JPS6011592A - Liquid detergent composition - Google Patents
Liquid detergent compositionInfo
- Publication number
- JPS6011592A JPS6011592A JP11699083A JP11699083A JPS6011592A JP S6011592 A JPS6011592 A JP S6011592A JP 11699083 A JP11699083 A JP 11699083A JP 11699083 A JP11699083 A JP 11699083A JP S6011592 A JPS6011592 A JP S6011592A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- fatty acid
- weight
- detergent composition
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims description 15
- 239000007788 liquid Substances 0.000 title claims description 5
- 239000003599 detergent Substances 0.000 title claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 15
- 229930195729 fatty acid Natural products 0.000 claims description 15
- 239000000194 fatty acid Substances 0.000 claims description 15
- 150000004665 fatty acids Chemical class 0.000 claims description 11
- -1 ammonium cations Chemical class 0.000 claims description 10
- 150000003839 salts Chemical class 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 6
- 229910052749 magnesium Inorganic materials 0.000 claims description 6
- 239000011777 magnesium Substances 0.000 claims description 6
- 125000003342 alkenyl group Chemical group 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 150000001735 carboxylic acids Chemical class 0.000 claims description 2
- 239000002253 acid Substances 0.000 description 7
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 235000015165 citric acid Nutrition 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 239000008233 hard water Substances 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000001630 malic acid Substances 0.000 description 2
- 235000011090 malic acid Nutrition 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000006277 sulfonation reaction Methods 0.000 description 2
- 239000011975 tartaric acid Substances 0.000 description 2
- 235000002906 tartaric acid Nutrition 0.000 description 2
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- MRTWZIXSCCETHN-UHFFFAOYSA-N 2-sulfododecanoic acid Chemical compound CCCCCCCCCCC(C(O)=O)S(O)(=O)=O MRTWZIXSCCETHN-UHFFFAOYSA-N 0.000 description 1
- CJAJEZSCULAKCB-UHFFFAOYSA-N 2-sulfohexadecanoic acid Chemical compound CCCCCCCCCCCCCCC(C(O)=O)S(O)(=O)=O CJAJEZSCULAKCB-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 241000270295 Serpentes Species 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
本発明はα−スルホ脂肋酸ジ塩を主要活性成分として含
有する洗液液性に俊れた数体洗浄剤組成９勿に１碧する
。DETAILED DESCRIPTION OF THE INVENTION The present invention provides a detergent composition with excellent washing properties, which contains α-sulfolipid acid di-salt as a main active ingredient.
α−スルホ脂肪酸の水溶性ジ塩は硬水中にて白濁沈殿を
生じ、洗浄性能に著るしい悪形書を与えていることが知
られている。そのためアルキルベンゼンスルホン酸塩と
の併用（％ 公昭４７−１２５８２号）などの方法が開
示されているが、洗液液性を未だ十分に改善しうるもの
ではなかった。It is known that water-soluble di-salts of α-sulfo fatty acids form cloudy precipitates in hard water, which seriously impairs the cleaning performance. Therefore, methods such as the combination use with alkylbenzene sulfonate (% Publication No. 47-12582) have been disclosed, but these methods have not yet been able to sufficiently improve the washing properties.
本発明者らは、これらの点を考慮して、洗液液性に後れ
た洗浄剤組成物を開発すべく鋭意検討を重ねた貼果、α
−スルホ脂肪酸の特定のジ塩に有機カルボン酸またはそ
の塩と、特定炭素数の脂肪酸残基を有する高級脂肪酸ジ
アルカノールアミドを特定比率で配合す−ることにより
、この目的を達成しうろことを見い出し、この知見に基
いて本発明を完成するに至った。Taking these points into consideration, the present inventors have conducted intensive studies to develop a cleaning agent composition that is not as good as a cleaning liquid.
-By blending a specific di-salt of a sulfo fatty acid with an organic carboxylic acid or its salt and a higher fatty acid dialkanolamide having a fatty acid residue having a specific number of carbon atoms, this objective can be achieved. Based on this finding, we have completed the present invention.
すなわち、本発明の液体洗浄剤組成物は以下の（ａ）〜
（ｃ）成分を含有することを特徴とする。That is, the liquid cleaning composition of the present invention has the following (a) to
It is characterized by containing component (c).
（＆）一般式（Ｉ）
（式中、Ｒは炭素数８〜１６のアルキル基またはアルケ
ニル基であり、Ｍおよびゾはいずれもマグネシウムおよ
び置換または未置換のアンモニウム基より成る群から選
ばれた水溶性塩を形成するカチオンであって、それぞれ
同一であっても異なってもよい。）で表わされるα−ス
ルホ脂肪酸ジ塩５〜５０重量％、
（ｂ） 有機カルｙ＋ンン酸および／またはその塩０．
０１〜３０重Ｍ％、
（ｃ）脂肪酸残基の炭素数が１０〜１４の高級脂肪酸ジ
アルカノールアミド０〜３０重量％。(&) General formula (I) (wherein R is an alkyl group or alkenyl group having 8 to 16 carbon atoms, M and zo are both selected from the group consisting of magnesium and a substituted or unsubstituted ammonium group. 5 to 50% by weight of α-sulfo fatty acid di-salts represented by cations forming water-soluble salts, each of which may be the same or different; (b) organic carbonic acid and/or its Salt 0.
(c) 0 to 30% by weight of a higher fatty acid dialkanolamide whose fatty acid residue has 10 to 14 carbon atoms.
本発明組成物に（、）成分として用いるα−スルホ脂肪
酸塩は、前記一般式（Ｉ）で表わされる構造を有してお
り、その式中のＲは炭素数８〜１６のアルキル基又はア
ルケニル基である。Ｍ、Ｍ’はマグネシウム又は置換、
未置換のアンモニウムであり、モノエタノールアミン、
ジェタノールアミン、トリエタノールアミンなどの置換
アンモニウムが好ましい。α−スルホ脂肪酸塩の具体例
としては、α−スルホラウリン酸、α−スルホミリスチ
ン酸、α−スルホパルミチン酸、α−スルホ硬化パーム
脂肪岐、α−スルホ硬化牛脂脂肪岐、α−スルホヤシ脂
肪酸のマグネシウム・２アンモニウム・２トリエタノー
ルアミン・２ジェタノールアミン−２モノエタノールア
ミン・％マグネシウム１アンモニウム”３Ａマグネシウ
ムｌトリエタノールアミンなどが例示できる。このα−
スルホ脂肪酸は、全炭素数１０〜１８の脂肪酸を通常の
連続薄膜型スルホン化装置又は種型スルホン化装置でス
ルホン化したのち、中和するか、あるいは脂肪酸エステ
ルをスルホン化したのち、強アルカリ下で加熱処理する
ことによって得られる。The α-sulfo fatty acid salt used as the component (,) in the composition of the present invention has a structure represented by the above general formula (I), in which R is an alkyl group having 8 to 16 carbon atoms or an alkenyl group. It is the basis. M, M' are magnesium or substituted,
Unsubstituted ammonium, monoethanolamine,
Substituted ammoniums such as jetanolamine and triethanolamine are preferred. Specific examples of α-sulfo fatty acid salts include α-sulfolauric acid, α-sulfomirristic acid, α-sulfopalmitic acid, α-sulfohydrogenated palm fatty acid, α-sulfohydrogenated beef tallow fatty acid, and α-sulfohydrolysate fatty acid. Examples include magnesium, 2 ammonium, 2 triethanolamine, 2 jetanolamine, 2 monoethanolamine, %magnesium 1 ammonium"3A magnesium 1 triethanolamine, etc.
Sulfo fatty acids are produced by sulfonating fatty acids with a total carbon number of 10 to 18 using a conventional continuous thin film sulfonation device or seed type sulfonation device, then neutralizing them, or by sulfonating fatty acid esters and then sulfonating them under strong alkali. Obtained by heat treatment.
本発明組成物におけるα−スルホ脂肪酸塩の含有量は５
〜５０重量％、好ましくは１５〜３０重量％の範囲であ
って、この含有量が５重量係未満では十分な効果を発揮
せず、また５０Ｍ輩俤を超えると洗浄剤の溶解性が劣化
して好ましくない。The content of α-sulfo fatty acid salt in the composition of the present invention is 5
~50% by weight, preferably 15 to 30% by weight; if this content is less than 5% by weight, sufficient effect will not be exhibited, and if it exceeds 50M, the solubility of the cleaning agent will deteriorate. I don't like it.
本発明組成物に（ｂ）成分として用いる有機カルゼン酸
またはその塩としては、例えば乳酸、グルコン酸、シュ
ウ酸、マロン酸、コハク酸、グルタル酸、マレイン酸、
クエン酸、酒石酸、リンゴ酸など、あるいはそれらのア
ルカリ金属塩や、置換、未置換のアンモニウム塩が挙げ
られ、好ましくは低級多価カルゼン酸またはその塩であ
り、これらの中で最も好ましいものはクエン酸トリエタ
ノールアミンである。Examples of the organic carzenic acid or its salt used as component (b) in the composition of the present invention include lactic acid, gluconic acid, oxalic acid, malonic acid, succinic acid, glutaric acid, maleic acid,
Examples include citric acid, tartaric acid, malic acid, etc., their alkali metal salts, and substituted or unsubstituted ammonium salts, preferably lower polycarzenic acids or their salts, and the most preferred among these are citric acid, tartaric acid, malic acid, etc. The acid triethanolamine.
これらの有機カルゼン酸またはその塩は、それぞれ単独
で用いてもよいし、 ２．ｆｉｎ以上混合して用いても
よく、その含有量は０．０１〜３０重量％、好ましくは
５〜１５重ｉ−％の範囲である。These organic carzenic acids or salts thereof may be used alone, or 2. A mixture of fin or more may be used, and the content thereof is in the range of 0.01 to 30% by weight, preferably 5 to 15% by weight.
また、本発明の組成物に用いられる高級脂肪 ５−
酸ジアルカノールアミドは、炭素数１０〜１４の飽和又
は不飽和の脂肪酸とジェタノールアミンとから容易に得
ることができる。Further, the higher fatty 5-acid dialkanolamide used in the composition of the present invention can be easily obtained from a saturated or unsaturated fatty acid having 10 to 14 carbon atoms and jetanolamine.
これらのアルカノールアミド類は単独又は２種以上を混
合使用することができる。These alkanolamides can be used alone or in combination of two or more.
この第３の成分である高級脂肪酸ジアルカノールアミド
は、水を媒体とする組成物中に０〜３０重量％の量範囲
で添加使用される。その量が３０重ａ：チを超えるとす
すぎ性が悪（なり好ましくない。好ましい量は１０〜２
０重量％の範囲である。The third component, higher fatty acid dialkanolamide, is added to the water-based composition in an amount ranging from 0 to 30% by weight. If the amount exceeds 30% by weight, the rinsing properties will be poor (and undesirable).The preferred amount is 10 to 2%.
It is in the range of 0% by weight.
本発明組成物には、前記の必須成分に加えて必要に応じ
、通常洗浄剤に用いられている界面活性剤、香料、色素
などを用いることができる。In addition to the above-mentioned essential components, the composition of the present invention may contain, if necessary, surfactants, fragrances, pigments, etc. that are commonly used in detergents.
前記の界面活性剤としては、α−オレフィンスルホン故
ナナトリウム直鎖アルキルベンゼンスルホン酸ナトリウ
ム、アルキル硫酸ナトリウム、ポリオキシエチレンアル
キルエーテル硫酸ナトリウム、などのアニオン性界面活
性剤、あるいは慣用の非イオン性界面活性剤、両性界面
活性 ６−
剤、カチオン性界面活性剤を悸げることかできる。Examples of the surfactant include anionic surfactants such as α-olefin sulfone late sodium linear alkylbenzene sulfonate, sodium alkyl sulfate, sodium polyoxyethylene alkyl ether sulfate, or conventional nonionic surfactants. It is possible to use surfactants, amphoteric surfactants, and cationic surfactants.
実施例
以下の第１表〜第３表に示す組成の本発明の洗浄剤組成
物を調製し、洗液液性を評価した。EXAMPLES Cleaning compositions of the present invention having the compositions shown in Tables 1 to 3 below were prepared and their cleaning properties were evaluated.
洗液液性評価法
試料を３°ＤＨ硬水に、組成物として０．１５ ｗｔ％
の洗液濃度となるように浴解し、この浴液を高さ２５０
ｍｍ内径２５．５ ｔｒｙの比色管（ガラス製）に入れ
目視で判定した。Washing liquid property evaluation method Sample was added to 3°DH hard water at 0.15 wt% as a composition.
The bath solution was dissolved at a height of 250 mm.
It was placed in a colorimetric tube (glass) with an inner diameter of 25.5 mm and visually determined.
○：透 明 △：極僅か白濁 ×二白 濁 （以下余白） ７− ８− ０ ８ ロ 。 ○ Ｏロ ８ ロ 、−巳 −〇 。 〜 。 。〈 −６ 侭 〈 り ｐ＋＋ ００ １ ０ ０ 棋 ＝ ！ ・Ｏ禽 ○ ゝ ０ 膿 ○ 脩 “ ０ “ ′°° ・ −〇 〈 Ｕ′ 唖 の 綜 〈 ＣＱ １ロ に） に） Ｈ 特 ト −Ｊ 朗 占受 〒屡 一、Ｓ へ′Ｘ 纒 ０ へ ヤ慇 童 廻 栗＠ （○: Transparent △: Very slightly cloudy ×Nihaku turbidity (Margin below) 7- 8- 0 8 b. ○ O ro 8 ro , - Snake -〇 . ~. . < -6 Ambition < ri p++ 00 1 0 0 Chess =!・O bird ○ ゝ Pus ○ Shu “ ′°° ・ −〇 < U' Mute's Skein < CQ 1ro ni) ni) H Special To-J Akira Fortune telling 1. To S'X Go to 0 Children's circle chestnut@ (
Claims (1)
ニル基であり、Ｍおよびゾはいずれもマグネシウムおよ
び置換または未置換のアンモニウム基より成る群から選
ばれた水溶性塩を形成するカチオンであって、それぞれ
同一であっても異なってもよい。） で表わされるα−スルホ脂肪酸ジ塩５〜５０重量係、 （ｂ） 有機カルボン酸および／またはその塩０．０１
〜３０重ｉチおよび （Ｃ） 脂肪酸残基の炭素数が１０−１４の高級脂肪酸
ジアルカノールアミド０〜３０重量％を含有することを
特徴とする液体洗浄剤組成！１勿。[Claims] 1. (,) General formula (I) (wherein R is an alkyl group or alkenyl group having 8 to 16 carbon atoms, M and zo are both magnesium and substituted or unsubstituted ammonium cations forming water-soluble salts selected from the group consisting of groups, each of which may be the same or different; Carboxylic acid and/or its salt 0.01
~30% by weight and (C) A liquid detergent composition characterized by containing 0 to 30% by weight of a higher fatty acid dialkanolamide whose fatty acid residue has 10-14 carbon atoms! 1 Of course.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11699083A JPS6011592A (en) | 1983-06-30 | 1983-06-30 | Liquid detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11699083A JPS6011592A (en) | 1983-06-30 | 1983-06-30 | Liquid detergent composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6011592A true JPS6011592A (en) | 1985-01-21 |
Family
ID=14700743
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11699083A Pending JPS6011592A (en) | 1983-06-30 | 1983-06-30 | Liquid detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6011592A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1995006107A1 (en) * | 1993-08-27 | 1995-03-02 | The Procter & Gamble Company | Concentrated light duty liquid or gel dishwashing detergent compositions containing sugar |
| JP2008236717A (en) * | 2007-03-20 | 2008-10-02 | Estec Corp | Speaker |
-
1983
- 1983-06-30 JP JP11699083A patent/JPS6011592A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1995006107A1 (en) * | 1993-08-27 | 1995-03-02 | The Procter & Gamble Company | Concentrated light duty liquid or gel dishwashing detergent compositions containing sugar |
| JP2008236717A (en) * | 2007-03-20 | 2008-10-02 | Estec Corp | Speaker |
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