JPS6152760B2 - - Google Patents
Info
- Publication number
- JPS6152760B2 JPS6152760B2 JP54073144A JP7314479A JPS6152760B2 JP S6152760 B2 JPS6152760 B2 JP S6152760B2 JP 54073144 A JP54073144 A JP 54073144A JP 7314479 A JP7314479 A JP 7314479A JP S6152760 B2 JPS6152760 B2 JP S6152760B2
- Authority
- JP
- Japan
- Prior art keywords
- water
- acid
- copolymer
- weight
- aqueous medium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001577 copolymer Polymers 0.000 claims description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 20
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 16
- 150000003839 salts Chemical class 0.000 claims description 16
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 claims description 10
- 239000000654 additive Substances 0.000 claims description 10
- 230000015572 biosynthetic process Effects 0.000 claims description 10
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 230000000996 additive effect Effects 0.000 claims description 7
- 239000012736 aqueous medium Substances 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 5
- 239000011976 maleic acid Substances 0.000 claims description 5
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 230000002401 inhibitory effect Effects 0.000 claims 1
- 150000002505 iron Chemical class 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 12
- 239000010802 sludge Substances 0.000 description 12
- 235000002639 sodium chloride Nutrition 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 238000012360 testing method Methods 0.000 description 7
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 229910052742 iron Inorganic materials 0.000 description 5
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 5
- 229910019142 PO4 Inorganic materials 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 230000003750 conditioning effect Effects 0.000 description 4
- 150000003009 phosphonic acids Chemical class 0.000 description 4
- 239000001488 sodium phosphate Substances 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 235000011121 sodium hydroxide Nutrition 0.000 description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 description 3
- 235000011152 sodium sulphate Nutrition 0.000 description 3
- 235000010265 sodium sulphite Nutrition 0.000 description 3
- MNCGMVDMOKPCSQ-UHFFFAOYSA-M sodium;2-phenylethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=CC1=CC=CC=C1 MNCGMVDMOKPCSQ-UHFFFAOYSA-M 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- QQVDJLLNRSOCEL-UHFFFAOYSA-N (2-aminoethyl)phosphonic acid Chemical compound [NH3+]CCP(O)([O-])=O QQVDJLLNRSOCEL-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- QIFCIFLDTQJGHQ-UHFFFAOYSA-M potassium;2-phenylethenesulfonate Chemical compound [K+].[O-]S(=O)(=O)C=CC1=CC=CC=C1 QIFCIFLDTQJGHQ-UHFFFAOYSA-M 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000011008 sodium phosphates Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical class [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 2
- YUEFGDDCJLELFH-UHFFFAOYSA-N (2-amino-1-phosphonoethyl)phosphonic acid Chemical compound NCC(P(O)(O)=O)P(O)(O)=O YUEFGDDCJLELFH-UHFFFAOYSA-N 0.000 description 1
- MJPWXCPGHYETKV-UHFFFAOYSA-N (3-hydroxy-1-phosphonopropyl)phosphonic acid Chemical compound OCCC(P(O)(O)=O)P(O)(O)=O MJPWXCPGHYETKV-UHFFFAOYSA-N 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- JTKYQIJFSJJSDU-UHFFFAOYSA-N 2-phenylethenylsulfonyl 2-phenylethenesulfonate Chemical compound C=1C=CC=CC=1C=CS(=O)(=O)OS(=O)(=O)C=CC1=CC=CC=C1 JTKYQIJFSJJSDU-UHFFFAOYSA-N 0.000 description 1
- GLULCKCBVYGUDD-UHFFFAOYSA-N 2-phosphonobutane-1,1,1-tricarboxylic acid Chemical compound CCC(P(O)(O)=O)C(C(O)=O)(C(O)=O)C(O)=O GLULCKCBVYGUDD-UHFFFAOYSA-N 0.000 description 1
- MOMKYJPSVWEWPM-UHFFFAOYSA-N 4-(chloromethyl)-2-(4-methylphenyl)-1,3-thiazole Chemical compound C1=CC(C)=CC=C1C1=NC(CCl)=CS1 MOMKYJPSVWEWPM-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 239000007832 Na2SO4 Substances 0.000 description 1
- YIKJVGZVJVPVPA-JSDYAFQMSA-N OC(=O)\C=C/C(=O)OS(=O)(=O)C=CC1=CC=CC=C1 Chemical compound OC(=O)\C=C/C(=O)OS(=O)(=O)C=CC1=CC=CC=C1 YIKJVGZVJVPVPA-JSDYAFQMSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001414 amino alcohols Chemical class 0.000 description 1
- XDIJWRHVEDUFGP-UHFFFAOYSA-N azanium;2-phenylethenesulfonate Chemical compound [NH4+].[O-]S(=O)(=O)C=CC1=CC=CC=C1 XDIJWRHVEDUFGP-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- MSJMDZAOKORVFC-UAIGNFCESA-L disodium maleate Chemical compound [Na+].[Na+].[O-]C(=O)\C=C/C([O-])=O MSJMDZAOKORVFC-UAIGNFCESA-L 0.000 description 1
- 235000019800 disodium phosphate Nutrition 0.000 description 1
- 229910000397 disodium phosphate Inorganic materials 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- GATNOFPXSDHULC-UHFFFAOYSA-N ethylphosphonic acid Chemical compound CCP(O)(O)=O GATNOFPXSDHULC-UHFFFAOYSA-N 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 229910052588 hydroxylapatite Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- MBKDYNNUVRNNRF-UHFFFAOYSA-N medronic acid Chemical compound OP(O)(=O)CP(O)(O)=O MBKDYNNUVRNNRF-UHFFFAOYSA-N 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- -1 poly(methylene) phosphonic acids Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- ATLPLEZDTSBZQG-UHFFFAOYSA-N propan-2-ylphosphonic acid Chemical compound CC(C)P(O)(O)=O ATLPLEZDTSBZQG-UHFFFAOYSA-N 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000019983 sodium metaphosphate Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000008400 supply water Substances 0.000 description 1
- 229920001864 tannin Polymers 0.000 description 1
- 239000001648 tannin Substances 0.000 description 1
- 235000018553 tannin Nutrition 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
- C02F5/14—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing phosphorus
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US91571378A | 1978-06-15 | 1978-06-15 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS551897A JPS551897A (en) | 1980-01-09 |
| JPS6152760B2 true JPS6152760B2 (pl) | 1986-11-14 |
Family
ID=25436161
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7314479A Granted JPS551897A (en) | 1978-06-15 | 1979-06-12 | Scale preventive composition and its method |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS551897A (pl) |
| CA (1) | CA1114978A (pl) |
| DE (1) | DE2923718A1 (pl) |
| ES (1) | ES481476A1 (pl) |
| FR (1) | FR2431999A1 (pl) |
| GB (1) | GB2023121B (pl) |
| IT (1) | IT1121786B (pl) |
| SE (1) | SE431533B (pl) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63176871A (ja) * | 1987-01-17 | 1988-07-21 | Daihatsu Motor Co Ltd | トランスミツシヨンの潤滑装置 |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PT71647B (en) * | 1979-08-16 | 1982-01-21 | Calgon Corp | Process for preparing a composition for the control of scale and deposits in gas-liquid separation |
| US4306991A (en) | 1979-09-18 | 1981-12-22 | Chemed Corporation | Scale inhibition |
| CA1151498A (en) * | 1979-10-23 | 1983-08-09 | Dearborn Chemicals Ltd. | Treatment of aqueous systems |
| DE3230291A1 (de) * | 1981-08-18 | 1983-03-03 | Dearborn Chemicals Ltd., Widnes, Cheshire | Zusammensetzung zur verhinderung von kesselstein in waessrigen systemen |
| US4409192A (en) * | 1982-04-26 | 1983-10-11 | Betz Laboratories, Inc. | Gas scrubbing methods |
| JPS58199877A (ja) * | 1982-05-03 | 1983-11-21 | ナルコ・ケミカル・カンパニ− | 鉄金属の腐蝕防止用組成物及び方法 |
| CA1207211A (en) * | 1982-09-27 | 1986-07-08 | Dionisio G. Cuisia | Composition and method for inhibiting scale |
| US4581145A (en) * | 1982-09-27 | 1986-04-08 | Dearborn Chemical Company | Composition and method for inhibiting scale |
| US4556493A (en) * | 1983-02-16 | 1985-12-03 | Dearborn Chemical Company | Composition and method for inhibiting scale |
| CA1224999A (en) * | 1983-02-16 | 1987-08-04 | Dionisio G. Cuisia | Composition and method for inhibiting scale |
| US4576722A (en) * | 1983-02-22 | 1986-03-18 | The Mogul Corporation | Scale and sludge compositions for aqueous systems |
| CA1258963A (en) * | 1983-03-07 | 1989-09-05 | Bennett P. Boffardi | Synergistic scale and corrosion inhibiting admixtures containing carboxylic acid/sulfonic acid polymers |
| GB8311002D0 (en) * | 1983-04-22 | 1983-05-25 | Unilever Plc | Detergent compositions |
| DE19514272C2 (de) * | 1995-04-21 | 1997-02-20 | Amtra Aquaristik Gmbh | Mittel und Verfahren zur Regulierung der Härte und des pH-Wertes des Wassers von Süßwasseraquarien |
| EP0785174A1 (en) * | 1996-01-22 | 1997-07-23 | Monsanto Europe S.A./N.V. | Use of triaminophosphonates in cement |
| US6310031B1 (en) * | 1999-11-30 | 2001-10-30 | Amway Corporation | Method of inhibiting soil redeposition |
| CN107973425A (zh) * | 2017-12-13 | 2018-05-01 | 攀枝花钢城集团瑞天安全环保有限公司 | 复合缓蚀阻垢剂及其制备方法 |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5035065A (pl) * | 1973-02-14 | 1975-04-03 | ||
| JPS5175681A (ja) * | 1974-12-26 | 1976-06-30 | Chemed Corp | Mizujunkankeinitaisuru horiakurirusan hosupponsanshoriho |
| FR2322831A1 (fr) * | 1975-09-08 | 1977-04-01 | Betz Int | Copolymeres de styrene sulfone et d'anhydride maleique pour le controle de la formation et du depot de tartre, de boue et, en particulier, de phosphate de calcium dans des milieux aqueux |
| JPS5265140A (en) * | 1975-11-25 | 1977-05-30 | Chemed Corp | Method of preventing corrosion in water system and anticorrosion agent used in the method |
| US4048066A (en) * | 1976-11-17 | 1977-09-13 | Chemed Corporation | Method of inhibiting scale |
| JPS52110288A (en) * | 1976-01-07 | 1977-09-16 | Calgon Corp | Control of scale and deposition in scrubber |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3549538A (en) * | 1967-06-22 | 1970-12-22 | Nalco Chemical Co | Scale inhibition and removal in steam generation |
| US3890228A (en) * | 1973-04-13 | 1975-06-17 | Chemed Corp | Polyacrylate-polyphosphonic acid treatment in aqueous systems |
| IT1038850B (it) * | 1974-06-10 | 1979-11-30 | Grace W R & Co | Processo per il trattamento di acque |
| GB1539974A (en) * | 1976-11-10 | 1979-02-07 | Ciba Geigy Ag | Method of inhibiting corrosion and scaling of metals in contact with water |
-
1979
- 1979-05-30 CA CA328,648A patent/CA1114978A/en not_active Expired
- 1979-06-11 IT IT23459/79A patent/IT1121786B/it active
- 1979-06-12 DE DE19792923718 patent/DE2923718A1/de not_active Ceased
- 1979-06-12 SE SE7905174A patent/SE431533B/sv not_active IP Right Cessation
- 1979-06-12 ES ES481476A patent/ES481476A1/es not_active Expired
- 1979-06-12 JP JP7314479A patent/JPS551897A/ja active Granted
- 1979-06-12 FR FR7915042A patent/FR2431999A1/fr active Granted
- 1979-06-15 GB GB7920922A patent/GB2023121B/en not_active Expired
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5035065A (pl) * | 1973-02-14 | 1975-04-03 | ||
| JPS5175681A (ja) * | 1974-12-26 | 1976-06-30 | Chemed Corp | Mizujunkankeinitaisuru horiakurirusan hosupponsanshoriho |
| FR2322831A1 (fr) * | 1975-09-08 | 1977-04-01 | Betz Int | Copolymeres de styrene sulfone et d'anhydride maleique pour le controle de la formation et du depot de tartre, de boue et, en particulier, de phosphate de calcium dans des milieux aqueux |
| JPS5265140A (en) * | 1975-11-25 | 1977-05-30 | Chemed Corp | Method of preventing corrosion in water system and anticorrosion agent used in the method |
| JPS52110288A (en) * | 1976-01-07 | 1977-09-16 | Calgon Corp | Control of scale and deposition in scrubber |
| US4048066A (en) * | 1976-11-17 | 1977-09-13 | Chemed Corporation | Method of inhibiting scale |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63176871A (ja) * | 1987-01-17 | 1988-07-21 | Daihatsu Motor Co Ltd | トランスミツシヨンの潤滑装置 |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2023121B (en) | 1982-08-25 |
| JPS551897A (en) | 1980-01-09 |
| FR2431999B1 (pl) | 1985-05-10 |
| ES481476A1 (es) | 1980-07-01 |
| FR2431999A1 (fr) | 1980-02-22 |
| DE2923718A1 (de) | 1979-12-20 |
| IT7923459A0 (it) | 1979-06-11 |
| GB2023121A (en) | 1979-12-28 |
| SE431533B (sv) | 1984-02-13 |
| SE7905174L (sv) | 1979-12-16 |
| CA1114978A (en) | 1981-12-22 |
| IT1121786B (it) | 1986-04-23 |
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