JPS6116125Y2 - - Google Patents
Info
- Publication number
- JPS6116125Y2 JPS6116125Y2 JP5024680U JP5024680U JPS6116125Y2 JP S6116125 Y2 JPS6116125 Y2 JP S6116125Y2 JP 5024680 U JP5024680 U JP 5024680U JP 5024680 U JP5024680 U JP 5024680U JP S6116125 Y2 JPS6116125 Y2 JP S6116125Y2
- Authority
- JP
- Japan
- Prior art keywords
- laminated
- resistance
- layer
- metal
- sheet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052751 metal Inorganic materials 0.000 claims description 25
- 239000002184 metal Substances 0.000 claims description 25
- 229920005989 resin Polymers 0.000 claims description 12
- 239000011347 resin Substances 0.000 claims description 12
- 239000010408 film Substances 0.000 claims description 7
- 229920000554 ionomer Polymers 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 4
- 239000000758 substrate Substances 0.000 claims description 4
- 239000010409 thin film Substances 0.000 claims description 4
- 238000007731 hot pressing Methods 0.000 claims 1
- 239000010410 layer Substances 0.000 description 11
- 238000010292 electrical insulation Methods 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 231100000956 nontoxicity Toxicity 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- MIZLGWKEZAPEFJ-UHFFFAOYSA-N 1,1,2-trifluoroethene Chemical group FC=C(F)F MIZLGWKEZAPEFJ-UHFFFAOYSA-N 0.000 description 1
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 229910000669 Chrome steel Inorganic materials 0.000 description 1
- PYVHTIWHNXTVPF-UHFFFAOYSA-N F.F.F.F.C=C Chemical compound F.F.F.F.C=C PYVHTIWHNXTVPF-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- -1 alkalis Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 1
- 229920005648 ethylene methacrylic acid copolymer Polymers 0.000 description 1
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000002648 laminated material Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920006112 polar polymer Polymers 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Description
【考案の詳細な説明】
この考案は、金属板表面の性質を改善すること
に係り、アルミニユーム、鉄等の金属板の表面
に、特殊積層シートを強固に展接着して、耐候
性、耐薬品性、電気絶縁性、に優れ、かつ機械的
強度も強く、耐熱、耐寒性、不燃性、無毒性も兼
ね備えた、金属板を基板とする積層材を提供する
ことを目的としてなされたものである。[Detailed explanation of the invention] This invention relates to improving the properties of the surface of metal plates, and by firmly spreading and adhering a special laminated sheet on the surface of metal plates such as aluminum and iron, it has weather resistance and chemical resistance. This was developed with the aim of providing a laminated material using a metal plate as a substrate, which has excellent properties such as electrical insulation, high mechanical strength, heat resistance, cold resistance, non-combustibility, and non-toxicity. .
屋外、屋内における、設備品、機器、家具等に
使用される金属板には、耐候性、耐蝕性、不銹
性、保温保冷性、電気絶縁性等を要請される場合
が多く、従来この種の用途には、いわゆる不銹鋼
（クローム鋼、クロームニツケル鋼等）が用いら
れることが多いが、保温、保冷性、電気絶縁性、
特定薬品に対する抵抗性等を要する用途には応じ
難く而も高価であつて、加工性も他の金属に比し
て低い。この考案に係る積層金属板は、アルミニ
ユーム板、鉄板等の表面に、耐光性、耐摩擦性、
耐候性、不燃性、電気絶縁性等に優れた積層シー
トを強固に密着させることによつて前述のような
用途に適合した積層金属板を完成したものであ
る。 Metal plates used outdoors and indoors for equipment, equipment, furniture, etc. are often required to have weather resistance, corrosion resistance, rust resistance, heat and cold insulation properties, electrical insulation properties, etc. So-called non-rusting steels (chrome steel, chrome nickel steel, etc.) are often used for these applications, but they also have properties such as heat retention, cold retention, electrical insulation,
It is difficult to meet applications requiring resistance to specific chemicals, is expensive, and has lower workability than other metals. The laminated metal plate according to this invention has light resistance, abrasion resistance,
By tightly adhering laminated sheets with excellent weather resistance, nonflammability, electrical insulation, etc., a laminated metal plate suitable for the above-mentioned uses has been completed.
以下この考案に係る積層金属板の構成を図面に
示した例に基いて説明する。 The structure of the laminated metal plate according to this invention will be explained below based on an example shown in the drawings.
１、は耐光、耐熱、耐寒等の耐候性、耐薬品性
（酸、アルカリ、溶剤等に侵されない）、電気特性
（絶縁破壊電圧が大きく、誘電損失が小さい）、機
械的強度（引裂、耐折強度が特に強い）、不燃
性、無毒性等の諸性質に優れたフツ素系合成樹
脂、例へば、４フツ化エチレン重合体、２フツ化
ビニリデン重合体、エチレン−４フツ化エチレン
共重合体、４フツ化エチレン−６フツ化プロピレ
ン共重合体、３−フツ化エチレン重合体等の可撓
性フイルムであつてこの考案に係る積層金属板の
表面層を形成する。 1. Weather resistance such as light resistance, heat resistance, and cold resistance, chemical resistance (not attacked by acids, alkalis, solvents, etc.), electrical properties (high breakdown voltage, low dielectric loss), mechanical strength (tear resistance, Fluorine-based synthetic resins with excellent properties such as particularly strong flexural strength), nonflammability, and non-toxicity, such as ethylene tetrafluoride polymer, vinylidene difluoride polymer, and ethylene-tetrafluoroethylene copolymer. , a tetrafluoroethylene-hexafluoropropylene copolymer, a trifluoroethylene polymer, or the like, and forms the surface layer of the laminated metal plate according to this invention.
２、はアルミニユーム、クローム等の金属薄膜
層であつて、１、のフツソ樹脂系フイルムの片面
に真空蒸着法によつて密展着させたものであつ
て、フツ素系樹脂層１、とアイオノマー樹脂層
３、との接着媒体となり、更に光線、熱線等の反
射の効果も発揮する。通常光沢ある白銀色である
が、適当に着色することも可能である。 2. is a metal thin film layer of aluminum, chrome, etc., which is closely adhered to one side of the fluorine-based resin film of 1. by vacuum evaporation method, and fluorine-based resin layer 1 and ionomer. It serves as an adhesive medium with the resin layer 3, and also exhibits the effect of reflecting light, heat rays, etc. It is usually a shiny white silver color, but it can also be colored appropriately.
３、はいわゆるアイオノマー樹脂、即ちエチレ
ン−アクリル酸共重合体、又はエチレン−メタア
クリル酸共重合体の、亜鉛、ナトリウム、マグネ
シユーム等の金属イオンによる架橋体、のフイル
ム又はシートであつて、上記２、の金属薄膜層に
加熱圧着する。 3 is a film or sheet of a so-called ionomer resin, that is, a crosslinked product of ethylene-acrylic acid copolymer or ethylene-methacrylic acid copolymer with metal ions such as zinc, sodium, magnesium, etc. , heat and pressure bonded to the metal thin film layer.
アイオノマー樹脂は、熱可塑性であつて、その
構造は、極性の高い高分子鎖を金属イオンで結合
してなるものであるから、金属被着体、即ち前記
真空蒸着金属薄膜層２、及び金属基板４、と加
熱、加圧することによつてよく接着し、耐久性高
く、耐剥離強度の大なる積層を形成する。 Ionomer resin is thermoplastic and has a structure in which highly polar polymer chains are bonded with metal ions. 4. By heating and pressurizing, it adheres well and forms a laminated layer with high durability and high peel resistance.
４、は用途に適した厚みを有するアルミニユー
ム板、鉄板等であつて、前記積層シートと金属板
４、との接着は、加熱ロール（第２ａ図）、加熱
プレス（第２ｂ図）、等によつて容易に行われ
る。 4 is an aluminum plate, iron plate, etc. having a thickness suitable for the purpose, and the adhesion between the laminated sheet and the metal plate 4 is performed using a heating roll (Fig. 2a), a heating press (Fig. 2b), etc. Therefore, it is easily done.
以上のような構成よりなる積層金属板は、その
表層をなすフツ化樹脂層は、前述のように、すぐ
れた物理的性質を有し、機械的強度も強く、通常
使用されるあらゆる薬品、溶剤等にも侵されず、
耐温度特性においても、−100℃から200℃程度ま
での広い範囲で使用可能であり、更に電気絶縁性
も極めて優秀であつて、吸水率も事実上０に等し
い。 As mentioned above, the fluorinated resin layer forming the surface layer of the laminated metal plate with the above structure has excellent physical properties and strong mechanical strength, and is resistant to all commonly used chemicals and solvents. It is not affected by
In terms of temperature resistance, it can be used over a wide range of temperatures from -100°C to about 200°C, and it also has extremely good electrical insulation properties, and its water absorption rate is virtually zero.
又、アイオノマー樹脂フイルム又はシート層
３、は金属面に容易に強固に接着することは上述
の如くであるが、可撓性であつて、耐熱性、低温
特性も良好であつて、機械的強度も強く、難燃性
である。更にフツ化樹脂層１、と共に極めて優れ
た断熱効果を表わす。 In addition, as mentioned above, the ionomer resin film or sheet layer 3 easily and firmly adheres to metal surfaces, but it is also flexible, has good heat resistance and low-temperature properties, and has good mechanical strength. It is also strong and flame retardant. Furthermore, together with the fluorinated resin layer 1, it exhibits an extremely excellent heat insulating effect.
以上述べたように、この考案に係る積層金属板
は各積層組成物質の特性を有効に利用するもので
あつて、基板たる金属板の特性と相俟つて、極め
て有用な板状素材の完成をみたのである。 As mentioned above, the laminated metal plate according to this invention effectively utilizes the characteristics of each laminated composition material, and together with the characteristics of the metal plate as a substrate, it is possible to complete an extremely useful plate-like material. I saw it.
更にこの積層金属板の特徴は深絞り加工に充分
に耐え得ることであつて、従つて広汎な用途をも
つものである。上述の優れた諸性質を生かしたこ
の積層金属板の用途としては、建材、自動販売機
の外装、スチール家具、洗面化粧台、台所流し
台、バスタブ、電気機器のケーシング、キヤビネ
ツト、自動車内外装、耐熱耐冷機器等、極めて広
範囲にわたるものがある。 Furthermore, this laminated metal sheet is characterized by its ability to withstand deep drawing processes, and therefore has a wide range of uses. Applications of this laminated metal sheet that take advantage of the above-mentioned excellent properties include building materials, vending machine exteriors, steel furniture, bathroom vanities, kitchen sinks, bathtubs, electrical equipment casings, cabinets, automobile interiors and exteriors, and heat resistance. There is a wide range of cold-resistant equipment.
第１図は、本考案に係る積層金属板の部分拡大
断面図、第２ａ図は、加熱ロール法、第２ｂ図は
加熱プレス法の概略図、第３図は、深絞り加工例
（流し台）の一部断面斜視図。
図中、１……フツソ樹脂系フイルム層、２……
アルミニユーム、クローム等の金属薄膜層、３…
…アイオノマー樹脂フイルム又はシート層、４…
…金属基板、５……積層シート、６……積層金属
板、７……展着用ロール、８……積層シート巻取
機、９……圧着プレス。
Fig. 1 is a partially enlarged sectional view of a laminated metal plate according to the present invention, Fig. 2a is a schematic diagram of the heated roll method, Fig. 2b is a schematic diagram of the heated press method, and Fig. 3 is an example of deep drawing processing (sink). FIG. In the figure, 1... a soft resin film layer, 2...
Metal thin film layer of aluminum, chrome, etc., 3...
...Ionomer resin film or sheet layer, 4...
...Metal substrate, 5... Laminated sheet, 6... Laminated metal plate, 7... Roll for spreading, 8... Laminated sheet winder, 9... Pressure bonding press.
Claims (1)
して、フツ素樹脂系フイルム層及びアイオノマー
樹脂フイルム又はシート層の３層よりなる積層シ
ートのアイオノマー樹脂層を、金属基板の表面に
加熱圧着してなる積層金属板。 Laminated metal made by hot-pressing an ionomer resin layer of a laminated sheet consisting of three layers, a fluororesin film layer and an ionomer resin film or sheet layer, onto the surface of a metal substrate via a metal thin film layer of aluminum, chrome, etc. Board.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5024680U JPS6116125Y2 (en) | 1980-04-14 | 1980-04-14 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5024680U JPS6116125Y2 (en) | 1980-04-14 | 1980-04-14 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS56151136U JPS56151136U (en) | 1981-11-12 |
| JPS6116125Y2 true JPS6116125Y2 (en) | 1986-05-19 |
Family
ID=29645191
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5024680U Expired JPS6116125Y2 (en) | 1980-04-14 | 1980-04-14 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6116125Y2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE504195C2 (en) * | 1995-03-21 | 1996-12-02 | Ericsson Telefon Ab L M | Laminates for sealing and enclosing electronic components, as well as methods for making them |
-
1980
- 1980-04-14 JP JP5024680U patent/JPS6116125Y2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS56151136U (en) | 1981-11-12 |
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