JPS5930500A - Production of briquette - Google Patents

Production of briquette

Info

Publication number
JPS5930500A
JPS5930500A JP14156882A JP14156882A JPS5930500A JP S5930500 A JPS5930500 A JP S5930500A JP 14156882 A JP14156882 A JP 14156882A JP 14156882 A JP14156882 A JP 14156882A JP S5930500 A JPS5930500 A JP S5930500A
Authority
JP
Japan
Prior art keywords
briquette
coal
rolls
raw material
forming
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP14156882A
Other languages
Japanese (ja)
Other versions
JPS645998B2 (en
Inventor
Teruo Sanada
輝男 真田
Yoji Maekawa
前川 洋司
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TETSUGEN KK
Nippon Steel Corp
Original Assignee
TETSUGEN KK
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by TETSUGEN KK, Nippon Steel Corp filed Critical TETSUGEN KK
Priority to JP14156882A priority Critical patent/JPS5930500A/en
Publication of JPS5930500A publication Critical patent/JPS5930500A/en
Publication of JPS645998B2 publication Critical patent/JPS645998B2/ja
Granted legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B30PRESSES
    • B30BPRESSES IN GENERAL
    • B30B11/00Presses specially adapted for forming shaped articles from material in particulate or plastic state, e.g. briquetting presses, tabletting presses
    • B30B11/16Presses specially adapted for forming shaped articles from material in particulate or plastic state, e.g. briquetting presses, tabletting presses using pocketed rollers, e.g. two co-operating pocketed rollers

Abstract

PURPOSE:To obtain briquette having high strength of an original shape and having good quality and characteristics irrespectively of the moisture and grain size of raw material coal, by forming the raw material coal at the gap of forming rolls regulated at a specific ratio with respect to the diameter of rolls. CONSTITUTION:Raw material coal is formed at the gap of forming rolls regulated at 0.2-0.7% of the diameter of the rolls in the stage of producing briquette to be used for production of coke. A required amt. can be supplied into the mold on the roll surface without preliminary processing such as addition of water to the raw material coal on the rolls and addition of a binder or the like and the briquette having high quality is produced in a high yield. If the peripheral speed of the forming rolls is regulated to 0.6-1.0m/sec under the above-described conditions, the preferable output is obtd. If the briquette is produced under such conditions, the productivity of a coke furnace and the quality of the produced coke are made stable at all times and the reduction in installation and maintenance costs is made possible.

Description

【発明の詳細な説明】 本発明は]−クス製造に供するための成型炭の製造方法
に関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for producing briquette coal for use in the production of coal.

周知のように石炭性状の不安定は、]−クス炉操業及び
コークス品質の作り込みに大きな影響を与えることから
石炭の事前処理は非常に重要である。
As is well known, the instability of coal properties has a great effect on the operation of coke ovens and on the quality of coke, so pre-treatment of coal is very important.

]−クス品質の向上及び安定化対策としては装入炭の一
部を成型炭に置き換える成型炭配合法が多く用いられて
いる。
] - As a measure to improve and stabilize the quality of coal, a briquette blending method in which part of the charged coal is replaced with briquette coal is often used.

この成型炭の製造に当って、一般に用いられる方法は第
1図に示すように構成した装置を用いて1す(料供給べ
1しト〕ンベアーIK設けたコンベアース’f −+シ
2により秤駄した量に対して比率設定17たmの水3及
びパイン/2−4を原料に添加しつつ蒸気5で加熱し混
練する横型ニーター6に、惇き原ト1粒子の表面にパイ
、7/2−被膜をコーティングした後成型ロー1し7で
成型し成型炭を製造している。
In producing this briquette coal, the method generally used is to use a device configured as shown in Figure 1. A horizontal kneader 6 is heated with steam 5 and kneaded while adding 3 m of water and pine/2-4 at a ratio of 17 m to the weighed amount to the raw material. 7/2-After coating, molding is performed using molding rows 1 to 7 to produce molded coal.

そこで従来における成型炭のf!!造方法は、成型ロー
ルの千セッづを0.5咽の一定値に固定し該ロールの回
転に従って成型ロール表面にカツラ状に形成した成型モ
ールドに噛み込ますLる成復炭用原料炭の喰が適正に保
持されるよう成型ロー)しに供給される原料炭に最適な
すべり性を与え、該カツラ内への原料炭の過剰供給を防
止している。このすべり性を与えるためには、成型ロー
ル上、原料炭水分が14〜15%となるように加水調節
するものであった。つまり、このすべり性を与えない場
合、成型E  flyドに原料炭が過剰に供給されると
成型ロー1して加圧、圧縮された後、成型O−1シから
離れると共に上記原料炭の弾性復元力が働いて割れたり
、あるいはひび割れが発生し成型炭の原型をとどめず成
品塊歩留りを損うこととなるからである。
Therefore, conventional briquette f! ! The manufacturing method involves fixing the number of millimeters on a forming roll to a constant value of 0.5 mm, and as the roll rotates, the raw coal for synthesis coal is bitten into a forming mold formed in a wig shape on the surface of the forming roll. The raw coal supplied to the molding row is given optimal slipperiness so that the particles are held properly, and excessive supply of raw coal into the wig is prevented. In order to provide this slipperiness, water was added to the raw coal on the forming roll so that the moisture content was 14 to 15%. In other words, if this slipperiness is not provided, if raw coal is supplied in excess to the molding E-fly, it will be pressurized and compressed by the molding row 1, and then it will leave the molding row O-1 and the elasticity of the raw coal will decrease. This is because the restoring force acts to cause breakage or cracking, which prevents the briquette from retaining its original shape and impairs the yield of the finished product.

この従来の方法における成型性(は、第2図(a)〜(
e)の′eプルに示すように粉粒体がJJ11王の七−
)しド内に供給されてから圧縮力を受け、成型品ができ
ると考えられる。
The moldability in this conventional method (Fig. 2(a) to (
As shown in the 'e pull of e), the powder and granules are JJ11 King's Seven-
) It is thought that a molded product is formed after being fed into a mold and subjected to compressive force.

第2図の(a)は供給、(b)は下部での圧縮(逆流現
象)、(c)は中心部での圧縮、(d)は上部での圧縮
、(e)は排出の態様を示す。
In Figure 2, (a) shows the supply, (b) shows the compression at the bottom (backflow phenomenon), (c) shows the compression at the center, (d) shows the compression at the top, and (e) shows the discharge mode. show.

即ち、第2図の(a)は原料炭が成型ロールの回転によ
り七−ルド内に引き込まれ充嘱される。
That is, in FIG. 2(a), raw coal is drawn into the seven-fold chamber by the rotation of the forming rolls and filled with it.

(b)、<c)では原料炭の充填邸の圧縮がモー1しド
のF方から漸次進行し空隙率が減少する。それと同時に
f  II/ド内の成型原料炭の一部は、その材料の流
動性に従い、圧力がヒがるにつれて、より抵抗の少ない
方向、即ちロー)しの回転方向とは反対方向にE −1
bドからはみ出ようとする(逆流現象)。これによって
過剰供給が防がれる。
In (b) and <c), the compression of the coking coal filling chamber gradually progresses from the mode F direction, and the porosity decreases. At the same time, according to the fluidity of the material, some of the molded coking coal in f II/do moves in the direction of less resistance, i.e., in the direction opposite to the direction of rotation, as the pressure decreases. 1
Trying to get out of B (reflux phenomenon). This prevents oversupply.

(d)では成型がほぼ終了に近づいており、七−1しド
内の上部で最終的な圧縮が行なわれる。
In (d), the molding is almost completed, and the final compression is performed at the upper part of the chamber 7-1.

(e)は成型品が丘−ルドから離れはじめて成型炭がで
きるがロール上に原料炭が過剰供給され、かつすべや性
がない場合は第3図のbでの成型ローjし噛み込み原料
炭の逆流現象が起りにくく、(d)での加圧成型時の圧
力が過大となるので、成型0−1シから成型炭が離れる
と共に原料炭の弾性復元力が働き、成型炭に割れもしく
はひび割れυを生じることとなる。
In (e), briquette coal is formed when the molded product begins to separate from the mold, but if the coking coal is excessively supplied onto the rolls and is not smooth, the molding rolls shown in b in Figure 3 are used to form briquettes. Since the backflow phenomenon of coal is difficult to occur and the pressure during pressurization in (d) becomes excessive, the elastic restoring force of the coking coal acts as the briquette separates from the briquette 0-1, causing cracks or cracks in the briquette. This will result in cracks υ.

第3図は七−ルド内への原料過剰供給で原料のすべり性
悪く逆流現象のない状態を示す図で、(a)は供給、(
b)は下部での圧縮(逆流現象が起りにくい)、(C)
1は中心部での圧縮、(d)は上部での圧縮、(e)は
石炭粒度dp = ]、、 6 rmq、間隙0.5膿
で逆流不可の状態を示し7、(f)は排出の状態を示す
Figure 3 is a diagram showing a state in which raw materials have poor slipperiness and no backflow phenomenon due to excessive supply of raw materials into the seventh chamber; (a) shows the supply, (
b) Compression at the bottom (backflow phenomenon is less likely to occur), (C)
1 indicates compression at the center, (d) indicates compression at the top, (e) indicates coal particle size dp = ], 6 rmq, gap 0.5 pus, and no backflow is possible. 7 (f) indicates discharge. Indicates the status of

本発明者等d1これ等従来の成<p炭製造方法の間唄点
を解消する種々の実験、倹R・↑な市ね、良好な成型性
と品質を得るにあたって、原料炭の水分及び粒度が従来
溝、えられていた程影響しないことをす7出した。本発
明はこの知見をもとになされたもので、原料炭の水分、
粒度の変化に関係なく:爪型の強度の、高い区好な品質
性状を有する成型炭を]−クス原料として必叫・な曜を
自在に作り出せる方法を提供するものであり、その特徴
とするところは (1)  Fy’Zi観ロール′の甲セッづを[1−f
ly ?吊の0.2〜0.7チとすることを特徴とする
へ取込へ微六食へ成型炭の製造方法。
The present inventors conducted various experiments to solve the problem of the conventional coal production method, and conducted various experiments to solve the problem of cracking point in the conventional coal production method, and in order to obtain good moldability and quality, It was found that the effect was not as great as previously thought. The present invention was made based on this knowledge, and the moisture content of coking coal,
Regardless of the change in particle size: it provides a method for freely producing briquettes with claw-shaped strength and high quality properties as a raw material for coal, and its characteristics are as follows: Tokoro (1) The first set of Fy'Zi view role' [1-f
Ly? A method for producing briquette charcoal, characterized in that the charcoal is 0.2 to 0.7 inches thick.

(2)成型(]−+bの周速を(1,6〜1.. Om
/secにすることを特徴とする(1)の成型炭の製造
方法。
(2) The peripheral speed of molding (]-+b is (1,6~1.. Om
The method for producing briquette coal according to (1), characterized in that:

(3)  成型ロール間反力(全圧力)30〜105t
onにすることを特徴とする(1)、(2)の成型炭の
製造方法。
(3) Reaction force between forming rolls (total pressure) 30 to 105t
The method for producing briquette coal according to (1) or (2), characterized in that the method is turned on.

(4)粒915 mm (最大長)以下の原料炭を用い
ることを特徴とする(1)、(2)、 (3)の成型炭
の製造方法。
(4) The method for producing briquette coal according to (1), (2), or (3), characterized in that raw coal having grains of 915 mm (maximum length) or less is used.

である。It is.

本発明における各々の限定理由について以下に説明する
The reasons for each limitation in the present invention will be explained below.

先づ、ロール甲セッづを成型ロール径の0.2〜0.7
qbとするのは、第6図に示す如く0.2チ未満になる
と過大加圧成型となって前記した如く成型ロールから成
型炭が離れると原料炭の弾性復元力によって成型炭が崩
壊して、成型炭歩留りが実用歩留りである80チをド回
るだめであり、0・7チを超えると必要加圧力が得られ
ず、これも又成型炭が成型ロールを離れると崩壊して、
実用歩留りの80チを維持することが難しいがらである
First, mold the roll instep with a diameter of 0.2 to 0.7
The reason why qb is defined as qb is that if it is less than 0.2 inch as shown in Fig. 6, over-pressure molding will occur, and as mentioned above, when the molded coal separates from the molding roll, the molded coal will collapse due to the elastic restoring force of the coking coal. However, the yield of molten coal cannot exceed the practical yield of 80 inches, and if it exceeds 0.7 inches, the necessary pressurizing force cannot be obtained.
However, it is difficult to maintain a practical yield of 80 inches.

次に成型1コールの周速を0.6〜1.0 m/sec
に限定するのは第7図に示;7た如く、周速が0.6m
/see未満では好ましい生産址が維持できず、1、0
 m/secを超えると成型炭の必卯圧潰強度が州られ
ないからである。。
Next, set the peripheral speed of one molding call to 0.6 to 1.0 m/sec.
As shown in Figure 7, the circumferential speed is 0.6 m.
/see, a favorable production site cannot be maintained, and 1,0
This is because if it exceeds m/sec, the required crushing strength of the briquette coal cannot be maintained. .

又、成型D −1b間反力(全千力)を30〜105t
onとするのは、第8図で明らかなように30ton未
Id及び105ton頬の何れもが成717す炭の実用
歩留りの80チ維持757 ii t、 くなるからで
ある。
Also, the reaction force between molding D and 1b (total 1,000 force) is 30 to 105t.
The reason why it is turned on is because, as is clear from FIG. 8, the practical yield of charcoal produced at 30 tons and 105 tons is maintained at 80 inches.

第6図〜第8 +!!2Iは水分6〜14係で6月1y
が15叫(最大長)以Fの通常の原料炭による1m −
T。
Figures 6 to 8 +! ! 2I is water staff 6-14 June 1y
1 m - with ordinary coking coal of 15 mm (maximum length) or less
T.

甲セツづと1戊型炭歩留、[1−fシ周速と成型突圧潰
強寒、ロール間圧力と成型炭弗留・1)関係を示すもの
である、 即ち、本発明はJ1犯構成によって第41’l (e)
、(f)に示す如く、成型ロー1し間に成型ロー11.
径にもとづいて定する所定の甲セ・りづを設けろことに
より、ワールヒの原料炭に加水したりバイジターを増添
υ11等の事前加工を楕すことなくロー11.表面への
℃−ルド内へ必要量を供給し、D  II/−ヒの原料
炭に好ましい逆流現象の発現を可能とし高い歩留で高品
°mの成型炭の製造を可能ならしめるものである。
This shows the relationship between the yield of J1 type coal, [1-f] circumferential speed and molding crushing strength, inter-roll pressure and molded coal filtration, 1). By composition No. 41'l (e)
, (f), between the forming row 1 and the forming row 11.
By providing a predetermined instep and edge determined based on the diameter, it is possible to process low 11. It supplies the necessary amount to the surface of the ℃-hard, enables the expression of a favorable backflow phenomenon for DII/-H coking coal, and makes it possible to produce high-quality briquette coal with a high yield. be.

第4図は0−ルfセツづをロール径の0.2〜0.7チ
に広げた時の圧縮成型の態様を示す図で、(a)は供給
、(1))は下部での圧縮(逆流現象) 、(c)は中
心部での圧縮、((1)は上部での圧縮、(e)は石炭
粒度dp = 1.7 mm、間隙5〜7闘の状部を示
す図であり、(f)は排出の状態を示す図である。
Figure 4 is a diagram showing the compression molding mode when the 0-ru f set is spread to 0.2 to 0.7 inch of the roll diameter, (a) is the supply, (1)) is the lower part. Compaction (backflow phenomenon), (c) is compression at the center, ((1) is compression at the top, (e) is a diagram showing the shape of the coal particle size dp = 1.7 mm, gaps 5 to 7. (f) is a diagram showing the state of discharge.

次に実施例を表−1に示す。Next, Examples are shown in Table-1.

原t」炭は水分4〜14チ、粒115 、Mrl(+W
大長)以下のものを用い、装置は第1図して示したもの
を用いた。
The raw charcoal has a moisture content of 4 to 14, grains of 115, Mrl (+W
(Ocho) The following equipment was used, and the apparatus shown in Figure 1 was used.

比較例(5)の従来の0−ル甲ヤッづ0.5 mm操業
レベルでは第2図の説明通り、D−ル上原料炭水分が1
4チしベルでは安定した操業となるが、この状態でロー
1し周速をアラづした比較例(6)は加圧成型時間の減
少から品質低下を、来たし、又比較例(7)のロール水
分10チレベルでは第3図の逆流現象が困難となり、ロ
ール周速を下げて成型時間をかけても操業が著しく不安
定となり、これが生産性、品質低下とバラッ士の増大を
招く原因となる。
At the conventional 0.5 mm operation level in Comparative Example (5), as explained in Figure 2, the coking coal moisture on the D-ru was 1.
Stable operation is achieved with a 4-inch bell, but Comparative Example (6), in which the circumferential speed was uneven by Low 1 under this condition, resulted in quality deterioration due to a decrease in pressure molding time, and Comparative Example (7) When the roll moisture level is 10 degrees, the backflow phenomenon shown in Figure 3 becomes difficult, and even if the roll circumferential speed is reduced and the forming time is increased, the operation becomes extremely unstable, which causes a decrease in productivity, quality, and an increase in pieces. .

そこで本発明に基づく結果を実施例(1)に示すが、従
来の操業条件実験(5)のうちロール4p1ソづのみ5
胴と拡大することで、原料炭水分による逆流作用と第4
図の効果が加味されて極めて安定な操業となり、かっ千
セッづ拡大情に相当するロール通炭惜が増加し、逆流現
象の安定による生産性の向上、品質の安定・向上が見ら
れた。
Therefore, the results based on the present invention are shown in Example (1), and among the conventional operating condition experiments (5), roll 4p1
By expanding with the shell, the backflow effect due to coking coal moisture and the fourth
Taking into account the effects shown in the diagram, the operation became extremely stable, and the amount of roll passing through the coal increased, which corresponds to the expansion of coal flow, and productivity improved due to the stabilization of the backflow phenomenon, and stable and improved quality was observed.

これをベースとして本例(2)で原料炭性状と〇−ル甲
セッづを変化させた処、ロール通炭量の乾量ベースの増
加が生産増となり、又4セツづ拡大で更に向上する。本
例(3)、(4)のずセラづ拡大においても効果は向上
し得る結果を得たが、本例(4)の周速の低下は生産量
に比例して低下を示した。
Based on this, in this example (2), when the coking coal properties and 〇-ru A setting were changed, an increase in the dry weight basis of the roll coal passing amount resulted in an increase in production, and further improvement was achieved by increasing the amount of rolled coal by 4 sets. . In Examples (3) and (4), results were obtained in which the effect could be improved, but in Example (4), the peripheral speed decreased in proportion to the production amount.

以上説明した本発明によると従来のように成型炭の製造
にあたって成型原料炭の性状変化に応じて添加水分及び
バイジターの酸を調整することなく、必要駿の成型炭を
必要な品質レベ1しに応じて確保することができるため
、作業性よ〈〕−クス炉の生産性、製造]−クスの品質
を常に安定することができ、しかも設備費の低減、保守
費の節減が可能となる等得られる効果は大きい。
According to the present invention as described above, the necessary amount of briquette coal can be produced at the required quality level 1 without adjusting the added moisture and the acid of the vizier in accordance with the changes in the properties of the briquette coking coal during production of briquette coal as in the conventional method. As a result, it is possible to maintain stable workability (productivity of the cous oven, manufacturing) and the quality of the cous at all times, as well as reduce equipment costs and maintenance costs. The benefits are significant.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は従来の成型炭製造づ0セスを示す図、第2図(
a)、(b)、(c)、(d)、(e)、第3図(a)
、(b)、<C)、(d)、(e)、(f)<第4・図
(齢、(b)、(c)、(d)、(e)、(f)は成型
時の成型機の七−)しド内の原料加圧による圧縮成型の
状態を示す図であり、通常の状態をのすべり性悪く逆流
現象のない状態図を第3図に、第4図はD−ル甲ヤッづ
を0−ル径の0.2〜0.7%に広げた時の圧縮成型を
示す。 第5図、第6図は成型ロール4pツづ操業における製造
づDセスならびにフ0−を示す図、第7図は圧縮強度と
0−ル周速の関係を示す図、第8図は成型炭歩留と成型
反力の関係を示す図である。 1・・・原料供給コシベアー 2・・・コシベアースケール 3・・・水添加ライシ4
・・・バイシ情−添加うイシ  5・・・加熱用蒸気う
イシ6・・・三十シシクニーター  7・・・甲ヤッづ
D−ル8 ・・・ o  −ILI  −f  セ ソ
 づ休                     ペ
@裡駅q、E 04票老n悩(Σ) 荘 第8目 、6、型反ハ(電圧力’7on)
Figure 1 shows the conventional briquette production process, Figure 2 (
a), (b), (c), (d), (e), Figure 3 (a)
, (b), <C), (d), (e), (f) Fig. 3 shows the state of compression molding by pressurizing raw materials in the molding machine of the molding machine. - Shows compression molding when expanded to 0.2 to 0.7% of the O-ru diameter. Fig. 5 and Fig. 6 are diagrams showing the manufacturing process and the process of production in a 4-point forming roll operation. It is a figure showing the relationship between charcoal yield and molding reaction force. 1... Raw material supply Koshibear 2... Koshibear scale 3... Water-added rice 4
・・・Baishijou-addition 5...Heating steam vessel 6...30 shishikniter 7...Ko Yadzu D-le 8... o -ILI -f se so zukyu pe@裡駅q, E 04 votes Old n Worship (Σ) Zhuang No. 8, 6, Type Han Ha (voltage power '7on)

Claims (1)

【特許請求の範囲】 1 成型ロールの417ツづをロー1シイ1の0.2〜
0.7チとすることを特徴とする成型炭の製造方法。 2 成型ロールの周速を0.6〜1.0 m/seCに
することを特徴とする特許請求のqrl囲第1r11記
載の成型炭の製造方法。 3 成型ロー11間反力(全圧力)を30〜105to
n Kすることを特徴とする特許請求の範囲第1項、第
2項記載の成型炭の製造方法。 4 粒e 15 mn (i#大長)はFの11式料炭
を用いることを特徴とする特1作請求の範囲ピれ1L0
、第2項、第3項記11iVの成型炭V製造方法。
[Claims] 1 The 417 diameter of the forming roll is 0.2 to 0.2 of the row 1 sea 1.
A method for producing briquette coal, characterized in that the briquette is 0.7 inch. 2. The method for producing briquette coal according to claim 1r11, characterized in that the circumferential speed of the shaping roll is 0.6 to 1.0 m/sec. 3 The reaction force (total pressure) between forming rows 11 is 30 to 105 to
The method for producing briquette coal according to claims 1 and 2, characterized in that: nK. 4 Grain e 15 mn (i#Oicho) is characterized by using Type 11 coal of F. Claim 1 Peel 1L0
, Items 2 and 3, 11iV briquette V manufacturing method.
JP14156882A 1982-08-14 1982-08-14 Production of briquette Granted JPS5930500A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP14156882A JPS5930500A (en) 1982-08-14 1982-08-14 Production of briquette

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP14156882A JPS5930500A (en) 1982-08-14 1982-08-14 Production of briquette

Publications (2)

Publication Number Publication Date
JPS5930500A true JPS5930500A (en) 1984-02-18
JPS645998B2 JPS645998B2 (en) 1989-02-01

Family

ID=15294999

Family Applications (1)

Application Number Title Priority Date Filing Date
JP14156882A Granted JPS5930500A (en) 1982-08-14 1982-08-14 Production of briquette

Country Status (1)

Country Link
JP (1) JPS5930500A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4886441A (en) * 1987-11-06 1989-12-12 Food Equipment Engineering, Inc. Apparatus for forming three dimensional food products
JP2008290145A (en) * 2007-05-28 2008-12-04 Kao Corp Method for producing tablet
US10351658B2 (en) 2010-03-31 2019-07-16 Mitsubishi Chemical Corporation Biomass-resource-derived polyurethane, method for producing same, and biomass-resource-derived polyester polyol

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5178A (en) * 1974-06-20 1976-01-05 Nippon Steel Corp Funjobutsuno kaatsuseikeisochi
JPS5257203A (en) * 1975-11-05 1977-05-11 Keihan Rentan Kogyo Co Ltd Method and apparatus for molding molded coal

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5178A (en) * 1974-06-20 1976-01-05 Nippon Steel Corp Funjobutsuno kaatsuseikeisochi
JPS5257203A (en) * 1975-11-05 1977-05-11 Keihan Rentan Kogyo Co Ltd Method and apparatus for molding molded coal

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4886441A (en) * 1987-11-06 1989-12-12 Food Equipment Engineering, Inc. Apparatus for forming three dimensional food products
JP2008290145A (en) * 2007-05-28 2008-12-04 Kao Corp Method for producing tablet
US10351658B2 (en) 2010-03-31 2019-07-16 Mitsubishi Chemical Corporation Biomass-resource-derived polyurethane, method for producing same, and biomass-resource-derived polyester polyol

Also Published As

Publication number Publication date
JPS645998B2 (en) 1989-02-01

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