JPS62158826A - Method for directly quenching and tempering hot rolled steel bar or wire rod - Google Patents

Method for directly quenching and tempering hot rolled steel bar or wire rod

Info

Publication number
JPS62158826A
JPS62158826A JP29834585A JP29834585A JPS62158826A JP S62158826 A JPS62158826 A JP S62158826A JP 29834585 A JP29834585 A JP 29834585A JP 29834585 A JP29834585 A JP 29834585A JP S62158826 A JPS62158826 A JP S62158826A
Authority
JP
Japan
Prior art keywords
wire rod
tempering
quenching
steel bar
winding
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP29834585A
Other languages
Japanese (ja)
Inventor
Kazuo Arai
和夫 新井
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Steel Corp
Original Assignee
Kawasaki Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kawasaki Steel Corp filed Critical Kawasaki Steel Corp
Priority to JP29834585A priority Critical patent/JPS62158826A/en
Publication of JPS62158826A publication Critical patent/JPS62158826A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/52Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
    • C21D9/525Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length for wire, for rods

Abstract

PURPOSE:To utilize the sensible heat of a finish-rolled steel bar or wire rod and to considerably save energy by carrying out quenching and tempering between finish rolling and ring forming stages. CONSTITUTION:Four rapid cooling units 22 and a rapid heating unit 24 are arranged between a finish rolling mill 2 and a coiler 10. A wire rod 4 finish- rolled with the finish rolling mill 2 is quenched with the rapid cooling units 22 and tempered with the rapid heating unit 24. A reformer 20 is placed just behind the coiler 10 so as to avoid conventional conveyance in the form of a ring.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は熱間圧延棒鋼・線材の直接焼入れ・焼戻し方法
に関し、棒鋼・線材の製造分野で利用される。
[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a method for directly quenching and tempering hot rolled steel bars and wire rods, and is used in the field of manufacturing steel bars and wire rods.

〔従来の技術〕[Conventional technology]

一般に線材等の強靭性を強化する目的のオンライン熱処
理は第3図に示す如く圧延・巻取後リング状に成形され
た後実施されろ。すなわち、仕上圧延機2からの線材4
は水冷装置6で冷却された後、ピンチロール8を経て巻
取機10にてリング12に成形され、第4図に示す如く
リング同志の重なりを減らすため適宜の間隔でずらして
コンベア14上でファン16からの冷風18によって強
制冷却されリング収束装置リフオーマ−20に貯留され
る。なお強制冷却は水冷あるいはソルト冷却の場合もあ
る。
Generally, on-line heat treatment for the purpose of strengthening the toughness of wire rods, etc. is carried out after rolling and winding and forming into a ring shape, as shown in FIG. That is, the wire rod 4 from the finishing mill 2
After being cooled by a water cooling device 6, the rings are formed into rings 12 by a winder 10 via pinch rolls 8, and then placed on a conveyor 14 at appropriate intervals to reduce overlapping of the rings, as shown in FIG. The air is forcibly cooled by cold air 18 from the fan 16 and stored in the ring convergence device reformer 20. Note that forced cooling may be water cooling or salt cooling.

上記の方法は種々の技術的制約により下記の問題点は不
可避で容認せざるを得なかった。
Due to various technical constraints, the above method inevitably suffers from the following problems and has to be accepted.

(A)  リングの重なりが場所によって異なり、材料
の長さ方向の冷却速度にばらつきを生じ、連続冷却変態
(以下OCTと称する)開始温度が異なることが主原因
となって引張強さ、降伏強度、伸び、絞り等の室温にお
けろ諸相質に大き゛ なばらつきを生じていた。
(A) The overlap of the rings differs depending on the location, causing variations in the cooling rate in the longitudinal direction of the material, and the continuous cooling transformation (hereinafter referred to as OCT) starting temperature differs, which is the main cause of the tensile strength and yield strength. There were large variations in the properties of various phases such as elongation, elongation, and squeezing at room temperature.

(B)強制風冷においては、重なり密度の大小に応じて
風圧や風量を調節できるが、材質のばらつきを十分に減
少させることばできなかった。
(B) In forced air cooling, the wind pressure and air volume can be adjusted depending on the overlap density, but it has not been possible to sufficiently reduce variations in material quality.

(C)OCT開始が早い鋼種の高強度化や焼入れ処理の
ためには、水やソルト浴の如き大きな熱伝達率を有する
冷媒を使用する必要があり、この場合には線材の重なり
密度の程度に応じた冷媒供給量の調節は実際上不可能と
なり、冷却速度の差に起因した材質の変動は不可避であ
った。
(C) In order to increase the strength of steels that start OCT quickly and to harden them, it is necessary to use a coolant with a high heat transfer coefficient, such as water or a salt bath, and in this case, the overlap density of the wire rods must be It became practically impossible to adjust the amount of refrigerant supplied according to the cooling rate, and variations in material quality due to differences in cooling rates were inevitable.

(DJ第3図、第4図に示す如く巻取後のリング状の冷
却・搬送は装置が大型化し、設備コストやランニングコ
ストの増大を招来した。
(DJ As shown in FIGS. 3 and 4, the ring-shaped cooling and conveyance after winding requires an enlarged device, resulting in an increase in equipment costs and running costs.

(E)特にコンクリートパイル補強材として使用される
PC棒鋼などに供される焼入れ・焼戻し材の製造におい
ては、リング状態での適切な再加熱手段が見い出し難(
実用化には至っていなかった。
(E) It is difficult to find an appropriate reheating method in the ring state, especially in the production of hardened and tempered materials used for PC steel bars used as concrete pile reinforcing materials.
It had not been put into practical use.

〔発明が解決しようとする問題点〕[Problem that the invention seeks to solve]

本発明の目的は、上記従来技術の問題点を解決し、棒鋼
・線材の長さ方向の材質の変動を減少し巻取後のリング
搬送を省略できる熱間圧延棒鋼・線材の直接焼入れ・焼
戻し方法を提供するにある。
The purpose of the present invention is to solve the problems of the above-mentioned conventional technology, and to provide direct quenching and tempering of hot rolled steel bars and wires, which reduces fluctuations in material quality in the longitudinal direction of the steel bars and wires, and eliminates ring conveyance after winding. We are here to provide you with a method.

〔問題点を解決するための手段および作用〕本発明の要
旨とするところは次の如くである。
[Means and operations for solving the problems] The gist of the present invention is as follows.

すなわち、熱間仕上圧延終了後にリング状に成形して巻
取る棒鋼・線材の製造方法において、前記仕上圧延工程
とリング状への成形工程の間で前記棒鋼・線材を急冷装
置により焼入れろ工程と、前記焼入れ後急速加熱装置に
より焼戻す工程と、を有して成ることを特徴とする熱間
圧延棒鋼・線材の直接焼入れ・焼戻し方法である。
That is, in a method for manufacturing a steel bar or wire rod that is formed into a ring shape and wound after hot finish rolling, the steel bar or wire rod is quenched in a quenching device between the finish rolling step and the ring shape forming step. A method for directly quenching and tempering hot rolled steel bars and wire rods, comprising the steps of: tempering using the rapid heating device after quenching.

本発明者は圧延終了後巻取まで線材は直線状であり、変
態を終了してしまえば直ちに室温まで急冷してコイル結
束できることに着眼し、圧延終了〜巻取間における焼入
れ・焼戻し処理を意図した。
The inventor of the present invention focused on the fact that the wire is straight until it is coiled after rolling, and that once the transformation is completed, it can be rapidly cooled to room temperature and bundled into a coil, and intended to perform quenching and tempering treatment between the end of rolling and coiling. did.

従来の技術感覚では次の如く考えられていた。In the conventional technical sense, it was considered as follows.

(イ)2次加工メーカーにおけるメカニカルデスケーリ
ングを意識して、適正なスケール組成および厚みになる
ように巻取温度を800〜900℃の範囲に設定し、仕
上圧延機〜巻取機(レーイングヘッド)間において仕上
圧延温度1000〜1100℃からの冷却を目的とした
能力を有する水冷装置のみを設置しtコ。
(b) Keeping in mind the mechanical descaling at secondary processing manufacturers, the coiling temperature is set in the range of 800 to 900°C to obtain an appropriate scale composition and thickness, and the finishing mill to winding machine (laying Only a water cooling device capable of cooling the finish rolling temperature from 1000 to 1100°C was installed between the heads).

(ロ)熱処理は巻取以降に行うものであるとの既成概念
があった。
(b) There was a preconceived notion that heat treatment should be performed after winding.

(ハ)巻取温度が700℃以下と低いとトラブルを起こ
し易いと考えられていた。
(c) It was thought that troubles would easily occur if the winding temperature was as low as 700°C or less.

(ニ)圧延終了〜巻取間の所用時間は短かいので、この
間に変態を終了できるとの発想は皆無であった。
(d) Since the time required between the end of rolling and winding is short, there was no idea that the transformation could be completed during this time.

本発明者はこれらの概念について種々の検討を行った結
果、従来の発想を大きく転換し、次の如き知見を得るこ
とができた。
As a result of various studies on these concepts, the present inventor made a major change in the conventional thinking and was able to obtain the following findings.

(A)圧延後急冷して2次スケールの発生を阻止し、ス
ケールレスに近い線材製造の技術は注目に値する。
(A) The technology for manufacturing wire rods that is nearly scaleless by rapidly cooling the wire after rolling to prevent the formation of secondary scales is noteworthy.

(B)熱処理は圧延終了後可能な限り早〈実施すること
が、fit再結晶を抑制する、(11)粒成長を抑制す
る、(iii)加工歪の消滅を少なくする等に有効であ
り、高強靭性に不可欠な微細粒組織に仕上げろことがで
きるので、熱処理を巻取の後にすべきであるとの考えは
検討を要する。
(B) Heat treatment is carried out as soon as possible after the end of rolling.It is effective to suppress fit recrystallization, (11) to suppress grain growth, (iii) to reduce disappearance of working strain, etc. The idea that heat treatment should be performed after winding requires consideration because it can create a fine grain structure that is essential for high strength and toughness.

(C)巻取温度が低くても、加工性の著しく乏しし1下
部ベーナイトやマルテンサイト主体組織でない限り巻取
におけるトラブルの心配はない。
(C) Even if the winding temperature is low, there is no need to worry about trouble during winding unless the workability is extremely poor and the structure is mainly composed of lower bainite or martensite.

(D)圧延終了〜巻取間の所要時間が短か過ぎる問題に
対しては、圧延速度を落としてラインスピードを低下す
るか、あるいは仕上圧延機〜巻取機間の距離を必要なだ
け延長することで対処できる。たttシ、この所要時間
の延長には材料の品質に対する配慮を必要とする。
(D) If the time required between the end of rolling and winding is too short, reduce the rolling speed to lower the line speed, or extend the distance between the finishing mill and winding machine as necessary. You can deal with it by doing this. However, this increased turnaround time requires consideration of material quality.

本発明はこれらの知見に基づいてなされたものである。The present invention has been made based on these findings.

従来の技術では第3図に示す如く、仕上圧延812と巻
取機10の間には巻取温度コントロールのため水冷装置
6が2〜4基復熱のため適度の間隔を空けて配置され、
巻取後リング12をずらして搬送する過程で焼入れ槽続
いて焼戻し槽を経てリフオーマ−20にてリフオーミン
グされていた。
In the conventional technology, as shown in FIG. 3, 2 to 4 water cooling devices 6 are arranged between the finish rolling 812 and the winding machine 10 to control the winding temperature, with appropriate intervals for heat recovery.
In the process of shifting and transporting the ring 12 after winding, the ring 12 is reformed in a reformer 20 through a quenching tank, followed by a tempering tank.

これに対して本発明においては、第1図に示す如(仕上
圧延機2と巻取機10の間に4基の急冷装置22と急速
加熱装置24が設けられている。
In contrast, in the present invention, as shown in FIG. 1, four rapid cooling devices 22 and four rapid heating devices 24 are provided between the finishing rolling mill 2 and the winding machine 10.

急冷装置22ば高圧水流を利用するのが好ましく、急速
加熱装置24は誘導加熱方式が望ましく、いずれも短時
間処理および均一処理に適した方式である。
The rapid cooling device 22 preferably uses a high-pressure water stream, and the rapid heating device 24 preferably uses an induction heating method, both of which are suitable for short-time processing and uniform processing.

仕上圧延機2で仕上圧延された線材4は急冷装置22で
焼入れ後、急速加熱装置24で焼戻しされ、リフオーマ
−20を巻取機10の直後に配置し従来のリング状での
搬送をなくした。
The wire rod 4 that has been finish rolled in the finish rolling mill 2 is quenched in a rapid cooling device 22 and then tempered in a rapid heating device 24, and a reformer 20 is placed immediately after the winding machine 10, eliminating the conventional ring-shaped conveyance. .

リフオーマ−20は保温槽としての機能を有し、巻取時
点における未焼戻し部分(内層)の焼戻しを長さ方向で
均一化するよう配慮しである。
The reformer 20 has a function as a heat insulating tank, and is designed to uniformly temper the untempered portion (inner layer) in the length direction at the time of winding.

圧延終了後冷却が早いほどマルテンサイトの核発生数が
多く、結果として焼入所要時間が短かくなり、かつ焼戻
しにおいても焼入組織が微細な程焼戻しに要する時間が
同一温度の比較で短かくなるので、仕上圧延機2〜巻取
機zor4の距離を短かく設計することができる。
The faster the steel is cooled after rolling, the more martensite nuclei will be generated, and as a result, the time required for quenching will be shorter, and the finer the quenched structure, the shorter the time required for tempering at the same temperature. Therefore, the distance between the finishing rolling mill 2 and the winding machine zor4 can be designed to be short.

結晶粒の大きさと巻戻し後の材質との関係を第2図に示
した。なお結晶粒の大きさは粒径d−を靭性、降伏強度
、引張強さが高いので、早期冷却は一挙両得の技術であ
る。
Figure 2 shows the relationship between the size of crystal grains and the material quality after unwinding. Note that since the grain size is determined by the grain size d-, the toughness, yield strength, and tensile strength are high, so early cooling is a technology that achieves both goals at once.

焼戻しのための加熱温度は300〜600℃の範囲が望
ましいが、加熱温度が低い程加熱所要時間が短くてすむ
が、300℃未満では保持時間が長くなり、巻取までに
必要な焼戻し量が得難く、また加熱温度が高い程必要保
持時間は短かくてすむものの、加熱に要する時間が長く
なり昇熱の熱エネルギー負荷が多く不経済となるので3
00〜600℃の範囲が最適である。
The heating temperature for tempering is preferably in the range of 300 to 600°C. The lower the heating temperature, the shorter the heating time, but if it is lower than 300°C, the holding time will be longer and the amount of tempering required before winding will be shorter. Also, although the higher the heating temperature, the shorter the required holding time, the longer the time required for heating and the higher the thermal energy load for heating, which becomes uneconomical.
A range of 00 to 600°C is optimal.

なお、線径の太いものは同一冷媒条件での比較で冷却速
度が遅(なるが、圧延速度が小さいことによる冷却時間
の長大化によって大略相殺される。
Note that the cooling rate of wires with larger diameters is slower when compared under the same refrigerant conditions (although this is largely offset by the longer cooling time due to the lower rolling speed).

従って概略的には仕上圧延機2〜巻取45110間の距
離を変更することなく、同一の装置で広範囲の寸法に対
して必要な熱処理を施す乙とができる。
Therefore, in general, the necessary heat treatment can be applied to a wide range of dimensions using the same device without changing the distance between the finishing mill 2 and the winder 45110.

本発明は仕上圧延終了後巻取までの間で焼入れ焼戻しを
行い、棒鋼・線材の長さ方向の材質を均一化し、巻取後
のリング搬送を省略することができた。
In the present invention, quenching and tempering is performed after finish rolling and before winding, to make the material quality of the steel bar/wire material uniform in the length direction, and to omit ring conveyance after winding.

本発明法は焼入れ一焼戻しに関する技術であるが、焼゛
入のままで仕上げる直接焼入材の製造にも全く問題なく
適用できる乙とは勿論である。また、冷却を450〜6
50℃の範囲の任意温度で停止させ、思過冷却のまま巻
取−コイリングを行う直接パーライト変態処理線材の製
造も可能である。
Although the method of the present invention is a technology related to quenching and tempering, it can of course be applied without any problems to the production of directly quenched materials that are finished as quenched. Also, cooling to 450~6
It is also possible to produce a direct pearlite transformation treated wire by stopping at an arbitrary temperature in the range of 50° C. and then winding and coiling while under-cooling.

〔実施例〕〔Example〕

実施例1 第1表に示す成分の1030鋼を棒鋼スタンド18基お
よび線材仕上スタンド6基を用いて径12m+ntjX
材に圧延したが、その際、ビレットサイズ: 150胴
角、抽出温度:  1100℃、圧延仕上速度:30m
/s、仕上圧延温度:  1050℃であった。これら
の線材を本発明法により第1図に示す如き水冷ゾーンの
長さが8mX4槽= 32 m/4槽の急冷装置22で
、総水量8000 J/minで焼入し、これを本発明
例とした。
Example 1 1030 steel with the components shown in Table 1 was prepared using 18 bar stands and 6 wire finishing stands to reduce the diameter to 12 m + ntj
The billet size was 150 mm, the extraction temperature was 1100°C, and the finishing speed was 30 m.
/s, finish rolling temperature: 1050°C. These wire rods were quenched by the method of the present invention in a rapid cooling device 22 with a water cooling zone length of 8 m x 4 tanks = 32 m/4 tanks as shown in Fig. 1 at a total water flow rate of 8000 J/min. And so.

第  1  表 比較のため本発明例と同一条件の線材を第3図に示す装
置で巻取後、強制風冷およびオンライン焼入れを行い、
これを従来例とした。
Table 1 For comparison, wire rods under the same conditions as the examples of the present invention were wound up using the device shown in Figure 3, and then subjected to forced air cooling and online quenching.
This was taken as a conventional example.

これらのオンライン焼人材の機械的性質およびスケール
厚を調査して、その結果を第2表に示した。
The mechanical properties and scale thickness of these online fired materials were investigated, and the results are shown in Table 2.

第  2  表 第2表において、本発明例は従来例に比例して引張強さ
および絞りのマ、3σ共にすぐれスケール厚も1/8と
著しく少ない。
Table 2 In Table 2, the examples of the present invention are excellent in both tensile strength, reduction of area, and 3σ in proportion to the conventional examples, and the scale thickness is also significantly smaller at 1/8.

実施例2 第2表に示した本発明例と全く同一成分の材料を使用し
、これを焼入れまで実施例1と同一工程とし、その後急
速加熱装置24で450℃に加熱し放冷により焼戻し処
理を行い、これを本発明例とした。
Example 2 A material with exactly the same components as the present invention example shown in Table 2 was used, and the process was the same as in Example 1 until quenching, and then it was heated to 450°C with a rapid heating device 24 and tempered by cooling. This was used as an example of the present invention.

なお、従来例として本発明例と同一条件の線材を2次加
工メーカーにおいて900℃に再加熱しオーステナイト
化しその後、焼入れ、次に380℃×6秒の焼戻しを行
った。
As a conventional example, a wire rod under the same conditions as the present invention example was reheated at a secondary processing manufacturer to 900°C to austenite, then quenched, and then tempered at 380°C for 6 seconds.

これらの線材の機械的性質を調査し、その結果を第3表
に示した。
The mechanical properties of these wires were investigated and the results are shown in Table 3.

第3表から本発明例は2次加工メーカーにおけろ再加熱
による焼入れ・焼戻し材とほぼ同等のすぐれた結果であ
ることがわかる。
From Table 3, it can be seen that the examples of the present invention have excellent results that are almost equivalent to those obtained by quenching and tempering materials by reheating in secondary processing manufacturers.

第  3  表 〔発明の効果〕 本発明は上記実施例からも明らかな如く、棒鋼・線材の
仕上圧延工程とリング状成形工程の間で焼入れおよび焼
戻しを行うことによって次の効果をあげることができた
Table 3 [Effects of the Invention] As is clear from the above examples, the present invention can achieve the following effects by performing quenching and tempering between the finish rolling process and the ring forming process of the steel bar/wire rod. Ta.

(イ)オンラインで従来の2次加工メーカーにおける再
加熱による焼入れ焼戻し材と同等の品質のものが得られ
るので、圧延仕上の顕熱を利用し大幅な省エネルギーが
図れる。
(b) Since products of the same quality as quenched and tempered materials obtained by reheating at conventional secondary processing manufacturers can be obtained online, significant energy savings can be achieved by utilizing the sensible heat of the rolling finish.

(ロ)長さ方向に均一な材質の棒鋼・線材が得られる。(b) Steel bars and wire rods with uniform material in the length direction can be obtained.

(ハ)@取以降のリング状搬送および強制空冷のための
膨大な設備を必要としない。
(c) Huge equipment for ring-shaped conveyance and forced air cooling after @ removal is not required.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明法で使用する仕上圧延以降の装置の配置
図、第2図は焼戻し後の結晶粒の大きさと機械的性質と
の関係を示す線図、第3図は従来法て使用する仕上圧延
以降の装置の配置図、第4図は従来法のリング状成形後
の線材の形状を示す正面図である
Figure 1 is a layout diagram of the equipment used in the process of the present invention after finish rolling, Figure 2 is a diagram showing the relationship between grain size and mechanical properties after tempering, and Figure 3 is a diagram used in the conventional method. Figure 4 is a front view showing the shape of the wire rod after ring-shaped forming using the conventional method.

Claims (1)

【特許請求の範囲】[Claims] (1)熱間仕上圧延終了後にリング状に成形して巻取る
棒鋼・線材の方法において、前記仕上圧延工程とリング
状への成形工程の間で前記棒鋼・線材を急冷装置により
焼入れる工程と、前記焼入後急速加熱装置により焼戻す
工程と、を有して成ることを特徴とする熱間圧延棒鋼・
線材の直接焼入れ・焼戻し方法。
(1) In a method of forming a steel bar or wire rod into a ring shape and winding it after finishing hot finish rolling, the step of quenching the steel bar or wire rod in a rapid cooling device between the finish rolling step and the step of forming into a ring shape. , a step of tempering using the rapid heating device after quenching.
Direct quenching and tempering method for wire rods.
JP29834585A 1985-12-30 1985-12-30 Method for directly quenching and tempering hot rolled steel bar or wire rod Pending JPS62158826A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP29834585A JPS62158826A (en) 1985-12-30 1985-12-30 Method for directly quenching and tempering hot rolled steel bar or wire rod

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP29834585A JPS62158826A (en) 1985-12-30 1985-12-30 Method for directly quenching and tempering hot rolled steel bar or wire rod

Publications (1)

Publication Number Publication Date
JPS62158826A true JPS62158826A (en) 1987-07-14

Family

ID=17858469

Family Applications (1)

Application Number Title Priority Date Filing Date
JP29834585A Pending JPS62158826A (en) 1985-12-30 1985-12-30 Method for directly quenching and tempering hot rolled steel bar or wire rod

Country Status (1)

Country Link
JP (1) JPS62158826A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113122699A (en) * 2021-04-21 2021-07-16 山西太钢不锈钢股份有限公司 Cr13 type stainless steel wire rod and annealing method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113122699A (en) * 2021-04-21 2021-07-16 山西太钢不锈钢股份有限公司 Cr13 type stainless steel wire rod and annealing method thereof

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