JPS6172244A - Silver halide color photosensitive material - Google Patents

Abstract

PURPOSE:To make uniform color correction by contg. a specific colored cyan coupler. CONSTITUTION:The colored cyan coupler expressed by the formula is incorporated into a titled material. In the formula, R1 or R2 is preferably an aliphat. acyl amino group or arom. acyl amino group when R1 or R2 denotes an acyl amino group. R1 or R2 is 1-32C, more preferably 1-16C when the same is the aliphat. acyl amino group, and may be either of a chain or ring, straight chain or branched, satd. or unsatd. or substd. or unsubtd. The more preferable example of the substituent includes a halogen atom, aryl oxy group, etc. R1 or R2 is, preferably the substd. or unsubstd. phenyl group of 6-10C when the same is the arom. acyl amino group and the preferable example of the substituent is a halogen atom, etc.

Description

[Detailed description of the invention]

(Field of the Invention) The present invention provides a color photographic material 1 with improved color reproducibility.
It's related to c9, and it's related to the chasidic coupler for color correction. (By subjecting the silver halide color photographic material of the fjL technique to color development, the main beam of the modified aromatic-grade amine color and the turnip 2- react to form indophenol. , indoaniline, indamine, anomethine, fenokiguji/, phenazine 2, pigments similar to Hitere, are responsible for the formation of color images.In this method, i! The boundary V is useful for n% night, green, and red.
Old photosensitive silver halide emulsions and color image-forming couplers of n+: solid yellow, magenta, and cyan are no longer in use. The color image formed in this manner is an ideal spectral absorbing spectral absorber. Should Flj Ebo cyan color dark absorb only the # original light?Generally, green light and Yomoto should also wait for sub-absorption, and magenta color color 1 should absorb only green light, but -I It also has sub-absorption t for blue light and red light. As a way to improve this person's Ak, a masking method using a blasphemous color-forming coupler was put into practical use by Debo Awai! Do it. 77/The violet absorption of the dye produced by the coupler - 4 For the purpose of preventing oil leakage, Rie Ashio, the first ≠, 0 of the U.S.
0≠, ri27, British pin number 7, λ3゜ri J7q,
Same number /, 3≠, -! No. 7, American watch g3,! 13
,! 77/g, same u, /31. Jj1gb or same J
, P P A , Off issue fz to VcMed no Kabufu or nine people know. These two coupler beams have a zero-diameter absorptive beak, but the Kampling binary star is too large.
It is difficult to make gradient color correction due to small errors, and the fastness of the dye produced by colored couplers is not light, but when using Kushibekzo 1, which is public security, the fading of the image is noticeable. There were two shortcomings. (Objective of the invention) The purpose of this invention is to improve the various defects mentioned above. In other words, it is possible to perform uniform color correction. Color photos and materials for improving sex

[To provide b
Ru. (Structure of the Invention) The above object is to form a colored/uncoupler represented by the following general formula, and to form a color photosensitive material which is characterized by the following general formula. General formula (1) In the formula, 1 represents ureido ff5 or an acylamino group, 2 represents an acylamino group, Y represents a water atom or a halogen atom, XV'i aromatic azo group,
A heterocyclic azo group or a coupling reaction represents a dye that is removed and leaves the photographic layer. In the general formula CI), when R replaces a ureido group, it is preferably represented by the following general formula. General formula C : 1 group, sulfamoyl group, carbamoyl group, ureido group, sulfonyl group, carboxyl group, hydroxyl group, nitrone group, alkyl group, arylthio group, acyl group, sulfonamide group, acyloxy group,
Silicone vegetable products, alcohol? /cari nylamino group, oxamoyl group, thioafyl group, afurylbamoyl group, sulfinyl≠, thiofreido, thiocarbamoyl group,
Dianruaminohyak, or Ami 7 Group Nakkiri Washiko tl-
Ri's eyes may be glaring. m stands for 0 or 7, and m is 2 or more, and 3 may be 10. When 3 is a subgroup of an aliphatic group, the number of carbon atoms is 7 to 3λ, preferably 1 to /6, and is mutually cyclic, l4 or a-branched, and mwa! It may also be necessary for the Fushowa era, Okikyō, or GTM Kyō. When referring to the aromatic radical, it is preferably a phenyl group with a carbon formula of 1 to 10, and preferably a phenyl group with a carbon formula of 1 to 10. General formula (in IJ, this 1 or ζR2 is ananolamino 茫τ);! +"!L< is a fatty origin anora amino group or ζ aromatic acylamino group. Usually l or r 4, i9
, chained, circular, linear or branched, saturated or unsaturated, 10I or ζless straight. Preferred examples of the free radicals include the following: halo'Z #A
child, arylox7 group, arylthio group, aryloxycarbonyl group, alkoxycardanyl group, acylox7 group, acylamino group, sulfonamide group, hydroxyl group, carboxyl group, 7ano group, aryl group, alkoxy group, alkylthio group, These include carbamoyl, ureido group, sulfonyl group, f/l group, anilino group, or amine group. ru or v′iK 2 is aromatic Yasua/
Ruamine viscous carbon number 6 to 10 preferably 1 or direct conversion 1
Hiki is attached to the phenyl group of Maimata. Preferred examples of substituents include the following: /・rogen atom,
Sulfonamide group, alkoxy group, alkoxycarnyl group, aliphatic group, aryl group, 7/M, sulfonyl group, sulfamoyl group, anolamino group, hydroxyl group, alkylthio group, carbamoyl group, carboxyl group, imide group, carphoxol gold, hydroxyl/ruol,
Acyl carbamoyl = aliphatic acylamino group, aromatic acyl amino group 1
I got stuck and cut the grass above [Is the dust group an aliphatic group? When the number of carbon atoms is 1 to 3, preferably 7 to 6, the number of carbon atoms is 1 to 3, preferably 7 to 6. You can meet at any time. Similarly, the aromatic primordium that was listed above has a carbon number t ~ 1.
0 and preferably a phenyl group with no d substitution or no direct substitution. General formula (2 in IJ and Xri preferably the following general formula Cl
)b or (fVJ) General formula [1111%Formula% General formula (IV) In the formula, R4 represents an aromatic radical, and Ll is attached to the coupling position by a barron atom. Represents a linking group, R6 represents a hydrogen atom or a substituent, and R5 represents an atomic group that forms a diffusible dye + a- with -N=l'J-.In the general formula [■], represented by 几4 The aromatic group has 7 to 10 carbon atoms and is preferably a substituted or unsubstituted phenyl group.Substituents include an alkoxycarmenyl group, an aryloxycarbonyl-1 carbamoyl group, an acyl group, a halogen atom, Preferable examples include fatty acid group groups, sulfonamide groups, acylamino groups, nitro groups, sulfonyl groups, cyano groups, sulfamoyl groups, alkoxy groups, and dialkylamino groups. tc. The number of carbon atoms in the i part is /~36, preferably ζ/~/l, linear, direct or rt-branched, chain or cyclic, saturated or unsaturated, substitution %L< means no direct substitution. You can also use zn. The part of the aromatic primordium is the golden word Hitogi wa L
The substituent represented by R6 in formula (IV) is preferably a phenyl group or a phenyl group. Examples thereof include a group group, a sulfonyl group, a sulfamoyl shield, an aryl group, a sulfonamide group, and a cyano group. n li
When n is 2 or more, 6ri can be the same or different, expressing the conjugation of O~3.When n is ko, 6ri
When → is attached to a substituent in contact with it, it may be connected to the two groups 6 to form a cyclic structure (naphthalene/ring, etc.). The general formula (IV J2 and kL5 blown Vεn glaze is preferably one that can be narrowed down to (SL)3 s4), where 7 is a hydrocarbon residue (methyl 4, ethyl base, etc.)
where M is an alkali 11o/, a cation such as ammonium ion, and water: j! hI Ekiko Mushrooms. t is /
or 2. In the general formula (IV), Ll is preferably the following - -tJ - (J-L, 2-in the formula, (2 modified atoms, sulfur atom, ester #8 sweet,
It is an amide cycle, a sulfonamide bond, or a primary bond, and L2 is a 21-piece surikiri group group of carbon acids l to j (
廿1jE：゛Goenalenepropylene) (I1″ is represented.) The coupler of the present invention has /mo14 to jOmot4, and the preferable fL< is 3m
Mix ol~λOmol and use. -Z formula [l]-〇, FLi is expressed by the general formula (If) a! The effects of the present invention are most pronounced when using white ureid silkworms.
That's it. -P: In the invention, when used in combination with the → fixed king coupler, it is uniform.
The color correction effect is much more desirable than the home. Coupler (main coupler) V used in combination with the coupler of the present invention
Unaphthol and phenolic cyan coupler. Particularly preferred is the general formula (V) for the coupler to be used in combination with Ikubo.
It is expressed as . General formula [■] Seiko, Rt, kLz and Y have the same meanings as explained in Ichime formula CI) or [1], and Z represents a hydrogen atom or Campling separation fund. In the general formula [■], 2 is preferably a chlorine group, a Koma EB group oxy group, or an aromatic oxy group. When Z represents a fat-extended group, carbon ridge /~3, preferably /-/A is 1, chain or cyclic, linear or branched, saturated or unsaturated, direct or v 'i, unsubstituted, b is also L. As direct Pi, halogen atoms,
Aryl group, acylamino group, carbamoyl group, alkylthio group, arylthio group, alkoxy7''15s aryloki7 step, sulfonyl group, sulfonamide group, sulfamoyl group, carboxyl group, hydroxyfur group, 77
no group, sulfo group, nitro group, alkohinocarbonyl group,
Aryloki7carbonyl group, aryl group, acyloquine group, imido group, sulfamoylamino group, carbamoylamino group, amine group, sulfinyl group, ureido group, alkoxycarnylamino group, cal-gumoyloxy group, heterocycle group, aromatic group, hydroquinoamino group, phosphonyl group, %L'< is formyl group, etc. 1:) may be substituted with nCn or the like. When these 1d groups are part of the group, the number of groups is 1 to 32, preferably 1.
~ 16 and lol. Similarly, this 1I7i4 group is the part of the f fragrant group tzahitosa1! ! L or Omachi is preferably a phenyl group. In the general formula (V), when 2 is omitted from the aromatic side, the carbon number is z~10 and 69, preferably 7 directly substituted or unsubstituted phenoxy groups, 1, substituted Hong group Examples include halogen atoms, aliphatic groups, aromatic groups, alcoquinol groups, ananolamino groups, carbamoyl groups, alkylthio groups, arylthio groups, aryloxy groups, sulfonyl bonds, sulfonamide groups, sulfamoyl groups, carbonyl groups, and doroquinol groups.
Cyano group, sulfo group, alkokinocarbonyl group, aryloki7carbonyl group, ar/l group, a/ruoki7 group, ibad group, sulfamoylamino group, carbamoylamino group, amino group, sulfinyl group, ureido group , an alkoxycarbonylamino group, a carbamoyloxy group, a heterocyclic group, a hydroxyamino group, or a formyl group, and these may be further explained. These guys are fat 2! The part of the j group? The number of carbon atoms included is /~3
λ, preferably /, /1, 7, similarly containing an aromatic radical moiety, Id or 2, double phenyl groups are preferred. The coupler of the present invention is generally used by mixing a coupler represented by the general formula (V, 1) as a main coupler and an L coupler (1Jf). 1Jil (The mixing side 8 of the coupler is x dimension to the main coupler/JOmol 1 is suitable from mot%. The preferred DI coupler used in the present invention for Samurai is of the general formula (Vl), (■) or [■ ] and it becomes pregnant. General formula 1) (L3), -LJL General formula [1] ? (L3) q-1)! General formula [■] Fe + NHf1 C (JCHCtJ NH-ru,
. (Lx)q i)1 In the formula, approximately 1. R2* and Y are the same as defined in the general formula CI), and LSI is a heterocyclic thio group or a be/citriazolyl group (which may have a group). is the coupling reaction.
Fund representation %q that can be cleaved I is O or /
Represents ft. 8. 9 and 1o each represent an aromatic group, an aromatic group, or a bicyclic ring, fF. 1#i0
or / represents. The linking group represented by L3 and containing 1% is shown in U.S. Pat. British Tokuuchi No. λ, which is cleaved by an intramolecular Ifsugi If exchange reaction after detachment from the couplers described in Kohiro, R. 61, and JP-A-Sho J7-J1, No. 137. 07, 3t3, Tokukai Shoj7-/! Hiroλ3 Hiro issue, same j
Cohypothetical system described in 7-/Ir0JJ- etc.? U.S. Patent No. μ, /≠
T, 7 methylene oxides listed in the 3rd issue, Tokukai bean paste!
/-/ Oxycarginyloxy group or Machiyuaki described in Hiro trJt review! Examples include those that are cleaved by electron transfer via a single bond as described in Japanese Patent Application No. 10t223 and Japanese Patent Application No. 10tλ Co≠ of Sho J. In the present invention, On et al.'s 1! A bond may or may not be used. In the formula, L) When I represents a multi-X ring thio group, preferably tetrazolyl 1k, /, J, Hiro-thiadiazolyl-
λ-thio group, benzimidazolylthio group, this nb
By direct bonding, it can be used for aliphatic groups, aromatic groups, halogen atoms, anluamino groups, aryloxycarbonyl groups, alkoxycarbonyl groups, alkoxycarbonyl groups, amino groups, sulfo/amide groups, alcohol groups, etc. It is difficult to make two stones. In the formula υ1-gabe/citria/lyl it table v'j, preferable 1 is an id aliphatic group, an aromatic 5 group, a logeno atom, an acylamino group, an arylox/carbonyl group, an alkoxycarbonyl group, an amino group as a return group. group, sulfonamide i, alco f-'/≦, +rtUjll amino group, carbamoyloxy 7 group, alkoxycarbonyl amine 7 group,
Aryloxycarbonylamino group, or zeta frayed. tt6. Le9s? When RIO and RIO have an aliphatic group, carbon U ~ 30, preferably 7 ~ -〇 dewa 9, direct or tsubame 1 cliff, hyawa] or unsaturated, chain or chain, branched. There may be 6 in total. Preferred examples of the substituent t include arylox/kyo, alkoxy group, halogen group, alkoxycarbonyl group, acylamino group, and aryl group. When R8, 9 and 9 have a carbon number of 6 to 10, it is preferable that the phenyl group has 1 or no carbon atoms. Substituents include alkoxy groups, halogen atoms, acylamino groups, alkoxycarbonyl groups, aliphatic groups, aromatic groups, sulfonamide groups, ureido groups, and imide groups.
, sulfonyl group, sulfamoyl 6, carbamoyl 4,
Preferred examples include /ano group, alkylthio group, and alkylthio group. 8. When 9 and 10 represent a polycyclic group, the heteroatom is a nitrogen atom, an oxygen atom or a sulfur atom ρ.
It's a pleasure to eat shellfish and shellfish that are passed around. Preferred examples of the heterocycle include λ-pyridyl group, cochenyl group, caufuryl group, Hiromidazolyl group, cobyrimidinyl group,
Or 1. -1μ-triazol-3-yl group, etc. This 1"L group may further have a substituent group. (1) Preferred examples of subgroups include aliphatic groups, aromatic groups,...rogen atoms, ananolamino groups, alkoxy groups, and alkoxy groups. Or alkylthio pure. The general formula (Vl), C~1] and [city] are also 7L υ11 of the coupler /)) At least the -11 general formula (n colored card represented by [) When the coupler is used in combination with J) and %-+1 and the coupler with the general formula CVJ and 23n is used together with I:JJ-, the color reproducibility is improved. The color imparting A light-sensitive material is 1, if it is 1t.This means that the coupling speed-distortion of the coupler in Go 31 is 1.1. ;i ;s4 There is a slight difference in the actual fact that the company of the ingredients such as the current 1 millet, millet, pH 1 constant agent, etc. is properly responsible, and even if it is slightly different, it can be uniform. I made a mistake because I did it. The general formula is VIJ, (Vll)k-yohi [1vllll], and the number of moles for one history of the coupler set r, which is 100, is +
Then, - the combination of couplers expressed by the formula LIJ'''C↑
Let's say that the number of hardened moles of 85T of the Iwaishi n2 coupler is IcI in the stool mole concentration (bl strain, general formula LV), and the red sensitive milk QRinozu VCM is 7) 1 Fumitsu J mole. Number 59 ratio dial: (bl: (cl=(-~/ri:
(Yo~/j): At 100, bO time is preferable. Is this the coupler of this coupler? r: A total of 7 halogenated sickles, preferably 7 to 10 moles per X1 of the halogenated sickle. The uninvented colored coupler is used for w4J-sensitive emulsion, low-sensitivity emulsion layer or v'i-sensitive emulsion layer.
Can be used in any layer: Yes. Uj-1 tiu3b 5IJ3H COOC16H33 Kakegawa's preferred king coupler specific -j (C), JH (t) CsHx7 (E) (田5Fil 1 (J) (1'-) ch2cuueh3 CH3 U, Hll (tl (U) 1 thousand months 1 111+ζtsu 1'fu,)hLL de+rJ
N(L)-J) +I)1. :5H,,I 01'12 (v-s) ■ (Ll-9) (IJ-10) (Ll-//) (,L) ,-/uノ(Ll-/ri(L,I-/ 1.] 2 H5 (J CD-77) The compound of the present invention can be synthesized on a general POH method. The coupler represented by the formula -d formula 9 @ candy, the corresponding amine? diazotization, the equivalent 6 phenol and canoblinog, and the rc Eli piece Oy,
I'll check it out. Ma: c tj type (represented by IVJ) of the coupler that has a tongue-holding, the gap, Shio 1j, Go America, Takota defense or Vi same 4. / j , 1', j It is synthesized by the tJz method, which is similar to the synthesis method described in No. jt. Representative 1 of the coupler of the present invention
Derite below)・Ko・jΣbel. f>H theory Dll (11yqJ,,<Compound (1)
Synthesis of lower 2 to 8 routes? Synthesized from this. Fake Sen/, J6i above combination route V Koyoji'gunt'ko↓9 sweet 1 generation. Here, we will discuss the effects of compound 6 on mosquitoes in detail. o Compound 7: 3-1 and 22 of Compound 6 and 7. of Fluoropalani Robe/Zen. λr(i-N,N-dimenalformamide 200ml is combined with sodium hydroxide λ,!?τ methanol aomp<・JDeh!0
By reacting with a 0CV trowel for 2 hours, the compound 7 was
(I also used ethanol and hexagonal molluscs as the crystallization medium.) Combination of O compound 8: Mixed with 100 ml of i, r, yyzmets'-V7 chloride of compound 7 and heated to 3 at 0'C.
Br3L'J:)27.3? : Drop constant. After 1 hour, the reaction temperature was raised to 10°C, and the reaction was continued at that temperature for 3 hours. Po method (Teyossa processing is not the purpose of conversion proboscis 8τ/3゜2
Risamurai (Tan M crystal bath medium; mixed bath medium of Saigi ethyl and Hexa/). 0ization'gJ9@sei: compound 匈8/3. Ko? τ Impro/ξ Nord 100mf, yesterday 10-1 water IO-, I
i, mixed with 8 bath medium, reduced iron/! Reduction was carried out by heat reflux at the cutting edge using Example 0 Compound (Synthesis of 11: Compound 9-2 obtained in the previous step)
．． Using 32k gold, make diazonium 4 using a mixture of methanol and hydrochloric acid in the usual method with 1 ton of nitric soda,
．． Compound No. 32 was mixed with methanol and caseinoda in a water bath. Synthesis row (2) Addition of exemplified compound (3) Paradimethylaminoani 1) 73. ? ? Salt production rnL, water tom
Dissolve in a bath, cool to 0°C, and add sodium nitrite to water/θ-.
Umuko, /2? Diazotization was carried out by adding the bath solution dissolved in the bath. Coupling acid content corresponding to On - 〇FkM, caustic soda! , otsu? , 7jCJOrd, methanol 200-
9. The coupling reaction occurs in the bath liquid. Adjust the pH of the bath solution to O? water! Crystal fa precipitated by ε nor on 00-
By separating, I served the υ objective coupler (3). In the present invention, the coupler is added to the silver halide emulsion layer or ζ'
：#Kangen Photosensitivity to people, public methods, such as US+
! A method such as that described in No. 322.0λ7 is used. For example, phthalate alkyl esters (dibutyl phthanate, dioctyl 7-talate, etc.), phosphorus esters (diphenyl phosphate, triphenyl phosphate, tricresyl phosphate, octyl pterphosphatate, citric acid esters) Wl
tributyl citrate), octyl ester (tributyl octyl), alkyl amide (
e.g. Ebo7 ethyl lacrylamide), fatty acid esters (
Tributoxyethyl succinate, diethyl azelate), trino/n are esters (tite ebo torime 7/related triptylin, etc., or boiling point 3 o'c to / JOC + m $ 1; JX, guriba Ether acetate, lower alkyl acetate of butyl acetate, propion is dissolved into tate, etc. with ethyl, -butyl alcohol, menal imptylgtone, gouethoxyethyl acetate, metelselone lubricant (fCt/L), and hydrophilic colloid. Distributed to. The above-mentioned rrj1 bath medium and low temperature bath medium may be used in combination. Also, Tokuko Shoyo/-32113 consideration, Tokukai Shoyo l-j Tata 4
The dispersion method by Watagokiri described in No. tJ can also be used. When the coupler has a carvone group, it is introduced into the hydrophilic colloid A as an alkaline bath solution. It is advantageous to use gelatin as a binding agent or a protective colloid since it is used in the milk R layer and intermediate layer of uninvented light-sensitive materials, but other hydrophilic colloids may also be used. can. For example, gelatin conductors, graft polymers of gelatin and Asahi molecules, albumin, proteins such as Kaze3; cellulose derivatives such as hydroxyethyl cellulose, calhoki dimethyl cellulose, and cellulose-cleaved esters; , sugar conductors such as starch derivatives;
Polyvinyl alcohol, polyhinyl alcohol partial acetal, polyvinylpyrrolidone, polyacrylic acid, polymethacrylic acid, polyacrylamide, polyvinylimidazole, polyvinylvirazole, polyvinyl alcohol, polyvinyl alcohol partial acetal, polyvinyl alcohol, polyvinyl pyrrolidone, polyvinyl imidazole, polyvinyl virazole, etc. 8sei Kyusui Chusho can use its children's staff. As for gelatin, lime-processed gelatin r; or fast-embedded gelatin fBu11. 8: ioc, Sc+, Phot. Japan, INO/A, Pi
Enzyme-treated gelatin, which is self-contained and reliable, may be used, and gelatin hydrolysates and enzymatically decomposed products can also be used. Examples of gelatin derivatives include gelatin, thorn-ride, acid anhydride, inonoanato, bromo1 acid, alkansaldoa, vinyl sulfonamide, Frey/imidized 8-sulfonate, and polyalkylene sulfide. Type, Evo: P7
There are many compounds such as compound proboscises that can be obtained by chemical compound*1 reactions. In the device emulsion layer of the photographic light-sensitive material used in the present invention, silver halides include silver bromide, iodobromide, silver iodochlorobromide, and silver halide.
For (2), any silver chloride may be used. The bright silver halide is iodobromide, which is rich in silver iodide below /j mole. The preferred material for loading is 7.27 kg of λ mole, which is exposed to 1 mol of iodine and 1 mol of iodine is exposed to 1 mol. The size of the silver halide grains during milking (the diameter of grains that are spherical or approximate to the I'i sphere, X17
5) Yang Zeng of Lzi has the grain size of Lian, and it is based on projection L1 + Kariwa Ding. ) ζSpecial thickness: t is preferably 3μ or less. The particle size may be narrow, wide, or small. The silver halide grains in the Δ milking process may be crystalline crystals such as cubes or heliums, or heptagonal crystals such as cubes, spheres, plates, etc. ? It may be something that waits, or these crystal forms of Enokidai cedar. It may also be a mixture of particles of various crystal shapes. If the diameter of the enclosed particle is greater than or equal to its thickness, it is a super-flat plate...
Is Rogen G, η child more than JO Jin who has a total projection of 11J? It is possible to use all the emulsions that occupy the same area. Silver halide N has different layers inside and on the surface.
It may have a spherical structure, a bonded structure, or a uniform phase structure. It may be a particle in which mounds are formed as kings on the surface, or it may be a particle in which mounds are formed as kings inside the particle. Photo hole A'lIl'lF, (jl
afkiaes-4Chimie et Phys
ique Photogra-phique (P
aul l111ontel 7+: Published, /ri A7#
E), u, F, IJuffin-j)'hotogr
aphicEmulsion Ui〕emistry
(Published by i'he Focal Press, / 6A hand), V, L+, Zelikmanet al”J i
Qllklng and CoatingPhoto
graphic emulsion ('l'he
Focal)'res ÷ 1, / 6 years) etc., you can write it down and write it down. That is,
L7 Juun, neutral law, ammonia law can be any n.
Matacho bath house term and possible fd house halogen term? As for the reaction method, any combination of methods such as one-sided mixing, four-time mixing, and combinations thereof may be used. It is also possible to use a method in which the particles are formed by heating them in a low ion excess (so-called backmixing f:). Silver halide production as a form of simultaneous mixing
It is also possible to use a method in which the pAgi in the liquid phase is kept constant, that is, a so-called controlled double dilution method. According to this method, a halogenated emulsion with a crystalline shape and a nearly uniform particle size is produced. It is also possible to use a mixture of separately formed No. 2000/2000 emulsions with a diameter of 100 mm or more. In the process of preformation or physical formation of silver halides, cadmium salts, zinc salts, lead terms, merium terms, iridium salts or their complex salts, rhodium salts = their complex salts, iron salts or I'
I don't know what to do with Yoirousio. Emulsions are usually removed after precipitate formation or after physical formation, and the method used for this purpose has been the tardel pilot method, which is a method for gelling gelatin, which has been used since ancient times.
It may also contain polyanionic inorganic salts, such as sodium abrasive acid, anionic surfactants, anionic polymers (such as polystyrene sulfonic acid), or gelatin derivatives, such as fat-enhanced anorized gelatin, aromatic A sedimentation method (Flocure-7) using fluorinated gelatin, aromatic carbamoylated gelatin, etc.) may also be used.・・・Rogenated Eimitsubo, usually chemical species ~ no 0V, which is usually felt as 'f-J'i￥,', rlH, 'r
i e ser @-Llie Grundlag
ender Photography+5chenP
rosesse mit Silver-haloge
niden” (Akademische Verla
gsgesellschaft. /91I! ll') A7! The method described on page 731tL can be used. Is there a compound (I+I) that reacts with active gelatin or silver and degrades sulfur (for example, thiosulfate salts, thioureas, mercapto compounds, rhodanines)? Use of Xinhuangtan: Reducing substances (e.g. stannous salts, amines, hydrazi/derivatives, formamidine sulfuric acid, 7ran compounds); For example, total complex salts can be used alone or in combination with noble metals such as complex salts of metals of the Fuxin group such as 7)-Ft, Ir, and Pd. The photographic emulsion used for processing has been used for many years to reduce the cost of photographic performance by preventing capri during processing of light-sensitive materials, during storage, and during military processing. Contains compounds/
It can be applied to That is, anols, such as benzothiazolium salts, nitroimidazoles, nitrobenzimidazoles, chlorobenzimidazoles, bromo/dimidazoles, mercaptothiazoles, mercaptobenzothiazoles, and mercaptobenzimidazoles. , mercaptothiadiazoles, aminotriazoles, benzotria/-ols, nitrobenzotriazoles, mercaptotetrazole EJ (especially /
-phenyl-mercaptotetrazole), etc.; 7-stage mercaptopyrimidine; mercaptotriazines; thioketo compounds, such as oxatri/thione; '-Hydroxy+lmata (/, J, Ja
, 7) tetraazaindenes), R-ntaazaindenes-1, t:-: nzenothiosulfonic acid, benzenesulfine, benzenesulfo/amide, etc. can be used as anti-capri agents or stabilizers. In addition, many compounds can be fully exploited. Indefensible? The photographic emulsion TFI (formerly hydrophilic cocoid IWIIC) is used as a coating aid, to prevent band formation, to improve slipperiness, to emulsify and disperse, to prevent adhesion, and to improve photographic A properties ( If you get sick, you'll have to quit your job, get depressed, get worse). (You can use 100 active agents). γChisai r' HA ``r-to (Tsuriengopolyethylene glycol, goryechrenoglycol/polypropylene glycol=-Lugowhite kai, +wa, polynitison glycol althyl ether!A also, dipholinitinin glycol alkylaryl Ether Hu, ZV Ethylene Glycol Ester W, ZV Ethylene Glycol Ester J, ``Fulkyre/Glycol Alkyl Amide/or Amide, Tricone Polyethylene Oxide Blade L]
1 sword), glycidol derivatives (voice), argunyl succinate polyglyceride, alkylphenol polyglyceride), polyhydric alcohol fatty acid ester steel, and nonionic compounds such as Ruesdel in alcohol! Notes: Alkyl caldnate, alkyl sulfo/hydrochloride, alkylbenzene sulfonate, alkyl naphthalene sulfonate, alkyl mW esters, alkyl phosphorus wrinkle esters, N-Aflu IN-furukilta'71J Carboxyl 7 groups, sulfo groups, phospho groups, i-esters, such as esters, sulfosuccinic esters, sulfoalkyl polyoxyenalene alsol phenyl ethers, polyoxy/enalene/alkyl phosphorus esters, Anionic surfactant containing acidic group of phosphorus ester; aminoalkyl sulfo/cJ, a, aminoalkyl sulfo/cJ, a, aminoalkyl sulfo or phosphate ester, alkylpeta ink,
Both surfactants such as amine oxides: alkyl amine salts, aliphatic or aromatic secondary ammonium salts, heterocyclic primary ammonium salts such as pyridinium and imidazolium, and aliphatic or aromatic secondary ammonium salts; Cateosurfactants such as diphosphonium or sulfonium salts can be used. The photographic emulsion j of the photographic light-sensitive material of the present invention contains polyalkylene oxides, ethers, esters,
Amine and other compounds, thioether compounds, thiomorpholiy/JA1 quaternary ammonium compound theft, urethane fermentation 4
The photosensitive material V used in the present invention may also contain a urinary tract conductor, an imidanol derivative, 3-pyranolide/Category 4, and other hydrophilic colloids. Eyes such as improvement of size female quality to no
In this case, it is possible to find hundreds of dispersing proboscises of water-free or bath-bearing relatives. Relie is alkyl (meth)acrylate, alkoxyalkyl (meth)acrylate, methacryl (meth)acrylate, (meth)acrylamide,
Vinyl (world), such as D [vinyl], acrylonitrile, olefin, and vinyl, alone or! Ii
Sose or these and acrylic, methacrylic, α, β
-No! i! For example, a polymer containing a combination of hydroquinoalkyl (meth)acrylate, sulfoalkyl (methane acrylate, sten/sulfo/sulfonate, etc.) can be used. For the photographic processing of layers consisting of emulsions, known methods and known processing methods such as those described hereinabove are used. [Izu几τ]i can also be used. Depending on the purpose of this photographic processing, or a photographic processing that forms a color tone (color photographs are also included).The processed fan plate is Old 'lr 0C27,C)!O
The temperature between c'C and vcsan may be lower than iroc or may be higher than zO°c2. As a special form of tax source processing, the main beam of the tax law is
For example, 41 layers of milk? (Please note that you may use the method of processing and developing the +6 element material in an alkaline water bath.The current 1ψ Main Festival 95, the water-based one, is available in Research Disclosure/Otori No. itL?ir. Against the United States and No. 1,739,120, a British clock! / 3°!
No.3 again d4P! % allowance/, 1147.743 etc. VC
A tC of 0 can be achieved in the emulsion layer using the various methods described. This tax treatment is silver salt stabilization using thiocyanate! It's 8 years old, so I'm sorry for the inconvenience. As the foot fluid, it is best to use a commonly used type of fluid. As a foot agent, thiocyanate is a salt, thiocyanate (1), and as a foot-retaining agent, the same compound as that of young fruit can be used. During fixing, water-bathable aluminum may be used as a hardening agent. Conventional methods may be overused in cases of color dysphoria. -” ed, negative-positive method (e.g. Journal o
fmouthte 5ociety of 1～1utio
n f'1cultureand'f'elevisi
on Engineers' lr/volume (/Y!
1ll-), tt7-70/page 1cm. Is the color tax version as good as the color development? It consists of an alkaline water bath. The color development agent is a known primary amine developer, such as phenylene diamino additives (e.g. Hiro-amino-N, iN-diethylanilino, 3-
Methyl-≠-amino-IN, N-diethylanilino, q-amino-IN-ethyl-N-β- and dorothienylaniline, 3-methyl-≠-7mi/-N-ethyl-1
1-β-hydroxy7ethylaniline, 3-methyl-μm
Amino-N-niteruJN-β-methanesulfamide ethylaniline/, ≠-amino-3-methyl-ethyl-IN-β-methoxy/ethylaniline, etc.) can be used. this? Lg, L, F', A, I"11 a
S On person P h Ot Og r a p h
l CProcessing Chemistry (F
Published by ocalPress, / 46 years) P, 2.2A~
,! 2? , USA → Huh! ,/rij, 0/J thought, same co,!
? -15bt, ty4, -qf 14 r -1='
4' t J No. 7 etc.&CMe IU's? May be used. Color current 15 night is its old, alkaline pot to sulfite, carbonate, borate, and /v salt 0rLO and pH buffer,
It may contain bromides, iodides, organic anti-fogging agents, anti-fogging agents, etc. In addition, if necessary, water hardening agent, hydrochloric acid/ruamino preservative, benzyl alcohol, diethylene glycol VD@M htm mark 1° polyethylene glycol, quaternary ammonium salt, amines PO accumulation accelerator. , dye-forming coupler, current ψ coupler, barb shaved of sodium boron hydride, /-phenyl-3
- Virazolid/'s chelating agents, polycarbonate chelating agents, anti-fouling agents, etc. may also be used. The photocopying emulsion pigeon of the color development machine 1 dust trowel] appears and is quickly buried. The eyebrow processing may be performed simultaneously with the fixed eyebrow processing, or may be performed for each direction. For example, bleaching agents include iron (11
1, cobalt (Ill), chromium (■n, steel ([1)
Compounds of various types such as IR, Kino/dan, and nitrone compounds are used. For example, ferricyanide, tetrachromate, iron(1,)
M9 is an M complex salt of cobalt(III), such as etherenami/shitoha, nitrilotri,/. 3-Diamino-λ-propatol, amino/polycarbo such as vinegar: immh, or complex salts of organic acids such as citric acid, tartaric acid, and apple salts: persulfur salts, perma/ga/ba salts; nitrosophenols, etc. It's okay to use t-t. Of these, potassium ferrinanide, ethylenediamine 4 pga (
nl) Sodium and ethylenediamine 1 total 11 [(
Ill) It may be useful for ammonium mercury. Ethylenediamine is a complex salt of iron (for commercial use), which is an independent com- pany. Hour hand j, 0≠, 2,
No. 120, 1ff4j, u44/, P&A-
q, special public show 447-1'jOA number, special public show us-rr3
Fukada accelerator described in ggl, Tokukaisho! 3-6!732
In the issue, there is a lot of thiolated additives in B's own book, It7.
)D can also be done. In the pre-bath of dairy mills, nickel silver, and other compounds already known as milling, for example, American
rr specification, German watch No. 1 Koyoriλ specification,
Same girl O! Tata IT issue details, %f7!3-32731.
Publication No. j3-6713/Publication No. 43714/1
Publication number, lv) Z3-gr732 publication, same! 13-7
2t23 publication, pi j3-ta! 630, concave j3-P
143/Hokkaido, same! ! -10 蓼 J3 Publication, same! 3
-/λ11-4L Publication, J-14L/A23 Publication, Same J3-21≠Coro Publication, Research Disclosure No./7/No.P. @, Tokukaisho! O-/≠07-2
μ-mouthed thiazolidine derivatives with 6 self-exceeding n″C in the name of the name, Kimiaki Chichi≠, t-4jOA publication, JP-A-Shojl-2
No. 0132 Public Machine, 1st Tsukasa! Publication No. 3, No. 5273j, 3701. ! Thiourea visiting body described in t/No. 6, German license number 1/Core 71! Issue details, +! f Kaisho! r-/4 = 35 Iodide well mentioned in the public notice, Germany R
No. yttμio issue, lc1 core 44J'4LjO
In the specification of the No. 1, polyethylene/gamma oxides are listed as polyethylene/gamma oxides, polyamine compounds described in Japanese Patent Publication No. 1136, Japanese Patent Publication No. 4T Day 4, 1≠3 Gu Publication, same≠5'-j. The Hirohiro dirty bulletin, same! 3-ta ≠ ri No. 27 Koji, same ta ≠-367
Publication No. 27, same! ! -26! OA bulletin, same! ! -/1
It is also possible to use the 3rd AO license etc. together. The analogy can also be used in the following process. Processing process color tax source JJ"Cj minutes/! Abstract white leg bu HJr"C4 minutes water washing JJ"Cj is stable for /j seconds
3r. c Dry for J minutes/j seconds.
Sodium sulfite μ, oy Charcoal is sodium 30.09 Potassium bromide
/,≠? Hydroxyfluamine sulfur salt -1≠2≠-(N-ethyl-N-β
-Hydroxy/ethylamino)-no methylaniline chloride μ,! ? Boil the water / t (#4 white fixed liquid) Ethylenediamine 461, ferric ammonium salt, λ water salt ioo, oy ethylenediamine 4I! rl=1 disodium term! , 02 Ammonium thiosulfate water bath Kei (70 壬) ioo , o 餠! -ν Natoriwam 70.0 t
7 Noro 2
/, 0f-p
) i A, j (stable belly) formalin l
, 1 The four-component emulsion used in the present invention may be spectrally sensitized -47L in addition to methine colors # and -. The pigments used are /anino pigment, merocyanine 5-fold, double 8/ani/color, composite merocyanine pigment, holopillar/anino-chromatic, heminoania pigment, styryl color≠2 hemio-1,000-nonol pigment. is a comprehensive field. 4 children V
/-Useful dyes include /anine dyes, merocyanine dyes,
A pigment belonging to the complex merocyanine pigment. These pigments can be applied to any one of the bales that are usually used. Namely, pyrroline, tenxazoline, thiazolidine,
Pyrrole wa, oxanol cedar, thianol cedar, selenazole bales, imidasol, tetrazole rice, pyridino B, #z t; Rice grains with aromatic hydrocarbon rings fused to cedar from Andokori et al.
Applicable materials include cedar, inodor sand, benzoxazole sand, naphthoxazole paddy, dithiazole sand, naphthothiazole, benzoselenazole, benzimidazole, quinoline, etc. These groups may be substituted on carbon atoms. Merocyanine et, tri complex merocyanine dye has all the ketomethylene structures, such as cedar, and pyrazoline! −
On stage, thiohydantoin cedar,! -Thiocypzolidine--, ≠-Dione Cedar, Thiazolidine-J, ψ-Dione Cedar, Rhodanine Cedar, Thio/Gurubituruba-ka, etc.~2
V'1 is a useful sensitizing dye that can be used in a variety of applications, including a German patent.
, oio issue, US%, [u, 23/, A 3
1st issue, same u, 4L7j, 7th hiro issue, Inju,! 0
3, 77A issue, + JI Yu, siji, 00/ issue, same,
Riko, 329 direction, jdJj, +jt, Rijrigo, 1kawa 3. A72゜197 direction, 11: +lJ, otsuriμ, -/7
No., Yosuhiro, 02! , 3μ9g, II5" ≠ , 04L
A, No. 672, JA country special edition/, 2hiro-1j♂! No., Ushikoan≠Hiroshi-/≠030, IJI 32-24'J'≠
There are a lot of things that are written on the record and that you have to sell your belongings. CnZJ) rFI-sensitive dyes may be used in combination, but they can also be used in pairs, and combinations of resistant dyes can be used.
゛Yu's number, this, it's so bright; it's an old loquat and it's so good;
Use FL Rutsuso Sinko Ibara"v!li'fff#'n
ffu, A f f, j 44
j issue, le'12, ri77,219 power, same 3
, No. 397,060, same j, juu, Oj, No. 2, 1d
jJ, ju7, AltL1, 1yJ3,1.
/7,29Jq, 1crJj, 4,2F, Ri A+, (
F5JJ, All, No. 4110, 1aJ3, t 7
2. rye<, IElj, G75', No. 14uJ', 1aJ
J, 70J, J77, 1tyJJ, 742.3Q/No., bolt 3゜Ir141, tO'7, 1erlJ, J'
J7. J'Aj issue, Dohiro, Oλ&, 707 direction, Okoku Tokei/, 3μμ, 2g1 issue, 101/, Yo02. Za03, special public show 4t3-tt92141 ++2/J? 7f4
．． gl:jJtM)tfu-110611, samery-i
The awn is 1"L as described in O Tata, No. 25. It has a sensitizing dye, and in the 70th, it has no spectral RA sensitization effect. Is it a color that does not absorb spectral RA? There, one color sensitization is carried out by Sakura/Takashik St, Allll
You can also go to Chumiya. Non-invention) 1. At least one A component j' on the support
It can also be applied to multi-layer, multi-color, four-component materials with a sensitivity of τ. Tanoshiten's blue color photographic material is a +m'H, V-red sensitive emulsion on the support! The green-sensitive emulsion layer has at least one emulsion layer; For these layers, choose l-f or f according to your preference.B0/An-forming coupler for the red-sensitive emulsion layer and magenta-forming coupler for the green-sensitive emulsion layer. , one'f:r for the yellow Sugiyoshi coupler in the blue-sensitive emulsion layer.
It is customary to use both sides, but depending on the situation, different combinations may be used. Yohyunyuu 41 No. of photosensitive powder made using the present invention
The main coupler in the non-sensitizing layer is a dye-forming coupler, i.e., a color-forming coupler in the color development 1'-9 processing.
Compounds that can develop color by thermal coupling with grade amines (e.g., phenyl diamines, derivatives, amine phenol derivatives, etc.) may also be used. As a magenta coupler. ,!-Pyranoa7
Kapuku, big aK/neumidano coupler, pyrazolotriano coupler,/anoacetyl coumaron coupler, open a/ly acetonitrile coupler, yellow coupler, a/ly acetamide coupler (ylJ ebebe/diylacetanilide) pivaloylacetanilide 91), etc. These couplers are preferably non-diffusible ones that seal with a hydrogen group called a pallast group, or those that are polymerized. The coupler may be either ≠ sensitive to silver ions or vi- sensitive to silver ions. Father, colored coupler with color-corrected young fruit, Rorui is y4.1 ball and has a high level of disturbance suppression.
A coupler that releases a ll agent (a so-called VIA force brara may also be used.) In addition to 1) 11-i and couplers, there are also couplers that release a compounding reaction, and which have a colorless proboscis and which act as an inhibitor. The black colored υII-L coupling compound released may be tamed. In addition to the υ■ coupler, chemical compound 8, which releases an anti-agglomerate gold upon development, may be added to the light-sensitive material. In order to achieve the characteristics required for photosensitive materials, two or more rtts can be used together in the same layer, or the same compound can be bound to two or more different layers, of course. I can't support my left side. The photographic color formers used are conveniently selected to enhance intermediate scale images. / The maximum absorption band of the dye formed from the dye is FJI! 7 from Ioo
The maximum absorption band of the magenta dye formed from J Onm's dark, dark, maze/recolor development is approximately! OO to jrOnm
It is preferable that the maximum absorption band of the yellow dye formed from the yellow coloring μ ranges from about 000 nm to jrOnm. The uninvented photographic material may contain inorganic or organic T&M axes in the photographic emulsion layer and other hydrophilic colloids. For example, chromium salts (chromium alum, chromium acetate, etc.), aldehydes (formulthehyde, glyoxypur, geltaraldehyde 5t, etc.), N-methylol compounds (dimethylol 9-urea, methylol dimethylhydantoin, etc.). Non-Osensu/Magazine body (2,3-dihydroxydioquibuno, etc.), back injection vinyl compound nose (i, 3.s-) real talirorohe? phydro-S-triane/, /, 3-hynylsulfonyl-λ-bronoξnor, etc.,
s-triazinato), mucohalogeno odes (mufuchlor relatives, mucochinoki 7chloren t, etc.), etc.? ML′
riμ can be used in combination. In photosensitive materials produced by using a hydrophilic colloid, dyes, ultraviolet absorbers, etc. are contained in the hydrophilic colloid. . The light-sensitive material prepared using the present invention may contain, as a color antifogging agent, an I-hydroquinone derivative, an aminephenol derivative, a derivative of gallic acid, and a government-owned ascorbic acid derivative. The specific IJ is US shipping, ffco, 36
0. Ivy No. 0, 1erl, 2. Jj Otsu. No. 3.27, ° 10'', 2, ≠ 03,7
No. 27, IJ], 2, μ/r, tr
iJ issue, 42,67! , JIu issue, same! . 70/, /ri No. 7, ) 5J2, 70≠, No. 713, u
, 7, 2.1', &jP No., Ie+]J, 732.3
No. 00, same r, 7jr, 7At No., g Kaisho f0-2
No. 2212, same jO-ta 29+1? No., p] j O-
P J F 2t issue, same! 0-//(: No. 1337, I
eJ j 2- / 4tA23! g, Special Public Service 1986-2
It was written just before 3113. In the photosensitive material of the present invention, an ultraviolet absorber may be added to the hydrophilic colloid layer. 1] For example, benzotriazolated hydrogenated rice with an asol group (
V1] Eha Taste - Special Price 3. s3J, No. 79≠), ≠-thiazolides/compounds (e.g. US→ff!, J
/≠, %CD described in No. 72μ, No. 16j3, 3j2゜tri), benzophenone compounds (for example, JP-A Akihiro z-
27r≠), cinnamon ester compound (
For example, Mikuni Chichi edition 3.70! , 10! No. J, 70
7, 37j-4-VCgdg), getadiene compound theft (for example, U.S. Watch V. O≠j, self-published in issue 127)), Aibo, K
7noki 7dol compound wJ (for example, US watch 3,70
0, u! ! +j) can be used. United States Patent 3. μ Tata, No. 76i, JP-A-5≠-
≠IjJj may also be used. UV-absorbing coupler (naphthol type /a/
They may also include dye-forming couplers) or UV-absorbing polymers. In the present invention, the ultraviolet rays of 5, V absorption net (1 → constant 1) may be used as a mordant. , Rirui is Irajie/
For various purposes, water may contain dyes such as oquinonol dyes, hemioquinonol dyes, styryl dyes, melonoacine dyes,
Are cyanine dyes and azo dyes under investigation? Sill. Among them, oquinonol dyes, dihemioquinonol dyes, and mero/anine vermilion are commonly used. & In carrying out the invention, it can also be used in combination with the anti-fading agent listed below, and it can also be used in combination with the invention. . As the anti-return agent of Koyo,...Idoro sentsuno conductor, mitsuko is 24 fu, p-alkoxyphenols, p-oxyphenol conductors, and bisphenols. The common examples of hydrokinono visiting conductor are American clock λ, 360,
-20, same 2. ≠/♂, 6/3 issue, same, 67! r. Issue 3/4, same! , 70/, /ri No. 7, same λ, 20μ
, 7/3 No. 1 Bi]-97 Cor., No. 657, 2,73
2. J. No. 0, same? , 7Jj, 7Aj review, 1aJ2, 710,
10th layer number, i, r16. oir issue, British patent/, 3 Otsu 3. Octopus / No. 29, gallic fat ↓ body and wood country 3. μ57.07P No. 3,062.2
&λ, etc., and US patents r, 73r, 7Δ! for p-alkoxyphenols. No. 3
゜6rir,! No. 7o, Kimiaki Ichi≠Turco No. 77, and No. j2-&lJj of the same, and f'L of p-oxyphenol is described in U.S. Patent No. 3. Hiro 32,300
No. 1 Yu J,! 73.0/0 issue, 1yu J, j7u
. Aj7, 1ciJJ, 74L, t, jJ7, Tokukai Sho! Ko-ist33g, same! 2-/≠71 days power, same jj-
29, bisphenols are listed in US Patent No. FFJ, 700. Ryo is published in the μjj issue. Hereinafter, the present invention will be described in more detail based on the non-invention τ implementation, but the present invention is not limited thereto. Examples of leftover items 1. Cellulose acetate film support + # F + f k, F-joint texture 7: Sensitive material consisting of each layer of the number of sets, sample 10/~10! All made. (f, r, p-+/0/) 1st part; door 1 series milk ax JJ day
・・・・・・ ／ , 7 ta 2 /
m2LJ sensitizing dye I 6 x 10 for 1 mole of J Molue ■ Kanbaiteki ro for 1 mole of rhyme / , jXlo molar coupler (1") o for 1 mole of neck, o4t mole coupler Ll-J' for 1 mole of silver For θ, 00+2
Molar height 8 points Aiso bath medium Dichotilphthalate 0.69/Coupler/? 2nd Jfi: Gelatin enhances polymethyl methacrylate particles (diameter approx./.jμ): In the R layer, H-- and a surfactant agent were added as a hardening agent to the above composition. - The sample τ sample 10 was prepared using the above μ mouth. (Sample 102) Sample 10/ except that the coupler EX-/f was added to the 47th layer of Parallaxaceae 10/.
and a colleague made it. (Sample 103) Coupler (in place of coupler EX-/ in the first layer of KpVO2);
Same as sample 102 except for 7LI. (Sample 1o4t) Coupler (1) instead of coupler EX-/ in the first layer of sample 102? Coupler EX-/Other than committing an equimolar crime v
'i Sample 10λ was prepared in the same manner. (Trial ++10!r) Sample 10- No. 11- Coupler EX-/ Instead of V-coupler (3), coupler EX-//, j times the mole Ichinoguchi, but same as 1"i Fukina 102 Compound dye Inia/hydro-j,s'-dichloro-3,3 used to prepare the sample
1-(r-sulfopropyl)-2-ethylruthi γcarbo7ani/hydroxide viridinium salt crab sensitizer ■nia/human rotor ethyl-3,37-(r-sulfopropyl)-μ, j, Hiro'-57-dibencythi7carbo7ani/hydrocypoid triethylamine salt EX-/EX-,2 Na(J3S 5CJ3NaH-/CH2=CH5C)2CH2C(JNH-CH2CH2
=CH3O2CH2C(JN)l-CH2 obtained using 4-cut sea urchin tuna for samples 10/~10j of 2000
The processing shown below was carried out using Lux 17 ioo paper for red color. r 0C 1, color development 3 minutes/J
'Second λ Western White ・・・・・・・・・・・・ 6 minutes 3
0 seconds 3.7K wash ・・・・・・・・・・・・
3 minutes lj seconds 4 constant observation ・・・・・・・・・
・・≠Water wash・・・・・・・・
・・・・・・ 3 minutes ijsho 6, bamboo foot ・－・・・・・・
.../min The composition of the constant treatment used in the OS seconds is as follows. Color phenomenon 1 liquid nitro sankei kai sodium /, 02 sodium sulfite Hiroshi, oy disaster po sodium 30, 09 potassium bromide
1. Hiro? Hydroxyl/luamine dendritic salt 1. ≠2≠-(r'J-ethyl-IN-
β-Hydroquinoethylaminonorkomethyl-aniline diformate ≠, jP Add water / Ammonium bromide / lO, 09 Aqueous ammonia (corti) 2j, 0ml Ethylenediamine-tetraacetic acid sodium iron salt / 30 ? ice ir
l:g/4' II
l# Add water / l constant f
Liquid tetrabolili / is natototsumu λ, oy sodium lifeite ≠, oy ammonium thiosulfate (70%) /7! , 0rn 1 heavy sodium sulfate ≠, tf water at the tip
/ Stabilized liquid formalin 1. OI! After adding 1 g of water, the developed film was passed through dark red and green filters, and the density was measured. The results for sample 10/ are shown in FIG. Here, the value of ΔD tGl is determined by the equation), and the value of this value of tGl is obtained by calculating the results of several filters 7 against bonds for each of samples 10/~10j. 7
summarized in. Formula il+ △IJ((H1= IJICI −Dm i +1(G
) Here, ``IC;l'' represents the optical Q degree after applying the green filter in the brightness of light.When the case does not contain a colored coupler (5, 10/), a
l/An#MK? 1, and the magenta density also increases to 4 m imagewise, but when colored coupler E is added/Kanaji; when pressed (sample IO and gold color is considerably relaxed). Also, colored coupler Ex-s is added. In Shifc@ai (sample 103), the lower part of the base is overly masked, whereas the part of the base of the island is not masked. Also, it is uneven and hot as a masking,
This is not a satisfactory level from the viewpoint of the precise color correction required. In contrast, (1) of the present invention as a colored coupler
When Fu-Yobi (3) was used (sample 104t, 10ri), a uniform mask was obtained (29), and it is clear that the colored coupler of the present invention can be used with a vague mask. Example 1 Example t, sample 10/~/ 0.!
1, yh f -i m 11. Left 1dlFJ]
4Lf, i-yor; @L After applying the heat, we conducted one test on the solidity of the samples at the processing station. Each sample was placed in an uncontrolled atmosphere at too °C. Table 2V shows the decrease in density of the 777 color image when stored in the dark for 3 days.
11 or (3) (sample io≠ or 10
It shows modest and excellent color image preservation. EXAMPLE J3 Multilayer color quaternary material samples consisting of 6 increments of composition as shown below were prepared on a cellulose acetate film support. 1st layer; gelatin layer containing haley/y/prevention layer black colloid)' mk, 2nd layer; middle layer d, j-di-t-octylhydrokino/emulsification dispersion example gelatin layer 3rd layer; First red-sensitive emulsion layer silver iodobromide hole Δsu (silver iodide; jmol 壬)・・・・・・・・・−
... Silver coating amount / , A? /m2 Sensitive dye I・・・・・・・・・・・・・≠ per mole of silver! X70 Molar sensitizing dye■・・・・・・・・・・・・'M! For 1 mole/! x10 molar coupler (I!')...0 for 1 mole of nitrogen
．． 0/! Molar coupler ((J)...0.0 per mole of d
/! Molar coupler L) -J...t o for 1 mole of M,
ooor molar increase in tl; 1st red-sensitive emulsion non-iodobromide milk A (iodizing agent: 10 mol prefecture)...
・・・・Silver coating amount /,μ2/m2 Sensitizing dye 1・・・・・・・・・・・・3×7θ for 1/7 molar Sensitizing dye mouth・・・・・・・・・・・・・・・・per 1 mole of sparse/X10 molar coupler EX-s・・・・・・・・・o, oos molar coupler (C) per mol of silver・・・・・・・・・・・・...@0.0/7th mole for 1 mole! No. 8: Same as intermediate layer No. 21- tNi: First green-sensitive emulsion layer Silver iodobromide emulsion (Silver iodide: Hiromori)...
... Silver coating amount / , 2? /m2 Sensitizing dye■・・・・・・・・・・・・For 1 mole of silver! x10 molar comparison "kokan tomoe A IV.........UXlo to 1 mole of silver Molar coupler E person-t.........For 1 mole of me 0.0j mole coupler EX-7・・・・・・・・・・・・・0.00t mole coupler EX-J′・・・・・・・・・・・・・・・・1 silver
o, ooir morsi 4 7 IfJ; g' A1. τ):);
The emulsion's odour, the milking punishment (Iodized iron; zamol jin)...
・・・－・・・・・・Silver coating / Ifi / , 3 Y
/+n2Wa 4% dye■・・・・・・・・・・・・
3x70 for 1 mole of mole coupler E, X-2... ...0.0/7 mole of coupler E per 1 mole of silver -7O ---0.003 mole per 1 mole of silver; Yellow filter single-layer gelatin in water bath Yellow colloidal silver and one, J-G-T-
Gelatin layer called emulsification dispersion of octylno-hydrokino/Second layer: First practical emulsion layer Silver iodobromide emulsion (Iodide: t mol %)...
...am cloth* 0.7Y/m2 coupler EX-//...... 0.2j mol coupler kJX-/u for 1 mol V thread・・・-・@i0.0/for 1 mole! 1st mole or@: 42Wg emulsion layer silver iodobromide (silver iodide: 6 moles)・・・・・・・・・・・・
・Silver coating fEQ, A? / ””2 coupler EX
-／／・・・・・・・・・・・・0.0% per mole of silver.
06 mol 1st/f-: First protective layer silver iodobromide (iodide @ 1 mol, average grain size 0.07μ)...
・・・・・・・・・Amount of silver coating 0, j f
7m2 Gelatin layer, which refers to an emulsified dispersion of UV-absorbing LIV-/;
μ) r mo-mu se'latte 7 layers? Construction. Add gelatin hardening 41 H-/-P surface activator to the above groups rJi and vI to make 7ζ. above a
The sample prepared by o< was designated as the sample ++-O/. (Wipe) +-0d) Wipe) +u O/3rd layer p and 4th layer - Cubjie EX
-3 to 1 mole of armpit, respectively 0.0037 lb.
Sample 1 was prepared in the same manner as Sample 20/, except that 0.00/t mol was added. (Sample! 03) Trial) −+Co0λ 3rd I-3 yohi μth layer coupler EX
-71 puller bx-hirot, coupler EX- instead of JQ
Samples 10'' and 1σ'' were prepared except that the same molar amounts as 3 and 3 were added. (Sample #04t) Sample Co. +6J was also used except that coupler (2) was added in place of coupler Eλ-3 in the third layer of kHz 20λ and the μth shield, and several moles of coupler EX-3 were added. Te Kui no Saki Leghi. (Sample-〇j) Coupler EX-J of the 31st-2nd Hiro layer of sample JO
It was prepared in the same manner as the sample sample except that the coupler (9) was replaced with the coupler EX-3 and the Tanidera mold. Compounds used to prepare all samples m color sensitive aV near/hydro-2-ethyl-! ,! '-dichloro3.3'-di(r-sulfopropyl)oxypcarbocyani/・sodium salt sensitized color 6; anhydro-
s, t, s', t'-tetrachloro-/,/'-diethyl-3.3'-di(β-[β-(r-sulfopropoxy)ethquine]ethylimigzolocarbo/anine hydroxide sodium triwam) Salt EX-Hiroko (C) 12)z Hot Jx-s H x-6 α Coupler E, ', -7 r! a Coupler E included -2 Coupler E, ~-10 Coupler Eλ-// 8 people -/- LJV-/ Hjed sample λO/~2o! About 1 ooo lux 17 ioo using renbotsuenochi, after the red fukiyu, middle R,? +11. The same process was performed. Example 1: The current R-processed n7ζ film was passed through a red and black filter for basic y measurements. Similar to the above, several pieces of butterfly were used to determine the amount of tGl gold, and the results were summarized in Table 3. sample −0≠ and sample λor)('
It turns out that there is an uninvented colored coupler that can be obtained by a four-dimensional mask.

[Brief explanation of the drawing]

Figure 7 shows sample /Q/ → Emagumori. Special Edition Fuji Photo Film Company Figure 1 Procedural Amendment 1, Indication of Incident Showa! Application No. 19412r
No. 1, No. 2, Title of the invention Silver halide color photographic light-sensitive material 3, Relationship with the case of the person making the amendment Patent applicant 4, Subject of the amendment Column 5 of “Detailed Description of the Invention” of the specification, Contents of the amendment E! The description in the "Detailed Description of the Invention" column of the AMB document is amended as follows. (1) Insert "or a substituted or unsubstituted naphthyl group" after "phenyl group" on page r, line 16. (2) Insert "hydroxyl group," after "alkoxy group," on the μth line of the first page.

Claims (1)

[Scope of Claims] A silver halide color photographic light-sensitive material characterized by containing a colored cyan coupler represented by the following general formula. General formula [I] ▲There are mathematical formulas, chemical formulas, tables, etc.▼ In the formula, R_1 represents a ureido group or an acylamino group, R_2 represents an acylamino group, Y represents a hydrogen atom or a halogen atom, and X represents an aromatic azo group, a heterocyclic azo group, or a diffusible dye that is detached and removed from the photographic layer by a coupling reaction.