JPS61135791A - Thermal transfer recording sheet - Google Patents
Thermal transfer recording sheetInfo
- Publication number
- JPS61135791A JPS61135791A JP59256526A JP25652684A JPS61135791A JP S61135791 A JPS61135791 A JP S61135791A JP 59256526 A JP59256526 A JP 59256526A JP 25652684 A JP25652684 A JP 25652684A JP S61135791 A JPS61135791 A JP S61135791A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- thermal transfer
- recording sheet
- film
- antistatic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/423—Intermediate, backcoat, or covering layers characterised by non-macromolecular compounds, e.g. waxes
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Printing Methods (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は感熱転写記録用シートに関するものであり、特
にカラー画像を形成しうるオーバーヘッドプロジェクタ
−（以下にＯＨＰと略す）用シートに関するものである
。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a thermal transfer recording sheet, and particularly to a sheet for an overhead projector (hereinafter abbreviated as OHP) that can form a color image. .
従来、ＯＨＰ用シートは手書き原稿や電子写真方式で記
録されたシートを透過光或は反射光を用い投影するため
に使用されている。現在は黒色の文字や図形等の画像を
複写したシートが使用されている。Conventionally, OHP sheets have been used to project handwritten manuscripts or sheets recorded by electrophotography using transmitted light or reflected light. Currently, sheets with black characters, figures, and other images copied thereon are used.
しかし、近年カラー画像が投影可能な０ｆ−ＩＰ用レシ
ート対する要望が強くなってきている。However, in recent years, there has been a strong demand for Of-IP receipts on which color images can be projected.
カラー画像をうる方式としては、インジェット記録方式
、熱転写記録方式、電子写真方式などの画像形成方式が
ある。これらの方式のうち、サーマルヘッドを用いる熱
転写記録方式が騒音の少ないこと、装置が比較的廉価か
つコンパクトにできること、保守性に優れること、等の
利点があり多く用いられるようになってきた。As methods for producing color images, there are image forming methods such as an in-jet recording method, a thermal transfer recording method, and an electrophotographic method. Among these methods, the thermal transfer recording method using a thermal head has come to be widely used because of its advantages such as low noise, the ability to make the device relatively inexpensive and compact, and excellent maintainability.
しかし、従来の電子写真方式に使用される０ト！Ｐ用シ
ートは、フィルムに軟化点の高い樹脂を塗工しているた
めに、勢転写方式の複写機で複写した時には、インクが
転写しない欠点がある。また未処理のフィルムを使用し
た時は、インクの受理性が劣り、さらに静電気により複
写機での搬送性が悪いという欠点がある。However, the 0 to! used in conventional electrophotography methods! Since the P sheet is coated with a resin having a high softening point, it has the disadvantage that ink is not transferred when it is copied using a photocopying machine using a force transfer method. Furthermore, when an untreated film is used, there are drawbacks such as poor ink receptivity and poor transportability in a copying machine due to static electricity.
本発明者ｉ前述の実状に鑑み、熱転写方式の複写機での
インク受理性のよい塗工層と複写機での搬送性と帯電防
止効果について検討した結果、熱転写方式複写機での複
写性と搬送性の優れたＯＨＰ用シートを見い出し、本発
明に達した。In view of the above-mentioned actual situation, the inventor has investigated the coating layer with good ink receptivity in a thermal transfer copying machine, the transportability in the copying machine, and the antistatic effect. An OHP sheet with excellent transportability was discovered and the present invention was achieved.
本発明はフィルムの−５の面には熱により溶融するイン
クの受理層を、片方の面には滑り性と帯電防止性を寄与
した層を夫々設けた記録用シートを提供したもので、本
発明は５０℃ないし１１０℃の軟化点を有する樹脂組成
物と、帯電防止処理剤をフィルム上に塗工してなるＯＨ
Ｐ用シートである。The present invention provides a recording sheet in which an ink-receiving layer that melts by heat is provided on the -5 side of the film, and a layer that contributes to slipperiness and antistatic properties is provided on one side. The invention is an OH film obtained by coating a resin composition having a softening point of 50°C to 110°C and an antistatic treatment agent on a film.
This is a sheet for P.
〔作 用〕 以下に、図面に従い本発明の詳細な説明する。[For production] The present invention will be described in detail below with reference to the drawings.
まず、第１図は模式断面を示し、図中の１はフィルムで
あ、る。このフィルムは、ポリエステルフィルム、ポリ
プロピレンフィルム、セルロースフィルム、ポリイミド
フィルム、ポリカーボネートフィルムなどの透明なプラ
スチックフィルムであり、かつインク転写時の熱による
変形が起らないフィルムである。First, FIG. 1 shows a schematic cross section, and 1 in the figure is a film. This film is a transparent plastic film such as a polyester film, polypropylene film, cellulose film, polyimide film, or polycarbonate film, and is a film that does not undergo deformation due to heat during ink transfer.
次に、図中の２は、熱転写インク受理層である。本発明
に使用される塗工層は５０℃ないし１１０℃で軟化する
樹脂を配合した塗工剤組成物である。使用される樹脂と
しては、ポリエチレン。Next, 2 in the figure is a thermal transfer ink receiving layer. The coating layer used in the present invention is a coating composition containing a resin that softens at 50°C to 110°C. The resin used is polyethylene.
ポリ塩化ビニル、ポリスチレン、ポリアクリロニトリル
、ポリ酢酸ビニル、ポリビニルブチラール、ポリアクリ
ル酸エステル、ポリアミド。Polyvinyl chloride, polystyrene, polyacrylonitrile, polyvinyl acetate, polyvinyl butyral, polyacrylic acid ester, polyamide.
ポリエステル、ポリビニルアルコール及びこれらの共重
合体等があげられる。さらにこれらの樹脂に、ポリエチ
レングリコール、塩素化パラフィン等の可塑剤も添加で
きる。Examples include polyester, polyvinyl alcohol, and copolymers thereof. Furthermore, plasticizers such as polyethylene glycol and chlorinated paraffin can also be added to these resins.
いずれも５０℃ないし１１℃で軟化する樹脂であり、５
０℃より低い軟化温度をもつ樹脂は、多数枚重ねて放置
した時にブロッキングを起すために好ましくない。Both are resins that soften at 50°C to 11°C, and
Resins with a softening temperature lower than 0° C. are not preferred because they cause blocking when stacked in large numbers.
また、１１０’Ｃ以上の軟化温度をもつ樹脂は、サーマ
ルヘッドで転写されるインクの軟化温度よりも高いため
にインクが受理層へ転写せず、またインクの密着性が悪
くなるという欠点がある。In addition, resins with a softening temperature of 110'C or higher have the disadvantage that the ink is not transferred to the receiving layer because it is higher than the softening temperature of the ink transferred by the thermal head, and the ink adhesion is poor. .
これらの樹脂を溶解する溶剤としては、アルコール類、
ケトン類などの有機溶剤及び水の使用が可能である。Solvents that dissolve these resins include alcohols,
Organic solvents such as ketones and water can be used.
さらに、インク受理層とインクシートとの滑り性を向上
させる目的で顔料を添加することもできる。その添加量
は樹脂１００重ｆｆｉ部に対し１０重量部以下が望まし
いが、該フィルムの霞度が１５％以下であれば、ＯＨＰ
での投影に支障がないので、これ以上顔料を添加するこ
ともできる。Furthermore, a pigment may be added for the purpose of improving the slipperiness between the ink receiving layer and the ink sheet. The amount added is preferably 10 parts by weight or less per 100 parts by weight of the resin, but if the haze of the film is 15% or less, OHP
It is possible to add more pigments since this does not affect projection.
次に図中の３は帯電防止層である。カチオン系界面活性
剤、４級化塩型アクリル樹脂等の公知の水溶性及び有機
溶剤可溶性の帯電防止剤が使用できるが、熱転写複写機
各部、つまり搬送ロール、プラテンロールなどとの漬り
性のよいものが望ましい。滑り性の悪いものは搬送ジャ
ムの原因となるために好ましくない。Next, 3 in the figure is an antistatic layer. Known water-soluble and organic solvent-soluble antistatic agents such as cationic surfactants and quaternized salt-type acrylic resins can be used; A good one is desirable. Materials with poor slipperiness are undesirable because they may cause conveyance jams.
また、表面電気抵抗値は１ Ｘ １０ ＩｓΩ以下であ
ることが必要である。１ＱｌｓΩ以上では静電気の発生
により、該シート取り扱い時に、塵埃が付着しやすくな
り、インク転写時に印字ぬけの原因となる。Further, the surface electrical resistance value needs to be 1×10 IsΩ or less. When it is 1QlsΩ or more, static electricity is generated, which makes it easy for dust to adhere when the sheet is handled, which causes print omission during ink transfer.
更に、熱転写インク受理層及び帯電防止層の塗工方法で
あるが、公知の方法（ロールコーティング法、ロッドバ
ーコーティング法、スプレーコーティング法）により、
インク受理層については１〜１０ｇ／ｍ実用的には２〜
４ｇ／ｍ、帯電防止層については、０．０１〜３ｇ／Ｔ
ｄ実用的には０．０５〜２９／況程度塗工することがよ
い。Furthermore, as for the coating method of the thermal transfer ink receiving layer and the antistatic layer, a known method (roll coating method, rod bar coating method, spray coating method),
For the ink receiving layer, 1 to 10 g/m, practically 2 to 10 g/m.
4g/m, 0.01-3g/T for antistatic layer
dPractically speaking, it is preferable to apply the coating at a rate of about 0.05 to 29/cm.
そして、このような塗工層が設けられた後、可及的速か
に塗工層の乾燥が行なわれる。After such a coating layer is provided, the coating layer is dried as soon as possible.
（実施例〕
以下に本発明をより具体的に説明するために実施例を掲
げる。以下に示す部は全て重畿部である。(Examples) Examples are listed below to explain the present invention more specifically.All the sections shown below are heavy sections.
実施例１
１、熱転写インク受理層
ポリアクリル酸エステル樹脂 １００部（日本アク
リル製・プライマルＡＣ６１）二酸化ケイ素
３部く富士デビソン製・サイロイド９７８）
水
５０部２、帯電防止層
カチオン系界面活性剤 １部（古村油化工
業製・エリーク５ＥＩ５２）メタノール
１００部この塗工液２を厚さ５０μｍのポリエ
ステルフィルム（東し製・ルミラー）の表面に、バーコ
ーティング法により塗工し、乾燥後の厚さが１ｇ／Ｔｄ
となるようにした。次に裏面に塗工液１を同様に塗工し
、乾燥後の厚さを２ｇ／ＴＩｔとした。Example 1 1. Thermal transfer ink receiving layer polyacrylic acid ester resin 100 parts (Nippon Acrylic, Primal AC61) silicon dioxide
3 parts manufactured by Fuji Davison, Cyroid 978)
water
50 parts 2, antistatic layer cationic surfactant 1 part (manufactured by Furumura Yuka Kogyo, Elique 5EI52) methanol
100 parts of this coating solution 2 was coated on the surface of a 50 μm thick polyester film (Lumirror, manufactured by Toshi) by the bar coating method, and the thickness after drying was 1 g/Td.
I made it so that Next, Coating Liquid 1 was similarly applied to the back side, and the thickness after drying was set to 2 g/TIt.
このようにして与えられた熱転写記録シートを未処理ポ
リエステルフィルムと比較すると、表１の如く、インク
の受理性、複写時の搬送性。When the thermal transfer recording sheet thus obtained is compared with an untreated polyester film, as shown in Table 1, the ink receptivity and transportability during copying are evaluated.
帯電防止性の優れた性能を示していた。It showed excellent antistatic performance.
実施例２
１、熱転写インク受理層
ポリ酢酸ビニル樹脂 １００部（ヘキスト
合成製・モビニールＤＣ）
メタノール ５０部２、帯電防止
層
カチオン系アクリル樹脂 １部（ハマノ工業
製・ハマコートＥＳ １５０）メタノール
１００部実Ｉ＃ｉＶ／４１と同様に塗工乾燥
し、熱転写記録シートを得た。実施例１と同様に優れた
性能を示した。Example 2 1. Thermal transfer ink receiving layer polyvinyl acetate resin 100 parts (manufactured by Hoechst Synthesis, Movinyl DC) methanol 50 parts 2. Antistatic layer cationic acrylic resin 1 part (manufactured by Hamano Industries, Hamakote ES 150) methanol
A 100-part sample was coated and dried in the same manner as I#iV/41 to obtain a thermal transfer recording sheet. Similar to Example 1, excellent performance was shown.
（発明の効果）
本発明によれば表１に出すように、熱転写複合機でのイ
ンク受理性と搬送性の優れたＯＨＰ用記録シートが得ら
れた。(Effects of the Invention) According to the present invention, as shown in Table 1, an OHP recording sheet with excellent ink receptivity and transportability in a thermal transfer multifunction machine was obtained.
表１
く使用機種＞ ＣＨ３２０１（セイコー電子工業製
）く評価方法〉 ◎：特に良好 Ｏ：良好 Ｘ：
不良Table 1 Frequently used models> CH3201 (Seiko Electronics Industries) Evaluation method> ◎: Particularly good O: Good X:
defective
第１図は本発明の記録シートの模式断面図である。図面
中１・・・フィルム、２・・・インキ受理層。
３・・・帯電防止層
手続補正書（自説
昭和６０年３月１日
昭和５９年 特許願 第２５６５２６号２、発明の名称
感熱転写記録用シート
補 正 の 内 容
１ 、 明［ＩＬｔｌＦ５ｉ１ 行目ニ「１１℃」とあ
るを
「１１０℃」と訂正。
２、明細書第８頁末行に
［合Ｉ］とあるを
「写機」と訂正。FIG. 1 is a schematic cross-sectional view of the recording sheet of the present invention. In the drawing, 1...film, 2...ink receiving layer. 3...Antistatic layer procedural amendment (Own paper March 1, 1985 Patent Application No. 256526 2, Title of invention: Correction of thermal transfer recording sheet Contents 1, Bright [ILtlF5i 1st line 2 ``11℃'' was corrected to ``110℃.'' 2. On the last line of page 8 of the specification, the ``I'' was corrected to ``photographing machine.''
Claims (3)
の受理層を設け、かつ反対面には滑り性と帯電防止性を
付与した層を設けたことを特徴とする記録用シート。(1) A recording sheet characterized by having an ink-receiving layer that melts due to heat provided on one surface of the film, and a layer imparting slipperiness and antistatic properties provided on the opposite surface.
０℃ないし１１０℃で軟化し、かつまた反対面の表面電
気抵抗値は１×１０＾１＾５Ω以下であることを特徴と
する特許請求の範囲第１項記載の記録シート。(2) There are 5 ink receiving layers that melt due to heat on one side surface.
2. The recording sheet according to claim 1, which softens at a temperature of 0° C. to 110° C. and has a surface electrical resistance value of 1×10^1^5 Ω or less on the opposite side.
とする特許請求の範囲第１項又は第２項記載の記録用シ
ート。(3) The recording sheet according to claim 1 or 2, wherein the recording sheet has a haze of 15% or less.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59256526A JPS61135791A (en) | 1984-12-06 | 1984-12-06 | Thermal transfer recording sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59256526A JPS61135791A (en) | 1984-12-06 | 1984-12-06 | Thermal transfer recording sheet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61135791A true JPS61135791A (en) | 1986-06-23 |
| JPH0440196B2 JPH0440196B2 (en) | 1992-07-02 |
Family
ID=17293845
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59256526A Granted JPS61135791A (en) | 1984-12-06 | 1984-12-06 | Thermal transfer recording sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61135791A (en) |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61197284A (en) * | 1985-02-28 | 1986-09-01 | Dainippon Printing Co Ltd | Thermal transfer sheet |
| JPS61197283A (en) * | 1985-02-28 | 1986-09-01 | Dainippon Printing Co Ltd | Thermal transfer recording sheet |
| JPS62162592A (en) * | 1985-12-16 | 1987-07-18 | ミネソタ マイニング アンド マニユフアクチユアリング カンパニ− | Receptor sheet for heat mass transfer printing |
| JPS6378788A (en) * | 1986-09-22 | 1988-04-08 | Fuji Photo Film Co Ltd | Image receiving sheet |
| JPS6387285A (en) * | 1986-09-30 | 1988-04-18 | Dainippon Printing Co Ltd | Thermal transfer recording sheet with adhesive layer |
| JPS6391286A (en) * | 1986-10-06 | 1988-04-21 | Dainippon Printing Co Ltd | Sheet to be thermo-transferred |
| JPS6395990A (en) * | 1986-10-13 | 1988-04-26 | Nec Corp | Thermal transfer recording material |
| JPS63121841A (en) * | 1986-11-12 | 1988-05-25 | Fuji Photo Film Co Ltd | Dye fixing element |
| JPS63194982A (en) * | 1987-02-09 | 1988-08-12 | Dainippon Printing Co Ltd | Thermal transfer sheet for forming transparent copy |
| JPS63222895A (en) * | 1987-03-12 | 1988-09-16 | Dainippon Printing Co Ltd | Thermal transfer recording sheet |
| JPS63262285A (en) * | 1987-04-21 | 1988-10-28 | Dainippon Printing Co Ltd | Thermal transfer sheet |
| JPS6444781A (en) * | 1987-08-13 | 1989-02-17 | Dainippon Printing Co Ltd | Sheet to be thermally transferred |
| JPS6445688A (en) * | 1987-08-17 | 1989-02-20 | Taiho Ind Co | Ohp sheet for thermal transfer |
| JPH01165485A (en) * | 1987-11-20 | 1989-06-29 | Eastman Kodak Co | Antistatic layer for dyestuff-accepting member used for heat transfer method |
| JPH01235694A (en) * | 1988-03-17 | 1989-09-20 | Taiho Ind Co Ltd | Thermal transfer ohp sheet |
| JPH02217283A (en) * | 1989-02-18 | 1990-08-30 | Taiho Ind Co Ltd | Medium to be recorded for overhead projector |
| JPH02276685A (en) * | 1989-01-11 | 1990-11-13 | Fuji Photo Film Co Ltd | Film for thermal transfer printer |
| JPH06199062A (en) * | 1987-04-21 | 1994-07-19 | Dainippon Printing Co Ltd | Production of sheet to be thermally transferred |
| EP0686510A1 (en) | 1994-06-10 | 1995-12-13 | Kao Corporation | Thermal transfer recording medium |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57129789A (en) * | 1981-02-05 | 1982-08-11 | Fuji Kagakushi Kogyo Co Ltd | Heat sensitive transferring material |
| JPS58171992A (en) * | 1982-04-01 | 1983-10-08 | Dainippon Printing Co Ltd | Heat sensitive transfer sheet |
-
1984
- 1984-12-06 JP JP59256526A patent/JPS61135791A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57129789A (en) * | 1981-02-05 | 1982-08-11 | Fuji Kagakushi Kogyo Co Ltd | Heat sensitive transferring material |
| JPS58171992A (en) * | 1982-04-01 | 1983-10-08 | Dainippon Printing Co Ltd | Heat sensitive transfer sheet |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61197284A (en) * | 1985-02-28 | 1986-09-01 | Dainippon Printing Co Ltd | Thermal transfer sheet |
| JPS61197283A (en) * | 1985-02-28 | 1986-09-01 | Dainippon Printing Co Ltd | Thermal transfer recording sheet |
| JPS62162592A (en) * | 1985-12-16 | 1987-07-18 | ミネソタ マイニング アンド マニユフアクチユアリング カンパニ− | Receptor sheet for heat mass transfer printing |
| JPS6378788A (en) * | 1986-09-22 | 1988-04-08 | Fuji Photo Film Co Ltd | Image receiving sheet |
| JPS6387285A (en) * | 1986-09-30 | 1988-04-18 | Dainippon Printing Co Ltd | Thermal transfer recording sheet with adhesive layer |
| JPS6391286A (en) * | 1986-10-06 | 1988-04-21 | Dainippon Printing Co Ltd | Sheet to be thermo-transferred |
| JPS6395990A (en) * | 1986-10-13 | 1988-04-26 | Nec Corp | Thermal transfer recording material |
| JPS63121841A (en) * | 1986-11-12 | 1988-05-25 | Fuji Photo Film Co Ltd | Dye fixing element |
| JPS63194982A (en) * | 1987-02-09 | 1988-08-12 | Dainippon Printing Co Ltd | Thermal transfer sheet for forming transparent copy |
| JPS63222895A (en) * | 1987-03-12 | 1988-09-16 | Dainippon Printing Co Ltd | Thermal transfer recording sheet |
| JPS63262285A (en) * | 1987-04-21 | 1988-10-28 | Dainippon Printing Co Ltd | Thermal transfer sheet |
| JPH06199062A (en) * | 1987-04-21 | 1994-07-19 | Dainippon Printing Co Ltd | Production of sheet to be thermally transferred |
| JPS6444781A (en) * | 1987-08-13 | 1989-02-17 | Dainippon Printing Co Ltd | Sheet to be thermally transferred |
| JPS6445688A (en) * | 1987-08-17 | 1989-02-20 | Taiho Ind Co | Ohp sheet for thermal transfer |
| JPH0466197B2 (en) * | 1987-08-17 | 1992-10-22 | Taiho Kogyo Co Ltd | |
| JPH01165485A (en) * | 1987-11-20 | 1989-06-29 | Eastman Kodak Co | Antistatic layer for dyestuff-accepting member used for heat transfer method |
| JPH01235694A (en) * | 1988-03-17 | 1989-09-20 | Taiho Ind Co Ltd | Thermal transfer ohp sheet |
| JPH02276685A (en) * | 1989-01-11 | 1990-11-13 | Fuji Photo Film Co Ltd | Film for thermal transfer printer |
| JPH02217283A (en) * | 1989-02-18 | 1990-08-30 | Taiho Ind Co Ltd | Medium to be recorded for overhead projector |
| JPH0476788B2 (en) * | 1989-02-18 | 1992-12-04 | Taiho Kogyo Co Ltd | |
| EP0686510A1 (en) | 1994-06-10 | 1995-12-13 | Kao Corporation | Thermal transfer recording medium |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0440196B2 (en) | 1992-07-02 |
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