JPS6145199Y2 - - Google Patents
Info
- Publication number
- JPS6145199Y2 JPS6145199Y2 JP1979151556U JP15155679U JPS6145199Y2 JP S6145199 Y2 JPS6145199 Y2 JP S6145199Y2 JP 1979151556 U JP1979151556 U JP 1979151556U JP 15155679 U JP15155679 U JP 15155679U JP S6145199 Y2 JPS6145199 Y2 JP S6145199Y2
- Authority
- JP
- Japan
- Prior art keywords
- dyed
- printed
- fabric
- dyeing
- yarn
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004744 fabric Substances 0.000 claims description 31
- 238000004043 dyeing Methods 0.000 claims description 30
- 229920000728 polyester Polymers 0.000 claims description 10
- 239000000975 dye Substances 0.000 description 17
- 238000000034 method Methods 0.000 description 17
- 239000003795 chemical substances by application Substances 0.000 description 8
- 239000000835 fiber Substances 0.000 description 6
- 239000000986 disperse dye Substances 0.000 description 5
- 238000007639 printing Methods 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 238000010018 discharge printing Methods 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- LNETULKMXZVUST-UHFFFAOYSA-N 1-naphthoic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=CC2=C1 LNETULKMXZVUST-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- MMINFSMURORWKH-UHFFFAOYSA-N 3,6-dioxabicyclo[6.2.2]dodeca-1(10),8,11-triene-2,7-dione Chemical group O=C1OCCOC(=O)C2=CC=C1C=C2 MMINFSMURORWKH-UHFFFAOYSA-N 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N Benzoic acid Natural products OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 241001532207 Dasylirion Species 0.000 description 1
- 235000008763 Dasylirion wheeleri Nutrition 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- -1 benzoic acid ester Chemical class 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011158 quantitative evaluation Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 description 1
- 238000012876 topography Methods 0.000 description 1
Landscapes
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Description
本考案は、ポリエステル系フイラメント布帛か
らなる新規な捺染物に関するものである。さらに
詳しくは、大きな均染差からなるコントラストを
もつ模様のある特異な外観のポリエステルフイラ
メント布帛に関するものである。
従来、染着性を有するフイラメント布帛を得る
主な方法としては、先染めしたフイラメントを交
撚したり、染着性の異なる繊維を交撚または混繊
したものを布帛に形成し染色する方法がとられて
いた。これらの方法はいずれも染色性の異なるフ
イラメントを２種以上用いなければならないた
め、それぞれの繊維の欠点を回避できないほか、
フイラメントに個有の過度の均質性からなる単調
さがあつた。
これに対し、特開昭51−147618号等において開
示されているような、長手方向に小周期の太さ斑
や配向斑を有するフイラメントが開発された。か
かるフイラメントからなる布帛は構成糸の太さ
斑、染斑、撚斑、収縮斑、布帛中での不均一な蛇
行などをもたらし、天然繊維に似た自然な調子を
もつものであつた。しかし、このようなこなれた
斑をもつ布帛にも、布帛全体が同じような調子を
もつているという単調さはある。本考案者らは鋭
意研究の結果、特異な効果をもつ捺染布帛を考案
した。すなわち、本考案は次の構成を有する。
糸条の長手方向に染着差を有する単一種のポリ
エステル系フイラメントからなる布帛において、
地型部と捺染部が３級以上の均染差からなるコン
トラストをもつ模様を形成しており、かつ該地型
部または該捺染部の、いずれか一方が均染であ
り、他方は不均染であることを特徴とする捺染布
帛。
以下本考案について詳述する。
本考案で云うポリエステルとは、エチレンテレ
フタレート単位を80モル％以上を含むものであ
る。共重合成分としては、アジピン酸、セバシン
酸、イソフタル酸、ジフエニルジカルボン酸、ナ
フタリンカルボン酸などの二塩基酸類、オキシ安
息香酸の如きオキシ酸類、および、ジエチレング
リコール、プロピレングリコール、ネオペンチル
グリコール、ペンタエリスソトール、ポリエチレ
ングリコールモノメチルエーテルなどのグリコー
ル類のうちから１種または、２種以上のものを使
用したものである。
上述した単一種からなるポリエステル系繊維フ
イラメントは糸の長手方向に易染部と難染部とを
不規則に有していることを必須の条件とする。こ
のような糸条を製造する方法としては、延伸中に
間歇的に延伸部と未延伸部を与える方法や、加工
糸製造中に、200℃以上に保たれたホツトプレー
トやピンに、間歇的に接触させたり、さらには、
繊維束に、間歇的に、未解撚部を与える方法など
で得られたものであり、その製造法は特に限定れ
ないが、易染部と難染部のある糸条の太さの変化
をEVENESS TESTER（計測器工業製）で
USTER（Ｕ）％を測定して得た値が２％から30
％の範囲にある糸条が適当である。すなわち、Ｕ
％を測定して得た数値が30％以上であると、未延
伸糸が多いため、濃淡差が著しく、均染化は困難
であり、さらには、強力低下を招きやすい。本考
案による均染部の染着性を得るためにはＵ％が低
いほど有利であることから、望ましくは２〜20％
が良い。このような糸条は、たとえば、断面積の
大きい部分の複屈折が15〜80×10-3で、断面積の
小さい部分の複屈折が90〜200×10-3、糸条の長
手方向のFYL値の変動係数CV％が0.80％以下の
糸条に相当する。かかる糸条の製造方法は、たと
えば、特開昭51−147618号公報に開示されてい
る。このような糸条からなる布帛の一部に均染性
のある染着部を与える方法としては、
(1) 分散染料の中で、染料メーカーがＥ型また
は、SE型と呼称している染料を主として使用
する。
(2) 分散染料のタイプを問わず、均染能を有する
助剤を使用するなどの方法が考えられる。(1)で
は一般に、昇華堅ろう度が不良であり、また、
ビルドアツプ性が小さく、しかも、本考案で云
う均染性を満足させる染料が少ないのが現状で
ある。そのため、(2)で述べた選択された均染剤
を使用するのが望ましい。
均染性や不均染性の数量的な評価方法として
は、まだ、一般的に確実されていないため、発明
者らは、次の方法により、視覚的に均染性を評価
した。
(1) 基準染料の染色条件
第１表に挙げた基準染料 0.6％o.w.f.
染色浴のPH ５
浴比 １：40
昇温速度 70℃から15℃／min
温度、時間 130℃、30分
上記の条件で染色し、通常の還元洗浄を施す。
(2) 均染性評価基準
上記の染色布のイラツキや霜降りの程度と他の
染料による染色布や捺染布である被評価布の染色
面を比べて、均染性の等級を決定する。
The present invention relates to a novel printed material made of polyester filament fabric. More specifically, the present invention relates to a polyester filament fabric having a unique appearance and having a contrasting pattern consisting of a large level dyeing difference. Conventionally, the main methods for obtaining filament fabrics with dyeability include twisting yarn-dyed filaments, or twisting or mixing fibers with different dyeability into fabrics and dyeing them. It had been taken. All of these methods require the use of two or more types of filaments with different dyeability, so they cannot avoid the drawbacks of each fiber, and
There was a monotony caused by the excessive homogeneity inherent in filaments. In response to this, a filament has been developed that has small-period thickness irregularities and orientation irregularities in the longitudinal direction, as disclosed in Japanese Patent Application Laid-open No. 51-147618. Fabrics made of such filaments had uneven thickness, dyeing, twisting, shrinkage, uneven meandering in the fabric, and had a natural tone similar to that of natural fibers. However, even with such a well-seasoned patterned fabric, there is a monotony in which the entire fabric has a similar tone. As a result of intensive research, the inventors of this invention devised a printing fabric with unique effects. That is, the present invention has the following configuration. In a fabric made of a single type of polyester filament with dyeing differences in the longitudinal direction of the yarn,
The ground part and the printed part form a contrasting pattern with a level dyeing difference of grade 3 or higher, and either the ground part or the printed part is level dyed, and the other is unevenly dyed. A printed fabric characterized by being dyed. The present invention will be explained in detail below. The polyester referred to in the present invention is one containing 80 mol% or more of ethylene terephthalate units. Copolymerization components include dibasic acids such as adipic acid, sebacic acid, isophthalic acid, diphenyldicarboxylic acid, and naphthalene carboxylic acid, oxyacids such as oxybenzoic acid, and diethylene glycol, propylene glycol, neopentyl glycol, and pentaeryth. One or more types of glycols such as sotol and polyethylene glycol monomethyl ether are used. It is an essential condition that the above-mentioned polyester fiber filament made of a single species has easily dyed areas and difficult to dye areas irregularly in the longitudinal direction of the yarn. Methods for producing such yarns include a method in which stretched and unstretched sections are intermittently provided during drawing, and a method in which a hot plate or pin maintained at 200°C or higher is intermittently added during the production of processed yarn. or even come into contact with
It is obtained by adding untwisted parts intermittently to fiber bundles, and the manufacturing method is not particularly limited. with EVENESS TESTER (manufactured by Keikiki Kogyo)
The value obtained by measuring USTER (U)% is from 2% to 30
% range is suitable. That is, U
If the value obtained by measuring the percentage is 30% or more, there are many undrawn yarns, so the difference in shade is significant, level dyeing is difficult, and furthermore, strength is likely to decrease. In order to obtain the dyeability of the level dyed part according to the present invention, the lower the U%, the more advantageous it is, so it is preferably 2 to 20%.
is good. For example, such a yarn has a birefringence of 15 to 80 × 10 -3 in a part with a large cross-sectional area, a birefringence of 90 to 200 × 10 -3 in a part with a small cross-sectional area, and a birefringence in the longitudinal direction of the yarn. Corresponds to yarn with a coefficient of variation CV% of FYL value of 0.80% or less. A method for producing such yarn is disclosed, for example, in Japanese Patent Application Laid-Open No. 147618/1983. As a method of imparting a dyed area with level dyeing properties to a part of a fabric made of such threads, (1) Among disperse dyes, dyes called E type or SE type by dye manufacturers are used. Mainly used. (2) Regardless of the type of disperse dye, methods such as using an auxiliary agent with level dyeing ability can be considered. (1) generally has poor sublimation fastness, and
At present, there are few dyes that have low build-up properties and also satisfy the level dyeing properties referred to in the present invention. Therefore, it is desirable to use the selected leveling agent mentioned in (2). Since quantitative evaluation methods for level dyeing and non-level dyeing have not yet been generally established, the inventors visually evaluated level dyeing using the following method. (1) Dyeing conditions for standard dyes Standard dyes listed in Table 1 0.6% owf Dyeing bath PH 5 Bath ratio 1:40 Heating rate 70℃ to 15℃/min Temperature and time 130℃, 30 minutes Above conditions dye and perform normal reduction washing. (2) Level dyeing evaluation criteria The grade of level dyeing is determined by comparing the degree of irritation and marbling of the dyed fabric mentioned above with the dyed surface of the fabric to be evaluated, which is a fabric dyed with other dyes or a printed fabric.
【表】
本考案の布帛では濃淡を有する不均染部と均染
部の均染差が３級以上であることが必要である。
これ以下の均染差では、両者のコントラストが不
明確となつて、本発明の効果は少ない。
均染能を有する助剤としては、染着濃度が低下
することなく、柄際が鮮明であり、しかも、染色
堅ろう度を低下させないものを使用すべきであ
る。本考案者らは、数多くの均染剤と称する助剤
の中から、還元剤に対し、可抜性分散染料には、
安息香酸エステル系の均染剤が、不可抜性分散染
料には、ポリオキシアルキレンモノアルキルフエ
ニルエーテルやポリオキシアルキレンモノ脂肪酸
エステル系の均染剤が特に効果的であることを見
い出した。前者の市販均染剤としては、I.P.キヤ
リヤーＮ−20（一方社油脂製）、イオネツト．TD
−208（三洋化成製）、ニツカソルトLM−７（日
華化学製）等が、後者には、LEVEGAL HTN
（BAYER製）、PENEZOL 405（古川化学製）等
が挙げられる。しかしながら、この区別は明確な
ものではなく、可抜性染料に均染性能を与える助
剤の中で、不可抜性染料にも効果があるものもあ
り、また、この逆もあてはまる染料もある。均染
剤の使用量としては、多く使用すると不経済であ
り、また、染着濃度の低下や柄際が不鮮明になる
場合もあることなどから、可抜性染料に対しては
色糊重量に対し、２％から15％望ましくは３％か
ら８％であり、不可抜性染料に対しては、１％か
ら10％望ましくは２％から５％である。
このようにして、均染剤を添加した色糊と無添
加の色糊をオーバープリント、抜染、防抜染に適
用できる。均染剤を添加した色糊は、捺染部また
は地型部と呼ばれる比較的面積の大きい部分に印
捺することにより、一つのデザインで、捺染部は
均染、地型部は濃淡差を有する不均染または、柄
部は濃淡差を有する不均染、地型部は均染である
２通りのコントラストを有する捺染物を得ること
が可能である。このようにして、均染部も不均染
部も強調された特徴的な捺染物が得られる。つま
り均染部には、不均染部の存在により、フイラメ
ントライクで上品で、フラツトな感じになり、不
均染部は均染部の存在により、斑が多く、素朴
で、非フイラメント的になり、同質のものが調和
しているのとは異なつた美を感じさせる。
これは、本来、均染差だけしかないはずにもか
かわらず、染着差が糸条の太さ斑、撚斑、織組織
中での蛇行、未解撚などを不均染部では強調し、
均染部では目立たなくしているからである。
本考案の捺染布帛の例を第１図に示す。柄部が
均染、地型部が不均染であり両者のコントラスト
が強調される状態を模式的に示したものである。
本考案は、分散染料で染色可能なポリエステル
系フイラメントから成る織物、編物、不織布カー
ペツトなどの布帛に適用できるものである。
以下、実施例にて本考案を詳細に説明する。
実施例 １
ポリエステルフイラメントの繊維軸方向に断面
積の変化を有し、Ｕ％が10％、糸条の長手方向へ
のFYL値の変動係数CV％が0.62％である糸条か
らなる織物を充分精練し、次いで常法によりヒー
トセツトした。この織物に、水玉柄の捺染物を印
捺するために、水玉柄には、DIANIX RED Ｇ−
SE、地型部には、DIANIX BLUE KB−FS（三
菱化成製、可抜性染料）を使用し、下記、Ａ，Ｂ
処法の印捺糊を調合した。本考案である捺染物を
得るた水玉柄には、Ａ処法、地型にはＢ処法の印
捺糊で、比較例として、水玉柄と地型ともＢ処方
の印捺糊で、それぞれ印捺した。[Table] In the fabric of the present invention, it is necessary that the difference in level dyeing between unevenly dyed areas with shading and level dyed areas is grade 3 or higher.
If the leveling difference is less than this, the contrast between the two becomes unclear and the effect of the present invention is small. As an auxiliary agent having level dyeing ability, one should be used that does not reduce the dye density, provides a clear pattern border, and does not reduce dye fastness. The inventors of the present invention found that among the many auxiliary agents called leveling agents, there are
It has been found that benzoic acid ester-based leveling agents are particularly effective for non-extractable disperse dyes, and polyoxyalkylene monoalkylphenyl ether and polyoxyalkylene monofatty acid ester-based leveling agents are particularly effective. Commercially available leveling agents for the former include IP Carrier N-20 (manufactured by Ippo Sha Yushi), Ionets. T.D.
-208 (manufactured by Sanyo Chemical Co., Ltd.), Nitsuka Salt LM-7 (manufactured by Nicca Chemical Co., Ltd.), etc.;
(manufactured by BAYER), PENEZOL 405 (manufactured by Furukawa Chemical), etc. However, this distinction is not clear-cut; some auxiliaries that give level dyeing performance to removable dyes are also effective on non-removable dyes, and vice versa for some dyes. Regarding the amount of leveling agent used, it is uneconomical to use too much, and it may also reduce the dye density and make the edges of the pattern unclear, so for removable dyes, it is important to For non-removable dyes, it is 1% to 10%, preferably 2% to 5%. In this way, the colored paste added with a leveling agent and the colored paste without an additive can be applied to overprinting, discharge printing, and resist discharge printing. Color paste with a leveling agent added is printed on a relatively large area called the printed area or ground area, so that in one design, the printed area is evenly dyed and the ground area has a difference in shading. It is possible to obtain a printed product with two types of contrast: non-uniform dyeing or non-uniform dyeing with a difference in shading in the pattern area, and level dyeing in the ground area. In this way, a characteristic printed product is obtained in which both the level dyed areas and the uneven dyed areas are emphasized. In other words, the unevenly dyed area has a filament-like, elegant, and flat feel due to the presence of the unevenly dyed area, and the unevenly dyed area has a mottled, rustic, and non-filament-like feel due to the presence of the evenly dyed area. It creates a sense of beauty that is different from the harmony of things of the same quality. This is because even though there should only be a difference in dyeing evenly, the difference in dyeing emphasizes uneven yarn thickness, twist unevenness, meandering in the woven structure, ununtwisting, etc. in unevenly dyed areas. ,
This is because the uniformly dyed areas are less noticeable. An example of the printed fabric of the present invention is shown in FIG. This is a schematic illustration of a state in which the handle is uniformly dyed and the ground part is unevenly dyed, emphasizing the contrast between the two. The present invention can be applied to fabrics such as woven fabrics, knitted fabrics, and non-woven carpets made of polyester filaments that can be dyed with disperse dyes. Hereinafter, the present invention will be explained in detail with reference to Examples. Example 1 A woven fabric consisting of a polyester filament yarn having a cross-sectional area change in the fiber axis direction, a U% of 10%, and a coefficient of variation CV% of FYL value in the longitudinal direction of the yarn of 0.62% was fabricated. It was scoured and then heat set in a conventional manner. In order to print a polka dot pattern on this fabric, DIANIX RED G-
DIANIX BLUE KB-FS (manufactured by Mitsubishi Kasei, removable dye) was used for the SE and ground parts, and the following, A, B
I prepared a stamping paste for the recipe. The polka dot pattern used to obtain the printed material of the present invention was printed using the A process, and the ground pattern was printed using the B process.As a comparative example, both the polka dot pattern and the ground pattern were printed using the B process. I stamped it.
【表】
得られた印捺布は、乾燥後HTスチーマーにて
180℃で８分間処理し、次いで通常の還元洗浄を
行なつた。
これらの捺染物の前述した均染性の評価基準に
よる均染性は、次の通りであり、本考案による捺
染物は水玉部が均質でフイラメントライクであ
り、地型部が斑が強く、粗い印象を受けるもので
あつた。[Table] After drying, the obtained printed fabric was dried using an HT steamer.
It was treated at 180° C. for 8 minutes, followed by regular reduction cleaning. The level dyeing properties of these prints according to the above-mentioned level dyeing property evaluation criteria are as follows: The prints of the present invention have homogeneous dots and a filament-like appearance, and the ground areas are highly mottled and rough. It made an impression on me.
【表】
実施例 ２
実施例１と同じ織物に下記、Ｃ処法、Ｄ処法の
防抜染用印捺糊とＥ処法のオーバー用色糊を調合
した。[Table] Example 2 On the same fabric as in Example 1, the following printing pastes for resist discharge printing using Processes C and D and color paste for overlay using Processing E were mixed.
【表】
本考案の捺染物を得るため、Ｃ処法とＥ処法の
印捺糊で印捺した。
得られた印捺布を、実施例１と同じ条件で、ス
チーミングおよび還元洗浄を行なつた。
これらの捺染物を実施例１と同じ方法で行なつ
た均染性の評価は次の通りであり、本考案による
捺染物は、比較例に比べ水玉柄が浮き出ているよ
うな立体感のあるものであつた。[Table] In order to obtain the printed material of the present invention, printing was carried out using printing pastes of process C and process E. The obtained printed fabric was subjected to steaming and reduction washing under the same conditions as in Example 1. The level dyeing properties of these printed products were evaluated using the same method as in Example 1. It was hot.
【表】
実施例 ３
延伸したポリエステルフイラメントを通常の仮
撚加工機により、次の条件で仮撚した。
仮撚速度 120ｍ／min
加撚数 2000回／ｍ
第１ヒーター温度 180℃
第２ヒーター温度 170℃
オーバーフイート率 10％
このように仮撚して得られた糸を220℃に保た
れたホツトピンに間歇的に接触して得た糸条の織
物のＵ％は20％であつた。この織物を次の条件で
地染した。
KAYALON POLYESTER
LIGHT RED Ｂ−Ｓ ４％o.w.f
（日本化薬製 可抜性分散染料）
フイキサー PH−500 0.5ｇ／１
（三洋化成製、PH調整剤）
温度、時間 110℃、60分
次いで、通常の条件で還元洗浄を行なつた。
この染色布に前記、Ｃ処法、Ｄ処法の印捺糊
に、抜染助剤として、テリールキヤリヤーDPL
（明成化学製）を色糊の重量に対し、５％添加し
て抜染糊とし、水玉柄を使用してそれぞれの色糊
を印捺した。得られた印捺布を実施例１と同じ条
件でスチーミングおよび還元洗浄を行つた。
これらの捺染物を実施例１と同じ方法で、行つ
た均染性の評価は次の通りであり、本考案による
抜染品は比較例に比べ、水玉柄の部分は斑がなく
上品な感じで地型部はこなれた斑があり、天然品
のような自然な調子の強調されたものであつた。[Table] Example 3 The stretched polyester filament was false-twisted using a normal false-twisting machine under the following conditions. False twisting speed: 120m/min Number of twists: 2000 times/m First heater temperature: 180°C Second heater temperature: 170°C Overfeet rate: 10% The yarn obtained by false twisting in this way is placed on a hot pin maintained at 220°C. The U% of the yarn fabric obtained by intermittent contact was 20%. This fabric was ground dyed under the following conditions. KAYALON POLYESTER LIGHT RED B-S 4% owf (Nippon Kayaku, removable disperse dye) Fixer PH-500 0.5g/1 (Sanyo Chemical, PH adjuster) Temperature, time: 110℃, 60 minutes Next, normal Reduction cleaning was performed under the following conditions. This dyed cloth was printed with the above-mentioned printing pastes of C treatment and D treatment, and terry carrier DPL was used as a discharge aid.
(manufactured by Meisei Kagaku) was added in an amount of 5% to the weight of the colored paste to obtain a discharge printing paste, and each colored paste was printed using a polka dot pattern. The obtained printed fabric was subjected to steaming and reduction cleaning under the same conditions as in Example 1. The level dyeing properties of these printed products were evaluated using the same method as in Example 1, and the results are as follows: Compared to the comparative example, the discharge printed products of the present invention had no spots in the polka dot pattern and had an elegant appearance. The topography had familiar mottling, and the natural tone was emphasized, as if it were a natural product.
第１図は、この考案の捺染布帛の１例を示した
ものである。
１は柄を有する均染部、２は不均染部で地型部
に相当する。
FIG. 1 shows an example of the printed fabric of this invention. 1 is an evenly dyed part with a pattern, and 2 is an unevenly dyed part, which corresponds to the ground pattern part.
Claims (1)
エステル系フイラメントからなる布帛において、
地型部と捺染部が３級以上の均染差からなるコン
トラストをもつ模様を形成しており、かつ該地型
部または該捺染部の、いずれか一方が均染であ
り、他方は不均染であることを特徴とする捺染布
帛。 In a fabric made of a single type of polyester filament with dyeing differences in the longitudinal direction of the yarn,
The ground part and the printed part form a contrasting pattern with a level dyeing difference of grade 3 or higher, and either the ground part or the printed part is level dyed, and the other is unevenly dyed. A printed fabric characterized by being dyed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1979151556U JPS6145199Y2 (en) | 1979-11-02 | 1979-11-02 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1979151556U JPS6145199Y2 (en) | 1979-11-02 | 1979-11-02 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5669699U JPS5669699U (en) | 1981-06-09 |
| JPS6145199Y2 true JPS6145199Y2 (en) | 1986-12-19 |
Family
ID=29382523
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1979151556U Expired JPS6145199Y2 (en) | 1979-11-02 | 1979-11-02 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6145199Y2 (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51147618A (en) * | 1975-06-11 | 1976-12-18 | Toray Ind Inc | A process for producing textured polyester yarns having different dyei ng affinities in the longer direction to the yarns |
-
1979
- 1979-11-02 JP JP1979151556U patent/JPS6145199Y2/ja not_active Expired
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51147618A (en) * | 1975-06-11 | 1976-12-18 | Toray Ind Inc | A process for producing textured polyester yarns having different dyei ng affinities in the longer direction to the yarns |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5669699U (en) | 1981-06-09 |
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