JPS60146807A - Fungicide - Google Patents
FungicideInfo
- Publication number
- JPS60146807A JPS60146807A JP137784A JP137784A JPS60146807A JP S60146807 A JPS60146807 A JP S60146807A JP 137784 A JP137784 A JP 137784A JP 137784 A JP137784 A JP 137784A JP S60146807 A JPS60146807 A JP S60146807A
- Authority
- JP
- Japan
- Prior art keywords
- fungi
- agent
- boric acid
- fungicide
- hydrogen peroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000000855 fungicidal effect Effects 0.000 title claims abstract description 11
- 239000000417 fungicide Substances 0.000 title claims abstract description 9
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 21
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004327 boric acid Substances 0.000 claims abstract description 12
- 239000002562 thickening agent Substances 0.000 claims abstract description 9
- 229920002125 Sokalan® Polymers 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 abstract description 17
- 230000000694 effects Effects 0.000 abstract description 2
- 241000233866 Fungi Species 0.000 abstract 3
- 230000008929 regeneration Effects 0.000 abstract 2
- 238000011069 regeneration method Methods 0.000 abstract 2
- 230000002401 inhibitory effect Effects 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 description 7
- 239000000203 mixture Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000005708 Sodium hypochlorite Substances 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000002667 nucleating agent Substances 0.000 description 2
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 description 2
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- 206010028813 Nausea Diseases 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 208000002193 Pain Diseases 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000000843 anti-fungal effect Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 231100000869 headache Toxicity 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical class Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 230000008693 nausea Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は、浴室、床、壁および天井等に発生するカビを
過酸化水素および硼酸を含有する製剤で殺菌し、更には
、長期間に渡ってカビの再発生を防止するととに関する
。DETAILED DESCRIPTION OF THE INVENTION The present invention sterilizes mold that grows in bathrooms, floors, walls, ceilings, etc. with a preparation containing hydrogen peroxide and boric acid, and furthermore, prevents the regrowth of mold over a long period of time. Regarding prevention.
従来の殺カビ剤としては、塩素系、特に４〜６チの次亜
塩素酸塩を含有する製剤が市販されているが、該製剤は
、激しい塩素臭を放出するため、臭気が部屋全体に充満
し、頭痛や吐気を催させしめる。そのため、該製剤の使
用は、特定の場所、例えば浴室等、すぐに水洗できる場
所に限定されていた。仁のように、核製剤は、その臭気
、または、該製剤の残留による処理部位の変色のために
否応なしＫ、処理後、速やかに水で洗い落さなければな
らないため、殺カビ力はあっても、防カビ力は全く期待
できない。また、該製剤は、強い酸化作用を有するため
、金属類を発錆せしめたり、作業者の衣類を損傷せしめ
゛るおそれがある。As conventional fungicides, preparations containing chlorine, especially 4 to 6 hypochlorites, are commercially available, but these preparations emit a strong chlorine odor, causing the odor to spread throughout the room. It becomes full, causing headaches and nausea. Therefore, the use of this preparation has been limited to specific locations, such as bathrooms, where it can be easily washed with water. Nucleic preparations are unavoidable due to their odor or discoloration of the treated area due to the residue of the preparations, and because they must be washed off with water immediately after treatment, they have little fungicidal power. However, you can't expect any anti-mold ability at all. Furthermore, since the preparation has a strong oxidizing effect, it may cause rusting of metals or damage the clothing of workers.
本発明者等は、無臭の薬剤で殺菌力のある過酸化水素に
注目し、鋭意、検討した結果、過酸化水素とホウ酸を併
用した製剤は、救カピカだけでなく、長期間に渡って、
防カビ力があることを見出し、本発明を完成したヶ
即ち、本発明は、過酸化水素および、硼酸を倉本発明剤
が、殺カビカ罠加えて防カビカを有するのは、本発明剤
は、従来品と異なり、塗布後核剤を拭きとる必要がない
から、核剤の成分の一つである硼酸が処理部位に浸透し
、残留するためと考えられる。The present inventors focused on hydrogen peroxide, which is an odorless drug and has bactericidal properties, and as a result of intensive study, we found that a formulation containing hydrogen peroxide and boric acid was not only effective, but also effective for a long period of time. ,
They found that it has antifungal properties and completed the present invention.That is, the present invention has hydrogen peroxide and boric acid. Unlike conventional products, there is no need to wipe off the nucleating agent after application, so it is thought that boric acid, one of the components of the nucleating agent, penetrates into the treated area and remains.
本発明剤の成分である過酸化水素の濃度は、６チを越え
ると劇物に該当するし、また、使用時手指に痛覚を受け
る場合もあるので、１〜６チ好ましくは、３〜６％であ
り、硼酸の濃度は、０．５〜３．５チである。If the concentration of hydrogen peroxide, which is a component of the present agent, exceeds 6%, it is classified as a deleterious substance, and the hands and fingers may feel pain when using it, so the concentration of hydrogen peroxide is preferably 1 to 6%, preferably 3 to 6%. %, and the concentration of boric acid is 0.5 to 3.5%.
本発明剤の使用方法は、単にカビ発生個所に、本発明剤
を塗布し、そのまま放置すればよい（ｑ＃別な場合を除
き、本発明剤は拭きとる必要はない）のであるが、カビ
の発生個所は、種々であシ、壁や天井等の場合、本発明
剤を塗布しても、本発明剤はその効果が発揮される前に
、流れ落ちてしまうため、好ましい実施態様としては、
本発明剤に適当な増粘剤を配合することが好ましい。増
粘剤としては、ＣＭＣ，ヒドロキシグロビルメチルセル
ロース ポリアクリル酸ノーダ、アルギン酸ソーダおよ
びアクリル酸重合体等が上げられるが、増粘剤の種類に
よっては、本発明剤の粘度が経時的に変化（粘度が低下
）してしまう・ため、最も好ましい増粘剤としては、ア
クリル酸重合体が上げられる。更Ｋ、該粘度は、本発明
剤のＰＨＫ影響されるため、本発明剤は、ＰＨ３〜６、
好ましくは４〜５．５に調整されるべきである。The method of using the present invention agent is to simply apply the present invention agent to the area where mold has grown and leave it as it is (unless otherwise specified, there is no need to wipe off the present invention agent). There are various places where this occurs, such as walls and ceilings, and even if the present invention agent is applied, the present invention agent will wash off before its effect is exerted. Therefore, as a preferred embodiment,
It is preferable to incorporate a suitable thickener into the agent of the present invention. Examples of thickeners include CMC, hydroxyglobil methylcellulose polyacrylic acid, sodium alginate, and acrylic acid polymers, but depending on the type of thickener, the viscosity of the present agent changes over time (viscosity Therefore, the most preferred thickener is an acrylic acid polymer. Moreover, since the viscosity is affected by the PHK of the present agent, the present agent has a pH of 3 to 6,
Preferably it should be adjusted to 4-5.5.
尚、本発明剤の処理部位への浸透性を高める目的で、ア
ニオン系あるいはノニオン系界面活性剤を本発明剤に配
合すると効果的であり、又、本発明剤の成分の一つであ
る過酸化水素の安定剤として、８−オキシキノリン、各
種リン酸塩等の各種安定剤を配合することＫより、本発
明剤の貯蔵安定性を改善することができる。In addition, for the purpose of increasing the permeability of the present agent to the treated area, it is effective to add an anionic or nonionic surfactant to the present agent. The storage stability of the agent of the present invention can be improved by incorporating various stabilizers such as 8-oxyquinoline and various phosphates as stabilizers for hydrogen oxide.
本発明剤は、スプレー方式でどんな細部にも、手を全く
汚さず塗布でき、かつ、塗布後は、そのｔま放置すれば
殺カビ、され、更には、防カビ力も保持されるもので、
簡易かつ安全な殺カビ剤となる。The agent of the present invention can be applied to any detail by spray method without getting your hands dirty at all, and after application, if you leave it for a while, it will kill mold, and furthermore, it will retain its anti-mold ability.
It is a simple and safe fungicide.
以下に本発明を実施例で説明する。The present invention will be explained below using examples.
参考例
過酸化水素６％、硼酸３％、８−オキシキノリン１５０
Ｐｐｍの混合液に各々の増粘剤を加えＰＨ５，５にＮａ
ＯＨで調整し、増粘剤の評１価を行った。Reference example Hydrogen peroxide 6%, boric acid 3%, 8-oxyquinoline 150
Add each thickener to the Ppm mixture and adjust the pH to 5.5 with Na.
Adjustment was made with OH, and a first evaluation of the thickener was performed.
第１表
＊１ 重合度 ２７００〜７５００
＊２ 商品名［ハイビスワコ−１０５Ｊ（和光化成■品
）として市販
＊３１力月後の粘度安定性（視覚による判定）実施例１
増粘剤として参考例墓５のアクリル酸重合体を用いて下
記の組成物を製造し、Ｈｔ Ｏｔ の安定性及び浴室の
天井（材質：シージングボード）のカビ除去を試みた。Table 1 *1 Degree of polymerization 2700-7500 *2 Product name [Commercially available as Hibiswako-105J (Wako Kasei product) *Viscosity stability after 31 months (visual judgment) Example 1 Reference example as a thickener The following composition was prepared using the acrylic acid polymer No. 5, and an attempt was made to improve the stability of Ht Ot and to remove mold from a bathroom ceiling (material: sheathing board).
ＮａＯＨＰＨ５，５
＊４ 花王アトラス社製 アニオン界面活性剤カビの除
去試験は、比較例１として上記の組成物の中の硼酸を除
いた物、また比較例２として市販されている次亜塩素酸
ソーダ（有効塩素４チ）の′カビ取り剤を取り上けた。NaOHPH5,5 *4 Manufactured by Kao Atlas Co., Ltd. The anionic surfactant mold removal test was conducted using the above composition with boric acid removed as Comparative Example 1, and commercially available sodium hypochlorite as Comparative Example 2. (available chlorine: 4 t)' mold remover.
結果は第２表のごとくであったが、比較例２は粘稠性が
ないために液が流れ落ちてしまい、思うような処理がで
きず、５途中で断念した。The results were as shown in Table 2, but in Comparative Example 2, the liquid ran down due to lack of viscosity, and the desired treatment could not be performed, so the treatment was abandoned halfway through.
（注）回数とは、カビ発生部全面にスプレーで薬剤を塗
布し、その後その表面がよく乾燥した時、その表面をよ
く観察し、カビかのこっている時は、ふたたびスプレー
で塗布する。その回数をいう。(Note) The number of times refers to spraying the chemical over the entire surface of the mold-infested area, then observing the surface carefully when it has dried thoroughly, and spraying again if mold is present. The number of times.
尚、 Ｈ，０，の安定性は９５℃水浴中で液温か上昇後
１５〜２０分間加温し、その際のＨ２０ｔ の分解をガ
ス発生量で判定する方法であるが、これによると分解は
全く見られず、安定性は、著しく優れていることが言え
る。The stability of H,0, is determined by heating it in a 95°C water bath for 15 to 20 minutes after the liquid temperature rises, and determining the decomposition of H20t by the amount of gas generated at that time. It can be said that the stability is extremely excellent.
実施例２゜
実施例１と同組成物で押入れの壁（材質、ベニヤ板）の
カビ除去を試みた。比較例３として、同組成物中の硼酸
を除いたもの、又比較例４として、市販されている次亜
塩素酸ソーダ（有効塩素４．０チ）のカビ取り剤を取り
上げた。結果は、第３表の通りであった。Example 2 An attempt was made to remove mold from the wall of a closet (material: plywood) using the same composition as in Example 1. As Comparative Example 3, the same composition without boric acid was used, and as Comparative Example 4, a commercially available mold remover of sodium hypochlorite (available chlorine: 4.0 H) was used. The results were as shown in Table 3.
Claims (1)
る防カビカを有する殺カビ剤。 ２、増粘剤としてアクリル酸重合体を含有する特許請求
の範囲第１項記載の殺カビ剤。 ３、Ｐｌ−１範囲が３〜６の特許請求の範囲第１．２項
記載の殺カビ剤。[Scope of Claims] 1. A fungicide having a fungicide characterized by containing hydrogen peroxide and boric acid. 2. The fungicide according to claim 1, which contains an acrylic acid polymer as a thickener. 3. The fungicide according to claim 1.2, having a Pl-1 range of 3 to 6.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP137784A JPS60146807A (en) | 1984-01-10 | 1984-01-10 | Fungicide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP137784A JPS60146807A (en) | 1984-01-10 | 1984-01-10 | Fungicide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS60146807A true JPS60146807A (en) | 1985-08-02 |
Family
ID=11499793
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP137784A Pending JPS60146807A (en) | 1984-01-10 | 1984-01-10 | Fungicide |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60146807A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61158907A (en) * | 1985-01-07 | 1986-07-18 | Kao Corp | Mildew-removing agent composition |
| US4988500A (en) * | 1989-09-29 | 1991-01-29 | The Procter & Gamble Company | Oral compositions |
| JP2001503768A (en) * | 1996-11-13 | 2001-03-21 | ザ、プロクター、エンド、ギャンブル、カンパニー | Disinfecting composition for spray and method for disinfecting surface using the same |
| WO2003059069A1 (en) * | 2002-01-18 | 2003-07-24 | Novartis Ag | Methods for preserving ophthalmic solutions and preserved ophtalmic solutions |
-
1984
- 1984-01-10 JP JP137784A patent/JPS60146807A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61158907A (en) * | 1985-01-07 | 1986-07-18 | Kao Corp | Mildew-removing agent composition |
| US4988500A (en) * | 1989-09-29 | 1991-01-29 | The Procter & Gamble Company | Oral compositions |
| JP2001503768A (en) * | 1996-11-13 | 2001-03-21 | ザ、プロクター、エンド、ギャンブル、カンパニー | Disinfecting composition for spray and method for disinfecting surface using the same |
| WO2003059069A1 (en) * | 2002-01-18 | 2003-07-24 | Novartis Ag | Methods for preserving ophthalmic solutions and preserved ophtalmic solutions |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| AU2003245498B2 (en) | Enhanced activity hydrogen peroxide disinfectant | |
| US5531984A (en) | Antimicrobial composition | |
| US5281280A (en) | Composition for removing mildew containing hypochlorite, bicarbonate and d-limonene | |
| GB2319179A (en) | Cleaning and disinfecting compositions | |
| EP0047015B1 (en) | Sanitizing and bleaching composition | |
| DE10206172A1 (en) | Liquid bleach cleaning composition | |
| JP4526023B2 (en) | Agricultural fungicide composition | |
| US9538760B2 (en) | Disinfectant compositions with hydrogen peroxide | |
| US8114343B1 (en) | Corrosion inhibition of hypochlorite solutions using Zn and Ca | |
| JPS60146807A (en) | Fungicide | |
| JP4781664B2 (en) | Antibacterial agent | |
| US8105531B1 (en) | Corrosion inhibition of hypochlorite solutions using polyacrylate and Ca | |
| TW202044992A (en) | Sterilization or virus-inactivating agent composition, and method for enhancing efficacy of sterilization or virus inactivation | |
| CN108576035A (en) | A kind of mildew removing agent and preparation method thereof | |
| JP4680606B2 (en) | Water-based fungicide | |
| JP2001192700A (en) | Bleaching agent composition | |
| RU2192282C1 (en) | Disinfectant "septanol" | |
| JPS63267708A (en) | Antimold agent | |
| JPH11293281A (en) | Solid milder removing agent | |
| US12043820B2 (en) | Hard surface cleaning composition | |
| US4609482A (en) | Washing and cleaning agent with antimycetic action | |
| JP2008230154A (en) | Oil-in water composition for woody material treatment and two-agent type mildewproof composition for woody material, and mildewproof treatment method of woody material | |
| US20170156319A1 (en) | Product for mold prevention and treatment | |
| JP6781866B2 (en) | Deodorant and cleaning method for chlorine odor in residual scent of chlorine-based cleaning agent | |
| US20210338546A1 (en) | Hand cleaning composition with timed use duration |