JPS61129028A - Apparatus for treating exhaust gas - Google Patents

Apparatus for treating exhaust gas

Info

Publication number
JPS61129028A
JPS61129028A JP59250140A JP25014084A JPS61129028A JP S61129028 A JPS61129028 A JP S61129028A JP 59250140 A JP59250140 A JP 59250140A JP 25014084 A JP25014084 A JP 25014084A JP S61129028 A JPS61129028 A JP S61129028A
Authority
JP
Japan
Prior art keywords
absorbent
exhaust gas
cage mill
supplied
dry
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP59250140A
Other languages
Japanese (ja)
Other versions
JPS6247571B2 (en
Inventor
Katsuo Sekiguchi
関口 勝雄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Furukawa Mining Co Ltd
Original Assignee
Furukawa Mining Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Furukawa Mining Co Ltd filed Critical Furukawa Mining Co Ltd
Priority to JP59250140A priority Critical patent/JPS61129028A/en
Publication of JPS61129028A publication Critical patent/JPS61129028A/en
Publication of JPS6247571B2 publication Critical patent/JPS6247571B2/ja
Granted legal-status Critical Current

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  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)

Abstract

PURPOSE:To obtain the title apparatus requiring no large equipment, having high removal efficiency and capable of widely corresponding to the change in the property of exhaust gas or the alteration of a prescribed value, by providing a cage mill, which diffuses an absorbent throughout exhaust gas, on the way of an exhaust gas duct. CONSTITUTION:The absorbent supplied from an absorbent supply apparatus 6 is stirred and crushed by the cage mill provided on the way of the exhaust duct 1 of an urban garbage incinerator and discharged into exhaust gas at a high speed to be diffused therein. When exhaust prescription is enforced, water is supplied to the absorbent from a humidifier 14 and the wetted absorbent kneaded by a screw feeder 13 is supplied to the cage mill 7. The wetted absorbent is contacted with exhaust gas in a reaction part 8 and perfoms absorbing reaction to be converted to a dry powder which is, in turn, collected by an electric precipitator 2. In this case, the same removal ratio of harmful gas as a semi-dry system is obtained.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 この発明は、都市塵芥焼却炉等の排ガス中のHCl、な
どの有害ガスを処理する装置に関し、排ガスダクト中に
ケージミルを設けて有害ガスの吸収剤を排ガス中へ拡散
させ除去効率を向上させるものである。
[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a device for treating harmful gases such as HCl in the exhaust gas of municipal waste incinerators, etc., and a cage mill is provided in the exhaust gas duct to remove the harmful gases. This improves the removal efficiency by diffusing the absorbent into the exhaust gas.

〔従来の技術〕[Conventional technology]

一般に、都市塵芥中には、塩化ビニール、厨芥中の食塩
分その他雑多なものが含まれるため、都市塵芥焼却炉の
排ガス中には、HCI、SOx等の有害ガスが含まれて
いる。特に、HCIは、数 。
In general, municipal waste contains vinyl chloride, salt in kitchen waste, and other miscellaneous substances, so the exhaust gas from municipal waste incinerators contains harmful gases such as HCI and SOx. In particular, HCI has a number of

百ないし、2000ppmの高濃度となり、この排出は
、法律上規制されている。この有害ガスを捕集除去する
装置として、従来、水洗等の湿式ガス処理装置、排ガス
ダクト中に消石灰等の粉状の吸収剤を注入し、反応吸収
剤を後段の集塵器で捕集する乾式ガス処理装置、消石灰
スラリーを蒸発反応塔内に噴霧し、反応生成物は乾燥粉
体として集塵器で捕集する半乾式ガス処理装置が用いら
れていた。
The concentration is as high as 100 to 2000 ppm, and this emission is regulated by law. Conventionally, devices for collecting and removing harmful gases include wet gas treatment equipment such as water washing, injecting powdered absorbent such as slaked lime into the exhaust gas duct, and collecting the reactive absorbent in a subsequent dust collector. Dry gas treatment equipment, semi-dry gas treatment equipment was used in which slaked lime slurry was sprayed into the evaporation reaction tower and the reaction product was collected as dry powder in a dust collector.

〔発明が解決しようとする問題点〕[Problem that the invention seeks to solve]

湿式ガス処理装置は、除去率は高いが、別途排水処理を
行なう必要がある上に、塩酸等による腐蝕のため補修費
が嵩み、一方、乾式ガス処理装置は、設備費は安価であ
るが除去率が低く、出口430ppmの規制には対応で
きるが公害防止のための排出規制の強化(例えば200
ppm以下の如き上乗せ規制)に対しては吸収剤の増量
によっても十分に対応できない。これに対し、半乾式ガ
ス処理装置は、乾式に比べて除去率が高く規制強化に対
応でき、湿式の如き排水処理も必要としない利点がある
Wet gas treatment equipment has a high removal rate, but requires separate wastewater treatment and is expensive to repair due to corrosion caused by hydrochloric acid, etc. On the other hand, dry gas treatment equipment has low equipment costs, but The removal rate is low, and it is possible to comply with the regulation of 430 ppm at the outlet, but it is necessary to strengthen the emission regulation to prevent pollution (for example, 200 ppm).
Even if the amount of absorbent is increased, it is not possible to sufficiently meet the additional regulations such as ppm or less. On the other hand, semi-dry gas treatment equipment has the advantage that it has a higher removal rate than the dry type, can comply with stricter regulations, and does not require wastewater treatment like the wet type.

しかしながら、この半乾式も、消石灰スラリーを完全に
乾燥状態にするためには、大形の蒸発反応塔が必要であ
り、また、排ガスの量や温度やHCl5度の変化が大き
い場合、スラリーの濃度や噴霧量の調節が難かしく、排
ガス量が減少したり低温になると、スラリーの藩発が不
完全となり、スラリーの後段機器への付着固化、噴霧ノ
ズルの詰りなどを生ずる虞れがある。
However, this semi-dry type also requires a large evaporation reaction tower to completely dry the slaked lime slurry, and if there are large changes in the amount of exhaust gas, temperature, or HCl5 degree, the concentration of the slurry It is difficult to adjust the amount of spray and the amount of spray, and if the amount of exhaust gas decreases or the temperature becomes low, the slurry will not be generated completely, and there is a risk that the slurry will stick to downstream equipment and clog the spray nozzle.

この発明は、排ガス処理装置における上記問題を解決す
るものである。
This invention solves the above-mentioned problems in an exhaust gas treatment device.

而して、この発明の目的は、大形設備を必要とせず、除
去率の高い排ガス処理装置を提供するにあり、また、こ
の発明の目的は、排ガス性状の変化や、規制値の変更に
幅広く対応できる排ガス処理装置を提供するにある。
SUMMARY OF THE INVENTION An object of the present invention is to provide an exhaust gas treatment device that does not require large-scale equipment and has a high removal rate. The purpose of the present invention is to provide an exhaust gas treatment device that can be used in a wide range of applications.

〔問題点を解決するための手段〕[Means for solving problems]

この発明の排ガス処理装置は、集塵器へ接続される排ガ
スダクトの途中に、吸収剤供給装置から供給される吸収
剤を排ガス中へ拡散させるケージミルを設け、排ガスの
性状と規制値に応じて乾燥または加湿された吸収剤を供
給装置からケージミルへ供給することにより排ガス処理
を行なう。
The exhaust gas treatment device of this invention is provided with a cage mill that diffuses the absorbent supplied from the absorbent supply device into the exhaust gas in the middle of the exhaust gas duct connected to the dust collector, and according to the properties and regulation values of the exhaust gas. Exhaust gas treatment is performed by supplying dry or humidified absorbent from a supply device to a cage mill.

〔作用〕[Effect]

この発明のガス処理装置では、吸収剤をケージ   。 In the gas treatment device of this invention, the absorbent is caged.

ミルのロータで解砕、攪拌し、排ガス中へ拡散させるた
め、乾燥吸収剤を用いる場合も従来の乾式ガス処理装置
に比べて接触効率が良(除去率が高くなり、更に高い除
去率が要求されるときには、ケージミルへ加湿吸収剤を
供給することにより、特に蒸発反応塔の如き設備を要せ
ず半乾式ガス処理装置と同様の除去率を達成でき、しか
もノズルの詰りの如きトラブルは発生しない。
Because the rotor of the mill crushes, stirs, and diffuses into the exhaust gas, even when using a dry absorbent, the contact efficiency is better than that of conventional dry gas treatment equipment (higher removal rate, and even higher removal rates are required). By supplying a humidifying absorbent to a cage mill, it is possible to achieve the same removal rate as a semi-dry gas treatment device without requiring special equipment such as an evaporation reaction tower, and without problems such as nozzle clogging. .

〔実施例〕〔Example〕

以下、図面を参照してこの発明の詳細な説明する。第1
図は、この発明の一実施例である排ガス処理装置の構成
を示す説明図であり、都市塵芥焼却炉(図示せず)の排
ガスダクト1が、電気集塵器2へ接続され、この集塵器
2から処理ガスダクト3が排風機4を経て煙突5へと接
続されている。
Hereinafter, the present invention will be described in detail with reference to the drawings. 1st
The figure is an explanatory diagram showing the configuration of an exhaust gas treatment device that is an embodiment of the present invention, in which an exhaust gas duct 1 of a municipal waste incinerator (not shown) is connected to an electrostatic precipitator 2, and the dust collector A processing gas duct 3 is connected from the vessel 2 to a chimney 5 via an exhaust fan 4.

排ガスダクト1の途中には、吸収剤供給装置6から供給
される吸収剤を排ガス中へ拡散させるケージミル7が設
けられており、排ガスダクト1のケージミル7から電気
集塵機2までの部分が反応部8を形成している。
A cage mill 7 is provided in the middle of the exhaust gas duct 1 to diffuse the absorbent supplied from the absorbent supply device 6 into the exhaust gas, and the portion of the exhaust gas duct 1 from the cage mill 7 to the electrostatic precipitator 2 is a reaction section 8. is formed.

吸収剤供給装置6は、吸収剤輸送用タンク車10によっ
て搬入される吸収剤を貯留する吸収剤サイロ11と、吸
収剤サイロ11の底部に設けられた切出用のロークリバ
ルブ12と、ロータリバルブ12で切出された吸収剤を
移送しケージミル7へ投入するスクリューフィーダ13
と、スクリューフィーダ13内の吸収剤へ給水加湿する
加湿装置14とで構成されている。
The absorbent supply device 6 includes an absorbent silo 11 for storing absorbent carried in by a tank car 10 for transporting absorbent, a rotary valve 12 for cutting provided at the bottom of the absorbent silo 11, and a rotary valve 12. A screw feeder 13 transports the absorbent cut out and feeds it into the cage mill 7.
and a humidifier 14 that supplies water and humidifies the absorbent in the screw feeder 13.

スクリューフィーダ13には、複数のスクリュー15が
ケーシング1゛6内に並設されており、乾燥吸収剤をケ
ージミル7に供給する場合には、単にフィーダとして機
能し、加湿吸収剤を供給する場合には、加湿装置14か
ら水分を供給される吸収剤を攪拌、混練、調湿してケー
ジミル7へ投入する。
The screw feeder 13 has a plurality of screws 15 arranged in parallel inside the casing 1 and 6, and functions simply as a feeder when supplying dry absorbent to the cage mill 7, and functions only as a feeder when supplying humidified absorbent. The absorbent supplied with moisture from the humidifying device 14 is stirred, kneaded, and humidity-controlled, and then introduced into the cage mill 7.

ケージミル7は、公知の鉱石の気流乾燥装置に用いられ
るものと同様の構造であり、ケーシング17内に設けら
れたケージ状のロータ18が高速回転し、投入された吸
収剤を撹拌、解砕して高速で排ガス中へ放出し拡散させ
る。
The cage mill 7 has a structure similar to that used in a known ore flash drying device, and a cage-shaped rotor 18 provided in a casing 17 rotates at high speed to agitate and crush the introduced absorbent. It is released into the exhaust gas at high speed and diffused.

排出規制が厳しくない場合には、ケージミル7に乾燥吸
収剤を供給すれば、反応部8では従来の乾式に比べてよ
り完全な拡散が得られるため、有害ガスの除去率が向上
し吸収剤の使用量が低減される。
If emission regulations are not strict, supplying dry absorbent to the cage mill 7 will allow more complete diffusion in the reaction section 8 than in the conventional dry system, improving the removal rate of harmful gases and reducing the amount of absorbent. Usage is reduced.

排出規制が強化されたら、加湿装置14から吸収剤へ給
水し、スクリューフィーダ13で混練した加湿吸収剤を
ケージミル7へ供給する。ケージミル7は、加湿吸収剤
を十分に攪拌、解砕して排ガス中へ放出し、加湿吸収剤
は反応部8で排ガスと接触して吸収反応を行うと共に乾
燥されて乾燥粉体となり、集塵器2で補集される。この
場合には、この排ガス処理装置は、半乾式と同様の有害
ガスの除去率が得られ、1100pp以下の規制にも対
応できる。しかも、加湿吸収剤は、スクリューフィーダ
13によりケージミル7へ供給されるため、噴霧ノズル
が不要でノズルの詰りの如きトラブルは生じない。
When the discharge regulation is strengthened, water is supplied from the humidifier 14 to the absorbent, and the humidified absorbent kneaded by the screw feeder 13 is supplied to the cage mill 7. The cage mill 7 sufficiently stirs and crushes the humidifying absorbent and releases it into the exhaust gas, and the humidifying absorbent contacts the exhaust gas in the reaction section 8 to perform an absorption reaction and is dried to become a dry powder, which is then collected for dust collection. It is collected by instrument 2. In this case, this exhaust gas treatment device can obtain the same harmful gas removal rate as the semi-dry type, and can also comply with regulations of 1100 pp or less. Moreover, since the humidifying absorbent is supplied to the cage mill 7 by the screw feeder 13, a spray nozzle is unnecessary and troubles such as nozzle clogging do not occur.

この排ガス処理装置は、上記の如く規制値の変更に対応
できるほか、焼却炉の排ガスが高温でHCl等の含を量
の多い定常運転時には、加湿吸収剤を供給して高い除去
率を確保し、焼却炉の立上時、埋火時の如く、排ガスが
低温で有害ガス発生量が少ないときには乾燥吸収剤を供
給することにより集塵器への付着、固化を防止するよう
な切換え運転も可能である。
In addition to being able to respond to changes in regulatory values as described above, this exhaust gas treatment equipment supplies a humidifying absorbent to ensure a high removal rate during steady operation when the incinerator exhaust gas is high temperature and contains a large amount of HCl and other substances. When the flue gas is at a low temperature and the amount of harmful gas generated is small, such as when an incinerator is started up or a buried fire is started, it is possible to switch operation to prevent adhesion to the dust collector and solidification by supplying dry absorbent. It is.

なお、この実施例では、1台のスクリューフィーダ13
を設け、加湿装置14の給水と停止で加湿吸収剤と乾燥
吸収剤との切換えを行っているが、スクリューフィーダ
を加湿吸収剤用と乾燥吸収剤用との二基列とし、ダンパ
ー等で切換えるようにすることもできる。
In addition, in this embodiment, one screw feeder 13
The humidifying absorbent and the dry absorbent are switched by supplying and stopping the humidifying device 14, but the screw feeder is arranged in two rows, one for the humidifying absorbent and the other for the dry absorbent, and switching is performed using a damper or the like. You can also do it like this.

〔発明の効果〕〔Effect of the invention〕

この発明の排ガス処理装置は、上記の如く構成したため
、大形の蒸発反応塔の如き設備を必要とせず高い有害ガ
スの除去率が得られ、排ガスの性状の変化や規制値の変
更に幅広く対応でき、ノズルの詰りゃ集塵器への未乾燥
消石灰スラリーの付着、同化の如き運転上のトラブルを
防止することができる。
Since the exhaust gas treatment device of the present invention is configured as described above, it can achieve a high removal rate of harmful gases without requiring equipment such as a large evaporation reaction tower, and is widely compatible with changes in the properties of exhaust gas and changes in regulatory values. This can prevent operational troubles such as nozzle clogging, undried slaked lime slurry adhering to the dust collector, and assimilation.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は、この発明の一実施例である排ガス処理装置の
構成を示す発明図である。 図中、1は排ガスダクト、2は電気集塵器、6は吸収剤
供給装置、7はケージミル、11は吸収剤サイロ、12
はロータリバルブ、13はスクリューフィーダ、14は
加湿装置である。
FIG. 1 is an inventive diagram showing the configuration of an exhaust gas treatment device that is an embodiment of the present invention. In the figure, 1 is an exhaust gas duct, 2 is an electric precipitator, 6 is an absorbent supply device, 7 is a cage mill, 11 is an absorbent silo, 12
1 is a rotary valve, 13 is a screw feeder, and 14 is a humidifier.

Claims (2)

【特許請求の範囲】[Claims] (1)集塵器へ接続される排ガスダクトの途中に、吸収
剤供給装置から供給される吸収剤を排ガス中へ拡散させ
るケージミルを設けたことを特徴とする排ガス処理装置
(1) An exhaust gas treatment device characterized in that a cage mill is provided in the middle of an exhaust gas duct connected to a dust collector to diffuse an absorbent supplied from an absorbent supply device into the exhaust gas.
(2)吸収剤供給装置が加湿装置を備えており、加湿吸
収剤と乾燥吸収剤とを選択的に供給可能である特許請求
の範囲第1項記載の排ガス処理装置。
(2) The exhaust gas treatment device according to claim 1, wherein the absorbent supply device includes a humidifying device and can selectively supply a humidified absorbent and a dry absorbent.
JP59250140A 1984-11-27 1984-11-27 Apparatus for treating exhaust gas Granted JPS61129028A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP59250140A JPS61129028A (en) 1984-11-27 1984-11-27 Apparatus for treating exhaust gas

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP59250140A JPS61129028A (en) 1984-11-27 1984-11-27 Apparatus for treating exhaust gas

Publications (2)

Publication Number Publication Date
JPS61129028A true JPS61129028A (en) 1986-06-17
JPS6247571B2 JPS6247571B2 (en) 1987-10-08

Family

ID=17203412

Family Applications (1)

Application Number Title Priority Date Filing Date
JP59250140A Granted JPS61129028A (en) 1984-11-27 1984-11-27 Apparatus for treating exhaust gas

Country Status (1)

Country Link
JP (1) JPS61129028A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02230817A (en) * 1988-11-22 1990-09-13 Nec Corp Semiconductor integrated circuit
JP2008289953A (en) * 2007-05-22 2008-12-04 Takuma Co Ltd Fly ash supply apparatus, fly ash circulation system, and exhaust gas treatment facility

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02230817A (en) * 1988-11-22 1990-09-13 Nec Corp Semiconductor integrated circuit
JP2580805B2 (en) * 1988-11-22 1997-02-12 日本電気株式会社 Semiconductor integrated circuit
JP2008289953A (en) * 2007-05-22 2008-12-04 Takuma Co Ltd Fly ash supply apparatus, fly ash circulation system, and exhaust gas treatment facility

Also Published As

Publication number Publication date
JPS6247571B2 (en) 1987-10-08

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