JPS6061136A - Casting mold for slip casting - Google Patents

Casting mold for slip casting

Info

Publication number
JPS6061136A
JPS6061136A JP16812083A JP16812083A JPS6061136A JP S6061136 A JPS6061136 A JP S6061136A JP 16812083 A JP16812083 A JP 16812083A JP 16812083 A JP16812083 A JP 16812083A JP S6061136 A JPS6061136 A JP S6061136A
Authority
JP
Japan
Prior art keywords
mold
glue
added
slip
slip casting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP16812083A
Other languages
Japanese (ja)
Other versions
JPH0157642B2 (en
Inventor
Tatsuo Natori
名取 達雄
Hideo Nakae
秀雄 中江
Takashi Shimaguchi
島口 祟
Shoei Watanabe
渡辺 昭英
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Ltd
Original Assignee
Hitachi Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Ltd filed Critical Hitachi Ltd
Priority to JP16812083A priority Critical patent/JPS6061136A/en
Priority to KR1019840001943A priority patent/KR900000030B1/en
Priority to US06/599,483 priority patent/US4604141A/en
Priority to DE19843414096 priority patent/DE3414096A1/en
Publication of JPS6061136A publication Critical patent/JPS6061136A/en
Publication of JPH0157642B2 publication Critical patent/JPH0157642B2/ja
Granted legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00Producing shaped prefabricated articles from the material
    • B28B1/26Producing shaped prefabricated articles from the material by slip-casting, i.e. by casting a suspension or dispersion of the material in a liquid-absorbent or porous mould, the liquid being allowed to soak into or pass through the walls of the mould; Moulds therefor ; specially for manufacturing articles starting from a ceramic slip; Moulds therefor
    • B28B1/261Moulds therefor
    • B28B1/262Mould materials; Manufacture of moulds or parts thereof
    • B28B1/264Plaster

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Mold Materials And Core Materials (AREA)
  • Producing Shaped Articles From Materials (AREA)

Abstract

PURPOSE:To improve initial strength of a casting mold for slip casting and a collapsing property after heating and to permit easy removal of an intricate core by incorporating specific pts. wt. of glue into a gypsum mold added with a vegetable material such as cellulose or the like. CONSTITUTION:Glue is incorporated at a ratio, by weight %, of 100 gypsum, 2-20 cellulose and 0.2-1.0 glue into a gypsum mold added with a vegetable material such as cellulose having water absorptivity and water insolubility or the like. The initial strength of the mold is improved by the glue added thereto and if the slip-formed article and core are heated after casting, the binding force of the mold decreases and the easy removal of the core having an intricate shape is made possible.

Description

【発明の詳細な説明】 〔発明の利用分野〕 本発明は、たとえばセラミック粉末、金属粉末、炭素粉
末などの耐火性粉末を含むスリップ(泥漿)を鋳込んで
成形体を得るためのスリップ・キャステイン用鋳型に係
シ、特に逆勾配で抜去できないような形状″amな中子
を必要とする成形体の成形に好適なスリップ・キャステ
ィング用脚型に関するものである。
Detailed Description of the Invention [Field of Application of the Invention] The present invention relates to a slip casing for obtaining a molded body by casting slip containing refractory powder such as ceramic powder, metal powder, carbon powder, etc. The present invention relates to a slip casting mold suitable for molds for stains, and particularly for molding molded objects that require a core with a shape that cannot be removed due to a reverse slope.

〔発明の背景〕[Background of the invention]

空洞部の形状が複雑な中空成形体、すなわち逆勾配で抜
去できないような形状複雑な中子を必要とする成形体を
スリップ・キャスティングで成形する場合、従来の石膏
鋳型では中子の除去が困難もしくは不可能であった。
When using slip casting to mold a hollow molded body with a complicated cavity shape, that is, a molded body that requires a core with a complicated shape that cannot be removed due to a reverse gradient, it is difficult to remove the core using conventional plaster molds. Or it was impossible.

そこで、本願出願人は石膏鋳型に植物性物質、たとえば
片状セルロース(植物繊維)を2−20チの範囲で添加
することおよび若干の加熱操作によ1鋳型、特に中子の
崩壊性を格段に向上させる鋳型を開発し、本願に先立ち
特願昭58−65372で特許出願ずみである。しかし
、その先願に係る技術においては、セルロースの添加に
より鋳型の初期強度の低下率がやや大きいこと、および
加熱操作後の鋳型の崩壊性が完全とはいい難いことなど
から、よシ一層の改善が望まれていた。
Therefore, the applicant of the present application has added a vegetable material such as flaky cellulose (vegetable fiber) in the range of 2 to 20 to the plaster mold, and by a slight heating operation, the disintegration of one mold, especially the core, has been significantly improved. We have developed a mold that improves the performance of the invention, and have filed a patent application in Japanese Patent Application No. 58-65372 prior to filing this application. However, in the technology related to that earlier application, the rate of decrease in the initial strength of the mold is somewhat large due to the addition of cellulose, and the disintegration of the mold after heating operation is not perfect, so it is even more difficult to apply. Improvement was desired.

〔発明の目的〕[Purpose of the invention]

本発明は、上記の問題点を解決するためになされたもの
で、鋳型の初期強度をあげるとともに、加熱操作後の鋳
型崩壊性を格段に向上し、いかなる複雑な形状の中子で
あっても、その除去が容易なスリップ・キャスティング
用鋳型を提供することを、その目的としている。
The present invention was made to solve the above-mentioned problems, and it increases the initial strength of the mold and significantly improves the mold disintegration property after heating operation, so that it can be used for cores of any complex shape. The object of the present invention is to provide a slip casting mold that is easy to remove.

〔発明の概要〕[Summary of the invention]

本発明に係るスリップ・キャスティング用鋳型の構成は
、植物性物質を添加した石膏鋳型からなるスリップ・キ
ャスティング用鋳型において、前記石膏鋳型をニカワを
含有するものとしたものである。
The structure of the slip casting mold according to the present invention is that the slip casting mold is made of a gypsum mold to which a vegetable substance is added, and the gypsum mold contains glue.

なお付記すると、本発明のスリップ・キャスティング用
鋳型は、例えばセラミック粉末などを含むスリップを鋳
込んで形影するために用いる、片状セルロースを含んだ
石膏鋳型において、石膏鋳型に微量のニカワを添加する
ものである。
As an additional note, the slip casting mold of the present invention is a gypsum mold containing flaky cellulose, which is used to cast and shape a slip containing ceramic powder, etc., in which a small amount of glue is added to the gypsum mold. It is something.

次に本発明がなされた考え方について述べる。Next, the concept behind the present invention will be described.

セルロース等の植物性物質を含有する石膏鋳型に、さら
にニカワを微量添加する理由は、ニカワの添加によ#)
鋳型の初期強度を上昇させると共に、加熱操作後の鋳型
の崩壊性を格段に向上させるためである。
The reason why a small amount of glue is added to a plaster mold containing vegetable substances such as cellulose is due to the addition of glue.
This is to increase the initial strength of the mold and to significantly improve the collapsibility of the mold after heating operation.

含有する植物性物質が、吸水性と共に水不溶性の性質を
備えるものであれば一層好ましい。
It is more preferable that the vegetable substance contained has water-absorbing properties as well as water-insoluble properties.

本発明において吸水性の植物性物質として好ましいもの
は、例えばセルロース(植物繊維)であり、セルロース
は短かく裁断し片状にして使用するのが望ましい。その
理由は、片状にすると鋳型機料の流動性が良くなるから
である。また、セルロースを原料とした紙類などでも良
く、この場合、例えば薄葉紙などは吸水性かつ水不溶性
の点から好ましく、片状にして石膏スラリーに均一に分
散して使用する。
In the present invention, a preferred water-absorbing plant material is, for example, cellulose (vegetable fiber), and it is desirable to use cellulose in the form of short pieces. The reason for this is that the molding material has better fluidity when it is shaped into pieces. Papers made from cellulose may also be used. In this case, for example, thin paper is preferred from the viewpoint of water absorption and water insolubility, and is used after being made into pieces and uniformly dispersed in the gypsum slurry.

石膏鋳型に植物性物質とニカワを含有させる理由は、ニ
カワの添加によシ釣型の初期強度を高めると共に、鋳込
後のスリップ成形品を中子と共に加熱し植物性物質とニ
カワを燃焼させて、鋳型の粘結力を失なわせ鋳型の初期
強度をゼロ近くに低下させるためである。
The reason why vegetable matter and glue are included in the plaster mold is that the addition of glue increases the initial strength of the fishing mold, and the slip molded product after casting is heated together with the core to burn off the vegetable matter and glue. This is to cause the mold to lose its cohesive strength and reduce the initial strength of the mold to near zero.

また、植物性物質が水溶性でおると石膏粒子間に植物性
物質が充填され、吸水性が甚しく低下するため水不溶性
であることが好ましい。
Furthermore, if the plant material is water-soluble, the plant material will be filled between the gypsum particles and water absorption will be significantly reduced, so it is preferably water-insoluble.

石膏鋳型に吸水性の植物性物質を含有させる理由は、ス
リップからの鋳型の吸水効果を高めてスリップの固化時
間を短縮するためである。
The reason why the gypsum mold contains a water-absorbing vegetable substance is to increase the water absorption effect of the mold from the slip and shorten the solidification time of the slip.

石膏100重量部に、セルロースを2〜20重量部含有
させた石膏鋳型に、ニカワを添加する量は0.2〜1.
0重量部であることが望ましい。
Glue is added in an amount of 0.2 to 1.0% to a plaster mold containing 100 parts by weight of plaster and 2 to 20 parts by weight of cellulose.
Preferably, it is 0 parts by weight.

添加量が0.05重量部以下では、ニカワ添加の効果が
殆んど現われない、すなわち鋳型の初期強度が4Kg/
crA以下と小さいままなので、スリップ鋳込時などに
破損しやすく取扱いが困難であり、加熱後の残留圧縮強
度(以下「残留強度」と称す)がやや大きく、鋳型の除
去に困難が伴なうからである。
If the amount added is less than 0.05 parts by weight, the effect of adding glue will hardly appear, that is, the initial strength of the mold will be 4 kg/
Since it remains small at less than crA, it is easily damaged during slip casting and difficult to handle, and the residual compressive strength after heating (hereinafter referred to as "residual strength") is somewhat large, making removal of the mold difficult. It is.

また、ニカワの添加量が2,00重量部以上では、ニカ
ワ姉加による石膏鋳型の硬化時間の遅延が甚しく、到底
実用に供しえない。
Furthermore, if the amount of glue added is 2,00 parts by weight or more, the hardening time of the gypsum mold will be significantly delayed due to the glue, making it impossible to put it into practical use.

したがって、ニカワの添加量は石膏100重量部に対し
、0.05〜2.00重量部が適当である。
Therefore, the appropriate amount of glue to be added is 0.05 to 2.00 parts by weight per 100 parts by weight of gypsum.

本発明の鋳型を得るための、スリップの釣込みから成形
体の焼成までの工程は、スリップの鋳込み→加熱による
鋳型(中子)中の植物性物質とニカワの消失→鋳型の崩
壊および除去→成形体の焼成の順次で実施される。
In order to obtain the mold of the present invention, the process from loading the slip to firing the molded body is as follows: casting the slip → disappearance of vegetable matter and glue in the mold (core) by heating → collapse and removal of the mold → This is carried out in the order of firing the molded bodies.

造型後の鋳型は、80Cで約4時間加熱することによシ
十分な乾燥状態となり、スリップ中の水分を吸収するの
に適当な状態となる。ニカワが添加されているので、無
添加の場合に比べて十分な初期強度を備えている。
The mold after molding becomes sufficiently dry by heating at 80C for about 4 hours, and is in a state suitable for absorbing moisture in the slip. Since glue is added, it has sufficient initial strength compared to the case without the addition.

植物性物質およびニカワを焼失させるための加熱温度は
、500C程度で良く、植物性物質およびニカワの焼失
により石膏鋳型は粘結力を失ない、0、2 Kg / 
crA以下の外力によって容易に崩壊する。
The heating temperature for burning off the vegetable matter and glue may be around 500C, and the plaster mold will not lose its cohesive strength due to the burning off of the vegetable matter and glue.
Easily disintegrated by external forces below crA.

したがって外力は、例えば極めて微弱な圧縮空気もしく
は真空吸引が好ましく、これらによれば崩壊および除去
を同時に行なうことができる。
Therefore, the external force is preferably, for example, extremely weak compressed air or vacuum suction, which allows disintegration and removal to be performed at the same time.

石膏鋳型(中子)の除去によって未焼成の成形体(半完
成品)が造られ、その後の焼成によって完全な、セラミ
ックもしくは金属等の成形体が得られる。
An unfired molded body (semi-finished product) is produced by removing the plaster mold (core), and a complete molded body, such as ceramic or metal, is obtained by subsequent firing.

〔発明の実施例〕[Embodiments of the invention]

以下、具体的な実施例によって説明する。 This will be explained below using specific examples.

(実施例1) 石膏に片状セルロース、ニカワおよび水を第1表に示す
割合で添加し、200rPで5分間混練した。
(Example 1) Cellulose flakes, glue, and water were added to gypsum in the proportions shown in Table 1, and kneaded at 200 rP for 5 minutes.

(*)100meshを901通4 混線して得られた鋳型スラリーを木型に注入してφ50
XH50の試験片を作シ、マツフル炉で80〜800C
の温度で60分間加熱した。加熱後、試練片を取シ出し
空中放冷後の残留強度を測定した。その結果を第1図に
示す。
(*) 901 pieces of 100mesh were mixed and the resulting mold slurry was poured into a wooden mold to create a diameter of φ50.
Create a test piece of XH50 and heat it in a Matsufuru furnace at 80-800C.
The mixture was heated for 60 minutes at a temperature of . After heating, the test piece was taken out and its residual strength was measured after it was left to cool in the air. The results are shown in FIG.

第1図は、本発明の一実施例および従来のスリップ・キ
ャスティング用鋳型の加熱温度と残留強度との関係を示
す線図で、横軸に加熱温度(c×60分)、縦軸に残留
圧縮強度(Kg/ctd)をとっている。図中の曲線1
は、ニカワ無添加のもの、曲線2は、ニカワを0.2重
量部添加したものである。
FIG. 1 is a diagram showing the relationship between heating temperature and residual strength of an embodiment of the present invention and a conventional slip casting mold. Compressive strength (Kg/ctd) is taken. Curve 1 in the diagram
Curve 2 is the one with no glue added, and curve 2 is the one with 0.2 parts by weight of glue added.

図から明らかなように、ニカワを添加すると湿態強度は
全く同じであるにも拘らず、初期強度(80CX4時間
加熱後の強度)は20%向上する。その反面、400C
以上加熱した後の残留強度は、無添加の場合よシ低くな
っている。400Cに例をとると、ニカワ無添加の場合
の残留強度はI Q / cIIiであるのに対し、ニ
カワを0.2重量部添加すると0.2 Kii / c
IIiと、実に115の値となる。
As is clear from the figure, when glue is added, the initial strength (strength after heating at 80CX for 4 hours) increases by 20%, although the wet strength is exactly the same. On the other hand, 400C
The residual strength after heating is lower than that without additives. Taking 400C as an example, the residual strength when no glue is added is IQ/cIIi, but when 0.2 parts by weight of glue is added, the residual strength is 0.2Kii/c.
IIi, which is actually a value of 115.

したがって、ニカワを添加すると無添加の場合にくらべ
て、スリップ・キャスティング用中子の崩壊・除去は極
めて容易であることがわかる。
Therefore, it can be seen that the addition of glue makes it much easier to disintegrate and remove the core for slip casting than when no glue is added.

(実施例2) 石膏に片状セルロース、ニカワ、および水を第2表に示
す割合で添加し、2oorplで5分間混練した。
(Example 2) Cellulose flakes, glue, and water were added to gypsum in the proportions shown in Table 2, and kneaded at 20orpl for 5 minutes.

(II) : 10Qmeghを90優通過rQ) 試験片を実施例1と同様の方法で作シ、500Cで60
分間加熱したのち壁中放冷し、各試験片について残留強
度を測定した。結果を第2図の曲+11j11に示す。
(II): 10Q megh passed 90 rQ) A test piece was prepared in the same manner as in Example 1, and 60% at 500C.
After heating for a minute, the specimen was allowed to cool inside the wall, and the residual strength of each specimen was measured. The results are shown in song +11j11 in Figure 2.

第2図は、本発明の一実施例に係るスリップ・キャステ
ィング用調型におけるニカワの添加量と残留強度および
初期強度との関係を示す線図である。横軸にニカワ添加
量(チ)をとシ、縦軸に残留圧縮強度(Kl/crA)
および初期強度(K9/Cf/l)をとっている。
FIG. 2 is a diagram showing the relationship between the amount of glue added and residual strength and initial strength in a slip casting mold according to an embodiment of the present invention. The horizontal axis shows the amount of glue added (CH), and the vertical axis shows the residual compressive strength (Kl/crA).
and initial strength (K9/Cf/l).

図から明らかなように、ニカワの添加量が0.2以上に
なると残留強度は、無添加の場合に比べて115ないし
それ以下となる。
As is clear from the figure, when the amount of glue added is 0.2 or more, the residual strength becomes 115 or less compared to the case where no glue is added.

(実施例3) 実施例2と同様な方法で試験片を作シ、各試験片につい
て初期強度(80CX4時間加熱後の圧縮強度)を測定
し、第2図の曲線2に結果を示した。
(Example 3) Test pieces were prepared in the same manner as in Example 2, and the initial strength (compressive strength after heating at 80CX for 4 hours) was measured for each test piece, and the results are shown in curve 2 in FIG.

第2図から明らかなように、ニカワの添加量が1.0−
以上になると鋳型の初期強度は約3.7〜/(10) crl以下となる。
As is clear from Figure 2, the amount of glue added is 1.0-
If it is above, the initial strength of the mold will be about 3.7 to /(10) crl or less.

したがって、スリップ鋳込時などに破損しやすく、取扱
いが困難となる。
Therefore, it is easily damaged during slip casting and becomes difficult to handle.

これらの実施例から明らかなように、残留強度および初
期強度の双方を勘案すると、ニカワの添加量は0.2〜
1.0重量部が望ましい。
As is clear from these examples, when both residual strength and initial strength are taken into account, the amount of glue added is 0.2~
1.0 parts by weight is desirable.

また、これらの実施例では、植物性vlJ質とニカワを
官有させているので、鋳型の初期強度を向上させると共
に、スリップ鋳込後に加熱することによって、鋳型強度
を著しく低下させることが出来る。
In addition, in these Examples, since the vegetable VlJ material and glue are possessed, the initial strength of the mold is improved, and by heating after slip casting, the mold strength can be significantly reduced.

このため逆勾配で抜去できないような仮雑な形状の中子
を必要とする中空成形体も極めて容易につくることが出
来るという効果がある。
For this reason, there is an effect that hollow molded bodies that require a core of a temporary shape that cannot be removed due to a reverse gradient can be produced extremely easily.

なお、本例のスリップ・キャスティング用鋳型を主型に
適用すれば、主型を分割する必要が無くなり、このため
精度の高い成形体を作ることができ、さらに石膏鋳型の
吸水性が良好になったので、スリップの同化時間を短縮
できるなどの附随的効果がある。
In addition, if the slip casting mold of this example is applied to the main mold, there is no need to divide the main mold, so it is possible to make a highly accurate molded body, and the water absorption of the plaster mold is also improved. Therefore, there are additional effects such as shortening the slip assimilation time.

(11) 〔発明の効果〕 以上述べたように、本発明によれば、鋳型の初期強度を
あげるとともに、加熱操作後の鋳型の崩壊性を格段に向
上し、いかなる複雑な形状の中子であっても、その除去
が容易なスリップ・キャスティング用鋳型を提供するこ
とができる。
(11) [Effects of the Invention] As described above, according to the present invention, the initial strength of the mold is increased, the collapsibility of the mold after heating operation is significantly improved, and a core of any complicated shape can be used. Even if there is a slip casting mold, it is possible to provide a slip casting mold that is easy to remove.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は、本発明の一実施例および従来のスリップ・キ
ャスティング用鋳型の加熱温度と残留強度との関係を示
す線図、第2図は、本発明の一実施例に係るスリップ・
キャスティング用鋳型におけるニカワの添加量と残留強
度および初期強度との関係を示す線図でおる。 (12) 茅20 ニカワ不鹿量(Y)
FIG. 1 is a diagram showing the relationship between heating temperature and residual strength of slip casting molds according to an embodiment of the present invention and a conventional slip casting mold, and FIG.
It is a diagram showing the relationship between the amount of glue added and residual strength and initial strength in a casting mold. (12) Kaya 20 Glue Fuka amount (Y)

Claims (1)

【特許請求の範囲】 1、植物性物質を添加した石膏鋳型からなるスリップ・
キャスティング用碗型において、前記石膏鋳型をニカワ
を含有するものとしたことを特徴とするスリップ・キャ
スティング用鋳型。 2、植物性物質を吸水性のものとしだものである特許請
求の範囲第1項記載のスリップ・キャスティング用鋳型
。 3、植物性物質を水不溶性のものとしたものである特許
請求の範囲第1項記載のスリップ・キャスティング用鋳
型。 4、植物性物質をセルロースとしたものである特許請求
の範囲第1項記載のスリップ・キャスティング用鋳型。 5、石膏:100重量部に対し、セルロース=2〜20
重量部、ニカワ=0.2〜1.0重量部を含有する特許
請求の範囲第4項記載のスリップ・キャスティング用脚
型。 6、植物性物質を片状の紙類としたものである特許請求
の範囲第1項記載のスリップ・キャスティング用鋳型。
[Claims] 1. A slip plate made of a plaster mold to which vegetable matter has been added.
1. A slip casting mold for a casting bowl, characterized in that the plaster mold contains glue. 2. The slip casting mold according to claim 1, which is made of a water-absorbing plant material. 3. The mold for slip casting according to claim 1, which is made of a water-insoluble vegetable material. 4. The mold for slip casting according to claim 1, wherein the vegetable material is cellulose. 5. Gypsum: 100 parts by weight, cellulose = 2-20
The leg mold for slip casting according to claim 4, which contains 0.2 to 1.0 parts by weight of glue. 6. The mold for slip casting according to claim 1, which is made of vegetable material as paper flakes.
JP16812083A 1983-04-15 1983-09-14 Casting mold for slip casting Granted JPS6061136A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP16812083A JPS6061136A (en) 1983-09-14 1983-09-14 Casting mold for slip casting
KR1019840001943A KR900000030B1 (en) 1983-04-15 1984-04-12 Slip casting mold
US06/599,483 US4604141A (en) 1983-04-15 1984-04-12 Slip casting mold
DE19843414096 DE3414096A1 (en) 1983-04-15 1984-04-13 SLICK ENERGY FORM

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP16812083A JPS6061136A (en) 1983-09-14 1983-09-14 Casting mold for slip casting

Publications (2)

Publication Number Publication Date
JPS6061136A true JPS6061136A (en) 1985-04-08
JPH0157642B2 JPH0157642B2 (en) 1989-12-06

Family

ID=15862216

Family Applications (1)

Application Number Title Priority Date Filing Date
JP16812083A Granted JPS6061136A (en) 1983-04-15 1983-09-14 Casting mold for slip casting

Country Status (1)

Country Link
JP (1) JPS6061136A (en)

Also Published As

Publication number Publication date
JPH0157642B2 (en) 1989-12-06

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