JPS61271362A - Lustering agent - Google Patents

Lustering agent

Info

Publication number
JPS61271362A
JPS61271362A JP11218085A JP11218085A JPS61271362A JP S61271362 A JPS61271362 A JP S61271362A JP 11218085 A JP11218085 A JP 11218085A JP 11218085 A JP11218085 A JP 11218085A JP S61271362 A JPS61271362 A JP S61271362A
Authority
JP
Japan
Prior art keywords
weight
styrene
polishing agent
alkali
plasticizer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11218085A
Other languages
Japanese (ja)
Inventor
Mikio Kawashima
川島 幹夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Elevator Engineering and Service Co Ltd
Original Assignee
Hitachi Elevator Engineering and Service Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Elevator Engineering and Service Co Ltd filed Critical Hitachi Elevator Engineering and Service Co Ltd
Priority to JP11218085A priority Critical patent/JPS61271362A/en
Publication of JPS61271362A publication Critical patent/JPS61271362A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To provide a lustering agent which prevents rubber surface from being cracked and can keep luster over a long period of time, consisting of an acrylic/styrene copolymer, PE wax, an alkali-soluble resin, a plasticizer and a film-forming aid. CONSTITUTION:8-20wt% acrylic/styrene copolymer, 3-8wt% high-melting PE wax, 1-4wt% alkali-soluble styrene/maleic acid copolymer resin, 0.5-2wt% phthalate plasticizer, 2-6wt% glycol ether film-forming aid and optionally, surfactant (e.g. sulfonic acid fluoride), anti-foaming agent, etc. are blended together.

Description

【発明の詳細な説明】 〔発明の利用分野〕 本発明は艶出し剤に係り、特にゴム等の表面に光沢を与
える艶出し剤に関する。
DETAILED DESCRIPTION OF THE INVENTION [Field of Application of the Invention] The present invention relates to a polishing agent, and particularly to a polishing agent that imparts gloss to the surface of rubber or the like.

〔発明の背景〕[Background of the invention]

ゴムは加工の容易さや弾力性に富むなどの長所を持って
いることがら様々な分野で利用されている。しかしなが
ら、ゴムは硬度が低いために1表面に傷がつきやすく、
またその表面の光沢が失われ易い。そのため室内装飾品
のように外観が重要な場合、光沢を保持させる艶出し剤
が一般に用いられる。
Rubber is used in various fields because it has advantages such as ease of processing and high elasticity. However, because rubber has low hardness, it is easily scratched on one surface.
Moreover, the gloss of its surface is likely to be lost. Therefore, in cases where appearance is important, such as in interior decoration products, polishing agents that maintain gloss are generally used.

従来の艶出し剤としては、ノルマルパラフィンやカルナ
バろうな用いた通常のワックス類や、シリコーンオイル
を水とエマルジョンにしたものが用いられている。また
特殊な艶出し剤としては。
Conventional polishing agents include ordinary waxes such as normal paraffin and carnauba wax, and emulsions of silicone oil and water. Also as a special polishing agent.

特開昭55−7862号公報に示されたシリコーン油と
鉱油を主成分としたもの、特開昭55−58274号公
報に示されたモノオレフィンと無水マレイン酸トの共重
合ワックス、特開昭56−62861号公報に示された
アミン変性シリコーンオイルおよびジメチルシリコーン
を主成分としたワックス等が提案されている。
A copolymer wax of monoolefin and maleic anhydride as shown in JP-A-55-58274, which is mainly composed of silicone oil and mineral oil, as shown in JP-A-55-7862; Amine-modified silicone oil and a wax containing dimethyl silicone as a main component, as shown in Japanese Patent No. 56-62861, have been proposed.

しかしながら上述の艶出し剤は1手が触れるような場所
1例えばマイコンベア用ノ・ンドレールに用いた場合、
簡単に艶出し剤が手に転移してしまうため、比較的短時
間で光沢が失われてしまう。
However, when the above-mentioned polishing agent is used in a place that can be touched by one hand, for example, on a microconveyor rail,
Because the polish easily transfers to your hands, the shine will be lost in a relatively short period of time.

一般に、マイコンベア用ハンドレール+i 化粧−fム
でつくられており、ノ1ンドレールの表面には通常シリ
コーンオイルのエマルジョンを塗布して艶を出す方法が
とられている。しかし、ノ1ンドレールには多くの利用
者の手が触れるため、極めて短い時間でその光沢が失わ
れてしまう。このため。
Generally, handrails for microconveyors are made of handrails, and the surface of the handrails is usually coated with a silicone oil emulsion to give it a glossy finish. However, because the rail is touched by many users, it loses its luster in an extremely short amount of time. For this reason.

ハンドレールの表面にウレタン樹脂を塗布して硬化させ
る方法も行なわれている。しかしマンコンベアにおける
一般的なハンドレールは1図面に示すように無端状のハ
ンドレール1として接続形成され、駆動プーリー2によ
って駆動される。このときハンドレール1は、ローラー
3に圧接され。
Another method is to apply urethane resin to the surface of the handrail and harden it. However, a typical handrail on a passenger conveyor is connected as an endless handrail 1, as shown in FIG. 1, and is driven by a drive pulley 2. At this time, the handrail 1 is pressed against the roller 3.

しかも屈曲した状態で駆動されるため表面の樹脂層に亀
裂が生じ易かった。
Moreover, since it was driven in a bent state, cracks were likely to occur in the resin layer on the surface.

〔発明の目的〕[Purpose of the invention]

本発明の目的は1人間の手に触れ易(、シかも屈曲し易
い状態で使用されるゴムに対しても、その表面の亀裂を
防止して艶を長時間維持することができる艶出し剤を提
供するKある。
The purpose of the present invention is to provide a polishing agent that can prevent cracks on the surface of rubber and maintain its luster for a long time even when the rubber is used in a state where it is easily touched by human hands (and easily bent). There is a K that provides.

〔発明の概要〕[Summary of the invention]

本発明は、先ず作業時間を考慮して皮膜形成型とし、各
種のポリマー、ワックス、樹脂、可塑剤。
The present invention first takes into consideration the working time and uses various polymers, waxes, resins, and plasticizers to form a film.

皮膜形成助剤について、ハンドレールに悪影響を与えな
いこと、ゴムに対して密着性が良いこと。
The film forming aid should not have any negative effect on the handrail and should have good adhesion to rubber.

屈曲に対して亀裂が生じないこと等について検討した結
果、ポリマーとしてはアクリルスチレンコポリマー、ワ
ックスとしては高融点のポリエチレンワックス、樹脂と
してはアルカリ可溶性のスチレンマレイン駿共重金物、
可塑剤としてはフタル酸エステル系、皮膜形成助剤とし
てはグリコールエーテル系を主成分とし、水を溶媒とし
て上記目的を達成したことを特徴とする。
As a result of examining whether cracks would not occur when bent, etc., the polymer was an acrylic styrene copolymer, the wax was a polyethylene wax with a high melting point, and the resin was an alkali-soluble styrene-maleic heavy metal material.
The above object is achieved by using a phthalate ester as a plasticizer, a glycol ether as a film forming aid, and using water as a solvent.

〔発明の実施例〕[Embodiments of the invention]

以下本発明の一実施例を説明する。 An embodiment of the present invention will be described below.

上述したよ5に本艶出し剤は皮膜形成型であり。As mentioned above, this polishing agent is a film-forming type.

次のようにして得る。You can get it like this:

アクリルスチレンコポリマー ・・・・・・・・・・・
・13重量%高融点ポリエチレンワックス ・・・・・
・・・・・・・5重量%スチレン、レイン酸共重合樹脂
 ・N1・・2重量%7タル酸エステル系可塑剤 ・・
・・・・・・・・・・・・・1重量%グリコールエーテ
ル系皮膜形成助剤 ・・・4重量%スルホン酸フルオラ
イド系界面活性剤・・・0.5重量%および若干の消泡
剤を加え、水を溶媒としてこれら全体で100重量%と
なるよ5KL、全体を良(攪拌して乳白色の均一な溶液
である艶出し剤を得た。
Acrylic styrene copolymer ・・・・・・・・・・・・
・13% by weight high melting point polyethylene wax ・・・・・
...5% by weight styrene, leic acid copolymer resin ・N1...2% by weight 7-talate ester plasticizer...
・・・・・・・・・・・・1% by weight glycol ether film forming aid 4% by weight sulfonic acid fluoride surfactant 0.5% by weight and some antifoaming agent 5KL was added using water as a solvent so that the total amount was 100% by weight, and the whole was stirred to obtain a polishing agent which was a milky white uniform solution.

14年以上稼動してい℃光沢度が1〜3度までに艶ヲ失
ったマンコンベア用ハンドレールノ赤色。
A red hand rail for a passenger conveyor that has been in operation for over 14 years and has lost its luster by 1 to 3 degrees Celsius.

青色、黒色の3種類を用いて1本艶出し剤の効果を確認
した。先ず、上述のハンドレールを20%エタノール溶
液で拭きとって汚れを落し、十分に乾燥させた後1本艶
出し剤をネル製の布に含ませて良く絞り、素晴くハンド
レールの表面へ塗布した。
The effectiveness of one polishing agent was confirmed using three types, blue and black. First, wipe the above-mentioned handrail with a 20% ethanol solution to remove dirt, and after drying thoroughly, soak a flannel cloth with a polishing agent, wring it out well, and apply it to the surface of the handrail. Coated.

この1回の塗布では完全には艶が回復しないので。This one application will not completely restore the luster.

塗布後3分した乾燥後、再び同じ要領で塗布作業を繰返
したところ、はぼ均一に艶が回復した。従来のシリコー
ンオイルのエマルジョンの場合と。
After drying for 3 minutes after application, the application process was repeated in the same manner, and the gloss was almost uniformly restored. In the case of conventional silicone oil emulsion.

本艶出し剤による艶の回復状況を下表に示した。The table below shows the restoration of gloss with this polishing agent.

この表かられかるように1本艶出し剤は従来品に比べて
艶を長時間持続することができ、また亀裂の発生も見ら
れなかった。しかも本艶出し剤は塗布後の乾燥が早(短
時間で作業を終了することができる。
As can be seen from this table, the single polishing agent was able to maintain gloss for a longer time than conventional products, and no cracks were observed. Moreover, this polish dries quickly after application (you can finish the job in a short time).

また本艶出し剤の各成分の比率を変化させて実験したと
ころ、アクリルスチレンコポリマーが8〜20重量%、
ポリエチレンワックスが3〜8重量%、スチレンマレイ
ン酸共重合物系アルカリ可溶性樹脂が1〜4重量%、フ
タル酸エステル系可塑剤が0.5〜2重量%、グリコー
ルエーテル系皮膜形成助剤が2〜6重量%の範囲で用い
るのが良いことがわかった。
In addition, when we experimented with changing the ratio of each component of this polish, we found that the acrylic styrene copolymer was 8 to 20% by weight,
3-8% by weight of polyethylene wax, 1-4% by weight of styrene-maleic acid copolymer-based alkali-soluble resin, 0.5-2% by weight of phthalate-based plasticizer, and 2% by weight of glycol ether-based film-forming aid. It has been found that it is best to use it in a range of 6% by weight.

〔発明の効果〕〔Effect of the invention〕

以上説明したように本発明は、アクリルスチレンコホリ
マー、ポリエチレンワックス、スチレンマレイン酸共重
合物系アルカリ可溶性樹脂、フタル酸エステル系可塑剤
、グリコールエーテル系皮膜形成助剤を主成分とする艶
出し剤としたため。
As explained above, the present invention provides a polishing agent whose main components are an acrylic styrene copolymer, a polyethylene wax, an alkali-soluble styrene-maleic acid copolymer resin, a phthalate ester plasticizer, and a glycol ether film-forming aid. Because of that.

ゴムの表面の艶を長時間維持すると共に、マンコンベア
用ハンドレールのように屈曲して使用しても表面に亀裂
を生ずることがない。
The gloss of the rubber surface is maintained for a long time, and the surface does not crack even when used in a bent position like a handrail for a passenger conveyor.

【図面の簡単な説明】[Brief explanation of the drawing]

図面は本発明艶出し剤を適用するマンコンベア用ハンド
レールの側面図である。
The drawing is a side view of a handrail for a passenger conveyor to which the polishing agent of the present invention is applied.

Claims (1)

【特許請求の範囲】 1、アクリルスチレンコポリマー、ポリエチレンワック
ス、スチレンマレイン酸共重合物系アルカリ可溶性樹脂
、フタル酸エステル系可塑剤、グルコールエーテル系皮
膜助剤を主成分として含むことを特徴とする艶出し剤。 2、上記特許請求の範囲第1項記載のものにおいて、上
記アクリルスチレンコポリマーを8〜20重量%、上記
ポリエチレンワックスを3〜8重量%、上記スチレンマ
レイン酸共重合物系アルカリ可溶性樹脂を1〜4重量%
、上記フタル酸エステル系可塑剤を0.5〜2重量%、
上記グリコールエーテル系皮膜助剤を2〜6重量%とし
たことを特徴とする艶出し剤。
[Claims] 1. Main ingredients include acrylic styrene copolymer, polyethylene wax, styrene-maleic acid copolymer-based alkali-soluble resin, phthalate-based plasticizer, and glycol ether-based film auxiliary agent. Polishing agent. 2. In the product according to claim 1, the acrylic styrene copolymer is contained in an amount of 8 to 20% by weight, the polyethylene wax is contained in an amount of 3 to 8% by weight, and the styrene-maleic acid copolymer-based alkali-soluble resin is contained in an amount of 1 to 20% by weight. 4% by weight
, 0.5 to 2% by weight of the above phthalate plasticizer,
A polishing agent characterized by containing 2 to 6% by weight of the glycol ether film auxiliary agent.
JP11218085A 1985-05-27 1985-05-27 Lustering agent Pending JPS61271362A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11218085A JPS61271362A (en) 1985-05-27 1985-05-27 Lustering agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11218085A JPS61271362A (en) 1985-05-27 1985-05-27 Lustering agent

Publications (1)

Publication Number Publication Date
JPS61271362A true JPS61271362A (en) 1986-12-01

Family

ID=14580252

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11218085A Pending JPS61271362A (en) 1985-05-27 1985-05-27 Lustering agent

Country Status (1)

Country Link
JP (1) JPS61271362A (en)

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