JPS6028148B2 - photodiode - Google Patents

photodiode

Info

Publication number
JPS6028148B2
JPS6028148B2 JP51007976A JP797676A JPS6028148B2 JP S6028148 B2 JPS6028148 B2 JP S6028148B2 JP 51007976 A JP51007976 A JP 51007976A JP 797676 A JP797676 A JP 797676A JP S6028148 B2 JPS6028148 B2 JP S6028148B2
Authority
JP
Japan
Prior art keywords
photodiode
filter
coating layer
layer
phosphorus
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP51007976A
Other languages
Japanese (ja)
Other versions
JPS5291665A (en
Inventor
真一 柳瀬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Tokyo Shibaura Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tokyo Shibaura Electric Co Ltd filed Critical Tokyo Shibaura Electric Co Ltd
Priority to JP51007976A priority Critical patent/JPS6028148B2/en
Publication of JPS5291665A publication Critical patent/JPS5291665A/en
Publication of JPS6028148B2 publication Critical patent/JPS6028148B2/en
Expired legal-status Critical Current

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  • Light Receiving Elements (AREA)
  • Optical Filters (AREA)
  • Surface Treatment Of Optical Elements (AREA)

Description

【発明の詳細な説明】 本発明はフオトダィオード‘こ関し、フオトダィオード
‘こおけるフィル夕の改良された構造を提供することを
目的とする。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to photodiodes, and an object thereof is to provide an improved structure of a filter in a photodiode.

フオトダイオードの一例のカメラ用フオトダイオ−ド‘
こシリコンのものが多く用いられている。
Camera photodiode, an example of a photodiode
This silicon material is often used.

第1図aに示すシリコンフオトダィオードは、外囲器1
の本体laの受光面にガラスフィルタlbを備え、フオ
トダィオードベレツト2を外囲器内に配設する。そして
べレットの電極端子を外囲器の電極導出1」−ドlc,
lc′に夫々接続してなる。上記ガラスフィル夕はフオ
トダィオードベレットの分光感度特性9000Aにピー
クをもつなだらかな曲線であるところから、これを人間
の視感度(5600Aにピークをもつ)に合わせるため
7000A以上の長波長分をカットするものを適用する
。かかるガラスフィル夕には干渉型と吸収型とがある。
前者はガラスの片面に誘電体を通常13層程度蒸着する
必要があり、かっこの膜厚の制御が非常に繁雑で、製造
も難しく高価である。後者はガラスにリン系物質を添加
してなるが、この添加物のために吸湿しやすくガラスフ
ィル夕に白濁を生じ、光の透過率が低下する。これによ
りカメラにおける露出の過多、過少がおきる。さらに分
光感度が変化し、人間の視感度と少しずれる事によって
写真が赤味を帯びたり、青味を帯びたりする場合もある
。上記に対し、通常ガラスフィルタlbの両面に、第1
図bに示す如くフツ化マグネシウム3(MgF2)等を
被着することによって吸湿を防止してたいるが充分でな
く、白濁を生じ支障を来たすことが多い。
The silicon photodiode shown in FIG.
A glass filter lb is provided on the light-receiving surface of the main body la, and a photodiode bellet 2 is disposed within the envelope. Then, connect the electrode terminal of the pellet to the electrode lead 1 of the envelope,
lc' respectively. Since the above glass filter has a gentle curve with the spectral sensitivity characteristic of the photodiode pellet having a peak at 9000A, in order to match this to the human visual sensitivity (which has a peak at 5600A), the long wavelength of 7000A or more is Apply what you want to cut. There are two types of such glass filters: interference type and absorption type.
The former requires usually about 13 layers of dielectric material to be deposited on one side of the glass, and the control of the film thickness of the parentheses is extremely complicated, making manufacturing difficult and expensive. The latter is made by adding a phosphorous substance to glass, but this additive easily absorbs moisture, causing cloudiness in the glass filter and reducing light transmittance. This results in over- or under-exposure in the camera. Furthermore, the spectral sensitivity changes and may deviate slightly from the human visual sensitivity, causing the photograph to appear reddish or bluish. In contrast to the above, there is usually a first
As shown in FIG. b, moisture absorption is usually prevented by coating magnesium fluoride 3 (MgF2), etc., but this is not sufficient and often causes problems by causing cloudiness.

本発明は上記従来のフオトダィオ−ド‘こおける欠点を
除去するためになされたもので、改良された構造のフィ
ル夕を備えたフオトダィオードを提供する。
The present invention has been made to eliminate the above-mentioned drawbacks of conventional photodiodes, and provides a photodiode with an improved filter structure.

本発明のフオトダィオードは、受光部にフィル夕を有す
るフオトダィオー日こして、フィル夕の両王面に気相成
長により形成された被覆層を有し、この被覆層がSi0
2−リン添加Si02−Si02の積層構造からなるこ
とを特徴とするものである。
The photodiode of the present invention has a photodiode having a filter in the light receiving part, and has a coating layer formed by vapor phase growth on both sides of the filter, and this coating layer is made of Si0
It is characterized by having a laminated structure of 2-phosphorus-doped Si02-Si02.

以下、本発明の一実施例のフオトダィオード‘こかかる
一例のカメラ用フオトダィオード‘こつき詳細に説明す
る。第2図に本発明のかかるフオトダィオードのフィル
夕の一部を断面図で示す。
DESCRIPTION OF THE PREFERRED EMBODIMENTS A photodiode according to an embodiment of the present invention will be described in detail below. FIG. 2 shows a cross-sectional view of a portion of the filter of a photodiode according to the present invention.

即ち平板状のガラスフイルタlbの両主面にSi02(
二酸化ケイ素)の被覆層12を設ける。上記Si02層
は一般に用いられる気相成長の手段、即ち、シラン(S
i比)を酸素雰囲気中で加熱分解することにより次の化
学式の如く形成される。Si比十2仏→Si02十2日
20 そして層厚は多くの実験に基づき0.3〜2.0〃が好
適する。
That is, Si02 (
A coating layer 12 of silicon dioxide) is provided. The above Si02 layer was grown by a commonly used vapor phase growth method, namely silane (S
i ratio) is thermally decomposed in an oxygen atmosphere to form the following chemical formula. Si ratio 12 Buddhas → Si02 12 days 20 Based on many experiments, the layer thickness is preferably 0.3 to 2.0.

この限界は防湿能力の発生する下限が0.3ムであり、
光の透過性を維持できる限界が2ムであることに基づく
。次に第2図における被覆層12は、これを拡大して示
す第3図からわかるように、リンを添加したSi02層
1 2aを挟んで二つのSi02層1 2b,12b′
で形成された積層機構となっている。
This limit is the lower limit at which the moisture-proof ability occurs, and is 0.3 μm.
This is based on the fact that the limit at which light transparency can be maintained is 2 μm. Next, as can be seen from FIG. 3, which shows an enlarged view of the coating layer 12 in FIG.
It is a laminated mechanism formed by.

このリン添力ロSi02層12aは、前述のシランの加
熱分解による気相成長工程の途中でその雰囲気中にリン
を添加するという簡単な操作で形成される。このような
被覆層12はガラスフィル夕の湿気による自濁を防止す
るとともに、それ自身熱的影響によるクラックが防止さ
れ、常時フィル夕の白濁防止効果を失うことがないなど
、種々の効果がある。
This phosphorus-added Si02 layer 12a is formed by a simple operation of adding phosphorus to the atmosphere during the vapor phase growth step by thermal decomposition of silane described above. Such a coating layer 12 not only prevents the glass filter from becoming cloudy due to moisture, but also prevents cracking due to thermal effects, and has various effects such as not losing the filter's cloudiness prevention effect at all times. .

【図面の簡単な説明】[Brief explanation of drawings]

第1図aはフオトダィオードの断面図を示し、図bはフ
ィルタ部の一部の断面図、第2図は本発明の一実施例の
フオトダィオードのフィルタ部の一部の断面図、第3図
は第2図の被覆層部を拡大して示す断面図である。 なお、図中同一符号は同一または相当部分を夫々示すも
のとする。1・・・・・・フィル夕、12・・・・・・
被覆層、12a・・・・・・リン添加Si02層、12
b……Si02層。 第1図第2図 第3図
FIG. 1a shows a cross-sectional view of a photodiode, FIG. b shows a cross-sectional view of a part of the filter part, FIG. FIG. 3 is an enlarged cross-sectional view of the coating layer portion of FIG. 2; Note that the same reference numerals in the figures indicate the same or corresponding parts, respectively. 1...Fill evening, 12...
Covering layer, 12a... Phosphorus-added Si02 layer, 12
b...Si02 layer. Figure 1 Figure 2 Figure 3

Claims (1)

【特許請求の範囲】[Claims] 1 受光部にフイルタを有するフオトダイオードにおい
て、フイルタの両主面に気相成長により形成された被覆
層を有し、この被覆層がSiO_2−リン添加SiO_
2−SiO_2の積層構造からなることを特徴とするフ
オトダイオード。
1 A photodiode having a filter in the light receiving part has a coating layer formed by vapor phase growth on both main surfaces of the filter, and this coating layer is made of SiO_2-phosphorus-doped SiO_
A photodiode characterized by having a laminated structure of 2-SiO_2.
JP51007976A 1976-01-29 1976-01-29 photodiode Expired JPS6028148B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP51007976A JPS6028148B2 (en) 1976-01-29 1976-01-29 photodiode

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP51007976A JPS6028148B2 (en) 1976-01-29 1976-01-29 photodiode

Publications (2)

Publication Number Publication Date
JPS5291665A JPS5291665A (en) 1977-08-02
JPS6028148B2 true JPS6028148B2 (en) 1985-07-03

Family

ID=11680475

Family Applications (1)

Application Number Title Priority Date Filing Date
JP51007976A Expired JPS6028148B2 (en) 1976-01-29 1976-01-29 photodiode

Country Status (1)

Country Link
JP (1) JPS6028148B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0230448U (en) * 1988-08-17 1990-02-27
JPH0453397Y2 (en) * 1985-10-21 1992-12-15

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61176502U (en) * 1985-04-24 1986-11-04
JPH0517891Y2 (en) * 1986-12-27 1993-05-13
JP2542003Y2 (en) * 1988-11-21 1997-07-23 三菱電機株式会社 Optical semiconductor device module
JPH07297493A (en) * 1994-04-28 1995-11-10 Hamamatsu Photonics Kk Light-emitting device

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0453397Y2 (en) * 1985-10-21 1992-12-15
JPH0230448U (en) * 1988-08-17 1990-02-27

Also Published As

Publication number Publication date
JPS5291665A (en) 1977-08-02

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