JPS60130634A - Flame-retarding thermoplastic resin composition - Google Patents
Flame-retarding thermoplastic resin compositionInfo
- Publication number
- JPS60130634A JPS60130634A JP23605483A JP23605483A JPS60130634A JP S60130634 A JPS60130634 A JP S60130634A JP 23605483 A JP23605483 A JP 23605483A JP 23605483 A JP23605483 A JP 23605483A JP S60130634 A JPS60130634 A JP S60130634A
- Authority
- JP
- Japan
- Prior art keywords
- flame
- weight
- parts
- compound
- resin composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011342 resin composition Substances 0.000 title description 10
- 229920005992 thermoplastic resin Polymers 0.000 title description 3
- 150000001875 compounds Chemical class 0.000 claims abstract description 23
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910000410 antimony oxide Inorganic materials 0.000 claims abstract description 9
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract description 13
- 229920005989 resin Polymers 0.000 abstract description 11
- 239000011347 resin Substances 0.000 abstract description 11
- 239000000203 mixture Substances 0.000 abstract description 7
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract description 6
- 229920001519 homopolymer Polymers 0.000 abstract description 5
- 238000002156 mixing Methods 0.000 abstract description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract description 4
- 229920000098 polyolefin Polymers 0.000 abstract description 4
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 abstract description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 abstract description 3
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 abstract description 2
- JVPKLOPETWVKQD-UHFFFAOYSA-N 1,2,2-tribromoethenylbenzene Chemical compound BrC(Br)=C(Br)C1=CC=CC=C1 JVPKLOPETWVKQD-UHFFFAOYSA-N 0.000 abstract 1
- 239000003063 flame retardant Substances 0.000 description 15
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 10
- 230000000704 physical effect Effects 0.000 description 7
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical group C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 230000002411 adverse Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- WUOBERCRSABHOT-UHFFFAOYSA-N diantimony Chemical compound [Sb]#[Sb] WUOBERCRSABHOT-UHFFFAOYSA-N 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229920001890 Novodur Polymers 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- YMOONIIMQBGTDU-VOTSOKGWSA-N [(e)-2-bromoethenyl]benzene Chemical compound Br\C=C\C1=CC=CC=C1 YMOONIIMQBGTDU-VOTSOKGWSA-N 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- AHBGXHAWSHTPOM-UHFFFAOYSA-N 1,3,2$l^{4},4$l^{4}-dioxadistibetane 2,4-dioxide Chemical compound O=[Sb]O[Sb](=O)=O AHBGXHAWSHTPOM-UHFFFAOYSA-N 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical group COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910000411 antimony tetroxide Inorganic materials 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000005587 carbonate group Chemical group 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229920000831 ionic polymer Polymers 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、難燃性の優れたポリオンフィンおよび(また
は)スチレン系樹脂組成物に関するO
〔従来技術〕
ポリオンフィンおよび(または)スチレン系樹脂は現在
広範囲の用途に使用されているが易燃性という大きな欠
点を有している。このため従来、種々の難燃剤が研究さ
れ、多数の提案がなされているが、それらの中で、反応
型難燃剤は、目的とする難燃性の程度に応じて難燃剤の
共重合比を変えたポリマーを幾種類も作らねばならずま
た、難燃剤の種類によっては重合の調節が面倒であるた
め余り好ましいものではない。これに対して添加型難燃
剤は、これらの点では遥かに有利であるが特に低分子量
の難燃剤を使用した場合には、樹脂のもつ本来の性質、
殊に1熱性や機械的物性が低下することが多いため、最
近ではボ+1マー型難燃剤が使用されるよう妃なってき
た。しかしながら、使用する難燃剤の種類や童によって
は成形性、成形品の外観等に問題を生ずるため、要求さ
れる緒特性をバランスよく備えた難燃性樹脂組成物を得
ることは容易でない。Detailed Description of the Invention [Industrial Field of Application] The present invention relates to polyion fins and/or styrene resin compositions with excellent flame retardancy. Although it is currently used in a wide range of applications, it has the major drawback of being easily flammable. For this reason, various flame retardants have been researched and a number of proposals have been made. This method is not very desirable because it requires the preparation of many different types of polymers, and it is troublesome to control the polymerization depending on the type of flame retardant. Additive flame retardants, on the other hand, are far more advantageous in these respects, but especially when low molecular weight flame retardants are used, the inherent properties of the resin,
In particular, the thermal properties and mechanical properties of flame retardants often deteriorate, so in recent years, flame retardants of the Bo+1mer type have been increasingly used. However, it is not easy to obtain a flame-retardant resin composition that has the required properties in a well-balanced manner, since problems may arise in moldability, appearance of the molded product, etc. depending on the type and type of flame retardant used.
本発明の目的はポリオレフィンおよび(または)スチレ
ン系樹脂のもつ本来の特性、特に耐熱性9機械的物性を
損なうことなく、これらをバランスよく備えた難燃性樹
脂組成物を提供することにある。An object of the present invention is to provide a flame-retardant resin composition that has a good balance of polyolefin and/or styrenic resin without impairing their inherent properties, particularly heat resistance and mechanical properties.
ン系樹脂100重量部に対し、次の一般式で表わされる
繰返し単位を主成分とする化金物(■)1〜30重量部
および次の一般式〔但し1、式中nは1〜5の整数を表
わす〕で表わされる繰返し単位を主成分とjる化合物(
■)1〜30重i部並びに酸化アンチ七ン0〜30重首
部を混合してなることを特徴とする難燃性熱可Vii性
樹脂組成物である。1 to 30 parts by weight of a metal compound (■) whose main component is a repeating unit represented by the following general formula, and the following general formula [where n is 1 to 5] per 100 parts by weight of the carbon-based resin. A compound whose main component is a repeating unit represented by
(2) A flame-retardant thermoplastic resin composition comprising 1 to 30 parts by weight and 0 to 30 parts by weight of antiseptane oxide.
本発明における易燃性樹脂はボ11エチレン。The flammable resin in the present invention is Bo-11 ethylene.
ボ11プロピレン、ボ11ブテン、エチレン−プロピレ
ンコポリマーおよびこれらff) +(; IIママ−
少量の他モ/マーを共重合i−たコ。1(11マーなど
な包括するポリオレフ・イン、並びに、H: 11スチ
レン、ポリメチルスチレンホ3よびこねらに他モノマー
を共重合したAs拉JlI旨、ABS樹脂、MBsm脂
、AAS樹脂、AE54立()1旨ナト(7) #==
±土泣クポリり−および他、1511マーを配合したノ
・イイン/(クトy1ミリスザーレン樹脂などを包括す
るスチレン系樹脂、更rtc iまこれらの混合物であ
る。Bo-11 propylene, bo-11 butene, ethylene-propylene copolymer and these ff) +(; II mom-
Copolymerized with a small amount of other molecules/mers. 1 (including polyolefins such as 11-mer, H: 11 styrene, polymethylstyrene 3, and other monomers copolymerized with other monomers), ABS resin, MBsm resin, AAS resin, AE54 resin. ()1 effect nato (7) #==
Styrenic resins, including styrene resins containing 1511 mer and other 1511 mer, and mixtures thereof.
本発明妊おいて使用される化合物(11はテトラフロ上
ビスフェノールAカーボネートの繰返し単位のみよりな
るホモポリマー、テトラブロモビスフェノールAの一部
または(および)炭酸基の一部を他の二価フェノールま
たは(および)他の二塩基酸基で置換したコポリマーで
ある。コポリマー圧おいてはテトラブロモビスフェノー
ルAカーボネートの繰り返1.単位が少くとも50%を
占める。これらの二価フェノール、二塩基酸の例として
は、ビスフェノールA、1.1−ビス(4−ヒドロキシ
フェニル)ソクロヘキサン、ビス(4−ヒドロキシフェ
ニル)スルホン、テレフタル酸、イソフタル酸およびこ
れらのハpゲン置換体などを挙げることができろ。しか
しながら、原料向、製造面1本発明組成物の物性面より
みて、テトラブCJ七ビスフェノールAカーボネートの
ホモポリマーが第も好適である。The compound used in the present invention (11 is a homopolymer consisting only of repeating units of bisphenol A carbonate on tetrabromo, a part of tetrabromo bisphenol A or (and) a part of the carbonate group, or another dihydric phenol or ( and) with other dibasic acid groups.In the copolymer pressure, repeating units of tetrabromobisphenol A carbonate account for at least 50%. Examples of these dihydric phenols, dibasic acids Examples include bisphenol A, 1,1-bis(4-hydroxyphenyl)isoclohexane, bis(4-hydroxyphenyl)sulfone, terephthalic acid, isophthalic acid, and hapgen-substituted products thereof.However, , Raw Materials, and Production Aspects 1 From the physical properties of the composition of the present invention, a homopolymer of Tetrabu CJ heptabisphenol A carbonate is most preferred.
ポリマーの両末端は%忙制限がないがそれ自体の安定性
を高めるためにフエノーノ1或は低級アルキルまたはハ
ロゲンで置換t、た7エ/−ルで封鎖することが好まし
い。これら化合物+11は、試料0.70 、p、テト
ラヒドロフラン100mA!、20℃の比粘度0.01
5〜0.1好ましくは0.02〜0.08を有すること
が望ましい。この範囲を超えると本発明組成物の成形時
に流動性不良、溶融不完全などによるトラブルを生じ、
反対にこの節回未満では成形品の耐熱性や機織的物性を
損lx 5ので好ましくない。Both terminal ends of the polymer are preferably capped with phenol or lower alkyl or halogen-substituted esters, although there is no % restriction, in order to increase the stability of the polymer itself. These compounds +11 are sample 0.70, p, tetrahydrofuran 100 mA! , specific viscosity at 20°C 0.01
It is desirable to have a value of 5 to 0.1, preferably 0.02 to 0.08. If this range is exceeded, troubles such as poor flowability and incomplete melting may occur during molding of the composition of the present invention.
On the other hand, if it is less than this, the heat resistance and weaving properties of the molded article will be impaired, which is not preferable.
また化合物([1はブロモスチレンのホモポリマー並び
にその一部を仙のモノマー、例tば7クリロニトリル、
スチレン、メチルメタクリレートなどで置換し5たコポ
リマーである。In addition, compounds ([1] is a homopolymer of bromostyrene and a part of it is a monomer of the same type, for example, 7) is a monomer of bromostyrene,
It is a copolymer substituted with styrene, methyl methacrylate, etc.
(−かじ1よから原料面、製造面2本発明組成物の物性
面よりみてトIIプpモスチレンのポモポリマーが最も
好適である。これらの化合物(■)は試料0.70 g
、テトラヒドロフラン100m1.20℃の比粘度0.
03〜0.5、好ましくは0.05〜0.3を有するこ
とが望ましい。この範囲を超えると、本発明組成物の成
形時に流動性不良、焼けなどのトラブルを生じまたこの
範囲未満では成形品の耐熱性が低下する゛ので好ましく
ない。さらK、酸化アンチモンは、三酸化二7ンチ七ン
、四酸化二7ンチモンおよび五酸化二アンチモンをいう
が特に三酸化二アンチモンが好ましい。(From the point of view 1, starting from the raw material aspect and manufacturing aspect 2) From the viewpoint of the physical properties of the composition of the present invention, the pomopolymer of mosttyrene is most suitable.
, Tetrahydrofuran 100ml 1. Specific viscosity at 20°C 0.
03 to 0.5, preferably 0.05 to 0.3. If it exceeds this range, troubles such as poor flowability and burning may occur during molding of the composition of the present invention, and if it is less than this range, the heat resistance of the molded product will decrease, which is not preferable. Antimony oxide refers to antimony trioxide, antimony tetroxide, and diantimony pentoxide, with diantimony trioxide being particularly preferred.
本発明の樹脂組成物の混合割合は、易燃性樹脂100重
量部に対して化合物(T)が1〜30重量部、化合物(
[1が1〜30重量部および酸化アンチモンが0〜30
重量部であり、好ましくは化合物(1)が2〜20重量
部、化合物(Illが2〜2ON量部、および酸化アン
チモンが1〜20重景部重量る。化合物+1+が1重量
部未満では十分な難燃性が得られず、30重量部を超え
ると機械的物性に悪影響を与える。また化合物叩が1重
量部未満では十分な難燃性が得られず、303(置部を
超えると機械的物性が低下する。さらにまた、酸化アン
チモンが30重置部を超えると物性に悪影響を尊大る。The mixing ratio of the resin composition of the present invention is 1 to 30 parts by weight of compound (T) and 1 to 30 parts by weight of compound (T) to 100 parts by weight of flammable resin.
[1 to 30 parts by weight of 1 and 0 to 30 parts by weight of antimony oxide
Parts by weight, preferably 2 to 20 parts by weight of compound (1), 2 to 2 parts by weight of compound (Ill), and 1 to 20 parts by weight of antimony oxide. Less than 1 part by weight of compound +1+ is sufficient. If the amount exceeds 30 parts by weight, it will adversely affect mechanical properties. If the amount of the compound is less than 1 part by weight, sufficient flame retardance will not be obtained, and if it exceeds 303 parts by weight, mechanical properties will be adversely affected. Moreover, if the amount of antimony oxide exceeds 30 parts, the physical properties will be adversely affected.
本発明の樹脂組成物を製造するにをま、従来より既知の
混和方法を利用すそ)ことカーでき4)。To produce the resin composition of the present invention, conventionally known blending methods can be used (4).
たとえばポリオレフイレ−、taよび(またi2 )ス
チレン系樹脂のパウダーまたはベレットと第1を燃剤お
よび酸化アンチモンをタンフ゛ラー、V型ルンダー等で
混合した後、押出機等によって溶融混和して製造できる
。For example, it can be produced by mixing the powder or pellet of polyolefin, TA and (also I2) styrene resin, the first fuel, and antimony oxide in a tumbler, V-type lunder, etc., and then melting and blending them in an extruder or the like.
かぐして得られる樹脂組成物は射出成形。The resin composition obtained by smelting is injection molded.
押出成形、圧縮成形等の方法によって成ノ杉、υ。Narinosugi, υ by methods such as extrusion molding and compression molding.
にされる。本発明の難燃性樹脂組成91ま化合物(1)
単独、および化合物(11と酸化アンチモンの併用系や
、化合物(114独および化合e+ (II)と酸化ア
ンチモンの併用系と比φ7+て難燃1生。be made into Flame retardant resin composition 91 compound (1) of the present invention
Flame retardant of φ7+ when used alone or in combination with compound (11) and antimony oxide, or with compound (114 or compound e+ (II) and antimony oxide).
耐熱性1機械的物性の・くランスh″−優れたく、σ)
であり広範囲の用途に使用できる。Heat Resistance 1 Mechanical Properties - Clearance h'' - Excellent, σ)
It can be used for a wide range of purposes.
〔実施例1 以下に実施例を掲げて本発明ン詳述する。[Example 1 The present invention will be described in detail below with reference to Examples.
なお、実施例中の難燃性のFPf価はUL−94に従っ
て実施し物性の評価はASTMに従って実施した。In addition, the flame retardant FPf value in the examples was conducted in accordance with UL-94, and the evaluation of physical properties was conducted in accordance with ASTM.
実施例1〜3.比較例1〜4
アクII I:Iニトリル−ブタジェン−スチレン共重
合体(三菱モンサント昨)製タフレックスTFX−41
0) 10 o$量置部対し化合物(I)(帝人什成■
製FG−7500)、化合物(II) (B産)Jロ有
機化学■製パイロ壬ニック68PB)及び三酸化ニアン
チモン(住友金属鉱山■@!りを種々の割合で混合し3
0 mmφの押出機を用いてペレット化した。得られた
ベレットを80℃で3時間乾燥後射出成形によって試験
片を成形した。得られた試験片について難燃性、引張伸
度 II−4’8
inchノツチ付アイゾツト衝撃強さ、 + 8.6
kp/c11荷重曲げ温度を測定した。結果を表1に示
す。Examples 1-3. Comparative Examples 1 to 4 Aku II I:I nitrile-butadiene-styrene copolymer (Mitsubishi Monsanto Co., Ltd.) Tuflex TFX-41
0) Compound (I) (Teijin Yosei■
FG-7500) produced by JRO Organic Chemical Co., Ltd.), Compound (II) (produced by B) Pyrojin Nick 68PB produced by Jro Organic Chemical Co., Ltd.) and diantimony trioxide (Sumitomo Metal Mining Co., Ltd.) were mixed in various proportions.
It was pelletized using a 0 mmφ extruder. The obtained pellet was dried at 80° C. for 3 hours and then molded into a test piece by injection molding. The obtained test piece had flame retardancy, tensile elongation II-4'8 inch notched Izot impact strength, +8.6
kp/c11 load bending temperature was measured. The results are shown in Table 1.
#燃性は1/4 、 ]/8及び1/ 161nch
、$ 8について成は見出せなかった。#Flammability is 1/4, ]/8 and 1/161nch
, No results were found for $8.
実施例4〜6.比較例5〜8
ポリエチレン樹脂(日本石油化学■製W −1010)
100重世部に対し化合物(I)(帝人化成■製FG−
7500)、化合物I11 (日量フェロ有機化学■製
パイロチェック68PB)、及び三酸化ニアンチモン(
住友金属鉱山■製)を種々の割合で混合し1、笑施例工
と同様にして試験片を成形した。得られた試験片につい
て46.5 kg/ cram重で荷重曲げ温度を測定
した他は実施例1と同様に(、て物性を測定i−た。結
来を表2に示した。Examples 4-6. Comparative Examples 5 to 8 Polyethylene resin (W-1010 manufactured by Nippon Petrochemical Co., Ltd.)
Compound (I) (FG- manufactured by Teijin Chemicals) for 100 parts
7500), Compound I11 (Pyrocheck 68PB manufactured by Ferro Organic Chemicals), and Niantimony trioxide (
(manufactured by Sumitomo Metal Mining) in various proportions and molded into test pieces in the same manner as in Example 1. The physical properties of the obtained test piece were measured in the same manner as in Example 1, except that the bending temperature under load was measured at a load of 46.5 kg/cram.The results are shown in Table 2.
本発明の粗゛酸物についてはS燃性はI / 4 、1
/ 8及び] /1a 1nch 、厚さについてU
L−94V−2であり物性も良好であった。比較例にお
いては難燃a物性の、・)ンスσ)とれた組成は見出せ
なかった。Regarding the crude acid of the present invention, the S flammability is I/4, 1
/8 and] /1a 1nch, thickness U
It was L-94V-2 and had good physical properties. In the comparative example, no composition with good flame-retardant physical properties was found.
手 続 補 正 書
昭和59年J月j日
%許庁莢官 殿
1、 事件の表示
特願昭58−236054号
2 発明の名称
難燃性熱可輩性樹脂組成物
3、 補正をする者
事件との関係 特許出願人
5、 補正の対象
明細1の「発明の詳細な説明」の掴
6、++fi正の内容
明細wの第11頁第8行K + 46,5Jとあるを[
4,65Jに訂正する。Procedures Amendment Written date: J/J, 1980 To the Permanent Office Officer: 1. Indication of the case, Patent Application No. 58-236054. 2. Name of the invention: Flame-retardant thermoplastic resin composition 3. Person making the amendment. Relationship to the case Patent applicant 5, grasp of the "detailed description of the invention" of the specification subject to amendment 1, 6, ++fi correct description of contents w, page 11, line 8 K + 46,5J [
Corrected to 4.65J.
Claims (1)
脂100重量部に対し、次の一般式で表わされる繰返し
単位を主成分とする化合物(1)1〜30重量部および
次の一般式〔但し、式中nは1〜5の整数を表わす。1
で表わされる繰返し単位を生成分とする化合物Of)
]〜30重量部並びに酸什アンチモン0〜30重量部を
混合してなることを特徴とする難燃性熱可塑性樹脂組成
物。[Scope of Claims] +1+ 1 to 30 parts by weight of a compound (1) whose main component is a repeating unit represented by the following general formula and the following general formula [ However, in the formula, n represents an integer of 1 to 5. 1
A compound whose product is a repeating unit represented by (Of)
] to 30 parts by weight and 0 to 30 parts by weight of antimony oxide.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP23605483A JPS60130634A (en) | 1983-12-16 | 1983-12-16 | Flame-retarding thermoplastic resin composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP23605483A JPS60130634A (en) | 1983-12-16 | 1983-12-16 | Flame-retarding thermoplastic resin composition |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS60130634A true JPS60130634A (en) | 1985-07-12 |
JPS6411057B2 JPS6411057B2 (en) | 1989-02-23 |
Family
ID=16995054
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP23605483A Granted JPS60130634A (en) | 1983-12-16 | 1983-12-16 | Flame-retarding thermoplastic resin composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS60130634A (en) |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59217738A (en) * | 1983-05-24 | 1984-12-07 | Kanegafuchi Chem Ind Co Ltd | Flame-retardant synthetic resin composition |
-
1983
- 1983-12-16 JP JP23605483A patent/JPS60130634A/en active Granted
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59217738A (en) * | 1983-05-24 | 1984-12-07 | Kanegafuchi Chem Ind Co Ltd | Flame-retardant synthetic resin composition |
Also Published As
Publication number | Publication date |
---|---|
JPS6411057B2 (en) | 1989-02-23 |
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