JPS5951406A - Method of producing conductive or semiconductive polymer composition - Google Patents
Method of producing conductive or semiconductive polymer compositionInfo
- Publication number
- JPS5951406A JPS5951406A JP16173282A JP16173282A JPS5951406A JP S5951406 A JPS5951406 A JP S5951406A JP 16173282 A JP16173282 A JP 16173282A JP 16173282 A JP16173282 A JP 16173282A JP S5951406 A JPS5951406 A JP S5951406A
- Authority
- JP
- Japan
- Prior art keywords
- ring
- conductive
- polymer composition
- producing
- derivatives
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
産業上の利用分野
本発明は、電子デバイスの分野に利用される導電性ない
し半導電性重合体組成物の製造法に関する。DETAILED DESCRIPTION OF THE INVENTION FIELD OF INDUSTRIAL APPLICATION The present invention relates to a method for producing conductive or semiconductive polymer compositions used in the field of electronic devices.
従来例の構成とその問題点
３ベー−ミ゛
従来、たとえば、Ｋ、Ｋｅｉｊｉ Ｋａｎａｚａｗａ
ｅｔａｌ、、Ｊ、Ｃｈｅｍ、Ｓｏｃ、Ｃｈａｍ、Ｃｏｍ
ｍ、、ｓ ｓ ４ （１９７９）などに、支持電解質の
存在下でビロールを電解酸化して白金陽極板上に導電性
重合体組成物を製造する方法が記載されている。これら
の重合体組成物は、一般にきわめて微小な電流密度のも
とで製造され、十分な機械的強度をもたないものが多い
。Conventional configurations and their problems 3 Bases, for example, K, Keiji Kanazawa
etal,,J,Chem,Soc,Cham,Com
A method for producing a conductive polymer composition on a platinum anode plate by electrolytic oxidation of virol in the presence of a supporting electrolyte is described in, e.g. These polymer compositions are generally produced under extremely low current densities, and many do not have sufficient mechanical strength.
発明の目的
本発明は、実用に耐えるに十分な機械的強度をもち、と
くにフィルム状の形態をした導電性ないし半導電性重合
体組成物を与える製造方法を提供することを目的とする
。OBJECTS OF THE INVENTION The object of the present invention is to provide a method for producing a conductive or semiconductive polymer composition having sufficient mechanical strength to withstand practical use, particularly in the form of a film.
発明の構成
本発明は、後述の電解酸化を受ける化合物（以下、電解
酸化化合物と称する）を不純物との共存下、陽極近傍の
電流密度が１ｏ−４〜１ｏｋ／ｃ４の条件で電解酸化す
ることを特徴とする導電性力いし半導電性重合体組成物
の製造方法である。このうちでもとくに、１０−３〜Ｉ
Ａ／ｃｔＭの範囲が最も効果が太きい。このように、
本発明は従来よりもはるかに大きな電流密度を用いるこ
とに特徴づけられる。Structure of the Invention The present invention involves electrolytically oxidizing a compound that undergoes electrolytic oxidation (hereinafter referred to as an electrolytically oxidized compound), which will be described later, in the presence of impurities at a current density of 1o-4 to 1ok/c4 near the anode. A method for producing a conductive or semiconductive polymer composition characterized by the following. Among these, especially 10-3~I
The effect is greatest in the A/ctM range. in this way,
The present invention is characterized by the use of a much larger current density than conventional ones.
このような条件でつくった重合体組成物は、緻密で強じ
んがフィルム状の形態をもつ。コレハ、大電流で短時間
につくると、目的とする重合反応のみが優先的に起こる
ためと解される。これに対して、微少な電流密度で長時
間をかけて重合体組成物をつくると、目的とする重合反
応以外の副反応が支配的となるために、本発明のような
効果が生まれないと考えられる。The polymer composition produced under these conditions has a dense and tough film-like morphology. It is understood that this is because only the desired polymerization reaction occurs preferentially when it is produced in a short time using a large current. On the other hand, if a polymer composition is prepared over a long period of time at a minute current density, side reactions other than the desired polymerization reaction will become dominant, and the effects of the present invention may not be produced. Conceivable.
本発明で用いる電解酸化化合物は、次のａ、ｂ及びＣよ
りなる群から選択される。The electrolytically oxidized compound used in the present invention is selected from the group consisting of a, b and C below.
ａ） ベンゼンとその誘導体、
ｂ）酸素族元素または窒素族元素を複素環に１つ含む複
素五員環化合物、
Ｃ）ベンゼン環、酸素族元素または窒素族元素を環上に
１つ含む複素五員環がら選ばれた複数個の環が直接また
はエーテル、スルフィド、セレニド、テルリド結合のど
れかを介して結合した化合物。a) Benzene and its derivatives; b) five-membered heterocyclic compounds containing one oxygen group element or nitrogen group element on the hetero ring; C) five-membered heterocyclic compounds containing one benzene ring, oxygen group element or nitrogen group element on the ring. A compound in which multiple rings selected from member rings are bonded directly or through ether, sulfide, selenide, or telluride bonds.
６ページ
これらのうちで、複素五員環がフラン環、チオフェ／環
、セレノ７エン環、テルロフェ／環−ｔｆｉｃはピロー
ル環から選ばれた場合はとくに効果が大きく、強じんで
フィルム状の重合体組成物が得られる。Page 6 Among these, tfic is especially effective when the five-membered hetero ring is selected from the furan ring, thiophe/ring, seleno-7ene ring, and pyrrole ring, and forms a strong and film-like heavy ring. A combined composition is obtained.
さらに、不純物がホウハロゲン化イオン、パーハロケネ
ートイオン、硫酸イオン、ベンゼンスルフォン酸イオン
をもつ塩または電子受容体から選ばれた場合はよシすぐ
れた結果を与える。電子受容体には以下のようなものが
ある。Furthermore, better results are obtained when the impurity is selected from salts or electron acceptors with borohalide ions, perhalokenate ions, sulfate ions, benzenesulfonate ions. Electron acceptors include the following:
芳香族ニトロ化合物（２，４，７−ドリニトロンルオレ
ノンなど）、芳香族ニトリル化合物（フタロジニトリル
、１．３，６．８−テトラシアノピレンなど）、テトラ
シアノエチレン、テトラシアノキノジメタン誘導体、テ
トラシアノナフトキノジメタン誘導体、ベンゾキノン誘
導体（ｐ−ベンゾキノン、ｐ−クロラニル、ｐ−フルオ
ラ＝ ／ｌ／。Aromatic nitro compounds (2,4,7-dolinitronefluorenone, etc.), aromatic nitrile compounds (phthalodinitrile, 1,3,6,8-tetracyanopyrene, etc.), tetracyanoethylene, tetracyanoquinodimethane derivatives, tetracyanonaphthoquinodimethane derivatives, benzoquinone derivatives (p-benzoquinone, p-chloranil, p-fluora = /l/.
ジシアノジクロロキノンなト）。dicyanodichloroquinone).
実施例の説明
以下に実施例を挙げて本発明をさらに詳しく説６ ｔ
ｉ ”
明する。DESCRIPTION OF EMBODIMENTS The present invention will be explained in more detail with reference to Examples below.
i ” Clarify.
種々の電解酸化化合物０．１モルと不純物。、０１モル
とを溶媒２００ ｍｅに溶解、分散または乳化させて室
温下、電解酸化でＩＴＯガラス電極の陽極上にフィルム
状の導電性または半導電性重合体組成物を得た。次表に
電解酸化化合物、不純物、溶媒、製造時の電流密度と得
たフィルムの導電率を表す。0.1 mol of various electrolytically oxidized compounds and impurities. . The following table shows the electrolytic oxidation compound, impurities, solvent, current density during production, and conductivity of the obtained film.
（以 下金 白）
７ベー、ｚｊ
９ページ
なお、ピロール０．１モルとホウフッ化テトラ−ｎ−ブ
チルアンモニウム０．０１１モルトラニトロベンゼン
００ ｄに溶解させて、電流密度１Ｏ−５Ａ／ｃＪで電
解酸化した場合は、粗大な塊状組成物しか得られなかっ
た。(Hereinafter referred to as gold and white) 7 be, zz page 9 In addition, 0.1 mol of pyrrole and 0.011 mol of tetra-n-butylammonium borofluoride in tranitrobenzene
00 d and electrolytically oxidized at a current density of 10-5 A/cJ, only a coarse bulk composition was obtained.
このように本発明の製造方法はすぐれた効果を生むこと
がわかる。Thus, it can be seen that the manufacturing method of the present invention produces excellent effects.
発明の効果
以上のように、本発明の製造方法は、緻密で強じんなフ
ィルム状の導電性あるいは半導電性重合体組成物を与え
る。Effects of the Invention As described above, the production method of the present invention provides a conductive or semiconductive polymer composition in the form of a dense and strong film.
代理人の氏名 弁理士 中 尾 敏 男 ほか１名２７Name of agent: Patent attorney Toshio Nakao and 1 other person 27
Claims (1)
物を不純物との共存下、陽極近傍の電流密度が１０−４
〜１０Ａ／ｃ、Ｎの条件で電解酸化することを特徴とす
る導電性ないし半導電性重合体組成物の製造法。 ａ）ベンゼンまたはその誘導体 ｂ）酸素族元素または窒素族元素を複素環に１つ含む複
素五員環化合物 Ｃ）ベンゼン環、酸素族元素または窒素族元素を複素環
に１つ含む複素五員環から選ばれた複数個の環が直接ま
たはエーテル、スルフィド、セレニド、テルリド結合の
どれかを介して結合した化合物 舜） 複素五員環が、フラン環、チオフェン環、セレノ
フェン環、テルロフェン環及びピロール環よりなる群か
ら選ばれた特許請求の範囲第１項２１ ゛ 記載の導電性ないし半導電性重合体組成物の製造法。 （３）不純物が、ホウハロゲン化イオン、パーハロゲネ
ートイオン、硫酸イオンまたはベンゼンスルフォン酸イ
オンをもつ塩、または電子受容体である特許請求の範囲
第１項または第２項記載の導電性ないし半導電性重合体
組成物の製造法。 （４）電子受容体が、芳香族ニトロ化合物、芳香族ニト
リル化合物、テトラシアノエチレン、テトラシアノキノ
ジメタン誘導体、テトラシアノナフトキノジメタン誘導
体及びベンゾキノン誘導体よりなる群から選ばれた特許
請求の範囲第３項記載の導電性ないし半導電性重合体組
成物の製造法。[Claims] (1) When a compound selected from the group consisting of a, b and C below is used in the coexistence of an impurity, the current density near the anode is 10-4.
A method for producing a conductive or semiconductive polymer composition, characterized by electrolytically oxidizing it under conditions of ~10 A/c and N. a) Benzene or its derivatives b) Five-membered heterocyclic compound containing one oxygen group element or nitrogen group element in the heterocycle C) Five-membered heterocyclic ring containing one benzene ring, oxygen group element or nitrogen group element in the heterocycle A compound in which multiple rings selected from the following are bonded directly or through an ether, sulfide, selenide, or telluride bond.The five-membered heterocyclic ring is a furan ring, thiophene ring, selenophene ring, tellurophene ring, or pyrrole ring. A method for producing a conductive or semiconductive polymer composition according to claim 1, which is selected from the group consisting of: (3) The conductive or semi-conductive material according to claim 1 or 2, wherein the impurity is a salt containing a borohalide ion, a perhalogenate ion, a sulfate ion or a benzenesulfonic acid ion, or an electron acceptor. A method for producing a conductive polymer composition. (4) Claims in which the electron acceptor is selected from the group consisting of aromatic nitro compounds, aromatic nitrile compounds, tetracyanoethylene, tetracyanoquinodimethane derivatives, tetracyanonaphthoquinodimethane derivatives, and benzoquinone derivatives 4. A method for producing a conductive or semiconductive polymer composition according to item 3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16173282A JPS5951406A (en) | 1982-09-16 | 1982-09-16 | Method of producing conductive or semiconductive polymer composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16173282A JPS5951406A (en) | 1982-09-16 | 1982-09-16 | Method of producing conductive or semiconductive polymer composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5951406A true JPS5951406A (en) | 1984-03-24 |
Family
ID=15740826
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16173282A Pending JPS5951406A (en) | 1982-09-16 | 1982-09-16 | Method of producing conductive or semiconductive polymer composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5951406A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6174462B1 (en) | 1998-01-20 | 2001-01-16 | Denso Corporation | Conductive paste composition including conductive metallic powder |
-
1982
- 1982-09-16 JP JP16173282A patent/JPS5951406A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6174462B1 (en) | 1998-01-20 | 2001-01-16 | Denso Corporation | Conductive paste composition including conductive metallic powder |
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