JPS6124364B2 - - Google Patents

Info

Publication number
JPS6124364B2
JPS6124364B2 JP6359681A JP6359681A JPS6124364B2 JP S6124364 B2 JPS6124364 B2 JP S6124364B2 JP 6359681 A JP6359681 A JP 6359681A JP 6359681 A JP6359681 A JP 6359681A JP S6124364 B2 JPS6124364 B2 JP S6124364B2
Authority
JP
Japan
Prior art keywords
cineole
repellent
beetles
trees
adult
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP6359681A
Other languages
Japanese (ja)
Other versions
JPS57179105A (en
Inventor
Akira Ueno
Kenji Nagata
Michiaki Kawasaki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Takasago International Corp
Sankei Chemical Co Ltd
Original Assignee
Takasago International Corp
Sankei Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Takasago International Corp, Sankei Chemical Co Ltd filed Critical Takasago International Corp
Priority to JP6359681A priority Critical patent/JPS57179105A/en
Publication of JPS57179105A publication Critical patent/JPS57179105A/en
Publication of JPS6124364B2 publication Critical patent/JPS6124364B2/ja
Granted legal-status Critical Current

Links

Description

【発明の詳細な説明】[Detailed description of the invention]

本発明は、1,8−シネオールを有効成分とし
て含有する害虫忌避剤に関する。 植物に対し、各種の虫が害を及ぼすものである
が、なかでも、カミキリムシ類は、ブドウ、ミカ
ン等の果樹、松、杉等の樹木、桑などに加害し、
農業、林業、蚕業に大きな被害を与える害虫であ
る。カミキリムシ類の加害様式としては、主にブ
ドウのブドウトラカミキリ、桑のクワカミキリ、
キボシカミキリ、杉のスギカミキリなどの様に幼
虫が木部を加害するものであるが、マツノマダラ
カミキリの様に成虫が後食時に病原体を媒介する
例もある。 カミキリムシ類の防除方法としては、後食防止
あるいは産卵防止を目的とした成虫防除法と、被
害防止を目的とした幼虫防除法とがあり、前者に
はフエニトロチオン(MEP)、カーバリル
(NAC)などの殺虫剤の乳剤、水和剤が、後者に
はフエニトロチオン(MEP)、フエンチオエート
(PAP)、フエンチオン(MPP)などにエチレン
ブロマイド(EDB)を混合した混合殺虫剤の乳
剤または油剤が使用されている。 しかし、この様な農薬を効果的に使用するには
多くの問題点がある。すなわち、成虫を防除する
には、一時に広範囲に農薬を散布しなければなら
ず、またカミキリムシ類は成虫の発生期間が1〜
3ケ月と長いため、その間に数回農薬を散布しな
ければならない。この様に広範囲、多数回の農薬
散布は残留農薬により環境汚染、天敵類を含む生
物相の覚乱を引き起すおそれがある。また幼虫防
除には通常の10〜100倍という高農度の散布液を
使用するため、散布従事者が中毒事故を起こす例
も少くない。 そこで、本発明者らは、この様な問題を回避で
きる防除法を提供すべく鋭意研究を行つた結果、
香料として用いられているオイゲノール、ゲラニ
オール、アネトール、フエニルエチルブチレート
等の化合物がカミキリムシ類成虫に対して誘引作
用を示すのに対し、意外にも、1,8−シネオー
ルが強い忌避作用を示し、カミキリムシ類成虫の
行動を制御し、後食防止、産卵防止に著るしい効
果を示すことを見出し、本発明を完成した。 本発明の害虫忌避剤の有効成分である1,8−
シネオールは、天然の植物界に広く存在し、フト
モモ科、クスノキ科の植物の精油中に多量に含有
されている。特にユーカリ油の主成分であり、こ
れから蒸留等によつて容易に分離される。このも
のはシヨウノウ様のにおいと刺戟的味のある無色
の油状液体である。 本発明の忌避剤は、1,8−シネオール単独と
その構成とすることもできるが、目的によつて、
1,8−シネオールを適当な溶媒に溶解するか、
あるいは適当な固体担体に吸着あるいは混合し、
更に必要なれば、界面活性剤、分散剤等の補助剤
を添加して、油剤、乳剤、水和剤、粉剤、噴霧
剤、エアゾールなどの剤型とすることができる。 上記製剤化に使用する溶剤としては、エチルア
ルコール、プロピレングリコール等のアルコール
類、アセトン、メチルエチルケトン等のケトン
類、ヘキサン、石油ベンジン等の脂肪族炭化水素
類、ベンゼン、キシレン等の芳香族炭化水素類等
が適当である。固体担体としては、木粉、活性
炭、カオリン、ベントナイト、酸性白土、タル
ク、アルミナ等が用いられる。乳化剤、分散剤と
しては、ポリオキシエチレンアルキルエーテル、
ポリオキシエチレンアルキルアリルエーテル、ポ
リオキシエチレン脂肪酸エステル、脂肪酸モノグ
リセリド、脂肪酸グリコールエステル、ソルビタ
ン脂肪酸エステル、ポリオキシエチレンソルビタ
ン脂肪酸エステル、ヒマシ油硫酸塩のほか、カゼ
イン、アラビアガム等の植物性天然樹脂等がひろ
く使用しうる。 本発明の忌避剤を使用して、カミキリムシの防
除を行うには、保護しようとする果樹、樹木等の
まわりに1,8−シネオールのにおいを漂わせ、
後食、産卵のために飛来するカミキリムシを忌避
させる。その具体的方法としては、1,8−シネ
オールそれ自体、または適当な溶媒で希釈した液
をフアイバーボード、ロールコツトン、脱脂綿の
ごとき担体にしみこませるか、または適当な穴を
あけた容器に封入したものを、保護しようとする
果樹、樹木の回りに適宜配置し、徐々に1,8−
シネオールのにおいを揮散させる方法、あるい
は、施行状況に応じて、液状、粉状、粒状にした
ものを果樹、樹木の周囲に、あるいは場合によつ
ては直接その果樹、樹木に散布する方法等が例示
される。 本発明の忌避剤は他のカミキリムシ防除剤と併
用することもできる。 次に本発明を実施例および試験例によつて詳し
く説明する。 実施例 1 1,8−シネオール25gを縦6cm、横6cm、厚
さ1cmのフアイバーボード1枚に含浸させ、忌避
剤含浸フアイバーボードをつくつた。 実施例 2 1,8−シネオールとナタネ白絞油重量比で
1:1に混合した液8gを、直径1cm、長さ10cm
のロールコツトンに含浸させ、忌避剤含浸ロール
コツトンをつくつた。 実施例 3 1,8−シネオール50部、乳化剤として「ハイ
マール362H」(松本油脂製薬株式会社製品)5
部、流動パラフイン45部を混合撹拌して忌避剤の
乳剤をつくつた。 試験例 1 実施例1によつて得た1,8−シネオール含浸
フアイバーボードを、松林の中に、松1本当り3
枚の割合で、高さ2〜4mの位置に吊し、マツノ
マダラカミキリ成虫に対する後食防止効果を試験
した。処置1ケ月後に、各試験区より赤松5本に
つき新梢部の後食個所数、後食長を調査したとこ
ろ次の第1表に示す結果を得た。
The present invention relates to a pest repellent containing 1,8-cineole as an active ingredient. Various insects cause harm to plants, but among them, longhorn beetles cause damage to fruit trees such as grapes and mandarin oranges, trees such as pines and cedar, and mulberry trees.
It is a pest that causes great damage to agriculture, forestry, and silkworm industry. The main types of damage caused by longhorn beetles are the longhorn beetles on grapes, the mulberry longhorn beetles on mulberries, and
The larvae damage the xylem, such as the Japanese longhorn beetles and the Japanese cedar longhorn beetles, but there are also cases, such as the pine beetles, in which the adults transmit pathogens during their afterfeeding. Methods for controlling longhorn beetles include adult control methods aimed at preventing after-feeding or egg-laying, and larval control methods aimed at preventing damage. Insecticide emulsions and wettable powders are used, and the latter are mixed insecticide emulsions or oils that are a mixture of fenitrothion (MEP), fenthioate (PAP), fenthion (MPP), and ethylene bromide (EDB). However, there are many problems in using such pesticides effectively. In other words, in order to control adult insects, pesticides must be sprayed over a wide area at once, and for longhorn beetles, the adult generation period is 1 to 10 minutes.
Because it lasts for three months, pesticides must be sprayed several times during that time. Spraying pesticides over a wide area and many times in this manner may cause environmental pollution due to residual pesticides and disturbance of biota including natural enemies. In addition, spraying liquid with a high agricultural concentration 10 to 100 times higher than usual is used to control larvae, so there are many cases of poisoning among sprayers. Therefore, the present inventors conducted intensive research to provide a pest control method that can avoid such problems.
Compounds used as fragrances such as eugenol, geraniol, anethole, and phenylethyl butyrate have an attractive effect on adult longhorn beetles, but surprisingly, 1,8-cineole has a strong repellent effect. The present invention was completed based on the discovery that the present invention controls the behavior of adult longhorn beetles and exhibits remarkable effects on preventing afterfeeding and spawning. 1,8- which is the active ingredient of the pest repellent of the present invention
Cineole exists widely in the natural plant world, and is contained in large amounts in the essential oils of plants of the Myrtaceae and Lauraceae families. In particular, it is the main component of eucalyptus oil, and is easily separated from it by distillation or the like. It is a colorless oily liquid with a mustard odor and a pungent taste. The repellent of the present invention can be composed of 1,8-cineole alone, but depending on the purpose,
Dissolve 1,8-cineole in a suitable solvent, or
Or adsorbed or mixed on a suitable solid carrier,
Furthermore, if necessary, auxiliary agents such as surfactants and dispersants may be added to form dosage forms such as oils, emulsions, wettable powders, powders, sprays, and aerosols. Solvents used in the above formulation include alcohols such as ethyl alcohol and propylene glycol, ketones such as acetone and methyl ethyl ketone, aliphatic hydrocarbons such as hexane and petroleum benzene, and aromatic hydrocarbons such as benzene and xylene. etc. are appropriate. As the solid carrier, wood flour, activated carbon, kaolin, bentonite, acid clay, talc, alumina, etc. are used. As emulsifiers and dispersants, polyoxyethylene alkyl ether,
In addition to polyoxyethylene alkyl allyl ether, polyoxyethylene fatty acid ester, fatty acid monoglyceride, fatty acid glycol ester, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, castor oil sulfate, vegetable natural resins such as casein and gum arabic, etc. Can be used widely. To control longhorn beetles using the repellent of the present invention, place the odor of 1,8-cineole around the fruit trees, trees, etc. to be protected;
It repels longhorn beetles that fly in to eat and lay eggs. The specific method is to impregnate 1,8-cineole itself or a solution diluted with an appropriate solvent into a carrier such as fiberboard, roll cotton, or absorbent cotton, or to enclose it in a container with appropriate holes. Arrange them appropriately around the fruit trees and trees you want to protect, and gradually spread the 1,8-
There is a method to volatilize the smell of cineole, or a method to spray liquid, powder, or granular material around fruit trees and trees, or in some cases directly on the fruit trees and trees, depending on the implementation situation. Illustrated. The repellent of the present invention can also be used in combination with other longhorn beetle control agents. Next, the present invention will be explained in detail using Examples and Test Examples. Example 1 A repellent-impregnated fiberboard was prepared by impregnating 25 g of 1,8-cineole into a fiberboard measuring 6cm long, 6cm wide and 1cm thick. Example 2 8 g of a mixture of 1,8-cineole and rapeseed oil in a weight ratio of 1:1 was added to a tube with a diameter of 1 cm and a length of 10 cm.
The repellent-impregnated rolls were made by impregnating them with the repellent. Example 3 50 parts of 1,8-cineole, "Himar 362H" (manufactured by Matsumoto Yushi Pharmaceutical Co., Ltd.) as an emulsifier 5
A repellent emulsion was prepared by mixing and stirring 45 parts of liquid paraffin and 45 parts of liquid paraffin. Test Example 1 The 1,8-cineole-impregnated fiberboard obtained in Example 1 was placed in a pine forest at a rate of 3 ml per pine tree.
The suspension was hung at a height of 2 to 4 m, and the effect of preventing afterfeeding on adult beetles was tested. One month after the treatment, the number of afterfeeding sites and the length of afterfeeding in the new shoots of five red pine trees from each test plot were investigated, and the results shown in Table 1 below were obtained.

【表】 上の表より、1,8−シネオール含浸フアイバ
ーボードが、マツノマダラカミキリに対し強い忌
避作用を有することを示し、顕著な後食防止効果
がみられた。 試験例 2 実施例2によつて得た1,8−シネオール含浸
ロールコツトンを、桑1株当り2本の割合で桑株
の基部近くに吊し、キボシカミキリ成虫に対する
忌避作用、産卵防止効果を試験した。処置10日後
に、1処置区より桑株5株を抽出し、キボシカミ
キリの産卵個所数を調査し、次の第2表に示す結
果を得た。
[Table] The above table shows that the 1,8-cineole-impregnated fiberboard has a strong repellent effect against the pine beetle, and a remarkable effect of preventing after-eating was observed. Test Example 2 The 1,8-cineole-impregnated roll cotton obtained in Example 2 was hung near the base of a mulberry plant at a ratio of 2 per mulberry plant, and the effect of repelling adult longhorn beetles and preventing spawning was observed. was tested. 10 days after the treatment, five mulberry plants were extracted from one treatment area and the number of egg-laying locations of the long-eared longhorn beetles was investigated, and the results shown in Table 2 below were obtained.

【表】 *対照区には市販のフエニトロチオン白
色塗布剤(山本農薬株式会社製〓ガツト
サイド〓)を原液のまま桑株に塗布した。
上の表より、1,8−シネオール含浸ロールコ
ツトンがキボシカミキリに対し、強い忌避作用を
有することを示し、顕著な産卵防止効果がみられ
た。 試験例 3 実施例3によつて得た1,8−シネオールの乳
剤を、水にて5倍に希釈し、ミカンの主幹部に散
布することによるゴマダラカミキリ成虫に対する
忌避作用、産卵防止効果を検討した。乳剤を調製
し、ミカンの主幹部に散布後、10日後に試験区中
に生息するゴマダラカミキリ成虫数、及び試験区
中のミカン5本につき産卵個所数を調査したとこ
ろ次の第3表に示す結果を得た。
[Table] *For the control plot, a commercially available fenitrothion white coating agent (Gatsuto Side, manufactured by Yamamoto Nohyaku Co., Ltd.) was applied as a undiluted solution to the mulberry plants.
The above table shows that the 1,8-cineole-impregnated roll cotton has a strong repellent effect on the yellow-crowned beetle, and a remarkable effect of preventing egg-laying was observed. Test Example 3 The 1,8-cineole emulsion obtained in Example 3 was diluted 5 times with water and sprayed on the main trunk of mandarin oranges to examine its repellent effect on adult longhorn beetles and the effect of preventing spawning. . After preparing the emulsion and spraying it on the main stems of mandarin oranges, we investigated the number of adult beetles living in the test plot and the number of spawning sites for each of the five mandarin oranges in the test plot 10 days later.The results are shown in Table 3 below. I got it.

【表】 *対照区には市販のフエニトロチオン白
色塗布剤(山本農薬株式会社〓ガツトサ
イド〓)を使用した。
上の表より、1,8−シネオール乳剤が、ゴマ
ダラカミキリに対し、強い忌避作用を有すること
を示し、顕著な産卵防止効果がみられた。
[Table] *For the control plot, a commercially available fenitrothion white coating agent (Yamamoto Nohaku Co., Ltd., Gatsutoside) was used.
From the above table, it was shown that the 1,8-cineole emulsion had a strong repellent effect on the long-eared beetles, and a remarkable effect of preventing egg-laying was observed.

Claims (1)

【特許請求の範囲】[Claims] 1 1,8−シネオールを有効成分として含有す
ることを特徴とする害虫忌避剤。
1. An insect repellent characterized by containing 1,8-cineole as an active ingredient.
JP6359681A 1981-04-27 1981-04-27 Vermin repellent Granted JPS57179105A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6359681A JPS57179105A (en) 1981-04-27 1981-04-27 Vermin repellent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6359681A JPS57179105A (en) 1981-04-27 1981-04-27 Vermin repellent

Publications (2)

Publication Number Publication Date
JPS57179105A JPS57179105A (en) 1982-11-04
JPS6124364B2 true JPS6124364B2 (en) 1986-06-10

Family

ID=13233803

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6359681A Granted JPS57179105A (en) 1981-04-27 1981-04-27 Vermin repellent

Country Status (1)

Country Link
JP (1) JPS57179105A (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1068176C (en) * 1996-05-20 2001-07-11 谢建华 Long effective eating-proof pest repellant and its prepn. method
WO1999009826A1 (en) * 1997-08-21 1999-03-04 Kabushiki Kaisha Nihon Tekuma Treatment for surface treatment and cleaning, and wooden building material impregnated with said treatment
FR2802773B1 (en) * 1999-12-23 2003-01-03 Centre Nat Rech Scient USE OF WOOD WASTE OR EXTRACTS AS AN INSECTICIDE
CN112825855B (en) * 2021-01-08 2021-11-23 检科智创(北京)生物科技有限公司 Potato beetle repellent and application thereof

Also Published As

Publication number Publication date
JPS57179105A (en) 1982-11-04

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