JPS621446B2 - - Google Patents

Info

Publication number
JPS621446B2
JPS621446B2 JP8993982A JP8993982A JPS621446B2 JP S621446 B2 JPS621446 B2 JP S621446B2 JP 8993982 A JP8993982 A JP 8993982A JP 8993982 A JP8993982 A JP 8993982A JP S621446 B2 JPS621446 B2 JP S621446B2
Authority
JP
Japan
Prior art keywords
slag
weight
forming agent
basic
refractories
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP8993982A
Other languages
Japanese (ja)
Other versions
JPS591610A (en
Inventor
Sunao Mototani
Jiro Watanabe
Kengo Obara
Masami Kuroe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shinagawa Refractories Co Ltd
Original Assignee
Shinagawa Refractories Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shinagawa Refractories Co Ltd filed Critical Shinagawa Refractories Co Ltd
Priority to JP57089939A priority Critical patent/JPS591610A/en
Publication of JPS591610A publication Critical patent/JPS591610A/en
Publication of JPS621446B2 publication Critical patent/JPS621446B2/ja
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/28Manufacture of steel in the converter
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)

Description

【発明の詳細な説明】[Detailed description of the invention]

本発明は塩基性煉瓦屑を転炉、電気炉等塩基性
製鋼炉に使用後の煉瓦屑を主体として、滓化促進
剤および生石灰の消化防止剤ならびに硬化剤から
なる、改良された塩基性製鋼炉用複合造滓剤に係
る。 従来塩基性製鋼炉の操業においては造滓剤とし
て、一般に焼石灰を主体に使用しているが操業初
期の滓化性が不足するため螢石の併用が常識とさ
れてきた。しかし螢石を使用すると有害なフツ素
ガスが発生し、また炉内内張り耐火物(以下耐火
物という)の損傷を促進するなどの欠点があるに
もかゝわらず、焼石灰の滓化速度を高める働らき
が大きく、また溶鋼中の脱リン、脱酸反応を促進
し、炉の操業率を向上するなどの利点を有するた
め、螢石の使用は不可欠なものとされてきた。 したがつて螢石の欠点である耐火物の損傷を防
止するための対策としては、反応が活性な軽焼ド
ロマイトや軽焼マグネシアを使用して鋼中のスラ
グコントロール、すなわちスラグ中のMgO分を
飽和させて耐火物中のMgO析出を防止し、耐火
物表面に粘稠なMgO層を形成させる技術がおこ
なわれている。 本発明はこのような欠点をもつ螢石を滓化促進
剤として使用しない複合造滓剤であつて、操業初
期における造滓性を向上するとともに転炉などで
使用済の煉瓦屑を再利用したものであつて、耐火
物の損傷を防止し、しかも経済的に優位で安価な
省資源的な造滓剤を提供するものである。 すなわち、本発明は塩基性製鋼炉で使用済みの
塩基性煉瓦屑を主体に使用するため、耐火物の損
傷防止に有効なMgO成分を多量に含有し、その
うえ造滓性に有効なCaO成分も含有している。こ
の一例として、タールドロマイト、(タール、マ
グ・ドロなど)使用済煉瓦屑がMgO―CaO系組
成の代表例として挙げられる。また、滓化性を向
上するため、この煉瓦屑を粒径10mm以下に粉砕
し、融点を下げ造粒のための成形性を付与するた
めに、アルカリ含有超微粉をもつカオリン族など
の残留漂着粘土類、酸化鉄(ベンガラ、ミルスケ
ール、鉄粉等)、消石灰、炭素類の4原料をそれ
ぞれ粒径1.0mm以下で5〜10重量%添加(計20〜
40重量%)混合することによつて滓化性を著しく
向上することが実験の結果確認できた。 しかし、煉瓦屑中にCaOを含有する場合、 CaO+H2O→Ca(OH)2 の反応によつて、消化現象を起こすため消化防止
剤として、硼砂2〜6%溶液を3〜6重量%添加
混合することによつて消化を防止し、かつ母材の
溶融点を低下させる効果を挙げる。またMgCl2
飽和溶液を3〜6重量%添加して混練すると、マ
グネシアセメントを生成し硬化剤の役目をはた
す。 このようにして得られた混練物を造粒するか、
または煉瓦形状に成形し塊状に粗砕して乾燥工程
を経ないで使用するので、残存水分があるため実
用時溶鋼中でバブリング現象が発生し、その結果
造滓剤が粉化し反応がいつそう活発になり、造滓
効果が活発になる。また炭素材(黒鉛、タールな
ど)の添加によつて、造滓剤と溶鋼中の不純物と
の反応にもとずく発泡現象を防止する。すなわち
炭素分は消泡剤として働らく。 このように、本発明に係る塩基性製鋼炉用複合
造滓剤は使用済煉瓦屑を主体に配合するため、資
源の再利用に貢献し、さらに滓化性が速いこと、
消泡効果があること、耐火物の損傷防止に効果が
あること、造粒あるいは成形物を粗砕するなど所
要の形状にすることで運搬や炉内投入時の発塵防
止に有効で、種々優れた特性を具えている。 つぎに本発明の実施例を具体的に説明する。 実施例 本発明に係る造滓剤を試作して種々実験をおこ
ない効果を確認した。
The present invention is an improved basic steel manufacturing method that uses basic brick waste after being used in basic steelmaking furnaces such as converters and electric furnaces, and which contains a slag accelerator, a quicklime digestion inhibitor, and a hardening agent. Pertains to composite slag forming agents for furnaces. Conventionally, in the operation of basic steelmaking furnaces, burnt lime has generally been mainly used as a slag-forming agent, but since slag-forming properties are insufficient in the early stages of operation, it has been common practice to use fluorite in combination. However, the use of fluorite generates harmful fluorine gas and accelerates damage to the furnace lining refractories (hereinafter referred to as refractories). The use of fluorite has been considered indispensable because it has a great effect on increasing the molten steel, promotes dephosphorization and deoxidation reactions in molten steel, and improves the operating rate of the furnace. Therefore, as a measure to prevent damage to refractories, which is a drawback of fluorite, it is possible to control slag in steel by using reactively active dolomite or light calcined magnesia, that is, to reduce the MgO content in slag. Techniques are being used to prevent MgO precipitation in refractories by saturating them and forming a viscous MgO layer on the surface of the refractories. The present invention is a composite slag-forming agent that does not use fluorite, which has such drawbacks, as a slag accelerator, and improves slag-forming properties at the initial stage of operation, as well as reusing brick waste used in converters etc. The object of the present invention is to provide a slag forming agent that prevents damage to refractories, is economically advantageous, is inexpensive, and saves resources. In other words, since the present invention mainly uses basic brick waste used in basic steelmaking furnaces, it contains a large amount of MgO components that are effective in preventing damage to refractories, and also contains CaO components that are effective in slag-forming properties. Contains. As an example, tar dolomite and used brick waste (tar, mag-doro, etc.) are representative examples of MgO--CaO based compositions. In addition, in order to improve the slagability, this brick waste is crushed to a particle size of 10 mm or less, and in order to lower the melting point and give it moldability for granulation, residual kaolin group containing alkali-containing ultrafine powder is added. Add 5 to 10% by weight of four raw materials: clay, iron oxide (red iron oxide, mill scale, iron powder, etc.), slaked lime, and carbon, each with a particle size of 1.0 mm or less (total of 20 to 10% by weight)
As a result of experiments, it was confirmed that the sludge formation property was significantly improved by mixing 40% by weight). However, when CaO is contained in brick waste, the reaction of CaO + H 2 O → Ca (OH) 2 causes digestion, so 3 to 6% by weight of a 2 to 6% solution of borax is added as an anti-digestion agent. Mixing has the effect of preventing digestion and lowering the melting point of the base material. Furthermore, when 3 to 6% by weight of a saturated solution of MgCl 2 is added and kneaded, magnesia cement is produced and acts as a hardening agent. The kneaded material obtained in this way is granulated, or
Alternatively, since it is used without going through a drying process after being formed into a brick shape and coarsely crushed into blocks, there is residual moisture, which causes bubbling phenomenon in the molten steel during practical use, resulting in the slag forming agent becoming powder and the reaction occurring at any time. become active, and the slag effect becomes active. Furthermore, the addition of carbon materials (graphite, tar, etc.) prevents foaming caused by the reaction between the slag forming agent and impurities in the molten steel. In other words, the carbon content acts as an antifoaming agent. As described above, since the composite slag-forming agent for basic steelmaking furnaces according to the present invention mainly contains used brick waste, it contributes to the reuse of resources, and furthermore, it has a rapid slag-forming property.
It has a defoaming effect, it is effective in preventing damage to refractories, and it is effective in preventing dust generation during transportation and loading into furnaces by granulating or crushing molded products into the desired shape. It has excellent properties. Next, embodiments of the present invention will be specifically described. EXAMPLE The sludge forming agent according to the present invention was prototyped and various experiments were conducted to confirm its effectiveness.

【表】 この煉瓦屑を粒径10mm以下に粉砕して下表のご
とく配合した。なお比較試料としては、現在常用
中の造滓剤のうち代表的な軽焼マグネシアと、使
用済煉瓦屑単味品を挙げる。
[Table] This brick waste was crushed to a particle size of 10 mm or less and mixed as shown in the table below. Comparative samples include light burnt magnesia, which is a typical slag-forming agent currently in use, and a single product made from used brick scraps.

【表】 上表によつて、混合した試番No.1は水分10重量
%のみを添加し、同じくNo.2ないしNo.4は硼砂2
%水溶液を6重量%とMgCl2飽和溶液を3重量%
添加して、アーモンド状にブリケツテイングし
た。添加量はいずれも外掛け量である。 試料は長さ30mm、幅25mm、厚さ10mmのアーモン
ド状である。
[Table] According to the above table, mixed trial No. 1 has only 10% water added, and No. 2 to No. 4 have 2 borax.
6% aqueous solution and 3% MgCl2 saturated solution by weight
The mixture was added and briquetteted into an almond shape. All amounts added are external amounts. The sample is almond-shaped, 30 mm long, 25 mm wide, and 10 mm thick.

【表】 アーモンド状の複合造滓剤は固形のため、実用
時炉内に投入の際発塵防止に効果がある。
[Table] Since the almond-shaped composite slag forming agent is solid, it is effective in preventing dust generation when put into the furnace in practical use.

【表】 蒸壊試験は75℃で飽和蒸気中に3時間挿入し、
試料の消化程度を調べたところ、No.2は完全に崩
壊していたにも拘らず、No.1、No.3、No.4は変化
しなかつた。したがつて保管による粉化の懸念は
ないことが判つた。 #1 軟化点の測定は、試料を粉砕してゼーゲル
コーン形状に成形し、酸素―プロパン炉で
おこなつた。No.1、No.2に比較して、本発
明品No.3、No.4は軟化点が著しく低く(約
200℃程度あるいはそれ以上の差)、これは
滓化性が良いことを証明している。 #2 軟化点に関しては、造滓剤の初期滓化性を
判断する場合、造滓剤と高炉スラグの反応
速度が速い程、その効果が大きいという見
解から、各造滓剤100重量%に対して高炉
スラグ粉末(0.3mm以下)50重量%混合物
で、その軟化点を測定した。その結果、No.
1、No.2に比較して、本発明品No.3、No.4
は明らかに軟化点が低く(約100℃差)、反
応が速やかに進行することが確認できた。
この測定で、高炉スラグを採用した理由
は、転炉など塩基性製鋼炉の操業初期のス
ラグは高炉スラグによるため、造滓剤の初
期反応が重要な因子であるとの見地から、
この初期反応の速さを把握するのに適切で
あると考えたためである。 スラグ試験は、回転式侵蝕試験機を用いて滓化
性の確認実験をおこなつた。試料は80mm×60mm×
30mmのサイズで各配合についてそれぞれ成形圧力
200Kg/cm2で成形し、角度45度に傾斜した円筒内に
これらの試料を組み合せ、この円筒内ほぼ中央部
に、一辺50mmの正方形の上下面で高さ60mmの空間
部(50mm口×60mm)を形成し、この容器を回転さ
せながら酸素―プロパンバーナーで加熱し1550℃
昇温後、上記空間部に高炉スラグ片200グラムを
投入し、溶解20分後にスラグを排出して試料の侵
蝕深さを測定した。その結果、本発明品No.3およ
びNo.4はいずれも比較試料(常用商品)No.1の約
10倍、従来の使用済煉瓦屑単味からなるNo.2に比
較しても約2倍の侵蝕度を示し、本発明に係る複
合造滓剤は反応速度がきわめて速く、塩基性製鋼
炉用造滓剤として最も高性能であつて、耐火物と
の化学、物理的平衡(バランス)上から実用上有
益なものであることが実証された。
[Table] The steaming test was conducted by inserting the sample into saturated steam at 75℃ for 3 hours.
When the degree of digestion of the samples was examined, although No. 2 had completely disintegrated, No. 1, No. 3, and No. 4 remained unchanged. Therefore, it was determined that there was no concern about powdering during storage. #1 The softening point was measured by pulverizing the sample and forming it into a Segel cone shape in an oxygen-propane furnace. Compared to No. 1 and No. 2, the products of the present invention No. 3 and No. 4 have a significantly lower softening point (approximately
(difference of about 200℃ or more), which proves that it has good slagability. #2 Regarding the softening point, when determining the initial slag-forming ability of a slag-forming agent, the faster the reaction rate between the slag-forming agent and blast furnace slag, the greater the effect, so The softening point of a 50% by weight mixture of blast furnace slag powder (0.3 mm or less) was measured. As a result, No.
1. Compared to No. 2, the invention products No. 3 and No. 4
It was confirmed that the softening point was clearly lower (approximately 100°C difference) and the reaction proceeded rapidly.
The reason why blast furnace slag was used in this measurement was from the viewpoint that the initial reaction of the slag forming agent is an important factor, since the slag at the initial stage of operation of basic steelmaking furnaces such as converters is blast furnace slag.
This is because we thought it was appropriate to understand the speed of this initial reaction. The slag test was conducted using a rotary erosion tester to confirm slag formation. The sample is 80mm x 60mm x
Molding pressure for each formulation at 30mm size
These samples were molded at 200Kg/cm 2 and assembled in a cylinder inclined at an angle of 45 degrees.A space with a square shape of 50mm on a side and a height of 60mm (50mm opening x 60mm ) and heated this container with an oxygen-propane burner while rotating it to 1550℃.
After raising the temperature, 200 grams of blast furnace slag pieces were put into the space, and after 20 minutes of melting, the slag was discharged and the erosion depth of the sample was measured. As a result, both the invention products No. 3 and No. 4 were found to be about the same as comparative sample (commonly used product) No. 1.
The composite slag forming agent according to the present invention has an extremely fast reaction rate and is suitable for use in basic steelmaking furnaces. It has been demonstrated that it has the highest performance as a slag-forming agent and is practically useful due to its chemical and physical balance with refractories.

Claims (1)

【特許請求の範囲】[Claims] 1 塩基性製鋼炉で使用された塩基性煉瓦屑10mm
以下粉砕物60〜80重量%、粘土、酸化鉄、消石
灰、炭素それぞれ5〜10重量%の合計量100重量
%に対して、硼砂2〜6%溶液外掛3〜6重量
%、MgCl2飽和溶液外掛2〜6重量%添加混合、
所望形状に成形した、塩基性製鋼炉用複合造滓
剤。
1 10mm of basic brick waste used in a basic steelmaking furnace
The following: 60-80% by weight of the pulverized material, 5-10% by weight each of clay, iron oxide, slaked lime, and carbon, based on a total of 100% by weight, a 2-6% solution of borax, an outer layer of 3-6% by weight, and a saturated MgCl2 solution. Addition of 2 to 6% by weight of sokokake,
A composite slag forming agent for basic steelmaking furnaces that is molded into the desired shape.
JP57089939A 1982-05-28 1982-05-28 Composite slag forming agent for basic steel making furnace Granted JPS591610A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP57089939A JPS591610A (en) 1982-05-28 1982-05-28 Composite slag forming agent for basic steel making furnace

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP57089939A JPS591610A (en) 1982-05-28 1982-05-28 Composite slag forming agent for basic steel making furnace

Publications (2)

Publication Number Publication Date
JPS591610A JPS591610A (en) 1984-01-07
JPS621446B2 true JPS621446B2 (en) 1987-01-13

Family

ID=13984664

Family Applications (1)

Application Number Title Priority Date Filing Date
JP57089939A Granted JPS591610A (en) 1982-05-28 1982-05-28 Composite slag forming agent for basic steel making furnace

Country Status (1)

Country Link
JP (1) JPS591610A (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3726599B2 (en) * 1999-11-24 2005-12-14 Jfeスチール株式会社 Method for refining molten steel using refractory scrap containing carbon
JP4581751B2 (en) * 2005-03-07 2010-11-17 Jfeスチール株式会社 Prevention of dust from hot metal transport container
JP5347317B2 (en) * 2008-04-28 2013-11-20 Jfeスチール株式会社 How to reuse used tundish refractories
JP5391690B2 (en) * 2008-12-26 2014-01-15 新日鐵住金株式会社 Slag regulator
CN101892342B (en) * 2010-07-22 2012-04-25 新兴铸管股份有限公司 Slagging method for converter
CN109182640B (en) * 2018-09-20 2020-06-16 德龙钢铁有限公司 Method for reducing carbon oxygen deposit at smelting end point of converter
CN109750210B (en) * 2018-12-29 2020-09-22 广西长城机械股份有限公司 Production method of low-oxygen high-hydrogen-content manganese steel
RU2746198C1 (en) * 2020-04-12 2021-04-08 Акционерное общество "Завод алюминиевых сплавов" Alumina mixture for liquefaction of metallurgical slag

Also Published As

Publication number Publication date
JPS591610A (en) 1984-01-07

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