JPS5938600A - Fatigue inhibitor for heat transmitting tube - Google Patents

Fatigue inhibitor for heat transmitting tube

Info

Publication number
JPS5938600A
JPS5938600A JP14775382A JP14775382A JPS5938600A JP S5938600 A JPS5938600 A JP S5938600A JP 14775382 A JP14775382 A JP 14775382A JP 14775382 A JP14775382 A JP 14775382A JP S5938600 A JPS5938600 A JP S5938600A
Authority
JP
Japan
Prior art keywords
flame
heat transmitting
sprayed
powder
nickel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP14775382A
Other languages
Japanese (ja)
Inventor
Hide Amamiya
雨宮 秀
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Toshiba Corp
Tokyo Shibaura Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Corp, Tokyo Shibaura Electric Co Ltd filed Critical Toshiba Corp
Priority to JP14775382A priority Critical patent/JPS5938600A/en
Publication of JPS5938600A publication Critical patent/JPS5938600A/en
Pending legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F19/00Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers
    • F28F19/02Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers by using coatings, e.g. vitreous or enamel coatings
    • F28F19/06Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers by using coatings, e.g. vitreous or enamel coatings of metal
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06Metallic material
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F9/00Casings; Header boxes; Auxiliary supports for elements; Auxiliary members within casings
    • F28F9/007Auxiliary supports for elements
    • F28F9/013Auxiliary supports for elements for tubes or tube-assemblies
    • F28F9/0131Auxiliary supports for elements for tubes or tube-assemblies formed by plates

Abstract

PURPOSE:To prevent heat transmitting tubes from being damaged, by flame- spraying metallic powder to the surfaces of heat transmitting tubes which are supported by baffle plates. CONSTITUTION:A heat transmitting tube 10 is preliminarily treated so as to be ready to be flame-sprayed, by hardening the surface of the tube 10 by means of shot blasting or sandblasting, and by defatting using trichlene. Then, the mixed powder, consisting of less than 94wt% of titanium dioxide, oxide powder of 4- 8wt% of aluminum, and 2-6wt% of vanadium, and nickel and chrome alloy powder consisting of 12-18wt% of chrome, 5-9wt% of iron, and nickel for the remainder wt%, is flame-sprayed to the surface of a heat transmitting tube. In this case, less than 1mm. is enough for the thickness of a layer to be flame- sprayed, but for fear that a little number of pin holes will be formed in the flame-sprayed layer, it is necessary to fuse the part by heating it with flames immediately after flame-spraying.

Description

【発明の詳細な説明】 〔発明の技術分野〕 本発明は、例えは熱交換器に使用される伝熱管の疲労抑
制剤に関する。
DETAILED DESCRIPTION OF THE INVENTION [Technical Field of the Invention] The present invention relates to a fatigue suppressant for heat exchanger tubes used, for example, in heat exchangers.

〔発明の技術的背景〕[Technical background of the invention]

従来、タービンプラントは、熱効率の向上のため、熱交
換器、例えば復水器が使用されているが、何分にもター
ビンから排出される蒸気量が多いため、儂水器内には約
2万不以上の伝熱管を必要としている。また、伝熱′d
円を通る冷却材は海水を使用することが多く、このため
腐食防止上の見迅から最近はチタン製の伝熱管が好まれ
て多く採用さIするよう(ニなってきた。
Conventionally, turbine plants have used heat exchangers, such as condensers, to improve thermal efficiency, but because the amount of steam discharged from the turbine every minute is large, about 2 More than one heat transfer tube is required. Also, heat transfer′d
Seawater is often used as the coolant that passes through the tubes, and for this reason, titanium heat transfer tubes have recently become preferred and increasingly used in order to prevent corrosion.

しかしながら、復水器は、多誓の文換熱量を必要とする
から、タービンから送られてくる蒸気流れ(二よる振動
問題、振動に伴う繰返し荷重から起因する材料疲労問題
が生起されている。
However, since condensers require a large amount of heat exchange, problems arise due to vibration due to the steam flow sent from the turbine, and material fatigue problems due to repeated loads due to vibrations.

ところで、第1図は一般的なタービンプラントの系統を
示し、ボイラ(7)で発生せしめられた蒸気は、高圧タ
ービン(1)に送られ、ここで仕事を終えた蒸気は、再
熱器(8)に送られて再び加熱され、再熱蒸気は中圧タ
ービン(2)を経て低圧タービン(3)に導入され、発
熱機(4)を回動じて電気出力を出す。
By the way, Figure 1 shows the system of a typical turbine plant. Steam generated in the boiler (7) is sent to the high-pressure turbine (1), and the steam that has finished its work here is sent to the reheater ( 8) where it is heated again, and the reheated steam is introduced into a low-pressure turbine (3) via an intermediate-pressure turbine (2), which rotates a heat generator (4) to produce electrical output.

低圧タービン(3)で膨張仕事をした蒸気は、その熱を
回収するため復水器(5)で凝結せしめられ、汲水とな
ってポンプ(6)を経てボイラ(7)に戻される。
The steam that has undergone expansion work in the low-pressure turbine (3) is condensed in a condenser (5) to recover its heat, and is returned to the boiler (7) via a pump (6) as pumped water.

このよう(ニタービン排気な汲水(二1−る復水器は、
一般に第2図(二示すような構造が採用されている。
In this way, the water pumped from the turbine exhaust (21-ru condenser) is
Generally, a structure as shown in FIG. 2 is adopted.

すなわち、符号(9)は復水器を示し、この復水器(9
)の両側(二は氷室a4.α線が管板0段、α山を通し
て連設され、管板(rb、+、(l[)間に伝熱管uO
)が1、復水器(9)の長手方向シニわたって配設され
ている。また、復水器(9)(二は、タービン排気E(
二よる伝熱管(10)の振動防止からバッフル0υが要
所要所に立設されておシ、バッフル(II)1″−は、
第3図に示すよう(−1比較的余裕をもった孔(7)を
通して伝熱管部が軸装されている。
That is, code (9) indicates a condenser, and this condenser (9)
) on both sides (second is the ice chamber a4.α rays are connected through the tube plate 0 stage and α mountain, and the heat transfer tube uO is connected between the tube plate (rb, +, (l[)).
) are disposed across the length of the condenser (9). In addition, the condenser (9) (second is the turbine exhaust E (
In order to prevent vibration of the heat transfer tube (10), baffles 0υ are installed at strategic points, and baffles (II) 1″-
As shown in FIG. 3, the heat exchanger tube section is mounted through the hole (7) which has a relatively large margin.

さらに、伝熱管t10)は、第4図(二示すように、復
水器(9)の短手方向(一対し、釣9鐘状(二配設され
ていて、その中央に熱父換後生成されるガスを集める通
路(5a)、 (5b)が設けられている。
Furthermore, as shown in FIG. Passages (5a) and (5b) are provided to collect the generated gas.

しかして、復水器t9+に送られるタービン排気Eは、
第2凶に示すように、氷室a4を通して送られる海水と
閣某侯され、熱の授受後、海水は水呈q鴎を経て外部に
、タービン排気Eは凝結後、ホットウェル(【4Jに集
められ、ここからボイラ(二送給されている。
Therefore, the turbine exhaust E sent to the condenser t9+ is
As shown in the second figure, the seawater sent through the ice chamber A4 and a certain prince are exchanged with each other, and after receiving and receiving heat, the seawater passes through the water tank and goes outside, and the turbine exhaust E is condensed and collected in the hot well ([4J]. The water is fed from here to the boiler (2).

〔背景技術の問題点〕[Problems with background technology]

ところで、多くの伝熱管u蝮を支えるバッフルIは、そ
の孔径に余裕をもたせて穿設させているため、タービン
排気Eによる衝S(−よって孔縁端に伝熱管曲が繰返し
集中荷重を受け、また、孔Uηの隙間をタービン排気E
が常時通過している。このため、伝熱管+IGは振動が
激しく作用することと相まって応力腐食割れ等の電気化
学的縞食が生起され、材料自身の彼方破壊を誘発するお
それがある。
By the way, the baffle I, which supports many heat exchanger tubes, is drilled with a margin in its hole diameter, so that the heat exchanger tubes are subjected to repeated concentrated loads at the edge of the hole. , and the gap between the holes Uη and the turbine exhaust E
is constantly passing through. For this reason, in combination with the intense vibration acting on the heat exchanger tube +IG, electrochemical corrosion such as stress corrosion cracking may occur, which may induce further destruction of the material itself.

(発明の目的〕 本発明は、このような事情から、バッフル(二よって支
えられる伝熱管の表面に金属粉末を溶射すること(二よ
ってその損傷を防止しようとする伝熱管の疲労抑制剤を
提供することを目的とする。
(Object of the Invention) In view of these circumstances, the present invention provides a fatigue suppressant for heat exchanger tubes that prevents damage by thermally spraying metal powder onto the surface of heat exchanger tubes supported by baffles. The purpose is to

〔発明の概要〕[Summary of the invention]

上記目的は伝熱管の表面(−5二酸化チタン94重量多
以下、アルミ4〜8tLi%、バナジウム2〜6重量−
の酸化粉末と、クロム12〜18厘1チ、鉄5〜9M1
k%、残部ニッケルからなるニッケルクロム合金粉末と
の混合粉末を溶射すること(二よって達成される。
The above purpose is to prepare the surface of the heat exchanger tube (-5 titanium dioxide 94% by weight or less, aluminum 4-8tLi%, vanadium 2-6% by weight).
oxidized powder, chromium 12-18 ml 1 t, iron 5-9 M 1
This is accomplished by thermal spraying a mixed powder of nickel-chromium alloy powder consisting of nickel and nickel.

〔発明の実施例〕[Embodiments of the invention]

伝熱管の表1fi(二混合合金粉末を溶射する(二先立
ち、次のような手段が講じられる。先ず、伝熱管にショ
ツトブラスト 面硬化を行い、トリクレンで脱 し、溶射部位が容易(
二行い得るよう(二前処理を施す。
Table 1fi of the heat exchanger tube (2) The following measures are taken beforehand: First, the heat exchanger tube is subjected to shot blast surface hardening, which is removed with trichloride to make the sprayed area easier (
Two pre-treatments are performed so that two treatments can be performed.

しかるに二酸化チタン94重電チ以下、アルミ4〜8重
量係、バナジウム2〜6M量費の酸化粉末と、、クロム
12〜18に量多、鉄5〜9亜址チ、残部ニッケルから
なるニッケル・クロム合金粉末との混合粉末を伝熱管の
表面(−溶射する。この場合、溶射ノーは、1 vun
以下で十分であるが、溶射ノー(二多少のピンホールが
生成されることもあるので、溶射後、直ち(−火炎で加
熱し、浴融処理を行う。
However, oxidized powder with titanium dioxide of 94 gm or less, aluminum of 4 to 8 gm, vanadium of 2 to 6 m, and nickel consisting of a large amount of chromium 12 to 18, iron 5 to 9 g, and the balance nickel. The mixed powder with chromium alloy powder is thermally sprayed on the surface of the heat transfer tube (-). In this case, the thermal spray no.
The following is sufficient, but since some pinholes may be generated, immediately after thermal spraying, heat with flame and perform bath melting.

本発明は、チタン製の伝熱管について欣明したが、こJ
l,に限らず、他の栃質の溶射については次の手段が硝
しられる。
Although the present invention has been described with respect to a titanium heat exchanger tube, this J
The following methods are recommended for thermal spraying not only 1, but also other lysate materials.

すなわち、キュプロニッケル官、モネル管を伝熱管とし
て使用する場合は、銅加〜30j[蓋チ、ニッケル70
〜80重jt[からなる粉末合金を、アルミニウム黄鉋
裏の伝熱管を使用する場合は、アルミ8〜11重電袈、
鉄1〜2東i%,伐部銅からなる粉末を、またステンレ
ス製の伝熱管を使用する場合は、炭素0.03〜0.1
重菫チ、ニッケル8〜10重jtチ、クロム18〜20
重量%、残部鉄からなる合金粉末を溶射すればよい。ま
た、本発明は、伝熱管の表面(二上述会金粉末の溶射を
吠用するよう説明しであるが、これ(二限らず、伝熱管
を支えるバッフルの孔(二上述の手段を講じてもよい。
In other words, when using cupronickel tubes or monel tubes as heat transfer tubes, copper coating ~ 30j [lid, nickel 70
When using a powder alloy consisting of ~80 heavy jt [aluminium 8-11 heavy electric tube,
If using a stainless steel heat exchanger tube, use a powder consisting of 1% to 2% iron and 0.03% to 0.1% carbon.
Heavy violet, nickel 8-10 heavy jt, chromium 18-20
It is sufficient to thermally spray an alloy powder consisting of iron in the balance by weight%. In addition, although the present invention is described as using thermal spraying of the above-mentioned gold powder on the surface of the heat exchanger tube (2), this invention is not limited to the surface of the heat exchanger tube (2), and the hole of the baffle supporting the heat exchanger tube (2) Good too.

〔発明の効果〕 以上説明したように、本発明は伝熱管またはノ(ツフル
ロ上述の含金混合粉末ン溶射したから、タービン排気(
二よる伝熱管の疲労は抑制される。したがって、伝熱管
(二儀#J等(二よる過度な応力が作用しても損傷は抑
制され、尺期開の開用(二耐え得る等の利点がある。
[Effects of the Invention] As explained above, the present invention provides thermal spraying of the above-mentioned metal-containing mixed powder on heat transfer tubes or on turbine exhaust pipes.
Fatigue of the heat exchanger tubes due to this is suppressed. Therefore, even if excessive stress is applied to the heat exchanger tube (such as #J), damage is suppressed, and there are advantages such as being able to withstand the opening of the tube in the open position.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は従来の一般的タービンプラントの系統図、第2
図は復水器の実施例を示す概略図、弗3図は第2図のA
部の部分拡大図、第4図は第2図のIV − IV矢視
方向からの切断した概略断面図。 l・・・高圧タービン 2・・・中圧タービン 3・・・低圧タービン 5・・・復水器 7・・・ボイラ 9・・・復水器 10・・・伝熱も 11・・・バッフル (7317)  代理人 −)fm士 則 近 憲 怖
(ほか1名、)第1図
Figure 1 is a system diagram of a conventional general turbine plant;
The figure is a schematic diagram showing an example of a condenser, and Figure 3 is A in Figure 2.
FIG. 4 is a schematic cross-sectional view taken from the direction of the IV-IV arrow in FIG. 2; l...High pressure turbine 2...Intermediate pressure turbine 3...Low pressure turbine 5...Condenser 7...Boiler 9...Condenser 10...Heat transfer also 11...Baffle (7317) Agent -) FM officer Nori Chika Ken (and 1 other person) Figure 1

Claims (1)

【特許請求の範囲】[Claims] 伝熱前表面(二、二酸化チタ7θ4重童%以下、アルミ
4〜8N値係、バナジウム2〜6重量%の酸化粉末と、
クロム12〜18崖量係、鉄5〜9嵐量乞残部ニッケル
からなるニッケル・クロム合金粉末との混合粉末を浴射
した伝熱管の疲労抑制剤。
The surface before heat transfer (oxidized powder of titanium dioxide 7θ4% or less, aluminum 4-8N value, vanadium 2-6% by weight,
A fatigue suppressant for heat transfer tubes which is sprayed with a mixed powder of a nickel-chromium alloy powder consisting of 12 to 18 chromium, 5 to 9 iron, and nickel.
JP14775382A 1982-08-27 1982-08-27 Fatigue inhibitor for heat transmitting tube Pending JPS5938600A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP14775382A JPS5938600A (en) 1982-08-27 1982-08-27 Fatigue inhibitor for heat transmitting tube

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP14775382A JPS5938600A (en) 1982-08-27 1982-08-27 Fatigue inhibitor for heat transmitting tube

Publications (1)

Publication Number Publication Date
JPS5938600A true JPS5938600A (en) 1984-03-02

Family

ID=15437367

Family Applications (1)

Application Number Title Priority Date Filing Date
JP14775382A Pending JPS5938600A (en) 1982-08-27 1982-08-27 Fatigue inhibitor for heat transmitting tube

Country Status (1)

Country Link
JP (1) JPS5938600A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5529803A (en) * 1978-07-18 1980-03-03 Nippon Electric Co Continuous voice discriminating device

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5529803A (en) * 1978-07-18 1980-03-03 Nippon Electric Co Continuous voice discriminating device
JPS6131477B2 (en) * 1978-07-18 1986-07-21 Nippon Electric Co

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