JPS59230632A - Preparation of aqueous dispersion containing metal salt of higher fatty acid - Google Patents
Preparation of aqueous dispersion containing metal salt of higher fatty acidInfo
- Publication number
- JPS59230632A JPS59230632A JP10721983A JP10721983A JPS59230632A JP S59230632 A JPS59230632 A JP S59230632A JP 10721983 A JP10721983 A JP 10721983A JP 10721983 A JP10721983 A JP 10721983A JP S59230632 A JPS59230632 A JP S59230632A
- Authority
- JP
- Japan
- Prior art keywords
- fatty acid
- higher fatty
- metal salt
- dispersion
- glycol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 235000014113 dietary fatty acids Nutrition 0.000 title claims abstract description 21
- 239000000194 fatty acid Substances 0.000 title claims abstract description 21
- 229930195729 fatty acid Natural products 0.000 title claims abstract description 21
- 150000004665 fatty acids Chemical class 0.000 title claims abstract description 21
- 239000006185 dispersion Substances 0.000 title claims abstract description 18
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 16
- 239000002184 metal Substances 0.000 title claims abstract description 16
- 150000003839 salts Chemical class 0.000 title claims abstract description 16
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 18
- 238000006243 chemical reaction Methods 0.000 claims abstract description 13
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 7
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract description 6
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 150000001875 compounds Chemical class 0.000 claims abstract 3
- 238000004519 manufacturing process Methods 0.000 claims description 5
- -1 polyoxyethylene ethyl ether Polymers 0.000 abstract description 11
- 238000000034 method Methods 0.000 abstract description 8
- 235000021355 Stearic acid Nutrition 0.000 abstract description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 abstract description 5
- 239000008117 stearic acid Substances 0.000 abstract description 5
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 abstract description 3
- 239000000920 calcium hydroxide Substances 0.000 abstract description 3
- 229910001861 calcium hydroxide Inorganic materials 0.000 abstract description 3
- 235000011116 calcium hydroxide Nutrition 0.000 abstract description 3
- 229910052708 sodium Inorganic materials 0.000 abstract description 3
- 239000011734 sodium Substances 0.000 abstract description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 abstract description 2
- 238000010947 wet-dispersion method Methods 0.000 abstract description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- 239000007787 solid Substances 0.000 description 5
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
- 150000002736 metal compounds Chemical class 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 238000009500 colour coating Methods 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- BYLSIPUARIZAHZ-UHFFFAOYSA-N 2,4,6-tris(1-phenylethyl)phenol Chemical compound C=1C(C(C)C=2C=CC=CC=2)=C(O)C(C(C)C=2C=CC=CC=2)=CC=1C(C)C1=CC=CC=C1 BYLSIPUARIZAHZ-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical class C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- OMTBTKFXJPHMHY-UHFFFAOYSA-N ethoxy phenyl sulfate Chemical class CCOOS(=O)(=O)OC1=CC=CC=C1 OMTBTKFXJPHMHY-UHFFFAOYSA-N 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229910021508 nickel(II) hydroxide Inorganic materials 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 150000008054 sulfonate salts Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 description 1
- 239000013053 water resistant agent Substances 0.000 description 1
Landscapes
- Colloid Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Lubricants (AREA)
- Paper (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は高級脂肪酸金属塩の水性分散液の製造方法に関
する。さらに詳しくは、高級脂肪酸と■族金属の化合物
をノニオン系界面活性−剤の存在下に水中で反応させ、
さらに湿式分散１強制分散させる工程に、少なくとも１
種のグリコールを加えることを特徴とする高級脂肪酸金
属塩の水性分散液の製造方法に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for producing an aqueous dispersion of higher fatty acid metal salts. More specifically, higher fatty acids and group II metal compounds are reacted in water in the presence of a nonionic surfactant,
Furthermore, in the step of wet dispersion 1 forced dispersion, at least 1
The present invention relates to a method for producing an aqueous dispersion of a higher fatty acid metal salt, which comprises adding a seed glycol.
従来より高級脂肪酸金属塩は粉体或は水性分散液の形で
コート紙関係でフラワリング、ダスティング防止、カラ
ーコート液の粘度安定を目的として使用されている。一
方、各種建築材料、例えば石膏製品、セメント製品、セ
メント板、硅カル板。Hitherto, higher fatty acid metal salts have been used in the form of powder or aqueous dispersion in coated papers for the purpose of preventing flowering and dusting and stabilizing the viscosity of color coating liquids. On the other hand, various building materials such as gypsum products, cement products, cement boards, and silicon boards.
ＰＣ板又はパーティクルボード板等の耐水剤としても用
いられている。It is also used as a water-resistant agent for PC boards, particle boards, etc.
この様な各種用途で使用されている脂肪酸金属塩は複分
解法或は高温下での直接反応によって得られている。Fatty acid metal salts used in such various applications are obtained by double decomposition method or direct reaction at high temperature.
従って、水性分散液の製造に関しては多量の界面活性剤
を要し種々の欠点を有していた。Therefore, the production of aqueous dispersions requires a large amount of surfactant and has various drawbacks.
本発明者はこの様な欠点を改善すべく鋭意研究を重ね、
本発明に至り、ここにそれを提供せんと１”ろものであ
る。The inventor has conducted extensive research to improve these drawbacks,
Having arrived at the present invention, it would be a shame if we did not present it here.
本発明は、
（ａ） 高級脂肪酸と■族金属の化合物なノニオン系
界面活性剤の存在下水中で反応させ、
（ｈ）その得られた高級脂肪酸金属塩を機械的に湿式分
散させ、
＜ｃ＋ 必要に応じて、アニオン系界面活性剤を加え
、（ｄ、）（ａ）の反応前、（／Ｉ）の分散前あるいは
分散後又は（Ｃ）の添加後のいずれかの時点で少なくと
も１種のグリコールな加え、
（ｅ）メディア型分散機、ロールミルあるいはピストン
型高圧乳化機又はこれらを組合せてその金属塩を強制分
散させる
ことにより得られる高級脂肪酸金属塩の水性分散液の製
造方法である。The present invention comprises: (a) reacting a higher fatty acid with a group II metal compound in water in the presence of a nonionic surfactant; (h) mechanically wet-dispersing the obtained higher fatty acid metal salt; <c+ If necessary, an anionic surfactant is added, and at least one type of anionic surfactant is added before the reaction of (d,) (a), before or after dispersion of (/I), or after the addition of (C). (e) A method for producing an aqueous dispersion of a higher fatty acid metal salt obtained by forcibly dispersing the metal salt using a media-type dispersion machine, a roll mill, a piston-type high-pressure emulsifier, or a combination thereof.
本発明で用いる脂肪酸金属塩は遊離カルボキシル基を含
まない、従って反応に用いる金属化合物は脂肪酸に対し
て当モル以上用いる。The fatty acid metal salt used in the present invention does not contain a free carboxyl group, so the metal compound used in the reaction is used in an amount equal to or more than the equivalent molar amount to the fatty acid.
本発明で用いられろ高級脂肪酸は飽和又は不飽和脂肪酸
で、例えばカプロン酸、カプリル酸、ラウリン酸、ミリ
スチン酸、バルミチン酸、ステアリン酸およびオレイン
酸等からなる群より１種又は２種以上選ばれろ。The higher fatty acids used in the present invention are saturated or unsaturated fatty acids, such as one or more fatty acids selected from the group consisting of caproic acid, caprylic acid, lauric acid, myristic acid, valmitic acid, stearic acid, oleic acid, etc. .
金属化合物としてはＮｏ、Ｎｉ（ＯＨ）２又はＭ ｃ
１３２等で示され、式中Ｍ＆ｔＭｇ、ｃａ又はＢαのア
ルカリ土類金属及びＺｎの周期律表■族の金属である。As a metal compound, No, Ni(OH)2 or Mc
132, etc., in the formula M&tMg, ca or Bα, which is an alkaline earth metal, and Zn, which is a metal from group 1 of the periodic table.
次に、ノニオン系界面活性剤としては、ノニルフェノー
ル、オクチルフェノール、スチレン化フェノール、飽和
・不飽和高級アルコール等のポリオキシエチレンエーテ
ル又はポリオキシプロピレンエーテル、又はポリオキシ
エチレン／プロピレンエーテル等からなる群より１種又
は２種以上で用いられる。Next, as the nonionic surfactant, one selected from the group consisting of nonylphenol, octylphenol, styrenated phenol, polyoxyethylene ether or polyoxypropylene ether such as saturated/unsaturated higher alcohol, or polyoxyethylene/propylene ether, etc. Used in one species or in two or more species.
又、アニオン系界面活性剤としては、ノニルンエノール
、オクチルフェノール、スチレン化フェノール等のスル
ホコノ・り酸の塩（Ｋ、 Ｎａ、 Ｎ）Ｉ、 ）又はこ
れらのポリオキシエチレン付加物のスルホン酸塩等から
なる群より１種又は２種以上選ばれる。In addition, examples of anionic surfactants include salts of sulfoconophosphoric acid (K, Na, N) I, such as nonylene enol, octylphenol, and styrenated phenol, or sulfonate salts of polyoxyethylene adducts thereof. One or more types are selected from the group consisting of.
一方、グリコールとしてはエチレングリコール。On the other hand, ethylene glycol is a glycol.
ジエチレングリコール、フロピレンクリコール。Diethylene glycol, fluoropylene glycol.
ジプロピレングリコール、ポリエチレングリコールなど
からなる群より１種又は２種以上選ばれる。One or more types selected from the group consisting of dipropylene glycol, polyethylene glycol, etc.
本発明に使用される分散機とは、ロールミル。The dispersing machine used in the present invention is a roll mill.
ボールミル、メディア型分散機、ディスパーミル。Ball mill, media type dispersion machine, disper mill.
コロイドミル、各種ミギザー、ピストン型高圧乳化機が
掲げられる。Colloid mills, various microgizers, and piston-type high-pressure emulsifiers are listed.
以下、詳却１は実施例をもって説明するが、この範囲に
限定するものではない。Hereinafter, detailed description 1 will be explained using examples, but the scope is not limited to this.
実施例（１）
温水４５１．１ ｇ、消石灰５９４ｇ及びノニオン系界
面活性剤（ポリオキシエチレンエチルエーテル、 Ｅ、
Ｏ付加１４モル）１０ｙを反応釜に仕込み系内の温度
を８５°Ｃに加温し、攪拌しながらステアリン酸４４９
．５ ｇを加え反応を行なった。反−応終了後コロイド
ミルを用いて分散し、ジエチレングリコール２０ｇを加
え、更にアニオン系界面活性剤（ポリオキシエチレンノ
ニルフェノールのスルホン酸ソーダ）１０．９を添加し
た後、ホールミルυこて１時間処理し固形分５０％の製
品を得た。Example (1) 451.1 g of warm water, 594 g of slaked lime, and nonionic surfactant (polyoxyethylene ethyl ether, E,
Charge 10y (14 moles of O addition) into a reaction vessel, warm the temperature inside the system to 85°C, and add stearic acid 449 while stirring.
．． 5 g was added to carry out the reaction. After the reaction was completed, the mixture was dispersed using a colloid mill, 20 g of diethylene glycol was added, 10.9 g of an anionic surfactant (sodium sulfonate of polyoxyethylene nonylphenol) was added, and the mixture was treated with a whole mill υ trowel for 1 hour. A product with a solid content of 50% was obtained.
実施例（２）
温水５７０Ｉと塩化マグネシウム６１．５ ＆及びノニ
オン界面活性剤（ポリオキシエチレントリスチレン化フ
ェニルエーテル、 Ｅ、Ｏ付加７−ｅル）Ｌｌを反応釜
に仕込み９０℃に加温した後、攪拌しながらステアリン
酸６５６６ｇを徐々に加え反応を行なった。反応終了後
ポリエチレングリコール（ＭＷ＝２０００）ろＯｇを加
えコロイドミルな用いて分散した後、系内の温度を６０
℃に冷却し、次いでアニオン系界面活性剤（トリスチレ
ン化フェノールエトキシサルフェートＮαｍ）１６ｇを
添加し、然る後、メディア型分散機を用いて更に分散を
行ない、固形分５０．％の脂肪酸金属塩の水性分散液を
得た。Example (2) 570 I of warm water, 61.5 I of magnesium chloride & nonionic surfactant (polyoxyethylene tristyrenated phenyl ether, E, O added 7-el) L1 were charged into a reaction vessel and heated to 90°C. Thereafter, 6566 g of stearic acid was gradually added while stirring to carry out a reaction. After the reaction was completed, add Og of polyethylene glycol (MW = 2000) and disperse using a colloid mill, and then reduce the temperature in the system to 60°C.
℃, and then 16 g of anionic surfactant (tristyrenated phenol ethoxy sulfate Nam) was added, followed by further dispersion using a media type dispersion machine until the solid content was 50. % aqueous dispersion of fatty acid metal salts was obtained.
実施例（３）
温水５８２．２Ｌ消石灰３６．７ 、！９及び塩化マグ
ネシウム１２．ＩＬ！？、ノニオン系界面活性剤（ポリ
オキシエチレンステアリルエーテルＥ、Ｏ’１５モル）
１８ｇとジプロピレングリコール１５，９を加え系内の
温度を９０℃に加温した後、攪拌しながらステアリン酸
３４０．３．９を徐々に加え反応を行なった。反応終了
後ＴＫミキサーを用いて分散した後、ピストン型高圧乳
化機を用いて３００ｋｇ／藷の圧力で２回通し急冷し、
固形分４０％の脂肪酸金属塩の水性分散液を得た。Example (3) Warm water 582.2L Slaked lime 36.7L,! 9 and magnesium chloride 12. IL! ? , nonionic surfactant (polyoxyethylene stearyl ether E, O'15 mol)
After adding 18 g of dipropylene glycol 15.9 and heating the temperature in the system to 90° C., stearic acid 340.3.9 was gradually added while stirring to carry out a reaction. After the reaction was completed, the mixture was dispersed using a TK mixer, and then passed through twice using a piston-type high-pressure emulsifier at a pressure of 300 kg/flour, followed by rapid cooling.
An aqueous dispersion of fatty acid metal salts with a solid content of 40% was obtained.
性能試験結果（４）
４−１゜カラーコート用潤溺剤としての効朱塗料の調整
。Performance test results (4) 4-1゜Adjustment of effectiveness of red paint as lubricant for color coat.
潤滑剤：（Ａ）に対して固型分換算１０％水を加えて全
固型分４３係に調整
撹拌機、ケデイミル使用
カラーコート条件
原 紙：白板紙（３１５＆／ｆｆ１）塗工量：１５ｊ
Ｊ／ｍ）
塗工方法：バーコーター
乾燥方法：風乾後ドラムドライヤーにて１１０℃−３０
”
カラーコート液の経口の粘度変化並びにドラムドライヤ
ーの汚れの状態を判定Lubricant: Add 10% water (in terms of solid content) to (A) and adjust the total solid content to 43 parts Stirrer, use Kedaymill Color coating conditions Base paper: White paperboard (315&/ff1) Coating amount: 15j
J/m) Coating method: Bar coater Drying method: After air drying, use a drum dryer at 110℃-30
” Determine the oral viscosity change of color coating liquid and the state of dirt on the drum dryer.
Claims (1)
オン系界面活性剤の存在下水中で反応させ、（ｂ）その
得られた高級脂肪酸金属塩を機械的に湿式分散させ、 （Ｃ）心安に応じて、アニオン系界面活性剤を加え、 （ｄ）（ａ）の反応前、（ｂ）の分散前あるいは分散後
又は（Ｃ）の添加後のいずれかの時点で少なくとも１ｇ
Ｘのグリコールを加え、 （ｃ） メチイア型分散機、ロールミルあるいはピス
トン型旨圧乳化機又はこれらを組合せてその金属塩を強
制分散させる、 ことより得られる高級脂肪酸金属塩の水性分散液の製造
方法。[Claims] 1. (a) Reacting a compound of a higher fatty acid and a group II metal in water in the presence of a nonionic surfactant, and (b) mechanically wet-dispersing the obtained higher fatty acid metal salt. (C) Add an anionic surfactant depending on safety; (d) At any time before the reaction in (a), before or after dispersion in (b), or after the addition of (C). at least 1g
A method for producing an aqueous dispersion of a higher fatty acid metal salt obtained by adding the glycol of .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10721983A JPS59230632A (en) | 1983-06-15 | 1983-06-15 | Preparation of aqueous dispersion containing metal salt of higher fatty acid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10721983A JPS59230632A (en) | 1983-06-15 | 1983-06-15 | Preparation of aqueous dispersion containing metal salt of higher fatty acid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59230632A true JPS59230632A (en) | 1984-12-25 |
| JPH048105B2 JPH048105B2 (en) | 1992-02-14 |
Family
ID=14453505
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10721983A Granted JPS59230632A (en) | 1983-06-15 | 1983-06-15 | Preparation of aqueous dispersion containing metal salt of higher fatty acid |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59230632A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0253996A (en) * | 1988-05-20 | 1990-02-22 | Somar Corp | Paper coating solution and coated paper |
| JP2006137779A (en) * | 2004-11-10 | 2006-06-01 | San Nopco Ltd | Metallic soap for lubricant |
| WO2015104027A1 (en) * | 2014-01-08 | 2015-07-16 | Zemoura Adel | Method for producing metallic multipolar liquid soap |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5777642A (en) * | 1980-10-31 | 1982-05-15 | Kindai Kagaku Kogyo Kk | Preparation for aqueous dispersion of metallic salt of higher fatty acid |
-
1983
- 1983-06-15 JP JP10721983A patent/JPS59230632A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5777642A (en) * | 1980-10-31 | 1982-05-15 | Kindai Kagaku Kogyo Kk | Preparation for aqueous dispersion of metallic salt of higher fatty acid |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0253996A (en) * | 1988-05-20 | 1990-02-22 | Somar Corp | Paper coating solution and coated paper |
| JPH049238B2 (en) * | 1988-05-20 | 1992-02-19 | ||
| JP2006137779A (en) * | 2004-11-10 | 2006-06-01 | San Nopco Ltd | Metallic soap for lubricant |
| JP4709957B2 (en) * | 2004-11-10 | 2011-06-29 | サンノプコ株式会社 | Metal soap composition for lubricants |
| WO2015104027A1 (en) * | 2014-01-08 | 2015-07-16 | Zemoura Adel | Method for producing metallic multipolar liquid soap |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH048105B2 (en) | 1992-02-14 |
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