JPS6039172B2 - Failure detection device for electrical equipment - Google Patents

Failure detection device for electrical equipment

Info

Publication number
JPS6039172B2
JPS6039172B2 JP52033850A JP3385077A JPS6039172B2 JP S6039172 B2 JPS6039172 B2 JP S6039172B2 JP 52033850 A JP52033850 A JP 52033850A JP 3385077 A JP3385077 A JP 3385077A JP S6039172 B2 JPS6039172 B2 JP S6039172B2
Authority
JP
Japan
Prior art keywords
gas
detection device
electrical equipment
failure detection
reagent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP52033850A
Other languages
Japanese (ja)
Other versions
JPS53118752A (en
Inventor
武男 吉岡
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Electric Corp
Original Assignee
Mitsubishi Electric Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Electric Corp filed Critical Mitsubishi Electric Corp
Priority to JP52033850A priority Critical patent/JPS6039172B2/en
Publication of JPS53118752A publication Critical patent/JPS53118752A/en
Publication of JPS6039172B2 publication Critical patent/JPS6039172B2/en
Expired legal-status Critical Current

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  • Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
  • Gas-Insulated Switchgears (AREA)
  • Protection Of Transformers (AREA)

Description

【発明の詳細な説明】 本発明は電気機器の故障検出装置に係り、特に密閉容器
内に収納された高電圧回路ご有する機器に適用する薄な
電気機器の故障検出装置に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a failure detection device for electrical equipment, and more particularly to a thin failure detection device for electrical equipment that is applied to equipment having a high voltage circuit housed in a closed container.

一般に、電気機器内に故障が発生した場合には、分解ガ
スが発生するが、従ってガス検知管として市販されてい
るものを故障検知装置として利用する事が出来る。
Generally, when a failure occurs in an electrical device, decomposition gas is generated. Therefore, commercially available gas detection tubes can be used as a failure detection device.

しかしながら、かかる検知管は主として低濃度領域を対
象とするものであり、また対象物質1つのみ応答する為
、電気機器内に於いて発生する分解ガス生成物が複雑で
、且つ経時変化を伴なう場合、適切な測定検出が行なわ
れるか杏かについては疑問があった。従って、本発明の
目的は上記従来技術の欠点をなくし、電気機器の故障検
出を確実になし得る新規の電気機器の故障検出装置を提
供するにある。
However, such detection tubes mainly target low concentration areas and respond to only one target substance, so the decomposition gas products generated in electrical equipment are complex and change over time. There were doubts as to whether adequate measurement detection would be performed in such cases. SUMMARY OF THE INVENTION Accordingly, an object of the present invention is to eliminate the drawbacks of the prior art described above and to provide a new failure detection device for electrical equipment that can reliably detect failures in electrical equipment.

更に詳細には、本発明は、電気機器内に故障が発生した
際に生成するガスが大部分分酸性ガスである事に着目し
て、酸性ガスを検出する事に依って機器の故障の有無を
検出を行う如く構成される電気機器の故障検出装置を提
供するものである。すなわち本発明は絶縁性気体を加圧
封入した電気機器、この装置の一部から気体を導出し、
外部から観察可能な透明容器内に前記絶縁性気体中の分
解ガス成分もしくはこれら分解ガス成分の副次的生成ガ
ス成分に感応して変色する試薬を収納した検知素子に通
過せしめる電気機器の故障検出装置において、検知素子
が前記試薬を担持したクロマト用活性アルミナへのアル
カリ水溶液の添加量によって感度調整され、かつ試薬と
して前記分解ガス成分もしくは分解ガス成分の副次的生
成ガス成分に感応するpH子旨示薬であるプロモクレゾ
ールパープルを迄持させたことを特徴とする電気機器の
故障検出装置を提供するものである。以下、図面に従っ
て本発明を更に詳細に説明する。
More specifically, the present invention focuses on the fact that most of the gas generated when a failure occurs in electrical equipment is acidic gas, and detects the presence or absence of equipment failure by detecting acidic gas. An object of the present invention is to provide a failure detection device for electrical equipment that is configured to detect. That is, the present invention provides an electrical device in which an insulating gas is pressurized and the gas is drawn out from a part of this device.
Failure detection of electrical equipment by passing a reagent that changes color in response to decomposed gas components in the insulating gas or by-product gas components of these decomposed gas components to a detection element that is housed in a transparent container that can be observed from the outside. In the apparatus, the sensitivity of the detection element is adjusted by the amount of alkaline aqueous solution added to the activated alumina for chromatography carrying the reagent, and the pH element is sensitive to the decomposed gas component or a by-product gas component of the decomposed gas component as the reagent. The present invention provides a failure detection device for electrical equipment, characterized in that it retains promocresol purple, which is an indicator. Hereinafter, the present invention will be explained in more detail with reference to the drawings.

第1図は本発明に係る故障検出装置が適用される電気機
器の概略構成図で、同図中1は高電圧導体を内蔵したS
F6ガス封入の電気機器、2は前記電気機器1内のガス
を取り出すための配管路、3はSF6ガスを前記電気機
器1内に封止しておくための止め弁、4は前記配管路2
の流量調整弁、5は本発明に係る故障検出装薄、6は前
記配管路2内を流れるガスの流量を計測する流量計をそ
れぞれ示すものである。
Figure 1 is a schematic configuration diagram of an electrical device to which a failure detection device according to the present invention is applied, and 1 in the figure is an S
An electrical device filled with F6 gas, 2 a piping path for taking out the gas in the electrical device 1, 3 a stop valve for sealing SF6 gas in the electrical device 1, and 4 a piping path 2
5 is a failure detection device according to the present invention, and 6 is a flow meter for measuring the flow rate of the gas flowing in the piping path 2.

以上述べた如き構成を有する電気機器の故障検出装置を
SF6ガス機器に適用する場合の原理的な事項について
以下に説明する。
The following describes the principle of applying the failure detection device for electrical equipment having the configuration described above to SF6 gas equipment.

高電圧導体の綾綾部、絶縁物表面と高電圧導体の間、あ
るいは高電圧導体の間で放電が発生すると、SF6ガス
が分解し、SF4ガスをはじめとする低フッ素化ィオウ
化合物が発生する。
When a discharge occurs between the traverse of the high voltage conductor, between the surface of the insulator and the high voltage conductor, or between the high voltage conductor, SF6 gas decomposes and low fluorinated sulfur compounds such as SF4 gas are generated.

これら低フッ素化ィオウ化合物は化学的に不安定であり
、SF6ガス中に存在する水、あるいは機器を構成する
材料と反応し、HF,S02,SiF4をはじめとする
酸性ガスを生ずる。絶縁物の表面、あるいは近傍におい
て放電が発生すると、SF6ガスのみの分解ばかりでな
く、絶縁物中あるいは他の機器材料中の炭素、酸素ガス
が分解放出されることによりC02(炭酸ガス)が発生
する。
These low-fluorinated sulfur compounds are chemically unstable and react with water present in the SF6 gas or materials constituting the equipment, producing acidic gases such as HF, S02, and SiF4. When a discharge occurs on or near the surface of an insulator, not only SF6 gas is decomposed, but also carbon and oxygen gases in the insulator or other equipment materials are decomposed and released, producing CO2 (carbon dioxide gas). do.

発生する酸性ガスのうち、SF4,HF,SIF4は化
学的に不安定である。
Among the acid gases generated, SF4, HF, and SIF4 are chemically unstable.

このため、機器内部の構成部品との反応により消費され
るいつほう、吸湿および分解ガス吸着を目的として機器
内へ配置されている吸着剤中へもよく吸着されるため、
濃度低下が比較的速い。S02,C02は化学的に安定
な物質であり、吸着剤の効果は比較的ゆっくりしたもの
である。第2図は第1図示構成に適用された本発明の一
実施例に係る故障検出装置の詳細な構成を示す概略構成
図で同図中52は酸性ガスに感応して色ないしは濃度の
変化する検出素子、51は前記検出素子52の変化を観
測可能とする為の透明なアクリル樹脂で構成される外箱
、53は前記故障検出装置5と配管路2を接続する為の
接続管をそれぞれ示すものである。
For this reason, while it is consumed by reaction with the components inside the equipment, it is also well adsorbed into the adsorbent placed inside the equipment for the purpose of absorbing moisture and adsorbing decomposed gases.
Concentration decreases relatively quickly. S02 and C02 are chemically stable substances, and the effect of the adsorbent is relatively slow. FIG. 2 is a schematic configuration diagram showing the detailed configuration of a failure detection device according to an embodiment of the present invention applied to the configuration shown in FIG. A detection element, 51 indicates an outer box made of transparent acrylic resin to enable observation of changes in the detection element 52, and 53 indicates a connecting pipe for connecting the failure detection device 5 and the piping line 2. It is something.

ちなみに、同図aは故障検出装置5の側面図、bは矢印
X方向から見た正面図をそれぞれ示すものである。第3
図は第2図示検出素子52の詳細な構成を示す部分概略
構成図で、同図中521はガラス管、523は前記ガラ
ス管521内に封入されプロモクレゾールパープルを吸
着したクロマト用活性アルミナ522は前記活性アルミ
ナ523を支持するための綿をそれぞれ示すものである
Incidentally, figure a shows a side view of the failure detection device 5, and figure b shows a front view as seen from the direction of arrow X. Third
The figure is a partial schematic configuration diagram showing the detailed configuration of the second illustrated detection element 52, in which 521 is a glass tube, and 523 is an activated alumina for chromatography 522 sealed in the glass tube 521 and adsorbing promocresol purple. Each figure shows cotton for supporting the activated alumina 523.

ガス成分の動きに注目すると、故障時の電流が比較的大
きい場合、時間が経過してもSF4,HFその他のガス
成分はかなりの量残存している。しかしながら、故障電
流が微少であり、かつ持続的に発生している場合には途
中でSF4,HF,SiF4は大部分消失し、S02や
C02のみしか残留していないことがある。従って、故
障の存在を検出するためには、これらのすべての酸性ガ
スに応答することが望ましい。従って、第1,2,3図
に示す如く、配管路2を通じて電気機器1に封入された
ガスを導出して被測定ガスとし「滴定指示薬であるプロ
モクレゾールパープルを吸着したクロマト用活性アルミ
ナ523をガラス管521内に封入した検出素子52内
を通過させる。
Focusing on the movement of gas components, if the current at the time of failure is relatively large, a considerable amount of SF4, HF, and other gas components remain even after time passes. However, if the fault current is very small and occurs continuously, most of SF4, HF, and SiF4 may disappear during the process, leaving only S02 and C02. Therefore, it is desirable to respond to all these acid gases in order to detect the presence of a fault. Therefore, as shown in Figures 1, 2, and 3, the gas sealed in the electrical equipment 1 is led out through the piping 2 and used as the gas to be measured. It passes through a detection element 52 sealed in a glass tube 521.

なお、ここで定量性を持たせる為には流量調整弁4にて
ガス流量を制御すればよい。活性アルミナ523の粒子
は小さく、通過するガスが酸性であれば、充分に反応し
て紫色から黄色へと変色する。従って、故障検出装置5
内の検出素子52の変色の状況をアクリル製の外箱51
を通じて観察する事に依り、電気機器1内に故障が発生
した事を知る事が出釆るものである。なお、第3図示検
出装置52は次の方法に依って作成される。指示薬溶液
であるプロモクレゾールパープル溶液(プロモクレゾー
ルパープル0.5夕十エチルアルコール(95vol%
)90の‘に水を加え全量を100の‘とする)3の‘
を活性アルミナ(中性)30夕に0.州NaOH溶液1
5の上を加え混合する。粒子間が粘着しやすくかつ均一
な着色状態になるまで縄梓を行う。この活性アルミナを
室温付近に保ちながら乾燥窒素ガスを流し乾燥する。乾
燥した活性ァルミナ粒子523をガラス管521内に密
に充填する。なお、ガラス管521の両端は緩衝および
保持を目的とした綿522でささえる。使用しない検出
素子52は通常プラスチックのキャップをかぶせておき
、外気との接触を断つのが好ましい。検出素子の応答に
ついては、含水率を1仇れ%に制御したとき、数種のS
F4濃度に対する応答、即ち変色域長さの結果は第4図
に示すとおりである。
In addition, in order to have quantitative property here, the gas flow rate may be controlled by the flow rate adjustment valve 4. The particles of activated alumina 523 are small, and if the gas passing through them is acidic, they will react sufficiently and change color from purple to yellow. Therefore, the failure detection device 5
The state of discoloration of the detection element 52 inside the acrylic outer box 51
It is possible to know that a failure has occurred in the electrical equipment 1 by observing the electrical equipment 1. Note that the third illustrated detection device 52 is created by the following method. Indicator solution promocresol purple solution (promocresol purple 0.5 to 10 ethyl alcohol (95 vol%)
) Add water to 90' to make the total volume 100') 3'
Activated alumina (neutral) 30 to 0. state NaOH solution 1
Add the above from step 5 and mix. Rope azusa until the particles become easily sticky and uniformly colored. This activated alumina is dried by flowing dry nitrogen gas while keeping it at around room temperature. Dried activated alumina particles 523 are densely packed into the glass tube 521. Note that both ends of the glass tube 521 are supported with cotton 522 for the purpose of buffering and holding. It is preferable that the detection element 52 that is not used is usually covered with a plastic cap to cut off contact with the outside air. Regarding the response of the detection element, when the water content was controlled to 1%, several types of S
The response to the F4 density, ie, the length of the color change area, is as shown in FIG.

ここでは活性アルミナとして中性のものを用いた。Here, neutral activated alumina was used.

活性アルミナはその製法において塩基性、中性、酸性の
ものが工業的に得られる。本検出素子のように酸性ガス
を検出するには塩基性もしくは中性のものに限定される
。さらに、検知素子の応答(変色)は主として塩基性度
によって支配されるため、アルカリ量を制御しやすい活
性アルミナ中性を用いると、アルカリ溶液(濃度)を変
えることによって検出濃度を広範囲にわたって容易にコ
ントロールすることができる。また、プロモクレゾール
パープルは色変化が補色に近い変化をするため、変色有
無を判定が容易となり、使用するpH子旨示薬として最
適である。
Activated alumina can be industrially obtained in basic, neutral, and acidic forms using its manufacturing method. To detect acidic gases like this detection element, it is limited to basic or neutral gases. Furthermore, since the response (color change) of the sensing element is mainly controlled by the basicity, using neutral activated alumina, which makes it easy to control the amount of alkali, it is possible to easily adjust the detection concentration over a wide range by changing the alkaline solution (concentration). can be controlled. In addition, since the color change of promocresol purple is close to that of complementary colors, it is easy to determine the presence or absence of color change, making it ideal as a pH indicator to be used.

以上述べた如く、本発明に依れば、事故発生直後ばはり
でなく、持続的に発生している部分放電などの故障検出
にいっそう効果的でかつ電気的あるいは機械的検出方法
とは別の原理であるためこれと併用でき、また、酸性ガ
スを生じる測定対象例えば空気を絶縁媒体とする電気機
器の部分放電の際に生ずるN02等の検知が可能で且つ
安価な電気機器の故障検出装置を得る事ができるもので
ある。
As described above, according to the present invention, it is more effective in detecting faults such as partial discharges that occur continuously, rather than just immediately after an accident occurs, and it is possible to detect faults that are different from electrical or mechanical detection methods. Since this is the principle, it can be used in conjunction with this, and it is also possible to detect an inexpensive failure detection device for electrical equipment that generates acidic gases, such as N02 generated during partial discharge in electrical equipment that uses air as an insulating medium. It is something that can be obtained.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明に係る故障検出装置が適用される電気機
器の概略構成図、第2図は第1図示構成に適用された本
発明の一実施例に係る故障検知装置の詳細な構成を示す
概略構成図、第3図は第2図示検出素子の詳細な構成を
示す部分概略構成図、第4図は検出素子の応答を説明す
る為のグラフである。 各図を通じて同一符号は同一又は相当部分を示し、2は
配管路、5は故障検出装置、52は検出素子、523は
クロマト用活性アルミナである。 第1図第2図 第3図 第4図
FIG. 1 is a schematic configuration diagram of an electrical device to which a failure detection device according to the present invention is applied, and FIG. 2 is a detailed configuration diagram of a failure detection device according to an embodiment of the present invention applied to the configuration shown in FIG. FIG. 3 is a partial schematic diagram showing the detailed configuration of the detection element shown in the second diagram, and FIG. 4 is a graph for explaining the response of the detection element. Throughout each figure, the same reference numerals indicate the same or equivalent parts, 2 is a piping path, 5 is a failure detection device, 52 is a detection element, and 523 is activated alumina for chromatography. Figure 1 Figure 2 Figure 3 Figure 4

Claims (1)

【特許請求の範囲】[Claims] 1 絶縁性気体を加圧封入した電気装置、この装置の一
部から気体を導出し、外部から観察可能な透明容器内に
前記絶縁性気体中の分解ガス成分もしくはこれら分解ガ
ス成分の副次的生成ガス成分に感応して変色する試薬を
収納した検知素子に通過せしめる電気機器の故障検出装
置において、検知素子が前記試薬を担持した活性アルミ
ナへのアルカリ水溶液加量によつて感度調整され、かつ
試薬として前記分解ガス成分もしくは分解ガス成分の副
次的生成ガス成分に感応するpH指示薬であるプロモク
レゾールパープルを担持させたことを特徴とする電気機
器の故障検出装置。
1 An electrical device in which an insulating gas is sealed under pressure, the gas is drawn out from a part of this device, and the decomposed gas components in the insulating gas or the by-products of these decomposed gas components are placed in a transparent container that can be observed from the outside. A failure detection device for electrical equipment in which a reagent that changes color in response to generated gas components is passed through a detection element containing a reagent, in which the sensitivity of the detection element is adjusted by adding an alkaline aqueous solution to activated alumina carrying the reagent, and 1. A failure detection device for electrical equipment, characterized in that it supports as a reagent promocresol purple, which is a pH indicator that is sensitive to the decomposed gas component or a by-product gas component of the decomposed gas component.
JP52033850A 1977-03-25 1977-03-25 Failure detection device for electrical equipment Expired JPS6039172B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP52033850A JPS6039172B2 (en) 1977-03-25 1977-03-25 Failure detection device for electrical equipment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP52033850A JPS6039172B2 (en) 1977-03-25 1977-03-25 Failure detection device for electrical equipment

Publications (2)

Publication Number Publication Date
JPS53118752A JPS53118752A (en) 1978-10-17
JPS6039172B2 true JPS6039172B2 (en) 1985-09-04

Family

ID=12397967

Family Applications (1)

Application Number Title Priority Date Filing Date
JP52033850A Expired JPS6039172B2 (en) 1977-03-25 1977-03-25 Failure detection device for electrical equipment

Country Status (1)

Country Link
JP (1) JPS6039172B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0316285U (en) * 1989-06-26 1991-02-19

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0316285U (en) * 1989-06-26 1991-02-19

Also Published As

Publication number Publication date
JPS53118752A (en) 1978-10-17

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