JPS5980261A - Ball core body for hard baseball and production thereof - Google Patents

Ball core body for hard baseball and production thereof

Info

Publication number
JPS5980261A
JPS5980261A JP57190555A JP19055582A JPS5980261A JP S5980261 A JPS5980261 A JP S5980261A JP 57190555 A JP57190555 A JP 57190555A JP 19055582 A JP19055582 A JP 19055582A JP S5980261 A JPS5980261 A JP S5980261A
Authority
JP
Japan
Prior art keywords
ball
particles
ionomer resin
cork particles
rubber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP57190555A
Other languages
Japanese (ja)
Inventor
坂東 「けん」介
高見 美次
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NAIGAI GOMU KK
NAIGAI RUBBER IND
Original Assignee
NAIGAI GOMU KK
NAIGAI RUBBER IND
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NAIGAI GOMU KK, NAIGAI RUBBER IND filed Critical NAIGAI GOMU KK
Priority to JP57190555A priority Critical patent/JPS5980261A/en
Publication of JPS5980261A publication Critical patent/JPS5980261A/en
Pending legal-status Critical Current

Links

Landscapes

  • Adornments (AREA)
  • Powder Metallurgy (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 この発明は硬式野球ボール、芯体、詳しくはゴム又は合
成樹脂で被覆されたコルク粒子をアイオノマー樹脂に練
込んで得られた混和物の粉砕粒子を加熱、加圧成形して
なる硬式野球ボールん・体及びその製造方法に関するも
のである。
Detailed Description of the Invention This invention is a hardball baseball, a core body, specifically, a mixture obtained by kneading cork particles coated with rubber or synthetic resin into an ionomer resin, and pulverized particles thereof are heated and molded under pressure. The present invention relates to a hardball baseball ball and body made of the same material, and a method for manufacturing the same.

従来の硬式野球ボールに体の公知例としては、エボナイ
トスポンヂ球足(実公昭25’−8957)、高スチロ
ール系合成ゴムを配合するスポンヂゴム球芯、(実公昭
31−10428、特公昭3l−1217)、高スチロ
ール系合成ゴムにキルク粉を配合して作成した硬質スボ
ンヂゴム六・を中心とし、その外層に才宛形をなす2枚
の密質ゴムを間隔を設けて冠せ更にその外層に外被の密
質ゴムを被覆して成る硬式野球ボール芯体(実公昭43
−32119)等がある。
Known examples of the bodies of conventional hardball baseballs include ebonite sponge ball feet (1989-8957), sponge rubber cores containing high styrene synthetic rubber (10428-10428, 31-1217). ), the outer layer is made of hard sponge rubber made by blending Kirk powder with high styrene synthetic rubber, and the outer layer is crowned with two pieces of dense rubber with a spaced apart shape. Hardball baseball core made of dense rubber
-32119) etc.

これらの公知例の中、実公昭25−8957、実公昭3
1−10428、特公昭31−1217に記載された芯
体は硬式@球ボール尤、体として耐久性において必ずし
も満足できるものでなく、又実公昭43−32119は
耐久性はほぼ満足できるが、構造が複雑なため製造上余
分な手数を必要としなお改良の余地が残されていた。
Among these publicly known examples, Utility Model Act 25-8957, Utility Model Number 3,
1-10428, the core body described in Japanese Patent Publication No. 31-1217 is not necessarily satisfactory in terms of durability as a hard type ball, and the core body described in Japanese Publication No. 43-32119 is almost satisfactory in terms of durability, but the structure is The complexity of the process required extra steps in manufacturing, leaving room for improvement.

この発明は上記公知例の欠点を改良するためになされた
ものてあり、高弾性で面4衝撃性にすぐれた合成樹脂で
あるアイオノマー樹脂とコルク粒子とを相互の接’M性
が叩打で緊密かつ均一に混合成形することにより、耐衝
撃性及び飛距離等の性能においてすぐれ、製造も容易で
ある硬式野球ボール7℃・体及びその製造方法を提供す
るものである。
This invention was made in order to improve the drawbacks of the above-mentioned known examples, and the mutual contact between ionomer resin, which is a synthetic resin with high elasticity and excellent surface impact resistance, and cork particles is brought into close contact by hammering. Furthermore, by uniformly mixing and molding, the present invention provides a 7°C hardball baseball body that has excellent performance such as impact resistance and flight distance, and is easy to manufacture, and a method for manufacturing the same.

この発明はゴム又は合成樹脂でm覆されたコルク粒子を
アイオノマー樹脂に練込んで得られた混和物の粉砕粒子
を加熱、加圧成形してなる1便鴇野球ボール及びその製
造方法である。
The present invention is a one-time baseball ball made by heating and press-molding pulverized particles of a mixture obtained by kneading cork particles covered with rubber or synthetic resin into an ionomer resin, and a method for manufacturing the same.

この発明に用いるコルク粒子の大きさは4.8 mm(
4メツシユ)〜2.8mm(7メツシユ)のものが適当
である。コルク粒子が4.8mrn(4メツシユ)より
太きいとアイオノマー樹脂に錬込んで得られた混和物の
粉砕工程でコルク粒子の内部での破壊が多くなり、アイ
オノマー樹脂による未被覆部が増加するため、ち・体の
耐衝撃性が低下する。又粉砕工程で粉砕されずに残った
大きいコルク粒子は、ボールとして使用するときの打撃
による衝撃によりコルク粒子の内部から破壊が進みボー
ルの耐衝撃性が低下する。コルク粒子が2.8mm(7
メツシユ)より小さくなるとミルでの混練時アイオノマ
ー樹脂へのコルク粒子の分散がUfJ難となる。又コル
ク粒子の表面積が極度に大きくなりアイオノマー樹脂の
混合比率を上げないと尤・体の耐衝撃性が低下する。
The size of the cork particles used in this invention is 4.8 mm (
4 meshes) to 2.8 mm (7 meshes) is suitable. If the cork particles are thicker than 4.8 mrn (4 meshes), the internal parts of the cork particles will increase in the crushing process of the mixture obtained by kneading into the ionomer resin, and the area not covered by the ionomer resin will increase. , the impact resistance of the body decreases. Further, large cork particles that remain unpulverized during the crushing process are destroyed from the inside by the impact of impact when used as a ball, reducing the impact resistance of the ball. Cork particles are 2.8 mm (7
When the mesh size is smaller than the mesh size, it becomes difficult to disperse the cork particles into the ionomer resin during kneading in a mill. In addition, the surface area of the cork particles becomes extremely large, and unless the mixing ratio of the ionomer resin is increased, the impact resistance of the body will decrease.

この発明に用いるアイオノマー樹脂はボールの飛距瑠を
伸ばし打撃音をよくするため、高硬度、高反発グレード
のものが望ましい。(例えばコーポレンS−600:商
標名、肥ダウ株式会社製)アイオノマー樹脂とコルク粒
子との混合比率はボールの飛距離、打撃音等の面からア
イオノマー樹脂が多い方がよいが、ボール構成の重量的
制限から比重の軽いコルク粒子を己合せざるをえない0
性能と比重のバランスからアイオノマー樹脂とコルク粒
子との程合比率は重殿比で60/40〜40/60が望
ましい。
The ionomer resin used in this invention is preferably of a high hardness and high repulsion grade in order to extend the flight distance of the ball and improve the impact sound. (For example, Corporen S-600: trade name, manufactured by Hi-Dow Co., Ltd.) Regarding the mixing ratio of ionomer resin and cork particles, it is better to have more ionomer resin in terms of flight distance, impact sound, etc., but the weight of the ball structure Due to physical limitations, it is necessary to combine cork particles with a light specific gravity.
In view of the balance between performance and specific gravity, the ratio of the ionomer resin to the cork particles is preferably 60/40 to 40/60 in terms of weight ratio.

コルク°粒子を表面未処理でアイオノマー樹脂に練込ん
だ場合と、ゴムラテックス又は合成樹脂エマルジョンで
表面被覆処理後練込んだ場合とを比較すると、九゛体に
したときの耐衝撃性において顕暑な差がみられ、表面被
覆処理のものがすぐれている。表向未処理の場合は混合
する相手であるアイオノマー砧脂が高粘性のため、コル
ク粒子の表面をぬらすことが固気[となり、コルク粒子
とアイオノマー樹脂との接着性が不充分となるためボー
ル、数体として使用時の耐衝撃性が劣る結果となると1
イf定される。
Comparing cork particles kneaded into ionomer resin without surface treatment and kneaded after surface coating with rubber latex or synthetic resin emulsion, it is found that the impact resistance when made into nine bodies is significantly lower than that of ionomer resin. There are significant differences, and those with surface coating are superior. If the surface is not treated, the ionomer resin that is mixed with it has a high viscosity, so wetting the surface of the cork particles becomes a solid gas, and the adhesion between the cork particles and the ionomer resin is insufficient, resulting in a ball. , if several units result in poor impact resistance during use, 1
If determined.

アイオノマー樹脂とコルク粒子とを単にまぜ合して金型
に仕込みjJU !+、加圧して亡体に成形した場合と
、ミルで混練して得られた’tfl= fil物を粉砕
して成形用粒子をつくり、このものを金型に仕込み加熱
、加圧後冷却して光体とした場合とを比較すると、後者
の場合が耐衝撃性、)1す距〃L等の性能?こおいて格
段に(り位となる。このことはアイオノマー樹脂とコル
ク粒子との相互の分散がきわめて均一となり、ボール芯
体としての性能の向上に役立ったと推定される。
Simply mix the ionomer resin and cork particles and place it in a mold.jJU! +, when pressurized and molded into a corpse, and 'tfl = obtained by kneading in a mill = The fil material is crushed to make particles for molding, this is placed in a mold, heated, pressurized, and then cooled. Comparing the case where it is used as a light body, the latter case has performance such as impact resistance, distance (L), etc. It is assumed that this is because the mutual dispersion of the ionomer resin and cork particles becomes extremely uniform, which helps improve the performance of the ball core.

次にこの発明の一実施例について説明する。Next, one embodiment of the present invention will be described.

5メツシユの大きさのコルク粒子43gと酢酸ビニール
系樹脂エマルジョン(固形分45%)を16gきり、両
者を均一に混合して、室温で24時間乾燥し、約50g
の表面被覆処理をしたコルク粒子を得た。このものを試
験用ミルでアイオノマー樹脂コーボレンS〜600(商
標名、尼ダウ株式会社製)50gに練込み、均一に混合
して混和物約100gを得た。この混和物をクラッシャ
ーで粉砕し、芯・体成形用粒子を作製した。ついでこの
、?、体成形用粒子を25gとり、内径46mmの球形
ギャビテイを何する金型に仕込み、加熱プレスで加熱温
度150 、加圧圧力11kg/C!て20分C 間加熱、加圧した後、約10分間はぼ常温になるまで冷
却して取出し、図に示すこの発明の硬式野球ボール尼一
体1を得た。尾・体の重量は25g1外径は46mmで
あった。この絶佳1に毛糸及びビニロン単糸をまいて補
強系層2を形成し、更に配合ゴムをはりつけて外皮ゴム
層3とし、未加硫のボールを成形した。このものを常法
通り加硫金型につめ、加圧、加熱して加硫を行い、硬式
野球ボール八を作製した。ボールの重量は146g 、
外径は72.5mmであった。
43g of cork particles with the size of 5 mesh and 16g of vinyl acetate resin emulsion (solid content 45%) are mixed uniformly, and dried at room temperature for 24 hours to produce about 50g.
Cork particles with surface coating treatment were obtained. This product was kneaded into 50 g of an ionomer resin Kobolene S~600 (trade name, manufactured by Amida Dow Co., Ltd.) using a test mill and mixed uniformly to obtain about 100 g of a mixture. This mixture was crushed with a crusher to produce core/body molding particles. By the way, this? Take 25g of particles for body shaping, put them into a mold with a spherical gap of 46mm in inner diameter, and heat with a hot press at a heating temperature of 150°C and a pressure of 11kg/C! After heating and pressurizing the ball for 20 minutes at C, the ball was cooled to about room temperature for about 10 minutes and then taken out to obtain a hardball baseball ball 1 of the present invention as shown in the figure. The weight of the tail and body was 25 g, and the outer diameter was 46 mm. A reinforcing layer 2 was formed by sprinkling yarn and vinylon single yarn on this material 1, and compounded rubber was further applied to form a skin rubber layer 3, and an unvulcanized ball was formed. This material was packed into a vulcanization mold in the usual manner, and vulcanized under pressure and heat to produce eight hardball baseballs. The weight of the ball is 146g.
The outer diameter was 72.5 mm.

前1紀実施例で作製したボールと公認硬式野球ボール、
邸硬式野球ボール及びコルク粒子とアイオノマー樹脂と
を練込混和を行はず単に混合したのみの九体を使用して
作製したボールについて 1・車体ならびにボールとし
ての性能を対比すると次表の通りとなる。
The ball made in the BC1st example and the official hardball baseball ball,
Regarding hardball baseballs and balls made using nine bodies in which cork particles and ionomer resin were simply mixed without kneading, 1. A comparison of the performance as a car body and ball is as shown in the following table. .

表中、リバウンド高さは2体又はボールを高さ150c
mより大理石板上に落したときのリバウンド高さをcm
で示した。耐落下衝撃性は1底面径70mm、重岸、1
1kgの鉄製円柱形重錘を高さ1mより毎分6回の速度
で落下させて、試料に落下衝撃を加え、破壊を生じたと
きの回数で示した。音質はん体の場合にはリバウンド高
さ測定時に;こ・体を大理石板上に落したときの音質を
聞き判定した。ボルルの場合には実際に打撃を行い、ボ
ールがバットにジャストミートしたときの音質を聞き判
定した。裏打リバウンドは実際に打撃を行ったときボー
ルが落下し、地面に接しつつ走るときのリバウンドの状
況を視覚で判定した。飛距踵は実際に打撃を行いジャス
トミートしたときの飛距離で判定した。耐久性は実際に
使用した場合の使用によるボールの軟化、変形、飛距離
の低下、音質の変化、リバウンドの変化等を観察して判
定した。
In the table, the rebound height is 150c for two bodies or a ball.
The rebound height when dropped onto a marble board from m is cm.
It was shown in Drop impact resistance: 1 bottom diameter 70mm, heavy bank, 1
A 1 kg iron cylindrical weight was dropped from a height of 1 m at a rate of 6 times per minute to apply a falling impact to the sample, and the number of times at which breakage occurred was expressed as the number of times. Sound Quality When measuring the rebound height of a solid body, the sound quality was determined by listening to the sound quality when the body was dropped onto a marble board. In the case of Borl, the players actually hit the ball and listened to the sound quality when the ball just hit the bat. For back-up rebounding, the ball falls when the player actually hits the ball, and visually determines the rebound situation as it runs while touching the ground. Flying distance was determined by the flying distance when the ball was actually hit and just met. Durability was determined by observing the ball's softening, deformation, decrease in flight distance, change in sound quality, change in rebound, etc. due to actual use.

表中の評価記号◎は優秀、○は良好、△は劣ることを示
す。
The evaluation symbol ◎ in the table indicates excellent, ○ indicates good, and △ indicates poor.

コノ表によると、ボール、℃1体の性能においては本発
明の実施例ボールの二体が耐落下衝撃性において特にす
ぐれ、又リバウンド市さ、音質でも他の芯体に比し劣る
ところはない。同一の月料を使用しているが、本発明の
氾・体と製造方法の相応する、コルク粒子とアイオノマ
ー樹脂とを練込混和を行はす、第、に捏合したのみの7
;体は耐落下衝撃性において大きく劣り、リバウンド高
さ、音質共本発明の九・体に及ばない。製型方法の差が
顕聰にあられれているこいえる。
According to the table, in terms of the performance of one ball, the two example balls of the present invention are particularly excellent in drop impact resistance, and are not inferior to other cores in terms of rebound accuracy and sound quality. . Although the same monthly charge was used, the cork particles and ionomer resin were kneaded and mixed according to the method of production of the present invention.
;The body is significantly inferior in drop impact resistance, and neither rebound height nor sound quality is as good as the ninth body of the present invention. The differences in mold-making methods are clearly visible.

ボールの性能においては、本発明のも体使用ボールは公
認硬式!1iIJ球ボールと同等の1y秀な成績を示し
ている。一方、コルク粒子とアイオノマー樹脂とを練込
混和を行はず、華に混合したのみのに・体を使用したボ
ールは性能において、音質、飛距涛(L1耐久性、耐落
下衝撃性が明らかに劣り、千1体の場合と同様な傾向を
示している。
In terms of ball performance, the ball of the present invention is officially recognized as a hard ball! It shows excellent performance of 1y, which is equivalent to 1iIJ ball. On the other hand, the performance of balls using cork particles and ionomer resin, which were not kneaded and mixed but only mixed into flowers, showed poor sound quality, flying distance (L1 durability, and drop impact resistance). Inferior, showing the same tendency as in the case of 1,000 bodies.

準硬式野球ボールはに体の耐落下衝撃性が劣り、ボール
の性能においては耐久性、耐落下衝撃性が劣り、裏打リ
バウンドにおいてイレギュラーバウンドが見られた。
The body of the semi-hard baseball ball had poor drop impact resistance, and in terms of ball performance, it had poor durability and drop impact resistance, and irregular bounces were observed in the back rebound.

以上詳述したようにこの発明の硬式野球ボール范・体は
公認硬式IE球ボール足・体及び準硬式野球ボール/c
゛体に比しすぐれた耐衝撃性を裔し、このものを使用し
た硬式野球ホールは打撃時の音質、飛距離、耐久性、耐
衝撃性等の性能において公認硬式ボールに匹敵する性能
を発揮し、本実施例のように外皮をゴム層で形成すれば
外皮が耐水性となり、硬式野球の練習用ボールとして最
適のボールを提供することができる。
As described in detail above, the hardball baseball ball of the present invention has legs and bodies, certified hardball IE ball legs and bodies, and semi-hardball baseballs/c.
゛It has superior impact resistance compared to the ball, and hardball balls made using this ball demonstrate performance comparable to certified hardballs in terms of sound quality when hitting, flight distance, durability, impact resistance, etc. However, if the outer cover is formed of a rubber layer as in this embodiment, the outer cover becomes water resistant, making it possible to provide a ball that is optimal as a practice ball for hardball baseball.

次に、この発明の製造方法によればゴムラテックス又は
合成樹脂エマルジョンでコルク粒子の表面を被覆するこ
とにより、コルク粒子とアイオノマー樹脂との接着を良
好にし、更にコルク粒子をアイオノマー樹脂に練込んで
均一に混合し、得られた混和物を粉砕して成形用粒子を
つくり、この成形用粒子を金型に仕込み、加熱、加圧後
冷却して取出すととにより、相互に強固な接着をし、均
等に分散したコルク粒子とアイオノマー樹脂との混合成
形物であるボール、す体を製造することができる利点を
もつものである。
Next, according to the production method of the present invention, the surface of the cork particles is coated with rubber latex or a synthetic resin emulsion to improve the adhesion between the cork particles and the ionomer resin, and the cork particles are further kneaded into the ionomer resin. The particles are mixed uniformly, the resulting mixture is pulverized to create particles for molding, the particles are placed in a mold, heated and pressurized, and then cooled and taken out to form a strong bond to each other. This method has the advantage of being able to produce balls and bodies made of a mixture of uniformly dispersed cork particles and ionomer resin.

4、図面LD N ’:i’−すに’4 LMJ図はこ
の発明のに休を使用した一実施例である+1(Ij氏野
球ボールへの断面図である。
4.Drawing LD N':i'-Suni'4 The LMJ diagram is a cross-sectional view of +1 (Mr. Ij's baseball), which is an embodiment of the present invention using a blank.

1はだ体、2は補強系層、3は外皮ゴム層である。1 is a skin body, 2 is a reinforcing layer, and 3 is an outer skin rubber layer.

特許出願人 内外ゴム株式会社 代理人杉原@雄Patent applicant: Naigai Rubber Co., Ltd. Agent @Yu Sugihara

Claims (2)

【特許請求の範囲】[Claims] (1)ゴム又は合成樹脂で被覆されたコルク粒子をアイ
オノマー樹脂に練込んで得られた混和物の粉砕粒子を加
熱、加圧成形してなる硬式野球ボール沌・体。
(1) A hard baseball ball made by heating and press-molding crushed particles of a mixture obtained by kneading cork particles coated with rubber or synthetic resin into an ionomer resin.
(2)ゴムラテックス又は合成樹脂エマルジョンで被覆
されたコルク粒子を乾燥後アイオノマー樹脂に練込み、
得られた混和物を粉砕して成形用粒子をつくり、この成
形用粒子を金型に仕込み、加熱、加圧後冷却して取出す
ことを特徴とする硬式野球ボール氾・体の製造方法
(2) Cork particles coated with rubber latex or synthetic resin emulsion are kneaded into ionomer resin after drying,
A method for manufacturing a hard baseball ball body, which comprises: pulverizing the obtained mixture to create molding particles; charging the molding particles into a mold; heating and pressurizing; cooling; and taking out.
JP57190555A 1982-10-28 1982-10-28 Ball core body for hard baseball and production thereof Pending JPS5980261A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP57190555A JPS5980261A (en) 1982-10-28 1982-10-28 Ball core body for hard baseball and production thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP57190555A JPS5980261A (en) 1982-10-28 1982-10-28 Ball core body for hard baseball and production thereof

Publications (1)

Publication Number Publication Date
JPS5980261A true JPS5980261A (en) 1984-05-09

Family

ID=16260018

Family Applications (1)

Application Number Title Priority Date Filing Date
JP57190555A Pending JPS5980261A (en) 1982-10-28 1982-10-28 Ball core body for hard baseball and production thereof

Country Status (1)

Country Link
JP (1) JPS5980261A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60194968A (en) * 1984-03-16 1985-10-03 内山工業株式会社 Ball core body and its production
JP2008162631A (en) * 2006-12-27 2008-07-17 Yoshino Kogyosho Co Ltd Container having dispenser
JP2008162632A (en) * 2006-12-27 2008-07-17 Yoshino Kogyosho Co Ltd Container having dispenser
JP2008184197A (en) * 2007-01-31 2008-08-14 Yoshino Kogyosho Co Ltd Liquid-jetting instrument
JP2017104723A (en) * 2017-03-23 2017-06-15 ナガセケンコー株式会社 Baseball Ball

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60194968A (en) * 1984-03-16 1985-10-03 内山工業株式会社 Ball core body and its production
JPH0381393B2 (en) * 1984-03-16 1991-12-27 Uchama Kogyo Kk
JP2008162631A (en) * 2006-12-27 2008-07-17 Yoshino Kogyosho Co Ltd Container having dispenser
JP2008162632A (en) * 2006-12-27 2008-07-17 Yoshino Kogyosho Co Ltd Container having dispenser
JP2008184197A (en) * 2007-01-31 2008-08-14 Yoshino Kogyosho Co Ltd Liquid-jetting instrument
JP2017104723A (en) * 2017-03-23 2017-06-15 ナガセケンコー株式会社 Baseball Ball

Similar Documents

Publication Publication Date Title
US5779562A (en) Multi-core, multi-cover golf ball
US5984806A (en) Perimeter weighted golf ball with visible weighting
AU734172B2 (en) Titanium filled thick mantle, soft covered multi layered golf ball
US6315681B1 (en) Perimeter weighted golf ball with visible weighting
US6379269B1 (en) Multi-core, multi-cover golf ball
KR20190055012A (en) Graphene core of golf ball
JPH08322963A (en) Thread wound golf ball
JPS626459B2 (en)
JPH0857084A (en) Golf ball
EP0638338B1 (en) Thread wound golf ball
JPS5980261A (en) Ball core body for hard baseball and production thereof
CA2358601C (en) Golf ball having improved heat resistance
US7148262B2 (en) Method for drying and using swarf in golf balls
US7285058B2 (en) Pre-vulcanized or pre-crosslinked materials for golf balls
US7141196B2 (en) Method of manufacturing a golf ball having one or more layers
AU6784398A (en) Perimeter weighted golf ball with visible weighting
JPH01212577A (en) Golf ball having foamed cover
KR101850316B1 (en) Nano Bismuth Golf Ball Improved Driving Distance And Durability
JPS6053164A (en) Solid golf ball
TWI685413B (en) Multilayered golf ball having whiskers and manufacturing method thereof
KR102055203B1 (en) Method for preparing masterbatch comprising carbon nanotube and ionomer and method for preparing golf ball containing carbon nanotube
TWI630096B (en) Method and apparatus for molding dual cores for a golf ball
GB2085885A (en) Foamed polymer sports balls
JPS6179476A (en) Production of ball for baseball and softball
JPS6230026B2 (en)