JPS621365B2 - - Google Patents
Info
- Publication number
- JPS621365B2 JPS621365B2 JP55120696A JP12069680A JPS621365B2 JP S621365 B2 JPS621365 B2 JP S621365B2 JP 55120696 A JP55120696 A JP 55120696A JP 12069680 A JP12069680 A JP 12069680A JP S621365 B2 JPS621365 B2 JP S621365B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- hair rinse
- hair
- rinse agent
- quaternary ammonium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 claims description 28
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 21
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 10
- 239000000377 silicon dioxide Substances 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- -1 polyoxyethylene group Polymers 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 2
- 229910052799 carbon Chemical group 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims description 2
- 125000005526 alkyl sulfate group Chemical group 0.000 claims 1
- 230000000694 effects Effects 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 239000003921 oil Substances 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 239000003925 fat Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000008119 colloidal silica Substances 0.000 description 3
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 3
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 229940057995 liquid paraffin Drugs 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- HNJXPTMEWIVQQM-UHFFFAOYSA-M triethyl(hexadecyl)azanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](CC)(CC)CC HNJXPTMEWIVQQM-UHFFFAOYSA-M 0.000 description 1
- OWGHQYPQNSZTFQ-UHFFFAOYSA-M triethyl(octadecyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](CC)(CC)CC OWGHQYPQNSZTFQ-UHFFFAOYSA-M 0.000 description 1
- PDSVZUAJOIQXRK-UHFFFAOYSA-N trimethyl(octadecyl)azanium Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)C PDSVZUAJOIQXRK-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
本発明はヘアーリンス剤組成物、更に詳細には
第４級アンモニウム塩とシリカ微粉末を含有する
耐久性の優れたヘアーリンス剤組成物に関する。
洗髪後の種々の弊害を除去する目的で、従来か
らすすぎ時にジステアリルジメチルアンモニウム
クロライド等の第４級アンモニウム塩を有効成分
とするヘアーリンス剤が使用されている。
ヘアーリンス剤は毛髪に柔軟性、平滑性、帯電
防止性等を付与することを目的とするものである
が、第４級アンモニウム塩のみでは柔軟性、平滑
性に関し充分な効果が得られない。従つて、従来
のヘアーリンス剤には、これらの欠点を改善する
ために、高級アルコール、グリセライド、流動パ
ラフイン等の油脂類を配合するのが一般的であつ
た。
すなわち適当な油脂類と第４級アンモニウム塩
との乳化分散系が最も好ましいと考えられてい
た。しかしながら、第４級アンモニウム塩は、効
果を発揮するに充分な量の油脂類を安定に乳化、
分散する能力を有さないため、より親水性の高い
非イオン活性剤を配合し乳化、分散系を安定に保
つことが試みられていた。ところが、親水性の高
い非イオン活性剤はリンス効果を著しく低下させ
る作用を有するため、親水性の高い非イオン活性
剤を配合したヘアーリンス剤は第４級アンモニウ
ム塩と油脂類とを配合した場合、本来のリンス効
果を充分に発揮することができないという欠点が
あつた。
また一方、従来のヘアーリンス剤組成物では、
その本来のリンス効果、すなわち、毛髪に対する
柔軟性、平滑性、帯電防止性の付与効果が未だ完
全なものでないという欠点があつた。
また更に、従来のヘアーリンス剤では、ヘアー
リンス後、時間の経過とともにそのリンス効果は
容易に消失するので、長時間安定にリンス効果を
保つ、耐久性の優れたヘアーリンス剤の開発が要
望されていた。
そこで本発明者は、従来のヘアーリンス剤の欠
点を改良し、しかもリンス効果が優れ、かつ耐久
性のあるヘアーリンス剤を得べく鋭意研究をおこ
なつた結果、第４級アンモニウム塩にシリカ微粉
末を配合したヘアーリンス剤組成物は上記目的を
達成し得ることを見出し、本発明を完成した。
すなわち、本発明は次の二成分、
(A) 一般式（）
（式中、R1，R2，R3及びR4の１〜２個は炭
素数８〜20の長鎖アルキル基又は長鎖ヒドロキ
シアルキル基を示し、残余は炭素数１〜３のア
ルキル基、ヒドロキシアルキル基、ベンジル基
又は合計付加モル数10以下のポリオキシエチレ
ン基を示し、Ｘはハロゲン原子又は炭素数１〜
２のアルキル硫酸基を示す）
で表わされる第４級アンモニウム塩の一種又は
二種以上 0.1〜20重量％、
(B) シリカの微粉末 0.1〜10重量％
を含有するヘアーリンス剤組成物を提供するも
のである。
本発明の(A)成分である第４級アンモニウム塩の
好ましい具体例としては、例えばジステアリルジ
メチルアンモニウムクロライド、ステアリルトリ
メチルアンモニウムメトサルフエート、Ｎ―ステ
アリル―Ｎ，Ｎ，Ｎ―トリ（ポリオキシエチレ
ン）アンモニウムクロライド（合計３モル付
加）、セチルトリエチルアンモニウムブロマイ
ド、スチアリルジメチルアンモニウムクロライド
等が挙げられる。
また、(B)成分のシリカとしては、SiO2で表わ
される無水珪酸、結晶水を含むシリカ、コロイダ
ルシリカ等が使用されるが、就中、水に添加した
場合、分散性が優れている点でコロイダルシリカ
が最も好ましい。これらシリカは微粉末として使
用され、その粒度は平均粒径が１〜100mμ、特
に10〜40mμのものが好ましい。このシリカは、
その吸着力によつて、毛髪に付着し、成分(A)の効
果を持続せしめる作用を有するものである。
本発明のヘアーリンス剤組成物は、常法によ
り、ヘアーリンス剤全量に対し、0.1〜20重量％
（以下％と表わす）、好ましくは0.5〜５％の(A)成
分と、0.1〜10％、好ましくは0.5〜３％の(B)成分
を水、更に必要であればアルコール、プロピレン
グリコール、グリセリン等の適当な溶剤に溶解さ
せることにより製造される。この場合、その５％
溶液のPHが通常のヘアーリンス剤のそれと同じPH
３〜８になるようにクエン酸、乳酸等の有機酸、
リン酸、塩酸等の無機酸又は苛性ソーダ等の無機
アルカリ、トリエタノールアミン等の有機アルカ
リ等で調整するのが好ましい。
本発明のヘアーリンス剤組成物には、更に必要
に応じて脂肪酸高級アルコール、ラノリン油脂、
エステル、流動パラフイン、高級脂肪酸等の油脂
類、殺菌剤、増粘剤、香料等を適宜添加配合する
こともできる。
次に実施例を挙げて説明するが本発明はこれら
実施例に制約されるものではない。
実施例 １
アニオン界面活性剤を主成分とする市販のシヤ
ンプーで毛髪の束（長さ20cm、重さ30ｇ）を洗浄
処理し、これを下記組成のヘアーリンス剤組成物
中でリンス処理し、そのリンス効果について10名
の女性専門パネラーが経時的に官能評価をおこな
つた。リンス処理は、ヘアーリンス剤組成物各10
ｇをそれぞれ40℃、500mlの温水中で溶解し、こ
の中に上記毛髪の束を30秒間浸漬し、次いで30秒
間流水ですすいだ後、タオルで水を切ることによ
りおこなつた。この結果を第１表に示す。
組 成：
The present invention relates to a hair rinse composition, and more particularly to a highly durable hair rinse composition containing a quaternary ammonium salt and fine silica powder. Hair rinses containing quaternary ammonium salts such as distearyldimethylammonium chloride as an active ingredient have been used for rinsing in order to eliminate various harmful effects after hair washing. Hair rinse agents are intended to impart flexibility, smoothness, antistatic properties, etc. to hair, but quaternary ammonium salts alone do not provide sufficient effects regarding flexibility and smoothness. Therefore, conventional hair rinses generally contain fats and oils such as higher alcohols, glycerides, and liquid paraffin in order to improve these drawbacks. That is, an emulsified dispersion system of an appropriate fat or oil and a quaternary ammonium salt was considered to be the most preferable. However, quaternary ammonium salts stably emulsify a sufficient amount of fats and oils to be effective.
Since it does not have the ability to disperse, attempts have been made to mix more hydrophilic nonionic active agents to keep the emulsification and dispersion system stable. However, since highly hydrophilic nonionic surfactants have the effect of significantly reducing the rinsing effect, hair rinses containing highly hydrophilic nonionic surfactants do not work well when combined with quaternary ammonium salts and fats and oils. However, there was a drawback that the original rinsing effect could not be fully exhibited. On the other hand, in conventional hair rinse compositions,
The drawback is that the original rinsing effect, that is, the effect of imparting flexibility, smoothness, and antistatic properties to hair, has not yet been perfected. Furthermore, with conventional hair rinses, the rinsing effect easily disappears over time after rinsing the hair, so there is a need to develop a highly durable hair rinse that maintains a stable rinsing effect for a long time. was. Therefore, the present inventor conducted intensive research to improve the shortcomings of conventional hair rinse agents, and to obtain a hair rinse agent with excellent rinsing effect and durability. The present invention was completed based on the discovery that a hair rinse agent composition containing powder can achieve the above object. That is, the present invention has the following two components, (A) general formula () (In the formula, 1 to 2 of R 1 , R 2 , R 3 and R 4 represent a long-chain alkyl group or a long-chain hydroxyalkyl group with 8 to 20 carbon atoms, and the rest are alkyl groups with 1 to 3 carbon atoms. , a hydroxyalkyl group, a benzyl group, or a polyoxyethylene group with a total number of added moles of 10 or less, and X is a halogen atom or a carbon number of 1 to
Provided is a hair rinse agent composition containing 0.1 to 20% by weight of one or more quaternary ammonium salts represented by It is something to do. Preferred specific examples of the quaternary ammonium salt which is component (A) of the present invention include distearyldimethylammonium chloride, stearyltrimethylammonium methosulfate, N-stearyl-N,N,N-tri(polyoxyethylene ) ammonium chloride (total addition of 3 moles), cetyltriethylammonium bromide, stialyldimethylammonium chloride, and the like. In addition, as the silica of component (B), silicic anhydride represented by SiO 2 , silica containing water of crystallization, colloidal silica, etc. are used, but among them, when added to water, it has excellent dispersibility. Colloidal silica is most preferred. These silicas are used in the form of fine powder, and the average particle size thereof is preferably 1 to 100 mμ, particularly 10 to 40 mμ. This silica is
Due to its adsorption power, it adheres to the hair and has the effect of sustaining the effect of component (A). The hair rinse agent composition of the present invention can be prepared in an amount of 0.1 to 20% by weight based on the total amount of the hair rinse agent by a conventional method.
(hereinafter expressed as %), preferably 0.5 to 5% of component (A) and 0.1 to 10%, preferably 0.5 to 3% of component (B), in water, and if necessary alcohol, propylene glycol, glycerin. It is manufactured by dissolving it in a suitable solvent such as. In this case, 5%
The PH of the solution is the same as that of regular hair rinse agent.
Organic acids such as citric acid and lactic acid to make the ratio 3 to 8.
Preferably, it is adjusted with an inorganic acid such as phosphoric acid or hydrochloric acid, an inorganic alkali such as caustic soda, or an organic alkali such as triethanolamine. The hair rinse agent composition of the present invention further includes fatty acid higher alcohol, lanolin oil,
Oils and fats such as esters, liquid paraffin, and higher fatty acids, bactericides, thickeners, fragrances, and the like may be added and blended as appropriate. Next, the present invention will be described with reference to examples, but the present invention is not limited to these examples. Example 1 A bundle of hair (length 20 cm, weight 30 g) was washed with a commercially available shampoo containing an anionic surfactant as the main ingredient, and then rinsed in a hair rinse composition having the following composition. A panel of 10 female experts conducted a sensory evaluation of the rinse effect over time. For rinsing, apply 10 pieces of each hair rinse agent composition.
Each hair bundle was dissolved in 500 ml of warm water at 40°C for 30 seconds, rinsed with running water for 30 seconds, and then dried with a towel. The results are shown in Table 1. Composition:
【表】【table】
【表】 結 果：【table】 Result:
【表】
評価基準：
５ 非常にしつとりしなやか感がある。
４ しつとりしなやか感がある。
３ やや しつとりしなやか感がある。
２ 殆んどしつとりしなやか感がない。
１ 全く しつとりしなやか感 〃 。
上記結果から明らかな如く、本発明のヘアーリ
ンス剤組成物は、従来の第４級アンモニウム塩の
みの処方に比べ、そのしつとりしなやか感が強化
され、また耐久性が優れたものとなる。なお、シ
リカと類似の酸化チタンを配合したヘアーリンス
剤組成物（比較品１）は殆んど効果が認められ
ず、シリカ無添加のものとほぼ同じであつた。
実施例 ２
ヘアーリンス剤組成物(1)
（組成）
ステアリルトリメチルアンモニウム
クロライド 1.0（％）
ステアリルアルコール 0.7
流動パラフイン 1.0
無水珪酸（平均粒径15mμ） 0.8
ヒドロキシエチルセルロース 0.2
グリセリン 5.0
色 素 適量
香 料 適量
水 バランス
（製法）
70℃にを加熱し、この中に撹拌しながら，
及びを加え充分に分散させる。この水相中
に、同じく70℃に加熱した，，及びの混
合液を加え、撹拌しながら45℃迄冷却し、を加
える。更に40℃迄撹拌下冷却を続けヘアーリンス
剤組成物とする。
ヘアーリンス剤組成物(2)
（組成）
ジステアリルジメチルアンモニウム
クロライド 0.5（％）
モノステアリルトリエチル
アンモニウムクロライド 2.5
シリコンオイル 2.0
コロイダルシリカ（平均粒径5mμ）
1.0
プロピレングリコール 10.0
色 素 適量
香 料 適量
水 バランス
（製法）
70℃に加熱したを撹拌しながら、及びを
加え充分分散せしめる。この水相に同じく70℃に
加熱した，及びの混合液を加え、撹拌しな
がら45℃迄冷却しを加える。更に40℃迄撹拌下
冷却を続けヘアーリンス剤組成物とする。
本実施例により製造されたヘアーリンス剤組成
物(1)及び(2)はいずれもリンス効果が優れ、しかも
耐久性の極めて優れたものであつた。[Table] Evaluation criteria: 5 Very moist and supple feeling. 4. Feels moist and supple. 3 Slightly moist and supple feeling. 2 Almost no moist and supple feeling. 1. Completely moist and supple feeling. As is clear from the above results, the hair rinse composition of the present invention has enhanced moisturizing and supple feel and excellent durability compared to conventional formulations containing only quaternary ammonium salts. The hair rinse agent composition containing titanium oxide, which is similar to silica (comparative product 1), had almost no effect and was almost the same as one without silica. Example 2 Hair rinse composition (1) (Composition) Stearyltrimethylammonium chloride 1.0 (%) Stearyl alcohol 0.7 Liquid paraffin 1.0 Silicic anhydride (average particle size 15 mμ) 0.8 Hydroxyethyl cellulose 0.2 Glycerin 5.0 Color Pigment Appropriate amount Fragrance Appropriate amount Water Balance (Manufacturing method) Heat to 70℃, and while stirring,
Add and thoroughly disperse. Add a mixture of , and , which were also heated to 70°C, into this aqueous phase, cool to 45°C with stirring, and add . The mixture is further cooled to 40° C. with stirring to obtain a hair rinse composition. Hair rinse composition (2) (Composition) Distearyldimethylammonium chloride 0.5 (%) Monostearyltriethyl ammonium chloride 2.5 Silicone oil 2.0 Colloidal silica (average particle size 5mμ)
1.0 Propylene Glycol 10.0 Color Pigment Appropriate amount Fragrance Appropriate amount Water Balance (Production method) While stirring the mixture heated to 70℃, add and thoroughly disperse. To this aqueous phase, add a mixture of and, which was also heated to 70°C, cool to 45°C with stirring, and add. The mixture is further cooled to 40° C. with stirring to obtain a hair rinse composition. Both of the hair rinse agent compositions (1) and (2) produced in this example had excellent rinsing effects and extremely excellent durability.
Claims (1)
素数８〜20の長鎖アルキル基又は長鎖ヒドロキ
シアルキル基を示し、残余は炭素数１〜３のア
ルキル基、ヒドロキシアルキル基、ベンジル基
又は合計付加モル数10以下のポリオキシエチレ
ン基を示し、Ｘはハロゲン原子又は炭素数１〜
２のアルキル硫酸基を示す） で表わされる第４級アンモニウム塩の一種又は
二種以上 0.1〜20重量％、 (B) シリカの微粉末 0.1〜10重量％、 を含有するヘアーリンス剤組成物。 ２ シリカ微粉末の平均粒径が1.0〜100mμであ
る特許請求の範囲第１項記載のヘアーリンス剤組
成物。[Claims] First-order two components (A) General formula () (In the formula, 1 to 2 of R 1 , R 2 , R 3 and R 4 represent a long-chain alkyl group or a long-chain hydroxyalkyl group with 8 to 20 carbon atoms, and the rest are alkyl groups with 1 to 3 carbon atoms. , a hydroxyalkyl group, a benzyl group, or a polyoxyethylene group with a total number of added moles of 10 or less, and X is a halogen atom or a carbon number of 1 to
A hair rinse agent composition containing: (B) 0.1 to 20% by weight of one or more quaternary ammonium salts represented by (2) representing an alkyl sulfate group; and (B) 0.1 to 10% by weight of fine silica powder. 2. The hair rinse agent composition according to claim 1, wherein the silica fine powder has an average particle size of 1.0 to 100 mμ.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12069680A JPS5746910A (en) | 1980-09-02 | 1980-09-02 | Hair rinse composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12069680A JPS5746910A (en) | 1980-09-02 | 1980-09-02 | Hair rinse composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5746910A JPS5746910A (en) | 1982-03-17 |
| JPS621365B2 true JPS621365B2 (en) | 1987-01-13 |
Family
ID=14792706
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12069680A Granted JPS5746910A (en) | 1980-09-02 | 1980-09-02 | Hair rinse composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5746910A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59184115A (en) * | 1983-04-01 | 1984-10-19 | Shiseido Co Ltd | Hair cosmetic |
| US4526781A (en) * | 1984-04-25 | 1985-07-02 | Revlon, Inc. | Hair care compositions |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1022359B (en) * | 1956-03-16 | 1958-01-09 | Wella Ag | Shampoos |
| DE1492258A1 (en) * | 1965-04-01 | 1969-12-18 | Yardley & Company Ltd | Cosmetic agent |
| DE2053505A1 (en) * | 1970-10-31 | 1972-05-10 | Wella Ag, 6100 Darmstadt | Hair treatment preparations |
| JPS5148442A (en) * | 1974-08-20 | 1976-04-26 | Hoffmann La Roche | Senshokusareta funmatsujomohatsuhogozaioyobi sonoseizohoho |
| JPS51110046A (en) * | 1975-03-24 | 1976-09-29 | Myafuku Takeji | TOMEIKOKEISEIHATSURYONO SEIZOHO |
| JPS5234939A (en) * | 1975-09-11 | 1977-03-17 | Kao Corp | Hai rinse composition |
-
1980
- 1980-09-02 JP JP12069680A patent/JPS5746910A/en active Granted
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1022359B (en) * | 1956-03-16 | 1958-01-09 | Wella Ag | Shampoos |
| DE1492258A1 (en) * | 1965-04-01 | 1969-12-18 | Yardley & Company Ltd | Cosmetic agent |
| DE2053505A1 (en) * | 1970-10-31 | 1972-05-10 | Wella Ag, 6100 Darmstadt | Hair treatment preparations |
| JPS5148442A (en) * | 1974-08-20 | 1976-04-26 | Hoffmann La Roche | Senshokusareta funmatsujomohatsuhogozaioyobi sonoseizohoho |
| JPS51110046A (en) * | 1975-03-24 | 1976-09-29 | Myafuku Takeji | TOMEIKOKEISEIHATSURYONO SEIZOHO |
| JPS5234939A (en) * | 1975-09-11 | 1977-03-17 | Kao Corp | Hai rinse composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5746910A (en) | 1982-03-17 |
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