JPS60114689A - Spraying method of refractory in molten metal receiving vessel - Google Patents
Spraying method of refractory in molten metal receiving vesselInfo
- Publication number
- JPS60114689A JPS60114689A JP22141083A JP22141083A JPS60114689A JP S60114689 A JPS60114689 A JP S60114689A JP 22141083 A JP22141083 A JP 22141083A JP 22141083 A JP22141083 A JP 22141083A JP S60114689 A JPS60114689 A JP S60114689A
- Authority
- JP
- Japan
- Prior art keywords
- refractory
- spraying
- refractories
- water
- nozzle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Casting Support Devices, Ladles, And Melt Control Thereby (AREA)
- Furnace Housings, Linings, Walls, And Ceilings (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
(産業上の利用分野)
本発明は、溶融金属収納容器における耐火物の吹付方法
に関し、詳しくは、耐火物の乾式吹付方法の改良に関す
る。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a method for spraying refractories in a molten metal storage container, and more particularly to an improvement in a dry spraying method for refractories.
(従来技術) 一般に、溶融金属を収納する容器においては。(Conventional technology) Generally, in containers containing molten metal.
高温下の苛酷な使用条件に対処して長寿命を保持するた
めに耐火物の(ハ)張シを使用途中において中間補修を
施している。このような容器の中間補修方法としては1
作業環境の改善、及び施工能率と施工コストの点から耐
火物の吹付による補修が広く採用されている。而して、
容器内壁面の耐火物吹付施工においては、湿式法と乾式
法が用いられているが、湿式法、では、面1火物スラリ
ーが該吹付装置内に詰ると共に、施工面において吹付け
た耐火物か流下して落ちるため耐火物の損失か物めて大
きく甘だ、施工後の仕上り精製が粗−悪となる等の理由
からむしろ乾式法が主に採用されている。In order to maintain a long lifespan under harsh conditions of use under high temperatures, refractory (c) refractories are repaired midway through use. There are 1 intermediate repair methods for such containers.
Repair by spraying refractories has been widely adopted from the viewpoint of improving the working environment, construction efficiency, and construction cost. Then,
A wet method and a dry method are used for spraying refractories on the inner wall of a container, but in the wet method, the refractory slurry from side 1 clogs the spraying device, and the refractory sprayed on the construction surface The dry method is mainly used because of the large loss of refractories as the refractories flow down and the quality of the finished product after construction is poor.
しかし、この乾式法による耐火物の吹付施工も施工体表
面の耐火物の発塵を充分に抑止できないこと、及び耐火
物のりバンドロス(反発落下)が多く、シかも耐火物に
添加した水、もしくは助剤の混合不良による施工能率と
施工体表面の剥離等による仕上’) fr?度が慈い等
の欠点がある。従って。However, spraying of refractories using this dry method cannot sufficiently suppress the generation of dust from the refractories on the surface of the construction object, and there is a lot of band loss (repulsion falling) of the refractories. Construction efficiency due to poor mixing of auxiliary agents and finish due to peeling of the surface of the construction work') fr? There are drawbacks such as being too generous. Therefore.
従来より前述の乾式・吹付方法の問題点を解決するため
に、例えば実公昭52−9236号公報の如く、ノズル
チップの元部に耐火物粉粒に旋回運動を与えるように、
複数の噴出小孔を穿設したリングを有する水分添加混合
器を設けた吹付ノズル(以、下単にリング式ノズルと称
する)を用いた吹付施工法が行なわれている。In order to solve the problems of the dry spraying method described above, for example, as in Japanese Utility Model Publication No. 52-9236, a method has been proposed in which swirling motion is applied to the refractory powder particles at the base of the nozzle tip.
A spraying method using a spray nozzle (hereinafter simply referred to as a ring-type nozzle) equipped with a water addition mixer having a ring with a plurality of small ejection holes has been carried out.
このリング式ノズルを用いた吹付方法は、該ノズル部で
粉粒体に給水しながら、該粉粒体に旋回運動を付与し、
さらに、二次空気の吹込によって。This spraying method using a ring type nozzle involves applying a swirling motion to the powder while supplying water to the powder with the nozzle,
Additionally, by blowing in secondary air.
前記の旋回運動を助長し、水と耐火物の混合を促進する
ことから、ある程度の発塵とりバンドロスの防止を図れ
るが、単に、粉粒体に旋回運動を付与するのみでは、確
実に発塵を抑止すると共に。By promoting the above-mentioned swirling motion and promoting the mixing of water and refractories, it is possible to remove dust and prevent band loss to some extent, but simply imparting swirling motion to the powder will definitely prevent dust generation. as well as deterring.
施工体表面の耐火物のりバンドロスを防止し、しかも施
工能率と仕上シ精度の向上を図るに至っていない。It has not yet been possible to prevent adhesive band loss of refractory material on the surface of a construction body and to improve construction efficiency and finishing accuracy.
(発明の目的)
本発明は、前述した従来の吹付方法の欠点である発塵の
十分な抑止と施工体表面のりバンドロスの減少、及び施
工能率と施工面の仕上シ精度の向上を図る吹付方法であ
って、その特徴とするところは+ i4火物粉を供給す
る一次気体の供給圧力P。(Object of the Invention) The present invention is a spraying method that sufficiently suppresses dust generation, which are the drawbacks of the conventional spraying methods described above, reduces glue band loss on the surface of a construction object, and improves construction efficiency and finishing accuracy of the construction surface. Its feature is the supply pressure P of the primary gas that supplies the + i4 fire powder.
を1〜3 KF//ca とし、且つ、−次気体の供給
圧力P1と二次気体あ供給圧力P2とをP2/P+=1
.2〜3.0としたことにあり極めて優れた耐火物の吹
付方法である。is 1 to 3 KF//ca, and the supply pressure P1 of the negative gas and the supply pressure P2 of the secondary gas are P2/P+=1
.. 2 to 3.0, this is an extremely excellent method for spraying refractories.
(発明の構成・作用)
以下1本発明による耐火物の吹付方法について詳述する
。(Structure and operation of the invention) A method for spraying refractories according to the present invention will be described in detail below.
耐火物の乾式・吹付方法において、施工体表面の発塵と
りバンドロスを抑止するためには、吠付ける耐火物粉粒
に十分な加水を施すことによっである程度性ない得るが
、ノズルチップ元部(給水点)から先端の噴出口までの
距離か短かいことから。In the dry method/spraying method of refractories, in order to remove dust from the surface of the construction object and prevent band loss, it is possible to reduce the properties to some extent by adding sufficient water to the refractory powder particles that are barking. This is because the distance from the water supply point to the spout at the tip is short.
刷火物と水、もしくは添加助剤等を十分に混合できず、
かなりの発塵とリノ(ンドロスか発生すると共に、耐火
物中の含水量の)くラツキによるノズル詰りゃ施工体表
面の耐火物の流下をも招く。而して1本発明は、耐火物
を乾式で吹付ける際に、吹付時の発塵と施工体表面のリ
バンドロスの抑止を図ることが重要であることに着目し
、しかも、単に一耐人物粉に添加水を増加することなく
、むしろ極めて少ない加水範囲でもって、ノズルチップ
元部から先端の噴出口までの短かい距離で水と耐火物を
十分に混合することによって、前記の発塵と施工体表面
のりバンドロスを極めて効果的に抑止できることを見い
出したことにある。また、吹付時の耐火物の損失の減少
による耐火物の付着率の向上と施工能率の向上を図ると
共に、調湿の均一化によシ、施工体表面の仕上り精度上
も向上せしめたことに基づくものである。The printed material and water or additives cannot be mixed sufficiently,
If the nozzle is clogged due to considerable dust and reno (and loss) and uneven water content in the refractory, the refractory will flow down on the surface of the construction body. Therefore, the present invention focuses on the importance of suppressing dust generation during spraying and reband loss on the surface of the construction object when dry spraying refractories, and moreover, By sufficiently mixing water and refractories in a short distance from the base of the nozzle tip to the spout at the tip, without increasing the amount of water added, rather with an extremely small range of water addition, the above-mentioned dust generation and construction The present invention is based on the discovery that it is possible to extremely effectively suppress adhesive band loss on the body surface. In addition, by reducing the loss of refractories during spraying, the adhesion rate of refractories has been improved and construction efficiency has been improved, as well as more uniform humidity control and improved finishing accuracy on the surface of the construction object. It is based on
このように1本発明は、ノズル部の極めて短かい距離を
耐火物粉流が通過する間に、添加された水分を十分に均
等混合するために、加水された耐火物粉と該耐火物供給
用の一次気体(以下単に一次空気と称する)の流れに、
二次気体(以下単に二次空気と称する)を圧入してノズ
ル光跡近傍内部で、前記の一次空気と面1大物粉の混合
流に乱流を付与して優れた均一混合を得ると共に、効果
的な耐火物の吹付を成し得た。In this way, one aspect of the present invention is to mix the hydrated refractory powder and the refractory supply in order to mix the added water sufficiently and evenly while the refractory powder flow passes through a very short distance in the nozzle. In the flow of primary gas (hereinafter simply referred to as primary air),
A secondary gas (hereinafter simply referred to as secondary air) is pressurized to impart turbulence to the mixed flow of the primary air and surface-1 large powder inside the vicinity of the nozzle light trail, thereby obtaining excellent uniform mixing; Effective spraying of refractories was achieved.
即ち、本発明による耐火物の吹付方法は、第1図の本実
験結果に示すように、耐火物の供給用−次空気圧P1を
1.0〜3.0 Kf/dにすることによって、耐火物
の供給量を十分に確保して吹付施工を短時間で行ない、
しかもノズル内詰りを防止して、吹付耐大物の付着率を
向上させる。捷だ、単に。That is, the method for spraying refractories according to the present invention, as shown in the experimental results in FIG. We ensure a sufficient supply of material and carry out spraying work in a short time.
Moreover, it prevents clogging in the nozzle and improves the adhesion rate of large objects. It's simple, simply.
前記の耐火物の供給−次空気圧P1のみでは、付着率に
限界があるために、第2図に示す如く、該−次空気圧P
1と二次空気圧P2とf P27 Pl = 1.2〜
30とし、ノズル先端近傍内部に嵌挿した短管を介して
二次空気を圧入することによって、該ノズル先端内部で
、−次空気と耐火物粉の混合流に乱流を付与して添加さ
れた水分と耐火物粉とを十分に混合する。Since there is a limit to the adhesion rate when the refractory is supplied only at the air pressure P1, as shown in FIG.
1 and secondary air pressure P2 and f P27 Pl = 1.2 ~
30, and by pressurizing secondary air through a short pipe inserted inside the nozzle tip, turbulence is added to the mixed flow of secondary air and refractory powder inside the nozzle tip. Thoroughly mix the water and refractory powder.
マタ1本発明による耐火物の吹付方法は、第1図及び第
2図に示す如く、単に、−次空気圧の最適化、あるいは
P2/”lのみを満足しても耐火q勿の発頭とリバンド
ロスを抑止し、耐火物吹付時のイテ1゛着率の向上は望
めず、−次空気圧P、を1〜3 Kg/Cniの範囲で
、しかもP2/P、−1,2〜3.0の両方を満足する
ことによって、始めて、前記の耐火物粉の混合流に付与
する乱流が強化されて耐火物と添力1水、もしくは助剤
等の均等混合が十分に行なわれる。さらにまた、耐火物
供給−次空気圧P1が。Mata 1 As shown in Figs. 1 and 2, the spraying method for refractories according to the present invention is based on simply optimizing the -order air pressure or satisfying only P2/"l, which does not lead to the onset of fire resistance problems. In order to prevent reband loss and improve the item 1 coverage rate when spraying refractories, the negative air pressure P is in the range of 1 to 3 Kg/Cni, and P2/P is -1, 2 to 3.0. By satisfying both of the above, the turbulence imparted to the mixed flow of the refractory powder is strengthened, and the refractory and additive water or auxiliary agent are sufficiently mixed.Furthermore, , refractory supply - next air pressure P1.
1.0Kfj/cm未満になると、耐火物輸送管、ある
いは、吹付ノズル内に耐火物が詰シ吹付不能となる。When it is less than 1.0 Kfj/cm, it becomes impossible to fill and spray the refractory into the refractory transport pipe or the spray nozzle.
また、たとえ吹付が可能となったとしても耐火物の詰シ
防止の点から供給量を極度に少なくするため、施工に長
時間を要する。一方、 3.1 K9/cyf以上にな
ると、吐出噴流が強くなり、リバンドロス。Furthermore, even if spraying becomes possible, the amount of refractory supplied must be extremely small to prevent clogging, which requires a long time for construction. On the other hand, when it exceeds 3.1 K9/cyf, the discharge jet becomes strong and reband loss occurs.
が多発する。occurs frequently.
また、P2/P、の比が]−2未満になると、吹付ノズ
ル先端での耐火物と水分との混合が均一に行なわれず、
耐火物の流下とりバンドロス、及び発塵を招き、 P2
/P、が5. Oよシ太きいとノズル先端の面J火物の
吐出噴流が強くなることから、吹付面において、耐火物
のりバンドロスが多発する。このように、耐火物吹付に
おいて、発塵、及びリバンドロス等を抑止して、施工能
率の向上を図るには、−次空気圧P、を1.5−2.5
Kg/caとし、−次空気圧P1と二次空気圧P2と
の比をp2/ p、 = 1.5〜2.0とすると吹付
がより効果的に行なわれるので望ましい。Furthermore, if the ratio of P2/P is less than -2, the refractory and moisture will not be mixed uniformly at the tip of the spray nozzle,
This leads to band loss and dust generation due to falling refractory material, P2
/P, is 5. If it is thicker than O, the jet of refractory discharged from the surface J of the nozzle tip will become stronger, resulting in frequent band loss of the refractory on the spraying surface. In this way, in order to suppress dust generation, reband loss, etc. and improve construction efficiency in spraying refractories, the -second air pressure P should be set to 1.5-2.5.
Kg/ca, and the ratio of the secondary air pressure P1 to the secondary air pressure P2 is p2/p, = 1.5 to 2.0, since spraying can be performed more effectively.
なお、前記の吹付に用いられる一次、二次気体は例えば
空気、窒素、Ar、等のガス体で良く。The primary and secondary gases used in the above-mentioned spraying may be, for example, air, nitrogen, Ar, or the like.
また、吹付を行なう際の耐火物粉への吹付距離は。Also, what is the spraying distance to the refractory powder when spraying?
200〜700前で、この耐火物の添加水分量も10〜
20%にすることが望ましい。200 to 700, and the added moisture content of this refractory is also 10 to 700.
It is desirable to set it to 20%.
ここで、吹付距離が200 rnm未満になると、リバ
ンドロス、発塵が発生すると同時に、材料の広がり性が
悪く吹付時間が長くなる。一方、700n1m以上にな
るとノズル先端の耐火物の吐出噴流が拡散して味付困難
になる。Here, if the spraying distance is less than 200 rnm, ribbon loss and dust generation will occur, and at the same time, the spreadability of the material will be poor and the spraying time will be longer. On the other hand, if it exceeds 700 n1m, the jet of refractory discharged from the tip of the nozzle will diffuse, making it difficult to add flavor.
また、水分については、10俸未満になると耐火物中の
含水分量が少なくな9、リバンドロス、発塵が発生しや
すくなり、逆に水分か21%以上になると水分過多によ
るノズル内の詰りあるいは吹付面の耐火物流下及び乾燥
時の爆裂による剥離等が発生しやすくなる。Regarding moisture, if the moisture content is less than 10%, the moisture content in the refractory will be low9, reband loss, and dust generation will occur easily.On the other hand, if the moisture content is more than 21%, the nozzle may become clogged or sprayed due to excessive moisture. Peeling due to explosion during drying and refractory flow is more likely to occur.
(実施例)
次に1本発明による耐火物の吹付方法の実施例を図に基
づいて述べる。(Example) Next, an example of the method for spraying refractories according to the present invention will be described based on the drawings.
第3図は、ノズル先端部に振動性短管を有する吹付ノズ
ルを示し、第4図は、ノズル先端部に固定短管、を翁す
る吹付ノズルを示す。FIG. 3 shows a spray nozzle having a vibrating short tube at the nozzle tip, and FIG. 4 shows a spray nozzle having a fixed short tube at the nozzle tip.
まず、第3図において、1は、例えば適宜径の鋼管の如
き円筒であって、先端に絞9部1aを設けて耐火物の流
路を形成している。この円筒1で形成された耐火物流路
は1例えは、耐火物粉圧送装置(図示せず)に連接され
た一次空気圧P1の抑圧によシ、耐火物と一次空気の混
合流が矢印2の方向に供給される。First, in FIG. 3, numeral 1 is a cylinder such as a steel pipe of an appropriate diameter, and has a restrictor 9 portion 1a at its tip to form a flow path for the refractory. For example, by suppressing the primary air pressure P1 connected to a refractory powder pumping device (not shown), a mixed flow of refractory and primary air is created by the arrow 2. supplied in the direction.
址だ1円筒1の適宜部位には、複数の給水孔3を穿設し
、該給水孔3に連通した給水ヘッダー4と該給水ヘング
ー4に固設した給水管5が設けてあり、前記の耐火物粉
と一次空気の混合流に加水する。また、加水された混合
流は、さらに、先端部に穿設された二次空気圧入口6と
給気ヘラグー7に連接された給気管8によって、二次空
気が圧入される。この圧入二次空気は、円筒lの直管部
から先端絞9部la間内部に設けられた例えば硬質布。A plurality of water supply holes 3 are bored in appropriate parts of the cylinder 1, and a water supply header 4 communicating with the water supply holes 3 and a water supply pipe 5 fixed to the water supply head 4 are provided. Water is added to the mixed stream of refractory powder and primary air. In addition, secondary air is further pressurized into the water-added mixed flow through an air supply pipe 8 connected to a secondary air pressure inlet 6 bored at the tip and an air supply hose 7. This press-in secondary air is supplied by a hard cloth, for example, provided inside the cylinder l between the straight pipe part and the tip aperture 9 part la.
または硬質ゴム等からなる振動性の短管9を嵌挿した際
の絞9部1aの内壁面と該短管9との空隙部lOを介し
て内部に圧入される。Alternatively, the vibrating short tube 9 made of hard rubber or the like is press-fitted into the inside through the gap lO between the inner wall surface of the throttle 9 portion 1a and the short tube 9.
この二次空気の圧入によって、短管9の先端11近傍で
前記の矢印2方向に供給された耐火物と一次空気の混合
流に乱流が付与される。By press-fitting the secondary air, turbulence is imparted to the mixed flow of the refractory and primary air supplied near the tip 11 of the short pipe 9 in the two directions of the arrows.
また、第4図に示す如く、前記の硬質コムに替えて、例
えば鋼管、セラミック等を用いた非振動性の短管9でも
よく、十分に耐火物の混合流に乱流を付与することがで
きた。Further, as shown in Fig. 4, instead of the hard comb, a non-vibrating short pipe 9 made of, for example, a steel pipe or ceramic may be used, and it is possible to sufficiently impart turbulence to the mixed flow of refractories. did it.
(−発明の効果)
次に、第3図及び第4図に示ず吹付ノズルを用いてタン
ティッシュの内壁面にM f O系耐火物を含水量15
%、吹付距離350 rtrmにて吹付施工した拳法実
施例1と同一含水量、吹付距離でもって一次空気圧P、
を2. OKg/cnjでP2/P1を本法範凹外とし
た従来法とを第1表に比較して示すが1本法が。(-Effect of the invention) Next, using a spray nozzle not shown in FIGS.
%, primary air pressure P with the same water content and spraying distance as Kempo Example 1, which was sprayed at a spraying distance of 350 rtrm,
2. Table 1 shows a comparison with the conventional method in which P2/P1 is outside the scope of this method for OKg/cnj.
発塵、施工面でのりバンドロス、耐火物の流下による落
ち等がなく吹付方法として優れていることがわかる。It can be seen that this method is excellent as a spraying method because there is no dust generation, no adhesive band loss on the construction surface, no falling of refractories due to falling down, etc.
第1表
以上述べたように、乾式吹付において1本法を用いるこ
とによ)駒大物輸送配管、及びノズルの詰9を防、止で
きるとともに、リバンドロス、発塵。Table 1 As mentioned above, by using the single method in dry spraying, it is possible to prevent clogging of the piping for transporting large objects and nozzles 9, as well as reband loss and dust generation.
耐火物の流下による落ちなどの問題を解消できると共に
、施工面に対する付着率の向上から施工能率が、極めて
高く、シかも広く耐火物の内張りを施した容器に適用で
きる優れた耐火物の吹付方法である。This is an excellent method of spraying refractories that can solve problems such as falling refractories due to falling, and has extremely high construction efficiency due to improved adhesion to the construction surface, and can be applied to a wide range of containers lined with refractories. It is.
第1図は、耐火物供給−次空気圧P、と付着率の関係を
示す。第2図は、二次空気圧P2と一次空気圧P1の比
と付着率の関係を示す。第3図は、ノズル先端部に振動
性短管を設けた吹付ノズルの断面概略図を示し、第4図
は、ノズル先端部に固定短管を設けた吹付ノズルの断面
碩略図を示している。
l・・・円筒 Pl・・−次空気圧
P2・・・二次空気圧 3・・・給水孔4・・・給水ヘ
ッダー 5・・給水管
6・・・二次空気圧入口 7・・・給気ヘッダ=8・・
・給気管 9・・・短管
第1図
第 2 叉FIG. 1 shows the relationship between the refractory supply-sub-air pressure P and the adhesion rate. FIG. 2 shows the relationship between the ratio of the secondary air pressure P2 and the primary air pressure P1 and the adhesion rate. Fig. 3 shows a schematic cross-sectional view of a spray nozzle in which a vibrating short pipe is provided at the nozzle tip, and Fig. 4 shows a schematic cross-sectional view of a spray nozzle in which a fixed short pipe is provided in the nozzle tip. . l...Cylinder Pl...-Secondary air pressure P2...Secondary air pressure 3...Water supply hole 4...Water supply header 5...Water supply pipe 6...Secondary air pressure inlet 7...Air supply header =8...
・Air supply pipe 9...Short pipe Figure 1 2nd fork
Claims (1)
気体の混合流体に加水し1次いで該混合流体に二次気体
を圧入する耐火物の吹付方法において、該−火気体の供
給圧力P1を10〜3.0KvcnIとし、且つ、−火
気体の供給圧力P、と二次気体の供給圧力P2とをp2
/p、=1.2〜30とすることを特徴とする溶融金属
収納容器における耐火物の吹付方法。In a refractory spraying method in which a water supply port is drilled at the base of a nozzle tip to add water to a mixed fluid of refractory powder and a primary gas, and then a secondary gas is pressurized into the mixed fluid, the supply of the fire gas. The pressure P1 is 10 to 3.0 KvcnI, and the supply pressure P of fire gas and the supply pressure P2 of secondary gas are p2
A method for spraying refractories in a molten metal storage container, characterized in that /p is 1.2 to 30.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP22141083A JPS60114689A (en) | 1983-11-26 | 1983-11-26 | Spraying method of refractory in molten metal receiving vessel |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP22141083A JPS60114689A (en) | 1983-11-26 | 1983-11-26 | Spraying method of refractory in molten metal receiving vessel |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS60114689A true JPS60114689A (en) | 1985-06-21 |
Family
ID=16766298
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP22141083A Pending JPS60114689A (en) | 1983-11-26 | 1983-11-26 | Spraying method of refractory in molten metal receiving vessel |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS60114689A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101047016B1 (en) * | 2008-08-13 | 2011-07-07 | 조선내화 주식회사 | Water nozzle of fireproof spray equipment |
-
1983
- 1983-11-26 JP JP22141083A patent/JPS60114689A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101047016B1 (en) * | 2008-08-13 | 2011-07-07 | 조선내화 주식회사 | Water nozzle of fireproof spray equipment |
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