JPS6124770A - Destruction of fragile body - Google Patents

Destruction of fragile body

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Publication number
JPS6124770A
JPS6124770A JP14324784A JP14324784A JPS6124770A JP S6124770 A JPS6124770 A JP S6124770A JP 14324784 A JP14324784 A JP 14324784A JP 14324784 A JP14324784 A JP 14324784A JP S6124770 A JPS6124770 A JP S6124770A
Authority
JP
Japan
Prior art keywords
destroyed
agent
container
exothermic agent
reaction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP14324784A
Other languages
Japanese (ja)
Inventor
康夫 石井
太郎 井上
坂野 良一
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Taisei Corp
Original Assignee
Taisei Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Taisei Corp filed Critical Taisei Corp
Priority to JP14324784A priority Critical patent/JPS6124770A/en
Publication of JPS6124770A publication Critical patent/JPS6124770A/en
Pending legal-status Critical Current

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  • Drilling And Exploitation, And Mining Machines And Methods (AREA)
  • Working Measures On Existing Buildindgs (AREA)
  • Disintegrating Or Milling (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 「産業上の利用分野」 本発明は土木工事における岩盤破砕1.−岩石の小分割
、コンクリート構造物の破砕、解体、基礎工事における
コンクリート杭の枕頭破砕等の如き脆性体の破壊方法に
係るものである。
DETAILED DESCRIPTION OF THE INVENTION "Field of Industrial Application" The present invention is applicable to rock crushing in civil engineering works. - This relates to methods of destroying brittle bodies such as subdividing rocks, crushing and demolition of concrete structures, and crushing the head of concrete piles in foundation work.

「従来技術」 従来、岩石、またはコンクリート体等の破壊方法として
、火薬類による発破方法、油圧侯による方法、ル−カ等
による機械的衝撃力金利用する方法、更には石灰系膨張
剤による脹膨作用を利用する方法がある。
``Prior art'' Conventionally, as methods for destroying rocks or concrete bodies, there have been blasting methods using explosives, methods using hydraulic pressure, methods using mechanical impact force using lucas, etc., and furthermore, swelling using lime-based expansion agents. There is a method that utilizes the swelling effect.

而して発破による方法においては、被破壊体発破時の振
動、騒音、飛石が生じ、周辺環境の状態によってはその
使用が制限される他、火薬類取締法上の制約もある。
However, in the method of blasting, vibrations, noise, and flying stones are generated when the object to be destroyed is blasted, and its use is restricted depending on the state of the surrounding environment, and there are also restrictions under the Explosives Control Law.

このような振動、騒音、飛石の問題に対処するために、
火薬類のうち爆薬の爆速を通常のものよシ相当低下させ
た制御発破用爆薬を使用する方法や、ガス圧により破壊
するコンクリート粉砕器による方法も提案されている。
To deal with such problems of vibration, noise, and flying stones,
Among explosives, a method using controlled blasting explosives whose detonation speed is considerably lower than that of normal explosives, and a method using a concrete crusher that destroys the concrete using gas pressure have also been proposed.

しかしながらこれらの方法は何れも、振動、騒音、飛石
の問題音完全に解決するには至っていない。
However, none of these methods has completely solved the problems of vibration, noise, and flying stones.

また他の方法として、生石灰等と水との反応による体積
膨張を利用する破壊方法があシ、この方法においては反
応の速い生石灰なペースト状にして削孔部に装填し、孔
口金封塞するまでの間、反応を遅延させなければならな
いが、装填後は大きな膨張力が望ましい、このため各種
の反応促進方法が試みられている。
Another method is to utilize the volumetric expansion caused by the reaction between quicklime and water. In this method, quicklime is made into a paste that reacts quickly and is loaded into the drilled hole to seal the hole cap. Although the reaction must be delayed until then, a large expansion force is desirable after loading, and for this reason various methods of accelerating the reaction have been attempted.

例えば特公昭49−43416号公報に示す如き電熱線
の加熱による反応の促進方法があシ、また反応の遅延と
膨張力の増大と七図って膨張剤上使用した特開昭55−
142894号公報に示す方法があるが、これらは何れ
も生石灰系の水和反応を利用するのにあたっての困難往
管解決しようとするものであるが、破壊力自体を大幅に
増大しうるものではなく、また取扱い上の煩雑さが伴な
う。
For example, there is a method of accelerating the reaction by heating with a heating wire as shown in Japanese Patent Publication No. 43416/1982, and Japanese Patent Application Laid-Open No. 55/1987 (1986) discloses a method of promoting the reaction by heating with a heating wire.
There are methods shown in Publication No. 142894, but these all attempt to solve the difficulties of using the hydration reaction of quicklime, but they do not significantly increase the destructive force itself. , and the handling is complicated.

またテルミツト剤を併用した方法も提案されているが、
こ9方法におけるテルミツト剤の使用目的は生石灰の如
き膨張剤の水和反応を促進する点におiて、破壊力の主
力となる生石灰の反応遅延のための処理は、在来の生石
灰系の反応を利用する方法における場合と同様の煩雑な
問題が残っている。
A method using a thermite agent has also been proposed, but
The purpose of using thermite agent in these 9 methods is to promote the hydration reaction of swelling agents such as quicklime, and the treatment for delaying the reaction of quicklime, which is the main force of destructive force, The same complications as in reaction-based methods remain.

「発明の解決しようとする問題点」 本発明Fi、爆薬、火薬類の衝撃的な発破による被破壊
体の飛散及び振動、騒音な抑止するとともに、従来の石
灰系膨張剤の破壊力の不足と取扱い上の煩雑さ、破壊に
長時間を要すること等の問題点を解決しようとするもの
である。
"Problems to be Solved by the Invention" The present invention suppresses the scattering, vibration, and noise of objects to be destroyed due to the impactful blasting of explosives and explosives, and also solves the problem of the lack of destructive power of conventional lime-based expanding agents. This is an attempt to solve problems such as the complexity of handling and the long time it takes to destroy.

即ち本発明は、火薬類による場合と同等の発壊力を得、
短時間で破壊ができ、且つ膨張剤による破壊方法と同様
に破壊体の飛散や振動を伴なわない破壊方法を提供する
ことを目的とするものである。
That is, the present invention obtains an explosive force equivalent to that of explosives,
The object of the present invention is to provide a destruction method that can be destroyed in a short time and does not involve scattering or vibration of the destruction body, similar to the destruction method using an expanding agent.

「問題点を破壊する方法」 本発明は前記の目的を達成するために、岩石。"How to destroy problems" In order to achieve the above object, the present invention provides a method for producing rocks.

岩盤またはコンクリート体の如き脆性体よりなる°被破
壊体の削孔部内に、発熱剤、点火剤の粉末、及び抵抗発
熱体よりなる点火装置を封入してなる容器を装填したの
ち、前記点火装置に通電し、前記点火剤に着火して前記
発熱剤を反応せしめ、同発熱剤の反応熱によって被破壊
体の強度を劣化させるとともに、同被破壊体内含有水分
の気化によって発生した水蒸気圧によって前記被破壊体
を破壊せしめるようにしたものである。
After loading a container containing a heating agent, powder of ignition agent, and an ignition device made of a resistance heating element into the drilled part of the object to be destroyed, which is made of a brittle body such as rock or concrete, the ignition device is , the ignition agent is ignited, causing the exothermic agent to react, and the reaction heat of the exothermic agent deteriorates the strength of the object to be destroyed, and the water vapor pressure generated by vaporization of the moisture contained in the object causes the exothermic agent to react. It is designed to cause the object to be destroyed to be destroyed.

本発明は更に前記手段に加えて、被破壊体内の水分が破
壊に必要な水蒸気生成に十分でない場合、発熱剤、点火
剤の粉末及び抵抗発熱体よりなる点火装置を封入した容
器とともに、前記発熱剤の反応により気化する量以下の
水な封入した容器を被破壊体の削孔部に装填し、発熱剤
の反応熱によってこの容器内の水を気化せしめるように
したものである。
In addition to the above-mentioned means, the present invention further provides that when the moisture inside the object to be destroyed is not sufficient to generate the steam necessary for destruction, the present invention provides a container enclosing an ignition device consisting of a heat-generating agent, powder of ignition agent, and a resistance heating element. A container filled with water in an amount less than that which is vaporized by the reaction of the exothermic agent is loaded into the drilled part of the object to be destroyed, and the water in the container is vaporized by the reaction heat of the exothermic agent.

「作用」 本発明においては前記したように、被破壊体の削孔部内
に、発熱剤、点火剤の粉末、及び抵抗発熱体よりなる点
火装置を封入した容器を装填して、前記点火装置に通電
することによって前記点火剤に着火して前記発熱剤を反
応せしめるようにしたので、同発熱剤の反応熱によって
被破壊体が加熱され、強度が劣化すると同時に、前記発
熱剤の反応熱によって被破壊体内の含有水分が気化し、
この蒸気圧によって被破壊体は内部よシ破壊される。
"Operation" In the present invention, as described above, a container containing an igniter made of a heat generating agent, powder of igniting agent, and a resistance heating element is loaded into the drilled part of the object to be destroyed, and the igniter is connected to the igniter. By applying electricity, the ignition agent is ignited and the exothermic agent is caused to react, so that the object to be destroyed is heated by the reaction heat of the exothermic agent, and its strength is deteriorated. The moisture contained within the destroyed body evaporates,
This vapor pressure causes the object to be destroyed internally.

また前記容器とともに水を封入した容器を併用した場合
、同容器内の水が気化するが、被破壊体の削孔部の孔口
が溶融した発熱剤によって閉塞されるので、被破壊体に
大きな圧力が加えられ、破壊されるものである。
In addition, if a container filled with water is used in conjunction with the above-mentioned container, the water in the container will evaporate, but the hole in the drilled part of the object to be destroyed will be blocked by the melted exothermic agent, causing a large amount of damage to the object to be destroyed. It is something that is destroyed by applying pressure.

このように一本発明の方法によれば被破壊体は熱による
強度の劣化と、水蒸気圧による加圧によつて破壊される
ので、爆薬による発破時の如き衝撃を伴なわず、また被
破壊体の飛散を生起しなり4゜「実施例」 次に本発明を図示の実施例について説明する。
In this way, according to the method of the present invention, the object to be destroyed is destroyed by deterioration of its strength due to heat and pressurization by water vapor pressure, so there is no impact as in the case of blasting with explosives, and the object to be destroyed is 4 degrees of bending causing scattering of bodies ``Embodiment'' Next, the present invention will be described with reference to the illustrated embodiments.

(1)はコンクリート体の如き内部含有水分量の比較的
大きi被破壊体で、その破壊面(2)に沿って削孔し、
(第2図参照)同各削孔部(3)内に、発熱剤、点火剤
の粉末及び抵抗発熱体よりなる電気的点火装置を封入し
た容器(4)を装填する。
(1) is a body to be destroyed, such as a concrete body, with a relatively large internal moisture content, and a hole is drilled along its fracture surface (2),
(See FIG. 2) A container (4) containing an electric ignition device consisting of a heating agent, powder of ignition agent, and a resistance heating element is loaded into each of the drilled portions (3).

第3図は同容器(4)の詳細を示し、プラスチック製薄
肉容器内に酸化鉄とアルミニウムの粉末との混合物(重
量比2.81)よ)なる発熱剤(5)す封入し、同発熱
剤(5)上に過酸化バリウム、マグネシウム等の混合粉
末よ多なる点火剤(6)ヲ載せ、同点火剤(6)にニク
ロム線等の電気的点火装置(力を取付ける。
Figure 3 shows the details of the same container (4), in which a heat generating agent (5) consisting of a mixture of iron oxide and aluminum powder (weight ratio 2.81) is sealed inside the thin plastic container. An igniter (6) consisting of a mixed powder of barium peroxide, magnesium, etc. is placed on the agent (5), and an electric igniter (force) such as a nichrome wire is attached to the igniter (6).

このように前記容器(4)を削孔部(3)の奥部に装填
すると、前記点火装置(7)ケ脚線(8)′を介して点
火装置(9)に連結し、削孔部(3)の孔口をモルタル
等で閉塞する。
When the container (4) is loaded into the deep part of the drilled hole (3) in this way, the igniter (7) is connected to the igniter (9) via the leg wire (8)', and (3) Close the hole with mortar or the like.

同モルタルの硬化を俟って点火装置(9)K通電し。After the mortar had hardened, the ignition device (9) K was energized.

発熱剤(5)に点火して反応せしめ、その反応熱によっ
て被破壊体(1)t−加熱してその強度を劣化せしめる
とともに、被破壊体(1)の内部含有水分よシ前記反応
熱によって生じた水蒸気圧によって被破壊体(1)を破
壊する。
The exothermic agent (5) is ignited to cause a reaction, and the heat of reaction heats the object (1) to be destroyed, deteriorating its strength, and the moisture contained inside the object (1) is removed by the heat of reaction. The object to be destroyed (1) is destroyed by the generated water vapor pressure.

なお発熱剤(5)として図示の実施例におけるように、
従来チルオツド溶接に利用されてきたテルミツト剤の一
つとしての酸化鉄とアルミニウム粉末との混合物を用い
た場合の反応式は次式3Fe304+8AJ−9Fe+
4AA!zos+702.500calで表わされ、瞬
間的に大量の発熱量が得られ、テルミツト剤は約280
0℃の高温溶鉱状態の鉄とアルミナとなって削孔部を閉
塞する。
In addition, as in the illustrated example as the exothermic agent (5),
The reaction formula when using a mixture of iron oxide and aluminum powder as one of the thermite agents conventionally used in chilled welding is the following formula: 3Fe304+8AJ-9Fe+
4AA! It is expressed as zos + 702.500 cal, and a large amount of calorific value is obtained instantaneously, and thermite agent is approximately 280 cal.
It turns into iron and alumina in a high-temperature melted state at 0°C and blocks the drilled hole.

対照例として生石灰の水和反応を挙げる。この場合1反
応式は次式 CaO+H2O−+0a(OH)2+15,200ca
lで示され、前式に比して発熱量が少ないこともさるこ
とながら、前述のように生石灰の膨張反応を十分有効に
利用することは困難である。
The hydration reaction of quicklime is given as a comparative example. In this case, one reaction formula is the following formula: CaO+H2O-+0a(OH)2+15,200ca
In addition to the fact that the calorific value is smaller than that of the previous equation, it is difficult to utilize the expansion reaction of quicklime effectively as described above.

M4図はコンクリート体のように内部含有水分量が多く
な匹岩石等の被破壊体に本発明を適用した場合を示し、
前記発熱剤(5)、点火剤(6)及び電気的点火装置(
7)を封入した容器(4)に沿わせて、或iは回答器(
4)の奥部に水を封入した薄肉の袋または容器翰を削孔
部(3)に装填する。
Diagram M4 shows the case where the present invention is applied to a body to be destroyed, such as a solid rock with a large internal moisture content, such as a concrete body.
The exothermic agent (5), the ignition agent (6) and the electric ignition device (
7) along the container (4) sealed with i or the answering device (
4) Load a thin-walled bag or container with water sealed inside the hole (3).

しかるのち削孔部(3)の孔ロ金モルタルI等で閉塞し
、その硬化を俟って点火装置(9)に通電し、容器(4
)内の発熱剤(5)を着火して反応せしめ、その反応熱
によって被破壊体(1)を加熱してその強度を劣化せし
めるとともに、前記袋または容器顛内の水の加熱によっ
て生起した蒸気圧によプ被破壊体(1)を破壊する。・ なお前記実施例にお−ては、各削孔部(3)毎に酸化鉄
Fe3O4粉末303グラム、アルミニウム粉末108
グラムよりなる発熱剤を使用し、これに対して団グラム
の水を封入したポリエチレンの袋七前記発熱剤を容れた
容器の央部に沿わせるものである。
After that, the hole in the drilled hole (3) is closed with gold mortar I, etc., and after it hardens, the igniter (9) is energized and the container (4) is closed.
) is ignited and reacted, and the reaction heat heats the object to be destroyed (1) and deteriorates its strength, and the steam generated by heating the water in the bag or container. The object to be destroyed (1) is destroyed by pressure. - In the above example, 303 grams of iron oxide Fe3O4 powder and 108 grams of aluminum powder were used for each drilled part (3).
A polyethylene bag filled with a mass of water is placed along the center of the container containing the exothermic agent.

なお水の量り発熱剤の発熱量に対応して全量が気化する
程度の量に調整されることが望ましi。
It is desirable that the amount of water be adjusted to the extent that the entire amount is vaporized in accordance with the calorific value of the exothermic agent.

また被破壊体内の水分を勘案することは勿論であるが、
被破壊体に十分な水分がなく、水の容器を併用する場合
にもその全水量が加熱によって気化する量以下にするこ
とがより。
Of course, the moisture inside the body to be destroyed must be taken into account, but
Even if there is not enough water in the object to be destroyed and a water container is used, it is better to keep the total amount of water below the amount that can be vaporized by heating.

第5因は本発明の更に他の実施例を示し、削孔部(3)
K発熱剤等を封入した容器(4)と水の封入された袋ま
たは容器αQを装填するのに当9、両者(4)部間に断
熱材(I邊を介装し5発熱剤から袋または容器(II内
の水に対する熱伝導を遅延させ、前記発熱剤が反応して
流体状になシ、更KaI結して削孔部(3)の孔口全閉
塞するようになった後、袋または容器(11内の水が気
化して、同衾または容器αI¥C破壊するとともに削孔
部(3)の孔壁を破壊して被破壊体(1)を破壊するも
のである。本実施例によnば発熱剤の反応に先行して削
孔部(3)の孔口をモルタル等で閉塞する作業を省略で
きるという利点がある。
The fifth factor shows still another embodiment of the present invention, in which the drilling portion (3)
To load the container (4) filled with K exothermic agent, etc. and the bag or container αQ filled with water, insert a heat insulating material (I side) between the two parts (4) and insert the bag from the exothermic agent. Alternatively, after the heat transfer to the water in the container (II) is delayed, and the exothermic agent reacts and forms a fluid, it is further solidified and the hole of the drilled hole (3) is completely closed. The water in the bag or container (11) vaporizes and destroys the bag or container αI¥C, and also destroys the hole wall of the hole drilling part (3) and destroys the object (1) to be destroyed.This implementation For example, there is an advantage that it is possible to omit the work of closing the hole opening of the drilled part (3) with mortar or the like prior to the reaction of the exothermic agent.

「発明の効果」 本発明によれはこのように、被破壊体の削孔部に装填さ
れた容器に封入され九発熱剤の発熱反応によって、被破
壊体を直接高温で加熱してその強度を劣化させるととも
に、溶融された発熱剤によって密封された空間内の水を
完全に気化させることによって水蒸気圧を十分に破壊力
として利用するものである。
``Effects of the Invention'' According to the present invention, the object to be destroyed is directly heated to a high temperature by the exothermic reaction of the exothermic agent enclosed in a container loaded into the drilled part of the object to be destroyed, thereby increasing its strength. The water vapor pressure is fully utilized as a destructive force by completely vaporizing the water in the space sealed by the molten exothermic agent as well as deteriorating it.

而して前記破壊力は爆薬の如き衝撃力によるものではな
いので、被破壊体の飛散を生起することがなく、また従
来の生石灰系の膨張剤を使用した破壊方法のように、削
孔部に対する装填のための反応速度の調整の必要がなく
、削孔部からの噴出を抑えるだめの孔口閉塞の問題も生
起しない。
Since the destructive force is not caused by an impact force such as that of an explosive, the object to be destroyed will not be scattered, and unlike the conventional destructive method using a quicklime-based expansion agent, the drilling area will not be affected. There is no need to adjust the reaction rate for loading, and there is no problem of hole clogging to suppress ejection from the drilled hole.

従って簡単な操作により、短時間で安全な破壊作業が行
なわれるものである。
Therefore, safe destruction work can be carried out in a short time with simple operations.

以上本発明を実施例について説明したが、本発明は勿論
このような実施例にだけ局限されるものではなく、本発
明の精神を逸脱しない範囲内で種々の設計の改変を施し
うるものである、
Although the present invention has been described above with reference to embodiments, the present invention is, of course, not limited to such embodiments, and can be modified in various ways without departing from the spirit of the present invention. ,

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明に係る脆悸体の破壊方法の一実施例の実
施状態を示す縦断面図、第2図は被破壊体の削孔状態を
示す斜面図、第3図は削孔部に装填される容器の縦断面
図、第4図及び第5図は夫々本発明の方法の他の各実施
例の実施状況を示す縦断面図である。 (1)・・・被破壊体、(3)・・・削孔部、(4)・
・・容器、(5)−・・発熱剤、(6)・・・点火剤、
(力・・・電気的点火装置、(11・・・水全封入した
袋または容器。
FIG. 1 is a longitudinal cross-sectional view showing an embodiment of the method for destroying a brittle body according to the present invention, FIG. 2 is an oblique view showing the state of drilling a hole in the object to be destroyed, and FIG. 3 is a hole drilling section. FIGS. 4 and 5 are longitudinal sectional views showing the state of implementation of other embodiments of the method of the present invention, respectively. (1)...Object to be destroyed, (3)...Drilled part, (4)...
...Container, (5)--Exothermic agent, (6)--Ignition agent,
(Power: Electric ignition device, (11: Bag or container completely filled with water.

Claims (2)

【特許請求の範囲】[Claims] (1)岩石、岩盤またはコンクリート体の如き脆性体よ
りなる被破壊体の削孔部内に、発熱剤、点火剤の粉末、
及び抵抗発熱体よりなる点火装置を封入してなる容器を
装填したのち、前記点火装置に通電し、前記点火剤に着
火して前記発熱剤を反応せしめ、同発熱剤の反応熱によ
って被破壊体の強度を劣化させるとともに、同被破壊体
内含有水分の気化によって発生した水蒸気圧によって前
記被破壊体を破壊せしめることを特徴とする脆性体の破
壊方法。
(1) Powder of exothermic agent, ignition agent,
After loading a container in which an ignition device made of a resistance heating element is enclosed, electricity is applied to the ignition device to ignite the ignition agent to cause the exothermic agent to react, and the reaction heat of the exothermic agent causes the object to be destroyed to be destroyed. A method for destroying a brittle body, the method comprising: degrading the strength of the body, and destroying the body by water vapor pressure generated by vaporization of moisture contained in the body.
(2)岩石、岩盤またはコンクリート体の如き脆性体よ
りなる被破壊体の削孔部内に、発熱剤、点火剤の粉末、
及び抵抗発熱体よりなる点火装置を封入してなる容器と
ともに、前記発熱剤の反応により気化する量以下の水を
封入した容器を装填したのち、前記点火装置に通電し、
前記点火装置に着火して前記発熱剤を反応せしめ、同発
熱剤の反応熱によって被破壊体の強度を劣化させるとと
もに、同被破壊体内含有水分及び前記容器内封入水分の
気化によって発生した水蒸気圧によって前記被破壊体を
破壊せしめることを特徴とする脆性体の破壊方法。
(2) Powder of exothermic agent, ignition agent,
and a container enclosing an igniter made of a resistance heating element, and a container enclosing water in an amount less than that which is vaporized by the reaction of the exothermic agent, and then energizing the igniter,
The ignition device is ignited to cause the exothermic agent to react, and the reaction heat of the exothermic agent deteriorates the strength of the object to be destroyed, and the water vapor pressure generated by vaporization of the moisture contained in the object and the moisture sealed in the container. A method for destroying a brittle body, characterized in that the object to be destroyed is destroyed by:
JP14324784A 1984-07-12 1984-07-12 Destruction of fragile body Pending JPS6124770A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP14324784A JPS6124770A (en) 1984-07-12 1984-07-12 Destruction of fragile body

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP14324784A JPS6124770A (en) 1984-07-12 1984-07-12 Destruction of fragile body

Publications (1)

Publication Number Publication Date
JPS6124770A true JPS6124770A (en) 1986-02-03

Family

ID=15334306

Family Applications (1)

Application Number Title Priority Date Filing Date
JP14324784A Pending JPS6124770A (en) 1984-07-12 1984-07-12 Destruction of fragile body

Country Status (1)

Country Link
JP (1) JPS6124770A (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5221046A (en) * 1975-06-30 1977-02-17 Petro Tex Chem Corp Polychloroprene sol gel compounding elastomer compositions

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5221046A (en) * 1975-06-30 1977-02-17 Petro Tex Chem Corp Polychloroprene sol gel compounding elastomer compositions

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