JPS61255853A - Two layer type synthetic resin tube and manufacture thereof - Google Patents
Two layer type synthetic resin tube and manufacture thereofInfo
- Publication number
- JPS61255853A JPS61255853A JP9662485A JP9662485A JPS61255853A JP S61255853 A JPS61255853 A JP S61255853A JP 9662485 A JP9662485 A JP 9662485A JP 9662485 A JP9662485 A JP 9662485A JP S61255853 A JPS61255853 A JP S61255853A
- Authority
- JP
- Japan
- Prior art keywords
- tube
- synthetic resin
- layer
- fluororesin
- urethane resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Laminated Bodies (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
(産業上の利用分野)
本発明は、水、農薬その他の液等を搬送する2層式合成
樹脂チューブに関する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a two-layer synthetic resin tube for conveying water, agricultural chemicals, other liquids, and the like.
(従来の技術)
従来、互に異種の材料から成り且つ1体に成形された内
外2層から成る2層式合成樹脂チューブは公知である。(Prior Art) A two-layer synthetic resin tube consisting of two inner and outer layers made of different materials and molded into one body is conventionally known.
特に近年、フッ素樹脂は耐熱性と耐薬品性が抜群に優れ
、ウレタン樹脂は、ゴム弾性、機械的特性、耐油・溶剤
性等に優れていることが注目され、これらの需要の伸び
、用途拡大は目を見はるものがあるが、か−る優れた両
者の性質をもつ実用的な2層式チューブが開発されれば
望ましい。In particular, in recent years, fluororesins have attracted attention for their outstanding heat resistance and chemical resistance, and urethane resins have attracted attention for their excellent rubber elasticity, mechanical properties, oil and solvent resistance, etc., and demand for these is growing and applications are expanding. However, it would be desirable if a practical two-layer tube with both of these excellent properties could be developed.
(発明が解決しようとする問題点)
従来の互に異種の合成樹脂から成る2層式チューブは、
単く合成樹脂接着剤を介してその内外の成形層を相互に
強@に接着することは、その樹脂の撰択によっては極め
て困難である。例えば、上記のフッ素樹脂を使用する場
合、フッ素樹脂は非粘着性、無極性であるから、これと
例えばウレタン樹脂との2層から成る1体成形チューブ
管作成する場合、単にウレタン樹脂その他の各種の合成
樹脂接着剤を介して、その内外層の相互接着を試みても
得られた2層式チューブは、手による引張力で容易に剥
離してしまい実用的なチューブは得られなかった。試み
に、フッ素樹脂の成形チューブとウレタン樹脂その他の
合成樹脂の成形チューブとのいづれか1万又は両方に、
化学的又は物理的な手段で表面をエツチングし接着表面
積を大きくして接着面積を大きくしても、実用に適した
大きい相互接着が得られず、剥がれ易い欠点は解消でき
なかっ。(Problems to be solved by the invention) Conventional two-layer tubes made of different types of synthetic resins are
It is extremely difficult to strongly adhere the inner and outer molded layers to each other simply by using a synthetic resin adhesive, depending on the selection of the resin. For example, when using the above-mentioned fluororesin, since fluororesin is non-adhesive and non-polar, when creating a one-piece tube consisting of two layers of fluororesin and, for example, urethane resin, simply use urethane resin and other various types of resin. Even if an attempt was made to bond the inner and outer layers to each other using a synthetic resin adhesive, the resulting two-layer tube easily peeled off due to manual tension, and a practical tube could not be obtained. As a trial, either 10,000 yen of molded tubes of fluororesin, urethane resin or other synthetic resins, or both.
Even if the adhesive surface area is increased by etching the surface by chemical or physical means, a large mutual adhesion suitable for practical use cannot be obtained, and the problem of easy peeling cannot be solved.
た。Ta.
(問題点を解決するための手段)
本発明は、か\る従来の接着手段では接着不可能であっ
たフッ素樹脂も使用し得る新たな接着手段を具備した2
層式合成樹脂チューブを提供するもので、互に異種の材
料から成り、且つ1体に成形された内外2層から成る2
層式合成樹脂チューブにおいて、その両層の接合面t−
。(Means for Solving the Problems) The present invention provides a new adhesive means that can also use fluororesin, which could not be bonded using conventional adhesive means.
This product provides a layered synthetic resin tube, consisting of two inner and outer layers made of different materials and molded into one body.
In a layered synthetic resin tube, the joint surface t-
.
その1方の層の接合面に露出して埋め込んだ無機フィラ
ーとシランカップリング剤とヲ介して相互に接着せしめ
て成る。The two layers are bonded to each other through an inorganic filler exposed and embedded in the bonding surface of one of the layers and a silane coupling agent.
更に、本発明は、上記本発明の2層式合成樹脂チューブ
を通常の押出成形機により製造し得る製造法を提供する
もので、無機フィラーを含有せしめたフッ素樹脂などの
合成樹脂を内層チューブとして成形し、その上面に、シ
ランカップリング剤を添加したウレタン樹脂などの合成
樹脂を外皮チューブとして1体に成形することを特徴と
する。Furthermore, the present invention provides a method for producing the two-layer synthetic resin tube of the present invention using an ordinary extrusion molding machine, in which a synthetic resin such as a fluororesin containing an inorganic filler is used as the inner layer tube. It is characterized in that it is molded, and a synthetic resin such as urethane resin to which a silane coupling agent is added is molded into a single body as an outer skin tube on the upper surface thereof.
(実施例)
本発明の実施例をフッ素樹脂とウレタン樹脂とから成る
2層チューブ並にその製造法につき説明する。(Example) An example of the present invention will be described with reference to a two-layer tube made of a fluororesin and a urethane resin and a method for manufacturing the same.
図面は本発明の製造法の後記Tる具体例により製造され
た本発明の2層式合成樹脂チューブを模写的に表示した
もので、(1)はフッ素樹脂から成る内層チューブ(2
)はその外層面に強固に結着されたウレタン樹脂から成
る外層チューブを示し、両層チューブ(11T21の相
互の接合面は、該フッ素樹脂内層チューブ(1)に含有
せしめた無数の無機フィラー(3)のうちその外周接合
面に露出した状態のアンカーとしての機能上もつ無数の
粉末無機フィラー(3)とこれに1端で化学的に接合し
他端でウレタン樹脂外層の内周接合面に化学的に結合す
るシランカップリング剤(4)との極めて強固な接着手
段により極めて強′固に1体に結合された1体成形され
た2層式チューブである。The drawing is a schematic representation of a two-layer synthetic resin tube of the present invention manufactured by the specific example T described below of the manufacturing method of the present invention, and (1) shows an inner layer tube (2
) indicates an outer layer tube made of urethane resin that is firmly bonded to the outer layer surface, and the mutual joint surface of both layer tubes (11T21) is made of countless inorganic fillers ( Among 3), countless powdered inorganic fillers (3) which function as anchors are exposed on the outer joint surface of the filler, and one end is chemically bonded to this, and the other end is attached to the inner peripheral joint surface of the urethane resin outer layer. It is a two-layered tube molded in one piece that is extremely strongly bonded to one piece by extremely strong adhesive means with a chemically bonded silane coupling agent (4).
これにその2層間に相当の引張り剥離力を与えてその剥
離強度を試験したが全く剥離が見られなかった。かくし
て、本発明の2層式チューブ、は、夫々の両樹脂の優れ
た特性を発揮し得る耐薬品性、耐熱性、柔軟性、機械的
特性等の全てにおいて優れた2層式合成樹脂チューブの
実用的な製品として、農薬液等の各種化学薬液など用途
に応じて各種の流体を良好に搬送し得られ、又使用寿命
の大きい良好なホースとして使用し得る。This was tested for peel strength by applying a considerable tensile peel force between the two layers, but no peeling was observed. Thus, the two-layer synthetic resin tube of the present invention is a two-layer synthetic resin tube that is excellent in all aspects such as chemical resistance, heat resistance, flexibility, and mechanical properties that can exhibit the excellent properties of both resins. As a practical product, it can satisfactorily transport various fluids depending on the purpose, such as various chemical liquids such as agricultural chemicals, and can be used as a good hose with a long service life.
次に上記の実施例に示す、フッ素樹脂とウレタン樹脂と
2層から成るチューブの製法の1例につき詳述する。Next, one example of a method for manufacturing a tube made of two layers of fluororesin and urethane resin, shown in the above embodiment, will be described in detail.
フッ素樹脂としては、熱可塑性樹脂としての要件を充分
満足するものであれば足り、これに無機フィラーを混合
する工程があるので、混合し易い即ち流れ特性の良いも
のが好ましい。その例としでは、ポリクロロトリフルオ
ロエチレン(POTIF]I+) 、テトラフルオロl
エチレン−ヘキサフルオルプロピレン(TlcP)、テ
トラフルオaエチレン−パーフルオロアルキルビニルエ
ーテル(PIF人)、テトラフルオロエチレン−エチレ
ン(1+TIFK) 、ポリ7ツ化ビニリデン(PVD
7)等が挙げられるが、特に好ましくは、Xτym。The fluororesin may be any fluororesin as long as it fully satisfies the requirements for a thermoplastic resin, and since there is a step of mixing an inorganic filler with it, it is preferable to use a fluororesin that is easy to mix, that is, has good flow characteristics. Examples include polychlorotrifluoroethylene (POTIF]I+), tetrafluoroI
Ethylene-hexafluoropropylene (TlcP), Tetrafluoroethylene-perfluoroalkyl vinyl ether (PIF), Tetrafluoroethylene-ethylene (1+TIFK), Polyvinylidene hexafluoride (PVD)
7) etc., particularly preferably Xτym.
POT7mである。The POT is 7m.
フッ素樹脂に混入する無機フィラーとしては、石英、コ
田イドシリカ等のシリカ類、カオリン、!イカ、タルク
、ケイ酸カルシウム、ケイ酸アルミニウム等のケイ酸塩
類、酸化鉄、7Nミt。Inorganic fillers mixed into fluororesin include quartz, silicas such as Koda silica, kaolin, and! Squid, talc, silicates such as calcium silicate, aluminum silicate, iron oxide, 7N mit.
ill化アルミニウム等の金属酸化物類、アルミニウム
、銅等の金属類等の所望のその微細な無機フィラーの1
種又は2種以上を選択使用する。1 of desired fine inorganic fillers such as metal oxides such as aluminum oxide, metals such as aluminum and copper, etc.
Select and use one or more species.
これら無機フィラーは、接着助剤と良く化学結合する0
無機フィラーのフッ素樹脂に対する添加量は、フッ素樹
脂100部に対して1〜10部の範囲が好ましいが、こ
の範囲に限定されるものではない。These inorganic fillers have good chemical bonding with adhesion aids.
The amount of the inorganic filler added to the fluororesin is preferably in the range of 1 to 10 parts per 100 parts of the fluororesin, but is not limited to this range.
ウレタン樹脂としては、熱可堕性の要件を満足するもの
であれば足り、一般的には、1)アジピン酸とグリフー
ルから成るアジピン酸系ポリエステルポリオール、II
)g−カプロラクトンを開環して得るカプロラクトン系
ポリエステルポリオール又はl1l)ray等環成環状
エーテル環して得るエーテル系ポリオールに、有機ジイ
ソシアネートを付加重合させたタイプであれば何れでも
よい。特にシランカップリング剤YR8iX、のYがM
H,基の場合は、これに相溶し又反応する系のものが良
く、この点からみると残存NOD基を含有しているもの
程適し、任意の市販品を使用できる。As the urethane resin, it is sufficient as long as it satisfies the requirements of heat-fallenability, and generally, 1) adipic acid-based polyester polyol consisting of adipic acid and glyfur, II
) Any type may be used as long as an organic diisocyanate is addition-polymerized to a caprolactone-based polyester polyol obtained by ring-opening g-caprolactone or an ether-based polyol obtained by ring-forming a cyclic ether such as ray. In particular, Y of the silane coupling agent YR8iX is M
In the case of H, groups, those that are compatible with and react with H, are preferred, and from this point of view, those containing residual NOD groups are more suitable, and any commercially available products can be used.
接着助剤としては、前記の無機フィラーとウレタン樹脂
等の合成樹脂の反応基と夫々化学的に結合するものであ
れば足りるが、ウレタン樹脂の場合には、シランカップ
リング剤〔一般式YR8i X@ s 舷テYはME、
、 Ha、 01!、 ==b−等の反応基、Xは(
OOI(、OH,)、(OOH,)3等の反応基である
。〕を使用することが好ましく、就中、NH*基を有ウ
レタン樹脂の残存Woo基と相溶又は反応を起こし易い
ので好ましい。As the adhesion aid, it is sufficient that it chemically bonds with the above-mentioned inorganic filler and the reactive group of the synthetic resin such as urethane resin, but in the case of urethane resin, a silane coupling agent [general formula YR8i @s Y is ME,
, Ha, 01! , ==b-, etc., and X is (
These are reactive groups such as OOI(,OH,) and (OOH,)3. It is preferable to use ], and in particular, it is preferable because the NH* group is easily compatible with or reacts with the remaining Woo group of the urethane resin.
例えば、rアミノプロピルトリエトキシシラン(MH,
OH!OR,01!、81 (OOH,OH,)、
、N−β−(アミノエチル)−r−アミラブルピルトリ
メトキシシランCNH,0HfOHIHHOHffiO
H,OH,!31 (OOH) 、 、 7’−ウレイ
ドプルピルエトキシシラン(NH,0ONHO馬OH。For example, r-aminopropyltriethoxysilane (MH,
Oh! OR,01! ,81 (OOH,OH,),
, N-β-(aminoethyl)-r-amylablepyrtrimethoxysilane CNH,0HfOHIHHOHffiO
H,OH,! 31 (OOH), 7'-ureidopropylethoxysilane (NH,0ONHOH).
81 (OOII、OH,)、等が挙げられる。81 (OOII, OH,), etc.
該シランカップリング剤のウレタン樹脂に対する添加量
は、概して、ウレタン樹脂総量に対してα5〜10重量
倦が好ましく、1〜5重量%が最適である。The amount of the silane coupling agent added to the urethane resin is generally preferably α5 to 10% by weight, and optimally 1 to 5% by weight, based on the total amount of the urethane resin.
該シランカップリング剤の添加はウレタン樹脂の内部に
混入するかその表面に付着乃至塗布することで足りる。The silane coupling agent can be added by mixing it inside the urethane resin or adhering or coating it to the surface of the urethane resin.
次に上記フッ素樹脂を内層としウレタン樹脂を外層とす
る1体成形の2層式合成樹脂チューブを製造Tる好まし
い具体例を説明する。Next, a preferred specific example of manufacturing a two-layer synthetic resin tube formed in one piece, with the fluororesin as the inner layer and the urethane resin as the outer layer, will be described.
具体例
フッ素樹脂(テトラフルオaエチレンとエチレンの共重
合体11i’l”1FEt )のペレツ) 100ky
にケイ酸アルミニウム粉末5に9@2軸押出機で330
〜350℃の温度条件でブレンドし、ペレット化した。Specific example Fluororesin (pellets of tetrafluoro-a ethylene and ethylene copolymer 11i'l"1FEt) 100ky
aluminum silicate powder 5 to 9 @ 330 in twin screw extruder
It was blended and pelletized at a temperature of ~350°C.
このようにして得られたケイ酸アルミニウム含有フッ素
樹脂ペレットを30■φ単軸押出機で成形し内径1 m
m 、外径1.5−のチューブを作成した。The aluminum silicate-containing fluororesin pellets thus obtained were molded using a 30 mm diameter single-screw extruder to an inner diameter of 1 m.
A tube with an outer diameter of 1.5 m and an outer diameter of 1.5 mm was prepared.
1方、熱可塑性ウレタン樹脂ペレット(バンデツクスー
5067大日本インキ化学製)100に9にシランカッ
プリング剤(γ−アミノプロピルトリエトキシシラン)
5−をタンブラ−で混合し、熱可塑性ウレタン樹脂ペレ
ットの表面に均一に付着させ、100℃、2時間電気炉
で熱処理した。On the other hand, thermoplastic urethane resin pellets (Vandex 5067, manufactured by Dainippon Ink Chemical) 100 to 9, silane coupling agent (γ-aminopropyltriethoxysilane)
5- was mixed in a tumbler, uniformly adhered to the surface of a thermoplastic urethane resin pellet, and heat-treated in an electric furnace at 100° C. for 2 hours.
次に、前記のケイ酸アルミニウム含有7ツ素樹脂から成
る押出成形チューブを内層としこの外周面(前記のシラ
ンカップリング剤付着のウレタン樹脂を押出コーティン
グでt5msの厚さの外層チューブとなるよう連続的に
コーティングし、全体として内径1−外径Swaの2要
式チュプを製造した。Next, the extrusion-molded tube made of the aluminum silicate-containing 7-component resin is used as an inner layer, and the outer circumferential surface (the urethane resin to which the silane coupling agent is attached) is extrusion coated so as to form an outer layer tube with a thickness of 5 ms. A two-piece type tube having an inner diameter of 1 and an outer diameter of Swa was manufactured as a whole.
参考のため、無機フィラーを無添加の上記のフッ素樹脂
ペレットと、シランカップリング剤に付着させない上記
のウレタン樹脂ペレットとを材料とし、上記と同様和し
て2層式チューブを作成した。For reference, the above-mentioned fluororesin pellets with no inorganic filler added and the above-mentioned urethane resin pellets not attached to the silane coupling agent were used as materials and were combined in the same manner as above to create a two-layer tube.
上記の本発明の2層式チューブと参考例の2層式チュー
ブにつき治真を使用し手で強引に両層間を剥がすべく引
張り力を与えた所、本発明品は全く剥がれなかったに対
し参考品は容易に剥がれた。When we manually applied a tensile force to the two-layered tube of the present invention and the two-layered tube of the reference example to forcibly peel off the two layers by hand, the product of the present invention did not peel off at all, whereas the two-layered tube of the reference example did not peel off at all. The item peeled off easily.
(発明の効果)
本発明は、互に異なる合成樹脂を内外層とした2層式チ
ューブにおいてその両層の接着手段としてその両層の接
合面の1方の面に無数の無機フィラーを投錨固定させる
と共にその他方の面にシランカップリング剤を付着介在
させたので、これら無機フィラーとシランカップリング
剤とを介して内外両層は極めて強固に1体に結着した2
層式チューブをもたらし、フッ素樹脂層とウレタン樹脂
層とから成る2層式チューブの実用性が可能となり、そ
の製品はその夫々の優れた特性が発揮されて極めて産業
上利用範囲の広く利用できる等の効果を有する。(Effects of the Invention) The present invention provides a two-layered tube in which the inner and outer layers are made of different synthetic resins, and a countless number of inorganic fillers are anchored and fixed to one of the joint surfaces of the two layers as a means of adhering the two layers. At the same time, a silane coupling agent was attached to the other surface, so both the inner and outer layers were extremely firmly bonded together through the inorganic filler and the silane coupling agent.
A layered tube has been created, and a two-layered tube consisting of a fluororesin layer and a urethane resin layer has become practical, and the product exhibits the excellent characteristics of each layer and can be used in an extremely wide range of industrial applications. It has the effect of
図面は、本発明実施の1例の製品の1部の断面図を示す
。
(1)・・・内層チューブ
(2)・・・外層チューブ
(3)・・・無機フィラー
(4)・・・シランカップリング剤
手続補正書The drawing shows a cross-sectional view of a portion of an example of a product implementing the invention. (1) Inner tube (2) Outer tube (3) Inorganic filler (4) Silane coupling agent procedure amendment
Claims (1)
外2層から成る2層式合成樹脂チューブにおいて、その
両層の接合面を、その1方の層の接合面に露出して埋め
込んだ無機フィラーとシランカップリング剤とを介して
相互に接着せしめて成る2層式合成樹脂チューブ。 2 1方の合成樹脂はフッ素樹脂であり、これを内層チ
ューブとし、他方の合成樹脂はウレタン樹脂としこれを
外層チューブとして成る特許請求の範囲1項に記載の2
層式合成樹脂チューブ。 3 無機フィラーを含有せしめたフッ素樹脂などの合成
樹脂を内層チューブとして成形し、その上面に、シラン
カップリング剤を添加したウレタン樹脂などの合成樹脂
を外皮チューブとして1体に成形することを特徴とする
2層式合成樹脂チューブの製造法。[Scope of Claims] 1. In a two-layer synthetic resin tube consisting of two inner and outer layers made of different materials and molded into one body, the bonding surface of both layers is the bonding surface of one of the layers. A two-layer synthetic resin tube that is bonded to each other via an inorganic filler exposed and embedded on the surface and a silane coupling agent. 2 One synthetic resin is a fluororesin, which serves as the inner tube, and the other synthetic resin is a urethane resin, which serves as the outer tube.
Layered synthetic resin tube. 3 A synthetic resin such as a fluororesin containing an inorganic filler is molded as an inner layer tube, and a synthetic resin such as a urethane resin containing a silane coupling agent is molded into one body on the upper surface as an outer tube. A method for manufacturing a two-layer synthetic resin tube.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP60096624A JPH069917B2 (en) | 1985-05-09 | 1985-05-09 | 2-layer synthetic resin tube |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP60096624A JPH069917B2 (en) | 1985-05-09 | 1985-05-09 | 2-layer synthetic resin tube |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS61255853A true JPS61255853A (en) | 1986-11-13 |
JPH069917B2 JPH069917B2 (en) | 1994-02-09 |
Family
ID=14169993
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP60096624A Expired - Lifetime JPH069917B2 (en) | 1985-05-09 | 1985-05-09 | 2-layer synthetic resin tube |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH069917B2 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH09277459A (en) * | 1996-04-12 | 1997-10-28 | Asahi Glass Co Ltd | Laminate and its manufacture |
WO2006019650A1 (en) * | 2004-07-30 | 2006-02-23 | 3M Innovative Properties Company | Bonding compositions |
US7745545B2 (en) | 2001-05-21 | 2010-06-29 | 3M Innovative Properties Company | Bonding compositions |
JP2013123709A (en) * | 2011-12-15 | 2013-06-24 | Samsung Electro-Mechanics Co Ltd | Resin base material and method for producing the same |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006134764A1 (en) | 2005-06-14 | 2006-12-21 | Asahi Glass Company, Limited | Fluororesin multilayer laminate |
FR3065223B1 (en) | 2017-04-18 | 2019-07-05 | Societe Bic | DRY CLEANING INK WITH IMPROVED DRYING TIME |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4935480A (en) * | 1972-08-05 | 1974-04-02 | ||
JPS5033268A (en) * | 1973-07-24 | 1975-03-31 | ||
JPS5281314A (en) * | 1975-09-19 | 1977-07-07 | Mitsui Fluorochemicals Co Ltd | Composite of tetrafluoroethylenee perfluoro*alkylvinylether* copolymerized resin and glass or pottery |
JPS54110285A (en) * | 1978-01-20 | 1979-08-29 | Ugine Kuhlmann | Polyfluorovinylydeneepolyurethane composite * and manufacture therefor |
-
1985
- 1985-05-09 JP JP60096624A patent/JPH069917B2/en not_active Expired - Lifetime
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4935480A (en) * | 1972-08-05 | 1974-04-02 | ||
JPS5033268A (en) * | 1973-07-24 | 1975-03-31 | ||
JPS5281314A (en) * | 1975-09-19 | 1977-07-07 | Mitsui Fluorochemicals Co Ltd | Composite of tetrafluoroethylenee perfluoro*alkylvinylether* copolymerized resin and glass or pottery |
JPS54110285A (en) * | 1978-01-20 | 1979-08-29 | Ugine Kuhlmann | Polyfluorovinylydeneepolyurethane composite * and manufacture therefor |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH09277459A (en) * | 1996-04-12 | 1997-10-28 | Asahi Glass Co Ltd | Laminate and its manufacture |
US7745545B2 (en) | 2001-05-21 | 2010-06-29 | 3M Innovative Properties Company | Bonding compositions |
WO2006019650A1 (en) * | 2004-07-30 | 2006-02-23 | 3M Innovative Properties Company | Bonding compositions |
JP2008508396A (en) * | 2004-07-30 | 2008-03-21 | スリーエム イノベイティブ プロパティズ カンパニー | Binding composition |
JP2013123709A (en) * | 2011-12-15 | 2013-06-24 | Samsung Electro-Mechanics Co Ltd | Resin base material and method for producing the same |
Also Published As
Publication number | Publication date |
---|---|
JPH069917B2 (en) | 1994-02-09 |
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