JPS6111928B2 - - Google Patents
Info
- Publication number
- JPS6111928B2 JPS6111928B2 JP2449083A JP2449083A JPS6111928B2 JP S6111928 B2 JPS6111928 B2 JP S6111928B2 JP 2449083 A JP2449083 A JP 2449083A JP 2449083 A JP2449083 A JP 2449083A JP S6111928 B2 JPS6111928 B2 JP S6111928B2
- Authority
- JP
- Japan
- Prior art keywords
- antiperspirant
- composition
- liquid
- antiperspirant composition
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000001166 anti-perspirative effect Effects 0.000 claims description 41
- 239000003213 antiperspirant Substances 0.000 claims description 41
- 239000000203 mixture Substances 0.000 claims description 36
- 239000007788 liquid Substances 0.000 claims description 27
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 24
- 229920001296 polysiloxane Polymers 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 150000003839 salts Chemical class 0.000 description 11
- 229920002678 cellulose Polymers 0.000 description 8
- 239000001913 cellulose Substances 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 208000035985 Body Odor Diseases 0.000 description 4
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 4
- 206010040904 Skin odour abnormal Diseases 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 125000004122 cyclic group Chemical group 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 4
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000000306 component Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 230000035900 sweating Effects 0.000 description 3
- 230000002087 whitening effect Effects 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- -1 aluminum halide Chemical class 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000004034 viscosity adjusting agent Substances 0.000 description 2
- TURGQPDWYFJEDY-UHFFFAOYSA-N 1-hydroperoxypropane Chemical compound CCCOO TURGQPDWYFJEDY-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000003398 denaturant Substances 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229920003112 high viscosity grade hydroxypropyl cellulose Polymers 0.000 description 1
- 229920013821 hydroxy alkyl cellulose Polymers 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical group II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
本発明は新規な液状制汗剤組成物、更に詳しく
は制汗剤物質、一価の低級アルコール、揮発性シ
リコーン、アルコール可溶性セルロース誘導体及
び水を必須成分として含有した使用感に優れ、更
には長期間安定な透明液状制汗剤組成物に関す
る。
従来より、発汗を抑制し、また汗が分解して発
生するわきが等の体臭による悪臭を防止するため
に、制汗作用を有するアルミニウム塩等の金属塩
を含有させた液状の制汗剤組成物が用いられてき
た。しかるに、従来の液状制汗剤組成物は、制汗
作用を有する金属塩を水や水/エタノール混液ま
たはエタノールに溶解させ、これに目的に応じて
香料、粘度調整剤、可溶化剤、多価アルコール、
殺菌剤等を添加した組成であつたため使用時溶媒
が蒸散して金属塩が固化する過程で粘着性を生
じ、使用者に不快なべとつき感を与えたり、乾燥
に比較的長時間を要するため衣服が汚れやすいな
どの欠点を有していた。また、上記制汗剤組成物
中の溶媒が蒸散すると、金属塩の被膜が皮膚表面
に形成されるが、この金属塩の被膜には皮膚が有
するような弾性や柔軟性がないために皮膚に不快
なつつぱり感が生じて使用感が非常に悪いととも
に、被膜が生体の動きに伴つて生じる皮膚の伸縮
にそうことができないため、被膜に多数の細かな
亀裂が生じ制汗剤組成物を塗布した箇所が白い被
膜となり、体裁の悪い不快な外見を呈することに
もなつていた。更に、このように亀裂が生じた金
属塩被膜は皮膚への密着性が悪いため皮膚から剥
離されやすく、上記金属塩の有する制汗効果が十
分発揮されず、発汗の抑制や体臭の防止を有効に
行うことができない等の欠点を有していた。
本発明者らは従来の液状制汗剤組成物のもつ斯
様な欠点を改善すべく鋭意研究を進めた結果、今
般制汗剤物質を水及び一価低級アルコール系混合
溶媒に揮発性シリコーン及びアルコール可溶性セ
ルロース誘導体とともに溶解すれば、乾きが速
〓〓〓〓
く、べとつき感やつつぱり感が減少して使用感が
非常に良好であるとともに、制汗作用を有する金
属塩被膜の皮膚への密着性が良好でかつ亀裂が生
じ難く、このため発汗の抑制や体臭の防止を有効
に行うことができ、また、白化被膜が形成され
ず、使用感、安定性ならびに制汗効果の優れた液
状制汗剤組成物が得られることを見い出し、本発
明を完成した。
すなわち、本発明は
The present invention provides a novel liquid antiperspirant composition, more specifically, a novel liquid antiperspirant composition containing an antiperspirant substance, a monohydric lower alcohol, a volatile silicone, an alcohol-soluble cellulose derivative, and water as essential components, which has an excellent feeling of use, and further has a long-lasting use. The present invention relates to a transparent liquid antiperspirant composition that is stable over a period of time. Conventionally, liquid antiperspirant compositions containing metal salts such as aluminum salts that have an antiperspirant effect have been used to suppress sweating and prevent the bad odor caused by body odor such as armpits caused by the decomposition of sweat. has been used. However, conventional liquid antiperspirant compositions are made by dissolving a metal salt with an antiperspirant effect in water, a water/ethanol mixture, or ethanol, and then adding fragrances, viscosity modifiers, solubilizers, and polyhydric agents depending on the purpose. alcohol,
Because the composition contained disinfectants, etc., the solvent evaporates during use, and the metal salt becomes sticky during the solidification process, giving the user an unpleasant sticky feeling, and drying takes a relatively long time, making it difficult to wear clothes. However, it has disadvantages such as being easy to get dirty. In addition, when the solvent in the antiperspirant composition evaporates, a metal salt film is formed on the skin surface, but this metal salt film does not have the elasticity and flexibility that skin has, so it does not stick to the skin. An unpleasant feeling of tingling occurs, making it very uncomfortable to use.In addition, because the coating cannot accommodate the expansion and contraction of the skin that occurs with the movement of living organisms, many small cracks occur in the coating, making it difficult to use the antiperspirant composition. The applied area became a white film, giving it an unsightly and unpleasant appearance. Furthermore, the metal salt film with such cracks has poor adhesion to the skin and is easily peeled off from the skin, and the antiperspirant effect of the metal salt described above is not fully exerted, making it less effective in suppressing sweating and preventing body odor. However, it had disadvantages such as not being able to do so. The present inventors have carried out intensive research in order to improve the drawbacks of conventional liquid antiperspirant compositions, and as a result, we have now developed an antiperspirant material that contains volatile silicone and If dissolved together with alcohol-soluble cellulose derivative, drying becomes faster.
In addition, the metal salt coating, which has an antiperspirant effect, has good adhesion to the skin and is less prone to cracking, thus suppressing sweating. The present invention has been completed based on the discovery that a liquid antiperspirant composition can be obtained that can effectively prevent body odor and body odor, does not form a whitening film, and has excellent usability, stability, and antiperspirant effect. did. That is, the present invention
【表】
を含有し、かつ(ロ)一価低級アルコール、(ハ)揮発性
シリコーン及び水(ホ)水の各成分の相対比が、三角
座標上の次の各点、A(75.5:0.6:23.9)、B
(97.9:0.6:1.5)及びC(84.5:14.0:1.5)を結
んでできる三角形の内側(各辺上を含む)にある
液体制汗剤組成物を提供するものである。
本発明において、制汗剤物質とは公知の制汗剤
物質が使用でき、例えばハロゲン化アルミニウ
ム、ヒドロキシハロゲン化アルミニウム、ジルコ
ニルオキシハライド、ジルコニルヒドロキシハラ
イド等のアルミニウム、ジルコニウムの収斂性塩
及びアルミニウム、ジルコニウムの収斂性錯体を
単独若しくは混合して使用できる。これらの制汗
剤物質の中でも、アルミニウム収斂性塩が好適で
ある。アルミニウム収斂性塩の典型的なものとし
ては、塩化アルミニウムおよび一般式Al2(OH)n
Qo・xH2O(式中、Qは塩素、臭素または沃素を
示し、mは2〜5を示し、m+nは6であり、m
およびnは整数である必要はなく、xは約1〜6
である)のヒドロキシハロゲン化アルミニウムが
挙げられ、就中、Al2(OH)nClo・xH2Oのヒドロ
キシ塩化アルミニウムが最適である。
制汗剤物質は液状制汗剤組成物中に1乃至13重
量%(以下単に%と記載する。)、好ましくは2乃
至10%配合される。
本発明で使用する一価の低級アルコールとして
は、炭素数1乃至4の一価アルコールが挙げられ
る。一価の低級アルコールとしては、効果及び使
用中のにおいの点からエタノールが最適である。
エタノールには化粧品用の基準を満たす範囲にお
いてエタノール変性剤を添加しても良い。一価の
低級アルコールは液体制汗剤組成物中に70乃至90
%好ましくは75乃至85%配合される。
本発明で使用する揮発性シリコーンの典型的な
ものとしては、環状若しくは線状の低分子量ポリ
メチルシロキサンが挙げられる。環状揮発性シリ
コーンは一般式
(式中、n1=3〜6)
で示されるものであり、珪素原子が3〜6個のも
の、就中、4個のものが好ましい。線状揮発性シ
リコーンは一般式
(CH3)3Si−O〔−Si(CH3)2−O〕−n2Si(CH3)3
(式中、n2=1〜3)
で示されるものであり、珪素原子が3〜5個のも
のが好ましい。斯様な揮発性シリコーンとして
は、例えばダウ・コーニング社(Dow Corning
Corporation)から「DC344」、「DC345」及び
「DC200」が、またユニオン・カーバイド社
(Union Carbide Corporation)から「VS−
7207」及び「VS−7158」等が市販されており、
これらを適宜使用できる。揮発性シリコーンは、
液状制汗剤組成物中に0.5乃至13%、好ましくは
2乃至10%配合される。
本発明の液状制汗剤組成物は、必須成分である
これら一価低級アルコール、揮発性シリコーン、
及び水の三者の相対比率が第1図に示す如く一定
の範囲以内にあることを必要とする。すなわち、
一価低級アルコール:揮発性シリコーン:水が三
角座標内の各点、A(75.5:0.6:23.9)、B
(97.9:0.6:1.5)及びC(84.5:14.0:1.5)を結
んで得られる三角形の内側(各辺上を含む)にあ
ることを必要とする。
本発明で使用するアルコール可溶性セルロース
誘導体としてはヒドロキシプロピルセルロース、
エチルセルロース等が挙げられ、就中、セルロー
スに酸化プロピレンを反応して得られるセルロー
スのヒドロキシプロピルエーテル化物であるヒド
ロキシプロピルセルロースが最適である。ヒドロ
〓〓〓〓
キシプロピルセルロースは一般式、
(式中、RはHまたは〔−CH2CH(CH3)−O
−〕n1H基を、m1は1以上の整数を、n3は300〜
1000を示す)
で表わされるもので、その水溶液の粘度(2%、
20℃)は重合度により相違するが、略3000〜
4000cpsの値のものが好ましい。発明においては
平均分子量が10万〜40万(就中25万〜40万)のヒ
ドロキシプロピルセルロースを使用するのが好適
である。アルコール可溶性セルロース誘導体は液
体制汗剤組成物中に0.05乃至2%好ましくは0.1
乃至1.5%配合される。
本発明の液状制汗剤組成物の製造方法は、特に
限定されず、常法により容易に製造することがで
きるが、好ましい製造方法としては、例えば次の
方法が挙げられる。すなわち、制汗剤物質と水を
混合して均一に溶解し、次いでこれに一価の低級
アルコールを加えて均一に混合した後、アルコー
ル可溶性セルロース誘導体を揮発性シリコーンに
均一に分散した液を加えて、更に均一に透明溶解
することにより製造される。なお、全操作は、溶
媒の蒸散を防ぐため、室温下で行うのが好まし
い。
本発明の液状制汗剤組成物には、更にその使用
目的に応じて、色素、香料、殺菌剤、消炎剤、キ
レート剤、粘度調整剤、湿潤剤、界面活性剤等を
配合することができる。
斯くして得られた液状制汗剤組成物は、乾きが
速く、べたつき感やつつぱり感がなく、かつ白化
被膜の形成のない良好な使用感を有し、しかも長
期間にわたつて、濁りや沈澱がなく、透明で安定
である。
以下更に実施例をもつて本発明を詳細に説明す
るが、本発明はこれら実施例に限定されるもので
はない。
実施例 1
下記組成の液状制汗剤組成物を調製し、その安
定性及び官能使用感を下記評価基準に基づき評価
した。その結果を第1表に示す。なお表中には配
合時の液状も示した。[Table], and the relative ratio of each component of (b) monohydric lower alcohol, (c) volatile silicone, and (v) water is the following point on triangular coordinates, A (75.5:0.6 :23.9),B
(97.9:0.6:1.5) and C (84.5:14.0:1.5) to provide a liquid antiperspirant composition that lies inside the triangle (including on each side). In the present invention, known antiperspirant substances can be used as the antiperspirant substance, such as astringent salts of aluminum and zirconium such as aluminum halide, aluminum hydroxyhalide, zirconyloxyhalide, and zirconylhydroxyhalide; These astringent complexes can be used alone or in combination. Among these antiperspirant materials, aluminum astringent salts are preferred. Typical aluminum astringent salts include aluminum chloride and the general formula Al 2 (OH) n
Q o・xH 2 O (in the formula, Q represents chlorine, bromine or iodine, m represents 2 to 5, m+n is 6, m
and n need not be an integer, x is approximately 1 to 6
Al 2 (OH) n Cl o .xH 2 O is particularly suitable. The antiperspirant substance is incorporated in the liquid antiperspirant composition in an amount of 1 to 13% by weight (hereinafter simply referred to as %), preferably 2 to 10%. The monohydric lower alcohol used in the present invention includes monohydric alcohols having 1 to 4 carbon atoms. As the monohydric lower alcohol, ethanol is most suitable from the viewpoint of effectiveness and odor during use.
An ethanol denaturant may be added to ethanol within a range that satisfies standards for cosmetics. The monohydric lower alcohol has a content of 70 to 90% in liquid antiperspirant compositions.
% preferably 75 to 85%. Typical volatile silicones used in the present invention include cyclic or linear low molecular weight polymethylsiloxanes. Cyclic volatile silicone has the general formula (In the formula, n 1 =3 to 6) and preferably has 3 to 6 silicon atoms, particularly preferably 4 silicon atoms. Linear volatile silicone is represented by the general formula ( CH3 ) 3Si -O[-Si( CH3 ) 2 -O] -n2Si ( CH3 ) 3 (where n2 = 1 to 3). It is preferable to have 3 to 5 silicon atoms. Examples of such volatile silicones include those manufactured by Dow Corning Co., Ltd.
"DC344", "DC345" and "DC200" from Union Carbide Corporation, and "VS-" from Union Carbide Corporation.
7207” and “VS-7158” are commercially available.
These can be used as appropriate. Volatile silicone is
It is incorporated in the liquid antiperspirant composition in an amount of 0.5 to 13%, preferably 2 to 10%. The liquid antiperspirant composition of the present invention has these monohydric lower alcohols, volatile silicone, and
It is necessary that the relative proportions of these three components, water and water, be within a certain range as shown in FIG. That is,
Monohydric lower alcohol: Volatile silicone: Water is at each point in triangular coordinates, A (75.5:0.6:23.9), B
(97.9:0.6:1.5) and C (84.5:14.0:1.5) must be inside the triangle (including on each side). The alcohol-soluble cellulose derivatives used in the present invention include hydroxypropyl cellulose,
Examples include ethyl cellulose, among which hydroxypropyl cellulose, which is a hydroxypropyl ether of cellulose obtained by reacting cellulose with propylene oxide, is most suitable. Hydro〓〓〓〓
Xypropyl cellulose has the general formula, (wherein, R is H or [-CH 2 CH(CH 3 )-O
-] n1 is an H group, m 1 is an integer of 1 or more, n 3 is 300 ~
1000), and the viscosity of the aqueous solution (2%,
20℃) varies depending on the degree of polymerization, but approximately 3000~
A value of 4000cps is preferred. In the invention, it is preferable to use hydroxypropylcellulose having an average molecular weight of 100,000 to 400,000 (particularly 250,000 to 400,000). The alcohol-soluble cellulose derivative is present in the liquid antiperspirant composition in an amount of 0.05 to 2%, preferably 0.1%.
It is blended at 1.5% to 1.5%. The method for producing the liquid antiperspirant composition of the present invention is not particularly limited, and can be easily produced by conventional methods, but preferred production methods include, for example, the following method. That is, an antiperspirant substance and water are mixed and dissolved uniformly, then a monohydric lower alcohol is added thereto and mixed uniformly, and then a solution in which an alcohol-soluble cellulose derivative is uniformly dispersed in volatile silicone is added. It is manufactured by further uniformly and transparently dissolving it. Note that all operations are preferably performed at room temperature to prevent evaporation of the solvent. The liquid antiperspirant composition of the present invention may further contain pigments, fragrances, bactericides, anti-inflammatory agents, chelating agents, viscosity modifiers, wetting agents, surfactants, etc., depending on the purpose of use. . The liquid antiperspirant composition thus obtained dries quickly, has no sticky or sticky feeling, and has a good feeling of use without forming a whitening film. It is transparent and stable, with no precipitation or precipitation. EXAMPLES The present invention will be explained in detail below with reference to Examples, but the present invention is not limited to these Examples. Example 1 A liquid antiperspirant composition having the following composition was prepared, and its stability and sensory feeling on use were evaluated based on the following evaluation criteria. The results are shown in Table 1. The table also shows the liquid state at the time of blending.
【表】
水 バランス
評価基準
使用感:各検査項目とも下記の基準による絶対
評価で示す(表中の数字は20名のパネ
ルによる評価の平均値を示す)。
+2:非常にある
+1:ややある
0:ふつう
−1:あまりない
−2:全くない
安定性:3ケ月静置保存後
〇:良好
×:不良
〓〓〓〓
[Table] Water balance evaluation criteria Usability: Each inspection item is shown as an absolute evaluation based on the following criteria (the numbers in the table indicate the average value of the evaluation by a panel of 20 people). +2: Very much +1: Somewhat 0: Normal -1: Not very much -2: Not at all Stability: After 3 months of storage 〇: Good ×: Poor〓〓〓〓
【表】
実施例 2
下記組成の液状制汗剤組成物において、エタノ
ール、環状シリコーン及び水の配合量を種々変化
させ、実施例1と同様にして当該組成物の配合時
の液状、安定性及び官能使用感について検討し第
1図を得た。[Table] Example 2 In a liquid antiperspirant composition with the following composition, the amounts of ethanol, cyclic silicone, and water were varied, and the liquid state, stability, and The sensory feeling on use was examined and Figure 1 was obtained.
【表】
水 〓
実施例 3
下記の組成の液状制汗剤組成物を使用し、各種
制汗剤物質の使用感(べたつき及び白化)及ぼす
影響を調べた。その結果を第3表に示す。
組 成
制汗剤物質 (第3表)
環状シリコーン 2%
(DC344)
エタノール 80
グリセリン 1.0
ヒドロキシプロピルセルロース 0.3
(HPC−H)
香料 0.2
水 バランス[Table] Water 〓
Example 3 A liquid antiperspirant composition having the following composition was used to examine the effects of various antiperspirant substances on the feeling of use (stickiness and whitening). The results are shown in Table 3. Composition Antiperspirant substance (Table 3) Cyclic silicone 2% (DC344) Ethanol 80 Glycerin 1.0 Hydroxypropyl cellulose 0.3 (HPC-H) Fragrance 0.2 Water Balance
【表】
〓〓〓〓
[Table] 〓〓〓〓
【表】
たものである。
実施例 4
下記組成の液状制汗剤組成物を使用し、各種揮
発性シリコーンの使用感(べたつき)に及ぼす影
響を調べた。その結果を第4表に示す。[Table]
Example 4 A liquid antiperspirant composition having the following composition was used to examine the effects of various volatile silicones on the feeling of use (stickiness). The results are shown in Table 4.
【表】【table】
【表】
実施例 5
下記組成の液状制汗剤組成物を使用し、各種ヒ
ドロキシアルキルセルロースの使用感(つつぱり
感)に及ぼす影響を調べた。その結果を第5表に
示す。
〓〓〓〓
[Table] Example 5 A liquid antiperspirant composition having the following composition was used to investigate the influence of various hydroxyalkylcelluloses on the feeling of use (stretching feeling). The results are shown in Table 5. 〓〓〓〓
【表】【table】
【表】
準により求めたものである。
実施例 6
下記組成の液状制汗剤組成物を製造した。[Table] Calculated based on the standard.
Example 6 A liquid antiperspirant composition having the following composition was manufactured.
【表】【table】
【表】【table】
【表】
〓〓〓〓
[Table] 〓〓〓〓
【表】
得られた液状制汗剤組成物はいずれも速乾性
で、べとつき感やつつぱり感がなく、使用感が良
好で、かつ、長期間保存しても安定であつた。[Table] All of the obtained liquid antiperspirant compositions were quick-drying, had no sticky or sticky feeling, had a good feeling of use, and were stable even after long-term storage.
第1図は液状制汗剤組成物中の一価アルコー
ル、揮発性シリコーン及び水の相対的必要量範囲
を示す図である。
〓〓〓〓
FIG. 1 is a diagram showing the relative required amount ranges of monohydric alcohol, volatile silicone, and water in a liquid antiperspirant composition. 〓〓〓〓
Claims (1)
シリコーン及び(ホ)水の各成分の相対比が、三角座
標上の次の各点、A(75.5:0.6:23.9)、B
(97.9:0.6:1.5)及びC(84.5:14.0:1.5)を結
んでできる三角形の内側(各辺上を含む)にある
ことを特徴とする液状制汗剤組成物。[Scope of Claims] 1 Contains [Table], and the relative ratio of each component of (b) monohydric lower alcohol, (c) volatile silicone, and (e) water is at each of the following points on triangular coordinates: , A (75.5:0.6:23.9), B
(97.9:0.6:1.5) and C (84.5:14.0:1.5) A liquid antiperspirant composition characterized by being located inside (including on each side) of a triangle formed by connecting C (84.5:14.0:1.5).
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2449083A JPS59152318A (en) | 1983-02-16 | 1983-02-16 | Liquid adiaphoretic composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2449083A JPS59152318A (en) | 1983-02-16 | 1983-02-16 | Liquid adiaphoretic composition |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS59152318A JPS59152318A (en) | 1984-08-31 |
JPS6111928B2 true JPS6111928B2 (en) | 1986-04-05 |
Family
ID=12139620
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2449083A Granted JPS59152318A (en) | 1983-02-16 | 1983-02-16 | Liquid adiaphoretic composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS59152318A (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU662161B2 (en) * | 1991-07-18 | 1995-08-24 | Procter & Gamble Company, The | Liquid deodorant compositions |
JP3686756B2 (en) * | 1998-03-31 | 2005-08-24 | 株式会社資生堂 | Antiperspirant |
JP3702104B2 (en) * | 1998-09-18 | 2005-10-05 | 株式会社資生堂 | Antiperspirant composition |
JP5825053B2 (en) * | 2010-11-17 | 2015-12-02 | ライオン株式会社 | Liquid-based sweat deodorant composition |
CN103142729A (en) * | 2013-03-04 | 2013-06-12 | 上海浦东高星生物技术研究所 | Yellow sweat treating potion |
BR112020006993B1 (en) * | 2017-11-16 | 2022-08-09 | Beiersdorf Ag | TRANSPARENT HYDROALCOHOLIC FORMULATION IN ROLL-ON FORMAT |
-
1983
- 1983-02-16 JP JP2449083A patent/JPS59152318A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS59152318A (en) | 1984-08-31 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE69522343T2 (en) | GELPEN COMPOSITION CONTAINING DRAWINGS ENRICHED IN OPTICALLY ACTIVE FORM | |
US4944938A (en) | Antiperspirant and deodorant | |
US3255082A (en) | Method of preparing stable aluminum chlorhydrate-alkali metal- and alkaline earth metal salt complex antiperspirant stick | |
US4383988A (en) | Gelled antiperspirant | |
JP3112946B2 (en) | Antiperspirant gel composition containing a chelating agent | |
CN1184953C (en) | Non-sticky and quick-drying aqueous antiperspirant compositions | |
JPH05508881A (en) | Improved ointment base and usage | |
US4073880A (en) | Antiperspirant solution containing a substantially volatile polydimethyl siloxane liquid | |
US5487887A (en) | Clear antiperspirant roll-on compositions | |
EP1017356B1 (en) | Low residue solid antiperspirant | |
JP5825053B2 (en) | Liquid-based sweat deodorant composition | |
US4263274A (en) | Antiperspirant compositions and methods | |
JPS6111928B2 (en) | ||
JP2002544216A (en) | Antiperspirant composition and deodorant composition containing cyclohexasiloxane | |
JP6900122B2 (en) | Antiperspirant composition and antiperspirant | |
JPH05229925A (en) | Liquid antiperspirant composition | |
JPS6111204B2 (en) | ||
EP0016533B1 (en) | Anti-perspirant compositions | |
JP4101437B2 (en) | Gel cosmetic | |
EP0531328A1 (en) | Liquid antiperspirant compositions | |
JPS61155318A (en) | Liquid anhidrotic and antibromic cosmetic | |
JPH09249527A (en) | Gel composition containing sodium chloride and its production | |
JPS608218A (en) | Liquid antiperspirant composition | |
JPH07285843A (en) | Cosmetic | |
JP2019156813A (en) | Antiperspirant composition, and antiperspirant |