JPS61244543A - Polyacetylene film and manufacture thereof - Google Patents
Polyacetylene film and manufacture thereofInfo
- Publication number
- JPS61244543A JPS61244543A JP60087238A JP8723885A JPS61244543A JP S61244543 A JPS61244543 A JP S61244543A JP 60087238 A JP60087238 A JP 60087238A JP 8723885 A JP8723885 A JP 8723885A JP S61244543 A JPS61244543 A JP S61244543A
- Authority
- JP
- Japan
- Prior art keywords
- film
- polyacetylene
- filter film
- polymerization catalyst
- reaction tank
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 title claims description 51
- 229920001197 polyacetylene Polymers 0.000 title claims description 32
- 238000004519 manufacturing process Methods 0.000 title claims description 18
- 239000002685 polymerization catalyst Substances 0.000 claims description 20
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 claims description 19
- 238000006243 chemical reaction Methods 0.000 claims description 18
- 239000011248 coating agent Substances 0.000 claims description 8
- 238000000576 coating method Methods 0.000 claims description 8
- -1 polypropylene Polymers 0.000 claims description 5
- 239000004743 Polypropylene Substances 0.000 claims description 4
- 229920001155 polypropylene Polymers 0.000 claims description 4
- 239000011148 porous material Substances 0.000 claims description 4
- 239000004677 Nylon Substances 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 229920001778 nylon Polymers 0.000 claims description 3
- 150000002902 organometallic compounds Chemical class 0.000 claims description 3
- 150000003623 transition metal compounds Chemical class 0.000 claims description 3
- 239000004809 Teflon Substances 0.000 claims description 2
- 229920006362 Teflon® Polymers 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 claims description 2
- 239000010408 film Substances 0.000 description 41
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 239000007789 gas Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 239000011261 inert gas Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 3
- 239000011343 solid material Substances 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- Laminated Bodies (AREA)
- Non-Insulated Conductors (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明はドーピング剤にてドーピングを施すことにより
導電性部品となし、二次電池の電極などに用い得るアセ
チレンの重合によるアセチレン高重合体、特にフィルム
状のポリアセチレンと、その製造方法に関する。Detailed Description of the Invention (Industrial Field of Application) The present invention is an acetylene high polymer produced by polymerizing acetylene, which can be made into a conductive part by doping with a doping agent and used for electrodes of secondary batteries, etc. In particular, it relates to film-like polyacetylene and its manufacturing method.
（従来の技術）
従来、このようなフィルム状のポリアセチレンを得よう
とするときは、粉末状アセチレン高重合体を加圧成形す
る手段によるか、重合触媒溶液をガラス等の固形物表面
に塗布しておき、これにアセチレンを供’Ｔ−してやる
ことによって、当該固形物表面に繊維状の膜体を得、こ
れを剥離することでアセチレン高重合体である製品とす
る手段がとられている。(Prior art) Conventionally, when trying to obtain such film-like polyacetylene, it has been done either by pressure molding a powdered acetylene polymer or by applying a polymerization catalyst solution to the surface of a solid material such as glass. A method has been taken in which a fibrous film is obtained on the surface of the solid material by applying acetylene to the solid material, and this is peeled off to produce an acetylene high polymer product.
しかし、上記前者によるものは加圧により膜状とするも
のであるため、これを使用する際の操作が面倒であるば
かりか、機械的強度の低い成形品しか得られない難点が
あり、後者の重合触媒によるものは、前者に比し機械的
強度は大きくなるとはいえ、満足すべき強度のものどす
ることはできない。However, since the former method described above is made into a film shape by applying pressure, it is not only difficult to operate, but also has the disadvantage that only molded products with low mechanical strength can be obtained. Although those using polymerization catalysts have higher mechanical strength than the former, they cannot provide satisfactory strength.
また１−記後者のごとき製造方法によるときは。In addition, when using the manufacturing method described in 1-2.
カラス容器の内壁面を使用することになるので。Because we will be using the inner wall of the crow container.
これに伺着する重合触媒の層厚が不均一となり、従って
これにより得られるアセチレン高重合体の膜厚が不均一
となってしまうだけでなく、大きなポリアセチレンフィ
ルムを得ることが困難であり、しかも連続的な製造にも
不適当で、量産に向かないなど各種の欠陥が、その製品
自体と製造方法とに存している。This not only makes the layer thickness of the polymerization catalyst that arrives non-uniform, resulting in non-uniform film thickness of the resulting acetylene polymer, but also makes it difficult to obtain a large polyacetylene film. Various defects exist in the product itself and the manufacturing method, such as being unsuitable for continuous manufacturing and not suitable for mass production.
（発明が解決しようとする問題点）
本願第１発明は、」―記従来の難点に鑑み、これまでの
ようにポリアセチレンだけでフィルム状製品を得ようと
するのではなく、通気性のある薄いフィルターフィルム
を用い、これを裏打的な基材となし、ポーラスな当該基
材にポリ、アセチレンシートを一体的に生成積層させて
やることで、製造上、使用」−の取扱いが容易で、充分
な機械的強度をもたせようとするものである。(Problems to be Solved by the Invention) The first invention of the present application, in view of the conventional difficulties, does not attempt to obtain a film-like product using only polyacetylene as in the past, but instead attempts to obtain a film-like product using only polyacetylene, a thin film with breathable properties. By using a filter film as a backing base material and integrally laminating poly and acetylene sheets on the porous base material, it is easy to handle and sufficient for manufacturing and use. The aim is to provide high mechanical strength.
そして第２発明では、このようなポリアセチレンフィル
ムを製造するに際し、所望容器である反応槽に前掲フィ
ルターフィルムを内装しておき、これに重合触媒溶液を
コーテングした後、アセチレンガスを反応槽に供与して
やることで、コーテングの均一厚化をはかり、これによ
って均一厚の製品が得られるようにし、しかもフィルタ
ーフィルムを回動させたり巻取るといった機構を採択す
ることで、可成り大きな製品を、連続的に生産し得るよ
うにするのが、その目的である。In the second invention, when producing such a polyacetylene film, the above-mentioned filter film is placed inside a reaction tank, which is a desired container, and after coating the film with a polymerization catalyst solution, acetylene gas is supplied to the reaction tank. This makes it possible to make the coating uniform in thickness, thereby making it possible to obtain products with uniform thickness.In addition, by adopting a mechanism that rotates and winds up the filter film, it is possible to continuously produce fairly large products. Its purpose is to enable production.
（問題点を解決するための手段）
本願は前記目的を達成するため、第１発明ではフィルタ
ーフィルムの少なくとも一面に、アセチレンガスの重合
により生成されたポリアセチレンシートを、一体に形成
してなるポリアセチレンフィルムを提供しようとしてお
り、第２発明では、フィルターフィルムを不活性雰囲気
にあり低温に保持される反応槽内に配装し、このフィル
ターフィルムの一面または両面に遷移金属化合物と有機
金属化合物とからなる重合触媒をコーティングした後、
当該反応槽内にアセチレンを供給するようにしたポリア
セチレンシートの製造方法を提供しようとしている。(Means for Solving the Problems) In order to achieve the above object, the present invention provides a polyacetylene film in which a polyacetylene sheet produced by polymerization of acetylene gas is integrally formed on at least one surface of a filter film. In the second invention, a filter film is arranged in a reaction tank kept in an inert atmosphere and at a low temperature, and one or both surfaces of the filter film are made of a transition metal compound and an organometallic compound. After coating with polymerization catalyst,
The present invention aims to provide a method for producing a polyacetylene sheet in which acetylene is supplied into the reaction tank.
（作 用）
フィルターフィルムにアセチレンが重合生成により一体
に形成されているから、当該一体化の程度すなわち接着
強度も大きく、当該フィルターフィルムによりポリアセ
チレンシートが裏打ちされているので、その機械的強度
も大きくなり全体としてもフィルターフィルムの使用に
より大きな表面積を確保することができることになり電
極としても望ましい特性をもたせることができる。(Function) Since the filter film is integrally formed with acetylene by polymerization, the degree of integration, that is, the adhesive strength, is also high, and since the polyacetylene sheet is backed by the filter film, its mechanical strength is also high. As a whole, by using the filter film, a large surface area can be secured, and desirable characteristics can be provided as an electrode.
さらに製造方法にあっては、フィルターフィルムに重合
触媒が、浸漬その他所望の手段によって容易に付着し、
しかも同触媒コーティングは均一厚に形成され、この結
果、ポリアセチレンシートも均一な厚さに生成でき、こ
の際フィルターフィルムに対するポリアセチレンシート
の接着力も充分なものが得られる。Furthermore, in the manufacturing method, the polymerization catalyst is easily attached to the filter film by dipping or other desired means,
Moreover, the catalyst coating is formed to have a uniform thickness, and as a result, the polyacetylene sheet can also be formed to have a uniform thickness, and at this time, sufficient adhesive strength of the polyacetylene sheet to the filter film can be obtained.
（実 施 例）
本発明を図示によって詳記すれば、本願第１発明に係る
ポリアセチレンフィルムは、第１図に示すようにポリプ
ロピレン、ナイロン、ポリエチレン、テフロン、ガラス
等により形成され、多数の開成通孔１ａ・・・・・・に
よって通気性をもたせたフィルターフィルム１の両面ま
たは一面に、アセチレンガスの重合により生成されたポ
リアセチレンシート２を積層するようにしたものである
。(Example) To describe the present invention in detail with illustrations, the polyacetylene film according to the first invention of the present application is made of polypropylene, nylon, polyethylene, Teflon, glass, etc., as shown in FIG. A polyacetylene sheet 2 produced by polymerization of acetylene gas is laminated on both sides or one side of a filter film 1 which is made breathable through holes 1a.
ここで、上記フィルターフィルムｌとしては、例えば厚
さ１００μｍ程度、孔径０．２〜０．４色ｍ程度のもの
を用いることができ、製品の総厚としては０．０５關程
度以上にすることが、機械的強度を可成り向１−できて
望ましいが、２．０ｍｍ以上になると導電性部品として
のポリアセチレンの特性が充分に生かされ難いこととな
る。Here, as the above-mentioned filter film l, for example, a film with a thickness of about 100 μm and a pore diameter of about 0.2 to 0.4 color m can be used, and the total thickness of the product should be about 0.05 μm or more. However, if the thickness exceeds 2.0 mm, it will be difficult to fully utilize the properties of polyacetylene as a conductive component.
次に上記製品の製造方法に係る第２発明につき詳記する
と、同法の実施には第２図に示すごとき装置を用いるこ
とができる。Next, the second invention relating to the method for manufacturing the above-mentioned product will be described in detail. For carrying out the method, an apparatus as shown in FIG. 2 can be used.
同装置は、低温恒温槽３に反応槽４が内設され、さらに
反応槽２内には、上下配置により駆動プーリ５ａと従動
プーリ５ｂとによるコーテング用回動装置５が設けられ
ており、両プーリ５ａ、５ｂにはエンドレスとしたフィ
ルターフィルム１が、着脱操作可能なるように間装でき
るようになっており、従って当該操作ができるように低
温恒温槽３と反応層４とには、図示しない開閉自在なる
操作口が適所に設けられている。This apparatus includes a reaction tank 4 installed in a low-temperature thermostat 3, and a coating rotation device 5 with a driving pulley 5a and a driven pulley 5b arranged vertically in the reaction tank 2. An endless filter film 1 is interposed between the pulleys 5a and 5b so that it can be attached and detached.Therefore, to enable this operation, a low-temperature constant temperature bath 3 and a reaction layer 4 (not shown) are attached to the pulleys 5a and 5b. An operation port that can be opened and closed is provided at a suitable location.
さらに、」−記反応槽４にはアセチレン導入配管６、不
活性ガス導入配管７、重合触媒導入配管８そして損気配
管９が連結されており、これらの配管６．７．８．９、
には夫々開閉コツクロａ、７ａ、８ａ、９ａが介接され
ている。Further, an acetylene introduction pipe 6, an inert gas introduction pipe 7, a polymerization catalyst introduction pipe 8, and a gas loss pipe 9 are connected to the reaction tank 4, and these pipes 6.7.8.9,
Opening/closing locks a, 7a, 8a, and 9a are respectively interposed in the opening/closing holes.
そこで、−１−記装置を用いて本発明の方法を実施する
には、開閉コツクロａ、９ａを開いて、重合触媒導入配
管８から遷移金属化合物と有機金属化合物とからなる重
合触媒Ａを供給して、反応槽４に当該触媒Ａを所要量だ
け収納貯溜するが、この際予め、前記のようにコーテン
グ用回動装置５にフィルターフィルム１をセットしてお
くことになる。Therefore, in order to carry out the method of the present invention using the apparatus described in -1-, the opening/closing mechanism a, 9a is opened, and the polymerization catalyst A consisting of a transition metal compound and an organometallic compound is supplied from the polymerization catalyst introduction pipe 8. Then, the required amount of the catalyst A is stored and stored in the reaction tank 4, but at this time, the filter film 1 is set in advance on the coating rotating device 5 as described above.
次に開閉コック７ａ、９ａの開成により、ＮＺ等の不活
性ガスを不活性ガス導入配管７から反応槽４内に送り込
み、槽内を不活性ガス雰囲気となし、低温恒温槽３によ
って前記槽内の重合触媒を一７８℃に冷却する。Next, by opening the opening/closing cocks 7a and 9a, an inert gas such as NZ is sent into the reaction tank 4 from the inert gas introduction pipe 7 to create an inert gas atmosphere in the tank, and the low-temperature thermostat 3 The polymerization catalyst is cooled to -78°C.
ここで重合触媒には、トリエチルアルミニウム３、軸文
、チタニウムテトラブトキサイ白、９＋ｎＱ、トルエン
１５．１ ｍ９．を混合したものが使用される。Here, the polymerization catalyst includes triethylaluminum 3, cylindrical, titanium tetrabutoxy white, 9+nQ, and toluene 15.1 m9. A mixture of these is used.
次に、前記コーテング用回動装置５を稼動させながら、
開閉コック８ａを開いてアセチレン導入配管６から反応
槽４内にアセチレンガスを導入するのであり、このとき
、フィルターフィルム１は−［貯溜されている重合触媒
Ａに浸漬された後に、１−昇するから、同フィルムｌの
この場合両面が次々と重合触媒によってコーテング処理
され、従って当該重合触媒のコーテング箇所にアセチレ
ンガスの重合によるポリアセチレンシート２が生成積層
されることとなる。Next, while operating the coating rotation device 5,
The opening/closing cock 8a is opened to introduce acetylene gas into the reaction tank 4 from the acetylene introduction pipe 6. At this time, the filter film 1 is immersed in the stored polymerization catalyst A, and then rises by 1. In this case, both sides of the film 1 are successively coated with a polymerization catalyst, and therefore, a polyacetylene sheet 2 is produced and laminated by polymerization of acetylene gas at the location coated with the polymerization catalyst.
このようにして、エンドレスとしたフィルターフィルム
１の前面にわたってポリアセチレンシート２が形成され
たならば、これをトルエンで洗浄し、真空乾燥して製品
とする。Once the polyacetylene sheet 2 is formed over the front surface of the endless filter film 1 in this way, it is washed with toluene and vacuum dried to form a product.
ここで、さらに具体例を示せば、前記のように重合触媒
を一７８°Ｃに冷却し、この中に厚さ１１００ｐ、副成
通孔１ａ・・・・・・に孔径０．４ ｐＬｍのポリプロ
ピレンによるフィルターフィルム１を浸漬して引き上げ
、この直後にアセチレンガスを反応層４に導入した。Here, to give a more specific example, the polymerization catalyst is cooled to -78°C as described above, and a pore diameter of 0.4 pLm is placed in the secondary formation hole 1a with a thickness of 1100 p. A filter film 1 made of polypropylene was immersed and pulled up, and immediately after this, acetylene gas was introduced into the reaction layer 4.
これにより、当該ポリプロピレンの両面にポリアセチレ
ンの膜が生成されたので、これをトルエンで洗浄後、真
空乾燥し総厚３００ｐＬｍのポリアセチレンフィルムを
得た。As a result, a polyacetylene film was formed on both sides of the polypropylene, which was washed with toluene and vacuum dried to obtain a polyacetylene film with a total thickness of 300 pLm.
また厚さ１００ μｍ、孔径０．２ Ｂｍのナイロンに
よるフィルターフィルムを用いて、Ｌ記具体例と同じ要
領で製品を得たが、何れも形成されたポリアセチレンシ
ートは充分にフィルターフィルムに接着し、機械的強度
もあって、容易には損じないものであった。In addition, a product was obtained using a nylon filter film with a thickness of 100 μm and a pore size of 0.2 Bm in the same manner as in Example L, but the polyacetylene sheet formed in both cases adhered well to the filter film, It also had mechanical strength and was not easily damaged.
（発明の効果）
第１発明のポリアセチレンフィルムによるときは、多孔
なフィルターフィルムにポリアセチレンシー）・が密着
して生成されるから、容易に剥離することなく、機械的
にも強いので、その製造工程」二も、使用取扱上も至便
である。(Effect of the invention) When using the polyacetylene film of the first invention, the polyacetylene film) is produced in close contact with the porous filter film, so it does not peel off easily and is mechanically strong, so the manufacturing process thereof ” 2. It is also very convenient to use and handle.
また第２発明の製造方法によれば、均一厚のポリアセチ
レンフィルムを製造でき、大面積のものを連続的に製造
することも可能となり、上記第１発明のものを確実に量
産化できることとなる。Further, according to the manufacturing method of the second invention, it is possible to manufacture a polyacetylene film of uniform thickness, and it is also possible to continuously manufacture a film with a large area, thereby making it possible to reliably mass-produce the film of the first invention.
尚フィルターフィルムに重合触媒をコーテングするには
、前記実施例に限ることなく、反応槽内にスプレー装置
を設けて、当該触媒を吹き伺けるようにしてもよい。In addition, in order to coat the filter film with a polymerization catalyst, the method is not limited to the above embodiments, and a spray device may be provided in the reaction tank to spray the catalyst.
第１図の（ａ） （ｂ）は第１発明のポリアセチレン
フィルムを示す異種例の断面図、第２図は第２発明の方
法を実施するのに用い得る製造装置を示した縦断正面説
明図である。
１・・・・・・フィルターフィルム
２・・・・・・ポリアセチレンシート
４・・・・・・反応槽
Ａ・・・・・・重合触媒
代理人 弁理士 斎 藤 義雄
第１図
（′Ｌ） （ｂ）
第２図FIGS. 1(a) and 1(b) are sectional views of different examples of the polyacetylene film of the first invention, and FIG. 2 is a longitudinal sectional front view showing a manufacturing apparatus that can be used to carry out the method of the second invention. It is. 1... Filter film 2... Polyacetylene sheet 4... Reaction tank A... Polymerization catalyst agent Patent attorney Yoshio Saifuji Figure 1 ('L) (b) Figure 2
Claims (5)
レンンガスの重合により生成されたポリアセチレンシー
トを、一体に形成したことを特徴とするポリアセチレン
フィルム。(1) A polyacetylene film characterized in that a polyacetylene sheet produced by polymerizing acetylene gas is integrally formed on at least one surface of the filter film.
ロン、テフロン、ガラスが用いられて総厚が０．０５ｍ
ｍ〜２．０ｍｍである特許請求の範囲第１項記載のポリ
アセチレンフィルム。(2) The filter film uses polypropylene, nylon, Teflon, and glass, and has a total thickness of 0.05 m.
The polyacetylene film according to claim 1, which has a diameter of m to 2.0 mm.
径０．２μｍ〜０．４μｍ程度である特許請求の範囲第
１項または第２項記載のポリアセチレンフィルム。(3) The polyacetylene film according to claim 1 or 2, wherein the filter film has a thickness of about 100 μm and a pore diameter of about 0.2 μm to 0.4 μm.
に保持されている反応槽内に配装し、このフィルターフ
ィルムの一面またほ両面に、遷移金属化合物と有機金属
化合物とからなる重合触媒をコーティングした後、当該
反応槽内にアセチレンを供給するようにしたことを特徴
とするポリアセチレンフィルムの製造方法。(4) A filter film is placed in a reaction tank maintained at a low temperature in an inert atmosphere, and one or both sides of the filter film are coated with a polymerization catalyst consisting of a transition metal compound and an organometallic compound. A method for producing a polyacetylene film, characterized in that acetylene is supplied into the reaction tank after the reaction.
合触媒中に、フィルターフィルムを回動させて浸漬後、
引き上げるようにして行う特許請求の範囲第１項記載の
ポリアセチレンフィルムの製造方法。(5) Coating with the polymerization catalyst is done by rotating the filter film and immersing it in the polymerization catalyst provided in the reaction tank.
The method for producing a polyacetylene film according to claim 1, which is carried out by pulling it up.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60087238A JPS61244543A (en) | 1985-04-23 | 1985-04-23 | Polyacetylene film and manufacture thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60087238A JPS61244543A (en) | 1985-04-23 | 1985-04-23 | Polyacetylene film and manufacture thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS61244543A true JPS61244543A (en) | 1986-10-30 |
Family
ID=13909241
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60087238A Pending JPS61244543A (en) | 1985-04-23 | 1985-04-23 | Polyacetylene film and manufacture thereof |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61244543A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59189107A (en) * | 1983-04-12 | 1984-10-26 | Furukawa Electric Co Ltd:The | Production of thick polyacetylene film adhering to substrate |
| JPS59189106A (en) * | 1983-04-12 | 1984-10-26 | Furukawa Electric Co Ltd:The | Formation of polyacetylene film adhering to substrate |
-
1985
- 1985-04-23 JP JP60087238A patent/JPS61244543A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59189107A (en) * | 1983-04-12 | 1984-10-26 | Furukawa Electric Co Ltd:The | Production of thick polyacetylene film adhering to substrate |
| JPS59189106A (en) * | 1983-04-12 | 1984-10-26 | Furukawa Electric Co Ltd:The | Formation of polyacetylene film adhering to substrate |
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