JPS6029460A - Manufacture of ornamental material - Google Patents
Manufacture of ornamental materialInfo
- Publication number
- JPS6029460A JPS6029460A JP13854083A JP13854083A JPS6029460A JP S6029460 A JPS6029460 A JP S6029460A JP 13854083 A JP13854083 A JP 13854083A JP 13854083 A JP13854083 A JP 13854083A JP S6029460 A JPS6029460 A JP S6029460A
- Authority
- JP
- Japan
- Prior art keywords
- gold
- aluminum
- alloy
- platinum
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C26/00—Coating not provided for in groups C23C2/00 - C23C24/00
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physical Vapour Deposition (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は、指輪、ネックレス、バント′、ブレスレット
、時ｉｔ側など、貴金属又は、貴金属合金を使用した装
飾用飼料の製造方法に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for producing ornamental feed such as rings, necklaces, bunts, bracelets, and accessories using precious metals or alloys of precious metals.
従来、装飾用銀、白金、金またはそれらの合金上に紫色
を呈する金とアルミニウムから成る被膜をめっきにより
形成していたが、この被膜は紫色しか呈さないという欠
点を自していた。Conventionally, a purple-colored coating consisting of gold and aluminum has been formed on decorative silver, platinum, gold, or their alloys by plating, but this coating has the disadvantage that it only exhibits a purple color.
本発明は上記の欠点を解消せんがためになされたもので
あり、表面に赤紫色の金とアルミニウムから成る被膜を
有する種々の形状の装飾用Ｈ料の製造方法を提供せんと
するものである。The present invention has been made to solve the above-mentioned drawbacks, and it is an object of the present invention to provide a method for producing decorative H materials of various shapes having a reddish-purple coating of gold and aluminum on the surface. .
本発明は、装飾用銀、白金、金またはそれらの合金上に
金とアルミニウムから成る被膜を形成したのち、酸化性
雰囲気中で４４シ処理し、金とアルミニウムから成る被
膜の表面を酸化させることを４．；Ｉｒ徴とするもので
ある。The present invention involves forming a film made of gold and aluminum on decorative silver, platinum, gold, or an alloy thereof, and then treating the film in an oxidizing atmosphere for 44 hours to oxidize the surface of the film made of gold and aluminum. 4. ; It has an Ir signature.
而して本発明の製造法において、金とアルミニウムから
成る被膜をイ」消させる４、４１’−１に持前１川ｔＪ
乙白金、金またはそれらの合金を用いる理由は装ｆｉＦ
Ｈｒ品としてのＪｉｆｆ々の形状に加工することかでき
るためである。また装飾用銀、白金、金またはそれらの
合金」二に金とアルミニウムから成る被ｌ模を付着させ
た後、酸化性雰囲気中で一′ハ処理し、金とアルミニウ
ムから成る被１模の表面を酸化する理由は熱処理する前
の色を赤紫色に変えるためと車なる紫色の金−アルミニ
ウム合金そのものよりさらに、耐食性を向上させ且つ硬
くするためである。Accordingly, in the manufacturing method of the present invention, the film made of gold and aluminum is erased in 4, 41'-1.
The reason for using platinum, gold, or their alloys is
This is because it can be processed into Jiff shapes as Hr products. In addition, after adhering a pattern made of gold and aluminum to decorative silver, platinum, gold, or alloys thereof, the surface of the pattern made of gold and aluminum is treated in an oxidizing atmosphere. The reason for oxidizing is to change the color to reddish-purple before heat treatment, and to improve corrosion resistance and make it harder than the purple gold-aluminum alloy itself.
次に本発明の製造方法による具体的な装飾用飼料の製造
実施例について説明する。Next, specific examples of producing ornamental feed using the production method of the present invention will be described.
〔実施例１〕
１０鰭×１０１１×ｌｌｌ１１の白金−パラジウム１０
重量％板上に金−アルミニウム２２重量％のターゲット
を用いてスパッタリング装置により紫色を呈する金−ア
ルミニウム２２重量％の合金被膜をＱＪ＋ａｍめっきし
た後、この板を６００℃で１０分、大気中で熱処理を行
ったところ、その白金−パラジウム１０重量％板の表面
はあざやかな赤紫色を呈し、その表面のビッカース硬さ
が、７５から２４０に」二昇し、硬化した。[Example 1] 10 fins x 1011 x lll11 platinum-palladium 10
After QJ+am plating a gold-aluminum 22% by weight alloy film exhibiting a purple color using a sputtering device using a gold-aluminum 22% by weight target on a weight% board, this board was heat-treated at 600°C for 10 minutes in the air. When this was carried out, the surface of the platinum-palladium 10% by weight plate exhibited a bright reddish-purple color, and the Vickers hardness of the surface increased from 75 to 240, and was cured.
〔実施例２〕
外径１３＋ｉｍ、肉厚３＋ｎ＋＊のに１８甲丸指輪上に
独立した金及びアルミニウムのクーゲットを用いてスパ
ッタリング装置により金７５重量％とアルミニウム２５
重量％から成る被膜を０．３龍めっきした後、この指輪
を３００℃で３０分大気中で熱処理を行ったところ、そ
の指輪の表面はあざやかな赤紫色を呈しその表面のビッ
カース硬さが、 １１５から３６０に上昇し、硬化した
。[Example 2] Using a sputtering device, 75% by weight of gold and 25% by weight of aluminum were applied to an 18-round ring with an outer diameter of 13+im and a wall thickness of 3+n+* using independent gold and aluminum Cougets.
After plating a film consisting of 0.3% by weight, the ring was heat-treated at 300°C for 30 minutes in the air, and the surface of the ring exhibited a bright reddish-purple color and the Vickers hardness of the surface increased. It rose from 115 to 360 and was cured.
尚、実施例でば熱処理温度を６００℃及び３００℃につ
いて述べたが、本発明はこれに限るものではなく、酸化
する目的及び装飾用合金基祠の高温での極端な機械的性
質の劣化を避ける理由から１５０〜７５０℃が好ましい
。In the examples, heat treatment temperatures of 600°C and 300°C were described, but the present invention is not limited to these.The purpose of the present invention is to oxidize and to prevent extreme deterioration of mechanical properties of decorative alloy bases at high temperatures. The temperature is preferably 150 to 750°C for the reason of avoiding the temperature.
また、実施例ではアルミニウム２２市量％及び２５ｉ１
１ｆｉｔ％の金とアルミニウムから成る被膜について述
べたが、本発明はこれに限るものではなく、あざやかな
赤紫色を得る理由から金７０〜８５市量％。In addition, in the example, aluminum 22% by market weight and 25i1
Although the coating is made of 1 fit% of gold and aluminum, the present invention is not limited thereto, and in order to obtain a bright reddish-purple color, the coating may be made of 70 to 85% of gold by market weight.
アルミニウム１５〜３ｏ１Ｂ、％の範囲が灯ましい。The preferable range is aluminum 15-3o1B.%.
上記の説明で町らかなように本発明の製造法は、ｔＲ２
白金、金またはそれらの合金の表面に金とアルミニウム
から成る被膜を全面または部分的にめっきにて形成した
後、その被膜の表面に酸化物を形成させることにより、
従来法ではｉＭられなかった種々の形状の赤紫色又は赤
紫色と他の色の混しった表面が硬（傷つきにくい装飾制
料を製造できるので、従来の製造法にとって代わること
のできる画期的なものと言える。As stated above, the production method of the present invention is based on tR2
By forming a coating consisting of gold and aluminum on the surface of platinum, gold, or their alloys by plating the entire surface or partially, and then forming an oxide on the surface of the coating,
It is an epoch-making method that can replace conventional manufacturing methods because it can produce decorative materials with hard (and scratch-resistant) surfaces in various shapes of reddish-purple or reddish-purple mixed with other colors, which could not be imprinted using conventional methods. It can be said to be a thing.
出願人 田中貴金属工業株式会社Applicant Tanaka Kikinzoku Kogyo Co., Ltd.
Claims (1)
ミニウムから成る被＋１をめっきにより形成した後、ｊ
ｌｕ化性雰囲気中でｆ４５処理し、前記被１１史の表面
を酸化させることをＩＩＪｔ徴とする装飾用祠料の製造
方法。After forming a coating made of gold and aluminum by plating on decorative silver, platinum, gold, or an alloy thereof,
A method for producing a decorative amulet, which is characterized in that it is subjected to f45 treatment in a lu-oxidizing atmosphere to oxidize the surface of the treated material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13854083A JPS6029460A (en) | 1983-07-28 | 1983-07-28 | Manufacture of ornamental material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13854083A JPS6029460A (en) | 1983-07-28 | 1983-07-28 | Manufacture of ornamental material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6029460A true JPS6029460A (en) | 1985-02-14 |
Family
ID=15224538
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13854083A Pending JPS6029460A (en) | 1983-07-28 | 1983-07-28 | Manufacture of ornamental material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6029460A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1175515A1 (en) * | 1999-02-02 | 2002-01-30 | Singapore Polytechnic Ventures Pte Ltd. | Jewellery alloy compositions |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5091096A (en) * | 1973-12-18 | 1975-07-21 | ||
| JPS5095144A (en) * | 1973-12-26 | 1975-07-29 |
-
1983
- 1983-07-28 JP JP13854083A patent/JPS6029460A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5091096A (en) * | 1973-12-18 | 1975-07-21 | ||
| JPS5095144A (en) * | 1973-12-26 | 1975-07-29 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1175515A1 (en) * | 1999-02-02 | 2002-01-30 | Singapore Polytechnic Ventures Pte Ltd. | Jewellery alloy compositions |
| EP1175515A4 (en) * | 1999-02-02 | 2004-11-03 | Innomart Pte Ltd | Jewellery alloy compositions |
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