JPS61261005A - Mixing device for two liquids reactive raw material - Google Patents

Mixing device for two liquids reactive raw material

Info

Publication number
JPS61261005A
JPS61261005A JP10301985A JP10301985A JPS61261005A JP S61261005 A JPS61261005 A JP S61261005A JP 10301985 A JP10301985 A JP 10301985A JP 10301985 A JP10301985 A JP 10301985A JP S61261005 A JPS61261005 A JP S61261005A
Authority
JP
Japan
Prior art keywords
liquid
groove
raw material
outer cylinder
grooves
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP10301985A
Other languages
Japanese (ja)
Other versions
JPH06332B2 (en
Inventor
Takao Inoue
孝夫 井上
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Holdings Corp
Original Assignee
Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Industrial Co Ltd filed Critical Matsushita Electric Industrial Co Ltd
Priority to JP10301985A priority Critical patent/JPH06332B2/en
Publication of JPS61261005A publication Critical patent/JPS61261005A/en
Publication of JPH06332B2 publication Critical patent/JPH06332B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/30Mixing; Kneading continuous, with mechanical mixing or kneading devices
    • B29B7/34Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
    • B29B7/38Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
    • B29B7/40Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with single shaft
    • B29B7/42Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with single shaft with screw or helix
    • B29B7/421Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with single shaft with screw or helix with screw and additionally other mixing elements on the same shaft, e.g. paddles, discs, bearings, rotor blades of the Banbury type

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)

Abstract

PURPOSE:To obtain the small quantity of uniformly mixed reactive mixture with less tendency of bubble inclusion by providing one emitting mouth at the position where one liquid may be emitted to a first groove from the outer cylinder of a rotary axis with two or more grooves, and the other emitting mouth connected to the position where the residual liquid may be emitted to the other line groove, without contacting with the liquid in the first line groove. CONSTITUTION:The device is composed large of the rotary axis 1 with two grooves 3, 4 and the outer cylinder 2 closely engaged therewith. The emitting mouth 7 through which a reactive raw material A flows in, and another emitting mouth 8 through which a reactive raw material B flows in, are respectively connected to the groove 4 by connecting grooves 11 and 10 upon their injection mixing. The rotary axis is cut such that its outer diameter becomes small at its tip 5, thereby forming the gap 6 providing a mixing part between the outer cylinder and the rotary axis. The liquids A and B are sent under pressure and then mixed and agitated in the gap of its tip, while giving shear action to the liquid in between the rotary axis and the outer cylinder. Because said liquid is continuously injected, the injection of high accuracy may be achieved with less tendency of bubble inclusion.

Description

【発明の詳細な説明】 産業上の利用分野 本発明は、反応性射出成形機、注型機、2液液着剤など
に使用する2液反応原料の混合装置に関する。
DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a mixing device for two-liquid reaction raw materials used in reactive injection molding machines, casting machines, two-liquid adhesives, and the like.

従来の技術 本発明は、従来の真空注型やボッティング等に用いられ
る装置がスタティックミキサーや強制撹拌によるパワー
ミキシングなどの混合方法及び装置を用いているが、溶
剤等洗浄液による洗浄が必須であるため、材料ロスが多
い成形材料に溶剤が混入することがフシ成形品物性にバ
ラ付きが生じる洗浄工程があるため生産性が上がらない
などの問題があった。又、ウレタン、ナイロンなどの反
応性射出成形分野では、各種の衝突混合方法及び装置を
用いているが、衝突部が存在するため気泡を巻き込み易
かったり、高圧が必要であるため、油圧機構が必要など
大型装置としては適しているが、小型のしかもある程度
多容量の生産装置としては、不充分であった。
BACKGROUND OF THE INVENTION In the present invention, conventional equipment used for vacuum casting, botting, etc. uses a mixing method and equipment such as a static mixer or power mixing using forced stirring, but cleaning with a cleaning liquid such as a solvent is essential. Therefore, there were problems such as a cleaning process that caused a lot of material loss and mixing of the solvent into the molding material, which caused variations in the physical properties of the molded product, which prevented productivity from increasing. In addition, in the field of reactive injection molding of urethane, nylon, etc., various collision mixing methods and devices are used, but since there is a collision part, air bubbles are easily drawn in, and high pressure is required, so a hydraulic mechanism is required. Although it is suitable for large-scale equipment such as, it is insufficient as a small-sized production equipment with a relatively large capacity.

発明が解決しようとする問題点 本発明が解決しようとする問題点は、洗浄液の不要な混
合方法とその装置であり、気泡が入り難く、微量の均一
混合した反応混合物を得ることができる混合方法とその
装置である。又、エポキシ2液瞬間接着剤の様な材料に
対して最適なディスペンサーとしても利用できる2液反
応原料の混合方法及びそれを用いた装置。
Problems to be Solved by the Invention The problems to be solved by the present invention are a mixing method that does not require a cleaning liquid and an apparatus therefor, a mixing method that does not easily contain air bubbles, and can obtain a minute amount of a uniformly mixed reaction mixture. and its equipment. In addition, the method for mixing two-component reaction raw materials and the apparatus using the same can also be used as an optimal dispenser for materials such as two-component epoxy instant adhesives.

問題点を解決するための手段 2液反応原料の混合方法において、2条以上の溝を有す
る回転軸の外筒から一方の液を1条目の溝に吐出できる
位置に吐出口を設け、残りの液を他の条の溝に吐出でき
る位置に1条目の液に接することなく導通する吐出口を
設は各々の液原料は、回転軸の回転と共に送液され、先
端部において溝は無くなり、外筒と回転軸の狭い空隙間
の撹拌混合される2液反応原料の混合方法であシ、こう
する事により、2液は少量回転面で混合し薄膜部で硬化
するに過ぎず、溝形状をドリル刃の形状に類似させるこ
とにより、硬化物は、削り取られながら連続的に吐出出
来るという特徴を有している。
Means to Solve the Problem In a method for mixing two-component reaction materials, a discharge port is provided at a position where one of the liquids can be discharged from the outer cylinder of the rotating shaft having two or more grooves into the first groove, and the remaining A discharge port is provided at a position where the liquid can be discharged into the grooves of the other grooves so that it conducts without coming into contact with the liquid in the first line.Each liquid raw material is fed with the rotation of the rotating shaft, and the groove disappears at the tip and the outlet is connected to the outside. This is a mixing method of two-component reaction materials that are stirred and mixed in a narrow gap between the cylinder and the rotating shaft.By doing this, a small amount of the two components are mixed on the rotating surface and only harden in the thin film part, making it possible to form the groove shape. By making the shape similar to a drill blade, the cured product has the characteristic that it can be continuously discharged while being scraped off.

尚、2条溝は3条のものでもよく、中間に未使用溝を設
けることによって、硬化物を形成させ、さらに2液が混
合し難くすることもできる0又、この混合方法を用い走
混合装置としては、2液反応原料のタンクとそれを圧送
する機構と2条の溝に連結する回転軸上の溝経路を有し
、2条の溝を有する回転軸とそれを回転させるモータと
を有し、回転軸は先端吐出部の領域では、外筒との間に
ある垂直断面において水平の連続した空隙を少くとも1
ケ所以上有する構造であることを特徴とする2液反応原
料の混合装置であシ、こうすることにより、内筒と外筒
との間の剪断速度の違いにより2液は混合される。さら
に好しくけ、2条以上の溝を有する回転軸が軸方向に動
作する機構を有するものである。
The two grooves may be replaced with three grooves, and by providing an unused groove in the middle, it is possible to form a cured product and make it difficult for the two liquids to mix. The device has a tank for a two-liquid reaction raw material, a mechanism for pumping it, a groove path on a rotating shaft connected to two grooves, and a rotating shaft with two grooves and a motor for rotating it. The rotating shaft has at least one continuous horizontal gap in the vertical section between it and the outer cylinder in the region of the distal end discharge part.
This is a two-liquid reaction raw material mixing device characterized by having a structure having at least two parts, whereby the two liquids are mixed due to the difference in shear rate between the inner cylinder and the outer cylinder. More preferably, the rotary shaft has a mechanism in which a rotating shaft having two or more grooves moves in the axial direction.

作  用 以上の構成によシ、反応性射出成形や注型においては、
型ノズルタッチ構造を工夫することにより洗浄レスの連
続生産が可能となる。又、反応原料圧送する機構として
は、ピストンシリンダー。
However, in reactive injection molding and casting,
By devising the mold nozzle touch structure, continuous production without cleaning is possible. Also, the mechanism for pressure-feeding the reaction materials is a piston-cylinder.

ランスシリンダー、ベローズポンプ、ギヤポンプから選
ばれる一種又は複数の組合せによる機構であることが好
しく、さらに詳しくは、回転軸を軸方向に動作する方法
が、エア圧又はオイル圧による作動シリンダ一方式であ
ることが好ましい。尚、これらの混合装置は、用途によ
って、装置の一部又は各タンク径路毎に又は全体を加熱
又は、混合部の冷却などの温度制御が施こされることが
好ましい。以下、実施例をもとにさらに詳しく説明する
Preferably, the mechanism is one selected from a lance cylinder, a bellows pump, and a gear pump, or a combination of these. It is preferable that there be. In addition, it is preferable that these mixing apparatuses are subjected to temperature control such as heating a part of the apparatus, each tank path, or the whole apparatus, or cooling the mixing part, depending on the application. A more detailed explanation will be given below based on examples.

実施例 第1図は、本発明の混合方法を示す混合ノズルの実施例
である。2条の溝3.4を有する回転軸1とそれと密接
する外筒2とで大きく構成され、反応原料の一方(以下
A液と略称)が流入する吐出ロアともう一方の反応原料
(以下B液と略称)が流入する吐出口8とは、射出混合
時においては、それぞれ連結溝11と連結溝1oとで各
々条溝4とで連結される。又回転軸は、先端部6で、外
径が小さくなる様に切削されており、外筒との間に混合
部となる間隙6が形成されており、A液、B液は混合部
まで圧送され、回転軸と外筒との間で剪断が加えられ先
端部間隙で混合撹拌される。又、A液、B液吐出口部の
中間にバッキング14とB液吐出口部の上部にバッキン
グ13が形成されている。又、B液の径路はA液と接し
ないように回転軸内部に案内溝12を形成している。尚
、2条溝の形状は、ドリル刃形を模倣した方が良く、所
定の方形16にした。この様にすることにより、2液反
応原料は、溝で硬化することなく混合が可能となった。
Embodiment FIG. 1 is an embodiment of a mixing nozzle showing the mixing method of the present invention. It is largely composed of a rotating shaft 1 having two grooves 3.4 and an outer cylinder 2 in close contact with the rotary shaft 1, and has a discharge lower into which one of the reaction raw materials (hereinafter referred to as liquid A) flows and the other reaction raw material (hereinafter referred to as liquid B). The discharge port 8 into which liquid (abbreviated as "liquid") flows is connected to the groove 4 by a connecting groove 11 and a connecting groove 1o, respectively, during injection mixing. In addition, the rotating shaft is cut to have a smaller outer diameter at the tip 6, and a gap 6 is formed between it and the outer cylinder to serve as a mixing section, and liquids A and B are pumped to the mixing section. Then, shear is applied between the rotating shaft and the outer cylinder, and the mixture is mixed and stirred in the gap at the tip. Further, a backing 14 is formed between the A liquid and B liquid discharge ports, and a backing 13 is formed above the B liquid discharge port. Further, a guide groove 12 is formed inside the rotating shaft so that the path of the B liquid does not come into contact with the A liquid. The shape of the double groove should preferably imitate the shape of a drill bit, so it was made into a predetermined rectangular shape 16. By doing so, the two-liquid reaction raw materials could be mixed without being hardened in the groove.

尚、回転軸は先端9で回転モータに接続されている。Note that the rotating shaft is connected to a rotating motor at its tip 9.

第2図は、回転軸の簡易的な作製方法を示した手順図で
ある。所定の吐出液量範囲を考慮した上で、適当な切削
用ドリル16を選び、これで外筒となるべき外筒の内壁
を加工する。その後、ドリルの上部17を加工しbに示
した形状18とすもその後、0図に示した様なあらかじ
め加工しておいた、中央に溝26を有する半円柱を、b
図の加工部に接合する。その時、上、下に空隙20.2
1が同等に確保する。その後半円柱25を外周が均一に
なる様に加工し均一円周の形状19とする。
FIG. 2 is a procedure diagram showing a simple method for manufacturing a rotating shaft. After considering a predetermined discharge liquid volume range, an appropriate cutting drill 16 is selected and used to machine the inner wall of the outer cylinder that is to become the outer cylinder. After that, the upper part 17 of the drill is machined to form the shape 18 shown in b.Then, a semi-cylindrical cylinder having a groove 26 in the center, which has been machined in advance, as shown in Fig.
Join to the processed part shown in the figure. At that time, there is a gap 20.2 at the top and bottom.
1 will be equally secured. The second half of the cylinder 25 is processed to have a uniform outer circumference to form a shape 19 having a uniform circumference.

その後、各吐出口と連結する連結溝23.24を切削し
図eに示した回転軸22を得ることができる。尚、反応
原料の粘度が低い場合には、図−1に示したバッキング
溝も加工することが好ましい。
Thereafter, connecting grooves 23 and 24 connected to each discharge port are cut to obtain the rotating shaft 22 shown in Figure e. In addition, when the viscosity of the reaction raw material is low, it is preferable to also process the backing groove shown in FIG. 1.

第3図には、速硬化タイプ2液エポキシのディスペンサ
の実施例を正面図aと平面図すで示した。
FIG. 3 shows a front view a and a plan view of an embodiment of a fast-curing two-component epoxy dispenser.

第1図、第2図で示した本発明の混合部26は、A液用
のギヤポンプ(ゼニス社製)30と直流可変モータ31
とB液用のギヤポンプ29と直流可変モータ34の吐出
口と連結されている。又混合部は、o℃〜5°CK″±
1°Cで冷却温度制御部で冷却できる。サーキュレータ
と連結されている。さらに、回転軸は上部でエアー28
が作動式のシリンダー32と連結されその上に、直流モ
ータ33と連結されている。又、A液タンク、B液タン
クには一定圧力が加えられており、ギヤポンプ吸引口3
5.36と連結されている。こうすることによって、速
硬化2液型エポキシ(ラピッド、アラルダイト社製)が
8時間連続的に安定して使用でき使用後混合部のみをふ
き取る事によって、連続した使用が可能となった。
The mixing section 26 of the present invention shown in FIG. 1 and FIG.
and a gear pump 29 for liquid B and a discharge port of a variable DC motor 34. In addition, the mixing part is o℃~5°CK''±
It can be cooled at 1°C using the cooling temperature control unit. Connected to a circulator. Furthermore, the rotation axis is air 28 at the top.
is connected to an actuated cylinder 32 and connected thereto to a DC motor 33. Also, a constant pressure is applied to the A liquid tank and B liquid tank, and the gear pump suction port 3
It is connected to 5.36. By doing this, the fast-curing two-component epoxy (Rapid, manufactured by Araldite) could be stably used continuously for 8 hours, and by wiping off only the mixing part after use, continuous use became possible.

第4図には、本発明の混合方法を、反応性射出成形機に
適用した例を示した。A液タンク37゜B液タンク38
は圧送ポンプ、今回はランスシリンダーポンプ39.4
0を用いて、射出以外の時には、3方弁50,51を閉
じて配管43,45゜転させ弁50.51を開いて、混
合射出する。この方法を用いることにより、クロスリン
クドポリエステルアミドTK−222(式日薬品製)を
安定した少量部品の生産に使用することができた。
FIG. 4 shows an example in which the mixing method of the present invention is applied to a reactive injection molding machine. A liquid tank 37° B liquid tank 38
is a pressure pump, this time it is a lance cylinder pump 39.4
0, and at times other than injection, the three-way valves 50 and 51 are closed, the pipes 43 and 45 degrees are turned, and the valves 50 and 51 are opened to perform mixing and injection. By using this method, cross-linked polyester amide TK-222 (manufactured by Shikinichi Yakuhin) could be used for stable production of small-volume parts.

尚この場合、全径路を130°C〜150’Cに温度制
御49した。
In this case, the temperature of all paths was controlled 49 at 130°C to 150'C.

発明の効果 以上、本発明によって、歩容量の反応性射出成形及び接
着ディスペンサーなどに適した混合方法及びその装置が
提供できた。これによって、洗浄液が不要となシ安定し
た物性の成形品又は接着ができるようになった。又、連
続して射出されるため気泡が入シ難く精度の高い射出が
可能となった。
Effects of the Invention As described above, the present invention provides a mixing method and apparatus suitable for reactive injection molding of a walking capacity, an adhesive dispenser, and the like. This has made it possible to create molded products or adhesives with stable physical properties without the need for cleaning fluids. In addition, since the injection is performed continuously, it is difficult for air bubbles to enter, making it possible to perform highly accurate injection.

又、特殊な高圧、油圧等も不要な小型の混合装置を提供
出来たという点で、工業的価値は高い。
Furthermore, the present invention has high industrial value in that it was able to provide a compact mixing device that does not require special high pressure or hydraulic pressure.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明の一実施例の混合装置を示す混合ノズル
の断面図、第2図は同混合装置の回転軸の作製方法の各
手順を示す説明図、第3図aは速硬化2液エポキシ用デ
イスペン仇の正面図、第3図すは同平面図、第4図は反
応性射出成形機に本発明を適用した場合のプロセス図で
ある。 1・・・・・・回転軸、2・・・・・・外筒、3,4・
・・・・・2条の溝、7,8・・・・・・吐出口、6・
・・・・・間隙、26・・・・・・混合部、27・・・
・・・温度制御部、29,30・・・・・・ギヤポンプ
、32・・・・・・シリンダー、41・・・中温合部、
37.38・旧・・原料タンク、39,4o川川ランス
シリンダー、43.44,47.48・・・用循環パイ
プ。 代理人の氏名 弁理士 中 尾 敏 男 ほか1名第 
1 図 /−@転拘 2−−り[肖 7、δ−D上田) 第2図 ”      b     <、ch     (e)
0、)                   33 
           32−−シリンター第 4 図 :J7.3B−−−、/:テ、キ牛グンググq、40−
−−公又ンクンダー      ゛4f−−多星11令
Fig. 1 is a sectional view of a mixing nozzle showing a mixing device according to an embodiment of the present invention, Fig. 2 is an explanatory diagram showing each step of the method for manufacturing a rotating shaft of the same mixing device, and Fig. 3a is a quick curing 2 A front view of the liquid epoxy dispenser, FIG. 3 is a plan view thereof, and FIG. 4 is a process diagram when the present invention is applied to a reactive injection molding machine. 1...Rotating shaft, 2...Outer cylinder, 3, 4...
...2 grooves, 7, 8...discharge port, 6.
...Gap, 26...Mixing section, 27...
... Temperature control section, 29, 30 ... Gear pump, 32 ... Cylinder, 41 ... Medium temperature mixing section,
37.38 Old... Raw material tank, 39, 4o Kawakawa Lance cylinder, 43.44, 47.48... Circulation pipe. Name of agent: Patent attorney Toshio Nakao and 1 other person
1 Figure/-@Tenkin 2--ri [Portrait 7, δ-D Ueda] Figure 2" b <, ch (e)
0,) 33
32--Cylinder No. 4: J7.3B---, /: Te, Kigyu Gunguguq, 40-
--Komata Nkunda ゛4f--Massei 11th Reiya

Claims (4)

【特許請求の範囲】[Claims] (1)2液反応原料の混合装置において、2条以上の溝
を有する回転軸の外筒から一方の液を1条目の溝に吐出
できる位置に吐出口を設け、残りの液を2条目の溝に吐
出できる位置に1条目の液に接することなく導通する吐
出口を設け、各々の液原料は、回転軸の回転と共に送液
され、先端部において溝は無くなり、外筒と回転軸の狭
い空隙間の剪断により撹拌混合される2液反応原料の混
合装置。
(1) In a two-component reaction raw material mixing device, a discharge port is provided at a position where one of the liquids can be discharged from the outer cylinder of the rotating shaft having two or more grooves into the first groove, and the remaining liquid is transferred to the second groove. A discharge port that conducts without contacting the first liquid is provided at a position where it can be discharged into the groove, and each liquid raw material is fed as the rotating shaft rotates.The groove disappears at the tip, and the narrow line between the outer cylinder and the rotating shaft A mixing device for two-liquid reaction raw materials that are agitated and mixed by shearing the air gap.
(2)2液反応原料のタンクとそれを圧送する機構と2
条の溝に連結する経路と、2条の溝を有する回転軸と、
この回転軸を回転させるモータとを有し、回転軸は先端
吐出部の領域では、外筒との間にある垂直断面において
連続した空隙を少くとも1ケ所以上有する2液反応原料
の混合装置。
(2) A two-liquid reaction raw material tank and a mechanism for pumping it, and 2
a rotary shaft having a path connected to a groove in the groove, and a rotation shaft having two grooves;
A mixing device for a two-liquid reaction raw material, comprising a motor for rotating this rotary shaft, and the rotary shaft has at least one continuous gap in a vertical cross section between the rotary shaft and the outer cylinder in the region of the distal end discharge portion.
(3)2条以上の溝を有する回転軸が軸方向に動作する
機構を有する特許請求の範囲第2項記載の2液反応原料
の混合装置。
(3) The mixing device for two-liquid reaction raw materials according to claim 2, which has a mechanism in which a rotating shaft having two or more grooves moves in the axial direction.
(4)圧送する機構が、ピストンシリンダー、ランスシ
リンダー、ベローズポンプ、ギヤポンプから選ばれる一
種又は複数の組合せによる機構である特許請求の範囲第
2項記載の2液反応原料の混合装置。
(4) The mixing device for two-liquid reaction raw materials according to claim 2, wherein the pressure-feeding mechanism is a mechanism using one or a combination of a piston cylinder, a lance cylinder, a bellows pump, and a gear pump.
JP10301985A 1985-05-15 1985-05-15 Mixer for two-liquid reaction raw materials Expired - Lifetime JPH06332B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10301985A JPH06332B2 (en) 1985-05-15 1985-05-15 Mixer for two-liquid reaction raw materials

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10301985A JPH06332B2 (en) 1985-05-15 1985-05-15 Mixer for two-liquid reaction raw materials

Publications (2)

Publication Number Publication Date
JPS61261005A true JPS61261005A (en) 1986-11-19
JPH06332B2 JPH06332B2 (en) 1994-01-05

Family

ID=14342934

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10301985A Expired - Lifetime JPH06332B2 (en) 1985-05-15 1985-05-15 Mixer for two-liquid reaction raw materials

Country Status (1)

Country Link
JP (1) JPH06332B2 (en)

Also Published As

Publication number Publication date
JPH06332B2 (en) 1994-01-05

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