JPS6132367Y2 - - Google Patents

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Publication number
JPS6132367Y2
JPS6132367Y2 JP4091480U JP4091480U JPS6132367Y2 JP S6132367 Y2 JPS6132367 Y2 JP S6132367Y2 JP 4091480 U JP4091480 U JP 4091480U JP 4091480 U JP4091480 U JP 4091480U JP S6132367 Y2 JPS6132367 Y2 JP S6132367Y2
Authority
JP
Japan
Prior art keywords
cathode
metal
cathode plate
plate
metal material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP4091480U
Other languages
Japanese (ja)
Other versions
JPS56142461U (en
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Priority to JP4091480U priority Critical patent/JPS6132367Y2/ja
Publication of JPS56142461U publication Critical patent/JPS56142461U/ja
Application granted granted Critical
Publication of JPS6132367Y2 publication Critical patent/JPS6132367Y2/ja
Expired legal-status Critical Current

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  • Investigating And Analyzing Materials By Characteristic Methods (AREA)

Description

【考案の詳細な説明】[Detailed explanation of the idea]

本考案は、金属材料鑑別器に関するものであ
り、さらに詳しくは、非破壊的に金属材料中の複
数合金元素を同時に半定量的検知を可能とすると
ともに、特定金属材料を多量の異種金属材料から
迅速に選別する際などに利用する現場作業に適し
た信頼性の高い簡易分析が可能な金属材料鑑別器
を提供するものである。 従来の金属材料鑑別器は、第1図に示すように
陽極端3を金属被検体1に当接し、陰極端4とな
る導電性材料のピンセツトなどであらかじめ電解
液を含浸させた脱脂綿などの帯水性物質5をはさ
んで金属被検体1に当接し、これらを電源2を介
して電気回路に形成させる。つぎに所定の電流を
該電気回路に通電して帯水性物質5に含浸させた
電解液と、金属被検体1から溶出した金属イオン
との呈色反応により金属材料を鑑別していた。こ
のような金属材料鑑別器では、前記陰極端4が1
個所であるため (1) 金属材料中の合金成分は、1回あたり1成分
だけしか検知できない。 (2) 1個の金属被検体の複数の合金成分の定性ま
たは半定量を同時に検知できない。 (3) 複数個の金属被検体の特定成分の定性または
半定量を同時に検知できない。 などの問題点がある。 本考案は、上記問題点を解消した金属材料鑑別
器である。 以下、本考案の金属材料鑑別器を第2図から第
4図について詳述する。 すなわち、第2図に示すように導電性陰極板6
の上面に、電解液を含浸させた帯水性物質5を挿
入するために、少なくとも2以上の空間部8を有
する絶縁性仕切板7を載せる。これにより絶縁性
仕切板7の前記空間部8は、その一方の開口部が
陰極板6により塞がれることになる。この絶縁性
仕切板7の材質としてはプラスチツク,ガラス,
木材およびゴム等が好ましい。次に第3図に示す
ように、絶縁性仕切板7に画成した複数の空間部
8の夫々に、電解液を含浸させた脱脂綿などの帯
水性物質5を挿入する。この電解液は、金属被検
体1の検知部に溶出する金属イオンと呈色反応す
る試薬を含有するものであつて、これに好適に使
用される試薬の内容については後述する。 このように絶縁性仕切板7の空間部8に帯水性
物質5を挿入した後、この絶縁性仕切板7の前記
陰極板6が位置する側と反対側の面に、前記金属
被検体1を当接配置する。すなわち絶縁性仕切板
7の各空間部8は、その一方の開口部は前記陰極
板6により塞がれ、また他方の開口部は前記金属
被検体1によつて塞がれることになる。但し、開
口部を全面的に塞ぐことは要件ではなく、部分的
にのみ塞ぐようにしてもよい。 その後に直流電源2の陰極側を陰極板6に接続
すると共に、陽極側を金属被検体1に接続するこ
とにより、陰極板6から帯水性物質5を介して金
属被検体1に至る電気回路を形成する。 Ni,Cr,Mo,Cuなどの各金属イオンと呈色反
応する試薬を含有する電解液を含浸させた脱脂綿
などの帯水性物質5が、前記金属被検体1から溶
出した各金属イオンと反応して呈色することによ
り、呈色の有無および強弱により、金属被検体1
の合金成分の定性または半定量が同時に検知でき
る。 上記実施例で述べた金属被検体1の合金元素の
うち、たとえばNi,Cr,Mo,Cuなどを定性また
は半定量する場合に用いる電解液中の好適な試薬
の一例は次表に示した通りである。
The present invention relates to a metal material discriminator, and more specifically, it is capable of semi-quantitatively detecting multiple alloy elements in a metal material simultaneously and non-destructively. The object of the present invention is to provide a metal material discriminator capable of simple analysis with high reliability and suitable for on-site work used for rapid sorting. In the conventional metal material discriminator, as shown in Fig. 1, the anode end 3 is brought into contact with the metal object 1, and the cathode end 4 is a strip of absorbent cotton or the like impregnated with an electrolytic solution using conductive material tweezers or the like. The metal specimen 1 is brought into contact with the aqueous substance 5 sandwiched therebetween, and an electric circuit is formed between them via the power source 2. Next, a predetermined current is passed through the electric circuit to identify the metal material based on the color reaction between the electrolytic solution impregnated into the aqueous substance 5 and the metal ions eluted from the metal specimen 1. In such a metal material discriminator, the cathode end 4 is
(1) Only one alloy component in a metal material can be detected at a time. (2) Qualitative or semi-quantitative detection of multiple alloy components in one metal specimen cannot be detected simultaneously. (3) Qualitative or semi-quantitative detection of specific components of multiple metal samples cannot be detected simultaneously. There are other problems. The present invention is a metal material discriminator that solves the above problems. Hereinafter, the metal material discriminator of the present invention will be described in detail with reference to FIGS. 2 to 4. That is, as shown in FIG.
An insulating partition plate 7 having at least two spaces 8 is placed on the upper surface of the cell in order to insert the aqueous substance 5 impregnated with an electrolytic solution. As a result, one opening of the space 8 of the insulating partition plate 7 is closed by the cathode plate 6. The material of this insulating partition plate 7 is plastic, glass,
Wood, rubber, etc. are preferred. Next, as shown in FIG. 3, a water-absorbing substance 5 such as absorbent cotton impregnated with an electrolytic solution is inserted into each of the plurality of spaces 8 defined in the insulating partition plate 7. This electrolytic solution contains a reagent that undergoes a color reaction with the metal ions eluted into the detection portion of the metal specimen 1, and the contents of the reagent suitably used therein will be described later. After inserting the aqueous substance 5 into the space 8 of the insulating partition plate 7, the metal object 1 is placed on the surface of the insulating partition plate 7 opposite to the side where the cathode plate 6 is located. Place in contact. That is, one opening of each space 8 of the insulating partition plate 7 is closed by the cathode plate 6, and the other opening is closed by the metal object 1. However, it is not a requirement that the opening be completely blocked, but may be only partially blocked. After that, by connecting the cathode side of the DC power supply 2 to the cathode plate 6 and the anode side to the metal object 1, an electric circuit from the cathode plate 6 to the metal object 1 via the aqueous substance 5 is established. Form. A water-absorbing substance 5 such as absorbent cotton impregnated with an electrolytic solution containing a reagent that causes a color reaction with each metal ion such as Ni, Cr, Mo, and Cu reacts with each metal ion eluted from the metal specimen 1. The metal specimen 1 is determined by the presence or absence of coloration and its strength
Qualitative or semi-quantitative detection of alloy components can be detected at the same time. Examples of suitable reagents in the electrolyte used for qualitative or semi-quantitative determination of Ni, Cr, Mo, Cu, etc. among the alloying elements of the metal specimen 1 described in the above example are shown in the following table. It is.

【表】 つぎに、第4図に示すように非電導性陰極板9
を用いる場合には、該陰極板9の内部に導電線1
0を配設することにより、陽極端3と陰極端4と
の両極間に通電することができる。なお上記非電
導性陰極板9の材質としてはプラスチツクガラ
ス,木材およびゴム等が使用可能である。また導
電線10の材質は白金線でも良いが高価であるた
め陰極端4のみ白金とし、他の部分の導電線は、
銅線やアルミ線で接合することが好ましい。 以上のとおり、本考案の金属材料鑑別器は、特
定金属材料を多量の異種金属材料から迅速に選別
できるとともに、鑑別すべき1個の金属被検体の
複数の合金成分の定性または半定量を同時に検知
できる効果がある。さらに複数個の金属被検体の
特定成分の定性または半定量を同時に検知できる
効果がある。
[Table] Next, as shown in FIG.
When using a conductive wire 1 inside the cathode plate 9
By disposing 0, current can be applied between the anode end 3 and the cathode end 4. The non-conductive cathode plate 9 may be made of plastic glass, wood, rubber, or the like. The conductive wire 10 may be made of platinum wire, but it is expensive, so only the cathode end 4 is made of platinum, and the other conductive wires are made of platinum.
It is preferable to join using copper wire or aluminum wire. As described above, the metal material discriminator of the present invention can quickly sort out a specific metal material from a large amount of dissimilar metal materials, and simultaneously perform qualitative or semi-quantitative analysis of multiple alloy components in a single metal specimen to be identified. It has a detectable effect. Furthermore, there is an effect that qualitative or semi-quantitative detection of specific components of a plurality of metal objects can be detected simultaneously.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は、従来の金属材料鑑別器の操作状態を
示す図。第2図は本考案金属材料鑑別器の絶縁性
仕切板と陰極板とを組合わせた斜視図。第3図は
該金属材料鑑別器の使用状態の側面を示す図。第
4図は非導電性材料の内部に導電線を配設した陰
極板を用いた該金属材料鑑別器の使用状態を示す
図。 1:金属被検体、2:電源、3:陽極端、4:
陰極端、5:脱脂綿などの帯水性物質、6:導電
性材料の陰極板、7:絶縁性仕切板、8:仕切板
の空間部、9:非導電性材料の内部に導電線を配
設した陰極板、10:導電線。
FIG. 1 is a diagram showing the operating state of a conventional metal material discriminator. FIG. 2 is a perspective view of a combination of an insulating partition plate and a cathode plate of the metal material discriminator of the present invention. FIG. 3 is a side view showing the state in which the metal material discriminator is used. FIG. 4 is a diagram showing the usage state of the metal material discriminator using a cathode plate in which a conductive wire is arranged inside a non-conductive material. 1: Metal object, 2: Power source, 3: Anode end, 4:
Cathode end, 5: Aqueous substance such as absorbent cotton, 6: Cathode plate made of conductive material, 7: Insulating partition plate, 8: Space of partition plate, 9: Conductive wire arranged inside non-conductive material 10: Conductive wire.

Claims (1)

【実用新案登録請求の範囲】 (1) 陰極板と、 貫通空間部が少なくとも2以上画成され、前
記陰極板に当接配置されて、該陰極板により前
記空間部の一方の開口部が塞がれる絶縁性仕切
板と、 前記空間部に収納された電解液を含浸させた
帯水性物質と、 前記絶縁性仕切板に前記陰極板と反対側にお
いて当接配置されて、該絶縁性仕切板により前
記空間部の他方の開口部が塞がれる金属被検体
と からなり、 前記陰極板と金属被検体とに直流電源を接続
するよう構成したことを特徴とする金属材料鑑
別器。 (2) 陰極板は導電性材料で構成され、この陰極板
に直流電源の陰極側が直接接続される実用新案
登録請求の範囲第1項記載の金属材料鑑別器。 (3) 陰極板は非導電性材料で構成され、該陰極板
により絶縁性仕切板の貫通空間部の一方の開口
部を塞いだ際に、該陰極板の前記開口部に臨む
位置に陰極端が配設されており、この陰極端に
直流電源の陰極側が接続される実用新案登録請
求の範囲第1項記載の金属材料鑑別器。
[Claims for Utility Model Registration] (1) A cathode plate and at least two through spaces are defined, the cathode plate is arranged in contact with the cathode plate, and one opening of the space is closed by the cathode plate. an insulating partition plate that is detachable; an aqueous substance impregnated with an electrolytic solution stored in the space; and an insulating partition plate that is placed in contact with the insulating partition plate on a side opposite to the cathode plate. A metal material discriminator comprising: a metal specimen whose other opening of the space portion is closed by a metal specimen, and a DC power source is connected to the cathode plate and the metal specimen. (2) The metal material discriminator according to claim 1, wherein the cathode plate is made of a conductive material, and the cathode side of a DC power source is directly connected to the cathode plate. (3) The cathode plate is made of a non-conductive material, and when one opening of the through space of the insulating partition plate is closed with the cathode plate, a cathode end is placed at a position facing the opening of the cathode plate. The metal material discriminator according to claim 1, wherein a cathode side of a DC power source is connected to the cathode end of the metal material discriminator.
JP4091480U 1980-03-29 1980-03-29 Expired JPS6132367Y2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP4091480U JPS6132367Y2 (en) 1980-03-29 1980-03-29

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4091480U JPS6132367Y2 (en) 1980-03-29 1980-03-29

Publications (2)

Publication Number Publication Date
JPS56142461U JPS56142461U (en) 1981-10-27
JPS6132367Y2 true JPS6132367Y2 (en) 1986-09-20

Family

ID=29636304

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4091480U Expired JPS6132367Y2 (en) 1980-03-29 1980-03-29

Country Status (1)

Country Link
JP (1) JPS6132367Y2 (en)

Also Published As

Publication number Publication date
JPS56142461U (en) 1981-10-27

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