JPS61235115A - Manufacture of reinforcing member having protrusion on surface thereof - Google Patents

Manufacture of reinforcing member having protrusion on surface thereof

Info

Publication number
JPS61235115A
JPS61235115A JP7670085A JP7670085A JPS61235115A JP S61235115 A JPS61235115 A JP S61235115A JP 7670085 A JP7670085 A JP 7670085A JP 7670085 A JP7670085 A JP 7670085A JP S61235115 A JPS61235115 A JP S61235115A
Authority
JP
Japan
Prior art keywords
reinforcing member
resin
reinforcing
protrusions
compression
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP7670085A
Other languages
Japanese (ja)
Inventor
Noribumi Minowa
美濃和 則文
Takashi Nishimoto
敬 西本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DAINIPPON GLASS KOGYO KK
Shimizu Construction Co Ltd
Dainihon Glass Industry Co Ltd
Original Assignee
DAINIPPON GLASS KOGYO KK
Shimizu Construction Co Ltd
Dainihon Glass Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DAINIPPON GLASS KOGYO KK, Shimizu Construction Co Ltd, Dainihon Glass Industry Co Ltd filed Critical DAINIPPON GLASS KOGYO KK
Priority to JP7670085A priority Critical patent/JPS61235115A/en
Publication of JPS61235115A publication Critical patent/JPS61235115A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To form protrusions on the surface of the reinforcing member effectively by a method wherein synthetic resin forming material, including continuous reinforcing fibers, is introduced into a compression forming mold to form the reinforcing member having protrusions on the surface thereof by compression forming, thereafter, the compression forming mold is released to pull out the reinforcing member while this operation is repeated. CONSTITUTION:The continuous reinforcing fibers 1 are introduced into the tank 2 of uncured thermosetting resin to impregnate the resin into the fibers. The amount of impregnated resin is regulated by a squeeze 4, the squeezed resin is introduced into the compression forming mold 6 together with the reinforcing fibers 3 if necessary and compression molding is effected whereby the reinforcing member, having protrusions on the surface thereof, is formed. The reinforcing member, formed by compression, is pulled out by a take-off device 7 as the compression forming mold is being opened and the resin is cured, thereafter, the member is cut by a cutter 8 into a required length. In case the reinforcing member, formed by compression forming, is pulled out of the compression forming mold 6, the resin impregnated reinforcing fibers, which are continuous to the formed reinforcing member, are introduced into the forming mold 6, therefore, continuous compression forming may be effected by repeating above- described operations.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、表面に突起を有する合成樹脂製補強部材を連
続的に製造する方法に関するものである。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a method for continuously manufacturing a synthetic resin reinforcing member having projections on its surface.

〔従来の技術〕[Conventional technology]

トンネル内の岩盤を固定する等の目的のために、岩盤に
穴を穿ち、ロックボルトと呼ばれる補強部材を埋め込む
ことは知られている。鋼製のロックボルトは、トンネル
内等の高温多湿となシやすい雰囲気において、腐蝕し、
強度や剛性が低下することから、耐蝕性で作業性の良い
・合成樹脂製のロックボルトが注目されている。
It is known to drill holes in rock and embed reinforcing members called rock bolts in order to secure the rock in a tunnel. Steel rock bolts corrode in high-temperature, humid environments such as inside tunnels, and corrode.
As strength and rigidity decrease, synthetic resin rock bolts are attracting attention as they are corrosion resistant and easy to work with.

又、コンクリート用補強部材等においても、耐蝕性の観
点から、鉄筋に代り得る合成樹脂製補強部材が注目され
ている。このような、補強部材においては、岩盤やコン
クリートへの付着性を高めるために、表面に突起を設け
ることが有効とされている。
Furthermore, synthetic resin reinforcing members that can replace reinforcing bars are attracting attention from the viewpoint of corrosion resistance in reinforcing members for concrete and the like. In such reinforcing members, it is considered effective to provide protrusions on the surface in order to improve adhesion to rock or concrete.

〔発明の解決しようとする問題点〕[Problem to be solved by the invention]

鋼製の補強部材と同等以上の引張シ強度を得るために、
合成樹脂製の補強部材には、炭素繊維等の引張シ強度の
高い補強繊維を補強部材長手方向に充てんすることが通
常行なわれている。
In order to obtain tensile strength equal to or higher than that of steel reinforcement members,
Reinforcing members made of synthetic resin are usually filled with reinforcing fibers having high tensile strength, such as carbon fibers, in the longitudinal direction of the reinforcing member.

その製法としては、補強部材長手方向に対して連続した
補強繊維を充てんする場合に生産性が高いことから、引
抜き成形方法を採用することが多い。一方、コンクリー
トや岩盤との付着強度を高めるために、補強部材の表面
には突起を設けることが通常行なわれているが突起を補
強部材の長手方向に対し、平行に連続的に設ける場合に
は、引き抜き成形も可能であるが、長手方向に対しある
角度を有する突起や、平行であっても不連続な突起であ
る場合には、引き抜き成形は不可能であシ、生産性の低
下は免れない。
As a manufacturing method, a pultrusion method is often adopted because productivity is high when filling reinforcing fibers that are continuous in the longitudinal direction of the reinforcing member. On the other hand, in order to increase the adhesion strength with concrete or rock, it is common practice to provide projections on the surface of reinforcing members, but when the projections are continuously provided parallel to the longitudinal direction of the reinforcing member, Although pultrusion is possible, pultrusion is not possible in the case of protrusions that are at a certain angle to the longitudinal direction or are discontinuous even if they are parallel, and a decrease in productivity can be avoided. do not have.

〔問題点を解決するための手段〕[Means for solving problems]

本発明は、特に引抜き成形が不可能な表面に突起を有す
る合成樹脂製補強部材を効率的に製造する方法を提供す
るものでアシ、連続した補強繊維を含む合成樹脂成形素
材を圧縮成形型内に導入し、圧縮成形することにより表
面に突起を有する補強部材を形成せしめ、次いで圧縮成
形型を開き、該補強部材を引き出すと同時に該補強部材
に連らなる該成形素材を圧縮成形型に導入し、再び型を
閉じ圧縮成形を繰り返すことを特徴とする、表面に突起
を有する補強部材の製法に関するものである。
The present invention provides a method for efficiently manufacturing a synthetic resin reinforcing member having protrusions on the surface that cannot be particularly pultruded. A reinforcing member having protrusions on the surface is formed by compression molding, and then the compression molding mold is opened and the reinforcing member is pulled out.At the same time, the molding material connected to the reinforcing member is introduced into the compression molding mold. The present invention relates to a method for manufacturing a reinforcing member having protrusions on its surface, which is characterized in that the mold is closed again and compression molding is repeated.

添付第1図には、本発明の典型的な製法例を示し、fi
X2図には本発明方法により製造し得る、表面に突起を
有する補強部材の例を示し、第5図にはその補強部材の
長手方向に垂直な概略断面図の例(表面の突起は省略し
である)を示している。
Attached FIG. 1 shows a typical manufacturing method example of the present invention, and fi
Fig. ).

第1図に従って本発明を説明すると、マットやロービン
グ等の連続した補強繊維(1)を未硬化の熱硬化性樹脂
槽12)に導入し、樹脂を繊維に含浸させる。含浸樹脂
量をスククイーズ(4)によシ調節C1必要により樹脂
未含浸の連続した補強繊維(3)とともに、予備成形型
(5)を通し又は通さずに続いて圧縮成形型(6)内へ
導入し、圧縮成形することにより表面に突起を有する補
強部材を形成する。圧縮成形型を開いた後又は開きなが
ら、圧縮成形した補強部材を引き取り装置(7)Kよシ
引き出し、樹脂が固化した後、カッター(8)により必
要な長さに切断し製造する方法である。
The present invention will be described with reference to FIG. 1. Continuous reinforcing fibers (1) such as mats or rovings are introduced into an uncured thermosetting resin bath 12), and the fibers are impregnated with resin. Adjust the amount of impregnated resin by squeezing (4) C1 If necessary, pass it through the preforming mold (5) or not, and then into the compression molding mold (6) together with the continuous reinforcing fibers (3) that are not impregnated with resin. A reinforcing member having protrusions on the surface is formed by introducing and compression molding. In this method, after or while opening the compression mold, the compression molded reinforcing member is pulled out from the take-up device (7) K, and after the resin has solidified, it is cut into the required length with a cutter (8). .

圧縮成形した補強部材を圧縮成形型(6)から引き出す
際に、それに連らなる樹脂含浸補強繊維が成形型(6)
に導入されるため、繰り返し連続的に圧縮成形を行なう
ことができる。
When pulling out the compression molded reinforcing member from the compression mold (6), the resin-impregnated reinforcing fibers connected to it are removed from the mold (6).
Since the resin is introduced into the mold, compression molding can be performed repeatedly and continuously.

本発明方法では、引き抜き成形とは異なり成形型を開い
て引き取ることが可能であシ、第2図に示すような引き
抜き方向に対しある角度を持った突起部α2が存在して
いても引き取ることができる。このような突起部α2が
補強部材とコンクリートや岩盤との付着強度を高めるた
めに重要となるが、本発明方法は特にこのような突起部
を有した補強部材の製法に有効である。あるいは、引き
取シ方向と平行な突起部、例えば第2図の(11)のみ
が存在する場合であっても、長さ方向に不連続としたい
場合には、引き抜き成形では得ることができず、やけシ
本発明方法が効果的となる。
In the method of the present invention, unlike pultrusion molding, it is possible to open the mold and take it out, and even if there is a protrusion α2 having a certain angle with respect to the drawing direction as shown in FIG. I can do it. Such protrusions α2 are important for increasing the adhesion strength between the reinforcing member and concrete or rock, and the method of the present invention is particularly effective in manufacturing reinforcing members having such protrusions. Alternatively, even if there is only a protrusion parallel to the drawing direction, for example (11) in Fig. 2, if you want it to be discontinuous in the length direction, it cannot be obtained by pultrusion. However, the method of the present invention is effective.

突起部住9やα2は、コンクリートや岩盤中で特に力の
かかる部分であるから、充分に補強繊維が充てんされて
いることが好ましい。又、突起部中の補強繊維は、突起
部以外に存在する補強   □繊維と連続していること
が好ましいが、このためKは、樹脂の流れに追従しやす
いマット類、クロス類、バイアスクロス類又は不織布類
からなる補強繊維を補強部材の表面部に配置するとよい
。圧縮成形型に導入する樹脂含浸補強繊維は、樹脂が未
硬化のままでもよく、又、予備成型(5)を通さなくと
もよいが、予備成形型によシ補強部材の最終断面形状に
近似した形状に予備成形したシ、予熱によシ樹脂を半硬
化状態とした後圧縮成形してもよい。一部の補強繊維特
に補強部材の表面部を形成する繊維は、第1図(3)の
ように樹脂槽(2)を通さずに直接予備成形型や圧縮成
形型へ導入し、樹脂含浸補強繊維をサンドインチしなが
ら圧縮成形してもよい。これによシ樹脂のタレを防ぐこ
とができる。又、SMCやBMC等のプリプレグやプリ
ミックス等の材料を併用してもよい。
It is preferable that the protrusions 9 and α2 are sufficiently filled with reinforcing fibers, since these are parts of concrete or rock that are particularly subjected to force. In addition, it is preferable that the reinforcing fibers in the protrusions are continuous with the reinforcing fibers that exist outside the protrusions, but for this reason, K is suitable for mats, cloths, bias cloths, etc. that easily follow the flow of resin. Alternatively, reinforcing fibers made of nonwoven fabrics may be arranged on the surface of the reinforcing member. The resin-impregnated reinforcing fibers to be introduced into the compression molding mold may have an uncured resin or may not be subjected to preforming (5), but the reinforcing fibers may have a shape similar to the final cross-sectional shape of the reinforcing member in the preforming mold. The resin may be preformed into a shape or preheated to a semi-hardened state, and then compression molded. Some of the reinforcing fibers, especially those forming the surface part of the reinforcing member, are introduced directly into the preforming mold or compression molding mold without passing through the resin tank (2) as shown in Figure 1 (3), and are impregnated with resin and reinforced. Compression molding may be performed while sandwiching the fibers. This can prevent the resin from dripping. Further, materials such as prepregs and premixes such as SMC and BMC may be used in combination.

補強部材の形状は、第5図にその長手方向の断面を示し
たように1円柱状や角柱状が好ましいが、断面が偏平な
板状でもよい。補強部材の中心部には、ガラス繊維のロ
ービングやカーボン繊維のトウ(ロービングに相当する
)のごとき、長さ方向に連続した補強繊維を配置するこ
とが好ましいが、中心部は、従来の鋼製補強部材とし、
その外周部に繊維強化合成樹脂を配置し、本発明方法に
従って、外周部表面に突起を設けてもよい。本発明の補
強部材は、ロックボルトや鉄筋代替部材として、又はプ
レストレストコンクリート部材として使用し得る。補強
繊維の材質は、引張シ強度が特に高いことから、カーボ
ン繊維が好ましく、アクリル線維系、ピッチ系、レーヨ
ン系等のカーボン繊維を採用し得る。カーボン繊維の他
、ガラス繊維、ボロン繊維、各種金属繊維等の無機繊維
又は、麻、ビニロン、ポリアミド、ポリエステル等の天
然又は合成繊維でもよく、これらを単独であるいは2種
以上組み合せて使用可能である。補強繊維の形態は、チ
ョツプドストランドマット、コンティニュアスストラン
ドマット、サーフエシングマット、不織布、クロス、バ
イアスクロス、ロービング等各種の形態を単独であるい
は組み合せて使用でき、補強部材中心部には、ロービン
グ状補強繊維が、表面部にはコンティニュアスストラン
ドマット状補強繊維が好ましい。一方、補強部材を構成
する樹脂は、コンクIJ −ト補強用として使用する場
合にはコンクリートのアルカリ性に対して強いことから
、エポキシ樹脂やエポキシアクリレート樹脂が好ましい
が、エポキシ系樹脂の他、不飽和ポリエステル樹脂、フ
ェノール樹脂、等の熱硬化性樹脂でもよく、ポリカーボ
ネート樹脂、ポリ塩化ビニル樹脂、ポリプロピレン樹脂
等の熱可塑性樹脂であってもよい。補強部材中の補強繊
維の充てん割合は、補強部材の強度や剛性を充分に確保
するために、40〜80vo1%、好ましくは60〜8
0volチの範囲から選定するとよい。又、表面の突起
部中の補強繊維は少なくとも10 vol To以上充
てんすることが好ましい。
The shape of the reinforcing member is preferably cylindrical or prismatic, as shown in its longitudinal cross section in FIG. 5, but it may also be a plate with a flat cross section. The center of the reinforcing member is preferably provided with longitudinally continuous reinforcing fibers, such as glass fiber rovings or carbon fiber tows (corresponding to rovings); As a reinforcing member,
A fiber-reinforced synthetic resin may be placed on the outer periphery, and projections may be provided on the outer periphery surface according to the method of the present invention. The reinforcing member of the present invention can be used as a rock bolt or reinforcing member, or as a prestressed concrete member. As the material of the reinforcing fibers, carbon fibers are preferable because they have particularly high tensile strength, and acrylic fiber-based, pitch-based, rayon-based carbon fibers, and the like may be used. In addition to carbon fibers, inorganic fibers such as glass fibers, boron fibers, and various metal fibers, or natural or synthetic fibers such as hemp, vinylon, polyamide, and polyester may also be used, and these can be used alone or in combination of two or more types. . Various types of reinforcing fibers can be used, such as chopped strand mats, continuous strand mats, surfaging mats, non-woven fabrics, cloths, bias cloths, and rovings, either singly or in combination. , roving-like reinforcing fibers are preferable, and continuous strand mat-like reinforcing fibers are preferable on the surface portion. On the other hand, when the resin constituting the reinforcing member is used for reinforcing concrete IJ-T, epoxy resin or epoxy acrylate resin is preferable because it is strong against the alkalinity of concrete. Thermosetting resins such as polyester resins and phenol resins may be used, and thermoplastic resins such as polycarbonate resins, polyvinyl chloride resins, and polypropylene resins may be used. The filling ratio of reinforcing fibers in the reinforcing member is 40 to 80 vol%, preferably 60 to 8 vol. to ensure sufficient strength and rigidity of the reinforcing member.
It is preferable to select from a range of 0 vol. Further, it is preferable that the reinforcing fibers in the protrusions on the surface are filled in an amount of at least 10 vol To.

〔実施例〕〔Example〕

単位重量2.zzr/mのガラスロービングを45個の
巻から取り出し、エポキシアクレート樹脂に有機過酸化
物を配合した液状樹脂に含浸せしめ、含浸槽から出たロ
ービング束を直径8震のスクウイーズ孔の中を通過せし
める。ロービング束の両側に単位重量450 t 7m
2のコンティニュアスストランドマットを幅20−にし
たテープ状マット62枚を添わせて、圧縮金型内に導入
し、130℃の金型で50 kg /ass”の成形圧
力をかけて3分間保持する。金型の長さは3mである。
Unit weight 2. zzr/m glass rovings were taken out from 45 rolls, impregnated with a liquid resin containing epoxy acrylate resin and organic peroxide, and the roving bundle that came out of the impregnation tank was passed through a squeeze hole with a diameter of 8 earthquakes. urge Unit weight 450t 7m on both sides of roving bundle
The continuous strand mat from No. 2 was attached with 62 tape-shaped mats with a width of 20 mm, introduced into a compression mold, and molded with a molding pressure of 50 kg/ass in a mold at 130°C for 3 minutes. The length of the mold is 3 m.

金型を開いた後成形物は引取シローラーにて型長分だけ
引き出し、再度プレス成形に入る。この方式で直径F!
−5wmのガラス繊維強化丸棒に、長さ方向に垂直な幅
2霞、高さ2■突起を有する補強部材を得ることができ
た。
After opening the mold, the molded product is pulled out by the length of the mold using a take-off roller, and press molding is started again. With this method, the diameter is F!
A reinforcing member having a width of 2 mm and a height of 2 mm perpendicular to the length direction was obtained on a -5 wm glass fiber reinforced round bar.

なお、成形の間ロービング束には5跋の張力を与えゆる
みを防止した。さらに、ロービング束が成形型に入る前
に加熱炉を設けることにより、束の真円度を高めること
ができた。
Note that during the forming, the roving bundle was subjected to five tensions to prevent loosening. Furthermore, by providing a heating furnace before the roving bundle enters the mold, it was possible to improve the roundness of the bundle.

〔発明の効果〕〔Effect of the invention〕

本発明方法に従えば繊維強化合成樹脂製の補強部材表面
に突起を効率的に形成せしめることができる。圧縮成形
型を用いることができるため、各種形状の突起を自由な
方向に容易に形成し得る。補強部材の中心部と突起部は
連続した補強繊維を介して一体的に設けることができる
ため、突起部が破壊されにくい利点がある。
According to the method of the present invention, protrusions can be efficiently formed on the surface of a reinforcing member made of fiber-reinforced synthetic resin. Since a compression mold can be used, protrusions of various shapes can be easily formed in any direction. Since the center portion of the reinforcing member and the protrusion can be integrally provided via continuous reinforcing fibers, there is an advantage that the protrusion is less likely to be destroyed.

先回面の簡単な説明 第1図は、本発明方法の一例を示す概略側面図。第2図
(転)〜(つけ、本発明方法により製造し得る表面に突
起を有する補強部材の例を示す正面図。第3図翰〜(イ
)は、補強部材の長手方向に垂直な断面を示す概略図。
BRIEF DESCRIPTION OF THE PREFERRED EMBODIMENTS FIG. 1 is a schematic side view showing an example of the method of the present invention. Figures 2(a) to 3(a) are front views showing examples of reinforcing members having protrusions on the surface that can be manufactured by the method of the present invention. Figures 3(a) to 3(b) are cross-sections perpendicular to the longitudinal direction of the reinforcing members. Schematic diagram showing.

5・・・予備成形型 6・・・圧縮成形型 11・・・補強部材の長さ方向に平行な突起。5... Preforming mold 6...Compression mold 11...Protrusions parallel to the length direction of the reinforcing member.

12・・・補強部材の長さ方向に対しある角度を持った
突起。
12...Protrusion with a certain angle to the length direction of the reinforcing member.

Claims (1)

【特許請求の範囲】 1、連続した補強繊維を含む合成樹脂成形素材を圧縮成
形型内に導入し、圧縮成形することにより表面に突起を
有する補強部材を形成せしめ、次いで圧縮成形型を開き
、該補強部材を引き出すと同時に該補強部材に連らなる
該成形素材を圧縮成形型に導入し、再び型を閉じ圧縮成
形を繰り返すことを特徴とする、表面に突起を有する補
強部材の製法。 2、表面の突起が、補強部材長手方向に平行でない連続
又は不連続の突起である特許請求の範囲第1項記載の製
法。 3、表面の突起が、補強部材長手方向に平行で不連続な
突起である特許請求の範囲第1項記載の製法。
[Claims] 1. A synthetic resin molding material containing continuous reinforcing fibers is introduced into a compression molding mold, compression molding is performed to form a reinforcing member having protrusions on the surface, and then the compression molding mold is opened, A method for producing a reinforcing member having protrusions on the surface, the method comprising: pulling out the reinforcing member, introducing the molding material connected to the reinforcing member into a compression mold, closing the mold again and repeating compression molding. 2. The manufacturing method according to claim 1, wherein the protrusions on the surface are continuous or discontinuous protrusions that are not parallel to the longitudinal direction of the reinforcing member. 3. The manufacturing method according to claim 1, wherein the protrusions on the surface are discontinuous protrusions parallel to the longitudinal direction of the reinforcing member.
JP7670085A 1985-04-12 1985-04-12 Manufacture of reinforcing member having protrusion on surface thereof Pending JPS61235115A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP7670085A JPS61235115A (en) 1985-04-12 1985-04-12 Manufacture of reinforcing member having protrusion on surface thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7670085A JPS61235115A (en) 1985-04-12 1985-04-12 Manufacture of reinforcing member having protrusion on surface thereof

Publications (1)

Publication Number Publication Date
JPS61235115A true JPS61235115A (en) 1986-10-20

Family

ID=13612778

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7670085A Pending JPS61235115A (en) 1985-04-12 1985-04-12 Manufacture of reinforcing member having protrusion on surface thereof

Country Status (1)

Country Link
JP (1) JPS61235115A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5182064A (en) * 1990-10-17 1993-01-26 Nippon Petrochemicals Company, Limited Method for producing fiber reinforced plastic rods having helical ribs
US5593536A (en) * 1994-06-28 1997-01-14 Marshall Industries Composites Apparatus for forming reinforcing structural rebar
US5851468A (en) * 1994-06-28 1998-12-22 Kaiser; Mark A. Reinforcing structural rebar and method of making the same
US5876553A (en) * 1994-06-28 1999-03-02 Marshall Industries Composites, Inc. Apparatus for forming reinforcing structural rebar
US6493914B2 (en) 1996-10-07 2002-12-17 Marshall Industries Composites, Inc. Reinforced composite product and apparatus and method for producing same

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4533901Y1 (en) * 1966-07-19 1970-12-24
JPS5133832A (en) * 1974-09-18 1976-03-23 Shin Kobe Electric Machinery
JPS51101075A (en) * 1975-03-04 1976-09-07 Asahi Glass Co Ltd

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4533901Y1 (en) * 1966-07-19 1970-12-24
JPS5133832A (en) * 1974-09-18 1976-03-23 Shin Kobe Electric Machinery
JPS51101075A (en) * 1975-03-04 1976-09-07 Asahi Glass Co Ltd

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5182064A (en) * 1990-10-17 1993-01-26 Nippon Petrochemicals Company, Limited Method for producing fiber reinforced plastic rods having helical ribs
US5593536A (en) * 1994-06-28 1997-01-14 Marshall Industries Composites Apparatus for forming reinforcing structural rebar
US5626700A (en) * 1994-06-28 1997-05-06 Marshall Industries Composites Method for forming reinforcing structural rebar by pultruding a core and molding thereover
US5851468A (en) * 1994-06-28 1998-12-22 Kaiser; Mark A. Reinforcing structural rebar and method of making the same
US5876553A (en) * 1994-06-28 1999-03-02 Marshall Industries Composites, Inc. Apparatus for forming reinforcing structural rebar
US6493914B2 (en) 1996-10-07 2002-12-17 Marshall Industries Composites, Inc. Reinforced composite product and apparatus and method for producing same

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