JPS6055099A - Gypsum deterging composition - Google Patents

Gypsum deterging composition

Info

Publication number
JPS6055099A
JPS6055099A JP16543083A JP16543083A JPS6055099A JP S6055099 A JPS6055099 A JP S6055099A JP 16543083 A JP16543083 A JP 16543083A JP 16543083 A JP16543083 A JP 16543083A JP S6055099 A JPS6055099 A JP S6055099A
Authority
JP
Japan
Prior art keywords
gypsum
composition
cleaning
present
deterging
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP16543083A
Other languages
Japanese (ja)
Inventor
清水 久敬
大脇 成紘
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Aska Pharmaceutical Co Ltd
Original Assignee
Teikoku Hormone Manufacturing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Teikoku Hormone Manufacturing Co Ltd filed Critical Teikoku Hormone Manufacturing Co Ltd
Priority to JP16543083A priority Critical patent/JPS6055099A/en
Publication of JPS6055099A publication Critical patent/JPS6055099A/en
Pending legal-status Critical Current

Links

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  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Detergent Compositions (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 本発明は石コウ付着物洗浄用釦成物に関するものであり
、石コウの付着しているものからこれを取除くために、
すぐれた性能を有する組成物に関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a glazing product for cleaning plaster deposits, and in order to remove plaster deposits from objects,
The present invention relates to a composition having excellent performance.

従来、クエン酸アンモニウム、塩酸水等が使用されてい
たが、洗浄時間が長く、また、付着物が崩壊状態となっ
て取除れるが、完全に溶解してしまうことが不可能であ
るため、被洗浄物、洗浄容器、その他を再汚染する原因
となっていた。
Conventionally, ammonium citrate, hydrochloric acid, etc. have been used, but the cleaning time is long, and although the deposits can be removed by breaking down, it is impossible to completely dissolve them. This caused re-contamination of items to be cleaned, cleaning containers, and others.

本発明は、少くとも1種類のポリアミノカルボン酸化合
物またはその塩体と炭酸塩を成分として含むことを特徴
とする組成物である。ここにおいて用いられるポリアミ
ノカルボン酸化合物としては、エチレンジアミン4酢酸
(EDTA)、ヒドロキシエチルエチレンジアミントリ
酢酸()TEDTA )、ジエチレントリアミン5酢酸
(DTPA)、ニトリロトリ酢酸(NTA)等及びこれ
らの各種塩体(例えばNa、に、NH。
The present invention is a composition characterized by containing as a component at least one type of polyaminocarboxylic acid compound or its salt and carbonate. Examples of the polyaminocarboxylic acid compounds used here include ethylenediaminetetraacetic acid (EDTA), hydroxyethylethylenediaminetriacetic acid (TEDTA), diethylenetriaminepentaacetic acid (DTPA), nitrilotriacetic acid (NTA), and various salts thereof (e.g. Na , to NH.

塩)であり、炭酸塩としてはNa2CO3、K2CO3
、NaHCO3、KNHCO3、Ca COs等があげ
られる。
salt), and carbonates include Na2CO3 and K2CO3
, NaHCO3, KNHCO3, CaCOs, etc.

両者の混合割合はポリアミノカルボン酸化合物1:炭酸
塩0.1〜1(重量比)であるのが良く、好ましくはl
:0.2〜0.6である。
The mixing ratio of the two is preferably 1 to 1 (weight ratio) of the polyaminocarboxylic acid compound and 0.1 to 1 of the carbonate.
:0.2 to 0.6.

ポリアミノカルボン酸化合物はアルカリ(Na。The polyaminocarboxylic acid compound is alkali (Na.

K、NH,)にてpHを調整し、炭酸塩と混合溶解した
ときにpH5〜9、好ましくはpH6〜8.5となるよ
うに調整したものを用いるのが良いが、炭酸塩との組成
物を水に溶解し、pHを調整することによって好ましい
状態にすることもできる。
K, NH,) to adjust the pH so that when mixed and dissolved with carbonate, the pH will be 5 to 9, preferably pH 6 to 8.5. Preferable conditions can also be obtained by dissolving substances in water and adjusting the pH.

本発明組成物の使用方法とL2ては、これを水にとかし
、得られた水溶液のpHを調整し2、これに被洗浄物を
浸漬する方法、調整された水溶液を噴射して洗浄する方
法などがある。濃度は特に限定されるべきものではない
が、実際的には3〜20%で使用される。
Methods of using the composition of the present invention (L2) include a method of dissolving it in water, adjusting the pH of the resulting aqueous solution, and immersing the object to be cleaned in it; and a method of cleaning by spraying the adjusted aqueous solution. and so on. Although the concentration is not particularly limited, it is practically used at 3 to 20%.

本発明組成物を用いて洗浄するときは、被洗浄物の表面
から盛んに発泡するのがみられる。
When cleaning with the composition of the present invention, vigorous foaming can be seen from the surface of the object to be cleaned.

この発泡は、強固に付着している石コウを崩すことに役
立つ。即ち、石コウの表面積が増大するので、それによ
り本発明組成物の溶解作用が増大することとなり、石コ
ウの溶解をより速めると考えられる。捷だ、洗浄液のp
Hは処理前後とも弱酸性乃至は弱アルカリ性を保ってい
るので操作上極めて安全性が高く、かつ、処理後の液は
澄明である。被洗浄物はこれを水洗することにより、極
く簡単に洗浄液を洗いおとすことができるので、再汚染
中ることもなく、従来」:り知られていた方法より効果
的である。
This foaming helps break down the strongly adherent plaster. That is, since the surface area of the plaster increases, the dissolving action of the composition of the present invention increases, and it is believed that the dissolution of the plaster becomes faster. Don't worry, cleaning liquid p.
Since H maintains weak acidity or weak alkalinity both before and after treatment, it is extremely safe to operate, and the liquid after treatment is clear. By washing the object to be cleaned with water, the cleaning solution can be removed very easily, so there is no re-contamination, and this method is more effective than conventional methods.

尚、本発明組成物に例えば、クエン酸アンモニウム、酒
石酸アンモニウム等の添加剤を適宜に加えて使用するこ
きもできる。
Incidentally, the composition of the present invention may be used by appropriately adding additives such as ammonium citrate and ammonium tartrate.

以下、本発明を具体的に説明するため実施例及び比較例
を記述する(ここにおいて、部とあるのは重量を意味す
る)。
Examples and Comparative Examples will be described below in order to specifically explain the present invention (herein, "part" means weight).

実施例I HEDTAをNaOH水溶液にとがしpH5とする。こ
れにHEDTAとして1部に対してNaHCO30,5
部を加え5%濃度水溶液となるように調整した。
Example I HEDTA is dissolved in an aqueous NaOH solution to pH 5. To this, NaHCO30.5 is added to 1 part as HEDTA.
1.5% to make a 5% aqueous solution.

実施例2〜6、比較例1〜3 実施例1と同様にして次、の溶液を調整した。Examples 2-6, Comparative Examples 1-3 The following solutions were prepared in the same manner as in Example 1.

 3 − テストピースの作り方 市販のすりガラスに10−当り約0.1gの石コウを塗
布乾燥し、1cII×101の大きさに切シとってテス
トピースとする。
3 - How to make a test piece Apply approximately 0.1 g of gypsum per 10 cm to a commercially available frosted glass, dry, and cut into a size of 1 cII x 101 to make a test piece.

 4− 試験方法 ガラス製容器に液高9c1Mとなるように実施例及び比
較例の調整液を入れ、静置した状態でテストピースを入
れて石コウが完全に溶解するまでの時間を測定し、これ
を溶解時間とした。
4- Test method: Pour the adjustment solutions of Examples and Comparative Examples into a glass container to a liquid height of 9c1M, leave it standing, put a test piece in it, and measure the time until the gypsum completely dissolves. This was taken as the dissolution time.

結果を次表にまとめる。The results are summarized in the table below.

特許出願人 手続補正書(自発) 昭和68年/ρ月)8日 特許庁長官殿 1、発明の名称 龜 補正をする者 事件との関係 特許出願人 住 所 大阪市西区北堀江1丁目1番18号手続補正書
(自発) 昭和68年/ρ月〕S日 特許庁長官殿 昭和、f−、lP年特許願jI /ifり3θ号2 発
明の名称 1 補正をする者 事件との関係 特許出願人 住 所 大阪市西区北堀江1丁目1番18号1ン リN
kJflv 宿 1fj r kグh−亥アシ七ニウ”4閂末へ麦帳か1−−コし
ろ3と 1 過に殿支アシ七=・ンム、茹息(ト丙L(x+v 
’?+癌Ω77−Iしゆ歎ヌ17シ藏ジ、ヒト−すシ専
月」補間(217千4丘−7つ;Ll)p済1−・・−
J F 針#T 3゜】)明)(社)會/の 表のか2θ知丈肴を岸へl52 )(旋イブl/ 7 E]ンTA 2 k lA(f yl<r= ) ty
□L、11411 +□鯛制+h。
Patent Applicant Procedural Amendment (Spontaneous) 8th April 1988, Commissioner of the Japan Patent Office 1, Name of the invention Relationship to the case of the person making the amendment Patent Applicant Address 1-1 Kitahorie, Nishi-ku, Osaka No. 18 Procedural Amendment (Spontaneous) 1986/ρ Month] S Date, Director General of the Patent Office, Showa, f-, IP year patent application jI/ifri 3θ No. 2 Title of the invention 1 Relationship with the case of the person making the amendment Patent Applicant Address: 1-1-18 Kitahorie, Nishi-ku, Osaka-shi, 1-rin-N
kJflv Inn 1fj r kguh-Pig reeds 7 niu" 4 To the end of the bar, barley or 1--Koshiro 3 and 1.
'? + Cancer Ω77-I Shiyu Tonu 17 Shizuraji, Hitosushi Sengetsu' interpolation (217,000 4 hills - 7; Ll) p completed 1-...-
J F Needle #T 3゜]) Ming) (Company) Meeting/'s front or 2θ Chijo dish to the shore l52) (Turning Eve l/7 E]nTA 2 k lA (f yl<r=) ty
□L, 11411 +□Tai system +h.

こジ1に、EDTA 2k t/i/LρI;メーT1
 で7ハム/−/(1)3θ” ””#’Q t + 
轟依θ、 / 4ハスQ甑全体圀てμシうれlQ”J1
=つ・・で、と、、會乙4Xコれて・す試M妨人=K・
・書署ド(勺ミう 餌整爽。pHν、l 2會F(Pi!f’lkq rHl−タ〜7.i水解昨
用 を本 部q−テ支内未り状醒 4咽 て、Jうンr= oJ 3)υ月1#(B古2自/If丁 雫I<NHCO3,、、tかと r KHz、 、ヨ と玄T正T3゜ 以上−
Koji 1, EDTA 2k t/i/LρI; MeT1
7 ham/-/(1)3θ”””#’Q t +
Todoroki θ, / 4 lotus Q The whole area is μshiurelQ”J1
=Tsu・de・、、Meeting Otsu 4X Kore・Su Test M Disturber=K・
・The clerk's office de(庺mi u bait refreshment. pHν, l 2 meeting F(Pi! f'lkq rHl-ta~7. Un r = oJ 3) υ month 1# (B old 2 auto/If ding drop I<NHCO3,,, t and r KHz, , yo and Gen T positive T3゜ or more-

Claims (1)

【特許請求の範囲】[Claims] ポリアミノカルボン酸またはその塩体と炭酸塩とを主成
分として含有する石コウ洗浄用組成物。
A plaster cleaning composition containing a polyaminocarboxylic acid or a salt thereof and a carbonate as main components.
JP16543083A 1983-09-07 1983-09-07 Gypsum deterging composition Pending JPS6055099A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP16543083A JPS6055099A (en) 1983-09-07 1983-09-07 Gypsum deterging composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP16543083A JPS6055099A (en) 1983-09-07 1983-09-07 Gypsum deterging composition

Publications (1)

Publication Number Publication Date
JPS6055099A true JPS6055099A (en) 1985-03-29

Family

ID=15812274

Family Applications (1)

Application Number Title Priority Date Filing Date
JP16543083A Pending JPS6055099A (en) 1983-09-07 1983-09-07 Gypsum deterging composition

Country Status (1)

Country Link
JP (1) JPS6055099A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62146570A (en) * 1985-12-19 1987-06-30 Onoda Kagaku Kogyo Kk Mineral feed pellet
WO1997020910A1 (en) * 1995-12-07 1997-06-12 Draxis Health Inc. Gypsum removal composition and method of removing gypsum from skin
GB2338254B (en) * 1998-06-12 2002-10-16 Sofitech Nv Well completion clean-up fluids and method for cleaning up drilling and completion filtercakes
CN102351568A (en) * 2011-08-04 2012-02-15 重庆市兴渝高分子涂料有限公司 Base solution capable of removing acids and alkalis

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62146570A (en) * 1985-12-19 1987-06-30 Onoda Kagaku Kogyo Kk Mineral feed pellet
WO1997020910A1 (en) * 1995-12-07 1997-06-12 Draxis Health Inc. Gypsum removal composition and method of removing gypsum from skin
GB2338254B (en) * 1998-06-12 2002-10-16 Sofitech Nv Well completion clean-up fluids and method for cleaning up drilling and completion filtercakes
CN102351568A (en) * 2011-08-04 2012-02-15 重庆市兴渝高分子涂料有限公司 Base solution capable of removing acids and alkalis

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