
バック層、その他の写莫構成居についてもそれぞれの塗
布液を調製し、浸漬法、エアーナイフ法、カーテン塗布
法または米国特許第3,681.294号に記載のホッ
パー塗布法等の各種の塗布法により感光材料を作成する
ことができる。Similar to the heat-developable photosensitive material of the present invention, the 4L intermediate layer, the undercoat,
For the back layer and other photographic components, respective coating solutions are prepared, and various coating methods such as dipping method, air knife method, curtain coating method, or hopper coating method described in U.S. Pat. No. 3,681.294 are applied. A photosensitive material can be created by the method.
更に必要ならば、米国特許第2,1e1.yq1号およ
び英国時:5第837. Oり5号に記載されている方
法によって2府またはそれ以上を同時に塗布することら
できる。Further, if necessary, see US Pat. No. 2,1e1. yq1 and British Time: 5 No. 837. Two or more coats can be applied simultaneously by the method described in No. 5.
本発明の熱現像カラー感光材料の写真構成層に用いられ
る前記の成分は、支持体上に塗布され、塗布の厚みは、
乾ff、後1〜1,000μmが好ましく、より好まし
くは3〜20μmである。The above-mentioned components used in the photographic constituent layers of the heat-developable color light-sensitive material of the present invention are coated on a support, and the coating thickness is as follows:
After drying, the thickness is preferably 1 to 1,000 μm, more preferably 3 to 20 μm.
本発明の悲境俄カラー感光祠1′+1は、そのまま像様
露光した後、通常80℃〜200℃、好ましくは120
℃〜170℃の温度範囲で、1秒間〜180秒間、好ま
しくは1.5秒間〜120秒間加熱されるだ1ノで発色
現像される。また、必要に応じて水不透過性月利を密着
せしめて現像してもよく、或いは露光前に70℃〜18
0℃の温度範囲で予備加熱を施し ・でもよい。The color photoreceptor 1'+1 of the present invention is subjected to imagewise exposure as it is, and then the temperature is usually 80°C to 200°C, preferably 120°C.
Color development is carried out by heating at a temperature range of 170 DEG C. for 1 second to 180 seconds, preferably 1.5 seconds to 120 seconds. In addition, if necessary, it may be developed with a water-impermeable film in close contact with it, or it may be heated at 70°C to 18°C before exposure.
Preheating may be performed in the temperature range of 0°C.
本発明による熱現像カラー感光材料には、種々の露光手
段を用いることができる。潜像は可視光を含む輻射線の
画像状露光によって(τlられる。一般には通常のカラ
ープリントに使用される光源、例えばタングステンラン
プ、水銀灯、キセノンランプ、レーザー光線、CRT光
線等を光源として用うることができる。Various exposure means can be used for the heat-developable color photosensitive material according to the present invention. The latent image is formed by imagewise exposure to radiation, including visible light. In general, light sources used for conventional color printing, such as tungsten lamps, mercury vapor lamps, xenon lamps, laser beams, CRT beams, etc., can be used as the light source. I can do it.
加熱手段は、通常の熱現像感光材料に適用しく7る方法
がすべて利用でき、例えば加熱されたプロッタないしプ
レートに接触させたり、熱ローラーや熱ドラムに接触さ
せたり、高温の雰囲気中を通過させたり、あるいは高周
波加熱を用いたり、さらには、本発明の感光材料中もし
くは熱転写用受像層(要素)中に導電性層を設け、通電
や強磁界によって生ずるジュール熱を利用することもで
きる。加熱パターンは特に制限されることはなく、あら
かじめ予熱くブレヒート)した後、再度加熱する方法を
はじめ、高温で短時間、あるいは低温で長時間、連続的
に上昇、下降あるいは、操りかえし、さらには不連続加
熱も可能ではあるが、簡便なパターンが好ましい。また
露光と加熱が同時に進行する方式であってもよい。As the heating means, all methods applicable to ordinary heat-developable photosensitive materials can be used, such as contacting with a heated plotter or plate, contacting with a heated roller or drum, or passing through a high-temperature atmosphere. Alternatively, high frequency heating may be used, or furthermore, a conductive layer may be provided in the photosensitive material of the present invention or in the image receiving layer (element) for thermal transfer, and Joule heat generated by electricity or a strong magnetic field may be utilized. There are no particular restrictions on the heating pattern, such as preheating (preheating) and then reheating, heating at a high temperature for a short period of time, or at a low temperature for a long period of time, continuously raising, lowering, or changing the direction. Although discontinuous heating is possible, a simple pattern is preferred. Alternatively, a method in which exposure and heating proceed simultaneously may be used.
本発明の熱現像感光材11においては、同時に生じる銀
画像を取り除く為に熱現像後、漂白、定着浴で処理する
か、或いは特開昭59−136733号、米国特許第4
.124.398号、同4.124.387号各公報に
記載されている漂白、定着シートと重す合わけて処理す
ることにより、漂白、定着をおこなってら良い。In the heat-developable photosensitive material 11 of the present invention, in order to remove the silver image generated at the same time, the photothermographic material 11 is treated with a bleaching bath or a fixing bath after heat development, or JP-A-59-136733, U.S. Pat.
.. Bleaching and fixing may be carried out by separately processing the bleaching and fixing sheets as described in No. 124.398 and No. 4.124.387.
[実施例]
以下に本発明の実施例を示ずが、本発明の実施態様はこ
れらに限定されるものではない。[Examples] Examples of the present invention are not shown below, but the embodiments of the present invention are not limited thereto.
実施例−1
例示化合物(M−15)のカプラー570m(+ 、
1 。Example-1 Coupler 570m (+,
1.
4−ジオクチルハイドロキノン%moSrIIPエチル
1.3d及びジオクヂルテレフタレート 0.50を混
合し加熱溶解した。この溶液を界面活性剤を含む2.5
%のゼラチン水溶液6ccと混合し、水を加えて13c
cとした後ホモジナイザーで分散し、カプラーの分散液
を(qた。4-Dioctylhydroquinone% moSrIIP ethyl 1.3d and dioctyl terephthalate 0.50 were mixed and dissolved by heating. This solution contains 2.5 ml of surfactant.
% gelatin aqueous solution and add water to make 13c.
After c, it was dispersed with a homogenizer to obtain a coupler dispersion (q).
上記分散液6.5ccを150mgのゼラチン、300
m。Add 6.5 cc of the above dispersion to 150 mg of gelatin and 300 mg of gelatin.
m.
のポリビニルピロリドン(平均分子が30,000>、
3−メチルペンタン−1,3,5−1−リA−ル200
mg及びポリエチレングリコール(平均分子畠300)
を含む水3.5ccと混合し例示i1元剤(R−11>
200m1l+を加え、さらに下記に示す方法で調製
した4−スルホベンゾトリアゾール毎溶液4背を加えて
pl−1を5.5とした。この分散液に平均粒径0.1
2μmの沃臭化銀乳剤を銀に換算して3×10−4モル
添加(ピラチン75m0含有)し、水を加えて161g
に仕上げた1灸、バライタ紙上に乾燥膜厚が1.5μm
となるようにワイV−バーにて塗布して感光層を塗設し
、感光材料試料(試料No。of polyvinylpyrrolidone (average molecular weight 30,000>,
3-Methylpentane-1,3,5-1-lyal 200
mg and polyethylene glycol (average molecular weight 300)
Exemplary i1 base agent (R-11>
200 ml+ was added, and 4 volumes of each solution of 4-sulfobenzotriazole prepared by the method shown below were added to adjust pl-1 to 5.5. This dispersion has an average particle size of 0.1
Add 3 x 10-4 mol of silver iodobromide emulsion (containing 75 m0 of pyratine) of 2 μm silver iodobromide emulsion and add water to make 161 g.
1 moxibustion finished with a dry film thickness of 1.5 μm on baryta paper
A photosensitive layer was coated by coating with a Y-V-bar so that the photosensitive material sample (sample no.
1)を14だ。1) is 14.
得られた感光材料試料(試料No、1)を乾燥後、8.
0OOCM Sの白色露光をステップウェッジを通して
与えた後、150℃で1分間加熱現像をおこない、マゼ
ンタの画像を得た。得られた画像の緑色光に対する画像
濃度を表−1に示ず。After drying the obtained photosensitive material sample (sample No. 1), 8.
After applying white exposure of 0OOCM S through a step wedge, heat development was performed at 150° C. for 1 minute to obtain a magenta image. The image density of the obtained image with respect to green light is not shown in Table 1.
[4−スルホベンゾトリアゾール銀の調製124gの4
−スルホベンゾトリアゾール及び4りの水酸化ナトリウ
ムをエタノール−水(1:1)混合液30(h!2に加
え溶解した。この溶液に5規定の6FI酸銀溶液20−
を滴下した。この際5規定の水酸化ナトリウム溶液も同
時に滴下し、I)Hを7〜8に維持した。この溶液を1
時間室温で撹拌した後、水で400輩に1[上げて4−
スルホベンゾトリアゾールを20%過剰に含む4−スル
ホベンゾトリアゾール銀溶液を調製した。[Preparation of silver 4-sulfobenzotriazole 124 g of 4
-Sulfobenzotriazole and 4 ml of sodium hydroxide were added and dissolved in 30 h!2 of an ethanol-water (1:1) mixture.To this solution was added 20 ml of 5N 6FI acid silver solution.
was dripped. At this time, a 5N sodium hydroxide solution was also added dropwise at the same time to maintain I)H at 7-8. Add this solution to 1
After stirring at room temperature for an hour, add water to 400 ml and raise to 4-
A 4-sulfobenzotriazole silver solution containing 20% excess of sulfobenzotriazole was prepared.
実施例−2
実施例−1のカプラー分散液に以下に示す現ゆ抑制剤を
10m(+添加した以外は実施例−1と同じ試料(試l
lN0.2)を作製し、実施例−1と同じ露光、悲境位
:、漂白、定着をJ3こなった。結果を表−1に示づ。Example 2 The same sample as Example 1 (sample 1
1N0.2) was prepared and subjected to the same exposure, bleaching, and fixing as in Example 1. The results are shown in Table-1.
現像抑制剤
実施例−2の例示化合物(M−15)のカプラーを表−
1に示すカプラーに変えた以外は実施例−2と同様にし
て感光材料試Pt(試料N003〜6)を作製した。ま
た、比較例として実施例−1のカプラー(M−15)を
以下に示す比較カプラー(A、B)に変えた以外は実施
例−1と同様にして感光材料試料(試着No、7〜8)
を作製した。The couplers of the exemplary compound (M-15) of development inhibitor Example-2 are shown below.
Light-sensitive material samples Pt (samples Nos. 003 to 6) were prepared in the same manner as in Example 2, except that the coupler shown in Example 1 was used. In addition, as a comparative example, photosensitive material samples (try-on No. 7 to 8 )
was created.
これらの試11No、3〜8に対し、実施例−1と同じ
露光、熱現像を行ない表−1に示すマゼンタ画(役を得
た。These samples Nos. 11 and 3 to 8 were subjected to the same exposure and heat development as in Example 1, and the magenta images shown in Table 1 were obtained.
比較カプラーA
比較カプラーB
I
なお、感光材料試料No、4.5及び7についてはカプ
ラーをオイルプロテクト分散する為に高沸点溶剤として
ジオクチルアタレートを用いた。Comparative coupler A Comparative coupler B I For photosensitive material samples No. 4.5 and 7, dioctyl athalate was used as a high boiling point solvent in order to protect and disperse the coupler in oil.
実施例−4
実施例−1〜3の熱現像後の感光材11(試第11No
、1.2.3.5.7.8>を以下に記載のイーストマ
ン・コダック?J E −6処理(試料No。Example-4 Photosensitive material 11 after heat development of Examples-1 to 3 (Test No. 11
, 1.2.3.5.7.8> as described below by Eastman Kodak? JE-6 treatment (sample no.
1’ 、2’ 、3’ 、5’ 、7’ 、8’ )に
より、感光林料(試料NO,4’ 、6’ >をイース
トマン・コダック社ECN−2処理(試nNo、4’
。1', 2', 3', 5', 7', 8').
.
6′)により、それぞれ漂白、定着をおこない、クリア
ーなマゼンタ画像を19た。この11られたマゼンタ画
像の緑色光に対する画像濃度を表−1に示す。6'), bleaching and fixing were carried out, respectively, and a clear magenta image was obtained. Table 1 shows the image densities of the densified magenta images with respect to green light.
[E−6処II’]
1捏 温度 時間1、コンディシ
ョナー 25〜40℃ 2分2 、 漂 白
35〜38℃ 6分3、定
着 25〜40℃ 6分4、水 洗
4分[ECN−2処理コ
ニ程 温 度 時 間1、
ブレバス 27℃ 30秒2 、 ′a
白 27℃ 3分3
、水 洗 1分
4、定 着 25〜40℃ 5分5、水 洗
2分実施例−5
実施例−2の塗布液から有機正塩分散液を除き代りにグ
アニジントリクロロ酢泄の10%エタノール液0./l
vQを含む水溶液4dを加え、塗イ11のpHを6.5
とした以外は実施例−2と同じ塗布液を作製し、バライ
タ紙上に乾燥膜厚が7.5μmとなるように塗布、乾燥
して感光材料試料(試料N0.9)を作製し、実施例−
2と同様の露光、現像処理をおこない、D maxl、
49、D m1n0.12のマゼンタ画像を得た。[E-6 Process II'] 1 kneading Temperature: 1, conditioner: 25-40℃ 2 minutes, bleaching
35-38℃ 6 minutes 3, constant
Wash at 25-40℃ for 6 minutes and 4 minutes.
4 minutes [ECN-2 treatment temperature time 1,
Brevas 27℃ 30 seconds 2,'a
White 27℃ 3 minutes 3
, water washing 1 minute 4, fixation 25-40℃ 5 minutes 5, water washing 2 minutes Example-5 The organic normal salt dispersion was removed from the coating solution of Example-2 and replaced with 10% ethanol containing guanidine trichloroacetic acid. Liquid 0. /l
Add 4d of aqueous solution containing vQ and adjust the pH of Coating No. 11 to 6.5.
The same coating solution as in Example 2 was prepared except for the above, and it was applied onto baryta paper so that the dry film thickness was 7.5 μm, and dried to prepare a photosensitive material sample (sample No. 9). −
Perform the same exposure and development processing as in 2, D maxl,
49, a magenta image of D m1n0.12 was obtained.
以下余白
表−1
表−1に示される結果から、本発明のカプラーを用いた
感光材料では、いずれにおいてもQ maxが大きくD
minが小さく出ており、比較のカプラーでは濃度が低
くなるか力1りが大きくなって(IXる。有機銀塩を含
有していない感光材料でも本発明のカプラーを用いた感
光材料では濃度が得られ、カブリも小さい。Margin Table 1 Below: From the results shown in Table 1, it can be seen that in the light-sensitive materials using the coupler of the present invention, Q max is large and D
min is small, and the comparative coupler either has a lower density or has a larger force (IX). Even if the light-sensitive material does not contain an organic silver salt, the density will be lower in the light-sensitive material using the coupler of the present invention. and the fog is small.
実施例−6
実施例−1のハロゲン化銀を緑色感度を有する平均粒径
0,12μmのハロゲン化銀に代えた以外は、実施例−
1と同じカプラー(M−15)を用いた組成の塗布液を
バライタ紙上に乾燥膜厚が7.5μmとなるようにワイ
ヤーバーにて塗布して第1@光層とした。この第1感光
層上に、1.4−ジオクチルハイドロキノン20no+
が分散された4%ゼラチン液10CC[ポリエチレング
リコール(平均分子m 300) 200mgを含む。Example-6 Example-1 except that the silver halide in Example-1 was replaced with silver halide having green sensitivity and an average grain size of 0.12 μm.
A coating solution using the same coupler (M-15) as in Example 1 was applied onto baryta paper using a wire bar so that the dry film thickness was 7.5 μm to form a first @ optical layer. On this first photosensitive layer, 1,4-dioctylhydroquinone 20no+
10 cc of 4% gelatin solution [contains 200 mg of polyethylene glycol (average molecular m 300)].
]を乾燥膜厚211mとなる様にワイヤーバーで塗設し
て、中間口を設けた。] was coated with a wire bar so that the dry film thickness was 211 m, and an intermediate opening was provided.
この中間層上にカプラーを下記シアンカプラーに変え、
ハロゲン化銀を赤色感度を有するハロゲン化銀(ffi
加ω、銀に換算して9 X 10−4モル)に変えた以
外は第1!S光広と同じ居を塗設して、第2感光居を設
けた。Change the coupler to the cyan coupler below on this intermediate layer,
Silver halide with red sensitivity (ffi
No. 1 except that it was changed to ω, 9 x 10-4 mole in terms of silver)! The same residence as S. Mitsuhiro was painted and a second Kanko residence was built.
シアンカプラー
さらに第2rJiA光口上に10ccの4%ゼラチン液
を乾燥膜厚が2μmとなるように塗設して保護層とした
。The cyan coupler was further coated with 10 cc of 4% gelatin solution on the second rJiA light port so that the dry film thickness was 2 μm to form a protective layer.
得られた感光44萬1試(11(試11N0.10)を
乾燥後、8,0OOCM Sの赤色露光、緑色露光及び
白色露光を与え、実施例−2と同様に悲境O%漂白、定
着後、赤色光及び緑色光によりD max及び[) w
inの濃度を求めた。結果を表−2に示す。After drying the obtained photosensitive 440,000 1 test (11 (Test 11N0.10)), red exposure, green exposure and white exposure of 8,000 CM S were applied, followed by bleaching and fixing at 0% in the same manner as in Example-2. After that, D max and [) w by red light and green light
The concentration of in was determined. The results are shown in Table-2.
実施例−7
実施例−6のI’1113光膚のカプラー(M−15)
を(M−3)に代えた以外は実施例−6と同じ感光材料
試料(試料No、11)を作製した。得られた試料N0
.11を乾燥後、実施例−6と同じ露光、熱現像、漂白
、定着をおこない、赤色光及び緑色光によりD max
及びQ winの濃度を求めた。Example-7 I'1113 photodermal coupler (M-15) of Example-6
The same photosensitive material sample (sample No. 11) as in Example 6 was prepared except that (M-3) was used instead of (M-3). Obtained sample N0
.. After drying No. 11, the same exposure, heat development, bleaching, and fixing as in Example-6 were carried out, and D max was obtained using red light and green light.
and the concentration of Q win was determined.
結果を表−2に示す。The results are shown in Table-2.
以下余白
上記、実施例−6の試料No、10、実施例−7の試料
N0111が示す如く、重層感光材料においてはポリマ
ーカプラーの方がそれ自体の移動による混色が全くなく
、より好ましい。Margins below As shown in Samples No. 10 of Example 6 and Sample No. 0111 of Example 7, polymer couplers are more preferable in multilayer photosensitive materials because they cause no color mixing due to movement of the polymer couplers themselves.
Claims (1)
熱現像カラー感光材料に下記一般式(1)で表わされる
マゼンタカプラーを含有することを特徴とする熱現像カ
ラー感光材料。 一般式(1)▲数式、化学式、表等があります▼ [式中、ZはN原子と共に含窒素複素環残基を形成する
のに必要な原子群を表わし、R_1はアルキル基、アリ
ール基、アルキルアミノ基、アニリノ基、アシルアミノ
基またはウレイド基を表わし、R_2はアリール基また
は複素環残基を表わす。但し、R_1、R_2の少なく
とも一つはバラスト基またはバラスト基で置換されてい
る。][Scope of Claims] A heat-developable color photosensitive material having at least one heat-developable photosensitive layer on a support, which contains a magenta coupler represented by the following general formula (1). photosensitive material. General formula (1) ▲ Numerical formulas, chemical formulas, tables, etc. are available ▼ [In the formula, Z represents the atomic group necessary to form a nitrogen-containing heterocyclic residue together with the N atom, and R_1 is an alkyl group, an aryl group, It represents an alkylamino group, anilino group, an acylamino group or a ureido group, and R_2 represents an aryl group or a heterocyclic residue. However, at least one of R_1 and R_2 is substituted with a ballast group or a ballast group. ]
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1156386A JPS62169158A (en) | 1986-01-22 | 1986-01-22 | Thermally developable color photosensitive material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1156386A JPS62169158A (en) | 1986-01-22 | 1986-01-22 | Thermally developable color photosensitive material |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS62169158A true JPS62169158A (en) | 1987-07-25 |
Family
ID=11781400
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1156386A Pending JPS62169158A (en) | 1986-01-22 | 1986-01-22 | Thermally developable color photosensitive material |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS62169158A (en) |
-
1986
- 1986-01-22 JP JP1156386A patent/JPS62169158A/en active Pending
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPS6161158A (en) | Heat developing color photosensitive material | |
JPS62136648A (en) | Heat developable color photosensitive material | |
US4631251A (en) | Heat-developable color photo-sensitive material with polymeric coupler | |
JPS62169158A (en) | Thermally developable color photosensitive material | |
JPS6159336A (en) | Heat developing color photosensitive material | |
EP0186494B1 (en) | Heat-developable color photo-sensitive material | |
JPH0573223B2 (en) | ||
JPS62129852A (en) | Heat developable color photosensitive material | |
JPH029332B2 (en) | ||
JPH0588818B2 (en) | ||
JPS61210351A (en) | Heat developable color photosensitive material | |
JPS61175637A (en) | Heat-developable color photosensitive material | |
JPS62135827A (en) | Heat developable color photosensitive material | |
JPH0535858B2 (en) | ||
JPH0477892B2 (en) | ||
JPS625238A (en) | Heat developable photosensitive material | |
JPH0439660B2 (en) | ||
JPS6214649A (en) | Heat developable color photosensitive element | |
JPS6244738A (en) | Heat developable photosensitive material | |
JPS62143049A (en) | Heat-developable color photosensitive material | |
JPS61177451A (en) | Thermodeveloping color sensitive material | |
JPS6338935A (en) | Heat developable photosensitive material containing novel cyan dye providing substance | |
JPH0367255A (en) | Transfer type heat developable color photosensitive material | |
JPS62229241A (en) | Heat developable photosensitive material having high sensitivity and excellent thermal fogging and reciprocity law failure characteristic | |
JPH04139446A (en) | Transfer type heat developable color photosensitive material |