JPS61136659A - Cylinder liner for diesel engine - Google Patents

Cylinder liner for diesel engine

Info

Publication number
JPS61136659A
JPS61136659A JP25969684A JP25969684A JPS61136659A JP S61136659 A JPS61136659 A JP S61136659A JP 25969684 A JP25969684 A JP 25969684A JP 25969684 A JP25969684 A JP 25969684A JP S61136659 A JPS61136659 A JP S61136659A
Authority
JP
Japan
Prior art keywords
steadite
plate
cylinder liner
diesel engine
cementite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP25969684A
Other languages
Japanese (ja)
Inventor
Kazuhiko Shiroo
和彦 城尾
Masaaki Shiraishi
白石 雅章
Isao Takeda
竹田 勲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yanmar Co Ltd
Original Assignee
Yanmar Diesel Engine Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yanmar Diesel Engine Co Ltd filed Critical Yanmar Diesel Engine Co Ltd
Priority to JP25969684A priority Critical patent/JPS61136659A/en
Publication of JPS61136659A publication Critical patent/JPS61136659A/en
Pending legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02BINTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B3/00Engines characterised by air compression and subsequent fuel addition
    • F02B3/06Engines characterised by air compression and subsequent fuel addition with compression ignition
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05CINDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
    • F05C2203/00Non-metallic inorganic materials
    • F05C2203/04Phosphor

Landscapes

  • Cylinder Crankcases Of Internal Combustion Engines (AREA)

Abstract

PURPOSE:To obtain a cylinder liner for a diesel engine contg. platy steadite in the structure by incorporating specified amounts of P, Cr and Si into an iron casting contg. a specified amount of C. CONSTITUTION:A cylinder liner for a diesel engine contg. platy steadite in the structure is obtd. by incorporating 0.3-0.9wt% P, 0.6-0.9wt% Cr and 1.3-1.8wt% Si into a casting consisting of 2.8-3.6wt% C, <=0.1wt% each of Mn and S, and the balance Fe. Cu and Ca may be further incorporated.

Description

【発明の詳細な説明】 〔産業上の利用分野と背景〕 本発明は、ディーゼル機関に用いるシリンダライナの材
料に関する。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application and Background] The present invention relates to materials for cylinder liners used in diesel engines.

シリンダライナは、ディーゼル機関部材において、機能
面でも耐久面でも非雷に重要な部材であって、特に、高
い熱負荷を受け、かつ高温高圧ガスを往復摺動するピス
トンリングとともに密工1する機能を果たしている。か
かるシリンダライナに通用する材料は、一般に利用され
ているのは鋳鉄であるが、これは鋳鉄の耐摩耗性が著し
く優れているからである。一方、シリンダライナの摩耗
をその原因により分類すると、異物によるアブレーシブ
摩耗、S清不良により摩耗面が熔融流動するスカフイン
グ摩耗等があり、これらに対する耐摩耗性は、使用する
材質により向上させることができる。
The cylinder liner is a diesel engine component that is important for protection from lightning in terms of function and durability.In particular, the cylinder liner is subjected to a high heat load and has a secret function along with the piston ring, which slides back and forth through high-temperature, high-pressure gas. is fulfilled. Cast iron is generally used as a material for such cylinder liners because cast iron has extremely high wear resistance. On the other hand, if cylinder liner wear is classified by its causes, there are abrasive wear due to foreign objects, scuffing wear where the worn surface melts and flows due to poor S cleaning, etc. Wear resistance against these types of wear can be improved by the material used. .

〔従来の技術とその問題点〕[Conventional technology and its problems]

そのため、シリンダライナには高りん鋳鉄や、いわゆる
Pの共晶物を多量に発生させる材料や、更には、Pの添
加を抑えて、V、B、Tiなどを添加して特殊ステダイ
トを分布させる材料など、多数の耐摩耗性向上の材料が
提案され、実施されている。
For this reason, the cylinder liner is made of high-phosphorus cast iron or a material that generates a large amount of so-called P eutectic, or even suppresses the addition of P and adds V, B, Ti, etc. to distribute special steadite. A number of wear-resistance-enhancing materials have been proposed and implemented, such as materials.

一方、一般的には、例えば、前記特殊ステダイトを分布
させる方法の一種として、Cr 、S i、Pを添加す
ることにより板状炭化物、つまり板状ステダイトを生成
されるという技術も知られている。
On the other hand, generally, for example, as a type of method for distributing the special steadite, a technique is also known in which plate-shaped carbides, that is, plate-shaped steadite, are generated by adding Cr, Si, and P. .

ところが、かかる特殊ステダイトを生成したシリンダラ
イナで、■、B、Tiなどを添加したものは、重油燃焼
廃物により腐食を伴うような条件における耐摩耗性が優
れているので、広く用いられているものの、その材料費
が高価となっており、また、Cr 、5i−Pなどを添
加して板状炭化物を生成する一般的な技術は、シリンダ
ライナとしては未だ確立されておらず、安定して大量生
産する迄には至らない。
However, cylinder liners made from such special steadite, with additions such as ■, B, and Ti, are widely used because they have excellent wear resistance under conditions where corrosion occurs due to heavy oil combustion waste. However, the material costs are high, and the general technology of adding Cr, 5i-P, etc. to produce plate-like carbides has not yet been established for cylinder liners, and it cannot be used stably and in large quantities. It has not reached the stage of production.

〔問題点を解決するための手段〕[Means for solving problems]

そこで本発明は、これらの問題点を解決して、安価で、
かつ、安定した生産可能の板状ステダイトを生成するシ
リンダライナを提供しようとするもので、特に、昨今の
化石燃料の高騰化により低質燃料を使用することを余儀
なくされている現状下において、アブレーシブ摩耗に対
処しようとするものである。
Therefore, the present invention solves these problems and is inexpensive.
The aim is to provide a cylinder liner that produces plate-shaped steadite that can be stably produced.Especially in the current situation where the recent rise in the price of fossil fuels has forced the use of low-quality fuel, abrasive wear can be avoided. It is an attempt to deal with this.

先ず、本発明の創作過程について逮ぺれば、本発明を完
成するための困難性の一つは、板状ステダイト生成に影
響を与える問題点ないし要因の解明作業であった。すな
わち、その概要をいえば、次のとおりである。先ず、本
発明の安価なCr、Si 、Pなどを選んだ、そして全
ステダイト面積(−ステダイト+板状セメンダイト)に
対しては、Pの影響が大きく、次いで、Crとなってい
る。
First, regarding the creation process of the present invention, one of the difficulties in completing the present invention was the task of elucidating the problems or factors that affect the formation of plate-like steadite. That is, the outline is as follows. First, inexpensive Cr, Si, P, etc. of the present invention were selected, and on the total steadite area (-steadite + plate-like cementite), P had a large influence, followed by Cr.

その理由は、ステダイトがPの化合物であるFeIPに
よって成立しているとの裏付けであり、Pの増加により
、ステダイトの表面も増加することが判明した。一方、
Crは白銑化元素であり、板状セメンタイトの生成に大
きく関与するのであるが、殊に、板状ステダイトの白色
部はCr等の白銑化元素によって晶出したセメンタイト
であることが明確になった。
The reason for this is evidence that steadite is made up of FeIP, which is a P compound, and it has been found that as P increases, the surface of steadite also increases. on the other hand,
Cr is a white-pigmenting element and is greatly involved in the formation of plate-like cementite. In particular, it is clear that the white part of plate-shaped steadite is cementite crystallized by white-pigmenting elements such as Cr. became.

次に、板状セメンタイト部面積に及ぼす要因に対しては
、Crの影響が特に大きく、次にSiの影響があること
が判明した。これは板状セメンタイトがCrなどの白銑
化元素によって生成される炭化物であることを明確につ
きとめて判明した。
Next, it was found that Cr had a particularly large influence on the area of the plate-like cementite portion, followed by Si. This was made clear by clearly identifying that plate-like cementite is a carbide produced by a white ironing element such as Cr.

したがって、CrはBやVの特殊元素と同じ効果を備え
ていることが確認できたのである。なお、Crの場合、
板状セメンタイトが安定して晶出するのは、0.5%以
上含まれいるときという磁界も解明できた。次に、Si
はマイナス要因としての効果をもっているのが解明でき
たが、これは、Siがフェライト元素で、セメンタイト
化を阻止する効果をもつことによる。ただし、Siの影
響はCrに比べ、やや小さいので、それ程小量とする必
要はなく、1.3〜1.8%が適当であることをつきと
めたのである。
Therefore, it was confirmed that Cr has the same effect as special elements such as B and V. In addition, in the case of Cr,
It was also discovered that plate-like cementite crystallizes stably when the magnetic field contains 0.5% or more. Next, Si
It has been clarified that Si has a negative effect, and this is because Si is a ferrite element and has the effect of inhibiting cementite formation. However, since the influence of Si is slightly smaller than that of Cr, it was found that there is no need to make the amount so small, and that 1.3 to 1.8% is appropriate.

更に、別の観点である板状化率に及ぼす原因につき検討
したところ、板状化率とは全ステダイトに占める板状セ
メンタイトの割合をいうのであるが、これにはCrやS
iの直接因子が効果として現れることが判明した。更に
は、ステダイト量との比較であるから、間接的にはPの
効果も現れていることが判明した。    ・ なお、板状セメンタイトおよびステダイトの硬度につい
て検討したところ、Cr、Si、Pの三元素と肉厚が影
響することが判明した。殊に、ある程度の肉厚がないと
、共晶凝固までの時間が短く、Crなどの濃化がおこり
にくいことが判明した。したがって、シリンダライナと
しては、ボア15f)sn以上のものに好適であること
が判明した。
Furthermore, we examined the cause of plateletization rate from another point of view, and found that plateletization rate refers to the proportion of platelet cementite in the total steadite, which includes Cr and S.
It was found that the direct factor of i appears as an effect. Furthermore, since the comparison was made with the amount of steadite, it was found that the effect of P was also indirectly observed. - Further, when examining the hardness of plate cementite and steadite, it was found that the three elements of Cr, Si, and P and the wall thickness have an effect. In particular, it has been found that unless the wall thickness is to a certain extent, the time required for eutectic solidification is short and the concentration of Cr etc. is difficult to occur. Therefore, it has been found that the cylinder liner is suitable for a cylinder liner having a bore of 15f)sn or larger.

そして、Pについては、Pの量が少ないとステダイトの
量が減少し、板状セメンタイトの周囲をとりかこむ硬い
ステダイトの壁が少ないため、硬度が低下することも判
明した。
Regarding P, it was also found that when the amount of P is small, the amount of steadite decreases, and there are fewer hard walls of steadite surrounding the plate-like cementite, resulting in a decrease in hardness.

以上のごとく、本発明者は試行vJ誤の結果、板状ステ
ダイト生成に影響を与える各M要因を解明した結果、次
のごとき本発明を完成したのである。
As described above, as a result of the trial vJ error, the present inventors have elucidated each M factor that influences the formation of plate-like steadite, and as a result, the present invention has been completed as follows.

本発明は、T、C(Cの全量のこと)2.8〜3.6%
、Mn、Sを夫々0,1%以下含有し、残部Feである
鋳物に、Pを0.3〜0.9%、Crを0.6〜0.9
%、Siを1.3〜1.8%の範囲内で添加することに
より板状ステダイトを生成したディーゼル機関用シリン
ダライナに係るものであり、 更に、かかる発明にCu  −Caを接4tx添加した
板状ステダイトを生成したディーゼル機関用シリノダラ
イナに係るものである。
In the present invention, T, C (total amount of C) 2.8 to 3.6%
, Mn, and S at 0.1% or less, and the balance is Fe, P is 0.3 to 0.9%, and Cr is 0.6 to 0.9%.
%, Si in the range of 1.3 to 1.8% to form a plate-shaped steadite, and furthermore, 4tx of Cu-Ca was added to the invention. This invention relates to a cylinodar liner for diesel engines in which plate-shaped steadite is formed.

本発明の構成を更に詳述すれば、Crは板状ステダイト
生成に一番大きな効果を与え、板状ステダイトの白色部
は、前記のごとく、Cr等の白銑化元素によって晶出し
たセメンタイトであることの解明から、0.7%が最適
で、これにより板状ステダイトの安定晶出を図ることが
できる。そして、0.3〜0.9%範囲以下では板状ス
テダイトが生成できず、耐摩耗性が劣化し、これ以上で
あれば、のである。
To explain the structure of the present invention in more detail, Cr has the greatest effect on the formation of plate-shaped steadite, and as mentioned above, the white part of plate-shaped steadite is cementite crystallized by white ironing elements such as Cr. From what we have discovered, 0.7% is optimal, and with this, stable crystallization of plate-like steadite can be achieved. If the content is below the range of 0.3 to 0.9%, plate-like steadite cannot be produced and the wear resistance deteriorates, and if it is above this range, the problem is.

Pは前記のごとく、板状ステダイト生成には直接の効果
はないが、ステダイト生成の基本元素であり、かつ、耐
摩耗性を向上させるため、一定量(最適0.45%)の
Pが必要であり、したがって、0.3〜0.6%にする
ことが望ましく、これ以下であれば、フェライトが生成
できず、耐摩耗性が劣化するし、これ以上であれば、脆
弱化する。
As mentioned above, P has no direct effect on plate-like steadite formation, but it is a basic element for steadite formation, and a certain amount (optimally 0.45%) is required to improve wear resistance. Therefore, it is desirable to set the content to 0.3 to 0.6%; if it is less than this, ferrite cannot be produced and wear resistance deteriorates, and if it is more than this, it becomes brittle.

Slは前記のごとく、板抜ステダイト生成の阻害元素と
しての効果を持つことが判明したが、鋳造性、機械的性
質の確保のため−・定量(最適1.6%)は必要である
ので、1.3〜1.8%の範囲とし、これより以下では
鋳造性が悪化し、表面がチル化し易く、これ以上では板
状セメンタイトが育成しなくなる。つまり、靭性と硬さ
のバランスを図ることができる。
As mentioned above, it has been found that Sl has the effect of inhibiting the formation of blank steadite, but in order to ensure castability and mechanical properties, a quantitative amount (optimally 1.6%) is necessary. The content should be in the range of 1.3 to 1.8%, and if it is less than this, the castability will deteriorate and the surface will be likely to be chilled, and if it is more than this, plate-like cementite will not grow. In other words, it is possible to achieve a balance between toughness and hardness.

なお、Mnを0.4〜1.1%添加しているか板状ステ
ダイト生成には効果はない。
Note that adding 0.4 to 1.1% of Mn has no effect on the formation of plate-like steadite.

次に、Cu−Ca添加による効果は、パーライト部のミ
クロ硬さ、マクロ硬さ、引張り強さに現れた。パーライ
ト部のミクロ硬さにはかなり顕著な効果が現れているが
、これはCuによるパーライトの緻密化効果によるもの
である。しかも、これがマクロ硬度になると、幼果が低
下しており、これは板状ステダイトの多量品出や、Pが
0.5%以上含まれている場合や、Cu−Caの接種効
果が飽和するなどの要因によると解明された。そのため
、共晶セルの微細化による耐摩耗性向上のために、しか
も、Cuによる耐酸腐食摩耗向上のために、C11・C
a接種添加は0.8〜1.2%がよいことが判明した。
Next, the effect of adding Cu-Ca appeared in the micro-hardness, macro-hardness, and tensile strength of the pearlite part. A fairly remarkable effect appears on the microhardness of the pearlite portion, and this is due to the densification effect of the pearlite due to Cu. Moreover, when it comes to macro hardness, the young fruits are reduced, and this is due to the production of large quantities of plate-like steadite, when P content is more than 0.5%, and when the inoculation effect of Cu-Ca is saturated. It was determined that this was due to factors such as: Therefore, in order to improve the wear resistance by making the eutectic cells finer, and also to improve the acid corrosion wear resistance due to Cu, C11・C
It was found that 0.8 to 1.2% of the a inoculum is suitable.

かかる場合、海水直冷ライナに好適である。In such a case, it is suitable for a seawater directly cooled liner.

なお、本発明に加えて、耐酸腐食性向上であれば、純C
u添加だけでもよく、Cuは0.7〜1.1%の範囲が
よいことが判明した。
In addition to the present invention, if the acid corrosion resistance is improved, pure C
It has been found that it is sufficient to add only u, and that a range of 0.7 to 1.1% of Cu is good.

本発明は叙上の構成を採択したので、以下の試験例にみ
られるごとき効果を奏する。
Since the present invention adopts the configuration described above, it produces effects as seen in the following test examples.

〔試験例〕[Test example]

第1表のごとき供試材(Nllからぬ10までのもの)
を用いて、第2表のごとき、摩耗結果が得られた。
Sample materials as shown in Table 1 (from Nll to 10)
Using this, the wear results shown in Table 2 were obtained.

I     ゛  − −」ユ」:]H重ステ イトオとCrメッキの、 毛・
相手材はCrメッキを施した高りん鋳物である通常のピ
ストンリング材で、これらを試験した結果、第2表でみ
られるごとく、本発明である−1、漱2、ぬ3および嵐
9は成績が良好でいずれも、硬い板状ステダイトを晶出
させたもので、特にCu・Caによりマトリックを強化
したものが優れた耐摩耗性を示している。従来例のm5
 (B糸)は、本発明のCr系板状ステダイト材より劣
っており、Ih4 (V系)の特殊ステダイトば1lh
5と同等であるが、これはVの方がCとのM、相方が強
いためである。このため、■は単独でV炭化物を晶出し
やすい。しかしながら、セメンタイト中のFeとは、C
rの方が置換されやすく、Crの方がセメンタイトの中
に入りやすい、その結果、板状ステダイト生成にはCr
の方が有利であって、画表のごとき結果かえられたので
ある。
I ゛--"Yu":] H heavy state o and Cr plated hair.
The mating material was a normal piston ring material which is a Cr-plated high phosphorus casting, and as a result of testing these, as seen in Table 2, the present inventions -1, Sou2, Nu3 and Arashi9. The results were good, and all of them were made by crystallizing hard plate-like steadite, and in particular, those whose matrix was reinforced with Cu/Ca showed excellent wear resistance. Conventional m5
(B yarn) is inferior to the Cr-based plate-shaped steadite material of the present invention, and the special steadite material of Ih4 (V series) is 1lh.
It is equivalent to 5, but this is because V has a stronger M partner with C. For this reason, ■ alone tends to crystallize V carbide. However, Fe in cementite is C
r is more easily substituted, and Cr is more likely to enter cementite. As a result, Cr
It was more advantageous, and the result was changed as shown in the diagram.

しかも、V、Bともに溶湯コストが1lIi価(例えば
阻8を100とした場合、階4で120、Na5で11
5)であるのに対し、本発明は安価(104)となって
いる。
Moreover, the molten metal cost for both V and B is 1lIi value (for example, if 8 is 100, it is 120 for floor 4 and 11 for Na5.
5), whereas the present invention is inexpensive (104).

なお、本発明の板状ステダイトのミクロ硬度HMVは9
00−1200で、一般ノステダイトの硬さよりはるか
に硬く、かかる点が第2表に表示されている。
The microhardness HMV of the plate-shaped Steadite of the present invention is 9.
00-1200, which is much harder than that of common nostedite, and these points are shown in Table 2.

なお、また本発明の板状ステダイトを生成する合金の製
造方法は、従来例で示した例えばV添加の特殊ステダイ
トを生成した合金の製造方法と同様である。
Furthermore, the method for producing the alloy that produces the plate-shaped steadite of the present invention is the same as the method for producing the alloy that produced the special steadite containing, for example, V added in the conventional example.

Claims (3)

【特許請求の範囲】[Claims] (1)T、C2.8〜3.6%を含有し、残部Feであ
る鋳物に、Pを0.3〜0.9%、Crを0.6〜0.
9%、Siを1.3〜1.8%の範囲内で添加すること
により板状ステダイトを生成したディーゼル機関用シリ
ンダライナ。
(1) A casting containing 2.8 to 3.6% of T and C, with the balance being Fe, and 0.3 to 0.9% of P and 0.6 to 0.0% of Cr.
A cylinder liner for a diesel engine in which plate-shaped steadite is produced by adding 9% and Si in a range of 1.3 to 1.8%.
(2)Cu・Caを接種添加した特許請求の範囲第(1
)項に記載のディーゼル機関用シリンダライナ。
(2) Claim No. 1 (1) inoculating and adding Cu/Ca
Cylinder liner for diesel engines described in ).
(3)Cuを添加した特許請求の範囲第(1)項に記載
のディーゼル機関用シリンダライナ。
(3) The cylinder liner for a diesel engine according to claim (1), to which Cu is added.
JP25969684A 1984-12-08 1984-12-08 Cylinder liner for diesel engine Pending JPS61136659A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP25969684A JPS61136659A (en) 1984-12-08 1984-12-08 Cylinder liner for diesel engine

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP25969684A JPS61136659A (en) 1984-12-08 1984-12-08 Cylinder liner for diesel engine

Publications (1)

Publication Number Publication Date
JPS61136659A true JPS61136659A (en) 1986-06-24

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JP25969684A Pending JPS61136659A (en) 1984-12-08 1984-12-08 Cylinder liner for diesel engine

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JP (1) JPS61136659A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02104653A (en) * 1988-10-13 1990-04-17 Yanmar Diesel Engine Co Ltd Cylinder liner for internal-combustion engine and combination of cylinder liner with piston ring
JP2012188720A (en) * 2011-03-14 2012-10-04 Hino Motors Ltd Cast iron and cylinder liner produced from the cast iron
JP2012188719A (en) * 2011-03-14 2012-10-04 Hino Motors Ltd Cast iron and cylinder liner produced from the cast iron

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4959025A (en) * 1972-10-11 1974-06-07
JPS5131617A (en) * 1974-09-11 1976-03-17 Toyota Motor Co Ltd TAIMAMOCHUTETSUOSEIZOSURU HOHO
JPS57194241A (en) * 1981-05-26 1982-11-29 Yanmar Diesel Engine Co Ltd Wear resistant cast ferroalloy

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4959025A (en) * 1972-10-11 1974-06-07
JPS5131617A (en) * 1974-09-11 1976-03-17 Toyota Motor Co Ltd TAIMAMOCHUTETSUOSEIZOSURU HOHO
JPS57194241A (en) * 1981-05-26 1982-11-29 Yanmar Diesel Engine Co Ltd Wear resistant cast ferroalloy

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02104653A (en) * 1988-10-13 1990-04-17 Yanmar Diesel Engine Co Ltd Cylinder liner for internal-combustion engine and combination of cylinder liner with piston ring
JP2012188720A (en) * 2011-03-14 2012-10-04 Hino Motors Ltd Cast iron and cylinder liner produced from the cast iron
JP2012188719A (en) * 2011-03-14 2012-10-04 Hino Motors Ltd Cast iron and cylinder liner produced from the cast iron

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