JPS60130634A - Flame-retarding thermoplastic resin composition - Google Patents
Flame-retarding thermoplastic resin compositionInfo
- Publication number
- JPS60130634A JPS60130634A JP23605483A JP23605483A JPS60130634A JP S60130634 A JPS60130634 A JP S60130634A JP 23605483 A JP23605483 A JP 23605483A JP 23605483 A JP23605483 A JP 23605483A JP S60130634 A JPS60130634 A JP S60130634A
- Authority
- JP
- Japan
- Prior art keywords
- flame
- weight
- parts
- compound
- resin composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011342 resin composition Substances 0.000 title description 10
- 229920005992 thermoplastic resin Polymers 0.000 title description 3
- 150000001875 compounds Chemical class 0.000 claims abstract description 23
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910000410 antimony oxide Inorganic materials 0.000 claims abstract description 9
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract description 13
- 229920005989 resin Polymers 0.000 abstract description 11
- 239000011347 resin Substances 0.000 abstract description 11
- 239000000203 mixture Substances 0.000 abstract description 7
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract description 6
- 229920001519 homopolymer Polymers 0.000 abstract description 5
- 238000002156 mixing Methods 0.000 abstract description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract description 4
- 229920000098 polyolefin Polymers 0.000 abstract description 4
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 abstract description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 abstract description 3
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 abstract description 2
- JVPKLOPETWVKQD-UHFFFAOYSA-N 1,2,2-tribromoethenylbenzene Chemical compound BrC(Br)=C(Br)C1=CC=CC=C1 JVPKLOPETWVKQD-UHFFFAOYSA-N 0.000 abstract 1
- 239000003063 flame retardant Substances 0.000 description 15
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 10
- 230000000704 physical effect Effects 0.000 description 7
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical group C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 230000002411 adverse Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- WUOBERCRSABHOT-UHFFFAOYSA-N diantimony Chemical compound [Sb]#[Sb] WUOBERCRSABHOT-UHFFFAOYSA-N 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229920001890 Novodur Polymers 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- YMOONIIMQBGTDU-VOTSOKGWSA-N [(e)-2-bromoethenyl]benzene Chemical compound Br\C=C\C1=CC=CC=C1 YMOONIIMQBGTDU-VOTSOKGWSA-N 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- AHBGXHAWSHTPOM-UHFFFAOYSA-N 1,3,2$l^{4},4$l^{4}-dioxadistibetane 2,4-dioxide Chemical compound O=[Sb]O[Sb](=O)=O AHBGXHAWSHTPOM-UHFFFAOYSA-N 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical group COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910000411 antimony tetroxide Inorganic materials 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000005587 carbonate group Chemical group 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229920000831 ionic polymer Polymers 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、難燃性の優れたポリオンフィンおよび（また
は）スチレン系樹脂組成物に関するＯ
〔従来技術〕
ポリオンフィンおよび（または）スチレン系樹脂は現在
広範囲の用途に使用されているが易燃性という大きな欠
点を有している。このため従来、種々の難燃剤が研究さ
れ、多数の提案がなされているが、それらの中で、反応
型難燃剤は、目的とする難燃性の程度に応じて難燃剤の
共重合比を変えたポリマーを幾種類も作らねばならずま
た、難燃剤の種類によっては重合の調節が面倒であるた
め余り好ましいものではない。これに対して添加型難燃
剤は、これらの点では遥かに有利であるが特に低分子量
の難燃剤を使用した場合には、樹脂のもつ本来の性質、
殊に１熱性や機械的物性が低下することが多いため、最
近ではボ＋１マー型難燃剤が使用されるよう妃なってき
た。しかしながら、使用する難燃剤の種類や童によって
は成形性、成形品の外観等に問題を生ずるため、要求さ
れる緒特性をバランスよく備えた難燃性樹脂組成物を得
ることは容易でない。Detailed Description of the Invention [Industrial Field of Application] The present invention relates to polyion fins and/or styrene resin compositions with excellent flame retardancy. Although it is currently used in a wide range of applications, it has the major drawback of being easily flammable. For this reason, various flame retardants have been researched and a number of proposals have been made. This method is not very desirable because it requires the preparation of many different types of polymers, and it is troublesome to control the polymerization depending on the type of flame retardant. Additive flame retardants, on the other hand, are far more advantageous in these respects, but especially when low molecular weight flame retardants are used, the inherent properties of the resin,
In particular, the thermal properties and mechanical properties of flame retardants often deteriorate, so in recent years, flame retardants of the Bo+1mer type have been increasingly used. However, it is not easy to obtain a flame-retardant resin composition that has the required properties in a well-balanced manner, since problems may arise in moldability, appearance of the molded product, etc. depending on the type and type of flame retardant used.
本発明の目的はポリオレフィンおよび（または）スチレ
ン系樹脂のもつ本来の特性、特に耐熱性９機械的物性を
損なうことなく、これらをバランスよく備えた難燃性樹
脂組成物を提供することにある。An object of the present invention is to provide a flame-retardant resin composition that has a good balance of polyolefin and/or styrenic resin without impairing their inherent properties, particularly heat resistance and mechanical properties.
ン系樹脂１００重量部に対し、次の一般式で表わされる
繰返し単位を主成分とする化金物（■）１〜３０重量部
および次の一般式〔但し１、式中ｎは１〜５の整数を表
わす〕で表わされる繰返し単位を主成分とｊる化合物（
■）１〜３０重ｉ部並びに酸化アンチ七ン０〜３０重首
部を混合してなることを特徴とする難燃性熱可Ｖｉｉ性
樹脂組成物である。1 to 30 parts by weight of a metal compound (■) whose main component is a repeating unit represented by the following general formula, and the following general formula [where n is 1 to 5] per 100 parts by weight of the carbon-based resin. A compound whose main component is a repeating unit represented by
(2) A flame-retardant thermoplastic resin composition comprising 1 to 30 parts by weight and 0 to 30 parts by weight of antiseptane oxide.
本発明における易燃性樹脂はボ１１エチレン。The flammable resin in the present invention is Bo-11 ethylene.
ボ１１プロピレン、ボ１１ブテン、エチレン−プロピレ
ンコポリマーおよびこれらｆｆ） ＋（； ＩＩママ−
少量の他モ／マーを共重合ｉ−たコ。１（１１マーなど
な包括するポリオレフ・イン、並びに、Ｈ： １１スチ
レン、ポリメチルスチレンホ３よびこねらに他モノマー
を共重合したＡｓ拉ＪｌＩ旨、ＡＢＳ樹脂、ＭＢｓｍ脂
、ＡＡＳ樹脂、ＡＥ５４立（）１旨ナト（７） ＃＝＝
±土泣クポリり−および他、１５１１マーを配合したノ
・イイン／（クトｙ１ミリスザーレン樹脂などを包括す
るスチレン系樹脂、更ｒｔｃ ｉまこれらの混合物であ
る。Bo-11 propylene, bo-11 butene, ethylene-propylene copolymer and these ff) +(; II mom-
Copolymerized with a small amount of other molecules/mers. 1 (including polyolefins such as 11-mer, H: 11 styrene, polymethylstyrene 3, and other monomers copolymerized with other monomers), ABS resin, MBsm resin, AAS resin, AE54 resin. ()1 effect nato (7) #==
Styrenic resins, including styrene resins containing 1511 mer and other 1511 mer, and mixtures thereof.
本発明妊おいて使用される化合物（１１はテトラフロ上
ビスフェノールＡカーボネートの繰返し単位のみよりな
るホモポリマー、テトラブロモビスフェノールＡの一部
または（および）炭酸基の一部を他の二価フェノールま
たは（および）他の二塩基酸基で置換したコポリマーで
ある。コポリマー圧おいてはテトラブロモビスフェノー
ルＡカーボネートの繰り返１．単位が少くとも５０％を
占める。これらの二価フェノール、二塩基酸の例として
は、ビスフェノールＡ、１．１−ビス（４−ヒドロキシ
フェニル）ソクロヘキサン、ビス（４−ヒドロキシフェ
ニル）スルホン、テレフタル酸、イソフタル酸およびこ
れらのハｐゲン置換体などを挙げることができろ。しか
しながら、原料向、製造面１本発明組成物の物性面より
みて、テトラブＣＪ七ビスフェノールＡカーボネートの
ホモポリマーが第も好適である。The compound used in the present invention (11 is a homopolymer consisting only of repeating units of bisphenol A carbonate on tetrabromo, a part of tetrabromo bisphenol A or (and) a part of the carbonate group, or another dihydric phenol or ( and) with other dibasic acid groups.In the copolymer pressure, repeating units of tetrabromobisphenol A carbonate account for at least 50%. Examples of these dihydric phenols, dibasic acids Examples include bisphenol A, 1,1-bis(4-hydroxyphenyl)isoclohexane, bis(4-hydroxyphenyl)sulfone, terephthalic acid, isophthalic acid, and hapgen-substituted products thereof.However, , Raw Materials, and Production Aspects 1 From the physical properties of the composition of the present invention, a homopolymer of Tetrabu CJ heptabisphenol A carbonate is most preferred.
ポリマーの両末端は％忙制限がないがそれ自体の安定性
を高めるためにフエノーノ１或は低級アルキルまたはハ
ロゲンで置換ｔ、た７エ／−ルで封鎖することが好まし
い。これら化合物＋１１は、試料０．７０ 、ｐ、テト
ラヒドロフラン１００ｍＡ！、２０℃の比粘度０．０１
５〜０．１好ましくは０．０２〜０．０８を有すること
が望ましい。この範囲を超えると本発明組成物の成形時
に流動性不良、溶融不完全などによるトラブルを生じ、
反対にこの節回未満では成形品の耐熱性や機織的物性を
損ｌｘ ５ので好ましくない。Both terminal ends of the polymer are preferably capped with phenol or lower alkyl or halogen-substituted esters, although there is no % restriction, in order to increase the stability of the polymer itself. These compounds +11 are sample 0.70, p, tetrahydrofuran 100 mA! , specific viscosity at 20°C 0.01
It is desirable to have a value of 5 to 0.1, preferably 0.02 to 0.08. If this range is exceeded, troubles such as poor flowability and incomplete melting may occur during molding of the composition of the present invention.
On the other hand, if it is less than this, the heat resistance and weaving properties of the molded article will be impaired, which is not preferable.
また化合物（［１はブロモスチレンのホモポリマー並び
にその一部を仙のモノマー、例ｔば７クリロニトリル、
スチレン、メチルメタクリレートなどで置換し５たコポ
リマーである。In addition, compounds ([1] is a homopolymer of bromostyrene and a part of it is a monomer of the same type, for example, 7) is a monomer of bromostyrene,
It is a copolymer substituted with styrene, methyl methacrylate, etc.
（−かじ１よから原料面、製造面２本発明組成物の物性
面よりみてトＩＩプｐモスチレンのポモポリマーが最も
好適である。これらの化合物（■）は試料０．７０ ｇ
、テトラヒドロフラン１００ｍ１．２０℃の比粘度０．
０３〜０．５、好ましくは０．０５〜０．３を有するこ
とが望ましい。この範囲を超えると、本発明組成物の成
形時に流動性不良、焼けなどのトラブルを生じまたこの
範囲未満では成形品の耐熱性が低下する゛ので好ましく
ない。さらＫ、酸化アンチモンは、三酸化二７ンチ七ン
、四酸化二７ンチモンおよび五酸化二アンチモンをいう
が特に三酸化二アンチモンが好ましい。(From the point of view 1, starting from the raw material aspect and manufacturing aspect 2) From the viewpoint of the physical properties of the composition of the present invention, the pomopolymer of mosttyrene is most suitable.
, Tetrahydrofuran 100ml 1. Specific viscosity at 20°C 0.
03 to 0.5, preferably 0.05 to 0.3. If it exceeds this range, troubles such as poor flowability and burning may occur during molding of the composition of the present invention, and if it is less than this range, the heat resistance of the molded product will decrease, which is not preferable. Antimony oxide refers to antimony trioxide, antimony tetroxide, and diantimony pentoxide, with diantimony trioxide being particularly preferred.
本発明の樹脂組成物の混合割合は、易燃性樹脂１００重
量部に対して化合物（Ｔ）が１〜３０重量部、化合物（
［１が１〜３０重量部および酸化アンチモンが０〜３０
重量部であり、好ましくは化合物（１）が２〜２０重量
部、化合物（Ｉｌｌが２〜２ＯＮ量部、および酸化アン
チモンが１〜２０重景部重量る。化合物＋１＋が１重量
部未満では十分な難燃性が得られず、３０重量部を超え
ると機械的物性に悪影響を与える。また化合物叩が１重
量部未満では十分な難燃性が得られず、３０３（置部を
超えると機械的物性が低下する。さらにまた、酸化アン
チモンが３０重置部を超えると物性に悪影響を尊大る。The mixing ratio of the resin composition of the present invention is 1 to 30 parts by weight of compound (T) and 1 to 30 parts by weight of compound (T) to 100 parts by weight of flammable resin.
[1 to 30 parts by weight of 1 and 0 to 30 parts by weight of antimony oxide
Parts by weight, preferably 2 to 20 parts by weight of compound (1), 2 to 2 parts by weight of compound (Ill), and 1 to 20 parts by weight of antimony oxide. Less than 1 part by weight of compound +1+ is sufficient. If the amount exceeds 30 parts by weight, it will adversely affect mechanical properties. If the amount of the compound is less than 1 part by weight, sufficient flame retardance will not be obtained, and if it exceeds 303 parts by weight, mechanical properties will be adversely affected. Moreover, if the amount of antimony oxide exceeds 30 parts, the physical properties will be adversely affected.
本発明の樹脂組成物を製造するにをま、従来より既知の
混和方法を利用すそ）ことカーでき４）。To produce the resin composition of the present invention, conventionally known blending methods can be used (4).
たとえばポリオレフイレ−、ｔａよび（またｉ２ ）ス
チレン系樹脂のパウダーまたはベレットと第１を燃剤お
よび酸化アンチモンをタンフ゛ラー、Ｖ型ルンダー等で
混合した後、押出機等によって溶融混和して製造できる
。For example, it can be produced by mixing the powder or pellet of polyolefin, TA and (also I2) styrene resin, the first fuel, and antimony oxide in a tumbler, V-type lunder, etc., and then melting and blending them in an extruder or the like.
かぐして得られる樹脂組成物は射出成形。The resin composition obtained by smelting is injection molded.
押出成形、圧縮成形等の方法によって成ノ杉、υ。Narinosugi, υ by methods such as extrusion molding and compression molding.
にされる。本発明の難燃性樹脂組成９１ま化合物（１）
単独、および化合物（１１と酸化アンチモンの併用系や
、化合物（１１４独および化合ｅ＋ （ＩＩ）と酸化ア
ンチモンの併用系と比φ７＋て難燃１生。be made into Flame retardant resin composition 91 compound (1) of the present invention
Flame retardant of φ7+ when used alone or in combination with compound (11) and antimony oxide, or with compound (114 or compound e+ (II) and antimony oxide).
耐熱性１機械的物性の・くランスｈ″−優れたく、σ）
であり広範囲の用途に使用できる。Heat Resistance 1 Mechanical Properties - Clearance h'' - Excellent, σ)
It can be used for a wide range of purposes.
〔実施例１ 以下に実施例を掲げて本発明ン詳述する。[Example 1 The present invention will be described in detail below with reference to Examples.
なお、実施例中の難燃性のＦＰｆ価はＵＬ−９４に従っ
て実施し物性の評価はＡＳＴＭに従って実施した。In addition, the flame retardant FPf value in the examples was conducted in accordance with UL-94, and the evaluation of physical properties was conducted in accordance with ASTM.
実施例１〜３．比較例１〜４
アクＩＩ Ｉ：Ｉニトリル−ブタジェン−スチレン共重
合体（三菱モンサント昨）製タフレックスＴＦＸ−４１
０） １０ ｏ＄量置部対し化合物（Ｉ）（帝人什成■
製ＦＧ−７５００）、化合物（ＩＩ） （Ｂ産）Ｊロ有
機化学■製パイロ壬ニック６８ＰＢ）及び三酸化ニアン
チモン（住友金属鉱山■＠！りを種々の割合で混合し３
０ ｍｍφの押出機を用いてペレット化した。得られた
ベレットを８０℃で３時間乾燥後射出成形によって試験
片を成形した。得られた試験片について難燃性、引張伸
度 ＩＩ−４’８
ｉｎｃｈノツチ付アイゾツト衝撃強さ、 ＋ ８．６
ｋｐ／ｃ１１荷重曲げ温度を測定した。結果を表１に示
す。Examples 1-3. Comparative Examples 1 to 4 Aku II I:I nitrile-butadiene-styrene copolymer (Mitsubishi Monsanto Co., Ltd.) Tuflex TFX-41
0) Compound (I) (Teijin Yosei■
FG-7500) produced by JRO Organic Chemical Co., Ltd.), Compound (II) (produced by B) Pyrojin Nick 68PB produced by Jro Organic Chemical Co., Ltd.) and diantimony trioxide (Sumitomo Metal Mining Co., Ltd.) were mixed in various proportions.
It was pelletized using a 0 mmφ extruder. The obtained pellet was dried at 80° C. for 3 hours and then molded into a test piece by injection molding. The obtained test piece had flame retardancy, tensile elongation II-4'8 inch notched Izot impact strength, +8.6
kp/c11 load bending temperature was measured. The results are shown in Table 1.
＃燃性は１／４ 、 ］／８及び１／ １６１ｎｃｈ
、＄ ８について成は見出せなかった。#Flammability is 1/4, ]/8 and 1/161nch
, No results were found for $8.
実施例４〜６．比較例５〜８
ポリエチレン樹脂（日本石油化学■製Ｗ −１０１０）
１００重世部に対し化合物（Ｉ）（帝人化成■製ＦＧ−
７５００）、化合物Ｉ１１ （日量フェロ有機化学■製
パイロチェック６８ＰＢ）、及び三酸化ニアンチモン（
住友金属鉱山■製）を種々の割合で混合し１、笑施例工
と同様にして試験片を成形した。得られた試験片につい
て４６．５ ｋｇ／ ｃｒａｍ重で荷重曲げ温度を測定
した他は実施例１と同様に（、て物性を測定ｉ−た。結
来を表２に示した。Examples 4-6. Comparative Examples 5 to 8 Polyethylene resin (W-1010 manufactured by Nippon Petrochemical Co., Ltd.)
Compound (I) (FG- manufactured by Teijin Chemicals) for 100 parts
7500), Compound I11 (Pyrocheck 68PB manufactured by Ferro Organic Chemicals), and Niantimony trioxide (
(manufactured by Sumitomo Metal Mining) in various proportions and molded into test pieces in the same manner as in Example 1. The physical properties of the obtained test piece were measured in the same manner as in Example 1, except that the bending temperature under load was measured at a load of 46.5 kg/cram.The results are shown in Table 2.
本発明の粗゛酸物についてはＳ燃性はＩ ／ ４ 、１
／ ８及び］ ／１ａ １ｎｃｈ 、厚さについてＵ
Ｌ−９４Ｖ−２であり物性も良好であった。比較例にお
いては難燃ａ物性の、・）ンスσ）とれた組成は見出せ
なかった。Regarding the crude acid of the present invention, the S flammability is I/4, 1
/8 and] /1a 1nch, thickness U
It was L-94V-2 and had good physical properties. In the comparative example, no composition with good flame-retardant physical properties was found.
手 続 補 正 書
昭和５９年Ｊ月ｊ日
％許庁莢官 殿
１、 事件の表示
特願昭５８−２３６０５４号
２ 発明の名称
難燃性熱可輩性樹脂組成物
３、 補正をする者
事件との関係 特許出願人
５、 補正の対象
明細１の「発明の詳細な説明」の掴
６、＋＋ｆｉ正の内容
明細ｗの第１１頁第８行Ｋ ＋ ４６，５Ｊとあるを［
４，６５Ｊに訂正する。Procedures Amendment Written date: J/J, 1980 To the Permanent Office Officer: 1. Indication of the case, Patent Application No. 58-236054. 2. Name of the invention: Flame-retardant thermoplastic resin composition 3. Person making the amendment. Relationship to the case Patent applicant 5, grasp of the "detailed description of the invention" of the specification subject to amendment 1, 6, ++fi correct description of contents w, page 11, line 8 K + 46,5J [
Corrected to 4.65J.
Claims (1)
脂１００重量部に対し、次の一般式で表わされる繰返し
単位を主成分とする化合物（１）１〜３０重量部および
次の一般式〔但し、式中ｎは１〜５の整数を表わす。１
で表わされる繰返し単位を生成分とする化合物Ｏｆ）
］〜３０重量部並びに酸什アンチモン０〜３０重量部を
混合してなることを特徴とする難燃性熱可塑性樹脂組成
物。[Scope of Claims] +1+ 1 to 30 parts by weight of a compound (1) whose main component is a repeating unit represented by the following general formula and the following general formula [ However, in the formula, n represents an integer of 1 to 5. 1
A compound whose product is a repeating unit represented by (Of)
] to 30 parts by weight and 0 to 30 parts by weight of antimony oxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23605483A JPS60130634A (en) | 1983-12-16 | 1983-12-16 | Flame-retarding thermoplastic resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23605483A JPS60130634A (en) | 1983-12-16 | 1983-12-16 | Flame-retarding thermoplastic resin composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60130634A true JPS60130634A (en) | 1985-07-12 |
| JPS6411057B2 JPS6411057B2 (en) | 1989-02-23 |
Family
ID=16995054
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP23605483A Granted JPS60130634A (en) | 1983-12-16 | 1983-12-16 | Flame-retarding thermoplastic resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60130634A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59217738A (en) * | 1983-05-24 | 1984-12-07 | Kanegafuchi Chem Ind Co Ltd | Flame-retardant synthetic resin composition |
-
1983
- 1983-12-16 JP JP23605483A patent/JPS60130634A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59217738A (en) * | 1983-05-24 | 1984-12-07 | Kanegafuchi Chem Ind Co Ltd | Flame-retardant synthetic resin composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6411057B2 (en) | 1989-02-23 |
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