JPS591910A - Combustion method of fluidized-bed boiler - Google Patents
Combustion method of fluidized-bed boilerInfo
- Publication number
- JPS591910A JPS591910A JP10828982A JP10828982A JPS591910A JP S591910 A JPS591910 A JP S591910A JP 10828982 A JP10828982 A JP 10828982A JP 10828982 A JP10828982 A JP 10828982A JP S591910 A JPS591910 A JP S591910A
- Authority
- JP
- Japan
- Prior art keywords
- fluidized bed
- coal
- exhaust gas
- nox
- combustion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000009841 combustion method Methods 0.000 title claims description 10
- 239000003245 coal Substances 0.000 claims abstract description 33
- 238000002485 combustion reaction Methods 0.000 claims abstract description 17
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims abstract description 16
- 235000011941 Tilia x europaea Nutrition 0.000 claims abstract description 16
- 239000004571 lime Substances 0.000 claims abstract description 16
- 239000000843 powder Substances 0.000 claims description 12
- 244000144977 poultry Species 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 6
- 238000006243 chemical reaction Methods 0.000 abstract description 5
- 230000009467 reduction Effects 0.000 abstract description 2
- 150000001669 calcium Chemical class 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 16
- 239000002245 particle Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 230000008569 process Effects 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 239000003546 flue gas Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000012717 electrostatic precipitator Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C10/00—Fluidised bed combustion apparatus
- F23C10/002—Fluidised bed combustion apparatus for pulverulent solid fuel
Abstract
Description
【発明の詳細な説明】
本発明は流動層ボイラの燃焼方法に関し、より詳細には
未燃焼炭の燃焼性およびSO□と石灰の反応率を向上せ
しめ、かつNOXの還元効果を高めだ流動層ボイラの燃
焼方法に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a combustion method for a fluidized bed boiler, and more specifically, the present invention relates to a combustion method for a fluidized bed boiler, which improves the combustibility of unburned coal, the reaction rate of SO□ and lime, and enhances the NOx reduction effect. Concerning boiler combustion methods.
従来、流動層ボイラ1で石炭を燃焼せしめるに際しては
、第1図に示す如く、石炭を含む石灰粉末に空気を吹き
込み、石炭粉末を石灰流動層2形成下に燃焼させ、燃焼
排ガス12に同伴される灰分を、たとえばサイクロン6
で分離し、この分離した灰分をその!、まの状態で空気
または燃焼排ガスと共に流動層ボイラの流動層2中にも
どしていた。Conventionally, when burning coal in a fluidized bed boiler 1, as shown in FIG. For example, cyclone 6
Separate this separated ash into its! The fuel was returned to the fluidized bed 2 of the fluidized bed boiler together with air or combustion exhaust gas in a still state.
しかしながら、かかる従来の燃焼方法では、下記のよう
な欠点があった。However, such conventional combustion methods have the following drawbacks.
(イ) サイクロンで分離した灰分を流動層にもどして
灰分中の未燃焼炭を更に燃焼せしめようとしたにもかか
わらず、燃焼効率はほとんど向上しない。(b) Despite attempts to return the ash separated by the cyclone to the fluidized bed to further burn the unburned coal in the ash, the combustion efficiency hardly improves.
(ロ) また、灰分中の未反応石灰の利用率の向上もほ
とんど認められない。(b) Furthermore, there is almost no improvement in the utilization rate of unreacted lime in the ash.
(ハ)燃焼排カス中のNOX含有量を低下せしめる効果
がほとんどない。(c) There is almost no effect of lowering the NOX content in the combustion exhaust residue.
そこで本発明は、かかる従来の欠点を解消すベくなされ
たものであり、未燃焼代の燃焼性を向」二せしめ、石灰
の利用率を高めると同時に排ガ“ス中のNOX含有率を
著るしく低下することができるなどの特長を有するもの
である。Therefore, the present invention has been made to eliminate such conventional drawbacks, and improves the combustibility of unburned waste, increases the utilization rate of lime, and at the same time reduces the NOX content in exhaust gas. It has the advantage of being able to significantly reduce the
すなわち本発明の流動層ボイラ燃焼方法は石炭を含む石
灰粉末に空気を吹込み、該石灰粉末の流動層を形成せし
めつつ該石炭粉末を燃焼させる流動層ボイラの燃焼方法
において、燃焼排ガスからこれに同伴される灰分を分離
して粉砕し、この粉砕した灰分を前記流動層上の空間に
供給しつつ前記石炭粉末を燃焼せしめることを特徴とす
るものである。That is, the fluidized bed boiler combustion method of the present invention is a fluidized bed boiler combustion method in which air is blown into lime powder containing coal to form a fluidized bed of the lime powder and the coal powder is combusted. This method is characterized in that the entrained ash is separated and pulverized, and the pulverized ash is supplied to the space above the fluidized bed while the coal powder is combusted.
以下、本発明を図面に示した実施例にもとづき説明する
。The present invention will be described below based on embodiments shown in the drawings.
第2図は本発明の工程を示し、通常、粒径10間以下の
石灰と石炭粉末を混合状態で、或は夫々別々に流動層ボ
イラ1のガス分散板6上に供給する。一方、燃焼に必要
な空気の一部にガス分散板3を通して供給し、石炭粉末
を多量の石灰の存在下に流動層2を形成せしめつつ燃焼
させ、残部の空気を二次空気として流動層2上の空間4
で、後述する粉砕後の灰分6の供給位置よりも後流側に
供給する。通常、この流動層2中には伝熱管14が埋設
されており、被加熱流体、たとえば水を通して水蒸気を
発生せしめる。燃焼排ガス12は、ボイラの上部空間4
から排出され、サイクロン5において排ガスに同伴され
た灰分6が分離される。灰分が分離された排ガス7は更
に電気集塵機またはバッグフィルタ8によって残存する
灰分9が除去きれた後に清浄排ガス10として大気中に
放出される。FIG. 2 shows the process of the present invention. Lime and coal powder, each having a particle size of 10 mm or less, are usually supplied in a mixed state or separately onto the gas distribution plate 6 of the fluidized bed boiler 1. On the other hand, a part of the air required for combustion is supplied through the gas distribution plate 3, and the coal powder is combusted in the presence of a large amount of lime while forming a fluidized bed 2, and the remaining air is used as secondary air to form the fluidized bed 2. upper space 4
Then, it is supplied to the downstream side of the supply position of the pulverized ash 6, which will be described later. Usually, a heat transfer tube 14 is embedded in the fluidized bed 2, and a heated fluid such as water is passed through the fluidized bed 2 to generate steam. The combustion exhaust gas 12 is sent to the upper space 4 of the boiler.
The ash 6 entrained in the exhaust gas is separated in the cyclone 5. The exhaust gas 7 from which the ash content has been separated is further removed by an electrostatic precipitator or a bag filter 8 to remove remaining ash content 9, and then released into the atmosphere as a clean exhaust gas 10.
一方、サイクロン5で分離された灰分6は、粉砕機11
で粉砕された後に、空気量たは燃焼排ガス16によって
流動層ボイラ1の流動層2上の空間4に供給される。な
お、灰分9を灰分6と同様に粉砕して、ボイラ1に同様
に供給することもできる。サイクロン5で分離された灰
分6の粒子の中には、通常その外層部が石灰とSOXと
の反応によって形成されたcaso、で覆われ、内層部
には残存する未反応のCaCO3やCaOなどカルシウ
ム系の粒子と未燃の石炭系粒子(チャー)が存在する。On the other hand, the ash 6 separated by the cyclone 5 is transported to the crusher 11.
After being crushed in , it is supplied to the space 4 above the fluidized bed 2 of the fluidized bed boiler 1 by means of an air volume or flue gas 16 . Incidentally, the ash 9 can also be crushed in the same manner as the ash 6 and supplied to the boiler 1 in the same manner. Among the particles of ash 6 separated by cyclone 5, the outer layer is usually covered with caso formed by the reaction between lime and SOX, and the inner layer is covered with remaining unreacted calcium such as CaCO3 and CaO. There are coal-based particles and unburned coal-based particles (char).
本発明においては、かかる灰分を粉砕するので未燃焼の
石炭はその表面積が増大すると共に、カルシウム系粒子
については未反応の石灰が露出した状態となり、この状
態で流動層上の空間4に導入される。In the present invention, since such ash is pulverized, the surface area of unburned coal increases, and unreacted lime of calcium-based particles is exposed, and in this state, the coal is introduced into the space 4 above the fluidized bed. Ru.
ところで、流動層の内部では、石炭粉末を燃焼に必要な
理論空気量の一部によって流動層状態下に燃焼させてい
るので、還元性ガスを生成しており、導入された残部の
空気によって更に燃焼せしめられている。すなわち流動
層上の空間は、流動層に近い部分は全体として還元性で
あり、二次空気導入後は完全に酸化性に移行している。By the way, inside the fluidized bed, coal powder is burned under fluidized bed conditions using a part of the theoretical amount of air required for combustion, so reducing gas is generated, and the remaining air introduced further reduces the amount of reducing gas. It is being burned. In other words, the space above the fluidized bed is entirely reducing in the area close to the fluidized bed, and completely transitions to oxidizing after the introduction of secondary air.
このような雰囲気の空間Nの還元性部分に粉砕した灰分
を供給したとき、流動層2内で石炭の燃焼によって生成
したNOXは、流動層2上の空間4、特に流動層2に近
い部分の還元性雰囲気において還元性ガスであるN2.
NH3゜COなどと反応してN2に還元されると共に
、微粉状灰分中の石炭と下記のようにして、NOx +
C−+cox 十N2
排ガス中のNOX含有量を低下せしめる。かかるNOX
含有量の低下効果は、粉砕した炭分を燃焼排ガスを用い
てボイラに供給したとき、流動層上の空間が還元性に保
たれ易いので、より効果的である。次に流動層2上の後
流側の空間4に供給される二次空気により、未燃焼の石
炭は再び燃焼せしめられ、また未反応の石灰は石炭燃焼
によって生成しだSOxと反応してcaso4を形成す
る。When pulverized ash is supplied to the reducing part of the space N in such an atmosphere, NOx generated by combustion of coal in the fluidized bed 2 will be absorbed into the space 4 above the fluidized bed 2, especially in the part near the fluidized bed 2. N2, which is a reducing gas in a reducing atmosphere.
NH3 is reduced to N2 by reacting with CO, etc., and NOx +
C-+cox 10N2 Reduces NOX content in exhaust gas. NOx
The effect of lowering the content is more effective when the pulverized coal is supplied to the boiler using combustion exhaust gas, since the space above the fluidized bed is easily maintained in a reducing state. Next, the unburned coal is combusted again by the secondary air supplied to the space 4 on the downstream side above the fluidized bed 2, and the unreacted lime reacts with SOx generated by coal combustion and becomes caso4. form.
以上述べた如く本発明によれば、流動床ボイラの燃焼排
ガスに同伴された灰分を分離して微粉化し、これを流動
層上の空間に供給しながら石炭粉末を燃焼せしめるので
、灰分粒子中の未燃焼石炭が更に燃焼せしめられ、従っ
て石炭の燃焼効率が著るしく向上する。まだ、灰分粒子
中の未反応石灰が再びSOxとの反応に供されるので石
灰の利用率が向上すると共に、排ガスの脱硫効果を高め
ることができる。更に本発明においては、石炭燃焼によ
って生成したNOxを微粉砕した灰分中の未燃焼石炭と
反応せしめてN2に還元することができるので、排気ガ
ス中の・NOX含有量を大巾に低下せしめることができ
る。As described above, according to the present invention, the ash entrained in the flue gas of the fluidized bed boiler is separated and pulverized, and the coal powder is combusted while being supplied to the space above the fluidized bed. The unburned coal is further combusted, thus the coal combustion efficiency is significantly improved. However, since the unreacted lime in the ash particles is again subjected to the reaction with SOx, the utilization rate of lime is improved and the desulfurization effect of exhaust gas can be enhanced. Furthermore, in the present invention, NOx generated by coal combustion can be reduced to N2 by reacting with unburned coal in the pulverized ash, thereby significantly reducing the NOx content in exhaust gas. I can do it.
このように本発明は流動層ボイラに供給される石炭の燃
焼率を高めると同時に、排ガス中のSOXおよびNOx
を低下せしめる顕著な効果を有する。In this way, the present invention increases the combustion rate of coal supplied to a fluidized bed boiler, and at the same time reduces SOX and NOx in exhaust gas.
It has a remarkable effect of reducing
第1図は従来の流動層ボイラの作動工程を示す図、第2
図は本発明の実施例の作動工程を示す図である。
1・・・流動層ボイラ、2・・・流動層、4・・・流動
層上の空間、11・・・粉砕機。
代理人 弁理士 小 川 信 −
弁理士 野 口 賢 照
弁理士斎下和彦Figure 1 shows the operating process of a conventional fluidized bed boiler, Figure 2 shows the operating process of a conventional fluidized bed boiler.
The figure is a diagram showing the operation process of an embodiment of the present invention. DESCRIPTION OF SYMBOLS 1... Fluidized bed boiler, 2... Fluidized bed, 4... Space above fluidized bed, 11... Pulverizer. Agent: Patent Attorney Shin Ogawa − Patent Attorney Ken Noguchi Teru Patent Attorney Kazuhiko Saishita
Claims (1)
の流動層を形成せしめつつ該石炭粉末を燃焼させる流動
層ボイラの燃焼方法において、燃焼排ガスからこれに同
伴される灰分を分離して粉砕し、この粉砕した灰分を前
記流動層上の空間に供給しつつ前記石炭粉末を燃焼せし
めることを特徴とする流動層ポイ2の燃焼方法。 2、 石炭の燃焼に要する理論空気量以下の空気を流動
層内に供給し、残部の空気を、粉砕した灰分の供給位置
よりも後流側の流動層上の空間に供給する特許請求の範
囲第1項記載の流動層ボイラの燃焼方法。[Claims] 1. In a fluidized bed boiler combustion method in which air is blown into lime powder containing coal and the coal powder is combusted while forming a fluidized bed of the lime powder. A combustion method for fluidized bed poultry 2, characterized in that the ash is separated and pulverized, and the pulverized ash is supplied to a space above the fluidized bed while the coal powder is combusted. 2. Claims that supply air less than the theoretical amount of air required for combustion of coal into the fluidized bed, and supply the remaining air to the space above the fluidized bed on the downstream side of the supply position of the crushed ash. The combustion method for a fluidized bed boiler according to item 1.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10828982A JPS591910A (en) | 1982-06-25 | 1982-06-25 | Combustion method of fluidized-bed boiler |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10828982A JPS591910A (en) | 1982-06-25 | 1982-06-25 | Combustion method of fluidized-bed boiler |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS591910A true JPS591910A (en) | 1984-01-07 |
Family
ID=14480889
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP10828982A Pending JPS591910A (en) | 1982-06-25 | 1982-06-25 | Combustion method of fluidized-bed boiler |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS591910A (en) |
-
1982
- 1982-06-25 JP JP10828982A patent/JPS591910A/en active Pending
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