JPS59193273A - Method of preparing abrasion-resistant surface hardening treatment on article having irregular surface - Google Patents

Method of preparing abrasion-resistant surface hardening treatment on article having irregular surface

Info

Publication number
JPS59193273A
JPS59193273A JP2970784A JP2970784A JPS59193273A JP S59193273 A JPS59193273 A JP S59193273A JP 2970784 A JP2970784 A JP 2970784A JP 2970784 A JP2970784 A JP 2970784A JP S59193273 A JPS59193273 A JP S59193273A
Authority
JP
Japan
Prior art keywords
sheet
carbide
brazing
irregular surface
surface hardening
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2970784A
Other languages
Japanese (ja)
Inventor
デニス・イ−・シユウエル
マネク・ア−ル・ダストア−
ノ−マン・イ−・アルバ−
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Clevite Industries Inc
Original Assignee
Imperial Clevite Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Clevite Inc filed Critical Imperial Clevite Inc
Publication of JPS59193273A publication Critical patent/JPS59193273A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/32Selection of soldering or welding materials proper with the principal constituent melting at more than 1550 degrees C
    • B23K35/327Selection of soldering or welding materials proper with the principal constituent melting at more than 1550 degrees C comprising refractory compounds, e.g. carbides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K1/00Soldering, e.g. brazing, or unsoldering
    • B23K1/20Preliminary treatment of work or areas to be soldered, e.g. in respect of a galvanic coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K31/00Processes relevant to this subclass, specially adapted for particular articles or purposes, but not covered by only one of the preceding main groups
    • B23K31/02Processes relevant to this subclass, specially adapted for particular articles or purposes, but not covered by only one of the preceding main groups relating to soldering or welding
    • B23K31/025Connecting cutting edges or the like to tools; Attaching reinforcements to workpieces, e.g. wear-resisting zones to tableware
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/02Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape
    • B23K35/0222Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape for use in soldering, brazing
    • B23K35/0244Powders, particles or spheres; Preforms made therefrom
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C24/00Coating starting from inorganic powder
    • C23C24/08Coating starting from inorganic powder by application of heat or pressure and heat
    • C23C24/10Coating starting from inorganic powder by application of heat or pressure and heat with intermediate formation of a liquid phase in the layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/02Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape
    • B23K35/0222Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape for use in soldering, brazing
    • B23K35/0233Sheets, foils
    • B23K35/0238Sheets, foils layered

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Lining Or Joining Of Plastics Or The Like (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 (産業上の利用分野〉 本発明は、不規則な形状の表面を有する物品にコーテイ
ング材を被着する方法、より詳しく云うと、不規則な形
状の表面の少なくとも一部に固体粒子状の表面硬化材を
被着する方法に関する。
DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to a method of applying a coating to an article having an irregularly shaped surface, and more particularly, a method of applying a coating to an article having an irregularly shaped surface. The present invention relates to a method for applying a surface hardening material in the form of solid particles to a part.

(従来技術) 産業界においては、表面硬化′J/A(hard−fa
c i ng−mater i a l )を種々の物
品に被着することが広く行われている。然しながら、不
規則な形状の表面(irregularly・5hap
ed−surface)を有する物品にかかる材料の被
覆を施そうとする場合には、多くの問題が生ずる。
(Prior art) In industry, surface hardening 'J/A (hard-fa
BACKGROUND OF THE INVENTION It is widely practiced to apply curing-mater ial) to a variety of articles. However, irregularly shaped surfaces (irregularly・5hap
A number of problems arise when attempting to apply a coating of such materials to an article having an ed-surface.

表面に被覆を施す種々の電気めっき法が知られているが
、かかる技術は比較的薄い層を形成しようとする場合に
限定される。かかる点に対処するため、厚い層を形成し
ようとする場合には吹付(プ法が一般に採用されている
。しかしながら、この方法は「目視で行なう」ため、形
成されたコーティングの厚さが著しく不均一になるとい
う大きな欠点を有している。厚い]−ティングを被着J
る別の方法として、溶接により貼合わゼを行なう方法が
ある。しかしながら、この方法もまた、被覆を施そうと
する物品の表面形状に容易に倣うことができない場合に
は、溶接ビードが均一な厚さをもたなくなるという欠点
を有している。
Although various electroplating methods are known for applying coatings to surfaces, such techniques are limited to the formation of relatively thin layers. To address this issue, the spraying method is generally used when attempting to form a thick layer.However, since this method is ``visual'', the thickness of the formed coating may be significantly inconsistent. It has the major drawback of being uniform.
Another method is to bond by welding. However, this method also has the disadvantage that the weld bead will not have a uniform thickness if it cannot easily follow the surface topography of the article to be coated.

(発明の目的) 従って、本発明の目的は、表面硬化材の比較的厚い均一
なコーティングを不規則な形状の表面に被着する方法を
提供することにある。
OBJECTS OF THE INVENTION It is therefore an object of the present invention to provide a method for applying a relatively thick, uniform coating of hardfacing material to irregularly shaped surfaces.

本発明の別の目的は、以下の記載がら明らかになるもの
である。
Further objects of the invention will become apparent from the description below.

(発明の構成) 本発明に係る不規則表面を有する物品に耐摩耗性及び耐
食性の双方又はいずれか一方を備えた表面硬化材を被着
する方法は、ポリテトラフルオロエチレンの繊維マトリ
ックスに分散させた表面硬化材からなるシートを表面硬
化材で被覆しようとする不規則な表面を有する物品の該
不規則な表面に全体が直接接触しないが極めて接近する
ように配置する工程と、前記不規則な表面を前記表面硬
化材及び前記不規則な表面の少なくとも一部と接触しか
つ被覆するのに適したブレージング材とともに圧力応答
性の可撓性ハウジング内に配置する工程と、前記ハウジ
ングの外部に圧力を加えてハウジングを撓ませることに
より前記表面硬化材のシートに力を加えて前記不規則な
表面と直接接触させる工程と、このように処理された前
記物品を前記ポリテトラフルオロエチレンが揮発しかつ
前記入面硬化材が物品の不規則な表面に接着−する凝集
体(coherent−mass>を形成するのに充分
な温度に@す工程とを鍋えてなる構成に係るものである
(Structure of the Invention) A method of applying a surface hardening material having wear resistance and/or corrosion resistance to an article having an irregular surface according to the present invention includes dispersing it in a fiber matrix of polytetrafluoroethylene. a step of arranging a sheet made of a surface hardening material such that it is not in direct contact with the irregular surface of the article having an irregular surface to be coated with the surface hardening material, but is very close to the irregular surface; placing a surface in a pressure-responsive flexible housing with a hardfacing material and a brazing material suitable for contacting and covering at least a portion of the irregular surface; and applying pressure to the exterior of the housing. applying a force to the sheet of hardfacing material to bring it into direct contact with the irregular surface by deflecting the housing; and heating the surface hardening material to a temperature sufficient to form a coherent mass that adheres to the irregular surface of the article.

(実施例) 以下、本発明を好ましい実施例に関して説明づ−るが、
以下の実施例は、直径が約12.7mm(2インチ)の
鋼製ポル1〜のねじが切っである部分にニッケル・リッ
ヂ(nickel−rich)(7)ブレーズ合金(b
raze −a l l oy) にいれIζζ炭化タ
ングスレン被覆した例を承り−ものである。
(Example) The present invention will be described below with reference to preferred embodiments.
The following example uses nickel-rich (7) blaze alloy (b
We have received an example in which the tungsten carbide was coated with Iζζ tungsten carbide.

艮ざが約50.8mm(2インチ)′r:直径が約12
.7mm(1/2インチ)の鋼製ポル1〜を使用しlこ
 。
Approximately 50.8 mm (2 inches)'r: Diameter is approximately 12
.. Use a 7 mm (1/2 inch) steel hole.

ポル1〜は表面にグリフ1〜・ブシス1〜処理(gri
 t・blasting)を施すことにより清浄にした
。ポル1〜は直線1インチ当たり13のねし山を有しで
いた。
Pol 1~ has glyph 1~/busis 1~ treatment (gri
It was cleaned by applying t-blasting). Pol 1~ had 13 ridges per linear inch.

表面硬化材10のシートをボルト14のねじ部12上に
緩く拡げた。シート10は、65容団%の炭化タングス
テンと米国宇宙材料規格(AMS)4775に類似した
ニッケル合金35容団%とからなる固体粒子状の材料を
取込むフィブリル化したボリア1−ラフル第1コエヂレ
ンのマトリックスを有している。シート10は、クロス
(cloth)の周辺に沿って軽く塗布した接着剤16
を用いて所定の場所に保持した。しかしながら、接着剤
を使用することは重要ではない。シー1へ祠は被着しに
うとする物品上に容易に位置決めづ−ることができる。
A sheet of hardfacing material 10 was loosely spread over the threaded portion 12 of the bolt 14. Sheet 10 is a fibrillated Boria 1-Raful 1 coedylene material incorporating solid particulate material consisting of 65% by volume tungsten carbide and 35% by volume of a nickel alloy similar to American Space Materials Standard (AMS) 4775. It has a matrix of The sheet 10 has an adhesive 16 lightly applied along the periphery of the cloth.
was used to hold it in place. However, the use of adhesive is not critical. The sheath 1 can be easily positioned on the article to be deposited.

表面硬化材のシートで包囲したボルトを、可撓性のある
ゴム製のモールド18内に配置しlζ。七−ルドの口部
20は適宜のごむ栓22でシールしIC0次に、図示し
ない装置を使用して、モールドを外側から加圧した。こ
れは、加圧流体どして水を使用し等圧をかけることによ
り行った。勿論、他の外圧付与手段を利用することがで
きるが、加圧手段(よ本発明の一部をも形成Jるもので
ないから、代替加圧手段についてはここでtま述ベイT
いことにりる。
The bolt, surrounded by a sheet of surface hardening material, is placed in a flexible rubber mold 18. The opening 20 of the mold was sealed with a suitable waste stopper 22, and the mold was then pressurized from the outside using a device not shown. This was done by applying equal pressure using water as the pressurized fluid. Of course, other means for applying external pressure can be used, but as the means for applying external pressure does not form part of the present invention, alternative means for applying pressure will not be discussed here.
It's important to know.

ねじ部と接触した表面硬化及びブレーズ材の層叩Jうシ
ー1〜をイjづるねじイ・4きポル1へは次に、炉に入
れ、真空雰囲気において約1093℃(約2000’F
)の溜1度に加熱し、ボリテl〜ラフルオロ]−ヂレン
を分解させるとともに、表面硬化及びブレーズ祠から結
合凝集体を形成した。
The surface hardened and blazed material layer in contact with the threaded portion is then placed in a furnace and heated to approximately 1093°C (approximately 2000'F) in a vacuum atmosphere.
) was heated to 1 degree to decompose the bolite-l-lafluoro]-dylene and form bonded aggregates from surface hardening and blazes.

本発明は、不規則な表面を有し、かつ、表面硬化材を接
着あるいはイ」盾させるのに充分な温度に加熱したとぎ
に、分解あるいは実質上軟化を起さない物質に表面硬化
材を被着させるのに使用することができる。かかる基体
月利の主41−らのは、鋼並びにニツクル、コバル1〜
.チタン及びこれらの合金かある。
The present invention provides a method for applying a hardfacing material to a material that has an irregular surface and does not decompose or substantially soften when heated to a temperature sufficient to cause the hardfacing material to adhere or shield. It can be used to coat. The main monthly interest rates are steel, nickel, Kobal 1~
.. Are there titanium and their alloys?

本明細書におい゛C使用され−Cいる「表面硬化材のシ
ーhj  (”5heet  of  hard−1’
 a C! rl gITI a te r ! a 
l”)なる飴は、米国特許第4.194,040号明細
書に記載されでいる種類の伺J′81を云うものである
。即I5、表面便化材のシー1へは、約1乃至15容量
%のフィブリル化しり(f i br i l l a
ted)ポリテトラフルオロエチレン樹脂の71〜リツ
クスに【よば均一に分散させた約85乃至99容吊%の
固体粒子状材料から実質上なるものであり、このポリテ
トラフルオロエチレンのフィブリルは粒状飼料を互いに
結合しくi nterconnect)かつ取込むこと
によってシー1〜に自立性と−rlJ 1M性を(」勺
する。
5 sheets of hard-1' used herein.
aC! rl gITI a ter! a
1") is a candy of the type described in U.S. Pat. No. 4,194,040. to 15% by volume of fibrillated fibers (fibrillated)
ted) consists essentially of solid particulate material of about 85% to 99% solid particulate material uniformly dispersed in the 71% to 80% solids of polytetrafluoroethylene resin, the polytetrafluoroethylene fibrils forming a granular feed By interconnecting and incorporating the following, we give autonomy and -rlJ 1M property to Sea 1~.

本発明の実施にJ5いて使用されるシート月を製造する
方法が米国特許第3,864,124号明細書に記!さ
れている。このシー1〜拐は、ポリテトラフルオロエチ
レンと粒子材料との混合物を圧延、ホールミル処理(b
al 1mi l l ing)、延伸。
A method of manufacturing the sheet metal used in the practice of the present invention is described in U.S. Pat. No. 3,864,124. has been done. In this process, the mixture of polytetrafluoroethylene and particulate material is rolled and whole milled (b).
al 1mil ling), stretching.

伸長、拡張等により機械加工を行なって、なま強度が大
ぎくかつ弾性係数の小さいシー1〜あるいはマツ1へを
形成するものである。このシーI・又はマツ1〜は更に
、所望の形状に成形し、拡散及び溶融のいずれかあるい
は双方が起る濯1度に加熱してもよい。ポリテトラフル
オロエチレンは、所定の条件で機械加工づることにより
フィブリルのマトリックスに変わる。かがるフィブリル
は直径が1゜ミクロンよりも小さく、かつ、長さの直径
に対する比が10:1乃至100:1かそれ以上である
By performing mechanical processing by elongation, expansion, etc., sea 1 to pine 1 having a large raw strength and a small elastic modulus is formed. The Sea I or Pine 1 may be further formed into a desired shape and heated during rinsing to cause diffusion and/or melting. Polytetrafluoroethylene is transformed into a matrix of fibrils by machining under certain conditions. Curved fibrils have a diameter of less than 1.degree. micron and a length to diameter ratio of 10:1 to 100:1 or more.

得られたシート又はマツ1〜は弾性係数が低い点に特徴
がある。即ち、粒子材料の添加量が著しく多いにも拘ら
ず、種々様々の形状の物品に密着しかつ倣うことができ
る。クロスのような良好のドレープ適正(drapab
i l 1ty)と可撓性を有している。本発明におけ
るシー1〜の充填剤粒子は、可撓性の不織組成物(no
n−woven・corr+pos r t r on
)においで化学的あるいは金属学的に互いに結合してい
るのではない。
The obtained sheet or Pine 1~ is characterized by a low elastic modulus. That is, even though the amount of particle material added is extremely large, it can adhere to and imitate articles of various shapes. Good drapability like cloth (drapab)
It has flexibility. The filler particles of Sea 1~ in the present invention are flexible non-woven compositions (no.
n-woven・corr+pos r t r on
) are not chemically or metallurgically bonded to each other in odor.

上記したように混合物の機械加工を行なうと、ポリテト
ラフルオロエチレンがフィブリル化するとともに、この
フィブリル化により得られたフィブリルが粒子材料を捕
捉しかつ相互に結合させて、良好な可撓性と大きいなま
強度をイ11−る不織タイプのシート又はマットを形成
ターるのである。即ち、粒子材料を均一に分散させかつ
互いに結合させている編成(interwovan)又
は互イニからみ合った(i ntcrconnecte
d)フィブリルからなる三次元構造のマトリックスが上
記した混合物を以下に記載するようにし′で機械加工す
ることにより得られる。
When the mixture is machined as described above, the polytetrafluoroethylene fibrillates, and the fibrils obtained by this fibrillation trap and bind the particulate material to each other, providing good flexibility and large A non-woven type sheet or mat having a high raw strength is formed. That is, an interwoven or interconnected structure in which the particulate material is uniformly distributed and connected to each other.
d) A matrix of three-dimensional structure consisting of fibrils is obtained by machining the above mixture as described below.

シート材で使用される固体粒子状材料は、炭化物、窒化
物、珪化物及びこれらの混合物よりなる群から選ばれる
金属間研磨材料(inter−metal l ic−
abrasive−material)とすることがで
きる。また、固体粒子状材料は、ブレージング合金 (brazing−al toy)を含むコトもできる
The solid particulate material used in the sheet material is an inter-metal abrasive material selected from the group consisting of carbides, nitrides, silicides and mixtures thereof.
abrasive-material). The solid particulate material can also include brazing-altoys.

耐摩耗性材料は、実際には、炭化タングステン。The wear-resistant material is actually tungsten carbide.

炭化クロム、炭化タンタル、炭化チタン、炭化モリブデ
ン、炭化珪素、炭化硼素及びこれらの混合物よりなる群
から選ばれる炭化物であるのが好ましい。
Preferably, the carbide is selected from the group consisting of chromium carbide, tantalum carbide, titanium carbide, molybdenum carbide, silicon carbide, boron carbide, and mixtures thereof.

適当なブレージング合金としては、ニッケル。A suitable brazing alloy is nickel.

コバルト又は鉄の各合金があり、少なくとも40のロッ
クウェル硬度Cスケールを有することが好ましい。また
、融点が1200℃よりも低いニッケル。
Preferably, the cobalt or iron alloy has a Rockwell C scale of at least 40. Also, nickel has a melting point lower than 1200°C.

コバルト、銅又は銀の各合金を使用しても、良好な結果
を得ることができる。しかしながら、ブレージング合金
は本技術分野において周知であり、本発明の実施に対し
ては使用するブレージング合金は臨界的ではない。必要
なことは、ブレージング合金が強度の大きい71へリツ
クスを形成するとともに表面硬化材を不規則な表面に接
着させる機能を発揮することである。
Good results can also be obtained using cobalt, copper or silver alloys. However, brazing alloys are well known in the art, and the brazing alloy used is not critical to the practice of the present invention. What is needed is that the brazing alloy form a strong 71 helix and function to adhere the hardfacing material to irregular surfaces.

耐摩耗性材料とブレージング成分の双方の機能を、同じ
成分、例えば、ハイブリッド・ブレーズ(hybrid
−braze)f:より発揮させることができる場合が
ある。かかるハイブリッド・ブレーズの代表的なものに
、例えば、AMS−4775、4776及び4777の
材料仕様書に記載されているタイプのニッケルベースの
ブレーズがある。
The functions of both wear-resistant material and brazing component can be achieved by using the same component, e.g.
-braze) f: It may be possible to exhibit more. Typical of such hybrid brazes are, for example, nickel-based brazes of the type described in AMS-4775, 4776 and 4777 material specifications.

ブレージング材は、被覆しようとする表面に直接被着し
てもよく、あるいは米国特許第4.194.040号明
細書の記載に従って形成したクロス材として被着するこ
とができる。即ち、プレージン材は、表面硬化材のシー
トに混入することもでき、またこの材料の別のシートと
して被着することもでき、あるいは表面硬化材のシート
とのラミネ゛−トとして被着することもできるのである
The brazing material may be applied directly to the surface to be coated or as a cloth formed as described in U.S. Pat. No. 4,194,040. That is, the plasin material can be incorporated into the sheet of hardfacing material, can be applied as a separate sheet of this material, or can be applied as a laminate with the sheet of hardfacing material. You can also do it.

以上のように、本発明は、耐摩耗性の材料を不規則な形
状の物品の表面に被着して物品の物理的性質を改善する
独特な方法を提供するものである。
Thus, the present invention provides a unique method for applying abrasion resistant materials to the surface of irregularly shaped articles to improve the physical properties of the articles.

本発明は、例えば、差換え刃物(too 1bit)等
を処理して作業特性を改善するのに利用することができ
る。
The present invention can be used, for example, to improve work characteristics by processing a replacement blade (too 1 bit).

現在のところ本発明の好ましい実施例と考えられるもの
について説明してきたが、当業者であれば、本発明から
逸脱することなく種々の変更及び修正を行なうことがで
きるものであるから、かかる変更及び修正が本発明の精
神と範囲に含まれるものである限り本発明に包含される
ものである。
Although what is presently considered to be the preferred embodiment of this invention has been described, those skilled in the art will appreciate that various changes and modifications can be made without departing from this invention. Modifications are intended to be encompassed by the present invention as long as they fall within the spirit and scope of the invention.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明を実施するのに適した装置の一例を示す
概略図、第2図は本発明に従って耐摩耗性コーティング
が施されたねじの切っである鋼製シャフトの一部を示す
拡大横断面図である。 10・・・表面硬化材、12・・・ねじ部、14・・・
ポル1〜.1G・・・接着剤、18・・・ゴム製の可撓
性モールド、20・・・口部、22・・・ゴム栓。 手続補正書(自制 昭和59年 3月22日 特許庁長官  若  杉  和  夫  殿1、事件の
表示 特願昭59−29707号2、発明の名称 不規
則表面を有する物品に耐摩耗性表面硬化処理を施J方法 3、補正をする者 事件との関係 特許出願人 インペリアル・フレバイト・ インコーホレイテッド 4、代理人 東京都港区新1i4−31−6  支出ビル6階明細書 6、補正の内容 規定の大きさの活字で印刷した明細書(内容に392−
1 is a schematic diagram showing an example of equipment suitable for carrying out the invention; FIG. 2 is an enlarged view of a portion of a threaded steel shaft provided with a wear-resistant coating according to the invention; FIG. FIG. 10... Surface hardening material, 12... Threaded portion, 14...
Pol 1~. 1G...Adhesive, 18...Rubber flexible mold, 20...Mouth, 22...Rubber stopper. Procedural amendment (self-imposed March 22, 1980) Kazuo Wakasugi, Commissioner of the Patent Office1, Indication of the case: Japanese Patent Application No. 59-297072, Title of the invention: Abrasion-resistant surface hardening treatment for articles with irregular surfaces Method 3, Relationship with the case of the person making the amendment Patent applicant Imperial Frevite Incorporated 4, Agent Shin 1i4-31-6, Minato-ku, Tokyo Expenditure Building 6th Floor Specification 6, Provisions on the contents of the amendment Statement printed in font size (392-

Claims (1)

【特許請求の範囲】 (1) ボリア(ヘラフル第1」エチレンの繊維マl〜
リックスに分散させた表面硬化材からなるシートを表面
硬化材で被覆しJ:うとする不規則な表面を有する物品
の該不規則な表面に全体が直接接触しないが極めて接近
づ−るように配置する工程と、前記不規則な表面を前記
表面硬化材及び前記不規則な表面の少なくとも一部と接
触しかつ被覆づるのに適したブレージング拐とともに圧
力応答性の可撓性ハウジング内に配@づる工程と、前記
ハウジングの外部に圧力を加えてハウジングを撓ませる
ことにより前記表面硬化材のシートに力を加えて前記不
規則な表面と直接接触させる工程と、 このように処理された前記物品を前記ポリテトラフル′
A[1エチレンが揮発し・かつ前記表面硬化材が物品の
不規則な表面に接着する凝集体を形成するのに充分な温
度に暉ず工程とを備えてなる不規則表面を有する物品に
耐摩耗性表面硬化処理を施す方法。 (2) 前記表面硬化材のシー(・は約1乃至15容量
%のフィブリル化したボリテl〜ラフルAロ]−チレン
樹脂の71〜リツクスに均一に分散さt!tこ約85乃
至95容呈%の固体粒状材料から実質上なり、前記ポリ
テトラフルオロエチレンのフィブリルが前記粒状材料を
互いに結合させるとともに取込むことにより前記シー]
−に自立性と可撓性をイ」与づるものであることを特徴
とする特許請求の範囲第1項に記載の方法。 (3) 前記粒状材料は炭化物、窒化物、硼化物。 珪化物及びこれらの混合物よりなる群から選ばれる金属
間研磨材であることを特徴とする特許請求の範囲第2項
に記載の方法。 〈4) 前記金属間研磨材は炭化タングステン。 炭化クロム、炭化タンタル、炭化チタン、炭化モリブデ
ン、炭化珪素、炭化硼素、及びこれらの混金物よりなる
群から選ばれる炭化物であることを特徴とする特許請求
の範囲第3項に記載の方法。 (5) 前記ブレージング合金はニッケル合金。 コバルト合金及び鉄合金よりなる群から選ばれる合金で
あることを特徴とする特許請求の範囲第1項に記載の方
法。 (6) 前記ブレージング合金はニッケル、コバルト、
銅又は銀の合金であることを特徴とする特許請求の範囲
第1項に記載の方法。 (7) 前記ブレージング材は表面硬化材としても作用
することを特徴とする特許請求の範囲第1項に記載の方
法。 (8) 前記表面硬化材で被覆されるべき表面は最初に
ブレージング合金で被覆することを特徴とする特許請求
の範囲第1項に記載の方法。 (9) 前記ブレージング材は前記表面硬化材のシート
に混入されることを特徴とする特許請求の範囲第1項に
記載の方法。 (10)  前記ブレージング材はフィブリル化したポ
リテトラフルオロエチレンのマトリックスに分のシート
として前記不規則な表面に被着されることを特徴とする
特許請求の範囲第1項に記載の方法。 (11)  前記ブレージング材はフィブリル化したポ
リテトラフルオロエチレンのマトリックスに分散させた
粒状の表面硬化材からなる表面硬化材のシートに積層さ
れたシートとして前記不規則な表面に被着されることを
特徴とする特許請求の範囲第1項に記載の方法。
[Claims] (1) Boria (Heraful No. 1) ethylene fiber polymer
A sheet made of a surface hardening material dispersed in a liquid is coated with a surface hardening material, and the sheet is placed so that the entire surface of the article having an irregular surface does not come into direct contact with, but is very close to, the irregular surface of the article to be coated. and placing the irregular surface in a pressure-responsive flexible housing with a brazing layer suitable for contacting and covering the hardfacing material and at least a portion of the irregular surface. applying a force to the sheet of hardfacing material into direct contact with the irregular surface by applying pressure to the exterior of the housing to deflect the housing; The polytetraflu'
A[1] ethylene is volatilized and the surface hardening agent is heated to a temperature sufficient to form aggregates that adhere to the irregular surface of the article. A method of applying an abrasive surface hardening treatment. (2) About 85 to 95 volumes of the surface hardening material is uniformly dispersed in 71 to 95 volumes of the fibrillated bolite to fluorine resin of about 1 to 15% by volume. % of solid particulate material, the polytetrafluoroethylene fibrils bonding and entrapping the particulate material to each other to form the sheet]
2. A method according to claim 1, characterized in that the method is characterized in that it imparts independence and flexibility to -. (3) The particulate material is a carbide, nitride, or boride. 3. The method of claim 2, wherein the intermetallic abrasive is selected from the group consisting of silicides and mixtures thereof. <4) The intermetallic abrasive material is tungsten carbide. 4. The method according to claim 3, wherein the carbide is selected from the group consisting of chromium carbide, tantalum carbide, titanium carbide, molybdenum carbide, silicon carbide, boron carbide, and mixtures thereof. (5) The brazing alloy is a nickel alloy. The method according to claim 1, characterized in that the alloy is selected from the group consisting of cobalt alloys and iron alloys. (6) The brazing alloy is nickel, cobalt,
The method according to claim 1, characterized in that it is an alloy of copper or silver. (7) The method according to claim 1, wherein the brazing material also acts as a surface hardening material. 8. A method according to claim 1, characterized in that the surface to be coated with the hardfacing material is first coated with a brazing alloy. (9) The method of claim 1, wherein the brazing material is mixed into the sheet of surface hardening material. 10. The method of claim 1, wherein the brazing material is applied to the irregular surface as a sheet of fibrillated polytetrafluoroethylene matrix. (11) The brazing material is applied to the irregular surface as a sheet laminated to a sheet of hardfacing material comprising particulate hardfacing material dispersed in a matrix of fibrillated polytetrafluoroethylene. A method according to claim 1, characterized in:
JP2970784A 1983-02-28 1984-02-21 Method of preparing abrasion-resistant surface hardening treatment on article having irregular surface Pending JPS59193273A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US47005283A 1983-02-28 1983-02-28
US470052 1983-02-28

Publications (1)

Publication Number Publication Date
JPS59193273A true JPS59193273A (en) 1984-11-01

Family

ID=23866072

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2970784A Pending JPS59193273A (en) 1983-02-28 1984-02-21 Method of preparing abrasion-resistant surface hardening treatment on article having irregular surface

Country Status (6)

Country Link
JP (1) JPS59193273A (en)
CA (1) CA1228455A (en)
DE (1) DE3406418A1 (en)
FR (1) FR2541610A1 (en)
GB (1) GB2135698B (en)
SE (1) SE8305712L (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01169099A (en) * 1987-12-24 1989-07-04 Jdc Corp Casing for centrifugal projector

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FR2550978B1 (en) * 1983-05-26 1989-10-13 Rolls Royce METHOD FOR APPLYING SURFACE COATINGS ON ARTICLES
DE3508602A1 (en) * 1985-03-11 1986-09-11 Atilla Dipl.-Chem. Dr.-Ing. 4515 Bad Essen Akyol METHOD FOR TREATING WEAR-RESISTANT LAYERS ON TOOLS OR DEVICES
US4624860A (en) * 1985-10-15 1986-11-25 Imperial Clevite Inc. Method of applying a coating to a metal substrate using brazing material and flux
DE3708243A1 (en) * 1987-03-13 1988-09-22 Kloeckner Humboldt Deutz Ag Method for local surface treatment
US6004683A (en) * 1992-11-04 1999-12-21 C. A. Patents, L.L.C. Plural layered metal repair tape
US5348215A (en) * 1992-11-04 1994-09-20 Kevin Rafferty Method of bonding hard metal objects
WO1994011139A1 (en) * 1992-11-04 1994-05-26 Coating Applications, Inc. Metal repair tape
US6164916A (en) * 1998-11-02 2000-12-26 General Electric Company Method of applying wear-resistant materials to turbine blades, and turbine blades having wear-resistant materials
DE102006020101A1 (en) 2006-04-29 2007-10-31 Deutsches Zentrum für Luft- und Raumfahrt e.V. Harmetall wear protection layers for soft and non-hardenable metals
US8708655B2 (en) 2010-09-24 2014-04-29 United Technologies Corporation Blade for a gas turbine engine
JOP20200150A1 (en) 2011-04-06 2017-06-16 Esco Group Llc Hardfaced wearpart using brazing and associated method and assembly for manufacturing

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DE201136C (en) *
GB1049022A (en) * 1963-04-10 1966-11-23 Asahi Chemical Ind Method for coating surfaces of material
US4194040A (en) * 1969-04-23 1980-03-18 Joseph A. Teti, Jr. Article of fibrillated polytetrafluoroethylene containing high volumes of particulate material and methods of making and using same
US3876447A (en) * 1973-06-22 1975-04-08 Trw Inc Method of applying hard-facing materials
US4049432A (en) * 1976-09-30 1977-09-20 The United States Of America As Represented By The United States Energy Research And Development Administration High strength ferritic alloy-D53
DE2848997A1 (en) * 1978-11-11 1980-05-22 Eickhorn Geb Fischer Annette METHOD FOR REINFORCING WEAR PARTS

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01169099A (en) * 1987-12-24 1989-07-04 Jdc Corp Casing for centrifugal projector
JPH0578638B2 (en) * 1987-12-24 1993-10-29 Japan Dev & Construction

Also Published As

Publication number Publication date
SE8305712L (en) 1984-08-29
SE8305712D0 (en) 1983-10-18
GB2135698A (en) 1984-09-05
FR2541610A1 (en) 1984-08-31
CA1228455A (en) 1987-10-27
GB8330833D0 (en) 1983-12-29
GB2135698B (en) 1986-11-26
DE3406418A1 (en) 1984-08-30

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